JP2805373B2 - Fluorescent cosmetics - Google Patents

Description

Description: FIELD OF THE INVENTION The present invention relates to a fluorescent cosmetic, and more particularly to an improvement of a fluorescent material thereof.

[Prior Art] Conventionally, a so-called fluorescent cosmetic which shines even in a dark place has been developed and has attracted attention as an interesting cosmetic for use at night or indoors.

These general fluorescent cosmetics contain a fluorescent dye or a fluorescent pigment. As the fluorescent dye or the fluorescent pigment, 3-hydroxypyrene-5,8,10-trisulfonic acid (JP-A-58-198410) ) And organic fluorescent substances such as pigments in which an organic fluorescent pigment is contained in a synthetic resin (JP-A-62-277316).

[Problems to be Solved by the Invention] However, in the conventional fluorescent cosmetics, the light fastness of the organic fluorescent substance itself is poor, and it is difficult to apply an organic fluorescent substance that is not derived from a natural substance to the cosmetic that is directly applied to the skin. Problems remained from the viewpoint of safety.

In particular, poor light fastness means that the fluorescent property is deteriorated when, for example, the fluorescent cosmetic is displayed at a store for a long time, which greatly restricts the production or sale of the fluorescent cosmetic.

The present invention has been made in view of the above-mentioned problems of the conventional technology, and an object of the present invention is to provide a fluorescent cosmetic having high light resistance and high safety.

[Means for Solving the Problems] As a result of intensive studies conducted by the present inventors to achieve the above object, light resistance and safety can be obtained by blending an inorganic phosphor as a phosphor blended in a fluorescent cosmetic. It has been found that the properties are greatly improved, and the present invention has been completed.

That is, the fluorescent cosmetic described in claim 1 of the present application is characterized by blending an inorganic phosphor.

The fluorescent cosmetic according to claim 2 is characterized in that the inorganic phosphor is a zinc oxide phosphor.

 Hereinafter, the configuration of the present invention will be described in detail.

The inorganic phosphor used in the present invention includes MnCl ₂ (red), Sm ₂ (SO
_{4) 3} · 8H ₂ O (orange), CaWO ₄ (blue), MgWO ₄ (blue white), C
aMoO ₄ (yellow-green), KCl: Tl (cyan), NaCl: Mn (red), Zn
O: Zn (white-green), CaS: Bi (purple), ZnS: Cu (yellow-green), ZnS: Ag
(Purple), Zn ₂ SiO ₄ : Mn (green), Ca ₃ (PO ₄ ) ₂ : Ce: Mn (red)
Besides, Y ₂ O ₃ : Eu, YVO ₄ : Eu, Y ₂ O ₂ S: Eu, (Y, Cd) BO ₃ :
Eu, 0.5MgF ₂ GeO ₂ : Mn, Zn ₂ GeO ₄ : Mn, ZnS: Cu, ZnS: Cu, A
l, (Zn, Cd) S: Cu, Zn ₂ SiO ₄ : Mn, BaMgAl ₁₄ O ₂₃ : Eu ²⁺ , Mn
²⁺ , SrGa ₂ S ₄ : Eu ²⁺ , ZnS: Cu, Co, ZnS: Ag, Cu, Y ₂ SiO ₅ : Ca, Z
nS: Ag, Ga, Cl, Ga ₂ B ₅ O ₉ Cl: Eu ²⁺ BaMgAl ₁₄ O ₂₃ : Eu ²⁺ , (Zn,
Cd) S: Ag, (Zn, Cd) S: Ag, Al, (Zn, Cd) S: Au, Al, ZnS:
Cu, Au, Al, Zn (S, Se): Ag, Zn (S, Se): AgAl, Zn (S, S
e): Cu, Zn (S, Se): Cu, Al, ZnO: Zn, Zn ₂ SiO ₄ : Mn, ZnS:
Ag, Cu, ZnS: Pb, Cu, Gd ₂ O ₂ S: Tb, La ₂ O ₂ S: Tb, Y ₃ Al ₅ O ₁₂ : C
e, (Y, Gd) ₃ Al ₅ O ₁₂ : Ce, SrGa ₂ S ₄ : Eu, Y ₂ O ₂ S: Tb, Y ₂ SiO
_{5: Tb, 3.5MgGeO 2: Mn} , 3BaMgO · 8Al 2 O 3: Eu 2+, Mn 2+, 3BaM
gO · 8Al ₂ O ₃ : Eu ²⁺ , and a luminescent composition obtained by mixing In ₂ O ₃ and ZnS: Ag in a specific amount as a composition (Japanese Patent Publication No. 52-23911), ZnO
And a ZnS: Ag phosphor mixed in a specific amount and a light-emitting composition (JP-B-53-25719).

In addition to these, various compounds are known depending on the combination of metals.

Among these compounds, a zinc oxide phosphor is most preferable in terms of safety.

Since the zinc oxide phosphor is obtained by firing zinc oxide in a reducing atmosphere such as H ₂ or CO, it is represented as ZnO: Zn, but its composition is almost the same as that of commercially available zinc oxide. is there.

Commercially available zinc oxide phosphors include P-15 # 137ZnO: Zn for scanning (low voltage) manufactured by Sylvania Corporation.

The amount of the inorganic phosphor used in the fluorescent cosmetic according to the present invention is 0.01 to 99.9% by weight.

In the present invention, when blending the inorganic phosphor into cosmetics, if necessary, silicone treatment, metal soap treatment,
Fatty acid treatment, surfactant treatment, or acid, alkali,
After performing the treatment with the inorganic salts, and further performing the composite treatment thereof, they may be blended. It may be blended with other cosmetic powders in a hybrid form.

When the inorganic phosphor used in the present invention is a zinc oxide phosphor, the photosensitive wavelength for emitting fluorescence is in the ultraviolet region (370 nm), but in order to extend the visible wavelength (400 to 650 nm), phthalic anhydride, It is preferable to perform chemical sensitization by adsorbing maleic acid or the like and dye sensitization by adsorbing triphenylmethane, cyanine, or xanthene dyes.

The cosmetic of the present invention may contain any conventionally known optional components in addition to the above-mentioned essential parts.

Such components include, for example, talc, kaolin, sericite, muscovite, phlogopite, biotite, synthetic mica, mica, lithia mica, vermiculite, magnesium carbonate, calcium carbonate, diatomaceous earth, magnesium silicate , Calcium silicate, aluminum silicate, barium silicate, barium sulfate, strontium silicate, metal tungstate, silica, hydroxyapatite, zeolite, boron nitride, inorganic powder such as ceramic powder, nylon powder, polyethylene powder, polystyrene powder Benzoguanamine powder, polytetrafluoroethylene powder, distyrene benzene polymer powder, epoxy powder, acrylic powder, organic powders such as microcrystalline cellulose, inorganic white pigments such as titanium oxide and zinc oxide, iron oxide ( Ngara), inorganic red pigments such as titanium acid iron, inorganic brown pigments such as γ-iron oxide, yellow iron oxide,
Inorganic yellow pigments such as loess, black iron oxide, inorganic black pigments such as carbon black, mango violet, inorganic violet pigments such as cobalt violet, chromium oxide, chromium hydroxide, inorganic green pigments such as cobalt titanate, Inorganic blue pigments such as ultramarine blue, navy blue, etc., titanium oxide-coated mica, titanium oxide-coated bismuth oxychloride, bismuth oxychloride, titanium oxide-coated talc, fish scale foil, colored pigments such as titanium oxide-coated mica, aluminum powder, copper powder, etc. Metal powder pigments, Red No. 201, Red No. 202, Red 204
No., Red 205, Red 220, Red 226, Red 228, Red 405, Orange 203, Orange 204, Orange 205, Yellow 401
No. and organic pigments such as Blue No. 404, Red No. 3, Red No. 104,
Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 50
No. 5, orange No. 205, yellow No. 4, yellow No. 5, yellow No. 202, yellow No. 203, green No. 3, and blue No. 1 organic pigments such as zirconium, barium or alimiuni lake, chlorophyll, β-carotene, etc. Natural pigments, squalane, liquid paraffin, petrolatum, microcrystalline wax, ozokerite, ceresin, myristic acid, palmitic acid,
Stearic acid, oleic acid, isostearic acid, cetyl alcohol, hexadecyl alcohol, oleyl alcohol, cetyl 2-ethylhexanoate, palmitic acid 2-
Ethylhexyl, 2-octyldodecyl myristate,
Neopentyl glycol di-2-ethylhexanoate, glycerol tri-2-ethylhexanoate, oleic acid 2
-Various hydrocarbons such as octyldodecyl, isopropyl myristate, glycerol triisostearate, glycerol tricoconut oil, olive oil, avocado oil, beeswax, myristyl myristate, mink oil, lanolin, silicone oil, higher fatty acids, esters of fats and oils ,
Higher alcohols, oily components such as waxes, alkyd oils and fats, resins such as urea resins, plasticizers such as camphor and acetyltributyl citrate, ultraviolet absorbers, antioxidants, preservatives, surfactants, humectants, fragrances, And thickeners.

The form of the cosmetic according to the present invention can be in the form of a powder in a medium dish, a lump, a pencil, a stick, an emulsion, a cream, a solution, a powder, and the like.

[Example] Next, the present invention will be further described with reference to examples. The present invention is not limited to these examples. The amount is shown in% by weight.

Example 1 Oily stick foundation (1) Titanium dioxide 13 (2) Kaolin 12 (3) Zinc oxide phosphor (manufactured by Sylvania) 13.7 (4) Red iron oxide 1 (5) Yellow iron oxide 0.7 (6) Black iron oxide 0.1 (7) Squalane 37 (8) Cetyl 2-ethylhexanoate 16 (9) Sorbitan sesquiolate 1 (10) Aristo wax 4 (11) Carnauba wax 1.3 (12) Fragrance 0.2 (Production method) (7) (8) (9) is blended at 80 ° C, and (1)
Add (6), mix with a disper, and TK mill. Heat and dissolve (10) and (11), add, mix and degas. After gently mixing (12), the mixture was filled in a container at 80 ° C. and cooled to obtain a stick foundation.

Comparative Example 1 In the formulation of Example 1, the zinc oxide phosphor was replaced with a non-fluorescent zinc oxide commonly used in cosmetics.
A prototype was produced by the same method as described above.

Example 1 and Comparative Example 1 were applied to the face in half and in a dark place
When viewed under a 20 W BLB phosphor, it was confirmed that Example 1 emitted green-white fluorescence, but Comparative Example 1 did not emit any fluorescence.

Example 2 Eye shadow (1) Talc 6 (2) Muscovite 55 (3) Zinc oxide phosphor (manufactured by Sylvania) 20 (4) Ultramarine blue 8 (5) Yellow iron oxide 3 (6) Black iron oxide 1 (7) Squalane 4 (8) Cetyl 2-ethylhexanoate 1.9 (9) Sorbitan sesquiolate 0.8 (10) Preservative 0.1 (11) Fragrance 0.2 (Production method) Mix (1) to (6) with a Henschel mixer and mix A mixture of (7), (8), (9), (10) and (11), which had been dissolved by heating, was sprayed, mixed, crushed, and molded into a middle plate to obtain an eye shadow.

Comparative Example 2 A sample was prepared in the same manner as in Example 2 except that the zinc oxide phosphor was replaced with zinc oxide that is usually used in cosmetics in the formulation of Example 2.

When applied to the left and right eyelids of Example 2 and Comparative Example 2 and viewed under a 20 W BLB fluorescent lamp in a dark place, it was confirmed that Example 2 emitted green-white fluorescent light. Example 2
Did not fluoresce at all.

Example 3 Blusher (1) Talc 12.6 (2) Sericite 8.1 (3) Mica 60.9 (4) Sericite 3 (5) Zinc oxide phosphor (Sylvania) 3 (6) Ultramarine blue 0.1 (7) Yellow iron oxide 0.1 (8) Red iron oxide 0.4 (9) Red No. 226 0.4 (10) Titanium mica 3 (11) Squalane 3 (12) 2-Ethylhexyl palmitate 5 (13) Preservative 0.3 (14) Fragrance 0.1 (Production method) ( 1) to (9) were mixed with a Henschel mixer, and a mixture obtained by heating and mixing (11), (12), (13) and (14) was sprayed, mixed, pulverized, and then pulverized. After that, it was molded into a middle plate to obtain a brusher.

Comparative Example 3 A prototype was prepared in the same manner as in Example 3 except that the zinc oxide phosphor was replaced with 3-hydroxypyrene-5,8,10-trisulfonic acid in the formulation of Example 3.

When Example 3 and Comparative Example 3 were applied to the left and right cheeks and viewed under a 20 W BLB fluorescent lamp in a dark place, it was confirmed that both Example 3 and Comparative Example 3 emitted fluorescence. , Example 3 and Comparative Example 3 were molded into a medium dish, and subjected to a xenon fade meter for 30 hours.
When viewed under a fluorescent lamp, Example 3 emitted fluorescent light, while Comparative Example 3 emitted no fluorescent light at all.

Example 4 Powder foundation (1) Titanium oxide 2 (2) Talc 10 (3) Muscovite 3 (4) Sericite 55 (5) Zinc oxide phosphor (manufactured by Sylvania) 5 (6) Nylon powder 12 (7) Red Iron oxide 0.5 (8) Yellow iron oxide 1 (9) Black iron oxide 0.1 (10) Silicone oil 1 (11) 2-Ethylhexyl palmitate 9 (12) Sorbitan sesquiolate 1 (13) Preservative 0.3 (14) Fragrance 0.1 (Manufacturing method) (1) to (9) were mixed with a Henschel mixer, and (10), (11), (12), (13) and (14) were mixed by heating and dissolved. Was molded into a middle plate to obtain a powder foundation.

When Example 4 was applied to the face and irradiated with a 20 W BLB fluorescent lamp in a dark place, it was confirmed that green-white fluorescence was emitted.

Example 5 Emulsion foundation (1) Stearic acid 0.4 (2) Isostearic acid 0.3 (3) Cetyl 2-ethylhexanoate 4 (4) Liquid paraffin 11 (5) POE (10) Stearyl ether 2 (6) Talc 15 ( 7) Pigment 4 (8) Cetyl alcohol 0.3 (9) Preservative 0.07 (10) Zinc oxide phosphor (manufactured by Sylvania) 3 (11) Triethanolamine 0.42 (12) Propylene glycol 5 (13) Preservative 0.02 (14) Ion exchange water 54.19 (15) Fragrance 0.3 (Production method) (1) (2) (3) (4) (5) (6) (7) (8)
After heating and dissolving (9) at 85 ° C., (10) is added and uniformly dispersed. (11) (12) (13) and (14) at 85 ℃
The mixture obtained by heating and dissolving the mixture is gradually added and emulsified. After stirring for 10 minutes while maintaining the temperature at the time of emulsification, stir and cool to 45
° C. (15) was added thereto, stirring and cooling were continued to 35 ° C., taken out and filled in a container to obtain an emulsified foundation.

When Example 5 was applied to the face and irradiated with a 20-watt BLB fluorescent lamp in a dark place, it was confirmed that green-white fluorescence was emitted.

Example 6 Makeup Base (1) Ion-exchanged water 68.164 (2) Glycerin 7 (3) Propylene glycol 7 (4) Sodium hexametaphosphate 0.01 (5) EDTA / 3Na2 hydrate 0.01 (6) Red iron oxide 0.01 (7) Yellow Iron oxide 0.001 (8) Black iron oxide 0.05 (9) Titanium dioxide (anatase) 1.5 (10) Zinc oxide phosphor (Sylvania) 0.5 (11) Caustic soda 0.2 (12) Squalane 3 (13) Cetyl 2-ethylhexano Eate 3 (14) Vaseline 1 (15) Cetostearyl alcohol 3 (16) Stearic acid 2 (17) Glyceryl monostearate 2 (18) POE (10) Stearyl ether 1 (19) Paraben 0.5 (20) Fragrance 0.1 (manufactured Method) (1) to (11) were mixed at 70 ° C, and (12) to (2)
After mixing and dissolving 0), the mixture was emulsified, deaerated, cooled, filtered, and filled to obtain a decorative base.

When Example 6 was applied to the face and irradiated with a 20 W BLB fluorescent lamp in a dark place, it was confirmed that green-white fluorescence was emitted.

Example 7 Nail enamel (1) Nitrocellulose 12 (2) Modified alkyd resin 12 (3) Acetyltributyl citrate 5 (4) n-butyl acetate 36.4 (5) Ethyl acetate 6 (6) n-butyl alcohol 2 (7 ) Toluene 21 (8) Iron oxide pigment 0.5 (9) Titanium dioxide 0.1 (10) Pearl pigment 2 (11) Zinc oxide phosphor (manufactured by Sylvania) 2 (12) Organically modified montmorillonite 1 (Manufacturing method) (1) (2) ) (3) and part of (4), (5) (6)
And (7) were dissolved, and the remaining (12) and (4) were mixed and gelled, and mixed.
(9) (10) and (11) were added and mixed and filled in a container to obtain a nail enamel.

When Example 7 was applied to a nail and irradiated with a 20 W BLB fluorescent lamp in a dark place, it was confirmed that green-white fluorescence was emitted.

Example 8 Eyeliner (1) Black iron oxide 7 (2) Titanium dioxide 5 (3) Zinc oxide phosphor (manufactured by Sylvania) 2 (4) Vinyl acetate resin emulsion 45 (5) Glycerin 6 (6) POE (20) Sorbitan monolaurate 1.8 (7) Carboxymethyl cellulose (10% aqueous solution) 18 (8) Vegum (5% aqueous dispersion) 5 (9) Deionized water 9.9 (10) Preservative 0.1 (11) Fragrance 0.2 (Production method) ) Add (5) and (6) to (9) and add (1) to (3)
And a colloid mill treatment (pigment part). The other components were mixed, the pigment portion was added at 70 ° C., and the mixture was uniformly dispersed, and then cooled and filled to obtain an eyeliner.

When Example 8 was applied to the eyelid and irradiated with a 20 W BLB fluorescent lamp in a dark place, it was confirmed that green-white fluorescence was emitted.

Example 9 Lipstick (1) Hydrocarbon wax 3 (2) Candelilla wax 1 (3) Glyceryl isostate 40 (4) Liquid paraffin 45.8 (5) Titanium dioxide 4 (6) Zinc oxide phosphor (manufactured by Sylvania) 3 (7) Organic pigment 3 (8) Fragrance 0.2 (Production method) (1) (2) (3) and (4) are heated and melted at 85 ° C, and (5) (6) and (7) are added thereto. After adding and mixing (8)
Was mixed by stirring and filled in a container to obtain a lipstick.

When Example 9 was applied to the lips and irradiated with a 20 W BLB fluorescent lamp in a dark place, it was confirmed that green-white fluorescence was emitted.

Example 10 Fancy powder (1) Zinc oxide phosphor (manufactured by Sylvania) 95 (2) Sericite 4 (3) Fragrance 1 (4) Iron oxide pigment appropriate amount (Production method) (1) (2) and (4) After mixing, (3) was added, mixed and filled into a container to obtain a fancy powder.

When Example 10 was applied to the lips and irradiated with a 20 W BLB fluorescent lamp in a dark place, it was confirmed that green-white fluorescence was emitted.

Example 11 Transparent fluorescent nail enamel (1) Nitrocellulose 12 (2) Modified alkyd resin 12 (3) Acetyl tributyl citrate 5 (4) n-butyl acetate 39 (5) Ethyl acetate 6 (6) n-butyl alcohol 2 (7) Toluene 21 (8) Fine particle zinc oxide phosphor 2 (9) Organically modified montmorillonite 1 (Production method) (1) (2) (3) and part of (4), (5) (6)
And (7) were dissolved, and the remaining (9) and (4) were mixed and gelled. The mixture was further mixed with (8) and filled in a container to obtain a nail enamel. .

In addition, the said fine particle zinc oxide fluorescent substance was manufactured as follows.

Zinc oxide phosphor P-15 # 137ZnO-Zn10 manufactured by Sylvania
0 g was put together with water 1 in a 2-volume beaker, and after sufficiently stirring, the supernatant was allowed to stand for 5 minutes, and the supernatant was filtered to obtain 20 g of a fine zinc oxide phosphor.

This nail enamel was free of roughness, had a good feeling in use, and exhibited excellent fluorescence.

Example 12 Transparent Mascara (1) Carboxyvinyl polymer (trade name: Carbopol 941) 0.5 (2) 2-amino-2-methylpropanol 0.3 (3) Dextrin (trade name: Soluble starch # 16)
10.0 (4) Sodium gluconate 0.01 (5) Purified water 82.09 (6) 1,3-butylene glycol 2.0 (7) Ethanol 5.0 (8) Methyl paraben 0.1 (9) Fine particle zinc oxide phosphor 1.0 (Production method) (5) (1), (3), (4), and (6) are dissolved in
To this, (8) was dissolved in (7), (2) and (9) were added, and the mixture was stirred uniformly to obtain a mascara.

Note that the fine particle zinc oxide phosphor was produced according to Example 11 described above.

Example 13 Body Painting (1) Olive oil 99.8 (2) Fine particle zinc oxide phosphor 0.2 (Production method) (2) was dispersed in (1) to obtain body painting.

Note that the fine particle zinc oxide phosphor was produced according to Example 11 described above.

Example 14 Eye shadow (1) Talc 6 (3) Muscovite 55 (3) Calcium tungstate phosphor 20 (4) Ultramarine blue 8 (5) Yellow iron oxide 3 (6) Black iron oxide 1 (7) Squalane 4 ( 8) Cetyl 2-ethylhexanoate 1.9 (9) Sorbitan sesquiolate 0.8 (10) Preservative 0.1 (11) Fragrance 0.2 (Production method) (1) to (6) were mixed with a Henschel mixer, and mixed with (7) ) (8) (9) A mixture obtained by dissolving (10) and (11) by heating was sprayed, mixed, pulverized, and molded into a middle plate to obtain an eye shadow.

Here, calcium tungstate phosphor (CaWO ₄ )
Has blue fluorescence, and a fluorescent color is suitable as an eye shadow.

Example 15 Eye Shadow (1) Talc 6 (2) Muscovite 55 (3) Selenium and manganese-activated calcium phosphate phosphor 20
(4) ultramarine blue 8 (5) yellow iron oxide 3 (6) black iron oxide 1 (7) squalane 4 (8) cetyl 2-ethylhexanoate 1.9 (9) sorbitan sesquiolate 0.8 (10) preservative 0.1 (11) ) Fragrance 0.2 (Production method) (1) to (6) were mixed with a Henschel mixer, and a mixture obtained by heating and dissolving (7), (8), (9), (10) and (11) was sprayed and mixed. Thereafter, it was pulverized and formed into a middle plate to obtain an eye shadow.

Here, selenium and manganese-activated calcium phosphate phosphor (Ca ₃ (PO ₄ ) ₂ : Ce: Mn) has red fluorescence, and a fluorescent color is suitable as an eye shadow.

Example 16 Eye shadow (1) Talc 10 (2) Muscovite 62 (3) Zinc oxide phosphor (manufactured by Sylvania) 20 (4) Ultramarine blue 1 (5) Squalane 4 (6) Cetyl 2-ethylhexanoate 1.9 ( 7) Sorbitan sesquiolate 0.8 (8) Preservative 0.1 (9) Fragrance 0.2 (Production method) (1) to (4) were mixed with a Henschel mixer, and (5), (6), (7), (8) and ( 9) was heated and dissolved and mixed. The mixture was sprayed, mixed, pulverized, and molded into a middle plate to obtain an eye shadow.

The zinc oxide phosphor emits green-white light, but the emission color shifts to blue based on the combination with ultramarine blue.

For this reason, the eye shadow according to the present example was light blue, but the fluorescent color when a BLB fluorescent lamp was applied in a dark place was green blue.

Here, when a calcium tungstate phosphor (CaWO ₄ ) was used instead of the zinc oxide phosphor, the eye shadow was light blue, and the fluorescent color when a BLB fluorescent lamp was applied in a dark place was blue.

When a selenium or manganese-activated calcium phosphate phosphor (Ca ₃ (PO ₄ ) ₂ : Ce: Mn) is used instead of the zinc oxide phosphor, the eye shadow is light blue and BLB in a dark place.
The fluorescent color when illuminated with a fluorescent lamp was purple.

[Effects of the Invention] As described above, according to the fluorescent cosmetic according to claim 1 or 2 of the present application, since the inorganic fluorescent substance is blended, the fluorescent cosmetic has excellent fluorescent properties and light resistance. Safety is also greatly improved.

────────────────────────────────────────────────── ─── Continuation of the front page (56) References JP-A-58-198410 (JP, A) JP-A-62-53916 (JP, A) (58) Fields investigated (Int. Cl. ⁶ , DB name) A61K 7/02

Claims (2)

(57) [Claims] 1. A fluorescent cosmetic comprising an inorganic phosphor. 2. The fluorescent cosmetic according to claim 1, wherein the inorganic phosphor is a zinc oxide phosphor.