JP2018170995A - Oil and fat modifier, and oil and fat-containing food - Google Patents
Oil and fat modifier, and oil and fat-containing food Download PDFInfo
- Publication number
- JP2018170995A JP2018170995A JP2017071070A JP2017071070A JP2018170995A JP 2018170995 A JP2018170995 A JP 2018170995A JP 2017071070 A JP2017071070 A JP 2017071070A JP 2017071070 A JP2017071070 A JP 2017071070A JP 2018170995 A JP2018170995 A JP 2018170995A
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- Prior art keywords
- fatty acid
- oil
- fat
- mass
- saturated fatty
- Prior art date
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Landscapes
- Edible Oils And Fats (AREA)
- General Preparation And Processing Of Foods (AREA)
Abstract
Description
本発明は、油脂改質剤、油脂含有食品に関する。より詳細には、本発明は、トランス脂肪酸の含有量が少なく、対象物(たとえば食品)に添加されることにより、対象物の保形性が優れ、かつ、良好な口どけ性を付与し得る油脂改質剤、油脂含有食品に関する。 The present invention relates to an oil and fat modifier and an oil and fat-containing food. More specifically, the present invention has a low trans fatty acid content and is added to an object (for example, a food), whereby the object has excellent shape retention and can provide good mouth-feeling properties. The present invention relates to an oil and fat modifier and an oil and fat-containing food.
近年、健康志向の高まりとともに、たとえば食品に使用される油脂は、トランス脂肪酸を低減することが求められている(特許文献1〜2)。また、油脂は、マーガリン等の固体状態で保存される食品や、ホイップクリーム等の保形性の求められる食品に使用される場合、良好な保形性を示し、かつ、口の中で溶けやすいような融点であることが好ましい。しかしながら、このような油脂は、一般にトランス脂肪酸を多く含む硬化油脂(水素添加油脂)である。 In recent years, with increasing health consciousness, for example, fats and oils used in foods are required to reduce trans fatty acids (Patent Documents 1 and 2). In addition, fats and oils show good shape retention and are easily dissolved in the mouth when used in foods that are stored in a solid state such as margarine and foods that require shape retention such as whipped cream. Such a melting point is preferred. However, such fats and oils are generally hardened fats and oils (hydrogenated fats and oils) that contain a large amount of trans fatty acids.
パームオレインのようなトランス脂肪酸が比較的少なく、かつ、融点が低い油脂(構成脂肪酸中のシス型不飽和脂肪酸の割合が多い油脂)に対し、保形性(固化性)および口どけ性を両立し得る油脂改質剤は知られていない。特許文献1に記載の食品(マーガリン等)に使用されるポリグリセリン脂肪酸エステルや、特許文献2の食用加工油脂に使用されるポリグリセリン脂肪酸エステルは、いずれもパームオレイン等の低融点油脂に使用された場合に、形状安定性が優れない。 For oils and fats with relatively low trans-fatty acid and low melting point such as palm olein (oils and fats with a high proportion of cis-unsaturated fatty acids in the constituent fatty acids), it has both shape retention (solidification) and mouthfeel An oil and fat modifier that can be used is not known. Polyglycerin fatty acid esters used for foods (margarine and the like) described in Patent Document 1 and polyglycerin fatty acid esters used for edible processed fats and oils of Patent Document 2 are both used for low melting point fats and oils such as palm olein. The shape stability is not excellent.
本発明は、これら従来の課題に鑑みてなされたものである。本発明は、対象物(たとえば食品)に添加されることにより、対象物の保形性が優れ、かつ、良好な口どけ性を付与し得る油脂改質剤、油脂含有食品を提供することを目的とする。 The present invention has been made in view of these conventional problems. The present invention provides an oil and fat modifier and an oil and fat-containing food that can be added to an object (for example, a food) to give the object an excellent shape retention and can provide good mouth-feeling properties. Objective.
上記課題を解決する本発明の油脂改質剤、油脂含有食品には、以下の構成が主に含まれる。 The oil / fat modifier and the oil / fat-containing food of the present invention that solve the above-mentioned problems mainly include the following constitutions.
(1)構成脂肪酸として、炭素数8〜14の飽和脂肪酸(A1)と、炭素数16〜24の飽和脂肪酸(A2)とを含むショ糖脂肪酸エステル(A)を含む、油脂改質剤。 (1) An oil and fat modifier containing a sucrose fatty acid ester (A) containing a saturated fatty acid having 8 to 14 carbon atoms (A1) and a saturated fatty acid having 16 to 24 carbon atoms (A2) as a constituent fatty acid.
このような構成によれば、本発明の油脂改質剤は、油脂に用いられることにより、油脂の保形性および口どけ性が優れる。また、本発明の油脂改質剤は、油脂と混合されることにより油脂含有食品(たとえばマーガリンやホイップクリーム等)が調製される場合において、得られる油脂含有食品の保形性、口どけ性を両立させ得る。 According to such a configuration, the oil and fat modifier of the present invention is excellent in oil shape retention and mouth-feeling properties when used in oil and fat. Moreover, when the oil and fat modifier of the present invention is mixed with an oil and fat to prepare an oil and fat-containing food (for example, margarine, whipped cream, etc.), the oil-and-fat-containing food obtained has shape retention and mouthfeel. Can be compatible.
(2)グリセリン脂肪酸エステル、レシチンおよび前記ショ糖脂肪酸エステル(A)以外のショ糖脂肪酸エステルからなる群から選択される少なくとも1種をさらに含む、(1)記載の油脂改質剤。 (2) The oil and fat modifier according to (1), further comprising at least one selected from the group consisting of glycerin fatty acid ester, lecithin and sucrose fatty acid ester other than sucrose fatty acid ester (A).
このような構成によれば、油脂改質剤は、油脂と混合されることにより油脂含有食品(たとえばマーガリンやホイップクリーム等)が調製される場合において、得られる油脂含有食品の保形性、口どけ性等がより優れる。 According to such a configuration, when the oil / fat modifier is mixed with the oil / fat to prepare an oil / fat-containing food (for example, margarine or whipped cream), the shape retention of the obtained oil / fat-containing food is improved. It has better excellence.
(3)油脂と、(1)または(2)記載の油脂改質剤とを含む、油脂含有食品。 (3) A fat and oil-containing food comprising the fat and oil and the fat and oil modifier according to (1) or (2).
このような構成によれば、油脂含有食品は、本発明の油脂改質剤を含む。そのため、得られる油脂含有食品は、保形性、口どけ性等がより優れる。 According to such a structure, the fat-and-oil containing food contains the fat-and-oil modifier of the present invention. Therefore, the oil-and-fat-containing foods obtained are more excellent in shape retention, mouth-feeling properties and the like.
本発明によれば、対象物(たとえば食品)に添加されることにより、対象物の保形性が優れ、かつ、良好な口どけ性を付与し得る油脂改質剤、油脂含有食品を提供することができる。 According to the present invention, there are provided an oil and fat modifier and an oil and fat-containing food that are excellent in the shape retention of the object and can impart good mouth-feeling properties by being added to the object (for example, food). be able to.
<油脂改質剤>
本発明の一実施形態の油脂改質剤は、構成脂肪酸として、炭素数8〜14の飽和脂肪酸(A1)と、炭素数16〜24の飽和脂肪酸(A2)とを含むショ糖脂肪酸エステル(A)を含む。以下、それぞれについて説明する。
<Oil modifier>
The oil and fat modifier according to one embodiment of the present invention includes a sucrose fatty acid ester (A) containing, as constituent fatty acids, a saturated fatty acid having 8 to 14 carbon atoms (A1) and a saturated fatty acid having 16 to 24 carbon atoms (A2). )including. Each will be described below.
(ショ糖脂肪酸エステル(A))
ショ糖脂肪酸エステル(A)は、構成脂肪酸として、炭素数8〜14の飽和脂肪酸(A1)と、炭素数16〜24の飽和脂肪酸(A2)とを含む。
(Sucrose fatty acid ester (A))
Sucrose fatty acid ester (A) contains a C8-C14 saturated fatty acid (A1) and a C16-C24 saturated fatty acid (A2) as a constituent fatty acid.
・炭素数8〜14の飽和脂肪酸(A1)
炭素数8〜14の飽和脂肪酸(A1)は特に限定されない。一例を挙げると、飽和脂肪酸(A1)は、カプリル酸、ペラルゴン酸、カプリン酸、ラウリン酸、ミリスチン酸等である。飽和脂肪酸(A1)は、併用されてもよい。これらの中でも、飽和脂肪酸(A1)は、保形性がより優れる点から、炭素数12の飽和脂肪酸(たとえばラウリン酸)であることが好ましい。
-C8-14 saturated fatty acid (A1)
The saturated fatty acid (A1) having 8 to 14 carbon atoms is not particularly limited. For example, the saturated fatty acid (A1) is caprylic acid, pelargonic acid, capric acid, lauric acid, myristic acid and the like. The saturated fatty acid (A1) may be used in combination. Among these, the saturated fatty acid (A1) is preferably a saturated fatty acid having 12 carbon atoms (for example, lauric acid) from the viewpoint of better shape retention.
飽和脂肪酸(A1)の含有量は特に限定されない。一例を挙げると、飽和脂肪酸(A1)の含有量は、保形性がより優れる点から、ショ糖脂肪酸エステル(A)中、3質量%以上であることが好ましく、5質量%以上であることがより好ましく、8質量%以上であることがさらに好ましく、10質量%以上であることが特に好ましい。また、飽和脂肪酸(A1)の含有量は、保形性がより優れる点から、ショ糖脂肪酸エステル(A)中、50質量%以下であることが好ましく、40質量%以下であることがより好ましく、30質量%以下であることがさらに好ましい。 The content of the saturated fatty acid (A1) is not particularly limited. For example, the content of the saturated fatty acid (A1) is preferably 3% by mass or more, preferably 5% by mass or more in the sucrose fatty acid ester (A), from the viewpoint of better shape retention. Is more preferably 8% by mass or more, and particularly preferably 10% by mass or more. In addition, the content of the saturated fatty acid (A1) is preferably 50% by mass or less and more preferably 40% by mass or less in the sucrose fatty acid ester (A) from the viewpoint of better shape retention. More preferably, it is 30% by mass or less.
・炭素数16〜24の飽和脂肪酸(A2)
炭素数16〜24の飽和脂肪酸(A2)は特に限定されない。一例を挙げると、飽和脂肪酸(A2)は、パルミチン酸、マルガリン酸、ステアリン酸、アラキジン酸、ヘンイコシル酸、ベヘン酸、リグノセリン酸等である。飽和脂肪酸(A2)は、併用されてもよい。これらの中でも、飽和脂肪酸(A2)は、保形性および口どけ性がより優れる点から、炭素数16〜18の飽和脂肪酸を含むことが好ましく、炭素数16の飽和脂肪酸(たとえばパルミチン酸)および炭素数18の飽和脂肪酸(たとえばステアリン酸)を含むことがより好ましい。
-C16-24 saturated fatty acid (A2)
The saturated fatty acid (A2) having 16 to 24 carbon atoms is not particularly limited. For example, the saturated fatty acid (A2) is palmitic acid, margaric acid, stearic acid, arachidic acid, helicosyl acid, behenic acid, lignoceric acid and the like. The saturated fatty acid (A2) may be used in combination. Among these, the saturated fatty acid (A2) preferably contains a saturated fatty acid having 16 to 18 carbon atoms from the viewpoint of more excellent shape retention and mouth-opening properties, and a saturated fatty acid having 16 to 16 carbon atoms (for example, palmitic acid) and More preferably, it contains a saturated fatty acid having 18 carbon atoms (for example, stearic acid).
飽和脂肪酸(A2)の含有量は特に限定されない。一例を挙げると、飽和脂肪酸(A2)の含有量は、保形性がより優れる点から、ショ糖脂肪酸エステル(A)中、30質量%以上であることが好ましく、40質量%以上であることがより好ましく、50質量%以上であることがさらに好ましく、60質量%以上であることが特に好ましい。また、飽和脂肪酸(A2)の含有量は、口どけ性がより優れる点から、ショ糖脂肪酸エステル(A)中、97質量%以下であることが好ましく、95質量%以下であることがより好ましく、92質量%以下であることがさらに好ましく、90質量%以下であることが特に好ましい。 The content of the saturated fatty acid (A2) is not particularly limited. For example, the content of the saturated fatty acid (A2) is preferably 30% by mass or more and 40% by mass or more in the sucrose fatty acid ester (A) from the viewpoint of better shape retention. Is more preferably 50% by mass or more, and particularly preferably 60% by mass or more. In addition, the content of the saturated fatty acid (A2) is preferably 97% by mass or less, more preferably 95% by mass or less in the sucrose fatty acid ester (A) from the viewpoint that the mouth-feeling property is more excellent. Is more preferably 92% by mass or less, and particularly preferably 90% by mass or less.
飽和脂肪酸(A1)と飽和脂肪酸(A2)との含有割合は、保形性がより優れる点から、飽和脂肪酸(A1)1モルに対して、飽和脂肪酸(A2)を2モル以上含むことが好ましく、2.5モル以上含むことがより好ましく、3モル以上含むことがさらに好ましい。また、飽和脂肪酸(A1)と飽和脂肪酸(A2)との含有割合は、口どけ性がより優れる点から、飽和脂肪酸(A1)1モルに対して、飽和脂肪酸(A2)を10モル以下含むことが好ましく、8モル以下で含むことがより好ましく、7モル以下含むことがさらに好ましい。 The content ratio of the saturated fatty acid (A1) and the saturated fatty acid (A2) is preferably 2 mol or more of the saturated fatty acid (A2) with respect to 1 mol of the saturated fatty acid (A1) from the viewpoint of better shape retention. More preferably 2.5 mol or more, and further preferably 3 mol or more. Moreover, the content rate of a saturated fatty acid (A1) and a saturated fatty acid (A2) contains 10 mol or less of saturated fatty acids (A2) with respect to 1 mol of saturated fatty acids (A1) from the point that mouth-feel property is more excellent. It is more preferable that it is contained in 8 mol or less, and it is more preferable that it is contained in 7 mol or less.
飽和脂肪酸(A2)が炭素数16の飽和脂肪酸および炭素数18の飽和脂肪酸を含む場合において、炭素数16の飽和脂肪酸と炭素数18の飽和脂肪酸との割合は特に限定されない。一例を挙げると、炭素数16の飽和脂肪酸と炭素数18の飽和脂肪酸との割合は、20/80〜95/5(質量比)であることが好ましく、30/70〜92/8であることがより好ましく、40/60〜90/10であることがさらに好ましく、70/30〜85/15であることが特に好ましい。 In the case where the saturated fatty acid (A2) contains a saturated fatty acid having 16 carbon atoms and a saturated fatty acid having 18 carbon atoms, the ratio of the saturated fatty acid having 16 carbon atoms and the saturated fatty acid having 18 carbon atoms is not particularly limited. For example, the ratio of the saturated fatty acid having 16 carbon atoms and the saturated fatty acid having 18 carbon atoms is preferably 20/80 to 95/5 (mass ratio), and preferably 30/70 to 92/8. Is more preferably 40/60 to 90/10, and particularly preferably 70/30 to 85/15.
また、飽和脂肪酸(A2)が炭素数16の飽和脂肪酸および炭素数18の飽和脂肪酸を含む場合において、炭素数16の飽和脂肪酸および炭素数18の飽和脂肪酸の配合割合は特に限定されない。一例を挙げると、炭素数18の飽和脂肪酸は、保形性がより優れる点から、炭素数16の飽和脂肪酸100質量部に対し、5質量部以上配合されることが好ましく、10質量部以上配合されることがより好ましく、15質量部以上配合されることがさらに好ましい。また、炭素数18の飽和脂肪酸は、口どけ性がより優れる点から、炭素数16の飽和脂肪酸100質量部に対し、250質量部以下配合されることが好ましく、150質量部以下配合されることがより好ましく、100質量部以下配合されることがさらに好ましく、50質量部以下配合されることが特に好ましく、30質量部以下配合されることがより特に好ましい。 Further, when the saturated fatty acid (A2) includes a saturated fatty acid having 16 carbon atoms and a saturated fatty acid having 18 carbon atoms, the blending ratio of the saturated fatty acid having 16 carbon atoms and the saturated fatty acid having 18 carbon atoms is not particularly limited. For example, the saturated fatty acid having 18 carbon atoms is preferably blended in an amount of 5 parts by mass or more with respect to 100 parts by mass of the saturated fatty acid having 16 carbons from the viewpoint of better shape retention. It is more preferable that 15 parts by mass or more is blended. Moreover, it is preferable that 250 mass parts or less is mix | blended with respect to 100 mass parts of C16 saturated fatty acids, and 150 mass parts or less are mix | blended with respect to 100 mass parts of saturated fatty acids with a C18 saturated fatty acid from the point which mouth-feel property is more excellent. Is more preferably 100 parts by mass or less, further preferably 50 parts by mass or less, and particularly preferably 30 parts by mass or less.
また、炭素数16の飽和脂肪酸と炭素数18の飽和脂肪酸の含有割合は、保形性がより優れる点から、炭素数16の飽和脂肪酸1モルに対し、炭素数18の飽和脂肪酸を0.05モル以上含むことが好ましく、0.1モル以上含むことがより好ましい。また、炭素数16の飽和脂肪酸と炭素数18の飽和脂肪酸の含有割合は、口どけ性がより優れる点から、炭素数16の飽和脂肪酸1モルに対し、炭素数18の飽和脂肪酸を0.5モル以下含むことが好ましく、0.4モル以下含むことがより好ましく、0.3モル以下含むことがさらに好ましい。 In addition, the content ratio of the saturated fatty acid having 16 carbon atoms and the saturated fatty acid having 18 carbon atoms is 0.05% of the saturated fatty acid having 18 carbon atoms with respect to 1 mol of the saturated fatty acid having 16 carbon atoms from the viewpoint of better shape retention. It is preferable to contain more than mol, more preferably more than 0.1 mol. In addition, the content ratio of the saturated fatty acid having 16 carbon atoms and the saturated fatty acid having 18 carbon atoms is 0.5% of the saturated fatty acid having 18 carbon atoms with respect to 1 mol of the saturated fatty acid having 16 carbon atoms from the viewpoint of more excellent orality. It is preferably contained in an amount of not more than mol, more preferably not more than 0.4 mol, and still more preferably not more than 0.3 mol.
飽和脂肪酸(A1)と炭素数16の飽和脂肪酸との含有割合は、保形性がより優れる点から、飽和脂肪酸(A1)1モルに対し、炭素数16の飽和脂肪酸を1.5モル以上含むことが好ましく、2モル以上含むことがより好ましく、2.5モル以上含むことがさらに好ましい。また、飽和脂肪酸(A1)と炭素数16の飽和脂肪酸との含有割合は、口どけ性がより優れる点から、飽和脂肪酸(A1)1モルに対し、炭素数16の飽和脂肪酸を10モル以下含むことが好ましく、8モル以下含むことがより好ましく、7モル以下含むことがさらに好ましい。 The content ratio of the saturated fatty acid (A1) and the saturated fatty acid having 16 carbon atoms includes 1.5 moles or more of the saturated fatty acid having 16 carbon atoms with respect to 1 mole of the saturated fatty acid (A1) from the viewpoint of better shape retention. Preferably, 2 mol or more is contained, more preferably 2.5 mol or more. In addition, the content ratio of the saturated fatty acid (A1) and the saturated fatty acid having 16 carbon atoms includes 10 mol or less of the saturated fatty acid having 16 carbon atoms with respect to 1 mol of the saturated fatty acid (A1) from the viewpoint of more excellent orality. It is preferable that 8 mol or less is included, and 7 mol or less is more preferable.
飽和脂肪酸(A1)と炭素数18の飽和脂肪酸との含有割合は、保形性がより優れる点から、飽和脂肪酸(A1)1モルに対し、炭素数18の飽和脂肪酸を0.1モル以上含むことが好ましく、0.2モル以上含むことがより好ましく、0.3モル以上含むことがさらに好ましい。また、飽和脂肪酸(A1)と炭素数18の飽和脂肪酸との含有割合は、口どけ性がより優れる点から、飽和脂肪酸(A1)1モルに対し、炭素数18の飽和脂肪酸を2.5モル以下含むことが好ましく、2モル以下含むことがより好ましく、1.5モル以下含むことがさらに好ましい。 The content ratio of the saturated fatty acid (A1) and the saturated fatty acid having 18 carbon atoms includes 0.1 mol or more of the saturated fatty acid having 18 carbon atoms with respect to 1 mol of the saturated fatty acid (A1) from the viewpoint of better shape retention. It is preferable that 0.2 mol or more is included, and 0.3 mol or more is more preferable. In addition, the content ratio of the saturated fatty acid (A1) and the saturated fatty acid having 18 carbon atoms is 2.5 mol of the saturated fatty acid having 18 carbon atoms with respect to 1 mol of the saturated fatty acid (A1) from the viewpoint of more excellent orality. It is preferably contained in an amount of preferably 2 mol or less, more preferably 1.5 mol or less.
ショ糖脂肪酸エステル(A)全体の説明に戻り、ショ糖脂肪酸エステル(A)の平均エステル化度は、保形性がより優れる点から、4以上であることが好ましく、4.5以上であることがより好ましく、5以上であることがさらに好ましい。また、平均エステル化度は、口どけ性がより優れる点から、7.5以下であることが好ましく、7以下であることがより好ましい。なお、本実施形態において、平均エステル化度は、下記式より算出し得る。 Returning to the description of the sucrose fatty acid ester (A) as a whole, the average degree of esterification of the sucrose fatty acid ester (A) is preferably 4 or more, more preferably 4.5 or more from the viewpoint of better shape retention. More preferably, it is 5 or more. In addition, the average degree of esterification is preferably 7.5 or less, more preferably 7 or less, from the viewpoint that the mouth-feeling property is more excellent. In this embodiment, the average degree of esterification can be calculated from the following formula.
<平均エステル化度の算出方法>
平均エステル化度を「X」とする次式において、下記OHV、MwSug、MwFaを代入してXを算出する。
(ショ糖1分子中のOH基の数−X)
=(サンプル1g中のOH基のモル数)/(サンプル1g中のショ糖脂肪酸エステルのモル数)
=((OHV)/(1000×56.11))/{1/(MwSug+(MwFa−18)X)}
OHV:ショ糖脂肪酸エステルの水酸基価(mgKOH/g)
MwSug:ショ糖の分子量
MwFa:構成脂肪酸の平均分子量
<Calculation method of average esterification degree>
In the following formula where the average degree of esterification is “X”, X is calculated by substituting the following OHV, MwSug, and MwFa.
(Number of OH groups in one sucrose molecule-X)
= (Mole number of OH group in 1 g of sample) / (Mole number of sucrose fatty acid ester in 1 g of sample)
= ((OHV) / (1000 × 56.11)) / {1 / (MwSug + (MwFa−18) X)}
OHV: Hydroxyl value of sucrose fatty acid ester (mgKOH / g)
MwSug: Molecular weight of sucrose
MwFa: Average molecular weight of constituent fatty acids
飽和脂肪酸(A1)および飽和脂肪酸(A2)の配合割合は特に限定されない。一例を挙げると、飽和脂肪酸(A1)は、口どけ性がより優れる点から、飽和脂肪酸(A2)100質量部に対し、3質量部以上配合されることが好ましく、8質量部以上配合されることがより好ましく、10質量部以上配合されることがさらに好ましい。また、飽和脂肪酸(A1)は、保形性がより優れる点から、飽和脂肪酸(A2)100質量部に対し、50質量部以下配合されることが好ましく、40質量部以下配合されることがより好ましく、30質量部以下配合されることがさらに好ましい。 The blending ratio of the saturated fatty acid (A1) and the saturated fatty acid (A2) is not particularly limited. If an example is given, it is preferable that 3 mass parts or more are mix | blended with respect to 100 mass parts of saturated fatty acid (A2), and 8 mass parts or more are contained for saturated fatty acid (A1) from the point which mouth-feel property is more excellent. It is more preferable that 10 parts by mass or more is blended. Moreover, it is preferable that 50 mass parts or less are mix | blended with respect to 100 mass parts of saturated fatty acid (A2), and, as for saturated fatty acid (A1), 40 mass parts or less are mix | blended from the point which shape retention property is more excellent. Preferably, 30 parts by mass or less is further blended.
飽和脂肪酸(A2)が炭素数16の飽和脂肪酸を含む場合において、飽和脂肪酸(A1)および炭素数16の飽和脂肪酸の配合割合は特に限定されない。一例を挙げると、炭素数16の飽和脂肪酸は、保形性がより優れる点から、飽和脂肪酸(A1)100質量部に対し、100質量部以上配合されることが好ましく、200質量部以上配合されることがより好ましく、300質量部以上配合されることがさらに好ましく、400質量部以上配合されることが特に好ましい。また、炭素数16の飽和脂肪酸は、保形性がより優れる点から、飽和脂肪酸(A1)100質量部に対し、1000質量部以下配合されることが好ましく、900質量部以下配合されることがより好ましく、800質量部以下配合されることがさらに好ましい。 In the case where the saturated fatty acid (A2) contains a saturated fatty acid having 16 carbon atoms, the blending ratio of the saturated fatty acid (A1) and the saturated fatty acid having 16 carbon atoms is not particularly limited. For example, the saturated fatty acid having 16 carbon atoms is preferably blended in an amount of 100 parts by mass or more and 100 parts by mass or more based on 100 parts by mass of the saturated fatty acid (A1) from the viewpoint of better shape retention. It is more preferable that 300 parts by mass or more is added, and 400 parts by mass or more is particularly preferable. Moreover, it is preferable that 1000 mass parts or less is mix | blended with respect to 100 mass parts of saturated fatty acid (A1), and 900 mass parts or less may be mix | blended with respect to 100 mass parts of saturated fatty acid (A1) from the point that shape retention property is more excellent. More preferably, it is more preferably 800 parts by mass or less.
飽和脂肪酸(A2)が炭素数18の飽和脂肪酸を含む場合において、飽和脂肪酸(A1)および炭素数18の飽和脂肪酸の配合割合は特に限定されない。一例を挙げると、炭素数18の飽和脂肪酸は、保形性がより優れる点から、飽和脂肪酸(A1)100質量部に対し、50質量部以上配合されることが好ましく、100質量部以上配合されることがより好ましい。また、炭素数18の飽和脂肪酸は、保形性および口どけ性がより優れる点から、飽和脂肪酸(A1)100質量部に対し、400質量部以下配合されることが好ましく、300質量部以下配合されることがより好ましく、200質量部以下配合されることがさらに好ましい。 When the saturated fatty acid (A2) contains a saturated fatty acid having 18 carbon atoms, the blending ratio of the saturated fatty acid (A1) and the saturated fatty acid having 18 carbon atoms is not particularly limited. For example, the saturated fatty acid having 18 carbon atoms is preferably blended in an amount of 50 parts by mass or more and 100 parts by mass or more based on 100 parts by mass of the saturated fatty acid (A1) from the viewpoint of better shape retention. More preferably. The saturated fatty acid having 18 carbon atoms is preferably added in an amount of 400 parts by mass or less and 100 parts by mass or less with respect to 100 parts by mass of the saturated fatty acid (A1) from the viewpoint of better shape retention and mouthfeel. It is more preferable that 200 parts by mass or less is blended.
なお、ショ糖脂肪酸エステル(A)は、構成脂肪酸として、飽和脂肪酸(A1)および飽和脂肪酸(A2)以外の他の脂肪酸を含んでもよい。他の脂肪酸は、酢酸、プロピオン酸、ブタン酸、ペンタン酸、ヘキサン酸、ヘプタン酸、ペンタデカン酸、ヘキサコサン酸、オクタコサン酸などの飽和脂肪酸、ミリストレイン酸、パルミトレイン酸、オレイン酸、バクセン酸、リノール酸、リノレン酸、エレオステアリン酸、エイコサジエン酸、エイコサトリエン酸、エイコサテトラエン酸、エイコサペンタエン酸、ドコサジエン酸、ドコサトリエン酸、ドコサテトラエン酸、ドコサペンタエン酸、ドコサテトラエン酸、ネルボン酸などの不飽和脂肪酸等である。 In addition, sucrose fatty acid ester (A) may contain fatty acids other than saturated fatty acid (A1) and saturated fatty acid (A2) as a constituent fatty acid. Other fatty acids are acetic acid, propionic acid, butanoic acid, pentanoic acid, hexanoic acid, heptanoic acid, pentadecanoic acid, hexacosanoic acid, octacosanoic acid and other saturated fatty acids, myristoleic acid, palmitoleic acid, oleic acid, vaccenic acid, linoleic acid , Linolenic acid, eleostearic acid, eicosadienoic acid, eicosatrienoic acid, eicosatetraenoic acid, eicosapentaenoic acid, docosadienoic acid, docosatrienoic acid, docosatetraenoic acid, docosapentaenoic acid, docosatetraenoic acid, nervonic acid And unsaturated fatty acids.
ショ糖脂肪酸エステル(A)の含有量は特に限定されない。一例を挙げると、ショ糖脂肪酸エステル(A)の含有量は、保形性がより優れる点から、油脂改質剤中、5質量%以上であることが好ましく、10質量%以上であることがより好ましく、20質量%以上であることがさらに好ましい。ショ糖脂肪酸エステル(A)の含有量は、油脂改質剤中、100質量%であってもよい。 The content of the sucrose fatty acid ester (A) is not particularly limited. For example, the content of the sucrose fatty acid ester (A) is preferably 5% by mass or more and preferably 10% by mass or more in the oil and fat modifier from the viewpoint of better shape retention. More preferably, it is more preferably 20% by mass or more. The content of the sucrose fatty acid ester (A) may be 100% by mass in the oil and fat modifier.
(好適に配合される任意成分)
本実施形態の油脂改質剤は、上記ショ糖脂肪酸エステル(A)以外に、適宜、任意成分が含有されてもよい。好適な任意成分は、グリセリン脂肪酸エステル、レシチンおよび上記ショ糖脂肪酸エステル(A)以外の他のショ糖脂肪酸エステルからなる群から選択される少なくとも1種の任意成分である。これら好適な任意成分が含有されることにより、油脂改質剤は、油脂と混合されることにより油脂含有食品(たとえばマーガリンやホイップクリーム等)が調製される場合において、得られる油脂含有食品の保形性、口どけ性等がより優れる。これらの中でも、好適な任意成分は、グリセリン脂肪酸エステルを含むことが好ましく、グリセリン脂肪酸モノエステル(モノグリセリド)を含むことがより好ましい。
(Optional component to be blended suitably)
In addition to the sucrose fatty acid ester (A), the oil and fat modifier of the present embodiment may contain arbitrary components as appropriate. A suitable optional component is at least one optional component selected from the group consisting of glycerin fatty acid ester, lecithin and sucrose fatty acid ester other than the above sucrose fatty acid ester (A). When these suitable optional components are contained, the oil and fat modifier is mixed with the oil and fat to prepare the oil and fat-containing food (for example, margarine and whipped cream). More excellent in shape and mouth-feel. Among these, it is preferable that a suitable arbitrary component contains glycerol fatty acid ester, and it is more preferable that glycerol fatty acid monoester (monoglyceride) is included.
これら好適な任意成分の含有量は特に限定されない。一例を挙げると、これら好適な任意成分の含有量は、油脂改質剤中、1質量%以上であることが好ましく、5質量%以上であることがより好ましく、10質量%以上であることがさらに好ましい。また、これら好適な任意成分の含有量は、油脂改質剤中、80質量%以下であることが好ましく、60質量%以下であることがより好ましく、40質量%以下であることがさらに好ましい。 The content of these suitable optional components is not particularly limited. As an example, the content of these suitable optional components is preferably 1% by mass or more, more preferably 5% by mass or more, and more preferably 10% by mass or more in the oil and fat modifier. Further preferred. Further, the content of these suitable optional components is preferably 80% by mass or less, more preferably 60% by mass or less, and further preferably 40% by mass or less in the oil and fat modifier.
(他の任意成分)
本実施形態の油脂改質剤は、上記ショ糖脂肪酸エステル(A)や好適に配合される任意成分以外に、適宜、他の任意成分が含有されてもよい。このような他の任意成分は、ジグリセリン脂肪酸エステル、ジアシルグリセロール、有機酸モノグリセリド、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレート、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル等である。
(Other optional ingredients)
In addition to the sucrose fatty acid ester (A) and an optional component that is suitably blended, the oil and fat modifier of this embodiment may contain other optional components as appropriate. Such other optional components are diglycerin fatty acid ester, diacylglycerol, organic acid monoglyceride, polyglycerin fatty acid ester, polyglycerin condensed ricinolate, sorbitan fatty acid ester, propylene glycol fatty acid ester and the like.
以上、本実施形態の油脂改質剤は、油脂に用いられることにより、油脂の保形性および口どけ性が優れる。また、油脂改質剤は、油脂と混合されることにより油脂含有食品(たとえばマーガリンやホイップクリーム等)が調製される場合において、得られる油脂含有食品の保形性、口どけ性を両立させ得る。 As described above, the oil and fat modifier of the present embodiment is excellent in the shape retention and mouth-feeling properties of fats and oils when used in fats and oils. In addition, when an oil-and-fat-containing food (for example, margarine or whipped cream) is prepared by mixing with an oil or fat, the oil-and-fat modifier can achieve both shape retention and mouth-feeling properties of the obtained oil and fat-containing food. .
<油脂改質剤の製造方法>
本実施形態の油脂改質剤の製造方法は特に限定されない。一例を挙げると、油脂改質剤は、ショ糖、飽和脂肪酸(A1)および飽和脂肪酸(A2)をジメチルスルホキシド(DMSO)等の適宜の溶媒に溶解し、加熱し、減圧下で数時間反応させ、溶媒を留去し、精製、乾燥することによりショ糖脂肪酸エステルを作製し、得られたショ糖脂肪酸エステルを、そのまま、または、適宜の任意成分を混合することにより、製造し得る。
<Manufacturing method of oil and fat modifier>
The manufacturing method of the fat modifier of this embodiment is not specifically limited. For example, the oil and fat modifier is prepared by dissolving sucrose, saturated fatty acid (A1) and saturated fatty acid (A2) in an appropriate solvent such as dimethyl sulfoxide (DMSO), heating, and reacting for several hours under reduced pressure. The sucrose fatty acid ester can be produced by distilling off the solvent, purifying and drying, and the resulting sucrose fatty acid ester can be produced as it is or by mixing appropriate arbitrary components.
<油脂含有食品>
本発明の一実施形態の油脂含有食品は、油脂と、上記した油脂改質剤とを含む。
<Oil-containing food>
The fat and oil-containing food of one embodiment of the present invention contains fat and oil and the above-described fat and oil modifier.
(油脂)
油脂は特に限定されない。一例を挙げると、油脂は、構成脂肪酸中に、シス型不飽和脂肪酸を含むことが好ましい。シス型不飽和脂肪酸は特に限定されない。一例を挙げると、シス型不飽和脂肪酸は、ミリストレイン酸、パルミトレイン酸、サピエン酸、オレイン酸、ガドレイン酸、エイコセン酸、エルカ酸、ネルボン酸、リノール酸、リノレン酸、エイコサジエン酸、エイコサペンタエン酸、ドコサジエン酸、ドコサヘキサエン酸等である。シス型不飽和脂肪酸は併用されてもよい。これらの中でも、シス型不飽和脂肪酸は、オレイン酸、エルカ酸、リノール酸、リノレン酸、エイコサペンタエン酸、ドコサヘキサエン酸であることが好ましい。より具体的には、油脂は、これら不飽和脂肪酸を含むパームオレイン、パームスーパーオレイン、パーム核オレイン、綿実油等であることが好ましい。
(Oil and fat)
Oils and fats are not particularly limited. If an example is given, it is preferable that fats and oils contain a cis type unsaturated fatty acid in a constituent fatty acid. The cis unsaturated fatty acid is not particularly limited. For example, cis-type unsaturated fatty acids include myristoleic acid, palmitoleic acid, sapienoic acid, oleic acid, gadoleic acid, eicosenoic acid, erucic acid, nervonic acid, linoleic acid, linolenic acid, eicosadienoic acid, eicosapentaenoic acid, Docosadienoic acid, docosahexaenoic acid and the like. A cis-type unsaturated fatty acid may be used in combination. Among these, the cis-type unsaturated fatty acid is preferably oleic acid, erucic acid, linoleic acid, linolenic acid, eicosapentaenoic acid, or docosahexaenoic acid. More specifically, the fat is preferably palm olein, palm super olein, palm kernel olein, cottonseed oil or the like containing these unsaturated fatty acids.
シス型不飽和脂肪酸の含有量は特に限定されない。一例を挙げると、シス型不飽和脂肪酸の含有量は、構成脂肪酸中、10質量%以上であることが好ましく、20質量%以上であることがより好ましく、30質量%以上であることがさらに好ましい。また、シス型不飽和脂肪酸の含有量は、構成脂肪酸中、80質量%以下であることが好ましく、70質量%以下であることがより好ましく、60質量%以下であることがさらに好ましい。このような油脂が使用されることにより、油脂含有食品は、トランス脂肪酸の含有量が低減され得る。 The content of the cis-type unsaturated fatty acid is not particularly limited. As an example, the content of the cis-type unsaturated fatty acid is preferably 10% by mass or more, more preferably 20% by mass or more, and further preferably 30% by mass or more in the constituent fatty acids. . Moreover, it is preferable that it is 80 mass% or less in constituent fatty acid, as for content of a cis type unsaturated fatty acid, it is more preferable that it is 70 mass% or less, and it is further more preferable that it is 60 mass% or less. By using such fats and oils, the content of trans fatty acids can be reduced in the fat and oil-containing foods.
油脂の含有量は特に限定されない。油脂の含有量は、油脂含有食品の種類等に基づき、適宜調整され得る。一例を挙げると、油脂の含有量は、油脂含有食品中、10〜90質量%であることが好ましい。より具体的には、油脂含有食品がホイップクリームである場合、油脂の含有量は、保形性がより優れる点から、ホイップクリーム中、20質量%以上であることが好ましく、25質量%以上であることがより好ましく、28質量%以上であることがさらに好ましい。また、油脂の含有量は、分散性がより優れ、より低粘度となる点から、ホイップクリーム中、50質量%以下であることが好ましく、45質量%以下であることがより好ましく、42質量%以下であることがさらに好ましい。また、油脂含有食品がマーガリンまたはスプレッドである場合、油脂の含有量は、乳化性が優れる点から、マーガリンまたはスプレッド中、20質量%以上であることが好ましく、30質量%以上であることがより好ましく、40質量%以上であることがさらに好ましい。また、油脂の含有量は、マーガリンまたはスプレッド中、85質量%以下であることが好ましく、80質量%以下であることがより好ましく、75質量%以下であることがさらに好ましい。 The content of fats and oils is not particularly limited. The content of fats and oils can be adjusted as appropriate based on the type of the fat-and-fat-containing food. If an example is given, it is preferable that content of fats and oils is 10-90 mass% in fats and oils containing foodstuffs. More specifically, when the fat-containing food is a whipped cream, the content of the fat is preferably 20% by mass or more, more preferably 25% by mass or more in the whipped cream, from the viewpoint of better shape retention. More preferably, it is more preferably 28% by mass or more. In addition, the fat content is preferably 50% by mass or less, more preferably 45% by mass or less, and 42% by mass in the whipped cream from the viewpoint that the dispersibility is more excellent and the viscosity becomes lower. More preferably, it is as follows. In addition, when the fat-containing food is margarine or spread, the content of the fat is preferably 20% by mass or more, more preferably 30% by mass or more in the margarine or spread from the viewpoint of excellent emulsifiability. Preferably, it is more preferably 40% by mass or more. Moreover, it is preferable that it is 85 mass% or less in margarine or a spread, as for content of fats and oils, it is more preferable that it is 80 mass% or less, and it is further more preferable that it is 75 mass% or less.
(油脂改質剤)
油脂改質剤は、上記のとおりである。油脂改質剤の含有量は特に限定されない。一例を挙げると、油脂改質剤の含有量は、保形性がより優れる点から、油脂含有食品中、0.1質量%以上であることが好ましく、0.2質量%以上であることがより好ましく、0.5質量%以上であることがさらに好ましく、1質量%以上であることが特に好ましい。また、油脂改質剤の含有量は、口どけ性および風味がより優れる点から、油脂含有食品中、10質量%以上であることが好ましく、5質量%以上であることがより好ましく、3質量%以上であることがさらに好ましく、2質量%以上であることが特に好ましい。
(Oil modifier)
The oil and fat modifier is as described above. The content of the oil and fat modifier is not particularly limited. For example, the content of the oil and fat modifier is preferably 0.1% by mass or more, and preferably 0.2% by mass or more in the oil / fat-containing food from the viewpoint of better shape retention. More preferably, it is more preferably 0.5% by mass or more, and particularly preferably 1% by mass or more. In addition, the content of the oil / fat modifier is preferably 10% by mass or more, more preferably 5% by mass or more, and more preferably 3% by mass in the oil / fat-containing food from the viewpoint of more excellent mouthfeel and flavor. % Or more is more preferable, and 2% by mass or more is particularly preferable.
(任意成分)
本実施形態の油脂含有食品は、上記油脂および油脂改質剤以外に、適宜、任意成分が含有されてもよい。このような他の任意成分は、トコフェロール、L−アスコルビン酸パルミチン酸エステル、茶抽出物等の酸化防止剤、カロチン等の着色料、脱脂粉乳、クリーム等の乳成分、カゼイン、カゼインナトリウム、ホエーなどの乳蛋白、蔗糖、液糖、はちみつ、ブドウ糖、果糖、黒糖、麦芽糖、乳糖、水飴、ソルビトール、エリスリトール、異性化液糖、ショ糖結合飴、オリゴ糖、トレハロース、ヘミセルロース等の糖類、水、食塩、酸味料、調味料、香料、重合リン酸塩等の乳化安定剤、ローカストビーンガム、カラギーナン、アルギン酸類、ペクチン、キサンタンガム、寒天、グルコマンナン、ゼラチン、化工澱粉、澱粉等の増粘安定剤、防腐剤が例示される。また、これらが適宜配合された本実施形態の油脂加工食品は、上記したホイップクリーム、マーガリン、スプレッド以外に、カレールー、チョコレート、ソフトクリーム、アイスクリーム、アイスミルク、ラクトアイス、パン、ケーキ、クッキー、ビスケット等であってもよい。
(Optional component)
In addition to the fats and oils and fat modifiers, the fat and oil-containing food of the present embodiment may contain arbitrary components as appropriate. Such other optional ingredients include tocopherol, L-ascorbic acid palmitate, antioxidants such as tea extract, colorants such as carotene, milk ingredients such as skim milk powder, cream, casein, casein sodium, whey, etc. Milk protein, sucrose, liquid sugar, honey, glucose, fructose, brown sugar, maltose, lactose, starch syrup, sorbitol, erythritol, isomerized liquid sugar, sucrose-binding sugar, oligosaccharides, trehalose, hemicellulose and other sugars, water, salt , Emulsion stabilizers such as acidulant, seasoning, fragrance, polymerized phosphate, locust bean gum, carrageenan, alginic acids, pectin, xanthan gum, agar, glucomannan, gelatin, modified starch, starch, and other thickening stabilizers, Preservatives are exemplified. In addition to the whipped cream, margarine, and spread described above, the processed oil / fat food according to the present embodiment, in which these are appropriately blended, includes curry roux, chocolate, soft cream, ice cream, ice milk, lact ice, bread, cake, cookies, biscuits. Etc.
以上、本実施形態の油脂含有食品は、上記した油脂改質剤を含む。そのため、得られる油脂含有食品は、保形性、口どけ性等がより優れる。 As mentioned above, the fat-and-oil containing foodstuff of this embodiment contains an above-described fat-and-oil modifier. Therefore, the oil-and-fat-containing foods obtained are more excellent in shape retention, mouth-feeling properties and the like.
<油脂加工食品の製造方法>
本実施形態の油脂加工食品の製造方法は特に限定されない。一例を挙げると、油脂加工食品は、たとえばホイップクリームである場合、油脂、油脂改質剤のほか、ホイップクリームの調製において通常使用される各種原材料を混合し、攪拌、乳化、泡立て等を行うことにより製造し得る。他の油脂加工食品の場合も同様に、常法により製造し得る。
<Manufacturing method of processed oil and fat food>
The manufacturing method of the oil-fat processed food of this embodiment is not specifically limited. For example, when the processed oil and fat food is a whipped cream, for example, in addition to the fat and oil modifier, various raw materials usually used in the preparation of whipped cream are mixed, stirred, emulsified, foamed, etc. Can be produced. Similarly, in the case of other processed oils and fats, it can be produced by a conventional method.
以下、実施例により本発明をより具体的に説明する。本発明は、これら実施例に何ら限定されない。 Hereinafter, the present invention will be described more specifically with reference to examples. The present invention is not limited to these examples.
使用した原料を以下に示す。
(ショ糖脂肪酸エステル1)
ショ糖19.3g、ラウリン酸メチル14.2g、パルミチン酸メチル61.7g、ステアリン酸メチル19.0gをDMSO100gに溶解し、90〜110℃、減圧下で10時間反応させた。溶媒を留去後、精製、乾燥を経て、ショ糖脂肪酸エステル1を得た。
(ショ糖脂肪酸エステル2〜7)
表1に記載の原料および割合とした以外は、ショ糖脂肪酸エステル1と同様の操作を行い、ショ糖脂肪酸エステル2〜7を得た。
得られたショ糖脂肪酸エステル1〜7における各脂肪酸の割合(モル比)は、以下の表2のとおりであった。
(ポリグリセリン脂肪酸エステル1)
重合度6のポリグリセリンと、混合脂肪酸(ラウリン酸/ステアリン酸/ベヘン酸=2/2/6(モル比))とのエステル化物(平均エステル化度:4.5)
(グリセリン脂肪酸モノエステル1)
エマルジーMS(理研ビタミン社製、蒸留モノグリセリド)
(グリセリン脂肪酸モノエステル2)
エマルジーMU(理研ビタミン社製、蒸留モノグリセリド)
The raw materials used are shown below.
(Sucrose fatty acid ester 1)
19.3 g of sucrose, 14.2 g of methyl laurate, 61.7 g of methyl palmitate and 19.0 g of methyl stearate were dissolved in 100 g of DMSO and reacted at 90 to 110 ° C. under reduced pressure for 10 hours. After the solvent was distilled off, sucrose fatty acid ester 1 was obtained through purification and drying.
(Sucrose fatty acid ester 2-7)
Except having set it as the raw material and ratio of Table 1, operation similar to sucrose fatty acid ester 1 was performed, and sucrose fatty acid ester 2-7 was obtained.
The ratio (molar ratio) of each fatty acid in the obtained sucrose fatty acid esters 1 to 7 was as shown in Table 2 below.
(Polyglycerin fatty acid ester 1)
Esterified product (average degree of esterification: 4.5) of polyglycerin having a polymerization degree of 6 and a mixed fatty acid (lauric acid / stearic acid / behenic acid = 2/2/6 (molar ratio))
(Glycerin fatty acid monoester 1)
Emergy MS (Riken Vitamin Co., distilled monoglyceride)
(Glycerin fatty acid monoester 2)
Emulgie MU (manufactured by Riken Vitamin Co., distilled monoglyceride)
(実施例1〜7)
表3に示されるショ糖脂肪酸エステルを油脂改質剤として用い、下記(1)〜(3)の評価を行った。結果を表3に示す。
(Examples 1-7)
Using the sucrose fatty acid ester shown in Table 3 as an oil and fat modifier, the following (1) to (3) were evaluated. The results are shown in Table 3.
(比較例1)
油脂改質剤としてポリグリセリン脂肪酸エステル1を用いた以外は、実施例1と同様の方法により評価を行った。結果を表3に示す。
(Comparative Example 1)
Evaluation was performed in the same manner as in Example 1 except that the polyglycerin fatty acid ester 1 was used as the oil and fat modifier. The results are shown in Table 3.
<評価方法>
(1)油脂の形状保持性
パームオレイン20質量部、油脂改質剤0.2質量部を、80℃に加熱し、混合した。これを、ガラス製容器(直径3cm×高さ7cm)に投入し、10℃で24時間、25℃で24時間、10℃で24時間、25℃で24時間静置した。続いて、ガラス製容器を25℃環境下で横に倒した状態で固定し、3分後、10分後および30分後に、油脂の流動性の有無を目視で観察した。
(評価基準)
1:30分後に流動性が見られなかった。
2:30分後に流動性が見られた。
3:10分後に流動性が見られた。
4:3分後に流動性が見られた。
<Evaluation method>
(1) Shape retention of fats and oils 20 parts by weight of palm olein and 0.2 parts by weight of fat and oil modifier were heated to 80 ° C and mixed. This was put into a glass container (diameter 3 cm × height 7 cm) and allowed to stand at 10 ° C. for 24 hours, 25 ° C. for 24 hours, 10 ° C. for 24 hours, and 25 ° C. for 24 hours. Subsequently, the glass container was fixed in a state where it was laid down horizontally at 25 ° C., and after 3 minutes, 10 minutes and 30 minutes, the presence or absence of fluidity of the oil and fat was visually observed.
(Evaluation criteria)
No fluidity was seen after 1:30 minutes.
2:30 Fluidity was observed after 30 minutes.
3: Fluidity was seen after 10 minutes.
4: Flowability was observed after 3 minutes.
(2)油脂の口どけ性
パームオレイン20質量部、油脂改質剤0.2質量部を、80℃に加熱し、混合した後、10℃で24時間、25℃で24時間、10℃で24時間静置した。得られた油脂の口どけ性を、パネラー10人による官能試験により評価し、その平均値を評価結果とした。
(評価基準)
1:良好であった。
2:やや良好であった。
3:特に良好ではないが、許容範囲内であった。
4:やや悪かった。
5:悪かった。
(2) Oil-and-mouth irritability 20 parts by mass of palm olein and 0.2 parts by mass of an oil-and-fat modifier are heated to 80 ° C. and mixed, and then mixed at 10 ° C. for 24 hours, 25 ° C. for 24 hours, and 10 ° C. It was allowed to stand for 24 hours. The oleaginability of the obtained fats and oils was evaluated by a sensory test by 10 panelists, and the average value was taken as the evaluation result.
(Evaluation criteria)
1: Good.
2: Slightly good.
3: Not particularly good, but within an acceptable range.
4: It was a little bad.
5: It was bad.
(3)油脂固化物の強度
パームオレイン20質量部、油脂改質剤0.2質量部を、80℃に加熱し、混合した。これを、縦4cm×横4cm×高さ3cmの容器に入れ、10℃に冷却して固化させた。これを、20℃で7日間静置した後、表面の中央に70gの錘(底面積1cm2)を乗せ、油脂固形物の崩壊有無を確認した。
(評価基準)
○:崩壊が見られなかった。
×:崩壊が見られた。
(3) Strength of oil and fat solidified product 20 parts by mass of palm olein and 0.2 parts by mass of the oil and fat modifier were heated to 80 ° C. and mixed. This was placed in a container 4 cm long × 4 cm wide × 3 cm high and cooled to 10 ° C. to solidify. This was allowed to stand at 20 ° C. for 7 days, and then a 70 g weight (bottom area 1 cm 2 ) was placed on the center of the surface to confirm the presence or absence of the collapse of the oil solid.
(Evaluation criteria)
○: No collapse was observed.
X: Collapse was observed.
表3に示されるように、本発明の油脂改質剤は、いずれも保形性(形状保持性)が良好であり、かつ、口どけ性も良好であり、充分な強度を示した。 As shown in Table 3, each of the oil and fat modifiers of the present invention had good shape retention (shape retention) and good mouth-feeling properties, and showed sufficient strength.
(実施例8〜17、比較例2〜3)
表4に示される処方(単位:質量部)にしたがい、油脂改質剤を作製した。得られた油脂改質剤を用いて、下記(4)および(5)の評価を行った。結果を表4に示す。
(Examples 8 to 17, Comparative Examples 2 to 3)
According to the formulation (unit: part by mass) shown in Table 4, an oil and fat modifier was prepared. The following (4) and (5) were evaluated using the obtained oil and fat modifier. The results are shown in Table 4.
(4)ホイップクリームの形状保持性
表4に記載の油脂改質剤およびパームオレイン40質量部を80℃で混合した。ここに、水54質量部、ショ糖ステアリン酸エステル(商品名:DKエステルF−110、第一工業製薬社製)0.2質量部および脱脂粉乳(南日本酪農協同社製)6質量部、ヘキサメタリン酸Na0.1質量部(商品名:EXTRA PURE REAGENT、ナカライテスク社製)の混合溶液を加え、攪拌機(商品名:TKロボミックス(プライミクス社製))を用いて、80℃、回転数10000rpmにて5分間攪拌した。続いて、ホモジナイザー(商品名:NPH−30−600、日本精機製作所社製)を用いて、1次圧10MPa、2次圧2MPaの条件で、80℃で処理した。これを、10℃まで冷却し、10℃で12時間エージングすることにより、水中油型乳化物を得た。得られた水中油型乳化物を、ケンミックス(商品名:アイコープレミアKMM770、愛工舎製作所社製)を用いて10℃でホイップすることにより、ホイップクリームを得た。なお、ホイップは、30秒毎にホイップの比重を測定して、比重の低下が見られなくなるまで行った。得られたホイップクリームを、出口が星型の口金(切り込み数:10個)を用いて、高さ2cm程度、直径2cm程度に渦を巻きながら三角錐状に約0.8g絞り、10℃で12時間静置し、下記の基準で評価した。
(評価基準)
1:ホイップクリームは、12時間後でもほとんど変形が見られなかった。
2:ホイップクリームは、12時間後に変形が見られた。
3:ホイップクリームは、12時間後に大きく変形していた。
4:ホイップクリームは、12時間後に液状化していた。
(4) Shape retention property of whipped cream The fats and oil modifiers shown in Table 4 and 40 parts by mass of palm olein were mixed at 80 ° C. Here, 54 parts by mass of water, 0.2 part by mass of sucrose stearate (trade name: DK Ester F-110, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.) and 6 parts by mass of skim milk powder (manufactured by South Nippon Dairy Co., Ltd.) Add a mixed solution of 0.1 parts by mass of hexametaphosphate Na (trade name: EXTRA PURE REAGENT, manufactured by Nacalai Tesque) and use a stirrer (trade name: TK Robotics (manufactured by Primics)) at 80 ° C. and 10,000 rpm. For 5 minutes. Then, it processed at 80 degreeC on the conditions of primary pressure 10MPa and secondary pressure 2MPa using the homogenizer (brand name: NPH-30-600, Nippon Seiki Seisakusho make). This was cooled to 10 ° C. and aged at 10 ° C. for 12 hours to obtain an oil-in-water emulsion. The obtained oil-in-water emulsion was whipped at 10 ° C. using Kenmix (trade name: Aiko Premier KMM770, manufactured by Aikosha Seisakusho Co., Ltd.) to obtain a whipped cream. In addition, the whip was performed until the specific gravity of the whip was no longer observed by measuring the specific gravity of the whip every 30 seconds. The obtained whipped cream was squeezed about 0.8 g into a triangular pyramid while swirling about 2 cm in height and about 2 cm in diameter using a star-shaped mouthpiece (number of cuts: 10) at 10 ° C. It left still for 12 hours and evaluated on the following reference | standard.
(Evaluation criteria)
1: The whipped cream showed almost no deformation even after 12 hours.
2: Deformation of the whipped cream was observed after 12 hours.
3: The whipped cream was greatly deformed after 12 hours.
4: The whipped cream was liquefied after 12 hours.
(5)ホイップクリームの口どけ性
上記(4)で得られたホイップクリームの口どけ性を、パネラー10人による官能試験により評価し、その平均値を評価結果とした。
(評価基準)
1:良好であった。
2:やや良好であった。
3:特に良好ではないが、許容範囲内であった。
4:やや悪かった。
5:悪かった。
(5) Mouthability of whipped cream The mouthfeel of the whipped cream obtained in (4) above was evaluated by a sensory test by 10 panelists, and the average value was taken as the evaluation result.
(Evaluation criteria)
1: Good.
2: Slightly good.
3: Not particularly good, but within an acceptable range.
4: It was a little bad.
5: It was bad.
表4に示されるように、本発明の油脂含有食品は、保形性(形状保持性)が良好であり、かつ、口どけ性も良好であった。 As shown in Table 4, the oil and fat-containing food of the present invention had good shape retention (shape retention) and good mouthfeel.
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