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JP2995244B2 - Anisotropic conductive adhesive - Google Patents

Anisotropic conductive adhesive

Info

Publication number
JP2995244B2
JP2995244B2 JP4036963A JP3696392A JP2995244B2 JP 2995244 B2 JP2995244 B2 JP 2995244B2 JP 4036963 A JP4036963 A JP 4036963A JP 3696392 A JP3696392 A JP 3696392A JP 2995244 B2 JP2995244 B2 JP 2995244B2
Authority
JP
Japan
Prior art keywords
fine particles
conductive fine
wiring board
insulating adhesive
adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP4036963A
Other languages
Japanese (ja)
Other versions
JPH05209156A (en
Inventor
聡 金光
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Casio Computer Co Ltd
Original Assignee
Casio Computer Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Casio Computer Co Ltd filed Critical Casio Computer Co Ltd
Priority to JP4036963A priority Critical patent/JP2995244B2/en
Publication of JPH05209156A publication Critical patent/JPH05209156A/en
Application granted granted Critical
Publication of JP2995244B2 publication Critical patent/JP2995244B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/30Assembling printed circuits with electric components, e.g. with resistor
    • H05K3/32Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits
    • H05K3/321Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits by conductive adhesives

Landscapes

  • Adhesives Or Adhesive Processes (AREA)
  • Connections Effected By Soldering, Adhesion, Or Permanent Deformation (AREA)
  • Conductive Materials (AREA)
  • Non-Insulated Conductors (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】この発明は異方導電性接着剤に関
する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an anisotropic conductive adhesive.

【0002】[0002]

【従来の技術】例えば、一の配線基板の接続端子と他の
配線基板の接続端子とを互いに対向させた状態で導電接
続する際、導電性を有する金属等からなる導電性微粒子
を熱硬化性または光硬化性の樹脂からなる絶縁性接着剤
中に分散してなる異方導電性接着剤を用いることがあ
る。この場合、異方導電性接着剤を一の配線基板の接続
端子を含む接続部分と他の配線基板の接続端子を含む接
続部分との間に介在させ、熱圧着または光を当てながら
にての圧着をすると、異方導電性接着剤中の絶縁性接着
剤の一部が流動して逃げることにより、異方導電性接着
剤中の導電性微粒子の一部が一の配線基板の接続端子と
この接続端子と対向する他の配線基板の接続端子とに共
に接触し、これにより相対向する一の配線基板の接続端
子と他の配線基板の接続端子とが導電接続され、また隣
リ合う導電性微粒子間に介在された絶縁性接着剤が硬化
することにより、一の配線基板の接続端子を含む接続部
分と他の配線基板の接続端子を含む接続部分とが接着さ
れる。すなわち、このような異方導電性接着剤は、使用
状態において、厚さ方向には導電性を有するが、面方向
には絶縁性を有するものである。
2. Description of the Related Art For example, when conductive connection is performed in a state where connection terminals of one wiring board and connection terminals of another wiring board are opposed to each other, conductive fine particles made of conductive metal or the like are cured by thermosetting. Alternatively, an anisotropic conductive adhesive dispersed in an insulating adhesive made of a photocurable resin may be used. In this case, an anisotropic conductive adhesive is interposed between the connection part including the connection terminal of one wiring board and the connection part including the connection terminal of another wiring board, and is subjected to thermocompression bonding or light irradiation. When crimping is performed, a part of the insulating adhesive in the anisotropic conductive adhesive flows and escapes, so that a part of the conductive fine particles in the anisotropic conductive adhesive is connected to the connection terminal of one wiring board. The connection terminal and the connection terminal of the other wiring board facing each other are brought into contact with each other, whereby the connection terminal of the one wiring board and the connection terminal of the other wiring board facing each other are conductively connected, and When the insulating adhesive interposed between the conductive fine particles is cured, the connection portion including the connection terminal of one wiring board and the connection portion including the connection terminal of another wiring substrate are bonded. In other words, such an anisotropic conductive adhesive has conductivity in the thickness direction but has insulation in the surface direction in a used state.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、従来の
このような異方導電性接着剤では、絶縁性接着剤中に導
電性微粒子を分散させる際、一般に、絶縁性接着剤中に
導電性微粒子を混合した後練っているが、導電性微粒子
同士が付着して集合しやすい性質があり、このため導電
性微粒子を絶縁性接着剤中に均一に分散させにくく、絶
縁性接着剤中における導電性微粒子の分散密度に差異が
生じ、ひいては相対向する接続端子間で接続不良が生じ
たり、相隣接する接続端子間で短絡が生じたりすること
があるという問題があった。例えば、図5に示すよう
に、一の配線基板1の接続端子2と他の配線基板3の接
続端子4とを導電性微粒子5を絶縁性接着剤6中に分散
してなる異方導電性接着剤7を介して導電接続する際、
同図の左側に示すように、絶縁性接着剤6中における導
電性微粒子5の分散密度が小さすぎて相対向する接続端
子2、4間に導電性微粒子5が1つも存在しない場合、
相対向する接続端子2、4間で接続不良が生じ、一方、
同図の右側に示すように、絶縁性接着剤6中における導
電性微粒子5の分散密度が大きすぎて導電性微粒子5が
数珠つなぎに付着して集合した場合、相隣接する接続端
子2、4間で短絡が生じることになる。この発明の目的
は、絶縁性接着剤中における導電性微粒子の分散密度を
均一とすることのできる異方導電性接着剤を提供するこ
とにある。
However, in such a conventional anisotropic conductive adhesive, when the conductive fine particles are dispersed in the insulating adhesive, the conductive fine particles are generally dispersed in the insulating adhesive. Although it is kneaded after mixing, it has a property that the conductive fine particles adhere to each other and easily aggregate, so that it is difficult to uniformly disperse the conductive fine particles in the insulating adhesive, and the conductive fine particles in the insulating adhesive are used. In this case, there is a problem that a difference occurs in the dispersion density of the connection terminals, resulting in a connection failure between the connection terminals facing each other and a short circuit between the connection terminals adjacent to each other. For example, as shown in FIG. 5, a connection terminal 2 of one wiring board 1 and a connection terminal 4 of another wiring board 3 are formed by dispersing conductive fine particles 5 in an insulating adhesive 6. When conducting conductive connection via the adhesive 7,
As shown on the left side of the figure, when the dispersion density of the conductive fine particles 5 in the insulating adhesive 6 is too small and no conductive fine particles 5 exist between the connection terminals 2 and 4 facing each other,
A connection failure occurs between the connection terminals 2 and 4 facing each other.
As shown on the right side of the drawing, when the conductive fine particles 5 in the insulating adhesive 6 have too high a dispersion density and the conductive fine particles 5 adhere and bead together, the adjacent connection terminals 2 and 4 A short circuit will occur between them. An object of the present invention is to provide an anisotropic conductive adhesive capable of making the dispersion density of conductive fine particles in an insulating adhesive uniform.

【0004】[0004]

【課題を解決するための手段】この発明は、導電性微粒
子の表面に絶縁性接着剤が被膜されてなる多数の粒子を
平面状に並べたものである。
According to the present invention, a large number of particles each having a surface of conductive fine particles coated with an insulating adhesive are arranged in a plane.

【0005】[0005]

【作用】この発明によれば、導電性微粒子の表面に絶縁
性接着剤が被膜されてなる多数の粒子を平面状に並べて
なるものを例えば一の配線基板の接続端子を含む接続部
分と他の配線基板の接続端子を含む接続部分との間に介
在させ、熱圧着または光を当てながらにての圧着をする
と、導電性微粒子の表面に被膜された絶縁性接着剤の一
部が流動して逃げても、導電性微粒子がほぼそのままの
位置に保持され、したがって圧着後の絶縁性接着剤中に
おける導電性微粒子の分散密度を均一とすることができ
る。
According to the present invention, a conductive particle formed by arranging a large number of particles, each having a surface coated with an insulating adhesive on a surface, is connected to a connection portion including a connection terminal of one wiring board and another connection portion. When interposed between the connection part including the connection terminal of the wiring board and press-bonding while applying heat or light, a part of the insulating adhesive coated on the surface of the conductive fine particles flows. Even if it escapes, the conductive fine particles are held at almost the same position, and therefore, the dispersion density of the conductive fine particles in the insulating adhesive after pressure bonding can be made uniform.

【0006】[0006]

【実施例】図1はこの発明の一実施例における異方導電
性接着剤を示したものである。この異方導電性接着剤1
1は、導電性微粒子12の表面に絶縁性接着剤13が被
膜されてなる多数の粒子を樹脂からなるベースフィルム
14の上面に連続して並べて付着させたものからなって
いる。このうち導電性微粒子12は、導電性を有する金
属からなる微粒子、あるいは樹脂微粒子の表面に導電性
を有する金属薄膜をメッキや蒸着等により被膜してなる
もの等からなっている。絶縁性接着剤13は、熱硬化性
または光硬化性のエポキシ系もしくはアクリル系等の樹
脂からなっている。導電性微粒子12の表面に絶縁性接
着剤13を被膜する方法としては、絶縁性接着剤13を
形成するための樹脂を霧状にしておき、この霧状の樹脂
中に導電性微粒子12を通過させてその表面に樹脂を被
膜させる方法があり、また絶縁性接着剤13をメッキ性
を有する樹脂で形成する場合には、電気メッキや化学メ
ッキによって被膜させる方法もある。導電性微粒子12
の表面に絶縁性接着剤13が被膜されてなる多数の粒子
を長尺なベースフィルム14の上面に連続して並べて付
着させる方法としては、前記粒子を液体に混入し、これ
をベースフィルム14の上面に塗布し、この後乾燥して
その液体を蒸発させる方法がある。この液体としては、
絶縁性接着剤13がエポキシ系の樹脂からなる場合、ト
ルエン等のシンナー類を使用し、絶縁性接着剤13がア
クリル系の樹脂からなる場合、ノルマルヘキサンやテト
ラヒドロフラン等を使用する。
FIG. 1 shows an anisotropic conductive adhesive according to one embodiment of the present invention. This anisotropic conductive adhesive 1
Reference numeral 1 denotes a structure in which a number of particles obtained by coating the surface of conductive fine particles 12 with an insulating adhesive 13 are continuously arranged and adhered to the upper surface of a base film 14 made of resin. Among these, the conductive fine particles 12 are formed of fine particles made of a conductive metal, or those obtained by coating a conductive metal thin film on the surface of resin fine particles by plating or vapor deposition. The insulating adhesive 13 is made of a thermosetting or photocurable epoxy or acrylic resin. As a method of coating the surface of the conductive fine particles 12 with the insulating adhesive 13, a resin for forming the insulating adhesive 13 is atomized, and the conductive fine particles 12 pass through the mist-like resin. There is a method in which the surface is coated with a resin, and when the insulating adhesive 13 is formed of a resin having plating properties, there is also a method in which the film is formed by electroplating or chemical plating. Conductive fine particles 12
As a method of continuously arranging and adhering a number of particles formed by coating the surface of the base film 14 with the insulating adhesive 13 on the long base film 14, the particles are mixed into a liquid, and this is mixed with the base film 14. There is a method in which the liquid is evaporated on the upper surface and then dried to evaporate the liquid. As this liquid,
When the insulating adhesive 13 is made of an epoxy resin, a thinner such as toluene is used. When the insulating adhesive 13 is made of an acrylic resin, normal hexane or tetrahydrofuran is used.

【0007】次に、この異方導電性接着剤11を用いて
一の配線基板の接続端子と他の配線基板の接続端子とを
互いに対向させた状態で導電接続する場合について図2
〜図4を順に参照しながら説明する。まず、図2に示す
ように、一の配線基板21の接続端子22を含む接続部
分の上面に異方導電性接着剤11における導電性微粒子
12の表面に絶縁性接着剤13が被膜されてなる多数の
粒子が露出されている面を載置し、仮圧着して絶縁性接
着剤13を一の配線基板21の接続端子22の上面に仮
固定する。次に、ベースフィルム14を絶縁性接着剤1
3の表面から必要に応じてナイフ形状部材(図示せず)
等を用いて剥離する。この場合、剥離後のベースフィル
ム14をロールに巻き取るようにしてもよい。
Next, FIG. 2 shows a case where the connection terminals of one wiring board and the connection terminals of another wiring board are conductively connected to each other while using the anisotropic conductive adhesive 11 to face each other.
This will be described with reference to FIG. First, as shown in FIG. 2, the surface of the conductive fine particles 12 in the anisotropic conductive adhesive 11 is coated with the insulating adhesive 13 on the upper surface of the connection portion including the connection terminal 22 of one wiring board 21. The surface on which a large number of particles are exposed is placed, and temporarily press-bonded to temporarily fix the insulating adhesive 13 on the upper surface of the connection terminal 22 of one wiring board 21. Next, the base film 14 is coated with the insulating adhesive 1.
Knife-shaped member (not shown) as required from the surface of 3
It peels off using etc. In this case, the base film 14 after peeling may be wound around a roll.

【0008】ベースフィルム14を剥離すると、図3に
示すように、導電性微粒子12の表面に絶縁性接着剤1
3が被膜されてなる多数の粒子のみが平面状に並べられ
た状態で一の配線基板21の接続端子22の上面に仮固
定された状態となる。次に、この平面的に並べられて仮
固定されている粒子の上面に他の配線基板23の接続端
子24を含む接続部分の下面を位置合わせして載置す
る。そして、熱圧着または光を当てながらにての圧着を
すると、図4に示すように、導電性微粒子12の表面に
被膜された絶縁性接着剤13の一部が流動して逃げるこ
とにより、導電性微粒子12の一部が一の配線基板21
の接続端子22とこの接続端子22と対向する他の配線
基板23の接続端子24とに共に接触し、これにより相
対向する一の配線基板21の接続端子22と他の配線基
板23の接続端子24とが導電接続され、また隣り合う
導電性微粒子12の表面に被膜された各絶縁性接着剤1
3が流動して一体化した後硬化することにより、一の配
線基板21の接続端子22を含む接続部分と他の配線基
板23の接続端子24を含む接続部分とが接着される。
When the base film 14 is peeled off, as shown in FIG.
3 is temporarily fixed to the upper surface of the connection terminal 22 of one wiring board 21 in a state where only a large number of particles coated with 3 are arranged in a plane. Next, the lower surface of the connection portion including the connection terminal 24 of the other wiring substrate 23 is positioned and placed on the upper surface of the particles which are arranged and temporarily fixed in a plane. Then, when thermocompression bonding or pressure bonding is performed while applying light, as shown in FIG. 4, a part of the insulating adhesive 13 coated on the surface of the conductive fine particles 12 flows and escapes, and A part of the conductive fine particles 12 is one wiring board 21
And the connection terminal 22 of one wiring board 21 and the connection terminal of another wiring board 23 facing each other. 24 are electrically conductively connected to each other, and each of the insulating adhesives 1 coated on the surfaces of the adjacent conductive fine particles 12.
The connection part including the connection terminal 22 of one wiring board 21 and the connection part including the connection terminal 24 of the other wiring board 23 are bonded by curing after the flow 3 is integrated.

【0009】ところで、導電性微粒子12の表面に被膜
された絶縁性接着剤13の一部が流動して逃げても、導
電性微粒子12がほぼそのままの位置に保持され、した
がって絶縁性接着剤13中における導電性微粒子12の
分散密度を均一とすることができる。この結果、相対向
する接続端子22、24間に導電性微粒子12を少なく
とも1つ介在させることができ、ひいては相対向する接
続端子22、24間で接続不良が生じないようにするこ
とができ、また導電性微粒子12が数珠つなぎに付着し
て集合しないようにすることができ、ひいては相隣接す
る接続端子22、24間で短絡が生じないようにするこ
とができ、異方導電接続の信頼性が向上する。なお、配
線基板21、23は、樹脂等からなるフレキシブル基板
であってもよく、またガラスやセラミック等からなるハ
ード基板であってもよい。
By the way, even if a part of the insulating adhesive 13 coated on the surface of the conductive fine particles 12 flows and escapes, the conductive fine particles 12 are held at almost the same position. The dispersion density of the conductive fine particles 12 therein can be made uniform. As a result, at least one conductive fine particle 12 can be interposed between the opposed connection terminals 22 and 24, so that a connection failure can be prevented from occurring between the opposed connection terminals 22 and 24, In addition, the conductive fine particles 12 can be prevented from adhering to the beads in a daisy chain so that the conductive fine particles 12 do not aggregate, and thus a short circuit between the adjacent connection terminals 22 and 24 can be prevented. Is improved. The wiring boards 21 and 23 may be flexible boards made of resin or the like, or may be hard boards made of glass or ceramic.

【0010】[0010]

【発明の効果】以上説明したように、この発明によれ
ば、導電性微粒子の表面に絶縁性接着剤が被膜されてな
る多数の粒子を平面状に並べているので、導電性微粒子
の表面に被膜された絶縁性接着剤の一部が流動して逃げ
ても、導電性微粒子をほぼそのままの位置に保持するこ
とができ、したがって絶縁性接着剤中における導電性微
粒子の分散密度を均一とすることができ、ひいては異方
導電接続の信頼性を向上させることができる。
As described above, according to the present invention, since a large number of particles formed by coating the surface of the conductive fine particles with the insulating adhesive are arranged in a plane, the surface of the conductive fine particles is coated. Even if a portion of the insulating adhesive flows and escapes, the conductive fine particles can be held at almost the same position, so that the dispersion density of the conductive fine particles in the insulating adhesive is uniform. Therefore, the reliability of the anisotropic conductive connection can be improved.

【図面の簡単な説明】[Brief description of the drawings]

【図1】この発明の一実施例における異方導電性接着剤
の断面図。
FIG. 1 is a sectional view of an anisotropic conductive adhesive according to an embodiment of the present invention.

【図2】この異方導電性接着剤を一の配線基板の接続端
子を含む接続部分の上面に載置した状態の断面図。
FIG. 2 is a cross-sectional view showing a state where the anisotropic conductive adhesive is placed on the upper surface of a connection portion including a connection terminal of one wiring board.

【図3】この異方導電性接着剤のうちベースフィルムの
みを剥離した後その上面に他の配線基板の接続端子を含
む接続部分を載置する状態の断面図。
FIG. 3 is a cross-sectional view showing a state in which only a base film of the anisotropic conductive adhesive is peeled off and a connection portion including a connection terminal of another wiring board is placed on the upper surface thereof.

【図4】この異方導電性接着剤を用いて一の配線基板の
接続端子と他の配線基板の接続端子とを導電接続した状
態の断面図。
FIG. 4 is a cross-sectional view showing a state in which connection terminals of one wiring board and connection terminals of another wiring board are conductively connected using the anisotropic conductive adhesive.

【図5】従来の異方導電性接着剤の問題点を説明するた
めに示す断面図。
FIG. 5 is a cross-sectional view illustrating a problem of a conventional anisotropic conductive adhesive.

【符号の説明】[Explanation of symbols]

11 異方導電性接着剤 12 導電性微粒子 13 絶縁性接着剤 14 ベースフィルム Reference Signs List 11 anisotropic conductive adhesive 12 conductive fine particles 13 insulating adhesive 14 base film

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 導電性微粒子の表面に絶縁性接着剤が被
膜されてなる多数の粒子を平面状に並べてなることを特
徴とする異方導電性接着剤。
1. An anisotropic conductive adhesive comprising a large number of particles formed by coating a surface of conductive fine particles with an insulating adhesive on a surface.
【請求項2】 前記粒子をベースフィルム上に並べたこ
とを特徴とする請求項1記載の異方導電性接着剤。
2. The anisotropic conductive adhesive according to claim 1, wherein said particles are arranged on a base film.
JP4036963A 1992-01-29 1992-01-29 Anisotropic conductive adhesive Expired - Fee Related JP2995244B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4036963A JP2995244B2 (en) 1992-01-29 1992-01-29 Anisotropic conductive adhesive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4036963A JP2995244B2 (en) 1992-01-29 1992-01-29 Anisotropic conductive adhesive

Publications (2)

Publication Number Publication Date
JPH05209156A JPH05209156A (en) 1993-08-20
JP2995244B2 true JP2995244B2 (en) 1999-12-27

Family

ID=12484390

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4036963A Expired - Fee Related JP2995244B2 (en) 1992-01-29 1992-01-29 Anisotropic conductive adhesive

Country Status (1)

Country Link
JP (1) JP2995244B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4684087B2 (en) * 2005-11-21 2011-05-18 旭化成イーマテリアルズ株式会社 Connected structure

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