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JP2017199670A5
JP2017199670A5 JP2017083464A JP2017083464A JP2017199670A5 JP 2017199670 A5 JP2017199670 A5 JP 2017199670A5 JP 2017083464 A JP2017083464 A JP 2017083464A JP 2017083464 A JP2017083464 A JP 2017083464A JP 2017199670 A5 JP2017199670 A5 JP 2017199670A5
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positive electrode
lithium ion
ion battery
electrode material
battery according
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JP6930196B2 (en
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正極活物質粒子が官能基化グラフェンで被覆されてなるリチウムイオン電池用正極材料であって、
前記官能基化グラフェンによる前記正極活物質粒子の平均被覆率が80%以上であり;
前記正極材料のX線光電子分光測定による測定値から下記式(1)により求められる官能基化率が0.3以上1.3以下であるリチウムイオン電池用正極材料。
官能基化率=[(C−O一重結合に基づくピーク面積)+(C=O二重結合に基づくピーク面積)+(COO結合に基づくピーク面積)]/(C−C、C=C及びC−H結合に基づくピーク面積)・・・(1)
A positive electrode material for a lithium ion battery, wherein the positive electrode active material particles are coated with functionalized graphene,
An average coverage of the positive electrode active material particles by the functionalized graphene is 80% or more;
A positive electrode material for a lithium ion battery, wherein the functional grouping ratio of the positive electrode material determined by the following formula (1) from a value measured by X-ray photoelectron spectroscopy is from 0.3 to 1.3.
Functionalization rate = [(peak area based on C—O single bond) + (C = peak area based on O double bond) + (peak area based on COO bond)] / (C—C, C = C and Peak area based on CH bond) (1)
前記正極材料のレーザーラマン分光法により測定されるDバンド(1360cm −1 付近)の強度(I(D))とGバンド(1590cm −1 付近)の強度(I(G))の比(I(D)/I(G))が0.7以上1.7以下である、請求項1に記載のリチウムイオン電池用正極材料。 The ratio (I (G)) of the intensity (I (D)) of the D band (around 1360 cm −1 ) and the intensity (I (G)) of the G band (around 1590 cm −1 ) of the positive electrode material measured by laser Raman spectroscopy. The positive electrode material for a lithium ion battery according to claim 1, wherein D) / I (G)) is 0.7 or more and 1.7 or less. 前記I(D)/I(G)が0.8以上1.1以下である、請求項2に記載のリチウムイオン電池用正極材料。 The positive electrode material for a lithium ion battery according to claim 2, wherein the I (D) / I (G) is 0.8 or more and 1.1 or less. 前記官能基化グラフェンは、グラフェン層に平行な方向の大きさが1μm以上である、請求項1〜3のいずれかに記載のリチウムイオン電池用正極材料。 The positive electrode material for a lithium ion battery according to claim 1, wherein the functionalized graphene has a size in a direction parallel to the graphene layer of 1 μm or more. 前記官能基化グラフェンによる前記正極活物質粒子の平均被覆率が90%以上である、請求項1〜4のいずれかに記載のリチウムイオン電池用正極材料。 The positive electrode material for a lithium ion battery according to any one of claims 1 to 4, wherein an average coverage of the positive electrode active material particles with the functionalized graphene is 90% or more. 前記正極材料の官能基化率が0.8以上1.3以下である、請求項1〜5のいずれかに記載のリチウムイオン電池用正極材料。 The positive electrode material for a lithium ion battery according to any one of claims 1 to 5, wherein the positive electrode material has a functionalization ratio of 0.8 or more and 1.3 or less. 前記官能基化グラフェンによる被覆厚みが100nm以下である、請求項1〜6のいずれかに記載のリチウムイオン電池用正極材料。 The positive electrode material for a lithium ion battery according to any one of claims 1 to 6, wherein a coating thickness of the functionalized graphene is 100 nm or less. 前記正極活物質粒子が層状酸化物活物質粒子である、請求項1〜7のいずれかに記載のリチウムイオン電池用正極材料。 The positive electrode material for a lithium ion battery according to any one of claims 1 to 7, wherein the positive electrode active material particles are layered oxide active material particles. 前記正極活物質粒子がNiを含む層状酸化物活物質粒子である、請求項8に記載のリチウムイオン電池用正極材料。 The positive electrode material for a lithium ion battery according to claim 8, wherein the positive electrode active material particles are layered oxide active material particles containing Ni. 前記官能基化グラフェンのグラフェン層に平行な方向の大きさを前記正極活物質粒子の粒子径で除した値が0.05以上3.0以下である、請求項1〜9のいずれかに記載のリチウムイオン電池用正極材料。 The value obtained by dividing the size of the functionalized graphene in the direction parallel to the graphene layer by the particle diameter of the positive electrode active material particles is 0.05 or more and 3.0 or less. Positive electrode material for lithium ion batteries. 請求項1〜10のいずれかに記載のリチウムイオン電池用正極材料を含むリチウムイオン電池用正極。 A positive electrode for a lithium ion battery, comprising the positive electrode material for a lithium ion battery according to claim 1. 請求項11に記載のリチウムイオン電池用正極を用いてなるリチウムイオン電池。 A lithium ion battery using the positive electrode for a lithium ion battery according to claim 11. 酸化グラフェン分散液と正極活物質粒子とを液相混合した後に乾燥させる操作を複数回繰り返すことにより、リチウムイオン電池用正極活物質粒子が酸化グラフェンで被覆されてなる前駆体粒子を準備する工程;
該前駆体粒子を、X線光電子分光測定による測定値から下記式(1)により求められる官能基化率が0.3以上1.3以下となるように還元する工程;
を有するリチウムイオン電池用正極材料の製造方法。
官能基化率=[(C−O一重結合に基づくピーク面積)+(C=O二重結合に基づくピーク面積)+(COO結合に基づくピーク面積)]/(C−C、C=C及びC−H結合に基づくピーク面積)・・・(1)
A step of preparing precursor particles in which the positive electrode active material particles for a lithium ion battery are coated with graphene oxide by repeating the operation of mixing the liquid phase of the graphene oxide dispersion and the positive electrode active material particles and then drying the mixture;
A step of reducing the precursor particles so that a functional grouping ratio determined by the following formula (1) from a value measured by X-ray photoelectron spectroscopy is 0.3 or more and 1.3 or less;
A method for producing a positive electrode material for a lithium ion battery, comprising:
Functionalization rate = [(peak area based on C—O single bond) + (C = peak area based on O double bond) + (peak area based on COO bond)] / (C—C, C = C and Peak area based on CH bond) (1)
前記前駆体粒子を還元する工程を150℃以上300℃以下の温度環境下で行う、請求項13に記載のリチウムイオン電池用正極材料の製造方法。 The method for producing a positive electrode material for a lithium ion battery according to claim 13, wherein the step of reducing the precursor particles is performed in a temperature environment of 150C or more and 300C or less. 酸化グラフェン分散液を正極活物質粒子と混合する前か、あるいは混合する際に、前記正極活物質粒子をシランカップリング剤と接触させる、請求項13または14に記載のリチウムイオン電池用正極材料の製造方法。The positive electrode material for a lithium ion battery according to claim 13 or 14, wherein the positive electrode active material particles are brought into contact with a silane coupling agent before or during mixing the graphene oxide dispersion with the positive electrode active material particles. Production method.
JP2017083464A 2016-04-21 2017-04-20 Positive electrode materials for lithium-ion batteries and their manufacturing methods, positive electrodes for lithium-ion batteries, lithium-ion batteries Active JP6930196B2 (en)

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KR102212939B1 (en) * 2017-12-04 2021-02-04 한국전기연구원 Reduced graphene oxide - silicon metal particle composite, method for producing a composite, and fabrication of electrodes for secondary battery and process for preparing the same
JP7102831B2 (en) * 2018-03-23 2022-07-20 Tdk株式会社 Positive electrode and lithium ion secondary battery
JP2019175633A (en) * 2018-03-28 2019-10-10 Tdk株式会社 Lithium ion secondary battery
JP7031097B2 (en) * 2018-07-26 2022-03-08 株式会社Abri Charging / discharging method of lithium secondary battery
US12155062B2 (en) * 2019-02-01 2024-11-26 Nichia Corporation Electrode active material for non-aqueous secondary battery comprising carbon material modified with one-electron oxidant and method for producing the same
US12107250B2 (en) 2019-02-01 2024-10-01 Nichia Corporation Method for producing electrode active material for non-aqueous secondary battery
CN110311113B (en) * 2019-07-02 2021-04-13 宁夏汉尧石墨烯储能材料科技有限公司 Graphene-coated lithium ion battery cathode material
KR20220127230A (en) * 2019-12-27 2022-09-19 가부시키가이샤 한도오따이 에네루기 켄큐쇼 A method for producing an electrode slurry, a method for producing an electrode, a method for producing a positive electrode, an electrode for a secondary battery, a positive electrode for a secondary battery
JPWO2021141013A1 (en) * 2020-01-07 2021-07-15
CN114156462A (en) * 2021-06-15 2022-03-08 宁夏汉尧石墨烯储能材料科技有限公司 Lithium ion battery electrode with nano-scale coating for improving performance of monocrystal-like anode material
WO2023119857A1 (en) * 2021-12-22 2023-06-29 パナソニックホールディングス株式会社 Negative electrode for solid-state battery and solid-state battery
CN117999245A (en) * 2023-12-26 2024-05-07 广东邦普循环科技有限公司 Lithium manganate material and preparation method and application thereof

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