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JP2024086497A - Flour dough premix - Google Patents

Flour dough premix Download PDF

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JP2024086497A
JP2024086497A JP2022201655A JP2022201655A JP2024086497A JP 2024086497 A JP2024086497 A JP 2024086497A JP 2022201655 A JP2022201655 A JP 2022201655A JP 2022201655 A JP2022201655 A JP 2022201655A JP 2024086497 A JP2024086497 A JP 2024086497A
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flour dough
premix
derived
enzyme
flour
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JP7439893B1 (en
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真紀子 難波
Makiko Namba
瑠依 安川
Rui Yasukawa
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NOF Corp
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Abstract

To provide cereal flour dough premix which is excellent in dispersibility in cereal flour dough, has improved preserving properties, and in which rice oil-derived gum and enzyme can be blended in the cereal flour dough at any concentration from low concentration to high concentration.SOLUTION: In order to solve the above problem, cereal flour dough premix is provided, containing (A) liquid sugar, and (B) rice flour-derived gum or (C) enzyme, and having water activity of 0.80 or less. According to the present invention, it is possible to provide the cereal flour dough premix which is excellent in dispersibility in cereal flour dough, has improved preserving properties, and in which rice oil-derived gum and enzyme can be blended in the cereal flour dough at any concentration from low concentration to high concentration.SELECTED DRAWING: None

Description

本発明は、穀粉生地への分散性、保存性が向上し、低濃度から高濃度まで任意に穀粉生地中へ米油由来ガム質又は酵素を配合できる穀粉生地用プレミックスに関する。 The present invention relates to a premix for flour dough that has improved dispersibility and storage stability in flour dough and allows rice oil-derived gums or enzymes to be blended into the flour dough at any concentration from low to high.

穀粉生地を焼成してなる様々な食品を製造する際、原料を穀粉生地へ均一に分散させることは、出来上がる製品の品質安定性にもつながり重要である。
一般的に粉体原料であれば、穀粉と混合することで均一分散させることは可能であるが、酵素などの少量添加する粉体原料では、穀粉に均一に分散することができず、添加した効果を十分に発揮することができない。特許文献1では、流動穀粉生地にも分散しやすいように酵素を含む水中油型乳化油脂組成物を製造し、良好な分散性が得られる方法が提案されている。また、特許文献2では水に不溶の乳化剤をケーキ生地に分散させるため、油脂に乳化剤を溶解し水と乳化した分散性に優れた乳化油脂組成物が提案されている。
When producing various foods by baking flour dough, it is important to disperse the ingredients uniformly in the dough, as this leads to consistent quality of the finished products.
Generally, powdered raw materials can be uniformly dispersed by mixing with cereal flour, but powdered raw materials with a small amount of enzymes cannot be uniformly dispersed in cereal flour, and the effect of the addition cannot be fully achieved. Patent Document 1 proposes a method for producing an oil-in-water emulsified oil composition containing an enzyme so that it can be easily dispersed in a fluidized cereal flour dough, thereby obtaining good dispersibility. Patent Document 2 also proposes an emulsified oil composition with excellent dispersibility in which an emulsifier is dissolved in oil and emulsified with water in order to disperse a water-insoluble emulsifier in a cake dough.

特開2018-201457号公報JP 2018-201457 A 特開2015-171324号公報JP 2015-171324 A

しかし、特許文献1の方法では製品の保存性を高めるために加熱殺菌を行うと酵素が失活してしまうため、酵素を含有した水中油型油脂組成物では十分な加熱殺菌ができず、保存性が低下する。また、特許文献2の方法では、油脂と乳化剤の配合比率が固定化したものを穀粉生地に配合することになるため、低濃度から高濃度まで穀粉生地へ乳化剤を任意に配合することができず、油脂を配合できる範囲内でしか乳化剤を配合できない。したがって、穀粉生地へ均一分散が困難な酵素や、水に不溶の素材を穀粉生地へ均一に分散でき、低濃度から高濃度まで任意に有効成分を配合できる、保存性に優れた穀粉生地用プレミックスの提供が望まれている。
米油由来ガム質は、米糠から搾油された精製前の米原油に含まれるガム状の粘着物質であり、各種植物原油の中でも米原油はガム質が特に多く含まれていることが知られている。米油由来ガム質は米油の精製時に副産物として発生する未利用資源であり、これまで有効な活用方法が見出されておらず、家畜飼料用など付加価値の低い用途に使用されてきたにすぎず、穀粉生地に添加した際に得られる有用な効果については見出されていない。本発明者は、米油由来ガム質を穀粉生地に分散させることができれば、穀粉含有食品の食感や外観を向上させる効果があることを見出した。しかし、米油由来ガム質は粘度が高く、水へ不溶のため、穀粉生地への分散性に欠けるとともに、分散しやすい油中水型乳化物や水中油型乳化物のような乳化物とした場合、水相に米糠抽出物が懸濁し、米糠抽出物に含まれる窒素源等により微生物が繁殖し、乳化物の保存性が低下するという課題があった。また、油脂に米油由来ガム質を配合し、穀粉生地への分散性を向上させることはできるが、穀粉生地へ添加できる油脂量は限定的であり、米油由来ガム質の任意量を穀粉生地に添加できないといった課題があった。
また、粉体の酵素においても、穀粉生地への分散性に欠けるため十分な効果が発揮されず、これまで油脂に分散させるなどの方法がとられてきた。しかし、穀粉生地へ添加できる油脂量は限定的であり酵素の任意量を穀粉生地に添加できないといった課題があった。
However, in the method of Patent Document 1, when heat sterilization is performed to improve the shelf life of the product, the enzyme is inactivated, so that the oil-in-water type oil composition containing the enzyme cannot be sufficiently heat sterilized, and the shelf life is reduced. In addition, in the method of Patent Document 2, the mixture ratio of the fat and oil and the emulsifier is fixed and mixed into the flour dough, so the emulsifier cannot be mixed into the flour dough at any concentration from low to high, and the emulsifier can only be mixed within the range in which the fat and oil can be mixed. Therefore, it is desired to provide a flour dough premix with excellent shelf life that can uniformly disperse enzymes that are difficult to disperse uniformly in flour dough and water-insoluble materials in flour dough, and can be mixed with active ingredients at any concentration from low to high.
Rice oil-derived gums are gummy, sticky substances contained in unrefined rice crude oil extracted from rice bran, and it is known that among various types of vegetable crude oil, rice crude oil contains particularly large amounts of gums. Rice oil-derived gums are unused resources that are generated as by-products during the refining of rice oil, and no effective method for utilizing them has been found so far. They have only been used for low-value-added purposes such as livestock feed, and no useful effects have been found when they are added to flour dough. The present inventor has found that if rice oil-derived gums can be dispersed in flour dough, they can improve the texture and appearance of flour-containing foods. However, rice oil-derived gums have high viscosity and are insoluble in water, so they lack dispersibility in flour dough, and when they are made into emulsions such as water-in-oil emulsions or oil-in-water emulsions that are easy to disperse, there is a problem that the rice bran extract is suspended in the aqueous phase, and microorganisms grow due to the nitrogen source contained in the rice bran extract, which reduces the shelf life of the emulsion. In addition, while it is possible to blend rice oil-derived gums with fats and oils to improve their dispersibility in flour dough, there is a problem in that the amount of fat and oil that can be added to flour dough is limited, and it is not possible to add any amount of rice oil-derived gums to flour dough.
In addition, powdered enzymes are not effective because they lack dispersibility in flour dough, so methods such as dispersing them in fats and oils have been used up to now. However, there is a problem in that the amount of fat that can be added to flour dough is limited, and it is not possible to add an arbitrary amount of enzyme to flour dough.

本発明者は、米油由来ガム質、酵素を液糖で希釈した穀粉生地用プレミックスにおいて、水分活性を0.80以下とすることで保存性を向上するのみならず、穀粉生地への分散性を向上させることができ、低濃度から高濃度まで任意に穀粉生地中へ米油由来ガム質又は酵素を配合できることを見出した。すなわち本発明の目的は、穀粉生地への分散性に優れ、保存性が向上した、低濃度から高濃度まで任意に穀粉生地へ米油由来ガム質又は酵素を配合できる穀粉生地用プレミックスを提供することである。 The inventors have found that in a flour dough premix in which rice oil-derived gums and enzymes are diluted with liquid sugar, by setting the water activity to 0.80 or less, not only can the shelf life be improved, but also the dispersibility in the flour dough can be improved, and rice oil-derived gums or enzymes can be blended into the flour dough at any concentration from low to high. In other words, the object of the present invention is to provide a flour dough premix that has excellent dispersibility in flour dough, has improved shelf life, and allows rice oil-derived gums or enzymes to be blended into the flour dough at any concentration from low to high.

本発明は下記[1]~[5]である
[1](A)液糖及び(B)米油由来ガム質を含有し、水分活性が0.80以下である穀粉生地用プレミックス。
[2]前記(A)液糖の含有量が20質量%以上、90質量%以下であり、前記(B)米油由来ガム質の含有量が10質量%以上、80質量%以下である、[1]に記載の穀粉生地用プレミックス。
[3](A)液糖及び(C)酵素を含有し、水分活性が0.80以下である穀粉生地用プレミックス。
[4]前記(A)液糖の含有量が90質量%以上である、[3]に記載の穀粉生地用プレミックス。
[5](A)液糖、(B)米油由来ガム質及び(C)酵素を含有し、水分活性が0.80以下である穀粉生地用プレミックス。
The present invention relates to the following [1] to [5]: [1] A premix for flour dough containing (A) liquid sugar and (B) a gum derived from rice oil, and having a water activity of 0.80 or less.
[2] A premix for flour dough as described in [1], wherein the content of (A) liquid sugar is 20% by mass or more and 90% by mass or less, and the content of (B) rice oil-derived gum is 10% by mass or more and 80% by mass or less.
[3] A premix for flour dough containing (A) liquid sugar and (C) an enzyme and having a water activity of 0.80 or less.
[4] A premix for flour dough described in [3], in which the content of (A) liquid sugar is 90% by mass or more.
[5] A premix for flour dough containing (A) liquid sugar, (B) a gum derived from rice oil, and (C) an enzyme, and having a water activity of 0.80 or less.

本発明によれば、穀粉生地への分散性に優れ、保存性が向上した、低濃度から高濃度まで任意に穀粉生地へ米油由来ガム質又は酵素を配合できる穀粉生地用プレミックスを提供することができる。
またこれらの穀粉生地用プレミックスは穀粉生地への分散性が向上することにより、例えば製パンにおいてボリューム向上効果やソフトさ向上効果が十分に得られる。
According to the present invention, a flour dough premix can be provided which has excellent dispersibility in flour dough, improved storage stability, and allows rice oil-derived gums or enzymes to be blended into the flour dough at any concentration from low to high.
Furthermore, these premixes for flour dough have improved dispersibility in flour dough, and therefore can fully improve the volume and softness of bread, for example.

本発明の穀粉生地用プレミックスは、(A)液糖に、(B)米油由来ガム質および酵素から選ばれる1種類以上を含有し、水分活性が0.80以下であることを特徴とするものであり、穀粉生地に混合して使用するものである。
以下、本発明について詳細に説明する。
The premix for flour dough of the present invention is characterized by containing (A) liquid sugar and (B) one or more selected from rice oil-derived gums and enzymes, and having a water activity of 0.80 or less, and is used by mixing it with flour dough.
The present invention will be described in detail below.

(A)液糖
本発明に用いられる(A)液糖とは、液体状態の糖類、または、粉糖を溶液状態にしたものである。具体的には、グルコース、マント―ス、シュークロース、ラクトース、トレハロース、マルトトリオース、テトラオース、ソルビトール、キシリトール、エリスリトール、マルチトール等の単糖類、二糖類、三糖類、四糖類、五糖類、六糖類、澱粉加水分解物及びこれらを還元した糖アルコール、又は、それらの混合物の液状物、例えば、水飴、還元水飴、砂糖混合ぶどう糖果糖液糖などが用いられる。
流通する商品としては、例えば、「RCS-50」(王子コーンスターチ(株)製、砂糖混合ぶどう糖果糖液糖、水分活性0.73)、「アマミール」(三菱商事フードテック(株)製、還元水飴、水分活性0.82)などが挙げられる。
(A) Liquid sugar The (A) liquid sugar used in the present invention refers to sugars in a liquid state or powdered sugar in a solution state. Specifically, the liquid sugar may be monosaccharides such as glucose, manthose, sucrose, lactose, trehalose, maltotriose, tetraose, sorbitol, xylitol, erythritol, maltitol, disaccharides, trisaccharides, tetrasaccharides, pentasaccharides, hexasaccharides, starch hydrolysates, and sugar alcohols obtained by reducing these, or liquid mixtures thereof, such as starch syrup, reduced starch syrup, and sugar mixed glucose-fructose liquid sugar.
Examples of commercially available products include "RCS-50" (manufactured by Oji Cornstarch Co., Ltd., sugar mixed glucose-fructose liquid sugar, water activity 0.73) and "AmaMeal" (manufactured by Mitsubishi Corporation Foodtech Co., Ltd., reduced starch syrup, water activity 0.82).

本発明によれば、穀粉生地への分散性に優れ、保存性が向上した、低濃度から高濃度まで任意に穀粉生地へ米油由来ガム質および酵素を配合できる穀粉生地用プレミックスを提供することができる。 According to the present invention, it is possible to provide a flour dough premix that has excellent dispersibility in flour dough, has improved storage stability, and can be mixed with rice oil-derived gums and enzymes in any concentration from low to high into flour dough.

(A)液糖の水分活性は0.85以下が好ましく、0.80以下がさらに好ましく、0.75以下が特に好ましい。また、下限値としては、特に制限されないが、0.60以上が好ましく、0.65以上が特に好ましい。
さらに、水分活性が0.85以下の(A)液糖と(B)米油由来ガム質を混合した場合、穀粉生地への分散性を向上するとともに保存期間の長期化に伴うカビ等の微生物の発生を抑制しつつ、(B)米油由来ガム質の分離の発生を抑制することができる。(A)液糖の自由水の量が増加すると、(B)米油由来ガム質の分散性の低下を引き起こすおそれがあり、(A)液糖の水分活性は小さいことが好ましい。
また、水分活性が0.85以下の(A)液糖と(C)酵素を混合した場合、保存期間の経過による(C)酵素の活性低下を抑制して、穀粉生地用プレミックスとして優れた機能を得られるとともに保存期間の長期化に伴うカビ等の微生物の発生を抑制する。
The water activity of the liquid sugar (A) is preferably 0.85 or less, more preferably 0.80 or less, and particularly preferably 0.75 or less. The lower limit is not particularly limited, but is preferably 0.60 or more, and particularly preferably 0.65 or more.
Furthermore, when (A) liquid sugar having a water activity of 0.85 or less is mixed with (B) rice oil-derived gummy substance, it is possible to improve dispersibility in flour dough and inhibit the growth of microorganisms such as mold that accompanies prolonged storage periods, while inhibiting separation of (B) rice oil-derived gummy substance. An increase in the amount of free water in (A) liquid sugar may cause a decrease in dispersibility of (B) rice oil-derived gummy substance, and therefore it is preferable that (A) liquid sugar has a low water activity.
In addition, when (A) liquid sugar having a water activity of 0.85 or less is mixed with (C) enzyme, the decrease in activity of (C) enzyme over the course of storage is suppressed, providing excellent functionality as a premix for flour dough and suppressing the growth of microorganisms such as mold that occur over extended storage periods.

本発明の穀粉生地用プレミックスにおける(A)液糖の含有量は、(B)米油由来ガム質や(C)酵素の含有量によって適宜調整されるが、例えば、下限値としては、20質量%以上、30質量%以上、40質量%以上、50質量%以上、60質量%以上、70質量%以上、80質量%以上、90質量%以上、95質量%以上である。また、(B)米油由来ガム質を含有する穀粉生地用プレミックスの場合には、上限値としては、例えば、90質量%以下、80質量%以下、70質量%以下、60質量%以下である。 The content of (A) liquid sugar in the flour dough premix of the present invention is adjusted as appropriate depending on the content of (B) rice oil-derived gum and (C) enzyme, but for example, the lower limit is 20% by mass or more, 30% by mass or more, 40% by mass or more, 50% by mass or more, 60% by mass or more, 70% by mass or more, 80% by mass or more, 90% by mass or more, or 95% by mass or more. In the case of a flour dough premix containing (B) rice oil-derived gum, the upper limit is, for example, 90% by mass or less, 80% by mass or less, 70% by mass or less, or 60% by mass or less.

(B)米油由来ガム質
本発明に用いる(B)米油由来ガム質は、米糠から搾油された精製前の米原油に含まれるガム状の粘着物質であり、米油精製時の副生成物である。各種植物原油の中でも、米原油に特異的に多くガム質が含まれている。
その製造方法は特に限定されないが、米糠を110~120℃のクッカー処理し、水分を低減させたのち、ヘキサンを用いて搾油後、ヘキサンを留去し、得られた米原油に60~90℃の温水を対油1~3質量%添加し、穏やかに攪拌することにより米油由来ガム質を米原油から析出させ、その後、沈殿、遠心分離など任意の方法により米原油から分離し、乾燥、蒸留等などにより水分を除去して米油由来ガム質を得ることができる。これは米油の一般的な精製工程で得られた副生成物である。
なお、米原油から得られるアセトン不溶物量は、米糠に含まれるホスホリパーゼの活性や米糠の保存状態、水和条件により変動する。また、米油由来ガム質に含まれるアセトン不溶物の含有量は、遠心分離などの米原油から米油由来ガム質を分離する手段により調整することができる。
(B) Rice oil-derived gum The (B) rice oil-derived gum used in the present invention is a gummy, sticky substance contained in unrefined rice crude oil extracted from rice bran, and is a by-product of rice oil refining. Among various types of vegetable crude oil, rice crude oil is uniquely rich in gum.
The method of production is not particularly limited, but rice bran is treated in a cooker at 110-120°C to reduce the moisture content, then the rice bran is pressed using hexane, the hexane is distilled off, 1-3 mass% of hot water at 60-90°C relative to the oil is added to the resulting rice crude oil, and the rice oil-derived gummy substance is precipitated from the rice crude oil by gently stirring, and then the rice crude oil is separated by any method such as precipitation or centrifugation, and the moisture is removed by drying, distillation, etc. to obtain the rice oil-derived gummy substance. This is a by-product obtained in the general refining process of rice oil.
The amount of acetone insoluble matter obtained from rice crude oil varies depending on the activity of phospholipase contained in rice bran, the storage state of rice bran, and the hydration conditions. The amount of acetone insoluble matter contained in the rice oil-derived gummy matter can be adjusted by a method for separating the rice oil-derived gummy matter from the rice crude oil, such as centrifugation.

本発明の(B)米油由来ガム質には、ホスファチジルコリン、ホスファチジルエタノールアミン、ホスファチジルイノシトール、ホスファチジン酸等からなるリン脂質混合物、トリグリセライド、遊離脂肪酸、ロウ、その他多種の成分が含まれる混合物であり、その成分のすべてを特定することはできないが、上記の工程を経て米原油から得られたものであり、アセトン不溶物20質量%以上75質量%以下、酸価50以下、水分含量5質量%以下であるものが好ましく、水分含量1質量%以下であるものがより好ましい。アセトン不溶物の下限値としてより好ましくは35質量%以上である。なお、アセトン不溶物は基準油脂分析試験法の「4.3.1-2013 アセトン不溶物」に準じて、酸価は基準油脂分析試験法の「2.3.1-2013 酸価」に準じて測定した。 The rice oil-derived gum (B) of the present invention is a mixture containing a phospholipid mixture consisting of phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, phosphatidic acid, etc., triglycerides, free fatty acids, wax, and various other components. Although it is not possible to identify all of the components, it is obtained from rice crude oil through the above-mentioned process, and preferably has an acetone insoluble content of 20% by mass to 75% by mass, an acid value of 50 or less, and a moisture content of 5% by mass or less, and more preferably a moisture content of 1% by mass or less. The lower limit of the acetone insoluble content is more preferably 35% by mass or more. The acetone insoluble content was measured in accordance with "4.3.1-2013 Acetone Insoluble Content" of the Standard Method for Analysis of Fats, Oils, and Fat, and the acid value was measured in accordance with "2.3.1-2013 Acid Value" of the Standard Method for Analysis of Fats, Oils, and Fat.

(B)米油由来ガム質は粘度が高く、水へ不溶のためそのまま穀粉生地へ添加しても分散せず効果を発揮することができない。しかし(A)液糖と(B)米油由来ガム質を混合し、穀粉生地へ添加した場合、液糖の水への親和性により(B)米油由来ガム質は容易に穀粉生地へ均一分散することができる。穀粉生地へ均一分散した(B)米油由来ガム質は、グルテンの繋がりを強め、例えばパンにおいてはボリューム向上効果やソフトさ向上効果等が得られる。 (B) Rice oil-derived gum has a high viscosity and is insoluble in water, so if it is added directly to flour dough, it will not disperse and will not be effective. However, if (A) liquid sugar and (B) rice oil-derived gum are mixed and added to flour dough, the affinity of the liquid sugar for water allows (B) rice oil-derived gum to be easily dispersed evenly in the flour dough. (B) Rice oil-derived gum dispersed evenly in flour dough strengthens the bonds of gluten, which can have an effect of increasing the volume and softness of bread, for example.

本発明の穀粉生地用プレミックスにおける(B)米油由来ガム質の含有量は特に制限されないが、例えば10質量%以上、80質量%以下である。10質量%以上の場合には(B)米油由来ガム質の効果を十分に発揮することができる。また80質量%以下であれば本発明の穀粉生地用プレミックスを穀粉生地に混合する際の分散性に優れ、本発明の効果を十分に発揮することができる。(B)米油由来ガム質の含有量の下限値は、好ましくは20質量%以上であり、より好ましくは30質量%以上である。(B)米油由来ガム質の含有量の上限値は、好ましくは70質量%以下であり、より好ましくは60質量%以下である。 The content of (B) rice oil-derived gum in the flour dough premix of the present invention is not particularly limited, but is, for example, 10% by mass or more and 80% by mass or less. When it is 10% by mass or more, the effect of (B) rice oil-derived gum can be fully exhibited. When it is 80% by mass or less, the premix for flour dough of the present invention has excellent dispersibility when mixed with flour dough, and the effect of the present invention can be fully exhibited. The lower limit of the content of (B) rice oil-derived gum is preferably 20% by mass or more, more preferably 30% by mass or more. The upper limit of the content of (B) rice oil-derived gum is preferably 70% by mass or less, more preferably 60% by mass or less.

(B)米油由来ガム質は上記方法にて製造してもよく、市販品を入手してもよい。市販品としては、例えば、「Ricelec BK」(Irgovel社製)等が商業的に入手できる。 (B) The rice oil-derived gum may be produced by the above method, or may be obtained commercially. For example, "Ricelec BK" (manufactured by Irgovel) is a commercially available product.

(C)酵素
本発明に用いる(C)酵素の種類は特に制限されないが、例えば、α-アミラーゼ、マルトース生成α-アミラーゼ、β-アミラーゼ、グルコアミラーゼ、イソアミラーゼ、プロテアーゼ、グルコースオキシダーゼ、セルラーゼ、ヘミセルラーゼ、4-α-グルカノトランスフェラーゼ、6-α-グルカノトランスフェラーゼ等の粉末酵素が好ましく用いられる。
(C) Enzymes The type of enzyme (C) used in the present invention is not particularly limited, but for example, powdered enzymes such as α-amylase, maltogenic α-amylase, β-amylase, glucoamylase, isoamylase, protease, glucose oxidase, cellulase, hemicellulase, 4-α-glucanotransferase, and 6-α-glucanotransferase are preferably used.

本発明の穀粉生地用プレミックスにおける(C)酵素の含有量は特に制限されないが、例えば0.1~5質量%である。0.1質量%以上の場合には(C)酵素の効果を十分に発揮することができる。また5質量%以下であれば本発明の穀粉生地用プレミックスを穀粉生地に混合する際の分散性に優れ、本発明の効果を十分に発揮することができる。(C)酵素の含有量の下限値は、好ましくは0.2質量%以上であり、より好ましくは0.4質量%以上である。(C)酵素の含有量の上限値は、好ましくは4質量%以下であり、より好ましくは3質量%以下である。 The content of the enzyme (C) in the flour dough premix of the present invention is not particularly limited, but is, for example, 0.1 to 5% by mass. If it is 0.1% by mass or more, the effect of the enzyme (C) can be fully exerted. If it is 5% by mass or less, the premix for flour dough of the present invention has excellent dispersibility when mixed into flour dough, and the effect of the present invention can be fully exerted. The lower limit of the enzyme (C) content is preferably 0.2% by mass or more, and more preferably 0.4% by mass or more. The upper limit of the enzyme (C) content is preferably 4% by mass or less, and more preferably 3% by mass or less.

水溶性の(A)液糖に(C)酵素を分散させることで、穀粉生地中の澱粉やグルテン等になじみやすく、生地への分散性を向上することができるため、酵素の機能を最大限に発揮することができる。 By dispersing the enzyme (C) in the water-soluble liquid sugar (A), the enzyme can be more easily mixed with the starch, gluten, etc. in the flour dough, improving its dispersibility in the dough and allowing the enzyme to perform to its full potential.

[水分活性]
水分活性とは食品中の自由水の割合を表す数値であり、食品の保存性の指標とされるものである。本発明では、穀粉生地用プレミックスの水分活性を0.80以下とすることにより、穀粉生地用プレミックスの保存性を高めることができ、さらに穀粉生地への分散性が優れるといった想定外の効果を見出した。穀粉生地用プレミックスの保存性の観点から、0.75以下が好ましい。また、(B)米油由来ガム質又は(C)酵素の穀粉生地への分散性が向上するという観点から、0.50以上が好ましく、0.60以上がより好ましく、0.65以上が特に好ましい。
なお、本発明の水分活性は、水分活性測定装置(商品名:HygroLab、Rotronic社製)を用いて測定した。
[Water activity]
Water activity is a value that represents the proportion of free water in a food, and is an index of the shelf life of the food. In the present invention, by setting the water activity of the flour dough premix to 0.80 or less, the shelf life of the flour dough premix can be improved, and an unexpected effect of excellent dispersibility in the flour dough was found. From the viewpoint of shelf life of the flour dough premix, 0.75 or less is preferable. Also, from the viewpoint of improving the dispersibility of (B) rice oil-derived gum or (C) enzyme in the flour dough, 0.50 or more is preferable, 0.60 or more is more preferable, and 0.65 or more is particularly preferable.
The water activity in the present invention was measured using a water activity measuring device (product name: HygroLab, manufactured by Rotronic Corporation).

本発明における穀粉生地とは、穀粉に水、卵などの液状成分を混ぜ合わせた生地を指す。穀粉生地は加熱工程を経て、パン、ケーキ等さまざまな食品となる。特に限定されないが、穀粉としては、小麦粉、そば粉、ライ麦粉、大麦粉、米粉、トウモロコシ粉、オーツ粉末、小麦澱粉、トウモロコシ澱粉、モチ種トウモロコシ澱粉、馬鈴薯澱粉、さつまいも澱粉、タピオカ澱粉、米澱粉、さご澱粉、くず澱粉等を挙げることができる。穀粉の他に、イースト、イーストフード、乳化剤、油脂、加工澱粉、乳製品、食塩、糖類、調味料(グルタミン酸ソーダ類や核酸類)、保存料、ビタミン、カルシウム等の強化剤、蛋白質、アミノ酸、化学膨張剤、フレーバー、レーズン等の乾燥果実等が挙げられる。
穀粉生地は、その目的(パン、スポンジケーキ等)により水分量が異なるが、穀粉生地の水分活性は一般的に0.75以上0.98以下である。この範囲の水分活性である穀粉生地を本発明では好ましく用いることができる。
The flour dough in the present invention refers to a dough obtained by mixing flour with liquid ingredients such as water and eggs. The flour dough is heated to produce various foods such as bread and cake. Examples of flour include, but are not limited to, wheat flour, buckwheat flour, rye flour, barley flour, rice flour, corn flour, oat flour, wheat starch, corn starch, glutinous corn starch, potato starch, sweet potato starch, tapioca starch, rice starch, sago starch, and kudzu starch. In addition to flour, examples of the flour include yeast, yeast food, emulsifiers, oils and fats, processed starch, dairy products, salt, sugars, seasonings (monosodium glutamate and nucleic acids), preservatives, fortifiers such as vitamins and calcium, proteins, amino acids, chemical leavening agents, flavors, and dried fruits such as raisins.
Although the water content of flour dough varies depending on the purpose (bread, sponge cake, etc.), the water activity of flour dough is generally 0.75 to 0.98. Flour dough with a water activity in this range can be preferably used in the present invention.

[穀粉生地用プレミックスの製造方法]
本発明における穀粉生地用プレミックスは(A)液糖に対して、(B)米油由来ガム質および(C)酵素から選ばれる1種以上を添加、混合できればよい。
[Method of manufacturing flour dough premix]
The premix for grain flour dough in the present invention may be prepared by adding and mixing one or more selected from (B) rice oil-derived gums and (C) enzymes to (A) liquid sugar.

次に実施例を挙げて本発明を説明する。
[米油由来ガム質の製造]
米糠を120℃で加熱後、ヘキサンにて油溶成分を抽出し、110℃にて加熱することで溶媒を除去した米原油を用いた。
米原油を70℃に加温し、遠心分離を行い、夾雑物である沈殿部を除去した。その後、70℃の温水を米原油に対して3質量%添加し、攪拌後、遠心分離を行い、沈殿した水和物を得た。この水和物を、凍結乾燥機にて乾燥させ、水分量が5質量%以下となった米油由来ガム質を得た。得られた米油由来ガム質を以下のアセトン不溶物量は30質量%であった。
得られた米油由来ガム質を用いて、以下に示す実施例の穀粉生地用プレミックスを製造した。
The present invention will now be described with reference to examples.
[Production of gum derived from rice oil]
Rice bran was heated at 120°C, the oil-soluble components were extracted with hexane, and the solvent was removed by heating at 110°C to obtain crude rice oil.
The rice crude oil was heated to 70°C and centrifuged to remove the precipitate, which was an impurity. Then, 3% by mass of 70°C hot water was added to the rice crude oil, and after stirring, centrifuged to obtain a precipitated hydrate. This hydrate was dried in a freeze dryer to obtain a rice oil-derived gummy substance with a water content of 5% by mass or less. The amount of acetone insoluble matter in the obtained rice oil-derived gummy substance was 30% by mass.
The obtained rice oil-derived gum was used to produce the flour dough premix of the following example.

[穀粉生地用プレミックスの製造]
(実施例1-1~1-5、比較例1-1~1-2)
表1に示す配合組成の穀粉生地用プレミックスをベースに以下の方法により製造した。実施例1-1では、液糖(RCS-50)5kgをビーカー内でプロペラ攪拌にて攪拌しながら45℃まで加温する。そこに、45℃に加温した米油由来ガム質 5kgを少しずつ加え、投入後20分間攪拌を行い、穀粉生地用プレミックスを得た。
同様に、実施例1-2~1-5ついても表1に示す配合組成をベースに穀粉生地用プレミックスを上記方法で製造した。比較例1-1については米油ガム質と液糖(RCS-50)を混合せず、穀粉生地へ別々に添加した。比較例1-2については45℃まで加温した水5kgをビーカー内でプロペラ攪拌にて攪拌しながら、45℃に加温した米油由来ガム質 5kgを少しずつ加え、投入後20分間攪拌を行い、穀粉生地用プレミックスを得たが、攪拌停止直後に分離した。そして分離したものを穀粉生地へ添加した。
[Production of flour dough premix]
(Examples 1-1 to 1-5, Comparative Examples 1-1 to 1-2)
A flour dough premix having the composition shown in Table 1 was used as a base material for production by the following method. In Example 1-1, 5 kg of liquid sugar (RCS-50) was heated to 45°C in a beaker while stirring with a propeller. 5 kg of rice oil-derived gum heated to 45°C was gradually added thereto, and the mixture was stirred for 20 minutes after addition to obtain a flour dough premix.
Similarly, for Examples 1-2 to 1-5, flour dough premixes were produced by the above method based on the formulation shown in Table 1. For Comparative Example 1-1, rice oil gum and liquid sugar (RCS-50) were not mixed, but were added separately to the flour dough. For Comparative Example 1-2, 5 kg of rice oil-derived gum heated to 45°C was gradually added while stirring 5 kg of water heated to 45°C in a beaker with a propeller stirrer, and stirring was continued for 20 minutes after addition to obtain a flour dough premix, but separation occurred immediately after stirring was stopped. The separated product was then added to the flour dough.

(実施例2-1、比較例2-1~2-2)
表2に示す配合組成の穀粉生地用プレミックスをベースに以下の方法により製造した。実施例2-1では、液糖(RCS-50)9.95kgをビーカー内でプロペラ攪拌にて攪拌しながら45℃まで加温する。そこに、粉末酵素(スミチームL)50gを少しずつ加え、投入後20分間攪拌を行い、穀粉生地用プレミックスを得た。
比較例2-1については、液糖(RCS-50)と粉末酵素(スミチームL)を混合せず、穀粉生地へ別々に添加した。比較例2-2については45℃まで加温した水9.95kgをビーカー内でプロペラ攪拌にて攪拌しながら、粉末酵素(スミチームL)50gを少しずつ加え、投入後20分間攪拌を行い、穀粉生地用プレミックスを得た。
(Example 2-1, Comparative Examples 2-1 to 2-2)
A flour dough premix having the composition shown in Table 2 was used as a base material for production by the following method. In Example 2-1, 9.95 kg of liquid sugar (RCS-50) was heated to 45°C in a beaker while stirring with a propeller. 50 g of powdered enzyme (Sumiteam L) was gradually added thereto, and stirring was continued for 20 minutes after addition to obtain a flour dough premix.
In Comparative Example 2-1, the liquid sugar (RCS-50) and the powdered enzyme (Sumiteam L) were not mixed but added separately to the flour dough. In Comparative Example 2-2, 9.95 kg of water heated to 45°C was stirred in a beaker with a propeller while 50 g of the powdered enzyme (Sumiteam L) was added little by little, and the mixture was stirred for 20 minutes after the addition to obtain a flour dough premix.

(実施例3-1、比較例3-1)
表3に示す配合組成の穀粉生地用プレミックスをベースに以下の方法により製造した。液糖(RCS―50)4.95kgをビーカー内でプロペラ攪拌にて攪拌しながら45℃まで加温する。そこに、45℃に加温した米油由来ガム質 5kgを少しずつ加え、投入後10分間攪拌を行い、さらに粉末酵素(スミチームL)50gを少しづつ加え、投入後10分間攪拌を行い、穀粉生地用プレミックスを得た。比較例3-1については、液糖(RCS-50)、米油由来ガム質及び粉末酵素(スミチームL)を混合せず、穀粉生地へ別々に添加した。
(Example 3-1, Comparative Example 3-1)
A flour dough premix having the composition shown in Table 3 was produced by the following method. 4.95 kg of liquid sugar (RCS-50) was heated to 45°C in a beaker while stirring with a propeller. 5 kg of rice oil-derived gum heated to 45°C was gradually added thereto, and stirring was continued for 10 minutes after addition. 50 g of powdered enzyme (Sumiteam L) was further gradually added thereto, and stirring was continued for 10 minutes after addition to obtain a flour dough premix. For Comparative Example 3-1, the liquid sugar (RCS-50), rice oil-derived gum, and powdered enzyme (Sumiteam L) were not mixed, but were added separately to the flour dough.

[評価方法]
それぞれの評価項目について、評価方法を下記に記す。
[Evaluation method]
The evaluation methods for each evaluation item are described below.

(穀粉生地用プレミックスの水分活性)
製造した穀粉生地用プレミックスの水分活性は水分活性測定装置(商品名:HygroLab、Rotronic社製)を用いて測定した。具体的には、実施例又は比較例の穀粉生地用プレミックス各10gを水分活性測定装置の専用シャーレに配置し、25℃で水分活性を測定した。
(Water activity of flour dough premixes)
The water activity of the produced flour dough premix was measured using a water activity measuring device (product name: HygroLab, manufactured by Rotronic). Specifically, 10 g of each of the flour dough premixes of the Examples and Comparative Examples was placed in a dedicated petri dish of the water activity measuring device, and the water activity was measured at 25°C.

(穀粉生地用プレミックスの状態)
製造した穀粉生地用プレミックスを30℃、30日間保管し、状態について目視にて確認した。分離(沈殿)がないものを「良好」とし、分離(沈殿)があるものを「分離」とした。「良好」のみ合格とした。実施例1-1~1-5、比較例1-2について、米油由来ガム質と液糖が分離していないか確認を行った。実施例2-1、比較例2-2について、酵素が底部へ沈殿していないか確認を行った。実施例3-1について、米油由来ガム質と、液糖及び酵素が分離・沈殿していないか確認を行った。
(Flour dough premix)
The produced flour dough premix was stored at 30°C for 30 days and the condition was visually inspected. Those with no separation (precipitation) were rated "good", and those with separation (precipitation) were rated "separated". Only "good" were considered to pass. For Examples 1-1 to 1-5 and Comparative Example 1-2, it was checked whether the rice oil-derived gummy substance and liquid sugar had separated. For Example 2-1 and Comparative Example 2-2, it was checked whether the enzyme had precipitated to the bottom. For Example 3-1, it was checked whether the rice oil-derived gummy substance, liquid sugar and enzyme had separated and precipitated.

(穀粉生地用プレミックスの保存性)
製造した穀粉生地用プレミックスを30℃、30日間保管し、カビの発生について目視にて確認した。カビの発生がわずかにでも確認できたものは「有」、発生が確認できなかったものは「無」とした。「無」のみ合格とした。
(Storage of flour dough premix)
The produced flour dough premix was stored at 30°C for 30 days and visually inspected for mold growth. Those where even a slight amount of mold growth was observed were rated "present", and those where no mold growth was observed were rated "absent". Only those with "absent" were considered to pass.

(穀粉生地への分散性評価:目視試験)
小麦粉1kg、イースト20g、イーストフード1g、上白糖50g、塩17g、脱脂粉乳20g、水690gを関東混合機工業(株)製ミキサーボウルに投入し、ドゥフックにて低速2分間、中低速5分間攪拌後、ショートニング50gを投入し、低速3分間、中低速3分間混合後、穀粉生地用プレミックス10g投入し、低速にて攪拌し、目視にて穀粉生地用プレミックスの分散状況を確認した。
穀粉生地用プレミックスが穀粉生地へ添加後攪拌にて1分以下で分散した場合を「5」、1分を超えて2分以下で分散した場合を「4」、2分を超えて3分以下で分散した場合を「3」、3分を超えて5分以下で分散した場合を「2」、5分を超えても分散しない場合を「1」とし評価した。「5」、「4」のみ合格とした。
なお、表2実施例2-1、比較例2-1~2-2、実施例3-1、比較例3-1の酵素の分散性については目視にて確認できないため、製パン試験においてのボリューム、ソフトさ評価結果を分散性評価の指標とした。
(Evaluation of dispersibility in flour dough: visual test)
1 kg of wheat flour, 20 g of yeast, 1 g of yeast food, 50 g of white sugar, 17 g of salt, 20 g of skim milk powder, and 690 g of water were placed in a mixer bowl manufactured by Kanto Mixing Machinery Co., Ltd. and mixed with a dough hook at low speed for 2 minutes and at medium-low speed for 5 minutes. Then, 50 g of shortening was added and mixed at low speed for 3 minutes and at medium-low speed for 3 minutes. Then, 10 g of flour dough premix was added and mixed at low speed. The dispersion state of the flour dough premix was visually confirmed.
The flour dough premix was evaluated as "5" when dispersed within 1 minute or less after stirring after addition to the flour dough, as "4" when dispersed within more than 1 minute or less than 2 minutes, as "3" when dispersed within more than 2 minutes or less than 3 minutes, as "2" when dispersed within more than 3 minutes or less than 5 minutes, and as "1" when not dispersed even after 5 minutes. Only "5" and "4" were considered to be acceptable.
In addition, since the dispersibility of the enzymes in Example 2-1, Comparative Examples 2-1 to 2-2, Example 3-1, and Comparative Example 3-1 in Table 2 could not be confirmed visually, the volume and softness evaluation results in the bread-making test were used as indicators for dispersibility evaluation.

(穀粉生地への分散性評価:製パン試験)
ボリューム、ソフトさの評価については以下に示す配合にてワンローフ食パンを製造し評価を行った。なお、米油由来ガム質および酵素は穀粉生地へ均一に分散しなければ十分な効果を発揮できないことから、ボリューム、ソフトさ評価は穀粉生地への分散性評価の指標となる。
小麦粉1kg、イースト20g、イーストフード1g、上白糖50g、食塩17g、脱脂粉乳20g、水690gを関東混合機工業(株)製ミキサーボウルに投入し、ドゥフックにて低速2分間、中低速5分間攪拌後、ショートニング50gを投入し、低速3分間、中低速3分間混合後、穀粉生地用プレミックス10g投入し、低速2分間攪拌し穀粉生地(パン生地)を得た。80分間発酵したのち、430gに分割し、20分間のベンチタイムをとり、(株)オシキリ製モルダーにてコッペパン型に成型し、食パン型に詰め、温度38℃、湿度85%にて60分間ホイロをとり、上火180℃、下火210℃のオーブンにて28分間焼成しワンローフ食パンを製造した。製造後、室温まで自然放冷し、ビニール袋に密閉し室温で保管した。保管1日後に、ボリューム、ソフトさの評価を行った。
(Evaluation of dispersibility in flour dough: bread-making test)
The volume and softness were evaluated by producing a single loaf of bread with the following recipe. Note that the rice oil-derived gums and enzymes cannot be fully effective unless they are uniformly dispersed in the flour dough, so the volume and softness evaluations serve as indicators of the dispersibility of the rice oil-derived gums and enzymes in the flour dough.
1 kg of wheat flour, 20 g of yeast, 1 g of yeast food, 50 g of white sugar, 17 g of salt, 20 g of skimmed milk powder, and 690 g of water were put into a mixer bowl manufactured by Kanto Mixing Machinery Co., Ltd., and stirred with a dough hook at low speed for 2 minutes and at medium-low speed for 5 minutes, then 50 g of shortening was put in, and mixed at low speed for 3 minutes and at medium-low speed for 3 minutes, and then 10 g of flour dough premix was put in and stirred at low speed for 2 minutes to obtain flour dough (bread dough). After fermentation for 80 minutes, it was divided into 430 g, benched for 20 minutes, molded into a bread roll mold using a molder manufactured by Oshikiri Co., Ltd., packed into a bread mold, proofed for 60 minutes at a temperature of 38 ° C and humidity of 85%, and baked in an oven with an upper heat of 180 ° C and a lower heat of 210 ° C for 28 minutes to produce a one-loaf bread. After production, it was naturally cooled to room temperature, sealed in a plastic bag, and stored at room temperature. After one day of storage, the volume and softness were evaluated.

(ボリュームの評価方法)
焼成後1日目のワンローフ食パンの比容積を測定し、ボリューム評価の指標とした。比容積は、アステックス(株)製3Dレーザー体積計を用いて測定した。各表において、比較例1-1、比較例2-1、比較例3-1のワンローフ食パンの比容積を100とし、比容積が105以上の場合を「5」、105未満、102以上の場合を「4」、98以上、102未満の場合を「3」、95以上、98未満の場合を「2」、95未満の場合を「1」として評価した。「5」、「4」のみ合格とした。
(How to evaluate volume)
The specific volume of the one-loaf bread was measured on the first day after baking and used as an index for volume evaluation. The specific volume was measured using a 3D laser volume meter manufactured by Astex Corporation. In each table, the specific volume of the one-loaf bread of Comparative Example 1-1, Comparative Example 2-1, and Comparative Example 3-1 was set to 100, and the specific volume was evaluated as "5" when it was 105 or more, "4" when it was less than 105 and 102 or more, "3" when it was 98 or more and less than 102, "2" when it was 95 or more and less than 98, and "1" when it was less than 95. Only "5" and "4" were evaluated as passing.

(ソフトさの評価方法)
焼成後1日目のワンローフ食パンのソフトさを測定し、ソフトさ評価の指標とした。ワンローフ食パンを幅3cmでスライスし、中心部を4cm×4cmの正方形にカットしたものをサンプルとした。上面から1.5cm圧縮するのに必要な応力[N]を(株)山電製レオメーターで測定し、ソフトさの指標とした。各表において、比較例1-1、比較例2-1、比較例3-1のワンローフ食パンのソフトさを100とし、ソフトさが90未満の場合を「5」、90以上、95未満の場合を「4」、95以上、105未満の場合を「3」、105以上、110未満の場合を「2」、110以上の場合を「1」として評価した。「5」、「4」のみ合格とした。
(How to evaluate softness)
The softness of the one-loaf bread was measured on the first day after baking, and used as an index for softness evaluation. The one-loaf bread was sliced to a width of 3 cm, and the center was cut into a 4 cm x 4 cm square to prepare a sample. The stress [N] required to compress the bread 1.5 cm from the top surface was measured using a rheometer manufactured by Yamaden Co., Ltd., and used as an index for softness. In each table, the softness of the one-loaf bread of Comparative Example 1-1, Comparative Example 2-1, and Comparative Example 3-1 was set to 100, and the softness was evaluated as "5" when it was less than 90, "4" when it was 90 or more and less than 95, "3" when it was 95 or more and less than 105, "2" when it was 105 or more and less than 110, and "1" when it was 110 or more. Only "5" and "4" were considered to pass.

(酵素の残存活性)
1分間に1μmolのグルコースに相当する還元糖を生成する酵素量を1uとして定義し、1%の可溶性デンプン溶液を基質とし、40℃、pH7で10分間反応させ、生じた還元糖を定量することで酵素活性を求めた。
30℃、30日間保管した穀粉生地用プレミックス中の酵素活性を測定し、スミチームLの酵素活性から残存活性を評価した。
スミチームLの酵素活性を100とした際に、酵素の残存活性が95以上の場合を「5」、95未満90以上の場合を「4」、90未満85以上の場合を「3」、85未満80以上の場合を「2」、80未満の場合を「1」として評価した。「5」のみ合格とした。
(Residual enzyme activity)
The amount of enzyme that produces reducing sugars equivalent to 1 μmol of glucose per minute was defined as 1 u. A 1% soluble starch solution was used as the substrate, and the reaction was carried out at 40° C. and pH 7 for 10 minutes. The enzyme activity was calculated by quantifying the reducing sugars produced.
The enzyme activity in a flour dough premix stored at 30°C for 30 days was measured, and the residual activity was evaluated based on the enzyme activity of Sumiteam L.
When the enzyme activity of Sumiteam L was taken as 100, the residual enzyme activity of 95 or more was rated as "5", that of 90 or more but less than 95 was rated as "4", that of 85 or more but less than 90 was rated as "3", that of 80 or more but less than 85 was rated as "2", and that of less than 80 was rated as "1". Only "5" was considered to be acceptable.

(評価結果)
表1より、(A)液糖に(B)米油由来ガム質を混合することで分離なく良好な状態の穀粉生地用プレミックスが得られることが分かる。またカビ等の発生もなく、穀粉生地への分散性も優れていることが分かる。さらに、米油由来ガム質が穀粉生地へ均一分散することで、パンのボリューム、ソフトさが向上することが分かる(実施例1-1~1-5)。一方、穀粉生地用プレミックスの原料である米油由来ガム質と液糖を、混合することなく別々に穀粉生地へ投入した場合、米油由来ガム質は穀粉生地中へ均一分散せず、その結果してパンのボリューム、ソフトさ向上効果は得られない(比較例1-1)。また、プレミックスの原料として液糖ではなく水を用いた場合、米油由来ガム質と水は分離し、さらにカビの発生がみられた(比較例1-2)。
表2より、(A)液糖に(C)酵素を混合することで酵素は液糖内に均一分散され良好な状態の穀粉生地用プレミックスが得られることが分かる。またカビ等の発生もなく保存期間中の酵素の残存活性も高く維持された。さらに酵素が液糖内に均一分散することで、穀粉生地へ酵素が均一分散することができ、パンのボリューム、ソフトさが向上することが分かる(実施例2-1)。一方、穀粉生地用プレミックスの原料である酵素と液糖を、混合することなく別々に穀粉生地へ投入した場合、酵素は穀粉生地中へ均一分散せず、その結果してパンのボリューム、ソフトさ向上効果は得られない(比較例2-1)。プレミックスの原料として液糖ではなく水を用いた場合、酵素は溶解せず沈殿し、穀粉生地中へ均一分散せず、その結果としてパンのボリューム、ソフトさ向上効果は得られないことが分かる(比較例2-2)。
表3においても、表1、表2の結果と同様に本発明の穀粉生地用プレミックスを用いると良好な結果が得られた(実施例3-1)。一方、穀粉生地用プレミックスの原料である液糖、米油由来ガム質、酵素を、混合することなく別々に穀粉生地へ投入した場合、パンのボリューム、ソフトさ向上効果は得られなかった(比較例3-1)。
(Evaluation results)
From Table 1, it can be seen that by mixing (A) liquid sugar with (B) rice oil-derived gum, a flour dough premix in good condition without separation can be obtained. It can also be seen that there is no generation of mold and the like, and the dispersibility in flour dough is excellent. Furthermore, it can be seen that the rice oil-derived gum is uniformly dispersed in flour dough, improving the volume and softness of bread (Examples 1-1 to 1-5). On the other hand, when the rice oil-derived gum and liquid sugar, which are the raw materials of the flour dough premix, are added to the flour dough separately without mixing, the rice oil-derived gum does not disperse uniformly in the flour dough, and as a result, the effect of improving the volume and softness of bread cannot be obtained (Comparative Example 1-1). Furthermore, when water, rather than liquid sugar, was used as the raw material of the premix, the rice oil-derived gum and water separated, and further mold was observed (Comparative Example 1-2).
From Table 2, it can be seen that by mixing (A) liquid sugar with (C) enzyme, the enzyme is uniformly dispersed in the liquid sugar, and a good flour dough premix can be obtained. In addition, there was no generation of mold, and the residual activity of the enzyme was maintained at a high level during storage. Furthermore, it can be seen that by uniformly dispersing the enzyme in the liquid sugar, the enzyme can be uniformly dispersed in the flour dough, improving the volume and softness of the bread (Example 2-1). On the other hand, when the enzyme and liquid sugar, which are the raw materials of the flour dough premix, are added separately to the flour dough without mixing, the enzyme does not uniformly disperse in the flour dough, and as a result, the effect of improving the volume and softness of the bread is not obtained (Comparative Example 2-1). It can be seen that when water, rather than liquid sugar, is used as the raw material of the premix, the enzyme does not dissolve but precipitates, and is not uniformly dispersed in the flour dough, and as a result, the effect of improving the volume and softness of the bread is not obtained (Comparative Example 2-2).
In Table 3, similar to the results in Tables 1 and 2, good results were obtained when the flour dough premix of the present invention was used (Example 3-1). On the other hand, when the raw materials of the flour dough premix, namely, liquid sugar, rice oil-derived gum, and enzymes, were added separately to the flour dough without being mixed, the effect of improving the volume and softness of the bread was not obtained (Comparative Example 3-1).

(使用原料)
(1)(商品名)「Ricelec BK」、Irgovel製、アセトン不溶物量60質量%
(2)(商品名)「RCS-50」、王子コーンスターチ(株)製、砂糖混合ぶどう糖果糖液糖、水分活性0.73
(3)(商品名)「アマミール」、三菱商事フードテック(株)製、還元水飴、水分活性0.82
(4)(商品名)「スミチームL」、新日本化学工業(株)製、12000u/g、至適温度50℃


(Raw materials used)
(1) (Product name) "Ricelec BK", manufactured by Irgovel, acetone insoluble matter content: 60% by mass
(2) (Product name) "RCS-50", manufactured by Oji Cornstarch Co., Ltd., sugar mixed glucose-fructose liquid sugar, water activity 0.73
(3) (Product name) "AmaMeal", manufactured by Mitsubishi Corporation Foodtech Co., Ltd., reduced starch syrup, water activity 0.82
(4) (Product name) "Sumiteam L", manufactured by Shin Nippon Chemical Industry Co., Ltd., 12000 u/g, optimum temperature 50° C.


Claims (5)

(A)液糖及び(B)米油由来ガム質を含有し、水分活性が0.80以下である穀粉生地用プレミックス。 A flour dough premix containing (A) liquid sugar and (B) rice oil-derived gum and having a water activity of 0.80 or less. 前記(A)液糖の含有量が20質量%以上、90質量%以下であり、前記(B)米油由来ガム質の含有量が10質量%以上、80質量%以下である、請求項1に記載の穀粉生地用プレミックス。 The flour dough premix according to claim 1, wherein the content of the liquid sugar (A) is 20% by mass or more and 90% by mass or less, and the content of the rice oil-derived gum (B) is 10% by mass or more and 80% by mass or less. (A)液糖及び(C)酵素を含有し、水分活性が0.80以下である穀粉生地用プレミックス。 A flour dough premix containing (A) liquid sugar and (C) an enzyme and having a water activity of 0.80 or less. 前記(A)液糖の含有量が90質量%以上である、請求項3に記載の穀粉生地用プレミックス。 The flour dough premix according to claim 3, wherein the content of the liquid sugar (A) is 90% by mass or more. (A)液糖、(B)米油由来ガム質及び(C)酵素を含有し、水分活性が0.80以下である穀粉生地用プレミックス。

A premix for flour dough containing (A) liquid sugar, (B) a gum derived from rice oil, and (C) an enzyme, and having a water activity of 0.80 or less.

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