JP2016054670A - Powder fat composition for imparting milk flavor, and method for imparting milk flavor to food and drink - Google Patents
Powder fat composition for imparting milk flavor, and method for imparting milk flavor to food and drink Download PDFInfo
- Publication number
- JP2016054670A JP2016054670A JP2014182878A JP2014182878A JP2016054670A JP 2016054670 A JP2016054670 A JP 2016054670A JP 2014182878 A JP2014182878 A JP 2014182878A JP 2014182878 A JP2014182878 A JP 2014182878A JP 2016054670 A JP2016054670 A JP 2016054670A
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- Prior art keywords
- oil
- milk
- fat composition
- milk flavor
- composition
- Prior art date
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Landscapes
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Abstract
Description
本発明は、乳風味付与用粉末油脂組成物、および飲食品に乳風味を付与する方法に関する。さらに詳しくは、ミルク入りのコ−ヒ−、紅茶、ココアなど、乳原料を配合する飲食品の乳風味(ミルク風味)を増強し、乳原料の代替製品として使用することができる乳風味付与用粉末油脂組成物、および飲食品に乳風味を付与する方法に関する。 The present invention relates to a powdery fat composition for imparting milk flavor and a method for imparting milk flavor to food and drink. More specifically, for enhancing the milk flavor (milk flavor) of foods and drinks containing milk ingredients such as coffee, tea, cocoa with milk, and the like, which can be used as a substitute for milk ingredients. The present invention relates to a powdery fat composition and a method for imparting milk flavor to food and drink.
コ−ヒ−や紅茶は、世界中の多くの国で飲用されており、人々にとって非常になじみの深い嗜好飲料である。日本では、特にコ−ヒ−は巨大な飲料市場を形成しており、抽出されたコ−ヒ−に何も添加していない「ブラックタイプ(無糖)」をはじめとして、「レギュラ−タイプ」、「微糖タイプ」、「カフェオレタイプ」など、甘味料(グラニュー糖、白砂糖など)や乳原料などを種々の割合で添加したコ−ヒ−が、缶、紙パック、ペットボトル、瓶等の各種容器に詰められて、多種多様な形態の製品として製造・販売されている。それらの中でも、乳原料を添加したミルク風味のコ−ヒ−に対する需要は非常に高い。 Coffee and black tea are drunk in many countries around the world and are very popular taste drinks for people. In Japan, especially coffee has formed a huge beverage market, including “black type (sugar-free)” that does not add anything to the extracted coffee, and “regular type”. , "Fine sugar type", "cafe au lait type", etc., sweets (granulated sugar, white sugar etc.) and dairy ingredients added in various proportions, cans, paper packs, PET bottles, bottles Are manufactured and sold as products in various forms. Among them, demand for milk-flavored coffee to which milk ingredients are added is very high.
コ−ヒ−や紅茶などに添加される乳原料としては、牛乳のほか、粉乳(全脂粉乳、脱脂粉乳)、練乳、クリ−ムなどがある。これらの乳原料のうち、牛乳は水分が約90%を占めることから変質しやすく、輸送や保管に細心の注意が必要となる。それに対し、粉乳は保存性に優れるため、輸送や保管は容易であるが、ミルク本来の風味とは異なる風味を呈する。牛乳を濃縮した粘状の液体物である練乳は調達コストが比較的安くて保存性も高く、粉乳にはない滑らかな組織を有するが、芳醇な特有の風味があることから、以前ほど使用されなくなっている。クリ−ムは、コ−ヒ−に、コク味やまろやかさを付与して風味を向上させるが、天然クリ−ムは調達コストが高く、品質の保持が困難であるため、現在では植物性油脂を利用した合成クリ−ムが主流となっている。 Milk materials added to coffee, black tea, etc. include milk, powdered milk (whole milk powder, skimmed milk powder), condensed milk, cream and the like. Of these milk materials, milk accounts for about 90% of water, so it easily changes in quality, and careful attention is required for transportation and storage. On the other hand, milk powder is excellent in preservability and is easy to transport and store, but exhibits a flavor different from the original flavor of milk. Condensed milk, which is a viscous liquid concentrated milk, has a relatively low procurement cost and high storage stability, and has a smooth structure that is not found in powdered milk. It is gone. Cream improves the flavor by adding richness and mellowness to coffee, but natural cream is expensive to procure and it is difficult to maintain quality. Synthetic creams that use the are the mainstream.
しかしながら、これらの乳原料は、その比率が高まるほど「コーヒーらしさ」から離れる傾向があり、かつ、脂肪分の分離を招くことが多くなる。加えて、これらの乳原料は製品出荷以降の温度変化や時間の経過によって固化して、浮遊、分離することがあるため、乳原料を多く含むコーヒー飲料を飲む場合には、よく振ってから飲むことが必要とされる。なお、製品に乳固形分を3%以上含むもの(カフェ・オ・レ、カフェ・ラッテ、コ−ヒ−牛乳など)は「乳および乳原料の成分規格等に関する省令(乳等省令)」に基づき「乳飲料」に分類されている。 However, these milk raw materials tend to move away from the “coffee-likeness” as the ratio increases, and often cause fat separation. In addition, these dairy ingredients may solidify, float, and separate due to temperature changes after product shipment and the passage of time, so when drinking coffee beverages that contain a large amount of dairy ingredients, shake them before drinking Is needed. In addition, products containing 3% or more of milk solids in the product (Cafe au lait, cafe latte, coffee milk, etc.) are listed in the “Ministerial Ordinance on Milk and Milk Ingredient Standards (Ministerial Ordinance on Milk, etc.)” Based on “milk beverages”.
また、従来、乳原料を含有したコーヒー飲料を製造する際に、コーヒー抽出液に乳原料を添加し、加熱殺菌すると、乳原料の凝集物や沈澱物が発生したり、本来コ−ヒ−のもつフレッシュな香りが損なわれて、好ましくない臭いが発生したりするという問題があった。 In addition, conventionally, when producing a coffee beverage containing a milk material, if the milk material is added to the coffee extract and sterilized by heating, agglomerates and precipitates of the milk material are generated, There is a problem that the fresh fragrance is impaired and an unpleasant odor is generated.
さらに、乳原料は加温販売時の熱によって酸化され、経時によって劣化が進むと特有の臭気を発するため、これを避けるためにビタミンE等の酸化防止剤が添加されるが、それでも加温による風味の寿命は1〜2週間程度(通常の賞味期限は製造日から1年程度)であった。 In addition, dairy ingredients are oxidized by the heat at the time of warming sales, and when the deterioration progresses over time, a specific odor is emitted. To avoid this, antioxidants such as vitamin E are added, but it still depends on heating. The service life of the flavor was about 1 to 2 weeks (normal shelf life is about 1 year from the date of manufacture).
その他、最近の健康志向の高まりから、カロリ−の高い乳原料の摂取を極力控えたいという需要者の増加傾向が認められる。しかしながら、他方ではミルク風味を十分に楽しみたいという要望もある。そのため、摂取カロリ−をできるだけ少なくしつつ、ミルク風味を十分に味わうことができるコーヒー飲料が市場で求められている。 In addition, due to the recent increase in health-consciousness, there is an increasing trend of consumers who want to refrain from taking milk ingredients with high calories as much as possible. On the other hand, however, there is a desire to fully enjoy the milk flavor. Therefore, there is a demand in the market for coffee beverages that can fully enjoy the milk flavor while minimizing the intake calories.
こうした状況を受け、乳原料の添加量を少なくしても、その分失われた乳風味を補うことができるように、飲食品の乳風味を強化する技術開発が進められており、現在まで多数報告されている。それらの報告のうち、いくつかについて以下に列挙する。
例えば、コーヒー抽出液や紅茶抽出液に乳化物を混合させても、油脂分の浮上分離やタンパクの沈澱を抑制することができ、乳風味豊かなミルク入りコーヒー飲料またはミルク入り紅茶飲料とすることが可能となる濃縮乳タイプ乳化物として、炭素数が8〜10である中鎖脂肪酸のみからなる中鎖脂肪酸油脂を5〜30質量%含有し、かつ生クリ−ムからバタ−を製造する際の副産物であるバタ−ミルク中の乳固形分を5〜30質量%含有することを特徴とする濃縮乳タイプ乳化物が報告されている(特許文献1)。
Under such circumstances, technology development to enhance the milk flavor of foods and drinks has been promoted so that even if the amount of milk ingredients added is reduced, the lost milk flavor can be compensated. It has been reported. Some of these reports are listed below.
For example, even if an emulsion is mixed with a coffee extract or a tea extract, it is possible to suppress the separation of oil and fat and protein precipitation, and to make a milk-flavored coffee beverage or tea beverage with milk. When producing butter from fresh cream, containing 5-30% by mass of medium-chain fatty acid oil consisting only of medium-chain fatty acids having 8 to 10 carbon atoms, as a concentrated milk type emulsion capable of A concentrated milk type emulsion characterized by containing 5 to 30% by mass of a milk solid content in buttermilk, which is a by-product of (Patent Document 1).
また、コーヒー、紅茶等の飲食物のミルク風味を増強させる方法として、固形分あたりの糖組成が、5糖類以上が40重量%以上であり、7糖類以上が35重量%以下である低糖化還元水飴を飲食物に添加する方法が報告されている(特許文献2)。 Further, as a method for enhancing the milk flavor of foods and beverages such as coffee and tea, low saccharification and reduction in which the sugar composition per solid content is 40% by weight or more of 5 saccharides and 35% by weight or more of 7 saccharides or more A method of adding chickenpox to food and drink has been reported (Patent Document 2).
また、良好な乳風味とコク味を有するホイップクリ−ムとして用いることができる起泡性水中油型乳化組成物として、油脂を含有する油相と、高甘味度甘味料と乳清ミネラルを含有する水相とを混合し、乳化することにより得られる起泡性水中油型乳化組成物が報告されている(特許文献3)。 In addition, as a foamable oil-in-water emulsified composition that can be used as a whipped cream with good milk flavor and richness, it contains an oil phase containing fats and oils, a high-intensity sweetener, and whey minerals A foamable oil-in-water emulsified composition obtained by mixing and emulsifying with an aqueous phase is reported (Patent Document 3).
また、バタ−やチ−ズ等の乳原料の風味、コク味の賦与または増強するために、12−メチルトリデカナ−ルを1ppt〜100ppmの濃度で含有させ、乳脂肪感、ボディ−感、コク味などを増強することが報告されている(特許文献4)。 In addition, in order to impart or enhance the flavor and richness of milk materials such as butter and cheese, 12-methyltridecanal is contained at a concentration of 1 ppt to 100 ppm, and milk fat feeling, body feeling, It has been reported that the body taste is enhanced (Patent Document 4).
また、少量の乳成分しか含有しない飲食品に乳感と乳由来の香気や呈味といった乳風味を付与する方法、あるいは乳含有製品の乳風味をさらに向上する方法として、玄米あるいは催芽処理させた玄米を粉砕処理して得られる粉末を乳原料を含有する飲食品に添加し、加熱することにより、乳の香気が引き立ち、更に乳特有の生臭みが軽減され、乳特有の乳感や呈味も改良され、乳風味全体が向上した飲食品を得ることが報告されている(特許文献5)。 In addition, brown rice or germination treatment was performed as a method of imparting milk flavor such as milk feeling and milk-derived flavor and taste to foods and drinks containing only a small amount of milk components, or as a method of further improving the milk flavor of milk-containing products. By adding and heating the powder obtained by pulverizing brown rice to foods and drinks containing milk ingredients, the flavor of milk is enhanced, and the milk-specific odor is reduced, and the milk-specific milky feeling and taste It has been reported that a food and drink with improved milk flavor is obtained (Patent Document 5).
また、乳原料特有の甘いクリ−ミ−な香味を付与することができる乳風味賦与乃至増強剤として、(Z)−6−オクテナ−ルを有効成分として含有することを特徴とする乳風味賦与乃至増強剤が報告されている(特許文献6)。 Further, as a milk flavor imparting or enhancing agent capable of imparting a sweet creamy flavor peculiar to milk raw materials, it contains (Z) -6-octenal as an active ingredient, Or the enhancer has been reported (patent document 6).
また、食品中に乳味成分が少量存在するだけでも、充分な乳風味、コク味を得ることのできる、乳風味増強材の製造法として、コ−ン粉末と油脂を、水の沸点より低い温度で接触処理することを特徴とする乳風味増強材の製造法が報告されている(特許文献7)。 In addition, as a method for producing a milk flavor enhancer that can obtain a sufficient milk flavor and richness even if only a small amount of milk flavor component is present in the food, corn powder and fats and oils are lower than the boiling point of water. There has been reported a method for producing a milk flavor enhancer characterized by performing contact treatment at a temperature (Patent Document 7).
しかしながら、乳風味を増強するための従来技術は、コ−ヒ−や紅茶等の飲料の風味を損なう場合があり、自然な乳脂感、ミルク感、コクを付与するものではなかった。 However, the prior art for enhancing the milk flavor may impair the flavor of beverages such as coffee and black tea, and does not impart a natural milk fat feeling, milk feeling, and richness.
そこで、こうした状況に鑑み、先に、本出願人は、飲食品本来の風味を損なうことなく、乳脂感、生乳のようなフレッシュなミルク感、および濃厚感のあるコクを増強、付与することができる乳風味付与用乳化組成物を提案した(特許文献8)。 Therefore, in view of such circumstances, the applicant can first enhance and impart a milky feeling, a fresh milky feeling such as raw milk, and a richness without losing the original flavor of food and drink. An emulsion composition for imparting milk flavor was proposed (Patent Document 8).
特許文献8で提案された乳風味付与用乳化組成物は、飲食品に乳脂感やコク等を増強、付与することができ、乳原料の代替品として非常に有効である。しかしながら、製品の保存性や安定性の向上、取扱いの容易さ等、様々な目的のために、上記乳化組成物と同様の効果を奏する粉末状の乳風味付与用組成物が求められていた。 The emulsified composition for imparting milk flavor proposed in Patent Document 8 can enhance and impart milk fat feeling and richness to foods and drinks, and is very effective as a substitute for milk raw materials. However, for various purposes such as improvement in storage stability and stability of the product and ease of handling, there has been a demand for a powdery milk flavor imparting composition that exhibits the same effects as the above emulsion composition.
したがって、本願発明は、飲食品本来の風味を損なうことなく、乳脂感、生乳のようなフレッシュなミルク感、および濃厚感のあるコクを増強、付与することができる乳風味付与用粉末油脂組成物を提供することを目的とする。 Accordingly, the present invention provides a powdery fat composition for imparting milk flavor capable of enhancing and imparting a milky fat feeling, a fresh milk feeling such as raw milk, and a rich body without losing the original flavor of food and drink. The purpose is to provide.
本発明者らは、上記課題を解決するために、主として、特許文献8で提案された乳風味付与用乳化組成物を基礎として研究を重ね、本発明を完成するに至った。 In order to solve the above-mentioned problems, the present inventors have conducted research mainly on the basis of the emulsion composition for imparting milk flavor proposed in Patent Document 8, and have completed the present invention.
すなわち、本発明は、
以下の(A)〜(D)成分を含有する乳風味付与用粉末油脂組成物であり、また、以下の(A)〜(D)成分を含有する水中油型乳化組成物を噴霧乾燥して得られる乳風味付与用粉末油脂組成物である。
(A)ラウリン酸系油脂
(B)乳化剤
(C)賦形剤
(D)水
That is, the present invention
A powdery fat composition for imparting milk flavor containing the following components (A) to (D), and spray-drying an oil-in-water emulsion composition containing the following components (A) to (D): This is a powdery fat composition for imparting milk flavor.
(A) Lauric acid oil (B) Emulsifier (C) Excipient (D) Water
また、本発明は、前記乳風味付与用粉末油脂組成物を飲食品に添加することを特徴とする、飲食品に乳風味を付与する方法である。 Moreover, this invention is the method of providing milk flavor to food / beverage products characterized by adding the said powdered oil-fat composition for milk flavor provision to food / beverage products.
本発明は、乳成分を含有する飲食品に添加することで、該飲食品本来の風味を損なうことなく、該飲食品の乳脂感、ミルク感、コクを増強することができる。また、乳成分を含有しない飲食品に添加しても、該飲食品本来の風味を損なうことなく、該飲食品に乳脂感、ミルク感、コクを付与することができる。従来使用されていた乳原料に代わって、低カロリ−で安価な乳風味付与材料として使用することができる。 By adding to the food / beverage products containing a milk component, this invention can reinforce the milk fat feeling, milk feeling, and richness of this food / beverage products, without impairing the original flavor of the food / beverage products. Moreover, even if it adds to the food / beverage products which do not contain a milk component, a milk-fat feeling, a milk feeling, and richness can be provided to this food / beverage products, without impairing the original flavor of this food / beverage products. It can be used as a low-calorie and inexpensive milk flavoring material in place of conventionally used milk ingredients.
本発明の乳風味付与用粉末油脂組成物(以下、「粉末油脂組成物」という)は、(A)ラウリン酸系油脂、(B)乳化剤、(C)賦形剤、(D)水を含有する粉末油脂組成物であり、これらの成分を含有する乳化組成物を噴霧乾燥して得られるものである。以下、詳細に説明する。 The powdery fat composition for imparting milk flavor according to the present invention (hereinafter referred to as “powdered fat composition”) contains (A) lauric acid fat, (B) emulsifier, (C) excipient, and (D) water. It is a powdered oil composition that is obtained by spray-drying an emulsified composition containing these components. Details will be described below.
(A)成分であるラウリン酸系油脂は、前記乳化組成物において油相部を形成するベースとなる成分であり、本発明の粉末油脂組成物に乳脂感、コクを付与し、かつ、粉末油脂組成物を水性媒体に溶解した際に良好な乳化安定性を可能にする成分である。本発明において、ラウリン酸系油脂とは、油脂の全構成脂肪酸中にラウリン酸を35%以上含む油脂の意味であり、特にはラウリン酸を35〜55%含み、かつ、パルミチン酸を4〜13%含む油脂が好適に使用される。ラウリン酸系油脂としては、ヤシ油、パ−ム核油、高ラウリン菜種油、またはその硬化(水添)、分別、エステル交換を実施した油脂が例示され、これらは1種または2種以上を混合して用いることができる。具体的には、精製ヤシ油、精製パ−ム核油、硬化ヤシ油、およびヤシ・パーム混合加工油脂から選択される1種または2種以上を用いることが好ましい。 (A) The lauric acid fat which is a component is a component which becomes the base which forms an oil phase part in the said emulsified composition, imparts milk fat feeling and richness to the powdered fat composition of the present invention, and powdered fat It is a component that enables good emulsification stability when the composition is dissolved in an aqueous medium. In the present invention, lauric acid-based fats and oils mean oils and fats containing 35% or more of lauric acid in the total constituent fatty acids of the fats and oils, particularly 35 to 55% of lauric acid, and 4 to 13 of palmitic acid. % Containing fat is preferably used. Examples of lauric oils and fats include coconut oil, palm kernel oil, high lauric rapeseed oil, and oils and fats that have been hardened (hydrogenated), fractionated, and transesterified, and these are a mixture of one or more. Can be used. Specifically, it is preferable to use 1 type, or 2 or more types selected from refined coconut oil, refined palm kernel oil, hydrogenated coconut oil, and palm / palm mixed processed oil.
ラウリン酸系油脂単独ではなく、ラウリン酸系油脂を主成分とする食用油脂混合物も(A)成分として用いることができる。この混合物において、ラウリン酸系油脂以外の食用油脂としては、パ−ム油、菜種油、大豆油、綿実油、サフラワ−油、コ−ン油、米油、ラ−ド、牛脂、魚油等の動植物油脂、乳脂肪等が例示され、これらは1種または2種以上を混合して用いることができる。なお、ラウリン酸系油脂とラウリン酸系油脂以外の食用油脂との混合物を用いる場合は、十分な乳風味付与が確実に行われるようにするため、通常、該混合物中のラウリン酸系油脂の含量を50質量%以上にすることが望ましい。 An edible oil / fat mixture containing lauric acid / fat as a main component can be used as the component (A) instead of lauric acid / fat alone. In this mixture, edible fats and oils other than lauric fats and oils include palm oil, rapeseed oil, soybean oil, cottonseed oil, safflower oil, corn oil, rice oil, lard, beef fat, fish oil and other animal and vegetable fats and oils. Milk fat and the like are exemplified, and these can be used alone or in combination of two or more. When using a mixture of lauric oil and fat and edible fats and oils other than lauric oil, the content of lauric oil and fat in the mixture is usually in order to ensure that sufficient milk flavor is imparted. It is desirable that the content is 50 mass% or more.
本発明の粉末油脂組成物の全質量(固形分)中に含まれるラウリン酸系油脂の量は、通常、5〜80質量%、好ましくは、10〜70質量%、より好ましくは、20〜70質量%である。5質量%未満であると、乳脂感、コクを十分に付与することができず、80質量%を超えると、油脂の呈味が強くなりすぎたり、粉末油脂組成物から滲出したりする恐れがある。 The amount of lauric acid-based oil / fat contained in the total mass (solid content) of the powdered oil / fat composition of the present invention is usually 5 to 80% by mass, preferably 10 to 70% by mass, more preferably 20 to 70%. % By mass. If the amount is less than 5% by mass, the feeling of milk fat and richness cannot be sufficiently imparted, and if it exceeds 80% by mass, the taste of fats and oils may become excessively strong or may exude from the powdery fat composition. is there.
(B)成分である乳化剤としては、加工デンプン、アラビアガム、グリセリン脂肪酸エステル、キラヤ抽出物(キラヤサポニン)、ショ糖脂肪酸エステル、レシチン、酵素処理レシチン、ゼラチン、カゼイン、カゼインナトリウム、およびポリソルベ−トから選択される1種または2種以上を用いることが好ましい。これらのうち、加工デンプンを用いると、ラウリン酸系油脂の含有量をより一層増加させることができる点で好ましい。 As the emulsifier as component (B), modified starch, gum arabic, glycerin fatty acid ester, kiraya extract (kiraya saponin), sucrose fatty acid ester, lecithin, enzyme-treated lecithin, gelatin, casein, sodium caseinate, and polysorbate It is preferable to use 1 type, or 2 or more types selected from. Of these, the use of modified starch is preferred in that the content of lauric acid fat can be further increased.
加工デンプンは、デンプン本来の物理的性状を改善するために、デンプンに化学的、物理的または酵素的な加工を加えたものであり、具体的には、アセチル化アジピン酸架橋デンプン、アセチル化リン酸架橋デンプン、アセチル化酸化デンプン、オクテニルコハク酸デンプンナトリウム、酢酸デンプン、酸化デンプン、ヒドロキシプロピルデンプン、ヒドロキシプロピル化リン酸架橋デンプン、リン酸化デンプン、リン酸架橋デンプン、デンプングリコール酸ナトリウム、デンプンリン酸エステルナトリウム、焙焼デキストリン、酸処理デンプン、アルカリ処理デンプン、漂白デンプン、酵素処理デンプンが例示される。これらの中でも、特に、オクテニルコハク酸デンプンナトリウムが好ましい。 Modified starch is obtained by adding chemical, physical or enzymatic processing to starch in order to improve the original physical properties of starch. Specifically, modified starch includes acetylated adipic acid cross-linked starch, acetylated phosphorus, and the like. Acid cross-linked starch, acetylated oxidized starch, sodium octenyl succinate, starch acetate, oxidized starch, hydroxypropyl starch, hydroxypropylated phosphate cross-linked starch, phosphorylated starch, phosphate cross-linked starch, sodium starch glycolate, starch phosphate ester Examples include sodium, roasted dextrin, acid-treated starch, alkali-treated starch, bleached starch, and enzyme-treated starch. Of these, starch sodium octenyl succinate is particularly preferable.
グリセリン脂肪酸エステルとしては、例えば、モノグリセリン脂肪酸エステル、ジグリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル等であって、脂肪酸部分はパルミチン酸、ステアリン酸、オレイン酸、アラキジン酸、ベヘン酸であるものが例示される。 Examples of the glycerin fatty acid ester include monoglycerin fatty acid ester, diglycerin fatty acid ester, polyglycerin fatty acid ester and the like, and the fatty acid part is palmitic acid, stearic acid, oleic acid, arachidic acid, and behenic acid. The
ショ糖脂肪酸エステルとしては、例えば、脂肪酸部分がパルミチン酸、ステアリン酸、アラキジン酸、ベヘン酸であるものが例示される。 Examples of sucrose fatty acid esters include those in which the fatty acid moiety is palmitic acid, stearic acid, arachidic acid, or behenic acid.
(B)乳化剤は、噴霧乾燥の対象となる、(A)〜(D)成分等を含有する乳化組成物の全質量に対し、0.1〜50質量%、好ましくは、5〜30質量%の配合組成とする。0.1質量%未満であると、十分に乳化が行われず、一方、50質量%を超えると、乳化剤に起因する好ましくない風味が発生してしまう恐れがある。 (B) An emulsifier is 0.1-50 mass% with respect to the total mass of the emulsion composition containing (A)-(D) component etc. used as the object of spray drying, Preferably, it is 5-30 mass%. The composition is as follows. When the amount is less than 0.1% by mass, the emulsification is not sufficiently performed. On the other hand, when it exceeds 50% by mass, an unfavorable flavor may be generated due to the emulsifier.
(C)成分である賦形剤としては、アラビアガム、加工デンプン、デキストリン、トレハロース、糖アルコール類、パラチニット、還元デンプン糖化物、粉末水飴等のDE(Dextrose Equivalent)20以上のデンプン分解物、ゼラチン、蛋白加水分解物、増粘多糖類、シクロデキストリン等から選択される1種または2種以上を用いることが好ましい。これらのうち、特にトレハロースは、作製された粉末油脂組成物の保存安定性を向上させるうえで好ましい。 Examples of the excipient (C) include gum arabic, modified starch, dextrin, trehalose, sugar alcohols, palatinit, reduced starch saccharified product, DE (Dextrose Equivalent) starch decomposition product of 20 or more, gelatin, etc. It is preferable to use one or more selected from protein hydrolysates, thickening polysaccharides, cyclodextrins and the like. Among these, trehalose is particularly preferable for improving the storage stability of the produced powdered fat composition.
本発明の粉末油脂組成物の全質量(固形分)中に含まれる賦形剤の量は、20〜90質量%、好ましくは、30〜60質量%である。20質量%未満であると、粉末状の形態に維持することが困難となり、一方、90質量%を超えると、賦形剤に起因する好ましくない風味が発生してしまう恐れがある。 The quantity of the excipient | filler contained in the total mass (solid content) of the powdered oil-fat composition of this invention is 20-90 mass%, Preferably, it is 30-60 mass%. If it is less than 20% by mass, it will be difficult to maintain the powder form, while if it exceeds 90% by mass, an unfavorable flavor may be generated due to the excipient.
(D)成分である水は、乳化剤、賦形剤等の水溶性成分を溶解して水相部を形成するために使用される。噴霧乾燥の対象となる、(A)〜(D)成分等を含有する乳化組成物における水の量は、水溶性成分の種類等に応じて適宜決定すればよいが、通常、該乳化組成物の全質量に対し、20〜70質量%である。20質量%未満であると、粘度が高くなるため乳化粒子の調製が難しくなる場合がある。一方、70質量%を超えると、乳化粒子が破壊されやすくなるため不安定になる場合がある。 (D) Water which is a component is used to dissolve water-soluble components such as emulsifiers and excipients to form an aqueous phase. The amount of water in the emulsion composition containing the components (A) to (D) to be spray-dried may be appropriately determined according to the type of the water-soluble component, etc., but usually the emulsion composition The total mass is 20 to 70 mass%. If the amount is less than 20% by mass, the viscosity becomes high, so that it may be difficult to prepare the emulsified particles. On the other hand, if it exceeds 70% by mass, the emulsified particles are likely to be broken and may become unstable.
作製された本発明の粉末油脂組成物の全質量中に含まれる水の量は、通常、7質量%以下とする。7質量%を超えると、粉末油脂組成物の品質が低下する恐れがある。 The amount of water contained in the total mass of the produced powdered fat composition of the present invention is usually 7% by mass or less. When it exceeds 7 mass%, there exists a possibility that the quality of a powdered oil-fat composition may fall.
本発明の粉末油脂組成物には前述した(A)〜(D)成分に加えて、香料成分として、各種の合成香料、天然香料、天然精油、植物エキスなどを配合することができる。例えば、「特許庁、周知慣用技術集(香料)第II部食品香料、P88−131、平成12年1月14日発行」に記載されている天然精油、天然香料、合成香料を挙げることができる。 In addition to the components (A) to (D) described above, various synthetic fragrances, natural fragrances, natural essential oils, plant extracts and the like can be blended as fragrance components in the powdered fat composition of the present invention. For example, natural essential oils, natural fragrances, and synthetic fragrances described in "Patent Office, Well-known and commonly used technology (fragrance) Part II food fragrance, P88-131, issued on January 14, 2000" can be mentioned. .
例えば、δ−カプロラクトン、γ−カプロラクトン、γ−ヘプタラクトン、γ−オクタラクトン、γ−ノナラクトン、γ−デカラクトン、7−デセン−4−オリド、3−メチル−4−デセン−4−オリド、3−メチル−5−デセン−4−オリド、γ−ウンデカラクトン、γ−ドデカラクトン、γ−トリデカラクトン、γ−テトラデカラクトン、2−ヘキセン−5−オリド、2−ヘプテン−5−オリド、δ−オクタラクトン、2−オクテン−5−オリド、4−メチル−5−オクタノリド、δ−ノナラクトン、2−ノネン−5−オリド、4−メチル−5−ノナノリド、δ−デカラクトン、2−デセン−5−オリド、4−メチル−5−デカノリド、δ−ウンデカラクトン、2−ウンデセン−5−オリド、4−メチル−5−ウンデカノリド、δ−ドデカラクトン、2−ドデセン−5−オリド、4−メチル−5−ドデカノリド、δ−トリデカラクトン、2−トリデセン−5−オリド、4−メチル−5−トリデカノリド、δ−テトラデカラクトン、2−テトラデセン−5−オリド、2−ペンタデセン−5−オリド、2−ヘキサデセン−5−オリド、2−ヘプタデセン−5−オリド、2−オクタデセン−5−オリド、2−ノナデセン−5−オリド、2−エイコセン−5−オリド、ε−デカラクトン等のラクトン類;プロピオン酸、酪酸、吉草酸、イソ吉草酸、カプロン酸、トランス−2−ヘキセン酸、ヘプタン酸、カプリル酸、ノナン酸、5−ヒドロキシノナン酸、カプリン酸、2−デセン酸、4−デセン酸、5−デセン酸、6−デセン酸、9−デセン酸、5−ヒドロキシデセン酸、5−ヒドロキシウンデカン酸、ラウリン酸、5−ヒドロキシドデカン酸、ミリスチン酸、ペンタデカン酸、イソペンタデカン酸、パルミチン酸、ヘプタデカン酸、ステアリン酸、オレイン酸、リノ−ル酸、リノレン酸等の脂肪酸類;trans−2−オクテナ−ル、trans−2−ノネナ−ル、アセトアルデヒド、プロパナ−ル、ブタナ−ル、2−ブテナ−ル、ヘキサナ−ル、オクタナ−ル、4−ヘプテナ−ル、2,4−オクタジエナ−ル、ノナナ−ル、2−ノネナ−ル、2,4−ノナジエナ−ル、2,6−ノナジエナ−ル、デカナ−ル、2,4−デカジエナ−ル、12−メチルトリデカナ−ル、ウンデカナ−ル、2,4−ウンデカジエナ−ル、ドデカナ−ル、ベンズアルデヒド、バニリン、エチルバニリン、フルフラ−ル、ヘリオトロピンジエチルアセタ−ル等のアルデヒド類;蟻酸エチル、酢酸エチル、酢酸ブチル、酢酸イソアミル、酢酸デシル、酢酸ドデシル、酢酸フェネチル、乳酸エチル、酪酸エチル、2−メチル酪酸エチル、3−エチル酪酸エチル、吉草酸メチル、カプロン酸メチル、カプロン酸エチル、ヘプタン酸メチル、ヘプタン酸エチル、カプリル酸エチル、カプリル酸イソアミル、カプリル酸ヘプチル、ノナン酸メチル、ノナン酸エチル、カプリン酸メチル、カプリン酸エチル、ウンデカン酸エチル、ラウリン酸メチル、ラウリン酸エチル、ミリスチン酸エチル、パルミチン酸エチル、サリチル酸メチル、コハク酸ジエチル、セバシン酸ジエチル、5−ヒドロキシヘキサン酸エチル、5−ヒドロキシデカン酸エチル、5−ヒドロキシウンデカン酸エチル、5−ヒドロキシデカン酸プロピル、5−ヒドロキシデカン酸イソプロピル、5−ヒドロキシオクタン酸2−メチルプロピル、5−ヒドロキシ−9−メチルデカン酸エチル等のエステル類;エタノ−ル、プロパノ−ル、ブタノ−ル、ペンタノ−ル、ヘキサノ−ル、ヘプタノ−ル、オクタノ−ル、ノナノ−ル、デカノ−ル、ベンジルアルコ−ル、フェニルエチルアルコ−ル、フルフリルアルコ−ル等のアルコ−ル類;フラネオ−ル、2−ヘプタノン、2−オクタノン、3−オクタノン、1−オクテン−3−オン、2−ノナノン、3−ノナノン、8−ノネン−2−オン、2−ウンデカノン、2−トリデカノン、アセトイン、5−ヒドロキシ−4−オクタノン、ジアセチル、2,3−ペンタジオン、2,3−ヘキサジオン、2,3−ヘプタジオン、アセチルイソバレリル、p−メトキシアセトフェノン、ベンゾフェノン、マルト−ル等のケトン類;フェニルエチルアンスラニレ−ト、トリメチルアミン、インド−ル、スカト−ル、ピリジン、イソキノリン、ピラジン、メチルピラジン、2−アセチルピロリン等の含窒素化合物類;メチルメルカプタン、イソブチルメルカプタン、2,4−ジチアペンタン、ジメチルスルフィド、ジメチルジスルフィド、2,4−ジチアペンタン、ジメチルトリスルフィド、ビス(2−メチル−3−フリル)ジスルフィド、ジメチルスルフォキシド、ジメチルスルフォン、メタンチオ−ル、メチルスルフォニルメタン、メチルイソチオシアネ−ト、エチルイソチオシアネ−ト、アリルイソチオシアネ−ト、2−メチル−3−ブタンチオ−ル、メチオナ−ル、チオ酢酸エチル、チオ酪酸メチル、3−ブテニルイソチオシアネ−ト、2−メチルチオフェン、ベンゾチアゾ−ル、スルフロ−ル、アセチル乳酸チオメチルエステル、プロピオニル乳酸チオメチルエステル、ブチリル乳酸チオメチルエステル、バレリル乳酸チオメチルエステル、2−メチルブチリル乳酸チオメチルエステル、デシリル乳酸チオメチルエステル、アセチル乳酸チオエチルエステル、プロピオニル乳酸チオエチルエステル、ブチリル乳酸チオエチルエステル、バレリル乳酸チオエチルエステル、イソカプロイル乳酸チオプロピルエステル、2−アセチル−2−チアゾリン等の含硫化合物類など公知の香料化合物;乳脂のリパ−ゼ分解物;乳タンパク質のプロテア−ゼ分解物;乳、濃縮乳、粉乳、ミルクホエイ、バタ−、チ−ズ、ヨ−グルトもしくはこれらの混合物からの乳または乳加工品の分画物などを挙げることができる。 For example, δ-caprolactone, γ-caprolactone, γ-heptalactone, γ-octalactone, γ-nonalactone, γ-decalactone, 7-decen-4-olide, 3-methyl-4-decene-4-olide, 3- Methyl-5-decen-4-olide, γ-undecalactone, γ-dodecalactone, γ-tridecalactone, γ-tetradecalactone, 2-hexene-5-olide, 2-heptene-5-olide, δ -Octalactone, 2-octene-5-olide, 4-methyl-5-octanolide, δ-nonalactone, 2-nonene-5-olide, 4-methyl-5-nonanolide, δ-decalactone, 2-decene-5 Orido, 4-methyl-5-decanolide, δ-undecalactone, 2-undecen-5-olide, 4-methyl-5-undecanolide, δ-dodecalactone 2-dodecene-5-olide, 4-methyl-5-dodecanolide, δ-tridecalactone, 2-tridecen-5-olide, 4-methyl-5-tridecanolide, δ-tetradecalactone, 2-tetradecene-5 Orido, 2-Pentadecene-5-Olide, 2-Hexadecene-5-Olide, 2-Heptadecene-5-Olide, 2-Octadecene-5-Olide, 2-Nonadecene-5-Olide, 2-Eicosene-5-Olide, Lactones such as ε-decalactone; propionic acid, butyric acid, valeric acid, isovaleric acid, caproic acid, trans-2-hexenoic acid, heptanoic acid, caprylic acid, nonanoic acid, 5-hydroxynonanoic acid, capric acid, 2- Decenoic acid, 4-decenoic acid, 5-decenoic acid, 6-decenoic acid, 9-decenoic acid, 5-hydroxydecenoic acid, 5-hydroxyundecane , Fatty acids such as lauric acid, 5-hydroxydodecanoic acid, myristic acid, pentadecanoic acid, isopentadecanoic acid, palmitic acid, heptadecanoic acid, stearic acid, oleic acid, linoleic acid, linolenic acid; trans-2-octena , Trans-2-nonenal, acetaldehyde, propanal, butanal, 2-butenal, hexanal, octanal, 4-heptenal, 2,4-octadienal, nonana , 2-nonenal, 2,4-nonadienal, 2,6-nonadienal, decanal, 2,4-decadienal, 12-methyltridecanal, undecanal, 2, Aldehydes such as 4-undecadienal, dodecanal, benzaldehyde, vanillin, ethyl vanillin, furfural, heliotropin diethyl acetal; Ethyl acetate, ethyl acetate, butyl acetate, isoamyl acetate, decyl acetate, dodecyl acetate, phenethyl acetate, ethyl lactate, ethyl butyrate, ethyl 2-methylbutyrate, ethyl 3-ethylbutyrate, methyl valerate, methyl caproate, ethyl caproate , Methyl heptanoate, ethyl heptanoate, ethyl caprylate, isoamyl caprylate, heptyl caprylate, methyl nonanoate, ethyl nonanoate, methyl caprate, ethyl caprate, ethyl undecanoate, methyl laurate, ethyl laurate, myristine Ethyl acetate, ethyl palmitate, methyl salicylate, diethyl succinate, diethyl sebacate, ethyl 5-hydroxyhexanoate, ethyl 5-hydroxydecanoate, ethyl 5-hydroxyundecanoate, propyl 5-hydroxydecanoate, 5-hydroxy Esters such as isopropyl decanoate, 2-methylpropyl 5-hydroxyoctanoate, ethyl 5-hydroxy-9-methyldecanoate; ethanol, propanol, butanol, pentanol, hexanol, heptanol , Octanols, nonanol, decanol, benzyl alcohol, phenylethyl alcohol, furfuryl alcohol, etc .; furaneol, 2-heptanone, 2-octanone, 3 -Octanone, 1-octen-3-one, 2-nonanone, 3-nonanone, 8-nonen-2-one, 2-undecanone, 2-tridecanone, acetoin, 5-hydroxy-4-octanone, diacetyl, 2,3 -Pentadione, 2,3-hexadione, 2,3-heptadione, acetylisovaleryl, p-methoxyacetopheno , Ketones such as benzophenone, maltol; nitrogen-containing compounds such as phenylethylanthranilate, trimethylamine, indol, skatole, pyridine, isoquinoline, pyrazine, methylpyrazine, 2-acetylpyrroline; methyl mercaptan , Isobutyl mercaptan, 2,4-dithiapentane, dimethyl sulfide, dimethyl disulfide, 2,4-dithiapentane, dimethyl trisulfide, bis (2-methyl-3-furyl) disulfide, dimethyl sulfoxide, dimethyl sulfone, methanethiol, Methylsulfonylmethane, methyl isothiocyanate, ethyl isothiocyanate, allyl isothiocyanate, 2-methyl-3-butanethiol, methional, ethyl thioacetate, methyl thiobutyrate, 3-butenyl ester Thiocyanate, 2-methylthiophene, benzothiazole, sulfur, acetyl lactate thiomethyl ester, propionyl lactate thiomethyl ester, butyryl lactate thiomethyl ester, valeryl lactate thiomethyl ester, 2-methylbutyryl lactate thiomethyl ester, desilyl Known sulfur-containing compounds such as lactate thiomethyl ester, acetyl lactate thioethyl ester, propionyl lactate thioethyl ester, butyryl lactate thioethyl ester, valeryl lactate thioethyl ester, isocaproyl lactate thiopropyl ester, 2-acetyl-2-thiazoline Perfume compound of milk; Lipase degradation product of milk fat; Protease degradation product of milk protein; Milk or milk from milk, concentrated milk, powdered milk, milk whey, butter, cheese, yogurt or mixtures thereof Examples include processed products.
前記香料のうち、特に12−メチルトリデカナール、δ−ヘキサラクトン、δ−オクタラクトン、δ−デカラクトン、δ−ドデカラクトン、δ−テトラデカラクトン、γ−ノナラクトン、γ−デカラクトン、γ−ウンデカラクトンおよびγ−ドデカラクトンから選択される1種または2種以上を用いることは、本発明の粉末油脂組成物によって付与される乳脂感、コクを強化し、ミルクの香味を付与する点で特に有効である。 Among the fragrances, 12-methyltridecanal, δ-hexalactone, δ-octalactone, δ-decalactone, δ-dodecalactone, δ-tetradecalactone, γ-nonalactone, γ-decalactone, γ-undecalactone The use of one or more selected from γ-dodecalactone is particularly effective in enhancing the milk fat feeling and richness imparted by the powdered oil and fat composition of the present invention and imparting the flavor of milk. is there.
また、本発明の粉末油脂組成物には、C4〜C18の脂肪酸を添加することができる。これによって、クリ−ミ−な濃厚感や生乳のようなフレッシュ感をさらに強化することができる。なかでも、酪酸、ヘキサン酸、ラウリン酸、ステアリン酸、およびオレイン酸から選択される1種または2種以上は、本発明の乳化組成物によって付与される乳脂感、コクを強化し、ミルクの香味を付与する点で特に有効である。 Moreover, the C4-C18 fatty acid can be added to the powdery fat composition of this invention. As a result, a creamy rich feeling and a fresh feeling like raw milk can be further enhanced. Among them, one or more selected from butyric acid, hexanoic acid, lauric acid, stearic acid, and oleic acid enhance the milky feeling and richness imparted by the emulsified composition of the present invention, and the flavor of milk. Is particularly effective in terms of imparting.
本発明の粉末油脂組成物には、本発明の効果を妨げない範囲で、その他の水溶性、油溶性の各種成分を配合することもできる。その他の成分としては、例えば、水溶性色素(例えば、食用赤色2号、同3号、同102号、同104号、同105号および第106号;食品黄色4号および同5号;食用緑色3号;食用青色1号および同2号等の合成タール系色素;カカオ色素、クチナシ黄色素、クチナシ青色素、クチナシ緑色素、グレープスキン色素、コチニール色素、紫トウモロコシ色素、紫キャベツ色素、シソ色素、ハイビスカス色素、レッドビート色素、紅花色素、ラック色素、ターメリック色素、カラメル色素等の天然色素);水溶性ビタミン(例えば、ビタミンC、ビタミンB1、ビタミンB2、ビタミンB12、ナイアシン、パントテン酸、葉酸);油溶性ビタミン(例えば、ビタミンA、ビタミンD、ビタミンE、ビタミンK)、油溶性抗酸化剤(例えば、トコフェロ−ル類、ローズマリー抽出物、ビタミンCパルミテ−ト);香料保留剤(例えば、エチレングリコ−ル、プロピレングリコ−ル、ジプロピレングリコ−ル、グリセリン、ヘキシルグリコ−ル、ベンジルベンゾエ−ト、トリエチルシトレ−ト、ジエチルフタレ−ト、ハ−コリン、中鎖脂肪酸トリグリセリド、中鎖脂肪酸ジグリセリド);前記以外の乳化剤、増粘剤、安定剤等を例示することができる。 In the powdered fat composition of the present invention, other water-soluble and oil-soluble various components can be blended as long as the effects of the present invention are not hindered. Other components include, for example, water-soluble pigments (for example, food red No. 2, No. 3, No. 102, No. 104, No. 105 and No. 106; Food Yellow No. 4 and No. 5; Edible Green Synthetic tar dyes such as No. 3; Food Blue No. 1 and No. 2; Cocoa Dye, Gardenia Yellow Dye, Gardenia Blue Dye, Gardenia Green Dye, Grapeskin Dye, Cochineal Dye, Purple Corn Dye, Purple Cabbage Dye, Perilla Dye Natural pigments such as hibiscus pigment, red beet pigment, safflower pigment, lac pigment, turmeric pigment, caramel pigment); water-soluble vitamins (eg vitamin C, vitamin B 1 , vitamin B 2 , vitamin B 12 , niacin, pantothenic acid) Folic acid); oil-soluble vitamins (eg vitamin A, vitamin D, vitamin E, vitamin K), oil-soluble antioxidants (eg Tocopherols, rosemary extract, vitamin C palmitate); perfume retention agents (eg, ethylene glycol, propylene glycol, dipropylene glycol, glycerin, hexyl glycol, benzyl benzoate) , Triethyl citrate, diethyl phthalate, hacholine, medium chain fatty acid triglyceride, medium chain fatty acid diglyceride); emulsifiers, thickeners, stabilizers and the like other than those mentioned above.
本発明の粉末油脂組成物は、水や水系食品に分散させたときの分散粒子の平均粒子径は300〜5000nmであり、特には、1000〜3000nmであることが好ましい。このような平均粒子径を呈することにより、本発明の粉末油脂組成物は、牛乳の水溶液よりも全脂粉乳等の水溶液に添加した際に乳脂感を非常にアップさせるなどの特徴をもたらす。平均粒子径が300nm未満であると、乳脂感、コクが十分に付与されず、ミルク感が損なわれる場合があり、一方、5000nmを超えると、乳脂感、コクが十分に付与されず、油脂の呈味が強くなりすぎる恐れがある。 In the powdered fat composition of the present invention, the average particle size of the dispersed particles when dispersed in water or an aqueous food is 300 to 5000 nm, and particularly preferably 1000 to 3000 nm. By exhibiting such an average particle size, the powdered oil / fat composition of the present invention brings about features such as greatly improving the feeling of milk fat when added to an aqueous solution such as whole milk powder rather than an aqueous solution of milk. If the average particle size is less than 300 nm, the milky feeling and richness may not be sufficiently imparted, and the milky feeling may be impaired. On the other hand, if it exceeds 5000 nm, the milky feeling and richness will not be sufficiently imparted. Taste may be too strong.
前記分散粒子の平均粒子径は、粒子径測定機器を用いて測定すればよく、例えば、堀場製作所社製、レーザ回折/散乱式粒子径分布測定装置 Partica LA−950V2(品名、登録商標)が例示される。 The average particle size of the dispersed particles may be measured using a particle size measuring device, for example, a laser diffraction / scattering type particle size distribution measuring device Partica LA-950V2 (product name, registered trademark) manufactured by HORIBA, Ltd. Is done.
本発明の粉末油脂組成物は、そのまま飲食品にごく微量配合して乳風味を付与または増強することができる。該飲食品は乳成分を含有するものだけではなく、乳成分を含有しないものでもよい。本発明の乳化組成物は、乳成分を含有しない飲食品に添加しても、自然なミルク感、乳脂感、コクを付与することができる。 The powdery fat composition of the present invention can be added to or enhanced as it is by adding a very small amount to the food or drink as it is. The food and drink may not only contain milk components but also may contain no milk components. Even if it adds to the food / beverage products which do not contain a milk component, the emulsion composition of this invention can provide a natural milk feeling, milk fat feeling, and richness.
本発明の粉末油脂組成物の飲食品への配合量は、飲食品の種類や形態によって異なり一概に言えないが、例えば、飲食品の全体質量に対して、0.005〜2質量%の範囲を例示することができる。 Although the compounding quantity to the food / beverage products of the powdered fats and oils composition of this invention changes with kinds and forms of food / beverage products, it cannot say unconditionally, For example, the range of 0.005-2 mass% with respect to the whole mass of food / beverage products Can be illustrated.
本発明の粉末油脂組成物によって乳風味を付与することのできる飲食品の具体例としては何ら限定されるものではなく、例えば、コ−ラ飲料、果汁入炭酸飲料、乳類入炭酸飲料等の炭酸飲料類;果汁飲料、野菜飲料、スポ−ツドリンク、ハチミツ飲料、豆乳、ビタミン補給飲料、ミネラル補給飲料、栄養ドリンク、滋養ドリンク、乳酸菌飲料、乳飲料、ヨーグルト飲料等の食系飲料類;緑茶、紅茶、ウ−ロン茶、ハ−ブティ−、コーヒー飲料、ココア等の嗜好飲料類;チュ−ハイ、カクテルドリンク、発泡酒、果実酒、薬味酒等のアルコ−ル飲料類;バタ−、チ−ズ、ホイップクリーム、ミルク、脱脂粉乳、ヨ−グルト等の乳原料;アイスクリ−ム、ラクトアイス、氷菓、ヨ−グルト、プリン、ゼリ−、デイリ−デザ−ト等のデザ−ト類およびそれらを製造するためのミックス類;キャラメル、キャンディ−、錠菓、ホットケーキ、クラッカ−、ビスケット、クッキ−、パイ、チョコレ−ト、スナック等の菓子類およびそれらを製造するためのケ−キミックス等のミックス類;パン、ス−プ、ホワイトソース、各種インスタント食品等の一般食品類;を挙げることができる。 It is not limited at all as a specific example of the food / beverage products which can provide milk flavor by the powdered oil-fat composition of this invention, For example, a drink, carbonated drink containing fruit juice, carbonated drink containing milk, etc. Carbonated drinks; Fruit drinks, vegetable drinks, sports drinks, honey drinks, soy milk, vitamin supplement drinks, mineral supplement drinks, nutrition drinks, nourishing drinks, lactic acid bacteria drinks, milk drinks, yogurt drinks, and other food drinks; green tea , Black tea, oolong tea, herb tea, coffee beverages, cocoa and other favorite beverages; Chu-hai, cocktail drinks, sparkling liquor, fruit liquor, condiments, etc .; alcoholic beverages; butter, chi -Milk ingredients such as cream, whipped cream, milk, skim milk powder, yogurt; desserts such as ice cream, lact ice, ice confectionery, yogurt, pudding, jelly, daily dessert Mixes for producing them; caramels, candy, tablet confectionery, hot cakes, crackers, biscuits, cookie, pie, chocolate, snacks, etc. and cake mixes for producing them And general foods such as bread, soup, white sauce and various instant foods.
本発明が提供する粉末油脂組成物の製造方法は、必ずしも限定はされないが、好ましい製造方法としては、例えば、以下の各ステップを有する方法、すなわち、
a)水に、乳化剤、賦形剤等の水溶性成分を加えて60〜70℃で溶解し、水相部とするステップ、b)前記水相部を70〜75℃で15〜30分間程度、加熱殺菌し、その後、30〜70℃に冷却するステップ、c)前記冷却した水相部にラウリン酸系油脂、C4〜C18の脂肪酸、香料、油溶性抗酸化剤等の油溶性成分を30〜70℃で加えるステップ、d)前記油溶性成分と水相部とを乳化するため、T.K.ホモミクサー(プライミクス社製)等の高速回転式の撹拌機を用いて6000〜12000rpmで10〜30分間撹拌して、水中油型乳化組成物を調製するステップ、e)前記調製した水中油型乳化組成物を噴霧乾燥機で噴霧乾燥し、篩別して、本発明の粉末油脂組成物を得るステップ、を有する方法が例示される。噴霧乾燥、篩別して得た本発明の粉末油脂組成物の平均粒子径は、一般には、飲食品への溶解性等を考慮すると、50〜200μmが適当である。なお、本発明の粉末油脂組成物には、噴霧乾燥、篩別して得られた粉末をさらに凝集させて造粒化したものも含まれる。
Although the manufacturing method of the powdery fat composition provided by the present invention is not necessarily limited, as a preferable manufacturing method, for example, a method having the following steps, that is,
a) Step of adding water-soluble components such as emulsifiers and excipients to water and dissolving at 60 to 70 ° C. to form an aqueous phase portion, b) The aqueous phase portion at 70 to 75 ° C. for about 15 to 30 minutes Sterilization by heating, and then cooling to 30 to 70 ° C., c) 30 oil-soluble components such as lauric acid fat, C4 to C18 fatty acid, fragrance, oil-soluble antioxidant in the cooled water phase part A step of adding at ˜70 ° C., d) in order to emulsify the oil-soluble component and the aqueous phase, K. Step of preparing an oil-in-water emulsion composition by stirring at 6000 to 12000 rpm for 10 to 30 minutes using a high-speed rotating stirrer such as a homomixer (manufactured by Primix) e) The oil-in-water emulsion composition prepared above The method includes the steps of spray-drying the product with a spray dryer and sieving to obtain the powdered fat and oil composition of the present invention. In general, the average particle size of the powdery fat composition of the present invention obtained by spray drying and sieving is suitably 50 to 200 μm in view of solubility in food and drink. The powdered fat composition of the present invention includes those obtained by further agglomerating and granulating powder obtained by spray drying and sieving.
以下に実施例を挙げ、本発明を更に詳細に説明する。
[油脂の比較]
[実施例1]
軟水160gに加工デンプン40gおよびトレハロース120gを60〜70℃で溶解させ、70〜75℃で15分間、加熱殺菌した後、40〜50℃に冷却した。その後、これにヤシ・パーム混合加工油脂(日油社製、融点約38℃、品名:スーパーヌーコアH)40g、市販ビタミンE0.4gを40〜50℃で加え、混合した。次いで、この混合液を、T.K.ホモミクサーを用いて8000rpmで10分間撹拌して水中油型乳化組成物を作製した後、スプレードライヤーL−8型(大川原化工機社製)で噴霧乾燥(送風温度:150℃)し、粉末油脂組成物174gを得た(発明品1)。
The following examples further illustrate the present invention.
[Comparison of oils and fats]
[Example 1]
40 g of modified starch and 120 g of trehalose were dissolved in 160 g of soft water at 60 to 70 ° C., sterilized by heating at 70 to 75 ° C. for 15 minutes, and then cooled to 40 to 50 ° C. Thereafter, 40 g of palm / palm mixed processed oil (manufactured by NOF Corporation, melting point: about 38 ° C., product name: Super Nucoa H) and 0.4 g of commercially available vitamin E were added at 40-50 ° C. and mixed. Then, this mixed solution was treated with T.W. K. After stirring for 10 minutes at 8000 rpm using a homomixer, an oil-in-water emulsion composition was prepared, and then spray-dried (blowing temperature: 150 ° C.) with a spray dryer L-8 (Okawara Kako Co., Ltd.) to obtain a powdered fat composition 174 g of product was obtained (Invention 1).
[実施例2]
ヤシ・パーム混合加工油脂40gに代えて、精製パーム核油40g(不二製油社製、融点約25℃)を使用するほかは実施例1と同様の手順に従い、粉末油脂組成物174gを得た(発明品2)。
[Example 2]
174 g of a powdered oil / fat composition was obtained according to the same procedure as in Example 1 except that 40 g of refined palm kernel oil (manufactured by Fuji Oil Co., Ltd., melting point: about 25 ° C.) was used instead of 40 g of palm / palm mixed processed oil / fat. (Invention 2).
[実施例3]
ヤシ・パーム混合加工油脂40gに代えて、精製ヤシ油40g(日清オイリオグループ社製、融点約25℃)を使用するほかは実施例1と同様の手順に従い、粉末油脂組成物174gを得た(発明品3)。
[Example 3]
174 g of a powdered oil / fat composition was obtained according to the same procedure as in Example 1 except that 40 g of refined palm oil (manufactured by Nisshin Oillio Group, melting point: about 25 ° C.) was used instead of 40 g of the palm / palm mixed processed oil / fat. (Invention 3).
[実施例4]
ヤシ・パーム混合加工油脂40gに代えて、硬化ヤシ油40g(日清オイリオグループ社製、融点約31℃、品名:やし硬化油34)を使用するほかは実施例1と同様の手順に従い、粉末油脂組成物174gを得た(発明品4)。
[Example 4]
According to the same procedure as in Example 1, except that 40 g of hardened palm oil (manufactured by Nisshin Oillio Group, melting point: about 31 ° C., product name: palm hardened oil 34) is used instead of 40 g of palm-palm mixed processed oil and fat, 174 g of a powdered oil / fat composition was obtained (Invention 4).
[比較例1]
ヤシ・パーム混合加工油脂40gに代えて、精製パーム油40g(日清オイリオグループ社製、融点約38℃、品名:デリカプレミアム)を使用するほかは実施例1と同様の手順に従い、粉末油脂組成物174gを得た(比較品1)。
[Comparative Example 1]
Powdered fat composition according to the same procedure as in Example 1 except that 40 g of refined palm oil (manufactured by Nisshin Oillio Group, melting point: about 38 ° C., product name: Delica Premium) is used instead of 40 g of palm / palm mixed processed fat / oil. 174 g of product was obtained (Comparative product 1).
[比較例2]
ヤシ・パーム混合加工油脂40gに代えて、大豆硬化油40g(日清オイリオグループ社製、融点約30℃、品名:大豆硬化油34)を使用するほかは実施例1と同様の手順に従い、粉末油脂組成物174gを得た(比較品2)。
[Comparative Example 2]
According to the same procedure as in Example 1, except that 40 g of mixed palm oil and palm oil is used, 40 g of soybean hardened oil (manufactured by Nisshin Oillio Group, melting point of about 30 ° C., product name: soybean hardened oil 34) is used. 174 g of an oil and fat composition was obtained (Comparative product 2).
[比較例3]
ヤシ・パーム混合加工油脂40gに代えて、菜種硬化油40g(日清オイリオグループ社製、融点約33℃、品名:菜種硬化油34)を使用するほかは実施例1と同様の手順に従い、粉末油脂組成物174gを得た(比較品3)。
[Comparative Example 3]
Powdered rapeseed oil 40 g (manufactured by Nisshin Oillio Group, melting point: about 33 ° C., product name: rapeseed hardened oil 34) was used in place of 40 g of the palm-palm mixed processed oil and fat. 174 g of an oil and fat composition was obtained (Comparative product 3).
[比較例4]
ヤシ・パーム混合加工油脂40gに代えて、MCT(中鎖脂肪酸グリセリンエステル)40g(日清オイリオグループ社製、品名:ODO)を使用するほかは実施例1と同様の手順に従い、粉末油脂組成物174gを得た(比較品4)。
[Comparative Example 4]
According to the same procedure as in Example 1, except that 40 g of MCT (medium chain fatty acid glycerin ester) (manufactured by Nisshin Oillio Group, product name: ODO) is used instead of 40 g of the palm-palm mixed processed oil and fat, 174 g was obtained (Comparative product 4).
[比較例5]
ヤシ・パーム混合加工油脂40gに代えて、市販無塩バター40g(雪印メグミルク社製)を使用するほかは実施例1と同様の手順に従い、粉末油脂組成物174gを得た(比較品5)。
[Comparative Example 5]
174 g of a powdered oil / fat composition was obtained according to the same procedure as in Example 1 except that 40 g of commercially available unsalted butter (manufactured by Snow Brand Megmilk) was used instead of 40 g of the palm / palm mixed processed oil / fat (Comparative Product 5).
(官能評価)
市販牛乳20%水溶液および市販ミルク入り粉末コーヒー(原材料:インスタントコーヒー、植物油脂、脱脂粉乳、砂糖など)7%水溶液に発明品1〜4および比較品1〜5をそれぞれ0.1%添加・賦香し、その香味について、6名のパネルによる官能評価を行った。結果を表2、表3に示す。なお、前記原材料を用いて作製した水中油型乳化組成物の配合組成を表1に示す。
(sensory evaluation)
Addition and supplement of 0.1% of inventive products 1 to 4 and comparative products 1 to 5 to 7% aqueous solution of 20% aqueous solution of commercially available milk and powdered coffee containing milk (raw materials: instant coffee, vegetable oils and fats, skim milk powder, sugar, etc.) Scented and the sensory evaluation by the panel of six persons was performed about the flavor. The results are shown in Tables 2 and 3. Table 1 shows the composition of the oil-in-water emulsion composition produced using the raw materials.
表2、3の結果から明らかなように、牛乳20%水溶液、ミルク入り粉末コーヒー7%水溶液のいずれの場合でも、発明品1〜4は乳脂感、コクの増加が認められ、また、生乳と同様のミルク感が得られた。特に発明品1はその効果が顕著に認められた。
一方、比較品1〜5はいずれも乳脂感、コクの増加は感じられず、また、ミルク感も得られなかった。また、比較品1では牛乳とは異なる風味が感じられた。
以上の結果から、油脂のうち、ヤシ・パーム混合加工油脂、精製パーム核油、精製ヤシ油、硬化ヤシ油は、使用した乳化組成物を乳含有製品に添加することにより、乳脂感、コク、ミルク感を増加することができることが確認された。特にヤシ・パーム混合加工油脂はその効果が顕著であった。
As is apparent from the results of Tables 2 and 3, in any case of the 20% milk aqueous solution and the 7% aqueous coffee powder containing milk, the inventive products 1 to 4 showed increased milk fat feeling and richness. Similar milk feeling was obtained. In particular, the effect of the invention product 1 was remarkably recognized.
On the other hand, all of Comparative products 1 to 5 did not feel milky fat feeling and richness, and milk feeling was not obtained. Moreover, the flavor different from milk was felt in the comparative product 1.
From the above results, among the fats and oils, palm-palm mixed processed fats and oils, refined palm kernel oil, refined palm oil, and hardened palm oil are added to the milk-containing product by using the emulsified composition, thereby providing a sense of milk fat, richness, It was confirmed that the milk feeling can be increased. In particular, the effect of the mixed oil of palm and palm was remarkable.
[粉末油脂組成物の用途・効果確認]
[実施例5]
軟水160gに加工デンプン40gおよびトレハロース80gを60〜70℃で溶解した後、70〜75℃で15分間、加熱殺菌した後、40〜50℃に冷却した。その後、これにヤシ・パーム混合加工油脂(日油社製、スーパーヌーコアH、融点約38℃、登録商標)80g、市販ビタミンE0.4gを40〜50℃で加え、混合した。次いで、この混合液を、T.K.ホモミクサーを用いて8000rpmで10分間撹拌して水中油型乳化組成物を作製した後、スプレードライヤーL−8型(大川原化工機社製)で噴霧乾燥(送風温度:150℃)し、粉末油脂組成物170gを得た(発明品5)。
[Use and effect confirmation of powdered oil composition]
[Example 5]
40 g of modified starch and 80 g of trehalose were dissolved in 160 g of soft water at 60 to 70 ° C., then heat sterilized at 70 to 75 ° C. for 15 minutes, and then cooled to 40 to 50 ° C. Thereafter, 80 g of palm / palm mixed processed oil (manufactured by NOF Corporation, Super Nucor H, melting point: about 38 ° C., registered trademark) and 0.4 g of commercially available vitamin E were added at 40 to 50 ° C. and mixed. Then, this mixed solution was treated with T.W. K. After stirring for 10 minutes at 8000 rpm using a homomixer, an oil-in-water emulsion composition was prepared, and then spray-dried (blowing temperature: 150 ° C.) with a spray dryer L-8 (Okawara Kako Co., Ltd.) to obtain a powdered fat composition 170 g of product was obtained (Invention 5).
[実施例6]
ヤシ・パーム混合加工油脂80gにミルク香料A(長谷川香料社製)を加えて使用するほかは実施例5と同様の手順に従い、粉末油脂組成物170gを得た(発明品6)。
[Example 6]
According to the same procedure as in Example 5, except that milk flavor A (manufactured by Hasegawa Fragrance Co., Ltd.) was added to 80 g of palm / palm mixed processed fat / oil, 170 g of powdered fat / oil composition was obtained (Invention 6).
[実施例7]
ヤシ・パーム混合加工油脂80gにコーン香料B(長谷川香料社製)を加えて使用するほかは実施例5と同様の手順に従い、粉末油脂組成物170gを得た(発明品7)。
[Example 7]
According to the same procedure as in Example 5, except that corn flavor B (manufactured by Hasegawa Fragrance) was added to 80 g of palm / palm mixed processed fat and oil, 170 g of powdered fat and oil composition was obtained (Invention Product 7).
[実施例8]
ヤシ・パーム混合加工油脂80gにバター香料C(長谷川香料社製)を加えて使用するほかは実施例5と同様の手順に従い、粉末油脂組成物170gを得た(発明品8)。
[Example 8]
According to the same procedure as in Example 5 except that butter flavor C (manufactured by Hasegawa Fragrance Co., Ltd.) was added to 80 g of palm / palm mixed processed fat / oil, 170 g of powdered fat / oil composition was obtained (Invention 8).
[比較例6]
ヤシ・パーム混合加工油脂80gに代えて、MCT80gを使用するほかは実施例5と同様の手順に従い、粉末油脂組成物170gを得た(比較品6)。
[Comparative Example 6]
170 g of a powdered oil / fat composition was obtained in accordance with the same procedure as in Example 5 except that 80 g of MCT was used instead of 80 g of the palm / palm mixed processed oil / fat (Comparative Product 6).
[比較例7]
ヤシ・パーム混合加工油脂80gに代えて、MCT80gを使用し、さらにミルク香料Aを加えて使用するほかは実施例5と同様の手順に従い、粉末油脂組成物170gを得た(比較品7)。
[Comparative Example 7]
170 g of a powdered oil / fat composition was obtained in accordance with the same procedure as in Example 5 except that 80 g of MCT was used instead of 80 g of the palm / palm mixed processed oil / fat, and milk perfume A was added.
[比較例8]
ヤシ・パーム混合加工油脂80gに代えて、MCT80gを使用し、さらにコーン香料Bを加えて使用するほかは実施例5と同様の手順に従い、粉末油脂組成物170gを得た(比較品8)。
[Comparative Example 8]
170 g of powdered oil / fat composition was obtained in accordance with the same procedure as in Example 5 except that 80 g of MCT was used instead of 80 g of palm / palm mixed processed oil / fat and corn flavor B was added.
[比較例9]
ヤシ・パーム混合加工油脂80gに代えて、MCT80gを使用し、さらにバター香料Cを加えて使用するほかは実施例5と同様の手順に従い、粉末油脂組成物170gを得た(比較品9)。
[Comparative Example 9]
170 g of a powdered oil / fat composition was obtained in accordance with the same procedure as in Example 5 except that 80 g of MCT was used instead of 80 g of palm / palm mixed processed oil / fat and Butter Fragrance C was added.
[官能評価]
(粉末ココア飲料)
市販の粉末ココア飲料(カカオバター約23%、植物油脂、全粉乳などを含む)15gを熱水100gで溶解し、これに発明品5、6および比較品6、7をそれぞれ0.1%添加・賦香した。さらに、粉末油脂組成物を添加しない無添加品(参考品1)を同様の手順で調製した。これらのココア飲料の香味について、10名のパネルによる官能評価を行った。結果を表4に示す。
[sensory evaluation]
(Powdered cocoa drink)
15 g of commercially available powdered cocoa beverage (including cacao butter, about 23%, vegetable oil and fat, whole milk powder, etc.) is dissolved in 100 g of hot water, and invention products 5, 6 and comparative products 6, 7 are added to each 0.1%・ Scented. Furthermore, an additive-free product (reference product 1) to which no powdered oil / fat composition was added was prepared in the same procedure. The sensory evaluation by the panel of 10 persons was performed about the flavor of these cocoa drinks. The results are shown in Table 4.
表4の結果から明らかなように、本発明の粉末油脂組成物を添加した発明品5、6は乳脂感、コクが付与されており、特にミルク香料を添加した発明品6はミルクの香気がアップしていた。
一方、本発明の粉末油脂組成物とは異なる粉末油脂組成物を添加した比較品6、7はミルクの乳脂感、コクが付与されておらず、粉末油脂組成物とミルク香料を添加していない参考品1は、ミルクの濃厚感が弱かった。
As is apparent from the results in Table 4, the inventive products 5 and 6 to which the powdered oil and fat composition of the present invention has been added are given a milky feeling and richness. In particular, the inventive product 6 to which the milk flavor has been added has a milk aroma. It was up.
On the other hand, Comparative products 6 and 7 to which a powdered fat composition different from the powdered fat composition of the present invention is added are not imparted with milky fat feeling and richness, and the powdered fat composition and milk flavor are not added. Reference product 1 was weak in milk.
(粉末コーンクリームスープ)
市販のコーンクリームスープ粉末10gを熱水150gで溶解し、これに発明品5、7および比較品6、8をそれぞれ0.1%添加・賦香した。さらに、粉末油脂組成物を添加しない無添加品(参考品2)を同様の手順で調製した。これらのコーンクリームスープの香味について、10名のパネルによる官能評価を行った。結果を表5に示す。
(Powdered corn cream soup)
Commercially available corn cream soup powder (10 g) was dissolved in hot water (150 g), and invention products 5 and 7 and comparative products 6 and 8 were each added and flavored at 0.1%. Furthermore, an additive-free product (reference product 2) to which no powdered oil / fat composition was added was prepared in the same procedure. About the flavor of these corn cream soups, sensory evaluation by 10 panels was performed. The results are shown in Table 5.
表5の結果から明らかなように、本発明の粉末油脂組成物を添加した発明品5、7は乳脂感、コクが付与されており、特にコーン香料を添加した発明品7はコーンの香気がアップしていた。
一方、本発明の粉末油脂組成物とは異なる粉末油脂組成物を添加した比較品6、8はミルクの乳脂感、コクが付与されておらず、粉末油脂組成物とコーン香料を添加していない参考品2は、コーンの香気とミルクの風味が弱かった。
As apparent from the results in Table 5, the inventive products 5 and 7 to which the powdered oil composition of the present invention was added have a milky feeling and richness, and the inventive product 7 to which the corn flavor has been added particularly has a corn aroma. It was up.
On the other hand, Comparative products 6 and 8 to which a powdered fat composition different from the powdered fat composition of the present invention is added are not imparted with milky fat feeling and richness, and the powdered fat composition and corn flavor are not added. Reference product 2 had weak corn flavor and milk flavor.
(ホットケーキ)
市販のホットケーキミックス65g、牛乳60gに発明品5、8、比較品6、9をそれぞれ0.1%添加・賦香し、良く撹拌して生地を調製した。次いで、フライパンで該生地の両面を各3分ずつ焼いて、ホットケーキを作製した。さらに、粉末油脂組成物を添加しない無添加品(参考品3)を同様の手順で調製し、同様の手順でホットケーキを作製した。これらのホットケーキの香味について、10名のパネルによる官能評価を行った。結果を表6に示す。
(Pancake)
Inventive products 5 and 8 and comparative products 6 and 9 were added and flavored to 65 g of commercially available hot cake mix and 60 g of milk, respectively, and the dough was prepared by stirring well. Next, both sides of the dough were baked for 3 minutes each in a frying pan to prepare a hot cake. Furthermore, an additive-free product (reference product 3) to which no powdered oil / fat composition was added was prepared in the same procedure, and a hot cake was prepared in the same procedure. About the flavor of these hot cakes, sensory evaluation by 10 panels was performed. The results are shown in Table 6.
表6の結果から明らかなように、本発明の粉末油脂組成物を添加した発明品5、8は乳脂感、コクが付与されており、特にバター香料を添加した発明品8はバターの香気がアップしていた。
一方、本発明の粉末油脂組成物とは異なる粉末油脂組成物を添加した比較品6、9はミルクの乳脂感、コクが付与されておらず、粉末油脂組成物とバター香料を添加していない参考品3は、あっさりとし、濃厚感やコクが弱かった。
As is apparent from the results in Table 6, Inventions 5 and 8 to which the powdered oil composition of the present invention was added have a milky feeling and richness. In particular, Invention 8 to which a butter fragrance was added has a butter aroma. It was up.
On the other hand, Comparative Products 6 and 9 to which a powdered fat composition different from the powdered fat composition of the present invention was added were not given milky fat feeling and richness, and the powdered fat composition and butter flavor were not added. Reference product 3 was light and rich and rich.
Claims (14)
(A)ラウリン酸系油脂
(B)乳化剤
(C)賦形剤
(D)水 A powdery fat composition for imparting milk flavor containing the following components (A) to (D).
(A) Lauric acid oil (B) Emulsifier (C) Excipient (D) Water
(A)ラウリン酸系油脂
(B)乳化剤
(C)賦形剤
(D)水 A powdery fat composition for imparting milk flavor obtained by spray-drying an oil-in-water emulsion composition containing the following components (A) to (D).
(A) Lauric acid oil (B) Emulsifier (C) Excipient (D) Water
a)水に、乳化剤、賦形剤を加えて溶解し、水相部とするステップ、
b)前記水相部を加熱殺菌し、その後、30〜70℃に冷却するステップ、
c)前記冷却した水相部にラウリン酸系油脂を30〜70℃で加え、撹拌して、水中油型乳化組成物を調製するステップ、
d)前記調製した水中油型乳化組成物を噴霧乾燥させて粉末乾燥化して、乳風味付与用粉末油脂組成物を製造するステップ。 The manufacturing method of the powdery oil-fat composition for milk flavor provision which has the following steps.
a) a step of adding an emulsifier and an excipient to water and dissolving it to form an aqueous phase,
b) heat sterilizing the aqueous phase and then cooling to 30-70 ° C;
c) A step of adding an oil-in-water emulsified composition to the cooled aqueous phase portion by adding lauric acid oil at 30 to 70 ° C. and stirring.
d) A step of producing a powdery fat composition for imparting milk flavor by spray drying the prepared oil-in-water emulsion composition and powder-drying.
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