JP2607109Y2 - Printing sheet - Google Patents
Printing sheetInfo
- Publication number
- JP2607109Y2 JP2607109Y2 JP1992056669U JP5666992U JP2607109Y2 JP 2607109 Y2 JP2607109 Y2 JP 2607109Y2 JP 1992056669 U JP1992056669 U JP 1992056669U JP 5666992 U JP5666992 U JP 5666992U JP 2607109 Y2 JP2607109 Y2 JP 2607109Y2
- Authority
- JP
- Japan
- Prior art keywords
- printing sheet
- sheet
- fiber
- printing
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000463 material Substances 0.000 claims description 26
- 239000000835 fiber Substances 0.000 claims description 7
- 239000004744 fabric Substances 0.000 claims description 6
- 229920000742 Cotton Polymers 0.000 claims description 4
- 229920000704 biodegradable plastic Polymers 0.000 claims description 3
- 239000004745 nonwoven fabric Substances 0.000 claims description 3
- 239000002985 plastic film Substances 0.000 claims description 3
- 239000002759 woven fabric Substances 0.000 claims description 3
- 244000025254 Cannabis sativa Species 0.000 claims description 2
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims description 2
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims description 2
- 229920001407 Modal (textile) Polymers 0.000 claims description 2
- 229920000297 Rayon Polymers 0.000 claims description 2
- 235000009120 camo Nutrition 0.000 claims description 2
- 235000005607 chanvre indien Nutrition 0.000 claims description 2
- 239000011487 hemp Substances 0.000 claims description 2
- 239000002964 rayon Substances 0.000 claims description 2
- 238000004040 coloring Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- IUPHTVOTTBREAV-UHFFFAOYSA-N 3-hydroxybutanoic acid;3-hydroxypentanoic acid Chemical compound CC(O)CC(O)=O.CCC(O)CC(O)=O IUPHTVOTTBREAV-UHFFFAOYSA-N 0.000 description 2
- 229920013642 Biopol™ Polymers 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- AGPLQTQFIZBOLI-UHFFFAOYSA-N 1-benzyl-4-phenylbenzene Chemical group C=1C=C(C=2C=CC=CC=2)C=CC=1CC1=CC=CC=C1 AGPLQTQFIZBOLI-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- QIRNGVVZBINFMX-UHFFFAOYSA-N 2-allylphenol Chemical compound OC1=CC=CC=C1CC=C QIRNGVVZBINFMX-UHFFFAOYSA-N 0.000 description 1
- IPAJDLMMTVZVPP-UHFFFAOYSA-N Crystal violet lactone Chemical compound C1=CC(N(C)C)=CC=C1C1(C=2C=CC(=CC=2)N(C)C)C2=CC=C(N(C)C)C=C2C(=O)O1 IPAJDLMMTVZVPP-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- -1 cupola Polymers 0.000 description 1
- 238000009820 dry lamination Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000009822 solventless lamination Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009816 wet lamination Methods 0.000 description 1
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
Description
【0001】[0001]
【産業上の利用分野】本考案は印字用シート、さらに詳
しくはサーマルプリンタで印字可能であって適度な強度
・風合を有する印字用シートに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a printing sheet, and more particularly to a printing sheet which can be printed by a thermal printer and has an appropriate strength and hand.
【0002】[0002]
【従来の技術】近年、サーマルプリンタによる印字用シ
ートは種々の方面で使用されようとしているが、例えば
広い面積に印字したり、印字物を屋外で使用するごと
く、印字態様や使用目的によっては、印字適性以外に強
度・風合等の物理的特性が要求される。2. Description of the Related Art In recent years, printing sheets using a thermal printer have been used in various fields. For example, printing is performed in a wide area, or printed matter is used outdoors. In addition to printability, physical properties such as strength and hand are required.
【0003】しかしながら、かかる要求特性を十分満足
するものは従来ほとんど見当たらなかった。例えば、織
物、編物、布、繊維製ラベル、あるいは人工皮革等の材
料は、強度・風合は十分な大きさのものを実現するのは
容易である反面、材料表面の凹凸が激しいなどの理由
で、それ自体に直接印字するのに必ずしも適しない。一
方、各種プラスチックフィルムはその平面の平滑性より
印字適性を具備させるのは比較的容易であるが、厚手の
フィルムの製造が比較的困難であり、それ自体で適当な
強度・風合を持たせるのは容易でない。[0003] However, there has hitherto hardly been found one satisfying such required characteristics. For example, materials such as textiles, knits, cloths, textile labels, and artificial leather are easy to achieve with sufficient strength and feel, but the surface irregularities are severe. However, it is not always suitable for printing directly on itself. On the other hand, it is relatively easy to provide various plastic films with printability than the smoothness of the plane, but it is relatively difficult to produce a thick film, and it is necessary to provide appropriate strength and texture by itself. Not easy.
【0004】[0004]
【考案が解決しようとする課題】本考案の目的は、広い
面積への印字や屋外での使用にも耐え得る強度・風合を
具備する印字用シートを提供することにある。SUMMARY OF THE INVENTION An object of the present invention is to provide a printing sheet having a strength and a feeling that can withstand printing over a wide area and use outdoors.
【0005】[0005]
【課題を解決するための手段】かかる事情に鑑み、本考
案者らは、鋭意研究を重ねた結果、適度な強度・風合を
有する基材層の上に薄い印字適性層を設けることによっ
て前記課題を解決できることを見い出し、本考案を完成
するに至った。In view of such circumstances, the inventors of the present invention have conducted intensive studies, and as a result, by providing a thin printable layer on a base layer having an appropriate strength and hand. They found that they could solve the problem and completed the present invention.
【0006】すなわち、本考案は、シート状基材層と該
基材層の上に設けられた印字適性を有するフィルム層と
よりなることを特徴とする印字用シートを提供するもの
である。That is, the present invention provides a printing sheet characterized by comprising a sheet-like base layer and a printable film layer provided on the base layer.
【0007】以下、図面を参照して本考案を説明する。
図1を参照し、本考案の印字用シート(1)は、基材層
(2)とその上に設けられた印字適性フィルム層(3)
よりなる層状構造を有する。Hereinafter, the present invention will be described with reference to the drawings.
Referring to FIG. 1, the printing sheet (1) of the present invention comprises a substrate layer (2) and a printable film layer (3) provided thereon.
It has a layered structure consisting of
【0008】基材層(2)は、適当な強度・風合を有す
るシート状物とし、例えば、種々の材料よりなる繊維を
織物、編物、不織布などの形態としたシート状物が挙げ
られる。適度な強度・風合を持たせるという観点より、
基材層の厚みは、一般に、0.1mm〜1mm程度の範囲と
する。[0008] The base material layer (2) is a sheet-like material having an appropriate strength and feeling, and examples thereof include a sheet-like material in which fibers of various materials are formed into a woven fabric, a knitted fabric, a nonwoven fabric, or the like. From the viewpoint of giving appropriate strength and texture,
The thickness of the base material layer is generally in the range of about 0.1 mm to 1 mm.
【0009】一方、印字適性を付与するためのフィルム
層(3)の材料は特に限定されるものではなく、通常フ
ィルム形成能があるとされるプラスチックのフィルムを
単独であるいは複合フィルムとして使用することができ
る。本考案においては、フィルム層の厚みは、基材と一
体化したときに基材の風合を損なうことのないように薄
くするのが望ましく、相手となる基材の種類やフィルム
材料の種類によっても異なるが、一般に、5μ〜100
μの範囲とする。On the other hand, the material of the film layer (3) for imparting printability is not particularly limited, and a plastic film, which is generally considered to have a film forming ability, may be used alone or as a composite film. Can be. In the present invention, the thickness of the film layer is desirably thin so as not to impair the feel of the base material when integrated with the base material, depending on the type of the mating base material and the type of the film material. Are generally different,
The range is μ.
【0010】ここに、本考案においては、印字適性と
は、サーマルプリンタを用いての印字適性をいう。従っ
て、本考案の印字用シートは、大別してインクリボンを
用いる熱転写型シートと直接感熱発色させる感熱発色型
シートとに分けられる。溶融熱転写や昇華熱転写を含む
熱転写型シートの場合にはフィルム層につき特別の処理
を必要とする場合は少ないが、感熱発色型の場合には、
フィルム上に感熱発色層を設ける。本考案で用いること
ができる感熱発色層は特に限定されるものではなく、例
えば、一般的な塩基性染料として3,3−ビス(p−ジ
メチルアミノフェニル)−6−ジメチルアミノフタリド
のような染料、4,4'−ジヒドロキシ−ジフェニルメタ
ンのような顕色剤、その他、増感剤、バインダー等を適
宜配合して形成される。Here, in the present invention, printability means printability using a thermal printer. Accordingly, the printing sheet of the present invention is roughly classified into a thermal transfer type sheet using an ink ribbon and a thermosensitive coloring type sheet which directly performs thermosensitive coloring. In the case of a thermal transfer type sheet including fusion heat transfer and sublimation heat transfer, there are few cases where special treatment is required for the film layer, but in the case of a thermosensitive coloring type
A thermosensitive coloring layer is provided on the film. The heat-sensitive coloring layer that can be used in the present invention is not particularly limited. For example, a general basic dye such as 3,3-bis (p-dimethylaminophenyl) -6-dimethylaminophthalide is used. It is formed by appropriately mixing a dye, a developer such as 4,4'-dihydroxy-diphenylmethane, a sensitizer, a binder and the like.
【0011】本考案においては、印字用シートを使い捨
て目的で使用する場合には、基材層およびフィルム層を
共に生分解性を有する材料で形成することもできる。か
かる生分解性材料の例としては、基材層については、天
然素材に属する綿、麻や絹、あるいはセルロースを再生
した再生繊維としてのレーヨン、キュポラ、ポリノジッ
ク等が挙げられ、一方、フィルム層の材料としては、例
えば、英国ICI社製の「バイオポール」、昭和高分子
(株)製の「ビオノール」、日本合成化学工業(株)製
の「マタービー」などのごとき生分解性のプラスチック
が挙げられる。In the present invention, when the printing sheet is used for a disposable purpose, both the base material layer and the film layer can be formed of a biodegradable material. Examples of such a biodegradable material include, for the base material layer, cotton belonging to a natural material, hemp and silk, or rayon as a regenerated fiber obtained by regenerating cellulose, cupola, polynosic, and the like. Examples of the material include biodegradable plastics such as "Biopol" manufactured by ICI of the United Kingdom, "Bionor" manufactured by Showa Polymer Co., Ltd., and "Matabee" manufactured by Nippon Synthetic Chemical Industry Co., Ltd. Can be
【0012】次に、基材上にフィルム層を設ける方法と
しては、ドライもしくはウェットラミネーション、無溶
剤型ラミネーション、ホットメルトラミネーション、あ
るいはTダイ等による押出もしくは共押出ラミネーショ
ンのごとき各種ラミネート法が採用できる。従って、本
考案の印字用シートでは、基材層とフィルム層との間に
接着剤を介在させる場合、介在させない場合いずれも可
能である。なお、感熱発色層の形成は、材料の組合せに
より、適宜、ラミネート前あるいはラミネート後に行う
ことができる。Next, as a method of providing a film layer on a substrate, various laminating methods such as dry or wet lamination, solventless lamination, hot melt lamination, or extrusion or coextrusion lamination using a T-die or the like can be adopted. . Therefore, in the printing sheet of the present invention, it is possible to interpose an adhesive between the base material layer and the film layer, or not to interpose an adhesive. The formation of the thermosensitive coloring layer can be appropriately performed before or after lamination depending on the combination of materials.
【0013】かくして得られる本考案の印字用シート
は、基材の強度、伸びや引裂強度のために設置適性を有
しており、このような特性を生かして、殊に看板(例え
ば、冠婚葬祭用の使い捨て看板)、垂幕、各種ポップ
材、ゼッケン等に好適に用いることができる。The printing sheet of the present invention thus obtained has suitability for installation due to the strength, elongation and tear strength of the base material. It can be suitably used for funeral disposable signboards), banners, various pop materials, bib and the like.
【0014】[0014]
【実施例】以下に実施例および比較例を挙げて本考案を
さらに詳しく説明する。実施例1 基材織物として綿布の代表的組織であるコンパスを用い
る。この織物上に20μのポリエステルフィルムをウレ
タン系接着剤を用いてラミネートした。これを295mm
巾にスリットして20m巻の印字用シートを得た。この
印字用シートに、松下電器産業(株)製ワープロFW−
U1P605AIで毛筆書体の拡大文字で印字したとこ
ろ、鮮明な毛筆書体が印字でき、看板などに使用できる
品質を有していた。The present invention will be described in more detail with reference to the following Examples and Comparative Examples. Example 1 A compass, which is a typical structure of cotton cloth, is used as a base fabric. A 20 μm polyester film was laminated on the woven fabric using a urethane-based adhesive. This is 295 mm
The sheet was slit into a width to obtain a 20 m roll printing sheet. The printing sheet is provided with a word processor FW- manufactured by Matsushita Electric Industrial Co., Ltd.
When printing was performed using U1P605AI with enlarged characters of the brush typeface, a clear brush typeface could be printed and had a quality that could be used for a signboard or the like.
【0015】実施例2 基材としてポリエステル湿式不織布目付60g(広瀬製
紙(株)製HISTAR−15TH−60)を用い、こ
の上にTダイ法にて15μのEVAフィルムをラミネー
トした。さらに、このフィルム側に、以下の組成: A液 2−アニリノ−3−メチル−6− 40部 ジブチルアミノフルオラン 25%PVA水溶液 20部 水 40部 B液 4,4'−スルホニル−ビス− 20部 (2−アリルフェノール) p−ベンジルビフェニル 20部 25%PVA水溶液 40部 C液 ザイクセン−AL(30%アクリル酸 100部 /エチレン共重合体、住友精化(株)製) これらA,B,Cを A 5部 B 50部 C 20部 水 25部 よりなる感熱発色層を7μ厚さになるようにコーティン
グした。このコートしたフィルムを巾600mmにスリッ
トして、50m巻の印字シートを得た。この印字シート
を、グラフテック(株)製のTM1000−OPFのA
1サイズ機で印字したところ、鮮明な画像を出すことが
できた。このものは、和紙調の印字用シートとして、ホ
テルの結婚式場の案内看板に好適に使用できた。 Example 2 A 60 g polyester wet nonwoven fabric weight (HISTAR-15TH-60 manufactured by Hirose Paper Co., Ltd.) was used as a base material, and a 15 μm EVA film was laminated thereon by a T-die method. Further, on this film side, the following composition: Liquid A 2-anilino-3-methyl-6-40 parts Dibutylaminofluorane 25% aqueous solution of PVA 20 parts Water 40 parts Liquid B 4,4'-sulfonyl-bis-20 Part (2-allylphenol) p-benzylbiphenyl 20 parts 25% PVA aqueous solution 40 parts Liquid C saixen-AL (30% acrylic acid 100 parts / ethylene copolymer, manufactured by Sumitomo Seika Co., Ltd.) C was coated with a thermosensitive coloring layer comprising 5 parts of A, 50 parts of B, 20 parts of C, and 25 parts of water to a thickness of 7 μm. The coated film was slit to a width of 600 mm to obtain a 50 m- long printed sheet. This print sheet was used as TM1000-OPF A of Graphtec Co., Ltd.
When printing was performed using a one-size machine, a clear image could be obtained. This was suitable for use as a signboard at a hotel wedding ceremony as a Japanese paper print sheet.
【0016】実施例3 基材織物として実施例1と同様のコンパスを、フィルム
層の材料として英国ICI社製の生分解性プラスチック
の「バイオポール」用い、基材層の上にフィルム層を3
0μになるようにTダイ法によって設けることにより本
考案の生分解性型の印字用シートを得た。 Example 3 A compass similar to that of Example 1 was used as a base fabric, and a biodegradable plastic "Biopol" manufactured by ICI, UK was used as a material for the film layer.
The biodegradable printing sheet of the present invention was obtained by providing the film by the T-die method so that the thickness became 0 μm.
【0017】比較例 実施例1で用いたコンパス綿布を表面平滑とするために
カレンダーロールで押圧加工した。この印字用シートに
実施例1と同様の方法で印字したところ、糸目の箇所で
印字抜けが発生し、満足できる印字ができなかった。 Comparative Example The compass cotton cloth used in Example 1 was pressed with a calender roll in order to smooth the surface. When printing was performed on this printing sheet in the same manner as in Example 1, printing missing occurred at the thread portion, and satisfactory printing could not be performed.
【0018】[0018]
【考案の効果】本考案により、広い面積への印字や屋外
での使用に適した強度・風合を有する印字用シートが提
供される。According to the present invention, a printing sheet having a strength and a feeling suitable for printing over a large area and for outdoor use is provided.
【図1】 本考案の印字用シートを模式的に示す断面図
である。FIG. 1 is a cross-sectional view schematically illustrating a printing sheet of the present invention.
1:印字用シート、2:基材層、3:印字適性フィルム
層1: printing sheet, 2: base material layer, 3: printable film layer
───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7,DB名) B41M 5/38 - 5/40 ──────────────────────────────────────────────────続 き Continued on front page (58) Field surveyed (Int. Cl. 7 , DB name) B41M 5/38-5/40
Claims (3)
よりなるシート状基材層と、該基材層の上に設けられた
厚み5μ〜100μの印字適性を有する生分解性プラス
チックフィルム層とよりなることを特徴とする印字用シ
ート。1. A sheet-like base layer made of a biodegradable material having a thickness of 0.1 mm to 1 mm, and a biodegradable plastic film layer having a printability of 5 μ to 100 μ provided on the base layer. And a printing sheet comprising:
ーヨン繊維、キュポラ繊維およびポリノジック繊維から
選択される生分解性材料で構成される織物、編物または
不織布よりなる請求項1記載の印字用シート。2. The woven fabric, knitted fabric or nonwoven fabric comprising a biodegradable material selected from the group consisting of cotton fiber, hemp fiber, silk fiber, rayon fiber, cupola fiber and polynosic fiber. Printing sheet.
用いられる請求項1または2記載の印字用シート。3. The printing sheet according to claim 1, which is used for a signboard, a curtain, a pop material, or a bib.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1992056669U JP2607109Y2 (en) | 1992-08-12 | 1992-08-12 | Printing sheet |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1992056669U JP2607109Y2 (en) | 1992-08-12 | 1992-08-12 | Printing sheet |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0617952U JPH0617952U (en) | 1994-03-08 |
JP2607109Y2 true JP2607109Y2 (en) | 2001-04-16 |
Family
ID=13033832
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1992056669U Expired - Fee Related JP2607109Y2 (en) | 1992-08-12 | 1992-08-12 | Printing sheet |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2607109Y2 (en) |
-
1992
- 1992-08-12 JP JP1992056669U patent/JP2607109Y2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH0617952U (en) | 1994-03-08 |
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