JP2514817B2 - Anti-feeding agent for protein fiber - Google Patents
Anti-feeding agent for protein fiberInfo
- Publication number
- JP2514817B2 JP2514817B2 JP14975287A JP14975287A JP2514817B2 JP 2514817 B2 JP2514817 B2 JP 2514817B2 JP 14975287 A JP14975287 A JP 14975287A JP 14975287 A JP14975287 A JP 14975287A JP 2514817 B2 JP2514817 B2 JP 2514817B2
- Authority
- JP
- Japan
- Prior art keywords
- protein fiber
- fiber
- feeding agent
- protein
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000835 fiber Substances 0.000 title description 16
- 102000004169 proteins and genes Human genes 0.000 title description 9
- 108090000623 proteins and genes Proteins 0.000 title description 9
- 239000003795 chemical substances by application Substances 0.000 title description 6
- 230000001887 anti-feedant effect Effects 0.000 title description 4
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 claims description 5
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 claims description 5
- 229960000490 permethrin Drugs 0.000 claims description 5
- -1 2-ethylhexyl Chemical group 0.000 claims description 3
- 239000004480 active ingredient Substances 0.000 claims description 3
- OHAMOQALFCXZBV-UHFFFAOYSA-N 2,2-dichloroethenyl 2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)CC1C(=O)OC=C(Cl)Cl OHAMOQALFCXZBV-UHFFFAOYSA-N 0.000 claims 1
- 239000000443 aerosol Substances 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000000077 insect repellent Substances 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002728 pyrethroid Substances 0.000 description 3
- RLLPVAHGXHCWKJ-IEBWSBKVSA-N (3-phenoxyphenyl)methyl (1s,3s)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-IEBWSBKVSA-N 0.000 description 2
- 241000254173 Coleoptera Species 0.000 description 2
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- WLLGXSLBOPFWQV-OTHKPKEBSA-N molport-035-783-878 Chemical compound C([C@H]1C=C2)[C@H]2C2C1C(=O)N(CC(CC)CCCC)C2=O WLLGXSLBOPFWQV-OTHKPKEBSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229960005235 piperonyl butoxide Drugs 0.000 description 2
- 229950011008 tetrachloroethylene Drugs 0.000 description 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- CIFFBTOJCKSRJY-UHFFFAOYSA-N 3α,4,7,7α-tetrahydro-1h-isoindole-1,3(2h)-dione Chemical compound C1C=CCC2C(=O)NC(=O)C21 CIFFBTOJCKSRJY-UHFFFAOYSA-N 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 108010020346 Polyglutamic Acid Proteins 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- DFBKLUNHFCTMDC-PICURKEMSA-N dieldrin Chemical compound C([C@H]1[C@H]2[C@@]3(Cl)C(Cl)=C([C@]([C@H]22)(Cl)C3(Cl)Cl)Cl)[C@H]2[C@@H]2[C@H]1O2 DFBKLUNHFCTMDC-PICURKEMSA-N 0.000 description 1
- 229950006824 dieldrin Drugs 0.000 description 1
- NGPMUTDCEIKKFM-UHFFFAOYSA-N dieldrin Natural products CC1=C(Cl)C2(Cl)C3C4CC(C5OC45)C3C1(Cl)C2(Cl)Cl NGPMUTDCEIKKFM-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 229920002643 polyglutamic acid Polymers 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は安全性及び効力の高い蛋白質繊維の食害防止
剤に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application] The present invention relates to a highly safe and highly effective protein fiber food damage preventive agent.
蛋白質からなる繊維は、毛糸，毛織物，毛皮，羽毛，
また生糸や絹等の動物繊維やポリグルタミン酸繊維等の
合成物も含まれるが、これらの繊維類は、衣蛾の類やカ
ツオブシムシ類が原料の段階から使用中の衣服等に至る
まで食害を及ぼす。Fibers made of protein include yarn, woolen fabric, fur, feathers,
In addition, synthetic fibers such as animal fibers such as raw silk and silk and polyglutamic acid fibers are also included, but these fibers cause food damage from the stage of raw materials such as moths and beetles to the clothes in use. .
これに対し、保存場所にパラジクロルベンゼンや、最
近ではピレスロイド系のエンペンスリン等の昇華性、気
化性の防虫剤が使われ，また、その繊維に直接、食害防
止剤や殺虫が処理されている。On the other hand, paradichlorobenzene, and recently, a sublimable or vaporizable insect repellent such as pyrethroid-based empensulin is used, and the fiber is directly treated with an antifeedant or insecticide.
しかし、昇華性、気化性の防虫剤の場合には、狭い空
間でしか効かず、また気密性の高い容器内でなければ効
果が落ちるという限界がある。一方繊維に防虫剤を処理
する方法は、安全性が特に問題となる。その為、アルド
リン、ディルドリン等の殺虫剤は使用が禁止された。However, in the case of a sublimable or vaporizable insect repellent, it is effective only in a narrow space, and there is a limit that the effect is reduced unless it is in a highly airtight container. On the other hand, the method of treating the fiber with the insect repellent has a problem of safety. Therefore, the use of pesticides such as aldrin and dieldrin was prohibited.
ピレスロイド系の殺虫剤は安全性が高いが効力の持続
性が小さいものが多く、また高価であり、充分な効力を
持たせられる量を処理することが、費用の面で困難であ
る。Most of the pyrethroid insecticides are highly safe, but have a short duration of efficacy, and are expensive, and it is difficult in terms of cost to treat an amount capable of giving sufficient efficacy.
本発明者は、ピレスロイド系殺虫剤の中でも効力の持
続性の大きいｍ−フェノキシベンジル−３−（2,2−ジ
クロロビニル）−2,2ジメチルシクロプロパンカルボキ
シレート（以下ペルメトリンと称す）の効力増強につい
て検討し，これに５−〔−２−（２−ブトキシエトキ
シ）エトキシメチル〕−６−プロピル−1,3−ベンゾジ
オキソール（以下ピペロニルブトキサイドと称す）及び
Ｎ−（２−エチルヘキシル）3,6−エンドメチレン−1,
2,3,6テトラヒドロフタルイミド（以下MGK−264と称
す）を一定の割合で混合することにより、蛋白質繊維害
虫にたいする食害防止効力を飛躍的に向上させ得ること
を見出した。The present inventor has found that, among pyrethroid insecticides, the efficacy of m-phenoxybenzyl-3- (2,2-dichlorovinyl) -2,2 dimethylcyclopropanecarboxylate (hereinafter referred to as permethrin), which has a long lasting effect, is enhanced. Was investigated, and 5-[-2- (2-butoxyethoxy) ethoxymethyl] -6-propyl-1,3-benzodioxole (hereinafter referred to as piperonyl butoxide) and N- (2- Ethylhexyl) 3,6-endomethylene-1,
It has been found that by mixing 2,3,6 tetrahydrophthalimide (hereinafter referred to as MGK-264) at a constant ratio, the effect of preventing damage to protein fiber pests can be dramatically improved.
すなわち本発明は、活性成分がｍ−フェノキシベンジ
ル−３−（2,2−ジクロロビニル）−2,2ジメチルシクロ
プロパンカルボキシレート（ペルメトリン）,5−〔−２
−（２−ブトキシエトキシ）エトキシメチル〕−６−プ
ロピル−1,3−ベンゾジオキソール及びＮ−（２−エチ
ルヘキシル）3,6−エンドメチレン−1,2,3,6テトラヒド
ロフタルイミドからなることを特徴とする蛋白質繊維の
食害防止剤を提供するものである 本発明において用いられるペルメトリン、ピペロニル
ブトキサイド、MGK−264は互いに相溶性がよいので、そ
の混合割合は特に制限はされないないが、各成分を10〜
50重量％の範囲内で混合、攪拌すればよい。That is, in the present invention, the active ingredient is m-phenoxybenzyl-3- (2,2-dichlorovinyl) -2,2 dimethylcyclopropanecarboxylate (permethrin), 5-[-2
-(2-butoxyethoxy) ethoxymethyl] -6-propyl-1,3-benzodioxole and N- (2-ethylhexyl) 3,6-endomethylene-1,2,3,6 tetrahydrophthalimide Permethrin, piperonyl butoxide, and MGK-264 used in the present invention, which provide an anti-feeding agent for protein fibers, are well compatible with each other, so that the mixing ratio is not particularly limited. , Each ingredient 10 ~
It may be mixed and stirred within the range of 50% by weight.
本発明の蛋白質繊維の食害防止剤は粘度がある程度大
きいので、適当な芳香族、塩素化炭化水素、例えば、タ
ーペンやテトラクロルエチレン等で２倍〜30倍程度に希
釈して油剤やエアゾールの形で製品とすることが出来る 蛋白質繊維への処理は、油剤を有機溶剤で希釈し浸漬
した後、有機溶剤を揮散させる方法、また、エアゾール
を衣服や毛皮，カーペット等に散布すればよい。Since the protein fiber anti-feeding agent of the present invention has a high viscosity to some extent, it is diluted with a suitable aromatic or chlorinated hydrocarbon such as terpene or tetrachloroethylene to about 2 to 30 times to form an oil or aerosol. The protein fiber which can be made into a product can be treated by diluting an oil solution with an organic solvent and dipping it, and then volatilizing the organic solvent, or by spraying an aerosol on clothes, fur, carpet, and the like.
また、適当な乳化剤を加えて乳剤とし、水で希釈して
羊毛の原毛に噴霧、浸漬してもよいし、エアゾール剤と
して衣服や毛皮，カーペット等に処理することも出来
る。いずれの方法によっても、必要量の活性成分が、繊
維に付着することが必要である。It is also possible to add an appropriate emulsifier to form an emulsion, dilute it with water and spray it on the raw wool and soak it, or use it as an aerosol agent for treating clothes, furs, carpets and the like. Both methods require that the required amount of active ingredient be deposited on the fiber.
実施例１ 以下に本発明の食害防止剤の配合例を第１表に示す。 Example 1 Table 1 shows an example of blending of the food damage inhibitor of the present invention.
試験例 配合例Ａ〜Ｃ及び比較例の食害防止剤を、キシレンで
希釈し、モスリン布に、所定の薬剤濃度になるように含
浸させ、風乾後、3cm角に裁断し、直径5cmのガラスシャ
ーレに入れ、ヒメマルカツオブシムシ幼虫30頭を加え、
25℃，湿度65％の暗所に４週間放置した後、取出して食
害の程度を調べた。Test Example The anticorrosive agents of Formulation Examples A to C and Comparative Example were diluted with xylene, and a muslin cloth was impregnated with a predetermined chemical concentration, air-dried, and then cut into 3 cm squares, and a glass petri dish having a diameter of 5 cm. And add 30 larvae of the larvae of the beetle Beetle,
After left in a dark place at 25 ° C and a humidity of 65% for 4 weeks, they were taken out and examined for the degree of feeding damage.
結果は第２表の通りであった。 The results are shown in Table 2.
実施例２ 実施例１のＡ配合品9gに無臭灯油を加えて溶解させ全
体を150mlとした。これをエアゾール容器に充填し、バ
ルブ部分を取り付けた後、該バルブを通して噴射剤（LP
G/DME混合ガス）150mlを加圧充填して蛋白質繊維の食害
防止用エアゾールを得た。 Example 2 To 9 g of the compound A of Example 1 was added odorless kerosene and dissolved to make 150 ml in total. After filling this with an aerosol container and attaching the valve part, propellant (LP
G / DME mixed gas) (150 ml) was charged under pressure to obtain an aerosol for preventing damage to protein fibers.
実施例３ 実施例１のＢ配合品1kgにテトラクロルエチレンを溶
解させ、全体を２リットルとしてクリーニング用食害防
止剤を得た。Example 3 Tetrachlorethylene was dissolved in 1 kg of the B compounded product of Example 1 to make the total amount 2 liters to obtain a cleaning damage inhibitor.
本発明の蛋白質繊維の食害防止剤は、ペルメトリン単
独の場合と比較して、最高では10倍以上の効力がある。
コスト当たりの効力にすればさらにその価値は大きくな
るので、蛋白質繊維の食害防止剤として好適である。The protein fiber food damage inhibitor of the present invention is 10 times or more as effective as the case of using permethrin alone.
The value per unit cost increases further, so it is suitable as a food fiber damage inhibitor.
Claims (1)
（2,2−ジクロロビニル）−2,2ジメチルシクロプロパン
カルボキシレート（ペルメトリン）,5−〔−２−（２−
ブトキシエトキシ）エトキシメチル〕−６−プロピル−
1,3ベンゾジオキソール及びＮ−（２−エチルヘキシ
ル）3,6−エンドメチレン−1,2,3,6テトラヒドロフタル
イミドからなることを特徴とする蛋白質繊維の食害防止
剤1. The active ingredient is m-phenoxybenzyl-3-.
(2,2-Dichlorovinyl) -2,2 dimethylcyclopropanecarboxylate (permethrin), 5-[-2- (2-
Butoxyethoxy) ethoxymethyl] -6-propyl-
1,3 benzodioxole and N- (2-ethylhexyl) 3,6-endomethylene-1,2,3,6 tetrahydrophthalimide
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14975287A JP2514817B2 (en) | 1987-06-16 | 1987-06-16 | Anti-feeding agent for protein fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14975287A JP2514817B2 (en) | 1987-06-16 | 1987-06-16 | Anti-feeding agent for protein fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63315670A JPS63315670A (en) | 1988-12-23 |
| JP2514817B2 true JP2514817B2 (en) | 1996-07-10 |
Family
ID=15481978
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14975287A Expired - Lifetime JP2514817B2 (en) | 1987-06-16 | 1987-06-16 | Anti-feeding agent for protein fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2514817B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY132793A (en) * | 2002-12-30 | 2007-10-31 | Institute For Medical Res Malaysia | Insecticidal paint composition |
-
1987
- 1987-06-16 JP JP14975287A patent/JP2514817B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63315670A (en) | 1988-12-23 |
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