JP2017222813A5 - - Google Patents
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- Publication number
- JP2017222813A5 JP2017222813A5 JP2016120722A JP2016120722A JP2017222813A5 JP 2017222813 A5 JP2017222813 A5 JP 2017222813A5 JP 2016120722 A JP2016120722 A JP 2016120722A JP 2016120722 A JP2016120722 A JP 2016120722A JP 2017222813 A5 JP2017222813 A5 JP 2017222813A5
- Authority
- JP
- Japan
- Prior art keywords
- hard coat
- active energy
- energy ray
- coating film
- coat according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000011248 coating agent Substances 0.000 claims 10
- 238000000576 coating method Methods 0.000 claims 10
- 239000011342 resin composition Substances 0.000 claims 5
- 238000004519 manufacturing process Methods 0.000 claims 4
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 2
- 239000003999 initiator Substances 0.000 claims 2
- 230000001678 irradiating effect Effects 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 2
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims 1
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- -1 Acyl phosphine oxide Chemical compound 0.000 claims 1
- 239000006096 absorbing agent Substances 0.000 claims 1
- 239000003242 anti bacterial agent Substances 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 claims 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 claims 1
- 238000010030 laminating Methods 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 claims 1
- 125000001477 organic nitrogen group Chemical group 0.000 claims 1
- YBBJKCMMCRQZMA-UHFFFAOYSA-N pyrithione Chemical compound ON1C=CC=CC1=S YBBJKCMMCRQZMA-UHFFFAOYSA-N 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
Claims (11)
（Ｂ）有機窒素硫黄系抗菌剤；
を含む活性エネルギー線硬化性樹脂組成物からなり、
黄色ぶどう球菌について、ＪＩＳ Ｚ２８０１：２０１０に従い、温度２３℃において測定した抗菌活性値が２以上であるハードコート。
(A) multifunctional (meth) acrylate;
(B) organic nitrogen sulfur antibacterial agent;
An active energy ray curable resin composition containing
A hard coat having an antibacterial activity value of 2 or more measured at a temperature of 23 ° C. according to JIS Z 2801: 2010 for S. aureus.
The component (B) is 2-methyl-4-isothiazolin-3-one, 1,2-benzisothiazolin-3-one, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-n- The hard coat according to claim 1, comprising one or more selected from the group consisting of octyl-4-isothiazolin-3-one, and 1-hydroxypyridine-2 (1H) -thione.
The hard coat according to claim 1 or 2, wherein the active energy ray curable resin composition further comprises (C) a photopolymerization initiator.
The hard coat according to claim 3, wherein the component (C) contains a (C1) acylphosphine oxide photopolymerization initiator.
（Ｃ１）アシルフォスフィンオキサイド系光重合開始剤 ２０〜６０質量％と
（Ｃ２）アセトフェノン系光重合開始剤 ８０〜２０質量％からなり、
ここで上記成分（Ｃ１）と上記成分（Ｃ２）との和は１００質量％である
請求項４に記載のハードコート。
The component (C) is
(C1) Acyl phosphine oxide type photoinitiator 20 to 60 mass% and (C 2) acetophenone type photoinitiator 80 to 20 mass%,
The hard coat according to claim 4, wherein the sum of the component (C1) and the component (C2) is 100% by mass.
The hard coat according to any one of claims 1 to 5, wherein the active energy ray curable resin composition further comprises (D) a UV absorber.
An article comprising the hard coat according to any one of claims 1 to 6.
A decorative sheet comprising the hard coat according to any one of claims 1 to 6.
An article comprising the decorative sheet according to claim 8.
（１）フィルム基材の少なくとも一方の面の上に、上記活性エネルギー線硬化性樹脂組成物のウェット塗膜を形成する工程；
（２）上記工程（１）で得たウェット塗膜を予備乾燥し、乾燥塗膜にする工程；
（３）上記工程（２）で得た乾燥塗膜の面の上に、活性エネルギー線透過性フィルムを重ね、仮貼りする工程；及び、
（４）上記工程（３）で得た積層体に活性エネルギー線を照射し、上記乾燥塗膜を硬化させる工程；
を含む、上記製造方法。
The method for producing a hard coat according to any one of claims 1 to 6,
(1) on at least one surface of the film substrate to form a wet coating film of the active energy ray curable resin composition process;
(2) pre-drying the wet coating film obtained in the above step (1) into a dry coating film;
(3) a step of overlaying an active energy ray-transmissive film on the surface of the dried coating obtained in the step (2) and temporarily attaching the film;
(4) a step of irradiating the laminate obtained in the step (3) with an active energy ray to cure the dried coating film;
The above manufacturing method.
（１’）活性エネルギー線透過性フィルムの少なくとも一方の面の上に、上記活性エネルギー線硬化性樹脂組成物のウェット塗膜を形成する工程；(1 ') A step of forming a wet coating film of the active energy ray curable resin composition on at least one surface of the active energy ray transparent film;
（２’）上記工程（１’）で得たウェット塗膜を予備乾燥し、乾燥塗膜にする工程；(2 ') pre-drying the wet coating film obtained in the above step (1') into a dry coating film;
（３’）上記工程（２’）で得た乾燥塗膜の面の上に、フィルム基材を重ね、仮貼りする工程；及び、(3 ') a step of laminating a film substrate on the surface of the dried coating obtained in the above step (2') and temporarily attaching it;
（４’）上記工程（３’）で得た積層体に活性エネルギー線を照射し、上記乾燥塗膜を硬化させる工程；(4 ') a step of irradiating the laminate obtained in the step (3') with an active energy ray to cure the dried coating film;
を含む、上記製造方法。The above manufacturing method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016120722A JP6765867B2 (en) | 2016-06-17 | 2016-06-17 | Antibacterial hard coat and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016120722A JP6765867B2 (en) | 2016-06-17 | 2016-06-17 | Antibacterial hard coat and its manufacturing method |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020083532A Division JP7032473B2 (en) | 2020-05-12 | 2020-05-12 | Antibacterial hard coat and its manufacturing method |
| JP2020083531A Division JP7270578B2 (en) | 2020-05-12 | 2020-05-12 | ANTIBACTERIAL HARD COAT AND METHOD FOR MANUFACTURING SAME |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2017222813A JP2017222813A (en) | 2017-12-21 |
| JP2017222813A5 true JP2017222813A5 (en) | 2019-07-04 |
| JP6765867B2 JP6765867B2 (en) | 2020-10-07 |
Family
ID=60687864
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016120722A Active JP6765867B2 (en) | 2016-06-17 | 2016-06-17 | Antibacterial hard coat and its manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6765867B2 (en) |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10316728A (en) * | 1997-05-19 | 1998-12-02 | Showa Denko Kk | Curable composition and method for curing the same |
| JP2003342402A (en) * | 2002-05-27 | 2003-12-03 | Mitsubishi Rayon Co Ltd | Antimicrobial resin molding having scratch resistance and production method therefor |
| JP5699738B2 (en) * | 2011-03-29 | 2015-04-15 | コニカミノルタ株式会社 | Hard coat film, heat ray blocking film using the same, and organic element device |
-
2016
- 2016-06-17 JP JP2016120722A patent/JP6765867B2/en active Active
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