JP2668970B2 - Insecticide powder - Google Patents
Insecticide powderInfo
- Publication number
- JP2668970B2 JP2668970B2 JP63195848A JP19584888A JP2668970B2 JP 2668970 B2 JP2668970 B2 JP 2668970B2 JP 63195848 A JP63195848 A JP 63195848A JP 19584888 A JP19584888 A JP 19584888A JP 2668970 B2 JP2668970 B2 JP 2668970B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- powder
- insecticidal
- sorbitan
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000843 powder Substances 0.000 title claims description 31
- 239000002917 insecticide Substances 0.000 title description 14
- 230000000749 insecticidal effect Effects 0.000 claims description 26
- QPPQHRDVPBTVEV-UHFFFAOYSA-N isopropyl dihydrogen phosphate Chemical compound CC(C)OP(O)(O)=O QPPQHRDVPBTVEV-UHFFFAOYSA-N 0.000 claims description 21
- 239000000194 fatty acid Substances 0.000 claims description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- -1 sorbitan fatty acid ester Chemical class 0.000 claims description 9
- 239000002728 pyrethroid Substances 0.000 claims description 5
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 2
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical group CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 description 13
- 230000000694 effects Effects 0.000 description 13
- 239000000454 talc Substances 0.000 description 9
- 229910052623 talc Inorganic materials 0.000 description 9
- ISRUGXGCCGIOQO-UHFFFAOYSA-N Rhoden Chemical compound CNC(=O)OC1=CC=CC=C1OC(C)C ISRUGXGCCGIOQO-UHFFFAOYSA-N 0.000 description 7
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 7
- 229960005286 carbaryl Drugs 0.000 description 7
- 238000000354 decomposition reaction Methods 0.000 description 7
- 239000004147 Sorbitan trioleate Substances 0.000 description 6
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical group CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 6
- 235000019337 sorbitan trioleate Nutrition 0.000 description 6
- 229960000391 sorbitan trioleate Drugs 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 229940108410 resmethrin Drugs 0.000 description 5
- 239000013068 control sample Substances 0.000 description 4
- 229960000490 permethrin Drugs 0.000 description 4
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 238000002156 mixing Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 2
- 241000238657 Blattella germanica Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 2
- NCHJGQKLPRTMAO-XWVZOOPGSA-N [(2R)-2-[(2R,3R,4S)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NCHJGQKLPRTMAO-XWVZOOPGSA-N 0.000 description 2
- IJCWFDPJFXGQBN-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-octadecanoyloxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCCCC IJCWFDPJFXGQBN-RYNSOKOISA-N 0.000 description 2
- 239000000073 carbamate insecticide Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 229940035044 sorbitan monolaurate Drugs 0.000 description 2
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 2
- 239000001570 sorbitan monopalmitate Substances 0.000 description 2
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 2
- 239000001589 sorbitan tristearate Substances 0.000 description 2
- 235000011078 sorbitan tristearate Nutrition 0.000 description 2
- 229960004129 sorbitan tristearate Drugs 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
【発明の詳細な説明】 ［産業上の利用分野］ 本発明は、殺虫粉剤に関し、更に詳しくは、殺虫成分
の分解が少なく、粉体性状がよく、しかも速効性が大き
い殺虫粉剤に関する。Description: TECHNICAL FIELD The present invention relates to an insecticide powder, and more particularly, to an insecticide powder which has a low decomposition of an insecticidal component, a good powder property, and a large rapid effect.
［従来の技術］ 従来、ピレスロイド系殺虫成分、カーバメート系殺虫
成分などの殺虫成分を無機質担体に担体させて殺虫粉剤
としていたが、殺虫成分の分解防止のため安定化剤を配
合すると粉剤の流動性や分散性が損なわれることが多か
った。[Prior art] Conventionally, insecticides such as pyrethroid insecticides and carbamate insecticides are carried on an inorganic carrier to form an insecticide powder. However, when a stabilizing agent is added to prevent decomposition of the insecticides, the fluidity of the dust is reduced. And the dispersibility was often impaired.
そのため、安定化剤としてイソプロピルアシドホスフ
ェートを加える［粉体と工業,1986年，第８巻，第34ペ
ージ］とか、粉剤に性状改善剤としてソルビタン脂肪酸
エステルを配合する（特公昭60−58721号公報）とかし
て粉剤の流動性の分散性の改善をはかっていた。Therefore, isopropyl acid phosphate is added as a stabilizer [powder and industry, 1986, Vol. 8, p. 34], or a sorbitan fatty acid ester is added to the powder as a property improver (Japanese Patent Publication No. 60-58721). ), It was intended to improve the fluidity and dispersibility of the powder.
［発明が解決しようとする課題］ しかしながら、これらの粉剤は殺虫成分の分解が改善
されたものの、害虫に対する作用、特にノックダウン作
用などの速効性が阻害された。この傾向はピレスロイド
系殺虫成分を用いた場合に特に顕著であった。[Problems to be Solved by the Invention] However, although these dusts have improved decomposition of insecticidal components, their effects on insect pests, particularly their immediate effects such as knockdown effects, have been impaired. This tendency was especially remarkable when the pyrethroid insecticide was used.
本発明の目的は、殺虫成分の分解が少なく、速効性が
増大し、しかも粉体性状がよい殺虫粉剤を提供すること
にある。It is an object of the present invention to provide an insecticidal powder which has less decomposition of the insecticidal component, has an increased rapid effect and has a good powder property.
［課題を解決するための手段］ 本発明者らは、これら従来の殺虫粉剤を改善すべく鋭
意研究した結果、限定量のイソプロピルアシドホスフェ
ートとソルビタン脂肪酸エステルを併用することによ
り、粉剤中の殺虫成分の分解が少なくなり、速効性が増
大し、しかも粉体性状がよくなることを見いだして本発
明を完成した。[Means for Solving the Problems] The present inventors have intensively studied to improve these conventional insecticide dusts, and as a result, by using a limited amount of isopropyl acid phosphate and a sorbitan fatty acid ester in combination, the insecticide component in the dusts was reduced. The present invention has been completed by discovering that the decomposition of the powder is reduced, the rapid effect is increased, and the powder properties are improved.
本発明の製剤は、ピレスロイド系殺虫成分とカーバメ
ート系殺虫成分の、それぞれ一種又は二種以上からなる
殺虫成分0.05〜3.0重量％、イソプロピルアシドホスフ
ェート0.2〜5.0重量％及びソルビタン脂肪酸エステル0.
05〜0.1重量％を配合した殺虫粉剤である。The formulation of the present invention comprises a pyrethroid insecticidal component and a carbamate insecticidal component, each composed of one or more of 0.05 to 3.0% by weight of an insecticidal component, 0.2 to 5.0% by weight of isopropyl acid phosphate, and a sorbitan fatty acid ester of 0.
It is an insecticidal powder containing 05 to 0.1% by weight.
本発明において、ピレスロイド系殺虫成分とは、ｄ−
テトラメスリン、ｄ−レスメトリン、ベルメトリンなど
であり、カーバメート系殺虫成分とは、カルバリル、プ
ロポクスル、メトキサジアゾンなどである。In the present invention, the pyrethroid insecticidal component is d-
Tetramethrin, d-resmethrin, velmethrin and the like, and carbamate insecticides include carbaryl, propoxur, methoxadiazone and the like.
イソプロピルアシドホスフェートとソルビタン脂肪酸
エステルの両者は前記の範囲内で併用する場合のみ殺虫
成分の分解を減少すると共に速効性を増大し、しかも粉
体性状をよくする。Both isopropyl acid phosphate and sorbitan fatty acid ester, when used together within the above range, reduce the decomposition of the insecticidal component, increase the rapid action, and improve the powder property.
この範囲外の両者の使用又はこの範囲内であっても両
者のいずれか一方の単独使用は、前記作用の一以上を低
下させる。The use of both outside this range or the use of either one alone within this range reduces one or more of the above effects.
例えば、イソプロピルアシドホスフェートを単独に用
いる場合は、殺虫成分の分解を少なくさせ速効性を増大
させるには１重量％程度の量でよいが、粉体性状が悪く
なる。1.5〜2.0重量％の量では殺虫成分の安定化と粉体
性状がよくなるが、速効性が悪くなる。For example, when isopropyl acid phosphate is used alone, an amount of about 1% by weight is sufficient to reduce the decomposition of insecticidal components and increase the rapid effect, but the powder properties deteriorate. When the amount is 1.5 to 2.0% by weight, the insecticidal component is stabilized and the powder properties are improved, but the immediate effect is deteriorated.
前記の作用をすべてよくするには、ソルビタン脂肪酸
エステルを前記の量の範囲内で配合することが必要であ
る。In order to improve all of the above effects, it is necessary to incorporate the sorbitan fatty acid ester within the above-mentioned amount.
この範囲外の配合では殺虫成分の速効性が減少するば
かりか粉体性状も悪くなる。If the composition is out of this range, not only does the immediate effect of the insecticidal component decrease, but also the powder properties deteriorate.
なお、ソルビタン脂肪酸エステルとは、ソルビタンの
モノ、ジ又はトリ脂肪酸エステルであり、ここで脂肪酸
とはオレイン酸、ラウリン酸、ステアリン酸、イソステ
アリン酸、パルミチン酸などである。最も好ましいソル
ビタン脂肪酸エステルはソルビタントリオレエートであ
る。The sorbitan fatty acid ester is a mono-, di-, or tri-fatty acid ester of sorbitan, and the fatty acid here is oleic acid, lauric acid, stearic acid, isostearic acid, palmitic acid, or the like. The most preferred sorbitan fatty acid ester is sorbitan trioleate.
本発明の殺虫粉剤に使用し得る無機質担体としては、
クレー、タルク、カオリン、炭酸カルシウム、ベントナ
イト、無水ケイ酸、ホワイトカーボンなどがある。As the inorganic carrier that can be used in the insecticide powder of the present invention,
Clay, talc, kaolin, calcium carbonate, bentonite, silicic anhydride, white carbon and the like.
この他必要に応じて香料、着色剤などを配合すること
ができる。In addition to these, a fragrance, a coloring agent and the like can be added as necessary.
本発明の殺虫粉剤は、例えば次のようにして製造する
ことができる。The insecticidal powder agent of the present invention can be produced, for example, as follows.
まず、殺虫成分、安定化剤、その他必要な添加物の所
定量に無機質担体の一部を加えて全量の40重量％程度の
粉状体を用意し、常用の混合機でこれをよく混合してプ
レミックスとする。このプレミックスに残余の無機質担
体を加えて更によく混合して本発明の殺虫粉剤を製造す
る。First, a part of the inorganic carrier is added to a predetermined amount of the insecticidal component, stabilizing agent, and other necessary additives to prepare a powdery substance of about 40% by weight of the total amount, and this is thoroughly mixed with a conventional mixer. And premix. The remaining inorganic carrier is added to the premix and mixed well to produce the insecticidal powder of the present invention.
［発明の効果］ 本発明により、殺虫成分の分解が少なく、粉体性状が
よく、しかも速効性が大きい殺虫粉剤を提供することが
できる。[Effects of the Invention] According to the present invention, it is possible to provide an insecticidal powder agent which is less likely to decompose an insecticidal component, has a good powder property, and has a rapid effect.
［実施例］ 次に実施例及び試験例を挙げて本発明を具体的に説明
する。EXAMPLES Next, the present invention will be specifically described with reference to examples and test examples.
実施例１ フラッシュミキサー機で、医療用タルク76.5部，無水
ケイ酸5.5部,d−テトラメスリン0.25部，カルバリル5.0
部，イソプロピルアシドホスフェート12.5部及びソルビ
タントリオレエート0.25部を混合し、プレミックスを得
た。Example 1 Using a flash mixer, 76.5 parts of medical talc, 5.5 parts of silicic acid anhydride, 0.25 part of d-tetramethrin, 5.0 of carbaryl.
Parts, isopropyl acid phosphate 12.5 parts and sorbitan trioleate 0.25 parts were mixed to obtain a premix.
このプレミックス40.0部と医療用タルク60.0部をＶ型
混合機で30分間均一に混合して殺虫粉剤（ｄ−テトラメ
スリン0.1重量％，カルバリル2.0重量％，イソプロピル
アシドホスフェート5.0重量％，ソルビタントリオレエ
ート0.1重量％含有）を製造した。40.0 parts of this premix and 60.0 parts of medical talc are uniformly mixed in a V-type mixer for 30 minutes, and insecticide powder (d-tetramethrin 0.1% by weight, carbaryl 2.0% by weight, isopropyl acid phosphate 5.0% by weight, sorbitan trioleate 0.1%) % By weight).
実施例２ 医療用タルク87.75部，無水ケイ酸5.5部,d−レスメト
リン0.25部，プロポクスル2.5部，イソプロピルアシド
ホスフェート3.75部及びソルビタントリステアレート0.
25部を混合し、プレミックスを得た。Example 2 87.75 parts of medical talc, 5.5 parts of silicic anhydride, 0.25 part of d-resmethrin, 2.5 parts of propoxur, 3.75 parts of isopropyl acid phosphate, and 0.5 parts of sorbitan tristearate.
25 parts were mixed to obtain a premix.
以下、実施例１と同様にして殺虫粉剤（ｄ−レスメト
リン0.1重量％，プロポクスル1.0重量％，イソプロピル
アシドホスフェート1.5重量％，ソルビタントリステア
レート0.1重量％含有）を製造した。Thereafter, an insecticidal powder (containing 0.1% by weight of d-resmethrin, 1.0% by weight of propoxur, 1.5% by weight of isopropyl acid phosphate, and 0.1% by weight of sorbitan tristearate) was produced in the same manner as in Example 1.
実施例３ 医療用タルク88.0部，無水ケイ酸5.5部，ペルメトリ
ン0.5部，プロポクスル5.0部，イソプロピルアシドホス
フェート0.75部及びソルビタンモノラウレート0.25部を
混合し、プレミックスを得た。Example 3 A premix was obtained by mixing 88.0 parts of medical talc, 5.5 parts of silicic anhydride, 0.5 part of permethrin, 5.0 parts of propoxur, 0.75 parts of isopropyl acid phosphate and 0.25 parts of sorbitan monolaurate.
以下、実施例１と同様にして殺虫粉剤（ペルメトリン
0.2重量％，プロポクスル2.0重量％，イソプロピルアシ
ドホスフェート0.3重量％，ソルビタンモノラウレート
0.1重量％含有）を製造した。Thereafter, in the same manner as in Example 1, insecticidal powder (permethrin
0.2% by weight, Propoxur 2.0% by weight, isopropyl acid phosphate 0.3% by weight, sorbitan monolaurate
0.1% by weight) was produced.
実施例４ 医療用タルク90.0部，無水ケイ酸5.5部,d−テトラメ
スリン0.5部，メトキサジアゾン2.5部，イソプロルアシ
ドホスフェート1.25部及びソルビタンモノパルミテート
0.25部を混合し、プレミックスを得た。Example 4 90.0 parts of medical talc, 5.5 parts of silicic anhydride, 0.5 part of d-tetramethrin, 2.5 parts of methoxadiazone, 1.25 parts of isoprolacidophosphate and sorbitan monopalmitate
0.25 parts were mixed to obtain a premix.
以下、実施例１と同様にして殺虫粉剤（ｄ−テトラメ
スリン0.2重量％，メトキサジアゾン1.0重量％，イソプ
ロピルアシドホスフェート0.5重量％，ソルビタンモノ
パルミテート0.1重量％含有）を製造した。Thereafter, an insecticidal powder (containing 0.2% by weight of d-tetramethrin, 1.0% by weight of methoxadiazone, 0.5% by weight of isopropyl acid phosphate, and 0.1% by weight of sorbitan monopalmitate) was produced in the same manner as in Example 1.
実施例５ 医療用タルク83.75部，無水ケイ酸5.5部,d−テトラメ
スリン0.25部,d−レスメトリン0.25部，メトキサジアゾ
ン2.5部，イソプロピルアシドホスフェート7.5部及びソ
ルビタンモノイソステアレート0.25部を混合し、プレミ
ックスを得た。Example 5 Medical talc 83.75 parts, silicic acid anhydride 5.5 parts, d-tetramethrin 0.25 parts, d-resmethrin 0.25 parts, methoxadiazone 2.5 parts, isopropyl acid phosphate 7.5 parts and sorbitan monoisostearate 0.25 parts are mixed and premixed. Got
以下、実施例１と同様にして殺虫粉剤（ｄ−テトラメ
スリン0.1重量％,d−８レスメトリン0.1重量％，メトキ
サジアゾン1.0重量％，イソプロピルアシドホスフェー
ト3.0重量％，ソルビタンモノイソステアレート0.1重量
％含有）を製造した。Hereinafter, in the same manner as in Example 1, an insecticide powder (containing 0.1% by weight of d-tetramethrin, 0.1% by weight of d-8 resmethrin, 1.0% by weight of methoxadiazone, 3.0% by weight of isopropyl acid phosphate, and 0.1% by weight of sorbitan monoisostearate) was used. Manufactured.
実施例６ 医療用タルク90.0部，無水ケイ酸5.5部,d−テトラメ
スリン0.5部，メトキサジアゾン1.25部，プロポクスル
1.25部，イソプロピルアシドホスフェート1.25部及びソ
ルビタンモノオレエート0.25部を混合し、プレミックス
を得た。Example 6 Medical talc 90.0 parts, silicic acid anhydride 5.5 parts, d-tetramethrin 0.5 part, methoxadiazone 1.25 parts, propoxur
1.25 parts, isopropyl acid phosphate 1.25 parts, and sorbitan monooleate 0.25 part were mixed to obtain a premix.
以下、実施例１と同様にして殺虫粉剤（ｄ−テトラメ
スリン0.2重量％，メトキサジアゾン0.5重量％，プロポ
クスル0.5重量％，イソプロピルアシドホスフェート0.5
重量％，ソルビタモノオレエート0.1重量％含有）を製
造した。Thereafter, in the same manner as in Example 1, the insecticide powder (d-tetramethrin 0.2% by weight, methoxadiazone 0.5% by weight, propoxur 0.5% by weight, isopropyl acid phosphate 0.5%)
% By weight, containing 0.1% by weight of sorbita monooleate).
実施例７ 医療用タルク83.50部，無水ケイ酸5.5部,d−テトラメ
スリン0.25部，ペルメトリン0.5部，カルバリル5.0部，
イソプロピルアシドホスフェート5.0部及びソルビタン
トリオレート0.25部を混合し、プレミックスを得た。Example 7 Medical talc 83.50 parts, silicic acid anhydride 5.5 parts, d-tetramethrin 0.25 part, permethrin 0.5 part, carbaryl 5.0 parts,
A premix was obtained by mixing 5.0 parts of isopropyl acid phosphate and 0.25 part of sorbitan triolate.
以下、実施例１と同様にして殺虫粉剤（ｄ−テトラメ
スリン0.1重量％，ペルメトリン0.1重量％，カルバリル
2.0重量％，イソプロピルアシドホスフェート2.0重量
％，ソルビタントリオレエート0.1重量％含有）を製造
した。Thereafter, in the same manner as in Example 1, insecticidal powder (0.1% by weight of d-tetramethrin, 0.1% by weight of permethrin, carbaryl)
2.0% by weight, 2.0% by weight of isopropyl acid phosphate and 0.1% by weight of sorbitan trioleate).
試験例１ 第１表に示す処方により、ｄ−テトラメスリン0.1重
量％，カルバリル0.3重量％、イソプロピルアシドホス
フェート及び／又はソルビタントリオレエートを種々の
割合で配合した試料１〜16を実施例１に準じて調製し
た。Test Example 1 Samples 1 to 16 containing 0.1% by weight of d-tetramethrin, 0.3% by weight of carbaryl, isopropyl acid phosphate and / or sorbitan trioleate in various ratios according to the formulation shown in Table 1 were prepared according to Example 1. Prepared.
また、対照試料としてイソプロピルアシドホスフェー
トとソルビタントリオレエートとを全く配合しないもの
をこれらの試料に準じて調製した。Further, as a control sample, a sample containing no isopropyl acid phosphate and sorbitan trioleate was prepared according to these samples.
試料１〜16と対照試料をそれぞれ別個のポリエチレン
容器に入れて密栓し、40℃，相対湿度75％の恒温条件下
に６ケ月保存した後、試料中のｄ−テトラメスリンとカ
ルバリルの量をガスクロマトグラフで分析し、配合量に
対する残存率を求めた。Samples 1 to 16 and control sample were placed in separate polyethylene containers, sealed, and stored for 6 months under constant temperature conditions of 40 ° C and relative humidity of 75%. Then, the amounts of d-tetramethrin and carbaryl in the sample were analyzed by gas chromatography. And the residual ratio with respect to the blending amount was determined.
その結果を第１表に示す。 Table 1 shows the results.
試験例２ 試験例１で調製した試料１〜16と対照試料について、
チャバネゴキブリ（成虫オス）を用いてその効力試験を
紙接触法で行った。Test Example 2 For samples 1 to 16 prepared in Test Example 1 and a control sample,
The efficacy test was performed by the paper contact method using German cockroaches (adult male).
すなわち、直径9cmのシャーレを試料の数だけ用意
し、各シャーレの底面に紙に敷き、それぞれに試料の
一を50mgずつとって均一にひろげ、チャバネゴギブリ
（成虫オス）10匹を放ち、３連３反復で試験を行ない、
そのKT50値を測定した。That is, prepare a petri dish with a diameter of 9 cm as many as the number of samples, spread the paper on the bottom of each petri dish, take 50 mg of each sample and spread it evenly, release 10 German cockroaches (adult male), and release 3 Perform the test in three replicates,
The KT 50 value was measured.
その結果を第１表に示す。 Table 1 shows the results.
試験例３ 試験例１で調製した試料１〜16と対照試料の流動性を
粉体物性図説（日経技術図書版；第144〜157ページ）に
従って測定した。Test Example 3 The fluidity of the samples 1 to 16 and the control sample prepared in Test Example 1 were measured according to the powder physical property diagram (Nikkei Technical Book Edition; pages 144 to 157).
その結果を下記の５段階評価で第１表に示す。 The results are shown in Table 1 in the following five-grade evaluation.
（評価） ＋＋：良好 ＋：やや良好 ±：普通 −：やや不良 −−：不良 (Evaluation) ++: Good +: Fairly good ±: Fair-: Fairly bad ---: Bad
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ａ０１Ｎ 47:10） ────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Office reference number FI technical display area A01N 47:10)
Claims (1)
殺虫成分の、それぞれ一種又は二種以上からなる殺虫成
分0.05〜3.0重量％、イソプロピルアシドホスフェート
0.2〜5.0重量％及びソルビタン脂肪酸エステル0.05〜0.
1重量％を配合した殺虫粉剤。1. An insecticidal component consisting of one or more of a pyrethroid insecticidal component and a carbamate insecticidal component, each containing 0.05 to 3.0% by weight, and isopropyl acid phosphate.
0.2-5.0% by weight and sorbitan fatty acid ester 0.05-0.
Insecticidal powder containing 1% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63195848A JP2668970B2 (en) | 1988-08-05 | 1988-08-05 | Insecticide powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63195848A JP2668970B2 (en) | 1988-08-05 | 1988-08-05 | Insecticide powder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0245405A JPH0245405A (en) | 1990-02-15 |
| JP2668970B2 true JP2668970B2 (en) | 1997-10-27 |
Family
ID=16348017
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63195848A Expired - Lifetime JP2668970B2 (en) | 1988-08-05 | 1988-08-05 | Insecticide powder |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2668970B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2979197A (en) * | 1996-06-07 | 1998-01-05 | Nippon Soda Co., Ltd. | Agricultural chemical composition with improved raindrop resistance |
| EP2516540A1 (en) * | 2009-12-25 | 2012-10-31 | Sumitomo Chemical Co., Ltd | Polymer composition and molded articles shaped of the same |
| JP5989915B2 (en) * | 2013-09-20 | 2016-09-07 | 大日本除蟲菊株式会社 | 粉 Pest control powder |
-
1988
- 1988-08-05 JP JP63195848A patent/JP2668970B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0245405A (en) | 1990-02-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0064283B1 (en) | Stabilization of 1-substituted imidazole derivatives in talc | |
| AU658417B2 (en) | Chemically stable granules containing insecticidal phosphoroamidothioates | |
| KR890007739A (en) | Stabilized medicinal substances, preparation methods thereof, and stable pharmaceutical preparations | |
| US4895875A (en) | Stabilized peroxide solutions | |
| JP2668970B2 (en) | Insecticide powder | |
| GB2107589A (en) | Anhydrous composition containing anthralin or a derivative for use in the treatment of skin diseases | |
| BRPI0611481A2 (en) | composition for topical administration; and method for preventing or treating ectoparasitic infection or infestation in a warm-blooded animal | |
| JPS6145601B2 (en) | ||
| DE3627195A1 (en) | INSECTICIDAL GEL COMPOSITIONS | |
| JP2764270B2 (en) | Stable aqueous suspension pesticide composition | |
| CN1107290A (en) | Turfgrass insecticides | |
| JP3266656B2 (en) | Vitamin-impregnated granules and method for producing the same | |
| JPH02164803A (en) | Stable microbicidal composition | |
| US4313941A (en) | Stabilized granular nematicidal and insecticidal composition having O-ethyl-S,S-dipropyl dithiophosphate as an active substance | |
| JPH04193806A (en) | Stable insecticide composition and stabilizing method | |
| JP2627291B2 (en) | Stabilized insecticide / bactericidal pesticide composition | |
| JP3151638B2 (en) | Stabilized water-suspended pesticide composition | |
| JPS59122404A (en) | Fungicidal composition for agriculture and horticulture | |
| JP2602694B2 (en) | Smoke composition | |
| JPH05155706A (en) | Agricultural chemical composition | |
| KR960000196B1 (en) | Stable Granular Pesticide Fertilizer | |
| JPH05294803A (en) | Smoking agent composition and smoking method | |
| JP2610485B2 (en) | Agricultural and horticultural powder, wettable powder and method for stabilizing the same | |
| JP3001169B2 (en) | Fly incense stick | |
| JPS60169403A (en) | Stable agricultural and horticultural insecticidal composition |