JP2713588B2 - Cosmetic sample - Google Patents
Cosmetic sampleInfo
- Publication number
- JP2713588B2 JP2713588B2 JP63322783A JP32278388A JP2713588B2 JP 2713588 B2 JP2713588 B2 JP 2713588B2 JP 63322783 A JP63322783 A JP 63322783A JP 32278388 A JP32278388 A JP 32278388A JP 2713588 B2 JP2713588 B2 JP 2713588B2
- Authority
- JP
- Japan
- Prior art keywords
- wax
- cosmetic
- oil
- powder
- sample
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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- 239000000341 volatile oil Substances 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
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- GECRRQVLQHRVNH-MRCUWXFGSA-N 2-octyldodecyl (z)-octadec-9-enoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC GECRRQVLQHRVNH-MRCUWXFGSA-N 0.000 description 2
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- 239000012164 animal wax Substances 0.000 description 2
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- 239000002904 solvent Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
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- 239000012178 vegetable wax Substances 0.000 description 2
- XLTMWFMRJZDFFD-UHFFFAOYSA-N 1-[(2-chloro-4-nitrophenyl)diazenyl]naphthalen-2-ol Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C([N+]([O-])=O)C=C1Cl XLTMWFMRJZDFFD-UHFFFAOYSA-N 0.000 description 1
- GNCOVOVCHIHPHP-UHFFFAOYSA-N 2-[[4-[4-[(1-anilino-1,3-dioxobutan-2-yl)diazenyl]-3-chlorophenyl]-2-chlorophenyl]diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC(C(=C1)Cl)=CC=C1C(C=C1Cl)=CC=C1N=NC(C(C)=O)C(=O)NC1=CC=CC=C1 GNCOVOVCHIHPHP-UHFFFAOYSA-N 0.000 description 1
- UBVSIAHUTXHQTD-UHFFFAOYSA-N 2-n-(4-bromophenyl)-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(NC=2C=CC(Br)=CC=2)=N1 UBVSIAHUTXHQTD-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 1
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- 235000004936 Bromus mango Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- PYVHTIWHNXTVPF-UHFFFAOYSA-N F.F.F.F.C=C Chemical compound F.F.F.F.C=C PYVHTIWHNXTVPF-UHFFFAOYSA-N 0.000 description 1
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- 240000002834 Paulownia tomentosa Species 0.000 description 1
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- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
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- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052917 strontium silicate Inorganic materials 0.000 description 1
- QSQXISIULMTHLV-UHFFFAOYSA-N strontium;dioxido(oxo)silane Chemical compound [Sr+2].[O-][Si]([O-])=O QSQXISIULMTHLV-UHFFFAOYSA-N 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910001868 water Inorganic materials 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
- A45D40/0087—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks for samples
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D33/00—Containers or accessories specially adapted for handling powdery toiletry or cosmetic substances
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は化粧品見本に関し、更に詳しくは、粉体化粧
料の試供用の化粧品見本に関する。Description: TECHNICAL FIELD The present invention relates to a cosmetic sample, and more particularly, to a sample cosmetic sample for powder cosmetics.
粉体化粧料の試供用の化粧品見本として、従来次のよ
うな技術が知られている。Conventionally, the following techniques are known as a sample cosmetic sample for trial use of powder cosmetics.
例えば、パレット上に粉体化粧料がプレス成形された
プレスタイプの化粧品見本、あるいは紙に粉体化粧料が
印刷塗布された印刷タイプの化粧品見本などである。For example, there is a press-type cosmetic sample in which powder cosmetic is press-formed on a pallet, or a print-type cosmetic sample in which powder cosmetic is printed and applied on paper.
また、粉体化粧料の化粧品見本とは異なるが、溶解し
たワックス組成分に色材を分散して色材分散液を作り、
その分散液中に綿棒を入れて色材分散液を綿棒の先にじ
ゅうぶん吸収させ、次いで吸収させたその色材分散液を
綿棒の先でゲル化させた口紅タイプの試供用の化粧品見
本も知られている。Also, although different from the cosmetic sample of powder cosmetics, the coloring material is dispersed in the dissolved wax composition to make a coloring material dispersion,
Also put a cotton swab into the dispersion, absorb the colorant dispersion sufficiently with the tip of the cotton swab, and then gel the tip of the absorbed colorant dispersion with a cotton swab. Have been.
試供用の化粧品見本は無料で少量配布することを原則
とする。したがって試供用の化粧品見本はできるだけ安
価に生産されることが必要である。こうした点を考える
と、プレスタイプの化粧品見本は生産性が低くコストが
かかりすぎるという問題点があった。In principle, small samples of cosmetic samples for trial use will be distributed free of charge. Therefore, it is necessary that a sample cosmetic sample to be used is produced as inexpensively as possible. Considering these points, the press-type cosmetic sample has a problem that productivity is low and cost is too high.
また、紙に粉体化粧料を塗布して得られる化粧品見本
は、印刷の際に用いられる溶剤の種類により実際品と比
べて色が変わってしまうということがあり、使用感も異
なって、使用性も悪いという問題点があった。In addition, the cosmetic sample obtained by applying powder cosmetics to paper may change color compared to the actual product depending on the type of solvent used for printing, and the feeling of use is different, There was a problem that the sex was bad.
本発明は上記のような従来の問題点をかんがみ、実際
品と色も使用感も、更に使用性もほとんど変わらず、そ
れでいて生産も極めて容易で安価な化粧品見本を提供す
ることを技術的課題とする。In view of the conventional problems as described above, the present invention has a technical problem to provide an inexpensive cosmetic sample that is very easy to produce and has very little change in usability, usability, and usability. I do.
本発明は上記のような課題を解決するため、次のよう
な手段を採った。The present invention employs the following means in order to solve the above problems.
本発明は、粉体化粧料用の化粧品見本であり、ワック
スを5〜80重量%の割合で含有する組成物(以下「ワッ
クス組成物」という)を保持棒の端部に設けた弾性体に
保持させ、保持されたそのワックス組成物の表面に粉体
化粧料を付着させた。The present invention is a cosmetic sample for powder cosmetics, and is provided with an elastic body provided with a composition containing a wax at a ratio of 5 to 80% by weight (hereinafter referred to as "wax composition") at an end of a holding rod. The powder cosmetic was allowed to adhere to the surface of the retained wax composition.
本発明は、ワックス組成物を下地にしているため表面
の粉体化粧料を肌に付着させる場合、プレス形成された
化粧料を塗布している時とほとんど同じ使用感が得られ
る。しかも、比較的高価な粉体化粧料の使用割合も少な
いから、少量生産の場合でも経済的である。In the present invention, since the wax composition is used as a base, when the powder cosmetic on the surface is adhered to the skin, almost the same feeling in use as when applying a press-formed cosmetic is obtained. In addition, since the use ratio of relatively expensive powder cosmetics is small, it is economical even in the case of small-scale production.
例えば綿棒などの端部にワックス組成物が保持されて
用いられると、実際品であるプレス成形された商品、例
えばアイカラー、チークカラー、アイブローなどの使用
感に非常に近い使用感が得られて好ましい。For example, when the wax composition is used while being held at the end of a cotton swab or the like, a usability that is very close to the usability of a press-formed product such as an eye color, a cheek color, or an eyebrow is obtained. preferable.
このようなことは綿棒などに限らない。例えば端部に
スポンジ球が設けられているような棒体が保持棒として
用いられてもよい。その外、本製又は剛性紙で直状に形
成された棒体が用いられてもよい。端部を球状に膨らま
せた棒体でもよい。端部に膨らみを形成すると直状の場
合に比べて棒体端部に対するワックスの付着性が向上し
て好ましい。棒体の一端側にはスポンジ体が設けられ、
他端側は直状のままの棒体を保持棒とするなど、両端部
の材質を変えてもよい。両端部の材質を変えると、肌触
りの異なった2種類の化粧品を両端に同時に模して形成
した化粧品見本を得ることができる。This is not limited to swabs and the like. For example, a rod having a sponge ball provided at an end may be used as a holding rod. In addition, a bar made of a book or formed of rigid paper may be used. A rod body whose end is inflated spherically may be used. It is preferable to form a bulge at the end because the adhesion of the wax to the end of the rod body is improved as compared with the case where the rod is straight. A sponge body is provided on one end side of the rod body,
The material at both ends may be changed, for example, the other end side may be a holding rod made of a straight rod. By changing the material of the both ends, it is possible to obtain a cosmetic sample in which two types of cosmetics having different touches are simultaneously imitated and formed on both ends.
以下、本発明に係る化粧品見本を更に詳しく説明す
る。Hereinafter, the cosmetic sample according to the present invention will be described in more detail.
本発明に係る化粧品見本及びその製造方法では、ワッ
クスを主成分とする組成物が用いられる。In the cosmetic sample according to the present invention and the method for producing the same, a composition containing wax as a main component is used.
本発明で用いられるワックスとしては、例えば、植物
ロウ、鉱物ロウ、動物ロウなどの天然物系のロウが挙げ
られる。植物ロウとしては、カルナウバロウ、カンデリ
ラロウ、ベイベリーロウ、オウリキュリーロウ、エスパ
ルトロウ、サトウキビロウ、綿ロウ、ヌカロウなどがあ
る。鉱物ロウとしてはモンタンロウなどがある。動物ロ
ウとしては、ミツロウ、こん虫ロウ、鯨ロウ、セラック
ロウ、羊毛ロウなどがある。鯨ロウにはツチ鯨油、マッ
コウ鯨脳油、マッコウ鯨臓油、マッコウ鯨皮油、マッコ
ウ鯨骨油などが含まれる。羊毛ロウにはラノリン、還元
ラノリン、硬質ラノリンなどが含まれる。その外にもジ
ョジョバロウ、イボタロウなどが挙げられる。天然物系
のロウの外にも、石油系の合成ワックスが挙げられる。
本発明で用いられる石油系の合成ワックスとしては、パ
ラフィンワックス、マイクロクリスタリンワックス、ポ
リエチレン、地ロウ、ポリペンタジエンなどがある。こ
れら以外にもエポキシ系のエポキシレジンパルミトステ
アレート、さらに、例えば粘度が100万cPにも達するジ
メチルポリシロキサンのような高粘性シリコーンなどが
挙げられる。これらは単独で用いられてもよく、組み合
わされて用いられてもよい。これらのワックスの中でも
石油系の合成ワックスであるパラフィンワックス、マイ
クロクリスタリンワックス、ポリエチレンが好ましく、
特にこの三者の混合物、あるいは、エポキシ系樹脂であ
るエポキシレジンパルミトステアレートが好ましい。Examples of the wax used in the present invention include natural waxes such as vegetable wax, mineral wax, and animal wax. Examples of the vegetable wax include carnauba wax, candelilla wax, bayberry wax, ouriculi wax, esparto wax, sugarcane wax, cotton wax, and bran wax. Examples of the mineral wax include montan wax. Animal waxes include beeswax, insect wax, whale wax, shellac wax and wool wax. Whale wax includes whale whale oil, sperm whale brain oil, sperm whale gland oil, sperm whale skin oil, sperm whale bone oil, and the like. Wool waxes include lanolin, reduced lanolin, hard lanolin and the like. Other than that, there are Jojo Barlow and Ibotaro. In addition to natural waxes, synthetic waxes of petroleum type can be mentioned.
Examples of the petroleum synthetic wax used in the present invention include paraffin wax, microcrystalline wax, polyethylene, ground wax, and polypentadiene. Other than these, an epoxy-based epoxy resin palmitostearate, and a high-viscosity silicone such as dimethylpolysiloxane having a viscosity of, for example, 1,000,000 cP, may also be used. These may be used alone or in combination. Of these waxes, petroleum synthetic waxes such as paraffin wax, microcrystalline wax, and polyethylene are preferred,
In particular, a mixture of the three or epoxy resin palmitostearate, which is an epoxy resin, is preferable.
なお、上記のパラフィンワックス、マイクロクリスタ
リンワックス、ポリエチレンワックスのような粘着性の
弱いワックスを用いる場合、これらのワックスとともに
ワックス組成物中に不揮発性油分が含まれていると化粧
料のワックス組成物に対する接着性が向上して好まし
い。In addition, when a wax having low tackiness such as the above-mentioned paraffin wax, microcrystalline wax, and polyethylene wax is used, if a nonvolatile oil component is contained in the wax composition together with these waxes, the wax composition of the cosmetic may be used. It is preferable because the adhesiveness is improved.
ワックス組成物中に含めるとよい不揮発性油分には、
乾性油、半乾性油、不乾性油などの天然油が挙げられ
る。乾性植物油としては、アマニ油、エゴマ油、カヤ
油、サフラワー油、大豆油、シナギリ油、日本キリ油な
どがある。半乾性植物油としてはゴマ油、トウモロコシ
油、ナタネ油、綿実油などがある。不乾性植物油として
オリブ油、カボック油、クロモジ油、サザンカ油、茶種
油、ツバキ油、ヒマシ油、落花生油、アボカド油、アル
モンド油、パーシック油などがある。その外にも、エノ
油、ミンク油、卵黄油などが挙げられる。Non-volatile oils that may be included in the wax composition include:
Natural oils such as drying oils, semi-drying oils, and non-drying oils are included. Examples of the drying vegetable oil include linseed oil, perilla oil, kaya oil, safflower oil, soybean oil, cinnamon oil, and Japanese kiri oil. Semi-dry vegetable oils include sesame oil, corn oil, rapeseed oil, cottonseed oil and the like. Non-drying vegetable oils include olive oil, kabok oil, kuromoji oil, sasanqua oil, tea seed oil, camellia oil, castor oil, peanut oil, avocado oil, almond oil, persic oil and the like. In addition, eno oil, mink oil, egg yolk oil and the like can be mentioned.
本発明では不揮発性油分に石油系の合成油が用いられ
てもよい。例えば、流動パラフィン、スクワラン、シリ
コーン、プリスタンなどが挙げられる。石油系の合成油
としてはこの外にもエステル化合物が用いられてもよ
い。たとえば、オレイン酸オクチルドデシル、エルカ酸
オクチルドデシル、ミリスチン酸オクチルドデシル、ミ
リスチン酸イソプロピル、グリセリン脂肪酸エステルな
どが挙げられる。グリセリン脂肪酸エステルはモノエス
テルに限らず、例えばトリ−2−エチルヘキサン酸グリ
セリンなどのトリグリセリドなどでもよい。In the present invention, a petroleum-based synthetic oil may be used as the non-volatile oil component. For example, liquid paraffin, squalane, silicone, pristane and the like can be mentioned. Ester compounds may also be used as petroleum-based synthetic oils. For example, octyldodecyl oleate, octyldodecyl erucate, octyldodecyl myristate, isopropyl myristate, glycerin fatty acid ester and the like can be mentioned. The glycerin fatty acid ester is not limited to a monoester, and may be, for example, a triglyceride such as glycerin tri-2-ethylhexanoate.
上記の天然油と合成油とは単独で用いられてもよく、
同種類あるいは異なった種類同士で互いに組み合わされ
て用いられてもよい。さらに、常温で通常は硬化してい
るワックスであっても、上記のようなオイル分に加熱状
態で溶融・混合され、あるいはアルコール又は軽質流動
パラフィンのような揮発性油分に溶解されるような物質
であれば、上記のオイル分と組み合わせてあるいは単独
で、オイル分として用いることもできる。The above natural oil and synthetic oil may be used alone,
The same type or different types may be used in combination with each other. Furthermore, even if the wax is normally hardened at room temperature, it is melted and mixed with the above-mentioned oil in a heated state, or dissolved in a volatile oil such as alcohol or light liquid paraffin. If so, it can be used in combination with the above oil component or alone as the oil component.
またワックスがエポキシ系樹脂であるエポキシレジン
パルミトステアレートであるような場合には、通常、製
造時に揮発性油分がワックス組成物中に混入されて用い
られる。製造時に用いられ、ワックス組成物中に残留し
ていてもよい揮発性油分としては、例えば、軽質油流動
パラフィン、低粘度シリコーンなどが挙げられる。When the wax is epoxy resin palmitostearate, which is an epoxy resin, a volatile oil is usually mixed into the wax composition during production. Examples of volatile oils that may be used during production and that may remain in the wax composition include light oil liquid paraffin and low-viscosity silicone.
本発明でワックス組成物中のワックスの割合は、製造
時に揮発性油分が用いられない場合と、製造時に揮発性
油分が用いられる場合とで多少異なる。製造時に揮発性
油分が用いられない場合、ワックス組成物中のワックス
の割合は、通常、5〜60重量%、好ましくは20〜50重量
%が望ましい。ワックス組成物中のワックスの割合が5
重量%未満の場合は、オイル分が時間の経過とともに粉
体化粧料に浸透してしまい粉体化粧料の特性を劣化させ
る場合もあって余り好ましくない。ワックス組成物中の
ワックスの割合が60重量%を超える場合は、粉体化粧料
をじゅうぶん保持できなくなって余り好ましくない。In the present invention, the ratio of the wax in the wax composition is slightly different between the case where the volatile oil is not used during the production and the case where the volatile oil is used during the production. When no volatile oil is used during the production, the proportion of the wax in the wax composition is usually 5 to 60% by weight, preferably 20 to 50% by weight. The ratio of the wax in the wax composition is 5
If the amount is less than% by weight, the oil component penetrates into the powder cosmetic over time, and may deteriorate the properties of the powder cosmetic, which is not preferable. When the proportion of the wax in the wax composition exceeds 60% by weight, it is not preferable because the powder cosmetic cannot be held sufficiently.
製造時に揮発性油分が用いられる場合、ワックス組成
物中のワックスの割合は通常、5〜80重量%、好ましく
は10〜60重量%が望ましい。ワックス組成物中のワック
スの割合が5重量%未満の場合は化粧料のひび割れ、あ
るいは薄いはく離を生じさせ、また、保持棒に綿棒を用
い、保持棒端部の綿体にワックスを染み込ませたような
場合には綿繊維などが表面から飛び出して余り好ましく
ない。ワックス組成物中のワックスの割合が80重量%を
超える場合は、化粧料をワックス組成物に付着させにく
くなって余り好ましくない。When a volatile oil is used during the production, the proportion of the wax in the wax composition is usually 5 to 80% by weight, preferably 10 to 60% by weight. When the proportion of the wax in the wax composition was less than 5% by weight, the cosmetic was cracked or thinly peeled off, and a cotton swab was used as the holding rod, and the wax was impregnated into the cotton body at the end of the holding rod. In such a case, cotton fibers and the like jump out from the surface, which is not preferable. When the proportion of the wax in the wax composition exceeds 80% by weight, it is difficult to make the cosmetic adhere to the wax composition, which is not preferable.
本発明に係る化粧品見本でワックス組成物中に含まれ
るとよい不揮発性油分の割合は、ワックス組成物中で、
好ましくは2〜10重量%である。不揮発性油分がワック
ス中に2〜10重量%含まれるとワックスへの化粧料の付
着性が極めてよくなる。The proportion of the non-volatile oil that may be contained in the wax composition in the cosmetic sample according to the present invention is, in the wax composition,
Preferably it is 2 to 10% by weight. When the nonvolatile oil content is 2 to 10% by weight in the wax, the adhesion of the cosmetic to the wax becomes extremely good.
なお、ワックス組成物中に残留していてもよい揮発性
油分の割合は、好ましくは、5重量%以下である。In addition, the ratio of the volatile oil component that may remain in the wax composition is preferably 5% by weight or less.
上記のワックス組成物は本発明にいう保持棒の端部に
保持される。本発明で保持棒とは、例えば繊維体やスポ
ンジ体などを含んだ棒状体、例えば綿棒など、その外に
も、直状の又は非直状の棒体であって、ワックス組成物
を保持できるものを総称する。ここで繊維体とは、多孔
質、ガーゼ、海綿あるいは脱脂綿のような繊維質の成形
物をいう。スポンジ体とは、天然樹脂若しくは合成樹脂
製の弾性体成形物をいう。The above wax composition is held at the end of the holding rod according to the present invention. In the present invention, the holding rod is, for example, a rod-like body including a fibrous body or a sponge body, for example, a cotton swab, and also a straight or non-straight rod body, which can hold the wax composition. Things are collectively referred to. Here, the fibrous body refers to a fibrous molded product such as porous, gauze, sponge or absorbent cotton. The sponge body refers to an elastic molded article made of a natural resin or a synthetic resin.
本発明に係る化粧品見本及びその製造方法では、上記
のようなワックス組成物とともに粉体化粧料が用いられ
る。本発明で用いられる粉体化粧料には、アイカラー、
チークカラー、ベースメークファンデーション、アイブ
ローその外にも通常化粧料として用いられている多くの
粉体を挙げることができる。たとえば、タルク、白雲
母、合成雲母、金雲母、紅雲母、黒雲母、リチア雲母、
セリサイト、パーミキュライト、カオリン、二酸化チタ
ン、酸化チタン被覆雲母、酸化チタン被覆タルク、酸化
チタン被覆オキシ塩化ビスマス、オキシ塩化ビスマス、
魚鱗箔、着色酸化チタン被覆雲母等のパール顔料、アル
ミニウムパウダー、カッパーパウダー等の金属粉末顔
料、酸化鉄(ベンガラ)、チタン酸鉄の無機赤色顔料、
γ−酸化鉄等の無機褐色系顔料、黄酸化鉄、黄土等の無
機黄色系顔料、黒酸化鉄、カーボンブラック等の無機黒
色顔料、マンゴバイオレット、コバルトバイオレット等
の無機紫色顔料、酸化クロム、水酸化クロム、チタン酸
コバルト等の無機緑色系顔料、群青、紺青等の無機青色
系顔料、亜鉛華、ベントナイト、硫酸バリウム、金属石
けん、珪ソウ土、ケイ酸アルミニウム、ケイ酸カルシウ
ム、ケイ酸バリウム、ケイ酸マグネシウム、ケイ酸スト
ロンチウム、タングステン酸金属塩、炭酸カルシウム、
炭酸マグネシウム、酸化クロム、水酸化クロム、アルミ
ナ、ヒドロキシアパタイト、窒化ホウ素、シリカ、ナイ
ロンパウダー、ゼオライト、ベンゾグアナミンパウダ
ー、四フッ化エチレンパウダー、ポリアミドパウダー、
ポリエステルパウダー、ポリエチレンパウダー、ポリプ
ロピレンパウダー、ポリスチレンパウダー、セルロース
パウダー、赤色201号、赤色202号、赤色204号、赤色205
号、赤色220号、赤色226号、赤色228号、赤色405号、橙
色203号、橙色204号、黄色205号、黄色401号及び青色40
4号等の有機顔料、赤色3号、赤色104号、赤色106号、
赤色227号、赤色230号、赤色401号、赤色505号、橙色20
5号、黄色4号、黄色5号、黄色202号、黄色203号、緑
色3号及び青色1号のジルコニウム、バリウム又はアル
ミニウムレーキ等の有機顔料、クロロフィル、β−カロ
チン等の天然色素等が用いられる。これらは単独で用い
られてもよく、また、組み合わされて用いられてもよ
い。上記のような粉体化粧料の中でも特にアイカラー、
チークカラー、ベースメーク、アイブローがより好まし
い。In the cosmetic sample and the method for producing the same according to the present invention, a powder cosmetic is used together with the wax composition as described above. The powder cosmetic used in the present invention includes an eye color,
Teak color, base makeup foundation, eyebrow and many other powders commonly used as cosmetics can also be mentioned. For example, talc, muscovite, synthetic mica, phlogopite, biotite, biotite, lithic mica,
Sericite, permiculite, kaolin, titanium dioxide, titanium oxide coated mica, titanium oxide coated talc, titanium oxide coated bismuth oxychloride, bismuth oxychloride,
Pearl pigments such as fish scale foil, colored titanium oxide-coated mica, metal powder pigments such as aluminum powder and copper powder, iron oxide (bengara), inorganic red pigments of iron titanate,
Inorganic brown pigments such as γ-iron oxide, inorganic yellow pigments such as yellow iron oxide and loess, inorganic black pigments such as black iron oxide and carbon black, inorganic purple pigments such as mango violet and cobalt violet, chromium oxide, and water Inorganic green pigments such as chromium oxide and cobalt titanate, inorganic blue pigments such as ultramarine and navy blue, zinc white, bentonite, barium sulfate, metallic soap, sodium silicate, aluminum silicate, calcium silicate, barium silicate, Magnesium silicate, strontium silicate, metal tungstate, calcium carbonate,
Magnesium carbonate, chromium oxide, chromium hydroxide, alumina, hydroxyapatite, boron nitride, silica, nylon powder, zeolite, benzoguanamine powder, ethylene tetrafluoride powder, polyamide powder,
Polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, cellulose powder, Red 201, Red 202, Red 204, Red 205
No., Red No. 220, Red No. 226, Red No. 228, Red No. 405, Orange No. 203, Orange No. 204, Yellow No. 205, Yellow No. 401 and Blue No. 40
Organic pigments such as No. 4, Red No. 3, Red No. 104, Red No. 106,
Red 227, Red 230, Red 401, Red 505, Orange 20
No. 5, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Green No. 3 and Blue No. 1 organic pigments such as zirconium, barium or aluminum lake, natural pigments such as chlorophyll, β-carotene and the like are used. Can be These may be used alone or in combination. Especially eye color among powder cosmetics as above,
Teak color, base make and eyebrow are more preferred.
本発明で用いられるこれらの化粧料の粒度は5μ〜50
μ、好ましくは20μ程度が望ましい。The particle size of these cosmetics used in the present invention is from 5 μm to 50 μm.
μ, preferably about 20 μ.
更にこれらの粉体化粧料は例えばシリコーンとエステ
ル化合物などでなる油分でオイルコーティングされてい
るとよい。ワックス組成物の成分にもよるが、オイルコ
ーティングに用いられる油分の割合は、通常、アイカラ
ーの場合5〜25重量%、チークカラーの場合3〜20重量
%、ベースメークの場合5〜25重量%、アイブローの場
合5〜25重量%であると最も好ましい。粉体化粧料が過
度にオイルコーティングされていると、小さい圧力で圧
縮されてワックス組成物表面に容易に付着し、少量で化
粧料表面層を形成することができる。Further, these powder cosmetics are preferably oil-coated with an oil composed of, for example, silicone and an ester compound. Depending on the components of the wax composition, the proportion of oil used in the oil coating is usually 5 to 25% by weight for eye color, 3 to 20% by weight for cheek color, and 5 to 25% for base make. %, And 5 to 25% by weight in the case of eyebrow. If the powder cosmetic is excessively oil-coated, the powder cosmetic is compressed with a small pressure and easily adheres to the surface of the wax composition, and a cosmetic surface layer can be formed with a small amount.
また、上記の粉体化粧料中には香料、防腐剤、安定剤
などが発明の目的に反しないような割合で含まれていて
もよい。In addition, the above-mentioned powder cosmetics may contain a fragrance, a preservative, a stabilizer and the like in such a ratio as not to defeat the purpose of the invention.
本発明に係る化粧品見本は、通常、保持棒の端部に保
持させたワックス組成物に粉体化粧料を押し付けて付着
させることで製造される。The cosmetic sample according to the present invention is usually manufactured by pressing a powder cosmetic onto a wax composition held at an end of a holding rod and attaching the powder composition.
化粧料をワックス組成物に付着させるには、周壁や底
部などが弾性に形成されている弾性体容器中に収められ
た粉体化粧料中へ、保持棒で保持させているワックス組
成物を挿入し、弾性体容器などの外側から、例えば香
料、防腐剤、安定剤なども含んだ粉体化粧料全体を押し
付ければよい。化粧料に対するワックスの粘着性が高い
場合は強く押し付ける必要はない。押し付け圧力は、通
常、0.5〜5kg/cm2がよく、好ましくは、1.0〜4.0kg/cm2
がよい。In order to make the cosmetic adhere to the wax composition, the wax composition held by the holding rod is inserted into the powder cosmetic stored in the elastic body container whose peripheral wall and the bottom are formed elastically. Then, from the outside of the elastic container or the like, for example, the entire powder cosmetic containing a fragrance, a preservative, a stabilizer and the like may be pressed. If the wax has high adhesiveness to the cosmetic, it is not necessary to press hard. The pressing pressure is usually 0.5 to 5 kg / cm 2 , preferably 1.0 to 4.0 kg / cm 2
Is good.
なお、ワックス組成物は、例えば予め加熱若しくは適
当な溶媒に溶解され、例えば綿棒のような保持体の端部
に液状で吸収され、常温で固化されて用いられると、得
られた化粧品見本が更に使いやすくなって好ましい。The wax composition is heated or dissolved in a suitable solvent in advance, for example, absorbed in a liquid state at the end of a holder such as a cotton swab, and solidified at room temperature. It is preferable because it is easy to use.
本発明に係る化粧品見本は、ほお、目の周囲などに化
粧料を直接塗布して用いられる。製造時に揮発性油分を
用いた場合には、揮発性油分ができるだけ揮散した後に
用いるとよい。揮発性成分をじゅうぶん揮散させるため
には、ワックスなどが流動化しない温度で化粧品見本を
暖めてもよい。The cosmetic sample according to the present invention is used by directly applying a cosmetic to the cheeks, around the eyes, and the like. When a volatile oil is used at the time of production, the volatile oil is preferably used after being volatilized as much as possible. In order to sufficiently volatilize the volatile components, the cosmetic sample may be heated at a temperature at which the wax or the like does not fluidize.
以下本発明の実施例を図面を交えながら説明する。 Hereinafter, embodiments of the present invention will be described with reference to the drawings.
<実施例1> マイクロクリスタリンワックス20gとポリエチレンワ
ックス10gとの混合物で形成された30gのワックスと、不
揮発性油分のトリ−2−エチルヘキサン酸グリセリン70
gとの混合物でなるワックス組成物1を100cm3ビーカー
に採り、95℃に加熱して液状にした。次いで、保持棒で
ある家庭用綿棒2をそのビーカーの中に挿入し、綿棒2
の両端にある綿体2aにそのワックス組成物1を吸収さ
せ、その家庭用綿棒2を引き上げてワックス組成物吸収
綿棒を得た。Example 1 30 g of a wax formed of a mixture of 20 g of a microcrystalline wax and 10 g of a polyethylene wax, and glycerin 70 of tri-2-ethylhexanoate, a non-volatile oil component
The wax composition 1 consisting of a mixture of the wax composition and g was placed in a 100 cm 3 beaker and heated to 95 ° C. to make a liquid. Then, the household swab 2 as a holding stick is inserted into the beaker, and the swab 2
The wax composition 1 was absorbed in the cotton bodies 2a at both ends of the cotton swab, and the household cotton swab 2 was pulled up to obtain a wax composition-absorbing swab.
次に、エステル化合物でなるオレイン酸オクチルドデ
シルとシルコンとでなるコーティング剤4.5g、それと30
gの粉末アイカラー原料とを混合した粉末化粧料3中
に、上記で得られたワックス組成物吸収綿棒を挿入し、
綿棒の綿体2aを挿入したまま、図示外の弾性体容器の中
に置き、粉末化粧料3を容器の外から圧力2kg/m2で加圧
し、第1図に断面図で示す化粧品見本4を得た。Next, 4.5 g of a coating agent composed of octyldodecyl oleate composed of an ester compound and silcon, and 30
g of the powdered eye color raw material, and the obtained wax composition-absorbing swab inserted into the powdered cosmetic 3 mixed with
With the cotton swab 2a of the cotton swab inserted, it is placed in an elastic container (not shown), and the powder cosmetic 3 is pressurized from the outside of the container at a pressure of 2 kg / m 2 , and the cosmetic sample 4 shown in a sectional view in FIG. I got
このようにして得られた化粧品見本4を用い、目のま
ぶたの部分に粉末化粧料3を塗布した。Using the cosmetic sample 4 thus obtained, the powder cosmetic 3 was applied to the eyelids.
得られた化粧品見本4は、肌に化粧料3を塗布する
際、実際品であるプレス成形されたアイカラー商品とほ
とんど変わらない色と、使用感とを備えており、更に使
用性もほとんど変わってないということが分かった。When the cosmetic sample 4 is applied to the skin, the obtained cosmetic sample 4 has a color that is almost the same as a press-formed eye color product that is a real product and a feeling of use, and furthermore, the usability also changes. I knew it wasn't.
綿棒先端の綿体2aをカッターで2つに分割したとこ
ろ、比較的高価な粉末化粧料3は表面部分に多く付着し
て内奥部分には余り浸透していないことが分かった。し
たがって、化粧料3が付着している範囲の粉末化粧料3
の体積がじゅうぶん大きい割には、比較的高価な実際の
化粧料の付着量が決して多くないということも分かっ
た。When the cotton body 2a at the tip of the swab was divided into two parts by a cutter, it was found that the relatively expensive powder cosmetic 3 adhered much to the surface portion and did not penetrate much into the inner part. Therefore, the powdered cosmetic 3 within the range where the cosmetic 3 is attached
It was also found that the amount of the relatively expensive actual cosmetic was never large for the relatively large volume of the cosmetic.
しかもこの化粧品見本4は製造も極めて容易であると
いうことが分かった。In addition, it was found that the cosmetic sample 4 was extremely easy to manufacture.
なお、本実施例で同時に製造し化粧料3の塗布には用
いなかった化粧品見本4本を第5図の平面図、第6図断
面図に示すように、2枚の樹脂製シート11a,11bの間に
挟んで並行に並べ、その2枚のシート11a,11bを互いに
密着させた。次いで密着させたシート11a,11bに対し、
各化粧品見本1本1本の間に破断線12を入れたところ、
第5図に示すような極めてきれいな見本用の化粧品見本
セット12が得られた。また、このようにしてセットにさ
れた化粧品見本4は外周のシート11a,11bが密着して密
閉されていることによって大気との交流が絶たれ、化粧
品見本4に付着している化粧料3は長期間放置されても
変質してしまわないということも分かった。つまり、上
記のような化粧品見本セット12で化粧品見本4を保存す
ると、長期保管が可能であるということも分かった。As shown in the plan view of FIG. 5 and the cross-sectional view of FIG. 6, four resin samples 11a, 11b were manufactured at the same time in this example and were not used for applying the cosmetic 3. The two sheets 11a and 11b were brought into close contact with each other and arranged in parallel. Then, for the sheets 11a and 11b that were brought into close contact,
When a break line 12 is inserted between each cosmetic sample,
An extremely clean sample cosmetic sample set 12 as shown in FIG. 5 was obtained. In addition, the cosmetic sample 4 set as described above is cut off from the atmosphere by the outer sheets 11a and 11b being closely adhered and sealed, and the cosmetic 3 adhering to the cosmetic sample 4 is It was also found that it did not change even if it was left for a long time. In other words, it was also found that storing the cosmetic sample 4 with the cosmetic sample set 12 as described above enables long-term storage.
また、本実施例で製造し化粧料3の塗布に用いなかっ
た更に別の2本の化粧品見本4bを第7図に断面図で示す
ように凹部13が形成されている樹脂製シート14と平板な
樹脂製シート15との間に挟んで並行に並べ、密着させて
更に破断線16を入れた。Further, another two cosmetic samples 4b produced in the present example and not used for applying the cosmetic 3 were combined with a resin sheet 14 having a recess 13 as shown in a sectional view in FIG. The resin sheet 15 was arranged in parallel with the resin sheet 15 and closely adhered to each other.
<参考実験> 綿棒の先に赤い色材と油分をゲル化して含浸させてな
る口紅タイプの試供用化粧品見本について、先端部をカ
ッターで切断したところ中心部まで比較的高価な口紅化
粧料が深く染み込んでいることが分かった。<Reference experiment> A sample of a lipstick-type sample cosmetic sample made by gelling and impregnating a red colorant and oil on the tip of a cotton swab was cut at the tip with a cutter. I found that it was soaked.
<実施例2> 揮発性の軽質油流動パラフィン65gとエポキシレジン
パルミトステアレート35gとの混合物で形成されるワッ
クス組成物1を100cm3ビーカーに採り、80℃に加熱して
液状に溶解し液状のまま冷却した。次いで家庭用綿棒2
の両綿体2aにそのワックス組成物1を吸収させ、家庭用
綿棒2を引き上げて揮発性油分である軽質流動パラフィ
ンを揮散させ、ワックス組成物吸収綿棒を得た。<Example 2> taken Wax composition 1 is formed of a mixture of volatile light oil liquid paraffin 65g and an epoxy resin palmitostearate 35g in 100 cm 3 beaker, liquid soluble in the liquid by heating to 80 ° C. It was cooled as it was. Next, a household swab 2
The cotton composition 2a was absorbed with the wax composition 1, the household cotton swab 2 was pulled up, and light liquid paraffin as a volatile oil component was volatilized to obtain a wax composition-absorbing cotton swab.
次に、実施例1と同様の方法により、第1図に示すよ
うな化粧品見本4を得た。得られた化粧品見本4を用
い、目のまぶたの部分に化粧料3を塗布した。Next, a cosmetic sample 4 as shown in FIG. 1 was obtained in the same manner as in Example 1. Using the cosmetic sample 4 thus obtained, the cosmetic 3 was applied to the eyelids.
実施例1の化粧品見本4以上に肌触りがよかった外は
実施例1と同様の効果が確認された。The same effects as in Example 1 were confirmed, except that the cosmetic sample of Example 1 was better than the cosmetic sample 4 or more.
<実施例3> 綿棒2の代わりに、本製の細い棒5の両端部にスポン
ジ球6を接着した保持棒を使用した外は実施例2と同様
にし、第2図に示すような化粧品見本4を得た。<Example 3> Instead of the cotton swab 2, a cosmetic sample as shown in FIG. 2 was used in the same manner as in Example 2 except that a holding rod having a sponge ball 6 bonded to both ends of a thin rod 5 made of the present invention was used. 4 was obtained.
実施例2と同様の効果が確認された。 The same effect as in Example 2 was confirmed.
本発明は上記のような構成でなるため、粉体化粧料は
表面に付着して、粉体化粧料全体の量は決して多くな
く、しかも製造方法も極めて容易であるから少量生産の
場合であっても安価であり、また、実際品と色も使用感
も使用性もほとんど変わらない化粧品見本を得ることが
できる。Since the present invention is configured as described above, the powder cosmetic adheres to the surface, the amount of the powder cosmetic as a whole is never large, and the production method is extremely easy. However, it is possible to obtain a cosmetic sample which is inexpensive and hardly changes in color, usability and usability from the actual product.
また、オイル分を粉体化粧料に浸透させることなく粉
体化粧料の特性の劣化を防止するとともに、ワックス組
成物の表面に粉体化粧料を充分に保持させることができ
る。さらに、粉体化粧料のひび割れや薄い剥離を防止す
ることができるとともに、綿体にワックス組成物を染み
込ませた場合でも、綿繊維等が表面から飛び出すことを
防止することができる。さらに、ワックス組成物の表面
の付着性の向上を図ることができる。In addition, it is possible to prevent deterioration of the properties of the powder cosmetic without penetrating the oil component into the powder cosmetic, and to sufficiently hold the powder cosmetic on the surface of the wax composition. Furthermore, cracking and thin peeling of the powder cosmetic can be prevented, and even when the wax composition is impregnated into the cotton body, the cotton fibers and the like can be prevented from jumping out of the surface. Further, the adhesion of the surface of the wax composition can be improved.
第1図は実施例1及び2の化粧品見本図、第2図は実施
例3の化粧品見本図、第3図は化粧品見本を樹脂製シー
トの間に収めた化粧品見本セットの平面図、第4図は化
粧品見本セットの断面図、第5図は化粧品見本を2本収
めた化粧品見本セットの断面図である。 1……ワックス組成物、2……綿棒、2a……綿体、3…
…化粧料 4……化粧品見本、5……直状の木製の細い棒、6……
スポンジ球FIG. 1 is a cosmetic sample diagram of Examples 1 and 2, FIG. 2 is a cosmetic sample diagram of Example 3, FIG. 3 is a plan view of a cosmetic sample set in which the cosmetic sample is placed between resin sheets, FIG. The figure is a sectional view of a cosmetic sample set, and FIG. 5 is a sectional view of a cosmetic sample set containing two cosmetic samples. 1 .... wax composition, 2 .... cotton swab, 2a ... cotton body, 3 ....
… Cosmetics 4 …… Cosmetic sample 5 …… Straight wooden thin stick 6…
Sponge sphere
Claims (2)
組成物(以下「ワックス組成物」という)を保持棒の端
部に設けた弾性体に保持させ、保持されたそのワックス
組成物の表面に粉体化粧料を付着させた粉体化粧料用の
化粧品見本。1. A composition containing a wax in an amount of 5 to 80% by weight (hereinafter referred to as "wax composition") held on an elastic body provided at an end of a holding rod, and the held wax composition. Cosmetic sample for powder cosmetics with powder cosmetics attached to the surface of the surface.
れている請求項1記載の粉体化粧料用の化粧品見本。2. A cosmetic sample for powder cosmetics according to claim 1, wherein said elastic body is formed of cotton or sponge.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63322783A JP2713588B2 (en) | 1988-12-21 | 1988-12-21 | Cosmetic sample |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63322783A JP2713588B2 (en) | 1988-12-21 | 1988-12-21 | Cosmetic sample |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH02167104A JPH02167104A (en) | 1990-06-27 |
JP2713588B2 true JP2713588B2 (en) | 1998-02-16 |
Family
ID=18147588
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP63322783A Expired - Lifetime JP2713588B2 (en) | 1988-12-21 | 1988-12-21 | Cosmetic sample |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2713588B2 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2679879B1 (en) * | 1991-07-29 | 1993-11-26 | Oreal | METHOD FOR MANUFACTURING AN APPLICATOR ASSEMBLY CONTAINING A LOW DOSE OF MAKE-UP PRODUCT AND CORRESPONDING APPLICATOR ASSEMBLY. |
FR2767458B1 (en) * | 1997-08-21 | 1999-11-12 | Lvmh Rech | METHOD FOR MANUFACTURING A COMPACT POWDER COATED MEDIUM FOR COSMETIC USE AND MEDIUM OBTAINED THEREBY |
JP2006034416A (en) * | 2004-07-23 | 2006-02-09 | Sanritsu Kk | Liquid applicator |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4964190U (en) * | 1972-09-14 | 1974-06-05 | ||
JPS55179604U (en) * | 1979-06-11 | 1980-12-24 | ||
JPS62144939U (en) * | 1986-03-07 | 1987-09-12 |
-
1988
- 1988-12-21 JP JP63322783A patent/JP2713588B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPH02167104A (en) | 1990-06-27 |
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