JP2018143595A - Deodorant antimicrobial waterproof sheet, bedding sheet and head pad using the deodorant antimicrobial waterproof sheet - Google Patents

Abstract

An object of the present invention is to prevent soiling of mattresses and bed cushions due to excretion of bedclothes and the like, as well as deodorizing sweat odors and odors due to excretion of bedclothes, etc. Can suppress the spread of odors, and can also suppress the growth of bacteria. More specifically, it suppresses the activity of Staphylococcus aureus and influenza A virus, and deodorizes excreted odors such as ammonia and methyl mercaptan. It is another object of the present invention to provide a deodorant and antibacterial waterproof sheet that can be used, and a bedding sheet and a bed pad using at least a part of the deodorant and antibacterial waterproof sheet. The deodorizing and antibacterial waterproof sheet of the present invention is a sheet formed by laminating a fiber fabric on at least one surface of a waterproof layer, wherein the waterproof layer and / or the fiber fabric comprises a metal salt and a silicate. A deodorizing antibacterial agent containing a composite, a porous substance, and an amine compound is fixed. [Selection] Figure 1

Description

  The present invention relates to a deodorant antibacterial waterproof sheet, and more specifically, is suitably used for a sheet for bedding laid on a mattress, a bed cushion, etc., or a part of a bed pad placed under a sheet or under a sheet. The present invention relates to a deodorant antibacterial waterproof sheet.

  Conventionally, not only the sheets but also mattresses and bed cushions may be soiled with sweat and bedclothes, and the labor for exchanging them, washing, drying or drying in the sun has been heavy. In recent years, with the progress of aging, not only the demand for deodorization in the field of nursing and nursing care or hospitals, but also antibacterial performance is required as one of infection prevention, especially in nursing facilities and hospitals. There is a growing need for deodorant antibacterial performance when used in Japan.

  Patent Document 1 discloses a deodorant waterproof sheet in which a specific oxide and / or composite oxide is fixed in a waterproof sheet in which a water absorbing layer, a water retaining layer, and a water impermeable layer are sequentially arranged. However, since the invention of Patent Document 1 has a specific oxide and / or composite oxide fixed thereto, it has an effect on ammonia deodorization property and hydrogen sulfide deodorization property, but the bacteria to be retained are propagated. There was room for improvement in that it was in an easy state and further suppressed the generation of odor due to the propagation of bacteria.

  Patent Document 2 discloses a bedding pad in which a waterproof sheet for preventing water wetting, a moisture absorbing member, and a non-woven fabric are sequentially arranged on the upper part, and that the moisture absorbing member is preferably mixed with activated carbon. Yes. However, the idea of Patent Document 2 can reduce the labor of drying the mattress to dry wet rice and the like, and can be used in a disposable state because the waterproof sheet is inexpensive. Limited to physical adsorption capacity.

  Patent Document 3 discloses a deodorizing and antibacterial fiber fabric in which cellulose fibers and basic dye-type fibers are mixed, which contains polyamine, specific metal particles, and a hydrophilic agent, and a decrease rate of ammonia, etc. after 50 washings The invention of a deodorant antibacterial fiber fabric having a bacteriostatic activity value of S. aureus of a specific value or more is disclosed, and is excellent in deodorizing performance, antibacterial performance, water absorption / diffusion performance with respect to aging odor, and feeling of wear Deodorant antibacterial fibers that are excellent in However, the invention of Patent Document 3 is not limited to a fiber fabric in which cellulose fibers and basic dye-type fibers are mixed, and is suitable as an inner or sports apparel, but has a deodorizing performance against odors such as excretion odors. It was hard to say that it was enough.

JP 2000-301638 A Published Utility Model No. 61-55883 JP 2014-201859 A

  The present invention has been made in view of such technical background, and can prevent the futon and bed cushions from being polluted by excretion of bedclothes and the like, and can also eliminate the smell of sweat and the excretion of bedclothes and the like. In addition to being able to suppress the emission of unpleasant odors to the surroundings such as indoors, it is also possible to suppress the growth of bacteria, more specifically, suppress the activity of Staphylococcus aureus and influenza A virus, ammonia An object of the present invention is to provide a deodorant antibacterial waterproof sheet capable of deodorizing excretion odors such as methyl mercaptan, and a bedding sheet and a bed pad using at least a part of the deodorant antibacterial waterproof sheet. .

  In order to achieve the above object, the present invention provides the following means.

  [1] A sheet formed by laminating a fiber fabric on at least one surface of a waterproof layer, and a composite of a metal salt and a silicate on the waterproof layer and / or the fiber fabric, a porous material, and an amine compound A deodorizing and antibacterial waterproof sheet, characterized in that a deodorizing antibacterial agent containing

  [2] The deodorizing antibacterial waterproof sheet according to item 1, wherein the metal salt contains at least one selected from copper and zinc, manganese, cobalt, or nickel, or a metal salt of copper.

  [3] The deodorant antibacterial waterproof sheet according to the above item 1 or 2, wherein the deodorization removal rate with respect to the mixed odor composed of five kinds of bad odors is 70% or more.

  [4] The deodorant antibacterial waterproof sheet according to any one of items 1 to 3, wherein the antibacterial performance based on JIS L1902-2015 is 2.0 or more.

  [5] The deodorizing and antibacterial waterproof sheet according to any one of items 1 to 4, wherein the fiber fabric is a fabric having raised hair.

  [6] A sheet for bedding using at least a part of the deodorant antibacterial waterproof sheet according to any one of items 1 to 5 above.

  [7] A bed pad using at least a part of the deodorant antibacterial waterproof sheet according to any one of items 1 to 5 above.

  In the invention of [1], a composite of a metal salt and a silicate on a waterproof layer and / or a fiber fabric formed by laminating a fiber fabric on at least one surface of the waterproof layer, a porous material, and an amine compound As the deodorizing antibacterial agent containing sucrose is fixed, not only can the mattress and bed cushions be soiled due to the excretion of bedclothes, but also the smell of sweat and the odor due to excretion of the bedclothes can be deodorized. It is possible to suppress the emission of unpleasant odors to the surroundings such as indoors, and to suppress the growth of bacteria.

  In the invention of [2], the metal salt contains at least one selected from copper and zinc, manganese, cobalt, or nickel, or a metal salt of copper. Breeding can be suppressed. That is, excretion odors such as ammonia and methyl mercaptan can be eliminated, and the activity of Staphylococcus aureus and influenza A virus can be suppressed.

  In the invention of [3], since the deodorization removal rate with respect to the mixed odor composed of five kinds of bad odors is 70% or more, for example, against the unpleasant odor adhering due to odors and diaper changes due to long-term use, etc. Excellent deodorant performance can be exhibited.

  In the invention of [4], since the antibacterial performance of the deodorant antibacterial waterproof sheet conforming to JIS L1902-2015 is 2.0 or more, it exhibits excellent antibacterial performance against Staphylococcus aureus and influenza A virus. Can do.

  In the invention of [5], since the fiber fabric is a fabric having raised hair, since the thickness including the air layer is increased, a deodorant antibacterial waterproof sheet excellent in texture, cushioning properties and heat retaining properties can be obtained.

  In the invention of [6], the sheet for bedding using at least a part of the deodorizing antibacterial waterproof sheet according to any one of the preceding items 1 to 5 stains a mattress or a bed cushion due to excretion of rice cakes and the like. In addition to being able to prevent the smell of sweat and the smell of excretion such as rice bran, it can also suppress the emission of unpleasant odors to the surroundings such as indoors, and can also suppress the growth of bacteria.

  In the invention of [7], the bed pad using at least a part of the deodorizing antibacterial waterproof sheet according to any one of items 1 to 5 prevents soiling of a mattress or a bed cushion due to excretion of rice cakes and the like. In addition, it can not only eliminate the smell of sweat and odors from excretion such as rice bran, but it can also suppress the emission of unpleasant odors to the surroundings such as indoors, and can also suppress the growth of bacteria.

It is a schematic sectional drawing which shows an example of the deodorant antibacterial waterproof sheet of this invention. It is a schematic sectional drawing which shows the other example of the deodorant antibacterial waterproof sheet of this invention. It is a schematic sectional drawing which shows an example of the sheet | seat for bedding of this invention. It is explanatory drawing of the usage example of the sheet | seat for bedding of FIG. It is a schematic sectional drawing which shows an example of the bed pad of this invention.

  One embodiment of the deodorant antibacterial waterproof sheet according to the present invention is shown in FIG. The deodorant antibacterial waterproof sheet 1 is a sheet formed by laminating a fiber fabric 2 on at least one surface of a waterproof layer 3, and is a composite of a metal salt and a silicate on the waterproof layer 3 and / or the fiber fabric 2. And a deodorizing antibacterial agent containing a porous substance and an amine compound is fixed. FIG. 2 shows another embodiment of the deodorant antibacterial waterproof sheet in which the fabric 2 is laminated on both surfaces of the waterproof layer 3.

  According to the present invention, it is possible to prevent the futon and bed cushions from being polluted by excretion of bedclothes and the like, and not only to remove the smell of sweat and odor from excretion of bedclothes, but also to discomfort the surroundings such as indoors. Odor can be suppressed and bacteria can be prevented from breeding. Therefore, for example, by using the deodorant antibacterial waterproof sheet 1 as a part of the bedding sheet 4 or the bed pad 6, it is possible to suppress the dissipation of the unpleasant odor adhering not only at home but also at a care site or a hospital. In addition, the propagation of bacteria and viruses can be suppressed (see FIGS. 3, 4, and 5). More specifically, a textile fabric suitable for hygiene products that directly touches the skin, which can deodorize excretion odors such as ammonia and methyl mercaptan and suppress the activity of Staphylococcus aureus and influenza A virus. it can. Furthermore, it is preferable that the deodorization removal rate with respect to the mixed odor which consists of five types of bad odors is 70% or more, and the excellent deodorizing performance adhered by odors and diaper changes after long-term use is exhibited. The mixed odor is a bad odor composed of five kinds of bad odors such as ammonia, hydrogen sulfide, methyl mercaptan, acetic acid and indole.

  The waterproof layer 3 of the present invention is not particularly limited as long as it has waterproof properties, and examples thereof include rubber sheets, polyvinyl chloride-based, polyethylene-based, polyester-based, polyurethane-based resin sheets, and resin films. Can do. Further, the waterproof layer 3 is laminated on the fiber fabric 2 with no particular limitation. For example, the waterproof layer 3 is laminated via various adhesives, laminated via various hot melt resins, and a thermoplastic resin is extruded into a film shape with a T-die. Lamination by lamination and the material of the waterproof layer 3 are limited, but lamination may be performed by a known method such as lamination by fusing with a high frequency welder.

  Although it does not specifically limit as fiber used for the fiber fabric 2 of this invention, Natural fibers, such as cotton, wool, silk, hemp, Cellulosic fibers, such as rayon fiber, Polyester fiber, Polyamide fiber, Polypropylene fiber, Acrylic fiber Those made of synthetic fibers such as can be used.

  The form of the fiber fabric 2 of the present invention is not particularly limited, and may be any of a knitted fabric, a woven fabric, a non-woven fabric, and the like, and the thickness, configuration, ratio thereof, woven structure, knitted structure, and the like may be appropriately designed. . It does not specifically limit as a nonwoven fabric, For example, a spun bond nonwoven fabric, a chemical bond nonwoven fabric, a thermal bond nonwoven fabric, a needle punch nonwoven fabric, and a water needle nonwoven fabric can be mentioned.

  The deodorizing antibacterial agent of the present invention is a deodorizing antibacterial agent liquid containing a complex of a metal salt and a silicate, a porous substance, and an amine compound. Furthermore, it is preferable to add a binder resin in order to enhance the adhesion to the fiber fabric 2 and the waterproof layer 3.

  The metal salt of the complex of the metal salt and silicate preferably includes at least one selected from copper and zinc, manganese, cobalt, or nickel, or a metal salt of copper, Examples thereof include sodium silicate and potassium silicate.

  The porous material has a large surface area and excellent odor adsorption ability. For example, examples of such a porous material include inorganic porous materials such as silicon oxide, zeolite, porous silica, activated carbon, Examples include silica gel, barley stone, and diatomaceous earth. Among these, it is preferable to use zeolite or silicon oxide having an excellent adsorption ability for ammonia gas, indole and the like.

  Zeolite has a skeletal structure in which silicon and aluminum are three-dimensionally bonded through oxygen. In this skeleton, molecular-level holes (pores) are opened, and various molecules such as water and organic molecules are taken into the skeleton, so that it is very useful as an adsorbent. There are various types of zeolite. Among them, the artificial zeolite MFI type zeolite is very effective as an adsorbent because the two kinds of pores derived from the crystal structure are three-dimensionally connected. . If MFI-type zeolite is used as an adsorbent, it exhibits excellent adsorbability for basic gases such as ammonia and indole.

  Examples of the amine compound include a hydrazine derivative or an inorganic silicon compound carrying a polyamine compound. Examples of the hydrazine derivative include those obtained by reacting a hydrazine compound and a long-chain aliphatic compound, or those obtained by reacting a hydrazine compound and an aromatic compound. Among these, one or two compounds selected from the group consisting of hydrazine and semicarbazide, and a group selected from the group consisting of C8-16 monocarboxylic acids, dicarboxylic acids, aromatic monocarboxylic acids, and aromatic dicarboxylic acids. Selected from the group consisting of one or two compounds selected from the group consisting of hydrazine and semicarbazide and monoglycidyl derivatives and diglycidyl derivatives having 8 to 16 carbon atoms. Reaction products with one or more compounds are preferred.

  By using such a hydrazine derivative, it is possible to cause a chemical reaction with aldehydes, exhibit an excellent adsorption action, and ensure a malodor removal performance. Specific examples of the reaction product include sebacic acid dihydrazide, dodecanoic acid dihydrazide, isophthalic acid dihydrazide, and the like. The solubility of such a hydrazine derivative in water is desirably 5 g / L or less at 25 ° C. If the solubility in water is within this range, the hydrazine derivative is prevented from dissolving and flowing out even if it comes into contact with water by washing or the like.

  The inorganic silicon compound carrying the polyamine compound is not particularly limited, and examples thereof include porous silicon dioxide carrying the polyamine compound, aluminum silicate carrying the polyamine compound, and the like.

  Although it does not specifically limit as said polyamine compound, For example, an aliphatic polyamine, an aromatic polyamine, an alicyclic polyamine etc. are mentioned. Specific examples include diethylenetriamine and tetraethylenepentamine.

  The polyamine compound is particularly effective for deodorization of aldehyde gas, and the inorganic silicon compound is effective for deodorization of basic gas, and further includes inorganic porous materials, metal salts, metal oxides, metal hydroxides. Various odors can be effectively deodorized by selecting and combining them.

  The deodorant antibacterial agent of the present invention preferably further contains a surfactant. Examples of the surfactant include an anionic surfactant and a nonionic surfactant. As the anionic surfactant, at least one selected from hydroxyethylidenephosphonate, alkylsulfosuccinate, alkylsulfonate, or monoalkylphosphate is preferable. The nonionic surfactant is preferably at least one selected from polyoxyalkylene alkyl ether, polyoxyalkylene alkylphenyl ether, and polyoxyaryl ether. Generation | occurrence | production of the sticking spot with the fiber fabric 2 or the waterproof layer 3 can be suppressed by making a deodorizing antibacterial agent contain surfactant.

The deodorizing antibacterial agent adheres to the fiber fabric 2 or the waterproof layer 3 together with the binder resin. The fixing amount is preferably 0.1 g / m ² to 5 g / m ² (dry weight) with respect to the deodorant antibacterial waterproof sheet. Less than 0.1 g / m ² is not preferable because sufficient deodorant antibacterial performance cannot be obtained. Moreover, even if it exceeds 5 g / m < ² >, the improvement of a big deodorizing antibacterial performance is scarce, conversely, water absorption is reduced and cost increases, which is not preferable. More preferably from ^{0.5g / m 2 ~3g / m 2} ( dry weight).

  Any resin can be used as the binder resin. For example, self-crosslinking acrylic resin, methacrylic resin, urethane resin, silicone resin, glyoxal resin, vinyl acetate resin, vinylidene chloride resin, butadiene resin, melamine resin, epoxy resin, acrylic-silicone copolymer resin, ethylene- Examples thereof include vinyl acetate copolymer resin, isobutylene maleic anhydride copolymer resin, and ethylene-styrene-acrylate-methacrylate copolymer resin. Two or more of these resins may be mixed to form a binder resin.

  Deodorant antibacterial agent is a treatment liquid consisting of a water dispersion dispersed in water together with a binder resin, that is, a complex of metal salt and silicate, a porous substance, an amine compound, and a surfactant. After adding water and stirring, a binder resin and water are added and further stirred to prepare a treatment liquid comprising an aqueous dispersion. At this time, it is preferable to disperse the deodorizing antibacterial agent and the binder resin as much as possible, and the binder resin more preferably forms an emulsion state with water. Thus, it is preferable to disperse the deodorant antibacterial agent in water before dispersing the binder resin, because the deodorant antibacterial agent and the binder resin can be more uniformly dispersed.

  Moreover, you may mix | blend a various additive, such as a dispersing agent and a thickener, with the processing liquid of the said deodorizing antibacterial agent for various characteristics improvement. The fiber cloth 2 or the waterproof layer 3 may be brought into contact with the treatment liquid thus obtained, and may be one side, both sides, or all of the fiber fabric 2 or the waterproof layer 3. Although it does not specifically limit as a method, For example, a dipping method, a spray method, a coating method etc. are mentioned.

  Although it is made to dry after making it contact the process liquid of the said deodorizing antibacterial agent, the method of heat-processing as a drying means is preferable from drying efficiency and a binder resin being cured. The heat treatment temperature is preferably 100 to 180 ° C. By heat treatment at this temperature, the sticking property of the deodorant antibacterial agent can be further improved, and the sustained durability of the deodorant antibacterial performance and antiviral performance can be further improved.

  Next, specific examples of the present invention will be described, but the present invention is not particularly limited to these examples.

<Example 1>
After adding 8 parts by mass of copper silicate, 5 parts by mass of silicon oxide, 2 parts by mass of hydrazide compound, 0.5 parts by mass of polyoxyalkylene alkyl ether and 84.5 parts by mass of water, the mixture was stirred with a stirrer, and water was added. A dispersion was obtained. To this dispersion, 20 parts by mass of an acrylic binder resin (solid content 60%) was added and stirred well to obtain a uniform treatment liquid. Next, a raised knit (weight per unit area: 80 g / m ² ) made of polyester fiber was prepared, dipped in the treatment liquid, and then squeezed with a mangle. The pickup rate was 70%. Subsequently, it was dried at a temperature of 150 ° C. for 5 minutes. The obtained raised knit made of polyester fiber to which the deodorant antibacterial agent was fixed was laminated on one side of a polyethylene film via a hot melt adhesive (EVA (ethylene vinyl acetate copolymer) system). Thus, a deodorant antibacterial waterproof sheet was obtained. In addition, the adhesion amount of the deodorizing antibacterial agent is copper silicate 0.8 g / m ² , silicon oxide 0.5 g / m ² , hydrazide compound 0.2 g / m ² , polyoxyalkylene alkyl ether 0.05 g / m. ² and the acrylic binder resin was 1.2 g / m ² .

<Examples 2-7, Comparative Examples 1-6>
Table 1 shows the composition of the treatment liquids of each deodorant antibacterial agent in Examples and Comparative Examples, and Table 2 shows the fixing amount (dry weight) of each deodorant antibacterial agent component on the deodorant antibacterial waterproof sheet. Table 3 shows the removal rate of each offensive odor as the deodorizing performance, the antibacterial activity value of Staphylococcus aureus and MRSA and the antiviral activity value as the evaluation of the antibacterial performance, and the respective evaluations. In addition, since the comparative example 2 does not correspond to JISL1902-2015 since the fiber fabric is not laminated | stacked only by a waterproof layer, evaluation by the same antibacterial performance test as another Example and a comparative example was not performed.

  As can be seen from Table 3, in Examples 1 to 7, excellent deodorization performance was exhibited for each gas of mixed odor and single odor methyl mercaptan, ammonia, hydrogen sulfide, acetic acid, and indole. Furthermore, excellent results were also shown for antibacterial and antiviral tests. Thus, it showed excellent performance in any of deodorizing performance, antibacterial performance and antiviral performance. In Comparative Example 1, since the waterproof layer was not laminated, it was difficult to say that it was waterproof, and it was not possible to prevent dirt such as mattresses and bed cushions.

  On the other hand, in Comparative Examples 2 to 6, although the results showing the deodorizing performance against some offensive odors and the results showing the antibacterial performance were obtained, sufficient performance in all of the deodorizing, antibacterial and antiviral properties It was not something that demonstrated.

<Deodorization test of mixed odor>
In addition, the measurement of the deodorizing property of the mixed odor in the said Example and comparative example was performed based on ISO17299-5 (metal oxide semiconductor sensor method). As mixed odor, excretion odor is selected, methyl mercaptan, ammonia, hydrogen sulfide, acetic acid, and indole are selected, and the removal rate is evaluated as “◯” when 70% or more, and “×” when less than 70%. “Yes” was accepted.

<Deodorization test of single odor>
In addition, the measurement of the deodorant property of a single odor is performed in accordance with the SEK Mark Textile Product Certification Standard (JEC301 revised on April 1, 2015, General Textile Evaluation Technology Council) and measured as the above mixed odor. Each odor was measured with a single odor.

(Methyl mercaptan deodorization performance)
After putting a test sample (10 cm × 10 cm) into a 5 L bag, 3 L of methyl mercaptan gas is injected so that the concentration in the bag is 8 ppm, and after 2 hours, the remaining concentration of methyl mercaptan gas is measured. A blank was prepared in the same manner except that no test sample was added, the residual concentration of methyl mercaptan gas in this blank was measured, and the amount of methyl mercaptan gas removed from both measured values was calculated. From this, methyl mercaptan gas was calculated. The removal rate (%) was calculated.

(Ammonia deodorization performance)
The ammonia removal rate (%) was calculated in the same manner as in the measurement of the methyl mercaptan deodorizing performance, except that ammonia gas was used instead of methyl mercaptan and the concentration was 100 ppm in the bag.

(Hydrogen sulfide deodorization performance)
The removal rate (%) of hydrogen sulfide was calculated in the same manner as in the measurement of the deodorizing performance of methyl mercaptan, except that hydrogen sulfide gas was used instead of methyl mercaptan and the concentration was 4 ppm in the bag.

(Acetic acid deodorization performance)
The acetic acid removal rate (%) was calculated in the same manner as in the above methyl mercaptan deodorization performance measurement except that acetic acid gas was used instead of methyl mercaptan and the concentration was 30 ppm in the bag.

(Indole deodorization performance)
After putting a test sample (5 cm × 10 cm) into a 500 ml Erlenmeyer flask, inject 5 μl of indole solution and measure by gas chromatography after 2 hours. This blank was measured in the same manner, and the indole removal rate (%) was calculated from the measured values of both.

  Evaluation of the deodorization performance of a single odor is “◎” when the removal rate of the single odor is 85% or more, “◯” when the removal rate is 70% or more and less than 85%, and the removal rate is 70%. What was less than "x" was set as "x", and "○" or more was set as the pass.

<Antimicrobial test>
The antibacterial measurement was performed in accordance with JIS L1902: 2015, the bacterial solution absorption method. An antibacterial activity value of 2.0 or more is acceptable.

<Antiviral test>
Viral measurement was performed according to ISO18184. An antiviral activity value of 3.0 or higher is acceptable.

  In addition to preventing soiling of mattresses and bed cushions, it is possible to eliminate the smell of sweat and urine from excretion, etc. It is possible to provide a deodorant antibacterial waterproof sheet capable of suppressing breeding, and a bedding sheet and a bed pad using at least a part of the deodorant antibacterial waterproof sheet.

DESCRIPTION OF SYMBOLS 1 ... Deodorant antibacterial waterproof sheet 2 ... Textile fabric 3 ... Waterproof layer 4 ... Sheet for bedding 5 ... Futon 6 ... Bed pad

Claims (7)

A sheet formed by laminating a fiber fabric on at least one surface of the waterproof layer,
A composite of a metal salt and a silicate on the waterproof layer and / or the fiber fabric;
A porous material;
A deodorant antibacterial waterproof sheet characterized by having a deodorant antibacterial agent containing an amine compound adhered thereto.   The deodorant antibacterial waterproof sheet according to claim 1, wherein the metal salt includes at least one selected from copper and zinc, manganese, cobalt, or nickel, or a metal salt of copper.   The deodorant antibacterial waterproof sheet according to claim 1 or 2, wherein a deodorization removal rate with respect to a mixed odor composed of five kinds of bad odors is 70% or more.   The deodorant antibacterial waterproof sheet according to any one of claims 1 to 3, wherein the antibacterial performance conforming to JIS L1902-2015 is 2.0 or more.   The deodorant antibacterial waterproof sheet according to any one of claims 1 to 4, wherein the fiber fabric is a fabric having raised hair.   A sheet for bedding using at least a part of the deodorant antibacterial waterproof sheet according to any one of claims 1 to 5.   A bed pad using at least a part of the deodorant antibacterial waterproof sheet according to any one of claims 1 to 5.