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JP2018095864A - Snow-removing agent in which microorganism useful to soil or crop is impregnated and which is environment-friendly and manufacturing method therefor - Google Patents

Snow-removing agent in which microorganism useful to soil or crop is impregnated and which is environment-friendly and manufacturing method therefor Download PDF

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JP2018095864A
JP2018095864A JP2017237189A JP2017237189A JP2018095864A JP 2018095864 A JP2018095864 A JP 2018095864A JP 2017237189 A JP2017237189 A JP 2017237189A JP 2017237189 A JP2017237189 A JP 2017237189A JP 2018095864 A JP2018095864 A JP 2018095864A
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パクソンウ
Seong Woo Park
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/18Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • C05F11/08Organic fertilisers containing added bacterial cultures, mycelia or the like
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12NMICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N1/00Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
    • C12N1/20Bacteria; Culture media therefor

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Abstract

PROBLEM TO BE SOLVED: To provide a snow-removing agent excellent in economical efficiency and environment-friendly because additional works for recovering or removing the snow-removing agent remained in seasons required no snow-removing agent with a temperature increased are not required, and a manufacturing method therefor.SOLUTION: There is provided a snow-removing agent containing wood chip to which metal ion salts and microorganism are impregnated, in which the microorganism is at least one of ay bacillus selected from Bacillus subtilis, Bacillus amyloliquefaciens, Bacillus stearothermophilus, Bacillus cereus, Bacillus megaterium and Bacillus licheniformis. There is provided a snow-removing agent, in which the metal ion salt is a salt selected from magnesium chloride, sodium metasilicate, sodium chloride and lithium ion salt. There is provided a snow-removing agent, in which the wood chip is a chip with a thin sheet shape of 1 to 20 mm and unevenness on a surface.SELECTED DRAWING: None

Description

本発明は、ウッドチップに微生物と金属イオン塩を含浸させてなる除雪剤及びその製造方法に係り、より詳しくは、当該除雪剤を路面に撒布して摩擦力を付与し且つ積雪された雪を融雪する効果を同時に得ることができるだけでなく、ウッドチップ中に含浸された微生物が周辺の植物や土壌に栄養物質として作用して土壌の質を改善し、植物の成長に役立てられる土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤及びその製造方法に関する。   The present invention relates to a snow removal agent obtained by impregnating a wood chip with microorganisms and a metal ion salt and, more particularly, to a method for producing the snow removal agent. Not only can the effect of melting snow be obtained at the same time, but the microorganisms impregnated in the wood chip can act as nutrients on the surrounding plants and soil to improve the quality of the soil, and can be used for soil and crops that are useful for plant growth. The present invention relates to an environment-friendly snow removal agent impregnated with beneficial microorganisms and a method for producing the same.

近年、全地球的な気象異変などで冬期の暴雪が我が国は勿論、全世界的に頻繁に発生しており、そのため、交通の安全や円滑な運行のために道路などに積もった雪を除雪すべく、冬期に除雪剤の撒布が多くなされている。
一般に、除雪剤は、直接雪を溶かす融雪(融氷)剤と、雪を溶かすことはできないが圧雪又は結氷路面で一時的に摩擦力を高めるための摩擦剤とに分けられる。
In recent years, snowstorms in winter have frequently occurred not only in Japan but also worldwide due to global weather changes, etc. Therefore, snow on roads etc. is removed for traffic safety and smooth operation. Therefore, many snow removal agents are distributed in winter.
Generally, a snow removal agent is classified into a snow melting (melting) agent that melts snow directly and a friction agent that cannot melt snow but temporarily increases the frictional force on a snow surface or a frozen road surface.

通常、摩擦剤としては砂又は練炭灰を使用しているが、撒布初期に一時的に摩擦力を増加させて滑りを防止する効果はあるが、粒子が氷層の深部に次第に沈降しながら次の降雪時には積雪中に埋まってしまい、大した効果を期待し難く、配水管や集水井の詰まり、微細な粒子による空気汚染、異物による車両の破損、雪が溶けてから残留する砂又は練炭灰によって掃除が要されるなどの多くの作業人力や費用が更に所要されることから経済性に劣り、そのため、上り坂区間、陰地、常時結氷地域、地熱のない橋梁区間などの摩擦力が要される地域に限って制限的に使用されている。   Usually, sand or briquette ash is used as the friction agent, but it has the effect of preventing friction by temporarily increasing the frictional force in the initial stage of spreading, but the particles gradually settle down in the deep part of the ice layer. It is buried in the snow when it snows, and it is difficult to expect a great effect due to clogging of distribution pipes and drainage wells, air pollution due to fine particles, vehicle damage due to foreign objects, sand or briquette ash remaining after the snow melts It is inferior in economic efficiency because it requires a lot of workmanship and costs such as cleaning, so it requires frictional forces such as uphill sections, shaded areas, constantly freezing areas, bridge sections without geothermal heat, etc. It is used only in limited areas.

一方、融雪剤は、塩化物系除雪剤と非塩化物系除雪剤とに大別され、非塩化物系除雪剤に比べて塩化物系除雪剤の方が除雪効果に優れ、主に塩化物系除雪剤を使用している実情である。   On the other hand, snow-melting agents are roughly classified into chloride-based snow removal agents and non-chloride-based snow removal agents, and chloride-based snow removal agents have a better snow-removing effect than non-chloride-based snow removal agents. It is the fact that we use snow removing agent.

しかし、既存の塩化物系除雪剤は、除雪作業のために道路の路面や橋梁への撒布の際、前記塩化物系除雪剤中に含まれる塩素イオン(Cl)と鉄(Fe)とが反応しながら塩化鉄(FeCl)を生成し、これが自動車、鉄筋、鉄骨などを腐食させるという問題が発生している。 However, the existing chloride-based snow remover contains chlorine ions (Cl ) and iron (Fe) contained in the chloride-based snow remover when it is distributed on road surfaces and bridges for snow removal work. There is a problem that iron chloride (FeCl 2 ) is generated while reacting, which corrodes automobiles, reinforcing bars, steel frames and the like.

特に、塩化物系除雪剤のうち多用される塩化カルシウムは、水に溶解し又は土壌に吸収されると水質の汚染や土壌の酸性化を誘発し、且つ道路周辺の草木、農作物などの植物を枯死させるなど植物の生長に支障をもたらして環境汚染を誘発する原因の一つとして知られている。   In particular, calcium chloride, which is frequently used among chloride-based snow removal agents, induces water pollution and soil acidification when dissolved in water or absorbed by soil, and also helps plants such as plants and crops around roads. It is known as one of the causes of environmental pollution by hindering the growth of plants such as withering.

また、撒布される除雪剤は、無作為に広い範囲に振り撤かれるため、実際除雪に要する量よりも多くの量が撒布され、一度使用された除雪剤は雪が溶けながら発生した水とともに配水管に流れ込むので、再び雪が降ったり結氷した場合は、再度撒布しなければならない実情である。したがって、除雪作業の際に除雪に要する量よりも多量の除雪剤が使用されており、過量で撒布された除雪剤による車両の腐食、道路の破損などの問題が発生している。   In addition, since the snow removal agent to be distributed is randomly swung away over a wide range, a larger amount than the amount actually required for snow removal is distributed, and once used, the snow removal agent is distributed along with the water generated while the snow melts. If it snows or freezes again, it will be necessary to redistribute it. Therefore, a larger amount of snow removal agent is used than the amount required for snow removal during snow removal work, causing problems such as vehicle corrosion and road damage due to an excessive amount of snow removal agent.

これにより、前述した問題を解決するために種々の環境にやさしい除雪剤についての研究・開発が進行されてきており、そこで、本願出願人は、韓国登録特許第1617935号(2016年04月27日登録公告)を通して、山での伐木後に残った木や木工所での切り端などの廃木材を原料として作ったウッドチップを利用して、木材の摩擦性や金属イオンの徐放効果を用いた長期間の使用が可能な除雪剤を提案したことがある。   Accordingly, in order to solve the above-described problems, research and development on various environmentally friendly snow removal agents have been progressing. Therefore, the applicant of the present application is the Korean Patent No. 1617935 (April 27, 2016). Through the registration notice), we used wood chips made from waste wood such as trees left after cutting in the mountains and cut ends at the woodworking plant, and used the frictional properties of wood and the sustained release effect of metal ions. I have proposed a snow remover that can be used for a long time.

しかし、前記従来技術では、気温が上がると残存するウッドチップによって道路又は路面が美観上汚なく見え、且つ残存するウッドチップを回収するという追加作業によって経済性に劣るという問題があった。   However, the conventional technique has a problem that when the temperature rises, the road or road surface looks aesthetically unclean due to the remaining wood chips, and the additional work of collecting the remaining wood chips is inferior in economic efficiency.

韓国登録特許第1617935号(2016年04月27日登録公告)Korean Registered Patent No. 1617935 (Registration Notice on April 27, 2016)

本発明は、環境にやさしい材料であるウッドチップに金属イオン塩と微生物を含浸させて除雪剤を製造することによって、積雪された路面又は道路への摩擦力をウッドチップで高め、且つ前記ウッドチップ中に含浸された金属イオン塩で雪を溶かすことで摩擦剤と融雪剤の効果を併せて得ることができ、一方、ウッドチップ中に含浸された微生物が外部に放出されて周辺の土壌や植物に栄養成分として作用するだけではなく、気温が上ってもはや除雪剤を必要としない時期において前記ウッドチップ中に含浸された微生物によってウッドチップが生分解することで、残存するウッドチップを回収するという追加作業を必要としない、土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤及びその製造方法を提供摺ることをその目的とする。   According to the present invention, a wood chip, which is an environmentally friendly material, is impregnated with a metal ion salt and a microorganism to produce a snow removal agent, thereby increasing the frictional force on the snow-covered road surface or road with the wood chip. By melting snow with the metal ion salt impregnated inside, the effect of friction agent and snow melting agent can be obtained together, while the microorganisms impregnated in the wood chip are released to the outside and the surrounding soil and plants In addition to acting as a nutrient component, the wood chips are biodegraded by the microorganisms impregnated in the wood chips at a time when the temperature is no longer necessary and a snow removal agent is no longer needed, thereby recovering the remaining wood chips The purpose of the present invention is to provide an environmentally friendly snow removing agent impregnated with beneficial microorganisms in soil and crops, and a method for producing the same, which does not require additional work. That.

上述したような目的を達成するために、本発明の一実施形態は、金属イオン塩と微生物が含浸されたウッドチップを含む、土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤に関する。   In order to achieve the object as described above, one embodiment of the present invention relates to an environmentally friendly snow removal agent impregnated with microorganisms beneficial to soil and crops, including wood chips impregnated with metal ion salts and microorganisms. .

具体的に、前記微生物は、枯草菌及び乳酸菌からなる群より選択された1種以上を含んでいてよく、前記金属イオン塩は、塩化マグネシウム(magmesium chloride)、メタけい酸ナトリウム(sodium metasilicate)、塩化カルシウム(calcium chlride)、塩化ナトリウム(sodium chloride)及びリチウムイオン塩からなる群より選択された少なくとも一つ以上を含んでいてよい。
前記ウッドチップは、1〜20mm厚さの薄板状の木片であって、表面に凹凸が形成されたものを使用していてよい。
Specifically, the microorganism may include one or more selected from the group consisting of Bacillus subtilis and lactic acid bacteria, and the metal ion salt includes magnesium chloride, sodium metasilicate, It may contain at least one selected from the group consisting of calcium chloride, sodium chloride and lithium ion salt.
The wood chip may be a thin wooden piece having a thickness of 1 to 20 mm and having irregularities formed on the surface.

一方、本発明の他の実施形態は、金属イオン塩が溶解されたイオン溶液にウッドチップを浸漬させる浸漬段階;前記浸漬段階を通じて金属イオン塩が含浸されたウッドチップを乾燥する第1乾燥段階;前記第1乾燥段階を通じて乾燥されたウッドチップに微生物培養液を噴射する噴射段階;及び前記噴射段階を通じて微生物が含浸されたウッドチップを乾燥する第2乾燥段階;を含む、土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤を製造する方法である。   Meanwhile, in another embodiment of the present invention, a dipping step of dipping a wood chip in an ionic solution in which a metal ion salt is dissolved; a first drying step of drying the wood chip impregnated with the metal ion salt through the dipping step; A spraying step of spraying a microorganism culture solution onto the wood chips dried through the first drying step; and a second drying step of drying the wood chips impregnated with the microorganisms through the spraying step; This is a method for producing an environmentally friendly snow removal agent impregnated with microorganisms.

前記ウッドチップは、木板の表面に凹凸を形成する表面処理段階;及び表面に凹凸が形成された木板を1〜20mm厚さの薄板状の木片に破砕する破砕段階;を含んで製造されていてよい。   The wood chip is manufactured including a surface treatment step of forming irregularities on the surface of a wooden board; and a crushing step of crushing the wooden board with irregularities formed on the surface into thin plate-like pieces of wood having a thickness of 1 to 20 mm. Good.

前記金属イオン塩が溶解されたイオン溶液は、水に、塩化マグネシウム(magmesium chloride)、メタけい酸ナトリウム(sodium metasilicate)、塩化カルシウム(calcium chlride)、塩化ナトリウム(sodium chloride)及びリチウムイオン塩からなる群より選択された少なくとも一つ以上の金属イオン塩を1:0.5〜2質量比で溶解させてなるものを使用していてよい。このとき、前記金属イオン塩は、塩化マグネシウム100重量部、前記塩化マグネシウム100重量部を基準に、メタけい酸ナトリウム1〜10重量部、リチウムイオン塩1〜10重量部が含まれたものを使用していてよい。
前記微生物培養液は、枯草菌及び乳酸菌からなる群より選択された1種以上の微生物を培地に接種し培養して製造されたものであってよい。
The ion solution in which the metal ion salt is dissolved includes magnesium chloride (magnesium chloride), sodium metasilicate, calcium chloride, sodium chloride, and a lithium ion salt. What melt | dissolved the at least 1 or more metal ion salt selected from the group by 1: 0.5-2 mass ratio may be used. At this time, the metal ion salt used includes 100 parts by weight of magnesium chloride and 1 to 10 parts by weight of sodium metasilicate and 1 to 10 parts by weight of lithium ion salt based on 100 parts by weight of magnesium chloride. You can do it.
The microorganism culture solution may be produced by inoculating a medium with one or more microorganisms selected from the group consisting of Bacillus subtilis and lactic acid bacteria.

好ましくは、前記第1乾燥段階は、前記金属イオン塩が含浸されたウッドチップを120〜140℃で1〜2時間乾燥していてよく、前記第2乾燥段階は、微生物が含浸されたウッドチップを10〜30℃で20〜30時間乾燥することが好ましい。   Preferably, in the first drying step, the wood chip impregnated with the metal ion salt may be dried at 120 to 140 ° C. for 1 to 2 hours, and in the second drying step, the wood chip impregnated with the microorganism is used. Is preferably dried at 10 to 30 ° C. for 20 to 30 hours.

本発明は、環境にやさしい材料であるウッドチップ中に金属イオン塩と微生物を含浸させて除雪剤を製造することによって、前記ウッドチップ中に含浸された微生物が外部に放出されることで除雪剤が撒布された周辺の土壌や植物に栄養分として作用して土壌の質を改善し、且つ植物の成長に役立てられる。   According to the present invention, a snow removal agent is produced by impregnating a metal ion salt and a microorganism into a wood chip, which is an environmentally friendly material, so that the microorganism impregnated in the wood chip is released to the outside. It acts as a nutrient on the surrounding soil and plants that are spread and improves the quality of the soil and is useful for plant growth.

また、所定期間の経過後にウッドチップが微生物によって生分解することで、気温が上ってもはや除雪剤を必要としない時期において残存する除雪剤を回収又は除去する追加作業を行わなくてよいため経済性に優れ、且つ2次環境汚染を生じさせないため環境にやさしい。   In addition, since the wood chip is biodegraded by microorganisms after a predetermined period of time, there is no need to perform additional work to collect or remove the remaining snow removal agent at a time when the temperature rises and the snow removal agent is no longer needed. It is environmentally friendly because it does not cause secondary environmental pollution.

以下、本発明の好適な実施例を挙げて詳しく説明するに先立ち、本明細書及び請求の範囲において用いられた用語や単語は、通常又は辞書的な意味に限定して解釈されてはならず、本発明の技術的思想や概念に符合する意味として解釈されるべきであることを明らかにしておく。   Prior to the detailed description of the preferred embodiments of the present invention, the terms and words used in the present specification and claims should not be construed to be limited to ordinary or lexicographic meanings. It should be clarified that it should be construed as a meaning consistent with the technical idea and concept of the present invention.

本明細書の全体において、ある部分がある構成要素を「含む」とするとき、これは、特に拘りのない限り、他の構成要素を除くのではなく、他の構成要素をさらに含んでいてよいことを意味する。   Throughout this specification, when a part “includes” a component, this does not exclude other components but may further include other components, unless otherwise specified. Means that.

本明細書内において「ウッドチップ」とは、木を所定の大きさに破砕した小片を意味するものであり、広い意味では木の葉を除いた木の根、枝、幹などのすべての部分の小片を意味するものであってよい。
以下、本発明の土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤及びその製造方法について詳しく説明することにする。
In this specification, “wood chip” means a small piece obtained by crushing a tree into a predetermined size. In a broad sense, it means a small piece of a tree root, branch, trunk, etc., excluding the leaves of the tree. It may be.
Hereinafter, the environment-friendly snow removing agent impregnated with beneficial microorganisms in the soil and crops of the present invention and a method for producing the same will be described in detail.

先ず、本発明に係る土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤の場合、積雪された路面又は道路上に撒布して圧雪又は結氷した路面への摩擦力を向上させ、且つウッドチップ中に含浸された金属イオン塩で持続的に雪を溶かすことで融雪(融氷)効果を得ることができるだけでなく、土壌や作物に有益な微生物が外部に放出されて周辺の土壌及び植物に栄養分として作用して植物の成長や土壌の質を改善させることができる。また、所定の時期が過ぎて気温が上ってもはや除雪剤を必要としない時期になると、ウッドチップ中に含浸された微生物が活性化しながらウッドチップを生分解させ、残存する除雪剤を回収するという追加作業が不要となることで経済性が高まり、生分解したウッドチップが周辺の土壌や植物に栄養分として供給でき、環境親和性が高い。   First, in the case of an environmentally-friendly snow remover impregnated with beneficial microorganisms in the soil and crops according to the present invention, the frictional force on the snow-covered road surface or the road surface that has been snowed or frozen by spreading on the road surface is improved, and By melting snow continuously with metal ion salt impregnated in woodchips, it is possible not only to obtain a snow melting (ice melting) effect, but also microorganisms beneficial to the soil and crops are released to the surrounding soil and It can act as a nutrient for plants to improve plant growth and soil quality. Also, when the predetermined time passes and the temperature rises and the snow removal agent is no longer needed, the microorganisms impregnated in the wood chip are activated to biodegrade the wood chip and collect the remaining snow removal agent. This eliminates the need for additional work, improving economic efficiency, and providing biodegraded wood chips as nutrients to the surrounding soil and plants.

具体的に、本発明に係る土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤の場合、金属イオン塩と微生物が含浸されたウッドチップを含んでいてよい。   Specifically, in the case of the environment-friendly snow removal agent impregnated with beneficial microorganisms in the soil or crop according to the present invention, wood chips impregnated with metal ion salts and microorganisms may be included.

前記ウッドチップは、木葉を除く木の根、枝、幹などの木の硬い部分を細かく破砕した小片であり、一例として、伐木された木を板状に裁断した後、木板の表面の表面積を向上させるために凹凸を形成した後、これを破砕して使用し、又は、他の例として、光葉樹不良林樹種更新、造林などのため伐木される木又は木を使用して加工品を製造した後に発生する多量の林木副産物などを破砕して使用することができ、廃棄される資源をリサイクルして資源の効率性を向上させることができる。   The wood chip is a small piece obtained by finely crushing a hard part of a tree such as a tree root, a branch, or a trunk excluding leaves, and as an example, after cutting a cut tree into a plate shape, the surface area of the surface of the wooden board is improved. After forming irregularities for this purpose, this is crushed and used, or, as another example, after manufacturing processed products using trees or trees that are cut down for renewal, planting, etc. A large amount of forestry by-products generated can be crushed and used, and resources that are discarded can be recycled to improve resource efficiency.

前記ウッドチップでは木に形成されている多数の気孔内に雪を溶かす融雪効果を有する金属イオン塩が含浸されており、積雪された路面又は道路面に該ウッドチップを撒布した場合、前記金属イオン塩が雪と反応して雪を溶かす溶解過程が持続的に進行され、一瞬ではなく所定の期間に亘ってウッドチップ中に含浸されていた金属イオン塩が徐々に外部に排出されることで、除雪効果を持続させる徐放効果を得ることができる。   In the wood chip, a metal ion salt having a snow melting effect that melts snow is impregnated in a large number of pores formed in the tree, and when the wood chip is distributed on the road surface or road surface on which snow is accumulated, the metal ion The melting process in which the salt reacts with the snow to melt the snow is continuously progressed, and the metal ion salt impregnated in the wood chip over a predetermined period instead of a moment is gradually discharged to the outside. A sustained release effect that maintains the snow removal effect can be obtained.

好ましくは、前記ウッドチップは、圧雪又は結氷路面に適当な摩擦力を付与するためには、1〜20mm長さの薄板状の木片であってよく、より好ましくは、5〜10mm長さで厚みは1〜5mmであってよく、薄板状の木片の形態は特に限定されず、平衡四辺形、四角形、円形、球形、多角形などの多様な形態であってよい。   Preferably, the wood chip may be a thin plate-like piece of wood having a length of 1 to 20 mm, and more preferably a thickness of 5 to 10 mm in order to give an appropriate frictional force to the snow or ice road surface. May be 1 to 5 mm, and the form of the thin wooden piece is not particularly limited, and may be various forms such as a balanced quadrilateral, a square, a circle, a sphere, and a polygon.

前記ウッドチップの長さ、厚み、及び形態に応じて前記ウッドチップの表面積が変わり、そのため、前記ウッドチップにおける徐放効果に差異が生じ、ウッドチップの形態は薄板状であることが好ましい。   The surface area of the wood chip varies depending on the length, thickness, and form of the wood chip. Therefore, the sustained release effect of the wood chip varies, and the wood chip is preferably thin.

また、前記ウッドチップの表面はフラットであってもよいが、好ましくは、凹凸が形成されていてよく、前記ウッドチップの表面に形成された凹凸によってウッドチップの表面積が増加し、その結果、ウッドチップの広い表面積によって除雪効果を向上させることができ、且つ広い表面積によって路面の摩擦力を増加させることができる。   Further, the surface of the wood chip may be flat, but preferably, unevenness may be formed, and the surface area of the wood chip is increased by the unevenness formed on the surface of the wood chip. The snow removal effect can be improved by the large surface area of the chip, and the frictional force of the road surface can be increased by the large surface area.

一例として、前記ウッドチップの表面積を広げるために、製造されたウッドチップの表面には凹凸が形成されていてよく、形成された凹凸がラインに沿って配列して形成され、又は任意に不規則に形成されていてよい。また、形成された凹凸の断面は、流線形、波形、三角形、四角形、台形、多角形など、特に限定されずに多様な形態で形成されていてよく、凹凸の断面が一つの形態ではない前記挙げられた多様な形態が繰り返し、非規則的に配列されていてもよい。   As an example, in order to increase the surface area of the wood chip, the surface of the manufactured wood chip may be formed with unevenness, the formed unevenness is formed along a line, or arbitrarily irregular It may be formed. Further, the formed uneven section may be formed in various forms without particular limitation, such as streamline, corrugated, triangular, quadrangular, trapezoidal, polygonal, etc. The uneven section is not a single form. The various forms mentioned may be repeated and arranged irregularly.

より詳述すると、前記ウッドチップ中に含まれる金属イオン塩は、直接的に雪を溶かす融雪(融氷)の役割をするものであって、一般的に雪を溶かす除雪剤として使用されるものであれば特に限定されずにいずれも使用することができるが、好ましくは、塩化マグネシウム(magmesium chloride)、メタけい酸ナトリウム(sodium metasilicate)、塩化カルシウム(calcium chlride)、塩化ナトリウム(sodium chloride)及びリチウムイオン塩からなる群より選択された少なくとも一つ以上を含んでいてよい。   More specifically, the metal ion salt contained in the wood chip serves as a snow melting (melting ice) that melts snow directly, and is generally used as a snow removal agent that melts snow. Any of these may be used without any particular limitation, but preferably magnesium chloride, sodium metasilicate, calcium chloride, sodium chloride, and sodium chloride. At least one selected from the group consisting of lithium ion salts may be included.

より好ましくは、前記金属イオン塩のうちより環境にやさしい塩化マグネシウムを主原料として使用し、補助腐食及び除雪効果が極大化できるメタけい酸ナトリウム(sodium metasilicate)及びリチウムイオン塩などを使用していてよい。   More preferably, among the metal ion salts, more environmentally friendly magnesium chloride is used as a main raw material, and sodium metasilicate and lithium ion salts that can maximize the effect of auxiliary corrosion and snow removal are used. Good.

本発明に係る摩擦力及び除雪効果が向上した環境にやさしい除雪剤に使用される金属イオン塩は、前記ウッドチップの全重量の5〜40wt%の範囲で含まれていてよく、より好ましくは、10〜15wt%の範囲で含まれていてよく、より効果的な除雪効果を得るために、前記金属イオン塩は、塩化マグネシウム100重量部、前記塩化マグネシウム100重量部を基準に、メタけい酸ナトリウム1〜10重量部、リチウムイオン塩1〜10重量部を含んでいてよい。このとき、使用されるリチウムイオン塩は、特に限定されないが、一例として、塩化リチウム(lithium chloride、LiCl)、炭酸リチウム(lithium carbonate、LiCO)、酸化リチウム(lithium oxide、LiO)から選択されたものを使用していてよい。 The metal ion salt used in the environment-friendly snow removal agent with improved frictional force and snow removal effect according to the present invention may be contained in a range of 5 to 40 wt% of the total weight of the wood chip, more preferably, In order to obtain a more effective snow removal effect, the metal ion salt may contain 100 parts by weight of magnesium chloride and 100 parts by weight of magnesium chloride. 1 to 10 parts by weight and 1 to 10 parts by weight of a lithium ion salt may be included. At this time, the lithium ion salt to be used is not particularly limited, but examples include lithium chloride (LiCl), lithium carbonate (Li 2 CO 3 ), and lithium oxide (Li 2 O). The one selected from may be used.

したがって、本発明に係る摩擦力及び除雪効果が向上した環境にやさしい除雪剤の場合、積雪された雪の上に撒布された瞬間から持続的にウッドチップ中に含浸されていた金属イオン塩によって除雪効果が示されるため、既存の除雪剤に比べ、適切な量の除雪剤を使用することができるだけでなく、除雪の際、雪が降る度に除雪剤を撒布しなくても済むため、除雪作業性が向上するだけでなく経済性が向上し、且つ過量の金属イオン塩を使用しなくても済むため、2次環境汚染を防止することができる。   Therefore, in the case of the environmentally-friendly snow remover with improved frictional force and snow removal effect according to the present invention, the snow removal is performed by the metal ion salt that has been continuously impregnated in the wood chip from the moment it is spread on the snow that has accumulated. Since the effect is shown, it is possible not only to use an appropriate amount of snow removal agent compared to existing snow removal agents, but also to remove snow removal agent every time it snows, so snow removal workability In addition to improving the cost, the economy is improved and it is not necessary to use an excessive amount of metal ion salt, so that secondary environmental pollution can be prevented.

さらには、本発明に係る環境にやさしい除雪剤は、ウッドチップ中に微生物を更に含むことによって、金属イオン塩とともに前記微生物が外部に放出されることで、周辺の土壌や植物に栄養分として作用するだけでなく、雪が完全に溶けた後又は気温が上ってもはや除雪効果を必要としてない時点では前記ウッドチップ中に含まれた微生物によってウッドチップを生分解することで路面又は道路に残っているウッドチップを回収及び廃棄処理する追加作業を行わなくても済む。   Furthermore, the environment-friendly snow removal agent according to the present invention further includes microorganisms in the wood chip, so that the microorganisms are released to the outside together with the metal ion salt, thereby acting as a nutrient on the surrounding soil and plants. Not only after the snow has completely melted or when the temperature has risen and the snow removal effect is no longer needed, it remains on the road surface or road by biodegrading the wood chip with microorganisms contained in the wood chip. There is no need for additional work for collecting and disposing of the wood chips.

また、前記ウッドチップが融雪でできた水とともに配水管や集水管に流れていって管詰まりを生じさせたり、周辺の農地又は土壌に流出して2次環境汚染を起こしたりすることなく、ウッドチップが生分解し、その分解物が周辺の農地又は土壌に流出して栄養物質として作用し、その結果、土壌の質を改善し、農作物又は植物の成長に役立てられる堆肥の役割をすることができる。   In addition, the wood chip flows into the water distribution pipe and the water collecting pipe together with the water made from snow melting, and does not cause clogging, and does not flow into the surrounding farmland or soil and cause secondary environmental pollution. Chips biodegrade and the degradation products flow into the surrounding farmland or soil and act as nutrients, thereby improving soil quality and serving as a compost that can help crops or plants grow. it can.

具体的には、前記ウッドチップ中に含浸される微生物は、植物の生長や土壌の質改善に役立てられる有用微生物であって、植物の根での栄養分吸収を促進させることで生長を促進させるとともに、根伝染性病害に対して生物学的防除力を向上させ、病源菌と鉄に対する競争的な機作によって病源菌の生長を抑制させることで植物の生長や土壌の質改善に役立てられる。本発明に係る除雪剤の骨格であるウッドチップ中に含まれる微生物は、一般的に土壌の質を改善したり、植物に良い影響を及ぼす微生物であれば特に限定されずに使用可能であるが、好ましくは、枯草菌及び乳酸菌からなる群より選択された1種以上を使用していてよい。   Specifically, the microorganisms impregnated in the wood chip are useful microorganisms that are useful for improving plant growth and soil quality, and promoting growth by promoting nutrient absorption in the roots of plants. It is useful for improving plant growth and soil quality by improving biological control against root infectious diseases and suppressing the growth of pathogenic fungi by competitive mechanism against pathogenic fungi and iron. The microorganisms contained in the wood chip that is the skeleton of the snow removal agent according to the present invention can be used without particular limitation as long as it is a microorganism that generally improves soil quality or has a positive effect on plants. Preferably, one or more selected from the group consisting of Bacillus subtilis and lactic acid bacteria may be used.

枯草菌は自然界に広く分布する非病原性細菌であり、特に空気、枯草、下水、土壌の中に存在し、棒状の桿菌で鞭毛片親があるため運動性を持っており、菌体中央に円形又は卵円形の芽胞を形成する。一般的に培養基でも発育性に優れ、灰白色の大きなコロニーを形成しその周囲は放射状をなしている。前記枯草菌の特徴は芽胞を持っていて抵抗力が強く、菌体はグリコーゲンを含むグラム陽性菌であり、多数の炭水化物を分解して酸を生成することができる。前記枯草菌は30〜60℃で最も増殖が活発であり、50〜56℃の高温でも発育するが、70℃以上の蒸気中で15分放置すれば死滅する。このような枯草菌のうち代表的なバチルス・サブチリス(Bacillus subtilis)菌は、一般的に、清麹醤、納豆、みそ、キムチ、コチュジャン、醤油などの多様な醗酵食品に多量含まれており、本発明では、前記枯草菌の中でもバチルス・サブチリス(Bacillus subtilis)菌、バチルス・アミロリクエファシエンス(Bacillus amyloliquefaciens)菌、バチルス・ステアロサーモフィラス(bacillus stearothermophilus)菌、バチルス・セレウス(Bacillus cereus)菌、バチルス・メガテリウム(bacillus megaterium)菌、バチルス・リケニフォルミス(bacillus licheniformis)菌から選択された一つ以上を使用することが好ましい。   Bacillus subtilis is a non-pathogenic bacterium that is widely distributed in nature, especially in air, hay, sewage, and soil. Or an oval spore is formed. In general, the culture medium is also excellent in growth, forms a large grayish white colony, and its periphery is radial. The characteristic of Bacillus subtilis is that it has a spore and is highly resistant, and the microbial cell is a Gram-positive bacterium containing glycogen, and can generate an acid by decomposing many carbohydrates. The Bacillus subtilis grows most actively at 30 to 60 ° C. and grows even at a high temperature of 50 to 56 ° C., but dies if left in steam at 70 ° C. or higher for 15 minutes. Among such Bacillus subtilis, typical Bacillus subtilis bacteria are generally abundantly contained in various fermented foods such as neat soy sauce, natto, miso, kimchi, gochujang, and soy sauce. In the present invention, among the Bacillus subtilis, Bacillus subtilis, Bacillus amyloliquefaciens, Bacillus stearothermophilus, Bacillus stearothermophilus, Bacteria, Bacillus megaterium, Bacillus licheniformis It is preferred to use at least one material et selected.

乳酸菌は嫌気性細菌であって、漬け物やヨーグルトに多量含有されていると知られており、有機物分解酵素(protease、cellulase、amylaseなど)、ビタミン、アミノ酸、生長ホルモン、核酸などを産生し、乳酸産生で酸度を低下させて嫌気性有害微生物の増殖を抑制する機能があると知られている。乳酸菌が活性化すると、植物の種子発芽及び根の発育が促進され、有機酸(acetic acid、lactic acidなど)などを産生して不溶性リン酸化合物の陽イオンとキレート結合をすることでリン酸を可溶化させることができる。   Lactic acid bacteria are anaerobic bacteria and are known to be contained in pickles and yogurts in large quantities, producing organic matter-degrading enzymes (protease, cellulase, amylase, etc.), vitamins, amino acids, growth hormones, nucleic acids, etc. It is known to have a function of suppressing the growth of anaerobic harmful microorganisms by reducing the acidity in production. When lactic acid bacteria are activated, plant seed germination and root development are promoted, and organic acids (such as acetic acid and lactic acid) are produced to chelate the cations of insoluble phosphate compounds to form phosphate. It can be solubilized.

また、乳酸菌はバクテリオシン(bacterioncin)、過酸化水素(hydrogen peroxide)、乳酸(lactic acid)、抗ウイルス物質などの産生で病源菌を抑制することができる。主に醗酵堆肥接種菌として使用されており、堆肥を多量使用する作物では根の発育や初期生育に卓越な効果がある。本発明において使用される乳酸菌としては、ラクトバチルス・アシドフィルス(Lactobacillus acidophilus)菌、ラクトバチルス・プランタルム(Lactobacillus plantanum)菌、ラクトバチルス・ブルガリカス(Lactobacillus bulgaricus)菌、ラクトバチルス・カゼイ(Lactobacillus casei)菌、ストレプトコッカス・フェカーリス(Streptococcus faecalis)菌から選択された一つ以上を使用していてよい。   In addition, lactic acid bacteria can suppress pathogenic bacteria by producing bacteriocin, hydrogen peroxide, lactic acid, and antiviral substances. It is mainly used as an inoculum for fermentation compost, and it has a remarkable effect on root growth and initial growth in crops that use a large amount of compost. Examples of lactic acid bacteria used in the present invention include Lactobacillus acidophilus bacteria, Lactobacillus plantarum bacteria, Lactobacillus bulgaricus bacteria, Lactobacillus bulgaricus bacteria, One or more selected from Streptococcus faecalis may be used.

前記したように、本発明に係る除雪剤中では微生物として枯草菌又は乳酸菌を使用していてよく、前記枯草菌と乳酸菌は常温で活発に増殖又は培養される微生物の一つであって、除雪剤を必要とする積雪時又は気温が低い冬季など持続的に除雪機能を発揮しなければならない時は、低い気温によって枯草菌又は乳酸菌の活動が活発ではないことからウッドチップの生分解性が低下することでウッドチップ本来の形態を保持しつつ路面への摩擦力を付与し、且つ前記ウッドチップ中に含浸された金属イオン塩によって持続的に融雪させる除雪効果を発揮することができ、また、前記微生物が外部に放出されながら除雪剤が撒布された周辺の土壌の質改善及び植物の成長に役立てられる。   As described above, Bacillus subtilis or lactic acid bacteria may be used as microorganisms in the snow removal agent according to the present invention, and the Bacillus subtilis and lactic acid bacteria are one of microorganisms that are actively grown or cultured at room temperature, When the snow removal function must be performed continuously, such as when snow is required or when the temperature is low, the activity of Bacillus subtilis or lactic acid bacteria is not active due to the low temperature, which reduces the biodegradability of wood chips. It is possible to exert a snow removal effect that imparts frictional force to the road surface while maintaining the original shape of the wood chip, and continuously melts snow with the metal ion salt impregnated in the wood chip, While the microorganisms are released to the outside, it is useful for improving the quality of the surrounding soil where the snow removal agent is distributed and for growing the plant.

さらには、気温が上ってもはや除雪効果を必要としない時期になると、前記枯草菌及び乳酸菌の増殖が活発になりながらウッドチップの生分解性を促進させ、路面上に残存するウッドチップを分解させて除去することができるため、除雪剤を回収する追加作業を不要とするだけでなく、生分解するウッドチップが周辺の土壌や植物に栄養成分として作用して植物の生長に役立てられる。   Furthermore, when the temperature rises and the snow removal effect is no longer necessary, the biodegradability of the wood chips is promoted while the growth of the Bacillus subtilis and lactic acid bacteria is active, and the wood chips remaining on the road surface are decomposed. Therefore, not only the additional work of recovering the snow removal agent is unnecessary, but also the wood chips that are biodegraded act as nutrients on the surrounding soil and plants and are useful for plant growth.

一方、本発明に係る他の実施形態は、土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤の製造方法に関するものであって、好ましくは、金属イオン塩が溶解されたイオン溶液にウッドチップを浸漬させる浸漬段階;前記浸漬段階を通じて金属イオン塩が含浸されたウッドチップを乾燥する第1乾燥段階;前記第1乾燥段階を通じて乾燥されたウッドチップに微生物培養液を噴射する噴射段階;及び前記噴射段階を通じて微生物が含浸されたウッドチップを乾燥する第2乾燥段階;を含んで、本発明に係る土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤を製造することができる。   On the other hand, another embodiment according to the present invention relates to a method for producing an environmentally-friendly snow removal agent impregnated with microorganisms beneficial to soil and crops, preferably an ionic solution in which a metal ion salt is dissolved. A dipping step of dipping the wood chips; a first drying step of drying the wood chips impregnated with the metal ion salt through the dipping step; a spraying step of spraying a microbial culture solution onto the wood chips dried through the first drying step; And a second drying step of drying the wood chips impregnated with the microorganisms through the spraying step, an environment-friendly snow removal agent impregnated with microorganisms beneficial to the soil and crop according to the present invention can be produced. .

好ましくは、前記ウッドチップは、前述したように、木の加工後に発生する副産物、すなわち廃棄される木、木材を破砕して得ていてよく、木板の表面に凹凸を形成し破砕して得ていてよく、一例として、前記ウッドチップは、木板の表面に凹凸を形成する表面処理段階;及び表面に凹凸が形成された木板を1〜20mm厚みの薄板状の木片に破砕する破砕段階;を含んで製造されたウッドチップを使用していてよい。   Preferably, as described above, the wood chip may be obtained by crushing by-products generated after processing of the wood, that is, discarded wood, wood, and crushing by forming irregularities on the surface of the wood board. As an example, the wood chip includes a surface treatment step for forming irregularities on the surface of the wooden board; and a crushing step for crushing the wooden board with the irregularities formed on the surface into thin plate-like pieces of wood having a thickness of 1 to 20 mm. Wood chips made in can be used.

前記ウッドチップの表面に形成された凹凸の模様、形態は、前述したように多様な形態、ラインを有していてよく、フラットな表面に比べて表面積を増加させることができる凹凸形態であれば特に限定されない。   The pattern and form of the unevenness formed on the surface of the wood chip may have various forms and lines as described above, as long as it is an uneven form that can increase the surface area compared to a flat surface. There is no particular limitation.

前記したようにウッドチップの表面に凹凸が形成され表面積が向上することによって金属イオン塩の徐放性、すなわち融雪(融氷)効果の持続性及び融雪時間を制御することができ、前記表面積が広くなるほど積雪される雪を溶かす速度を高め、微生物による生分解期間も短縮させることができる。   As described above, unevenness is formed on the surface of the wood chip and the surface area is improved, so that the sustained release property of the metal ion salt, that is, the sustainability of the snow melting (ice melting) effect and the snow melting time can be controlled. The wider it is, the higher the melting speed of snow that accumulates, and the shorter the biodegradation period by microorganisms.

これは、本発明に係る土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤を私用する地域、時期に応じて、前記ウッドチップの表面に形成された凹凸の好適な形状及び形態を制御してウッドチップを表面積を調節することができる。一例として、雪がたくさん降って路面又は坂道の多い山間地方の場合、ウッドチップの表面に屈曲の激しい凹凸を形成することで摩擦力を極大化させるだけでなく、広い表面積によって早期に雪を溶かすことができる。逆に、雪の積雪量が多くなく雪の降る間隔又は時期が長い場合、ウッドチップの表面がフラットな、又は凹凸が細かいか少量、些細に形成されて屈曲の激しい凹凸が形成されたウッドチップに比べてウッドチップの表面積が狭い場合、相対的に長期間持続的且つ繰り返しの融雪効果を期待することができる。前記例は、本発明に係る環境にやさしい除雪剤の基本骨格になるウッドチップの多様な形態の一部の例示を記載したことであって、好ましくは、本発明の土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤が撒布される地域又は時期による、積雪される雪の量、陰地又は陽地に応じて、除雪剤の基本骨格になるウッドチップの表面の形態を適宜制御し、調節すればよく、このようにして製造されたウッドチップを使用して本発明の除雪剤を製造することができる。   This is because the preferred shape and form of the irregularities formed on the surface of the wood chip according to the region and time when the environment-friendly snow removal agent impregnated with beneficial microorganisms in soil and crops according to the present invention is used. Can control the surface area of the wood chip. As an example, in a mountainous region with a lot of snow falling and many roads or slopes, not only can the frictional force be maximized by forming uneven surfaces with a sharp bend on the surface of the wood chip, but the snow can be melted early with a large surface area. Can do. Conversely, if there is not a lot of snow and the snowfall interval or time is long, the wood chip surface is flat, or the irregularities are fine or small, and the irregularities are severely bent. In contrast, when the surface area of the wood chip is small, a relatively long-lasting and repeated snow melting effect can be expected. The above-described example is a description of some examples of various forms of wood chips that serve as the basic skeleton of the environmentally-friendly snow removal agent according to the present invention, and is preferably a microorganism beneficial to the soil or crop of the present invention. The shape of the surface of the wood chip, which is the basic skeleton of the snow removal agent, is appropriately controlled according to the amount of snow to be accumulated, shaded or positive, depending on the region or time when the environment-friendly snow removal agent impregnated with The snow removal agent of the present invention can be produced using the wood chip thus produced.

具体的に説明すると、先ず、浸漬段階では、ウッドチップに金属イオン塩が溶解されたイオン溶液にウッドチップを浸漬させてウッドチップ内部に金属イオン塩を含浸させていてよく、好ましくは、浸漬段階を通じてウッドチップ内部に形成された空隙中に金属イオン塩を含浸させていてよい。   Specifically, first, in the dipping stage, the wood chip may be dipped in an ionic solution in which the metal ion salt is dissolved in the wood chip, and the metal ion salt may be impregnated inside the wood chip. The metal ion salt may be impregnated in the void formed in the wood chip through.

前記浸漬段階で使用される金属イオン塩が溶解されたイオン溶液は、塩化マグネシウム(magmesium chloride)、メタけい酸ナトリウム(sodium metasilicate)、塩化カルシウム(calcium chlride)、塩化ナトリウム(sodium chloride)及びリチウムイオン塩からなる群より選択された少なくとも一つ以上の金属イオン塩を1:0.5〜2質量比で溶解させてなるものを使用していてよく、好ましくは、塩化マグネシウム100重量部、前記塩化マグネシウム100重量部を基準に、メタけい酸ナトリウム1〜10重量部、リチウムイオン塩1〜10重量部を含む金属イオン塩を水と0.5〜2:1質量比で溶解させてなるものを使用していてよく、より好ましくは、金属イオン塩と水が1:1質量比で混合してなる金属イオン塩が溶解されたイオン溶液を使用していてよい。このとき、水と金属イオン塩との1:1割合はウッドチップ中の金属イオン塩を効果的に含浸させるための最も好ましい割合である。   The ionic solution in which the metal ion salt used in the immersion step is dissolved is magnesium chloride, sodium metasilicate, calcium chloride, sodium chloride, and lithium ion. What dissolved at least 1 or more metal ion salt selected from the group which consists of a salt by 1: 0.5-2 mass ratio may be used, Preferably magnesium chloride is 100 weight part, Said chloride What dissolve | melts metal ion salt containing 1 to 10 weight part of sodium metasilicate and 1 to 10 weight part of lithium ion salt on the basis of 100 weight part of magnesium with water by 0.5-2: 1 mass ratio. May be used, more preferably Metal ion salt and water 1: metal ion salt formed by mixing 1 mass ratio may not use the dissolved ionic solution. At this time, the 1: 1 ratio of water and metal ion salt is the most preferable ratio for effectively impregnating the metal ion salt in the wood chip.

また、前記浸漬段階では、金属イオン塩が溶解されたイオン溶液にウッドチップを40〜80分間前記金属イオン塩が溶解されたイオン溶液にウッドチップを浸漬させることが好ましく、前記浸漬時間の範囲を外れると、ウッドチップに金属イオン塩が十分に浸漬されず、所望の融雪効果を期待し難く、且つ時間超過による利益がなくて製造工程や時間がかかって経済性に劣ることがある。   In the immersion step, the wood chip is preferably immersed in the ion solution in which the metal ion salt is dissolved for 40 to 80 minutes in the ion solution in which the metal ion salt is dissolved. If it is removed, the metal ion salt is not sufficiently immersed in the wood chip, it is difficult to expect the desired snow melting effect, and there is no profit due to excess time, which may be inferior in economic efficiency due to the manufacturing process and time.

前記浸漬段階を通じて金属イオン塩が含浸されたウッドチップは、120〜140℃で1〜2時間乾燥する第1乾燥段階を通じて1次的に乾燥して、前記ウッドチップの表面に金属イオン塩が含まれたウッドチップを製造することができる。   The wood chip impregnated with the metal ion salt through the immersion step is primarily dried through the first drying step of drying at 120 to 140 ° C. for 1 to 2 hours, and the surface of the wood chip contains the metal ion salt. Wood chips can be produced.

前記第1乾燥段階を通じて乾燥されたウッドチップの表面に微生物培養液を噴射する噴射段階を通じて、ウッドチップ中に微生物を含浸させることができ、好ましくは、微生物培養液をスプレーにて前記ウッドチップの表面に均一に噴射させることができる。
前記微生物培養液は、一般的に木を生分解させる微生物を培養した微生物培養液であれば特に限定されずに使用可能である。
The wood chip can be impregnated with a microorganism through a spraying step of spraying a microorganism culture solution onto the surface of the wood chip dried through the first drying step, and preferably the microorganism culture solution is sprayed on the wood chip. It can be sprayed uniformly on the surface.
The microorganism culture solution is not particularly limited as long as it is a microorganism culture solution in which microorganisms that biodegrade trees are generally cultured.

具体的に、前記微生物培養液は、一般的に木を生分解させることができる微生物を培地に接種して培養した後、公知の微生物培養液を製造する方法を用いて製造すればよく、特に限定されないが、好ましくは、枯草菌及び乳酸菌からなる群より選択された1種以上を含む微生物を培養して製造された微生物培養液を使用することが好ましい。   Specifically, the microorganism culture solution may be produced by using a method for producing a known microorganism culture solution after inoculating and cultivating a microorganism capable of biodegrading a tree in a medium. Although not limited, it is preferable to use a microorganism culture solution produced by culturing a microorganism containing at least one selected from the group consisting of Bacillus subtilis and lactic acid bacteria.

詳しくは、前記微生物培養液は、乳酸菌及び枯草菌が成長することができる栄養源が含まれている培地に30〜45℃で2〜3日間培養して製造することができる。特に、乳酸菌は3日以上培養しないことが好ましく、これは栄養物質の枯渇によって乳酸菌の活性が弱くなることがあり、培地内の乳酸菌の活動による乳酸が蓄積されて乳酸菌の生菌数が減少することがあるからである。   Specifically, the microorganism culture solution can be produced by culturing at 30 to 45 ° C. for 2 to 3 days in a medium containing a nutrient source capable of growing lactic acid bacteria and Bacillus subtilis. In particular, it is preferable not to culture lactic acid bacteria for more than 3 days. This is because the activity of lactic acid bacteria may be weakened due to depletion of nutrients, and lactic acid is accumulated due to the activity of lactic acid bacteria in the medium, reducing the number of live bacteria of lactic acid bacteria Because there are things.

例えば、液体培地(TSB)に枯草菌又は乳酸菌からなる群より選択された1種以上の微生物を30〜45℃で48〜72時間振盪培養したものを使用するか、MRS Broth培地を精製水に溶かしてから、121℃、1〜2気圧で10〜30分間滅菌した後、加圧殺菌された液体培地を予め殺菌されたフラスコに分注して枯草菌又は乳酸菌からなる群より選択された1種以上の微生物を接種し、40〜60℃の温度で80rpmの速度で撹拌しながら96時間培養して微生物培養液を製造することができる。
このとき、使用される枯草菌及び乳酸菌についての具体的な説明は、前述したとおりであり、ここでは省略することにする。
For example, a liquid medium (TSB) using one or more microorganisms selected from the group consisting of Bacillus subtilis or lactic acid bacteria and shaking cultured at 30 to 45 ° C. for 48 to 72 hours, or using MRS Broth medium as purified water After being melted and sterilized at 121 ° C. and 1-2 atm for 10 to 30 minutes, the pressure-sterilized liquid medium is dispensed into a pre-sterilized flask and selected from the group consisting of Bacillus subtilis or lactic acid bacteria 1 A microorganism culture solution can be produced by inoculating a microorganism of more than one species and culturing for 96 hours while stirring at a temperature of 40 to 60 ° C. at a speed of 80 rpm.
At this time, the specific description of Bacillus subtilis and lactic acid bacteria used is as described above, and will be omitted here.

前記噴射段階を通じて微生物が含浸されたウッドチップを、第2乾燥段階を通じて水分含量を低減させてから包装して、本発明に係る土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤を製造することができる。   A wood chip impregnated with microorganisms through the spraying step is packaged after reducing the water content through the second drying step, and an environmentally friendly snow removal agent impregnated with microorganisms beneficial to soil and crops according to the present invention. Can be manufactured.

具体的に、前記第2乾燥段階では、微生物が含浸されたウッドチップを10〜30℃で20〜30時間乾燥していてよく、前記第2乾燥段階の乾燥温度が10℃未満であると、所望の水分となるように乾燥するのに相当な時間がかかるだけでなく、十分に水分が乾燥されず保存及び流通過程で腐敗したり、カビが発生したりして、除雪剤の品質を低下させることがあり、乾燥温度が30℃を超えると、ウッドチップ中に含浸された微生物が活性化してウッドチップの生分解が進行し、除雪剤としての所望の摩擦力や融雪効果を期待し難い。   Specifically, in the second drying stage, the wood chips impregnated with microorganisms may be dried at 10-30 ° C. for 20-30 hours, and the drying temperature of the second drying stage is less than 10 ° C., Not only does it take a considerable amount of time to dry up to the desired moisture content, but the moisture content is not sufficiently dried and decays during storage and distribution, and mold is generated, reducing the quality of the snow removal agent. When the drying temperature exceeds 30 ° C., the microorganisms impregnated in the wood chip are activated and the biodegradation of the wood chip proceeds, and it is difficult to expect a desired frictional force and snow melting effect as a snow removal agent. .

したがって、本発明に係る土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤の場合、除雪剤をもはや必要としない時期に微生物によって除雪剤を生分解させることで残存する除雪剤を回収したり廃棄処理するという追加作業を遂行しなくても済むだけでなく、廃棄処理される林木副産物、木工所廃林木、建設現場の廃木材などの廃棄される廃木材を破砕してなるウッドチップを使用することで資源のリサイクル率を高め、且つ前記ウッドチップ中に含浸された金属イオン塩による徐放効果により、一度の撒布で一回きりではない繰り返し且つ持続的な融雪(除雪)効果が期待でき、経済性に優れ且つ環境親和的である。   Therefore, in the case of an environmentally friendly snow remover impregnated with beneficial microorganisms in the soil or crop according to the present invention, the remaining snow remover is recovered by biodegrading the snow remover with microorganisms at a time when the snow remover is no longer needed. Wood chips made by crushing discarded wood such as forest by-products, woodworking waste wood, and construction site waste wood. The recycle rate of the resources is increased by using the metal ion, and the sustained release effect by the metal ion salt impregnated in the wood chip has the effect of repeatedly and lasting snow melting (snow removal) that is not once in a single distribution. Expected, economical and environmentally friendly.

さらには、微生物によって分解されたウッドチップは堆肥としての活用価値が高く、除雪剤が撒布された周辺の土壌や植物に栄養物質を供給して土壌の質を改善し且つ植物の成長に役立てられる。   Furthermore, wood chips decomposed by microorganisms are highly useful as compost, and they can improve the quality of the soil by supplying nutrients to the surrounding soil and plants where snow removal agents are distributed, and are useful for plant growth. .

Claims (9)

金属イオン塩と微生物が含浸されたウッドチップを含み、
前記微生物は、バチルス・サブチリス(Bacillus subtilis)菌、バチルス・アミロリクエファシエンス(Bacillus amyloliquefaciens)菌、バチルス・ステアロサーモフィラス(bacillus stearothermophilus)菌、バチルス・セレウス(Bacillus cereus)菌、バチルス・メガテリウム(bacillus megaterium)菌及びバチルス・リケニフォルミス(bacillus licheniformis)菌から選択された少なくともいずれか一つの枯草菌であることを特徴とする、土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤。
Including wood chips impregnated with metal ion salts and microorganisms,
The microorganisms include Bacillus subtilis, Bacillus amyloliquefaciens, Bacillus stearothermulus, Bacillus steerotherm, Bacillus An environmentally friendly snow removal agent impregnated with microorganisms beneficial to soil and crops, characterized in that it is at least one Bacillus subtilis selected from Bacillus megaterium and Bacillus licheniformis.
前記金属イオン塩は、
塩化マグネシウム(magmesium chloride)、メタけい酸ナトリウム(sodium metasilicate)、塩化カルシウム(calcium chlride)、塩化ナトリウム(sodium chloride)及びリチウムイオン塩からなる群より選択された少なくとも一つ以上を含むことを特徴とする、請求項1に記載の土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤。
The metal ion salt is
And at least one selected from the group consisting of magnesium chloride, sodium metasilicate, calcium chloride, sodium chloride, and lithium ion salt. An environment-friendly snow removal agent, wherein the soil or crop according to claim 1 is impregnated with beneficial microorganisms.
前記ウッドチップは、
1〜20mm厚みの薄板状の木片であって、表面に凹凸が形成されたことを特徴とする、請求項1に記載の土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤。
The wood chip is
2. An environment-friendly snow-removing agent impregnated with microorganisms beneficial to soil and crops according to claim 1, which is a thin plate-like piece of wood having a thickness of 1 to 20 mm and having irregularities formed on the surface thereof.
金属イオン塩が溶解されたイオン溶液にウッドチップを浸漬させる浸漬段階;
前記浸漬段階を通じて金属イオン塩が含浸されたウッドチップを乾燥する第1乾燥段階;
前記第1乾燥段階を通じて乾燥されたウッドチップに微生物培養液を噴射する噴射段階;及び
前記噴射段階を通じて微生物が含浸されたウッドチップを乾燥する第2乾燥段階;を含み、
前記微生物培養液は、
バチルス・サブチリス(Bacillus subtilis)菌、バチルス・アミロリクエファシエンス(Bacillus amyloliquefaciens)菌、バチルス・ステアロサーモフィラス(bacillus stearothermophilus)菌、バチルス・セレウス(Bacillus cereus)菌、バチルス・メガテリウム(bacillus megaterium)菌及びバチルス・リケニフォルミス(bacillus licheniformis)菌から選択された少なくともいずれか一つの枯草菌を培地に接種して培養したものであることを特徴とする、土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤の製造方法。
An immersion step in which the wood chip is immersed in an ion solution in which the metal ion salt is dissolved;
A first drying step of drying the wood chips impregnated with the metal ion salt through the dipping step;
Spraying a microorganism culture solution onto the wood chips dried through the first drying step; and drying a wood chip impregnated with microorganisms through the spraying step;
The microorganism culture solution is
Bacillus subtilis, Bacillus amyloliquefaciens, Bacillus stearothermophilus, Bacillus stearotherm, Bacillus cereus An environment in which soil and crops are impregnated with beneficial microorganisms, characterized in that the medium is inoculated and cultured with at least one Bacillus subtilis selected from Bacillus licheniformis and Bacillus licheniformis An easy-to-use method for producing snow removal agents.
前記ウッドチップは、
木板の表面に凹凸を形成する表面処理段階;及び
表面に凹凸が形成された木板を1〜20mm厚みの薄板状の木片に破砕させる破砕段階;を含んで製造されたことを特徴とする、請求項4に記載の土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤の製造方法。
The wood chip is
A surface treatment step of forming irregularities on the surface of the wooden board; and a crushing step of crushing the wooden board with irregularities formed on the surface into a thin plate-like piece of wood having a thickness of 1 to 20 mm, Item 5. A method for producing an environmentally-friendly snow removal agent in which beneficial microorganisms are impregnated in the soil or crop of Item 4.
前記金属イオン塩が溶解されたイオン溶液は、
水に、
塩化マグネシウム(magmesium chloride)、メタけい酸ナトリウム(sodium metasilicate)、塩化カルシウム(calcium chlride)、塩化ナトリウム(sodium chloride)及びリチウムイオン塩からなる群より選択された少なくとも一つ以上の金属イオン塩を1:0.5〜2質量比で溶解させてなることを特徴とする、請求項4に記載の土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤の製造方法。
The ion solution in which the metal ion salt is dissolved is:
in water,
At least one metal ion salt selected from the group consisting of magnesium chloride, sodium metasilicate, calcium chloride, sodium chloride, and lithium ion salt; The method for producing an environmentally-friendly snow removal agent, wherein the soil or crop is impregnated with beneficial microorganisms according to claim 4, which is dissolved at a mass ratio of 0.5-2.
前記金属イオン塩は、
塩化マグネシウム100重量部、
前記塩化マグネシウム100重量部を基準に、メタけい酸ナトリウム1〜10重量部、リチウムイオン塩1〜10重量部が含まれてなることを特徴とする、請求項6に記載の土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤の製造方法。
The metal ion salt is
100 parts by weight of magnesium chloride,
7. Useful for soil and crops according to claim 6, comprising 1 to 10 parts by weight of sodium metasilicate and 1 to 10 parts by weight of lithium ion salt based on 100 parts by weight of magnesium chloride. Of an environmentally friendly snow removal agent impregnated with various microorganisms.
前記第1乾燥段階では、
前記金属イオン塩が含浸されたウッドチップを120〜140℃で1〜2時間乾燥することを特徴とする、請求項4に記載の土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤の製造方法。
In the first drying stage,
5. The environment-friendly snow removal agent impregnated with microorganisms beneficial to soil and crops according to claim 4, wherein the wood chip impregnated with the metal ion salt is dried at 120 to 140 ° C. for 1 to 2 hours. Manufacturing method.
前記第2乾燥段階では、
微生物が含浸されたウッドチップを10〜30℃で20〜30時間乾燥することを特徴とする、請求項4に記載の土壌や作物に有益な微生物が含浸された環境にやさしい除雪剤の製造方法。
In the second drying stage,
5. The method for producing an environmentally-friendly snow removal agent impregnated with microorganisms beneficial to soil and crops according to claim 4, wherein the wood chips impregnated with microorganisms are dried at 10 to 30 ° C. for 20 to 30 hours. .
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JPS62285979A (en) * 1986-06-03 1987-12-11 Nippon Gurinnaa:Kk Snow-thawing soil conditioner
JP2004059850A (en) * 2002-07-31 2004-02-26 Hazama Corp Snow melting agent, method for producing the same, and method for decomposing food waste
JP2004346289A (en) * 2003-05-20 2004-12-09 Takeuchi Mokuzai Kogyo Kk Anti-slip agent for use on frozen road surface, and method for manufacturing the same
KR20120051384A (en) * 2010-11-12 2012-05-22 정용길 Natural liquid compound for removing snow
KR20150089294A (en) * 2014-01-27 2015-08-05 주식회사 바이오푸른세상 Manufacturing for an eco-friendly frictional and de-icing agent using woodchips

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JPS62285979A (en) * 1986-06-03 1987-12-11 Nippon Gurinnaa:Kk Snow-thawing soil conditioner
JP2004059850A (en) * 2002-07-31 2004-02-26 Hazama Corp Snow melting agent, method for producing the same, and method for decomposing food waste
JP2004346289A (en) * 2003-05-20 2004-12-09 Takeuchi Mokuzai Kogyo Kk Anti-slip agent for use on frozen road surface, and method for manufacturing the same
KR20120051384A (en) * 2010-11-12 2012-05-22 정용길 Natural liquid compound for removing snow
KR20150089294A (en) * 2014-01-27 2015-08-05 주식회사 바이오푸른세상 Manufacturing for an eco-friendly frictional and de-icing agent using woodchips

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