JP2015168629A - Oil-in-water emulsified cosmetic - Google Patents
Oil-in-water emulsified cosmetic Download PDFInfo
- Publication number
- JP2015168629A JP2015168629A JP2014042770A JP2014042770A JP2015168629A JP 2015168629 A JP2015168629 A JP 2015168629A JP 2014042770 A JP2014042770 A JP 2014042770A JP 2014042770 A JP2014042770 A JP 2014042770A JP 2015168629 A JP2015168629 A JP 2015168629A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- component
- sucrose
- water
- skin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 52
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Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、ジラウロイルグルタミン酸リシンナトリウム、HLBが14以上のショ糖脂肪酸エステル及び/又はポリオキシエチレンステロールエーテル、HLBが4以下のショ糖脂肪酸エステル、グリセリン及び/又は1,3−ブチレングリコール、油剤並びに水を含有する水中油型乳化化粧料において、HLBが14以上のショ糖脂肪酸エステル及び/又はポリオキシエチレンステロールエーテルとHLBが4以下のショ糖脂肪酸エステルとを特定量比含有し、乳化粒子の粒径が1μm以下であることを特徴とする水中油型乳化組成物に関するものであり、更に詳しくは、みずみずしい使用感で肌なじみがよく、しかも肌のハリ感と保湿効果が長時間持続する水中油型乳化化粧料に関するものである。 The present invention relates to sodium lauryl dilauroylglutamate, sucrose fatty acid ester and / or polyoxyethylene sterol ether having an HLB of 14 or more, sucrose fatty acid ester having an HLB of 4 or less, glycerin and / or 1,3-butylene glycol, oil agent In addition, an oil-in-water emulsified cosmetic containing water contains a sucrose fatty acid ester having an HLB of 14 or more and / or a polyoxyethylene sterol ether and a sucrose fatty acid ester having an HLB of 4 or less, and contains emulsified particles. The oil-in-water emulsified composition is characterized by having a particle size of 1 μm or less. More specifically, the skin feels good with a fresh feeling of use, and the skin firmness and moisturizing effect lasts for a long time. The present invention relates to an oil-in-water emulsified cosmetic.
従来、化粧料に保湿効果を付与する目的でグリセリンや1,3−ブチレングリコール等の多価アルコールや水溶性高分子を多量に配合する方法が用いられていた。しかし、これらを多量に配合するとべたつき感が生じるという欠点があった。また、肌のハリ感を得る目的でペースト状の油剤や固体の油剤を多量に配合する方法が開示されている(特許文献1参照)。しかし、これらを多量に配合すると肌のハリ感は向上するものの、べたつき感や肌へのなじみの悪さが感じられるようになるという欠点があり、依然として肌のハリ感と良好な使用感を有する乳化化粧料の開発が望まれている。
ところで、乳化粒子の粒径を微細にするために、高圧乳化機等の機械力を用いて乳化粒子径を細かくする技術が知られている(特許文献2及び3参照)。しかしながら、高圧乳化機は乳化物の粘度が高い場合には高圧乳化機を通らない恐れがあり、乳化粒子径のばらつきを生じる場合がある。そのため、特別な装置を使わなくても乳化粒子径を1μm以下に小さくする技術開発が望まれている。
Conventionally, a method of blending a large amount of a polyhydric alcohol such as glycerin or 1,3-butylene glycol or a water-soluble polymer has been used for the purpose of imparting a moisturizing effect to cosmetics. However, when these are mixed in a large amount, there is a drawback that a sticky feeling is generated. Moreover, a method of blending a large amount of a paste-like oil agent or a solid oil agent for the purpose of obtaining a firm feeling of the skin has been disclosed (see Patent Document 1). However, blending these in a large amount improves the firmness of the skin, but it has the disadvantage that it feels sticky and unfamiliar to the skin, and it still has a firmness and a good feeling of use. Development of cosmetics is desired.
By the way, in order to make the particle size of the emulsified particles fine, there is known a technique for reducing the particle size of the emulsified particles using mechanical force such as a high-pressure emulsifier (see Patent Documents 2 and 3). However, when the viscosity of the emulsion is high, the high-pressure emulsifier may not pass through the high-pressure emulsifier, and the emulsion particle size may vary. Therefore, it is desired to develop a technology for reducing the emulsified particle diameter to 1 μm or less without using a special apparatus.
そこで、みずみずしい使用感で肌なじみがよく、しかも肌のハリ感と保湿効果が長時間持続する水中油型乳化化粧料を提供することを課題とする。 Therefore, it is an object to provide an oil-in-water emulsified cosmetic that has a fresh feeling of use and is well-familiar with the skin, and that has a firmness and a moisturizing effect for a long time.
かかる実情に鑑み、本発明者らは鋭意検討した結果、ジラウロイルグルタミン酸リシンナトリウム、HLBが14以上のショ糖脂肪酸エステル及び/又はポリオキシエチレンステロールエーテル、HLBが4以下のショ糖脂肪酸エステル、グリセリン及び/又は1,3−ブチレングリコール、油剤、水を含有し、更に乳化粒子の粒径が1μm以下であることを特徴とする水中油型乳化化粧料が、前記課題を解決することを見出し、本発明を完成した。 In view of such a situation, the present inventors have conducted intensive studies, and as a result, dilauroyl glutamic acid lysine sodium, HLB 14 or more sucrose fatty acid ester and / or polyoxyethylene sterol ether, HLB 4 or less sucrose fatty acid ester, glycerin And / or 1,3-butylene glycol, an oil agent, water, and the oil-in-water emulsified cosmetic characterized in that the particle size of the emulsified particles is 1 μm or less has been found to solve the above problems. The present invention has been completed.
すなわち本発明は、次の成分(a)〜(f);
(a)ジラウロイルグルタミン酸リシンナトリウム
(b)HLBが14以上のショ糖脂肪酸エステル及び/又はポリオキシエチレンステロールエーテル
(c)HLBが4以下のショ糖脂肪酸エステル
(d)グリセリン及び/又は1,3−ブチレングリコール
(e)油剤
(f)水
を含有し、成分(b)及び(c)の総含有量が0.8〜4質量%であり、その含有量比が、質量比で1:0.1〜1:1の範囲であり、更に乳化粒子の粒径が1μm以下であることを特徴とする水中油型乳化化粧料を提供するものである。
That is, the present invention comprises the following components (a) to (f);
(A) Sodium dilauroylglutamate ricin (b) sucrose fatty acid ester having an HLB of 14 or more and / or polyoxyethylene sterol ether (c) sucrose fatty acid ester having an HLB of 4 or less (d) glycerin and / or 1,3 -Butylene glycol (e) oil agent (f) It contains water, the total content of components (b) and (c) is 0.8 to 4% by mass, and the content ratio is 1: 0 by mass. The present invention provides an oil-in-water emulsified cosmetic that is in the range of 1 to 1: 1 and that the particle size of the emulsified particles is 1 μm or less.
また本発明は、成分(b)が、ショ糖パルミチン酸エステル、ショ糖ステアリン酸エステル、ポリオキシエチレン(20)フィトステロール及びポリオキシエチレン(25)フィトスタノールから選ばれる一種又は二種以上である、上記水中油型乳化化粧料を提供する。 In the present invention, the component (b) is one or more selected from sucrose palmitate, sucrose stearate, polyoxyethylene (20) phytosterol and polyoxyethylene (25) phytostanol, The oil-in-water emulsified cosmetic is provided.
また本発明は、成分(c)が、ショ糖ペンタヒドロキシステアリン酸エステルである、上記水中油型乳化化粧料を提供する。 Moreover, this invention provides the said oil-in-water type emulsion cosmetic whose component (c) is sucrose pentahydroxystearic acid ester.
本発明の水中油型乳化化粧料は、みずみずしい使用感で肌なじみがよく、しかも肌のハリ感と保湿効果が長時間持続する水中油型乳化化粧料である。 The oil-in-water emulsified cosmetic of the present invention is an oil-in-water emulsified cosmetic that has a fresh feeling of use and is well-familiar with the skin, and also has a firmness and moisturizing effect for a long time.
本発明に用いられる成分(a)ジラウロイルグルタミン酸リシンナトリウムは、本発明の水中油型乳化化粧料において、安定性に優れた乳化剤として機能するものであり、通常の化粧料に用いられるジラウロイルグルタミン酸リシンナトリウムであれば何れのものも用いることができる。ジラウロイルグルタミン酸リシンナトリウムは市販品を用いることが可能であり、市販されている旭化成ケミカルズ株式会社製のペリセアLB−10、ペリセア−30を用いることができる。ペリセアLB−10は、ジラウロイルグルタミン酸リシンナトリウム10%、1,3−ブチレングリコール10%、水80%で構成され、ペリセアL−30は、ジラウロイルグルタミン酸リシンナトリウム29%、水71%で構成される。 The component (a) lysine sodium dilauroyl glutamate used in the present invention functions as an emulsifier having excellent stability in the oil-in-water emulsified cosmetic of the present invention, and dilauroyl glutamic acid used in ordinary cosmetics. Any lysine sodium can be used. Commercially available dilauroyl glutamate lysine sodium can be used, and commercially available Perisea LB-10 and Perisea-30 manufactured by Asahi Kasei Chemicals Corporation can be used. Perisea LB-10 is composed of 10% lysine sodium dilauroylglutamate, 10% 1,3-butylene glycol and 80% water, and Perisea L-30 is composed of 29% lysine sodium dilauroylglutamate and 71% water. The
本発明の水中油型乳化化粧料における成分(a)の含有量は、0.1〜0.9質量%(以下、単に「%」と略す。)が好ましく、0.2〜0.6%がより好ましい。成分(a)の含有量がこの範囲であると、より乳化力と経時安定性に優れる水中油型乳化化粧料を得ることができる。 The content of the component (a) in the oil-in-water emulsified cosmetic of the present invention is preferably 0.1 to 0.9% by mass (hereinafter simply referred to as “%”), and is 0.2 to 0.6%. Is more preferable. When the content of the component (a) is within this range, an oil-in-water emulsified cosmetic with better emulsifying power and stability over time can be obtained.
本発明に用いられる成分(b)HLBが14以上のショ糖脂肪酸エステル及び/又はポリオキシエチレンステロールエーテルは、本発明の水中油型乳化化粧料において、乳化剤として機能するものであり、通常の化粧料に用いられるものであれば何れのものも用いることができる。具体的には、ショ糖ラウリン酸エステル、ショ糖ミリスチン酸エステル、ショ糖パルミチン酸エステル、ショ糖ステアリン酸エステル、ショ糖オレイン酸エステル、ポリオキシエチレン(20)フィトステロール、ポリオキシエチレン(30)フィトステロール、ポリオキシエチレン(25)フィトスタノール等が挙げられ、これらを一種又は二種以上用いることができる。これらの中でも、成分(b)として、ショ糖パルミチン酸エステル、ショ糖ステアリン酸エステル、ポリオキシエチレン(20)フィトステロール及びポリオキシエチレン(25)フィトスタノールから選ばれる一種又は二種以上を選択すると、より微細な乳化粒子を得易く、経時安定性が良好な水中油型乳化化粧料を得ることができる。尚、本発明における界面活性剤のHLB値は、下記に示すグリフィンの式により算出される値である。
HLB値=(親水基部分の分子量/界面活性剤の分子量)×20
The component (b) sucrose fatty acid ester and / or polyoxyethylene sterol ether having 14 or more HLB used in the present invention functions as an emulsifier in the oil-in-water emulsified cosmetic of the present invention. Any material can be used as long as it is used as a material. Specifically, sucrose laurate, sucrose myristic ester, sucrose palmitate, sucrose stearate, sucrose oleate, polyoxyethylene (20) phytosterol, polyoxyethylene (30) phytosterol , Polyoxyethylene (25) phytostanol, and the like, and one or more of them can be used. Among these, as component (b), when one or more selected from sucrose palmitate, sucrose stearate, polyoxyethylene (20) phytosterol and polyoxyethylene (25) phytostanol are selected, It is easy to obtain finer emulsified particles, and an oil-in-water emulsified cosmetic with good temporal stability can be obtained. The HLB value of the surfactant in the present invention is a value calculated by the following Griffin equation.
HLB value = (molecular weight of hydrophilic group portion / molecular weight of surfactant) × 20
ショ糖パルミチン酸エステル、ショ糖ステアリン酸エステル、ポリオキシエチレン(20)フィトステロール及びポリオキシエチレン(25)フィトスタノールは市販品を用いることが可能であり、ショ糖パルミチン酸エステルとしては三菱化学フーズ株式会社製のサーフホープ SE COSME C−1616(HLB16)、ショ糖ステアリン酸エステルとしては三菱化学フーズ株式会社製のサーフホープ SE COSME C−1816(HLB16)、ポリオキシエチレン(20)フィトステロールとしては日光ケミカルズ株式会社製のNIKKOL BPS−20(HLB15.5)、ポリオキシエチレンフィトスタノールエーテルとしては日光ケミカルズ株式会社製のNIKKOL BPSH−25(HLB14.5)等が例示できる。 Commercially available sucrose palmitate, sucrose stearate, polyoxyethylene (20) phytosterol and polyoxyethylene (25) phytostanol can be used, and sucrose palmitate is Mitsubishi Chemical Foods Corporation. Surf Hope SE COSME C-1616 (HLB16) manufactured by the company, Surf Hope SE COSME C-1816 (HLB16) manufactured by Mitsubishi Chemical Foods Co., Ltd. as the sucrose stearate, Nikko Chemicals as the polyoxyethylene (20) phytosterol NIKKOL BPS-20 (HLB15.5) manufactured by NIKKOL BPSH-25 (HLB14.5) manufactured by Nikko Chemicals Co., Ltd. is an example of polyoxyethylene phytostanol ether. Yes.
本発明に用いられる成分(c)HLBが4以下のショ糖脂肪酸エステルは、本発明の水中油型乳化化粧料において、保湿性に優れ、化粧膜による肌のハリ感とエモリエント効果の持続として機能するものであり、通常の化粧料に用いられるものであれば何れのものも用いることができる。具体的には、ショ糖ペンタヒドロキシステアリン酸エステル、ショ糖ヘキサイソステアリン酸エステル等が挙げられ、これらを選択すると、より化粧膜による肌のハリ感と保湿効果の持続効果を得易く、使用性が良好な水中油型乳化化粧料を得ることができる。 The sucrose fatty acid ester having a component (c) HLB of 4 or less used in the present invention is excellent in moisture retention in the oil-in-water emulsified cosmetic of the present invention and functions as a skin firmness and emollient effect by the cosmetic film. Any one can be used as long as it is used for ordinary cosmetics. Specifically, sucrose pentahydroxystearic acid ester, sucrose hexaisostearic acid ester, and the like can be mentioned, and when these are selected, it is easier to obtain a firmness of the skin and a moisturizing effect with a cosmetic film, and the usability is improved. A good oil-in-water emulsified cosmetic can be obtained.
ショ糖ペンタヒドロキシステアリン酸エステル、ショ糖ヘキサイソステアリン酸エステルは市販品を用いることが可能であり、ショ糖ペンタヒドロキシステアリン酸エステルとしてはクローダジャパン社製のCRODESTA 5−HS(HLB3.9)、ショ糖ヘキサイソステアリン酸エステルとしてはクローダジャパン社製のCRODESTA 6−IS(HLB3.5)等が例示できる。 Commercially available sucrose pentahydroxystearate and sucrose hexaisostearate can be used. As sucrose pentahydroxystearate, CRODESTA 5-HS (HLB3.9), manufactured by Croda Japan Co., Ltd. Examples of the sugar hexaisostearic acid ester include CRODESTA 6-IS (HLB3.5) manufactured by Croda Japan.
本発明の水中油型乳化化粧料における成分(b)及び(c)の総含有量は、0.8〜4%が好ましく、1〜3%がより好ましく、更にその含有量比は、質量比で1:0.1〜1:1の範囲である。成分(b)及び(c)の総含有量かつ質量比がこの範囲であると、より化粧膜による肌のハリ感と保湿効果の持続に優れ、使用性が良好であり、経時安定性に優れる水中油型乳化化粧料を得ることができる。一方、成分(b)及び(c)の総含有量かつ質量比がこの範囲から外れると、使用面で使用性が乏しくなったり、乳化系の安定性が低下してしまう場合がある。 The total content of the components (b) and (c) in the oil-in-water emulsified cosmetic of the present invention is preferably 0.8 to 4%, more preferably 1 to 3%, and the content ratio is a mass ratio. In the range of 1: 0.1 to 1: 1. When the total content and mass ratio of the components (b) and (c) are in this range, the skin feels better by the cosmetic film and the moisturizing effect is more excellent, the usability is good, and the stability over time is excellent. An oil-in-water emulsified cosmetic can be obtained. On the other hand, if the total content and mass ratio of the components (b) and (c) are out of this range, the usability may be poor in terms of use, or the stability of the emulsified system may be reduced.
本発明に用いられる成分(d)グリセリン及び/又は1,3−ブチレングリコールは、通常の化粧料に用いられるものであれば何れのものも用いることができ、これらを一種又は二種以上用いることができる。グリセリン及び/又は1,3−ブチレングリコールを選択すると、より微細な乳化粒子を得易く、経時安定性が特に良好な水中油型乳化化粧料を得ることができる。 As the component (d) glycerin and / or 1,3-butylene glycol used in the present invention, any one can be used as long as it is used in ordinary cosmetics, and these may be used alone or in combination. Can do. By selecting glycerin and / or 1,3-butylene glycol, it is possible to obtain an oil-in-water emulsified cosmetic that facilitates obtaining finer emulsified particles and has particularly good temporal stability.
本発明の水中油型乳化化粧料における成分(d)の含有量は、2〜20%が好ましく、4〜15%がより好ましい。成分(d)の含有量がこの範囲であると、肌なじみの良い使用感で、より保湿効果に優れる水中油型乳化化粧料を得ることができる。 The content of the component (d) in the oil-in-water emulsion cosmetic of the present invention is preferably 2 to 20%, more preferably 4 to 15%. When the content of the component (d) is within this range, an oil-in-water emulsified cosmetic with a better feeling of use and a better moisturizing effect can be obtained.
本発明に用いられる成分(e)油剤は、例えばエステル油、動植物油、炭化水素油、シリコーン油、高級脂肪酸、高級アルコール等が挙げられ、通常の化粧料に用いられる油剤であれば、固形、ペースト、液体の何れのものも用いることができる。具体的には、液状油としては、メドウフォーム油、アボカド油、アマニ油、アーモンド油、オリーブ油、キョウニン油、小麦胚芽油、ゴマ油、コメ胚芽油、コメヌカ油、サフラワー油、大豆油、トウモロコシ油、ホホバ油、マカデミアナッツ油、ミンク油、綿実油、ヤシ油、ヒマシ油、液状ラノリン、スクワラン、スクワレン、流動パラフィン、プリスタン、ポリイソブチレン、ウンデシレン酸、オレイン酸、リノール酸、リノレン酸、イソステアリン酸、アジピン酸−2−ヘキシルデシル、モノイソステアリン酸−アルキルグリコール、イソステアリン酸イソセチル、トリイソステアリン酸トリメチロールプロパン、ジ−2−エチルヘキサン酸エチレングリコール、2−エチルヘキサン酸セチル、トリ−2−エチルヘキサン酸トリメチロールプロパン、テトラ−2−エチルヘキサン酸ペンタエリスリトール、オクタン酸セチル、オレイン酸オレイル、オレイン酸オクチルドデシル、ジカプリン酸ネオペンチルグリコール、コハク酸2−エチルヘキシル、ステアリン酸イソセチル、ステアリン酸ブチル、セバシン酸ジ−2−エチルヘキシル、乳酸セチル、乳酸ミリスチル、リンゴ酸ジイソステアリル、トリイソステアリン酸グリセライド、トリ−2−エチルヘキサン酸グリセライド、ジ−2−ヘプチルウンデカン酸グリセライド、ダイマー酸ジエステル、メチルポリシロキサン、メチルフェニルポリシロキサン、エチルポリシロキサン、エチルメチルポリシロキサン、エチルフェニルポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン等が挙げられ、これらを一種又は二種以上用いることができる。また、ペースト油としては、カカオ脂、シアバター、硬化ヒマシ油、硬化ヤシ油、ラノリン、還元ラノリン、ラノリンアルコール、酢酸ラノリン、ラノリン脂肪酸イソプロピル、ワセリン、モノステアリン酸硬化ヒマシ油、モノヒドロキシステアリン酸硬化ヒマシ油、ヒドロキシステアリン酸コレステリル、ジペンタエリトリット脂肪酸(12−ヒドロキシステアリン酸・ステアリン酸・ロジン)エステル、N−ラウロイル−L−グルタミン酸ジ(コレステリル・ベヘニル・オクチルドデシル)、N−ラウロイル−L−グルタミン酸ジ(フィトステリル・ベヘニル・2−オクチルドデシル)、N−ミリストイル−N−メチルβアラニン(フィトステリル・デシルテトラデシル)、ポリグリセリン脂肪酸エステル、マカデミアナッツ油脂肪酸フィトステリル、ダイマー酸ジエステル等が挙げられ、これらを一種又は二種以上用いることができる。更に、固形油としては、セチルアルコール、ステアリルアルコール、ベヘニルアルコール、水添ナタネ油アルコール、アルキルグリセリルエーテル、カルナウバロウ、キャンデリラロウ、鯨ロウ、ミツロウ、セレシン、パラフィンワックス、マイクロクリスタリンワックス、ステアリン酸、ベヘン酸、12−ヒドロキシステアリン酸、パルミチン酸セチル、(イソステアリン酸・ベヘン酸)(グリセリル・ポリグリセリル−6)エステルズ、ジステアリン酸ポリエチレングリコール、モノステアリン酸グリセライド、トリベヘン酸グリセリル、ステアリル変性ポリシロキサン等が挙げられ、これらを一種又は二種以上用いることができる。 Examples of the component (e) oil used in the present invention include ester oils, animal and vegetable oils, hydrocarbon oils, silicone oils, higher fatty acids, higher alcohols, and the like. Either paste or liquid can be used. Specifically, as the liquid oil, meadow foam oil, avocado oil, linseed oil, almond oil, olive oil, kyounin oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, safflower oil, soybean oil, corn oil , Jojoba oil, macadamia nut oil, mink oil, cottonseed oil, palm oil, castor oil, liquid lanolin, squalane, squalene, liquid paraffin, pristane, polyisobutylene, undecylenic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid, adipic acid 2-hexyldecyl, monoisostearic acid-alkyl glycol, isocetyl isostearate, trimethylolpropane triisostearate, ethylene glycol di-2-ethylhexanoate, cetyl 2-ethylhexanoate, trimethylol tri-2-ethylhexanoate Propane, tetra-2-ethylhexanoate pentaerythritol, cetyl octanoate, oleyl oleate, octyldodecyl oleate, neopentyl glycol dicaprate, 2-ethylhexyl succinate, isocetyl stearate, butyl stearate, di-2 sebacate -Ethylhexyl, cetyl lactate, myristyl lactate, diisostearyl malate, glyceride triisostearate, glyceride tri-2-ethylhexanoate, glyceride di-2-heptylundecanoate, dimer acid diester, methyl polysiloxane, methyl phenyl polysiloxane , Ethylpolysiloxane, ethylmethylpolysiloxane, ethylphenylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, etc. Gerare, it can be used singly or in combination. In addition, as paste oil, cacao butter, shea butter, hydrogenated castor oil, hydrogenated coconut oil, lanolin, reduced lanolin, lanolin alcohol, lanolin acetate, lanolin fatty acid isopropyl, petrolatum, monostearic acid cured castor oil, monohydroxystearic acid cured Castor oil, cholesteryl hydroxystearate, dipentaerythritol fatty acid (12-hydroxystearic acid / stearic acid / rosin) ester, N-lauroyl-L-glutamic acid di (cholesteryl / behenyl / octyldodecyl), N-lauroyl-L- Glutamate di (phytosteryl, behenyl, 2-octyldodecyl), N-myristoyl-N-methyl β-alanine (phytosteryl, decyltetradecyl), polyglycerin fatty acid ester, macadamia nut oil fatty acid salt Tosuteriru, diester dimer acid and the like, and these can be used singly or in combination. Furthermore, solid oils include cetyl alcohol, stearyl alcohol, behenyl alcohol, hydrogenated rapeseed oil alcohol, alkyl glyceryl ether, carnauba wax, candelilla wax, whale wax, beeswax, ceresin, paraffin wax, microcrystalline wax, stearic acid, behenic acid. , 12-hydroxystearic acid, cetyl palmitate, (isostearic acid / behenic acid) (glyceryl / polyglyceryl-6) esters, polyethylene glycol distearate, glyceryl monostearate, glyceryl tribehenate, stearyl-modified polysiloxane, etc. One or more of these can be used.
本発明において、成分(e)中には、前記液状油を70%以上含有することが必須であり、より好ましくは75%以上含有することが好ましい。成分(e)中における、前記液状油の含有量が70%未満であると、肌なじみの良い使用感を得ることができない。 In the present invention, the component (e) must contain 70% or more of the liquid oil, more preferably 75% or more. When the content of the liquid oil in the component (e) is less than 70%, it is not possible to obtain a feeling of familiarity with the skin.
本発明の水中油型乳化化粧料における成分(e)の含有量は、10〜55%であることが好ましく、15〜50%がより好ましい。成分(e)の含有量が10%未満であると、肌に十分なしっとり感を与えることができず、保湿効果も良好ではない。また、成分(e)の含有量が55%を超えると、塗布時にべたつきを生じ、みずみずしい使用感も得ることができない。 The content of component (e) in the oil-in-water emulsion cosmetic of the present invention is preferably 10 to 55%, more preferably 15 to 50%. When the content of the component (e) is less than 10%, the skin cannot be sufficiently moistened and the moisturizing effect is not good. Moreover, when content of a component (e) exceeds 55%, stickiness will be produced at the time of application | coating and a fresh feeling of use cannot be obtained.
本発明に用いられる成分(f)水は、水中油型乳化化粧料の外相を形成する成分である。本発明の水中油型乳化化粧料における成分(f)の含有量は、25〜75%が好ましい。成分(f)の含有量がこの範囲であると、より乳化性が良好であり、みずみずしい使用感に優れる水中油型乳化化粧料を得ることができる。 The component (f) water used in the present invention is a component that forms the outer phase of an oil-in-water emulsified cosmetic. The content of component (f) in the oil-in-water emulsion cosmetic of the present invention is preferably 25 to 75%. When the content of the component (f) is within this range, an oil-in-water emulsified cosmetic with better emulsifiability and excellent fresh feeling can be obtained.
本発明の水中油型乳化化粧料における乳化粒子の粒径は、1μm以下であることが必須であり、0.5μm以下がより好ましい。乳化粒子の粒径が1μmを超えると、肌なじみの良い使用感、より経時安定性に優れる水中油型乳化化粧料を得ることができない。 The particle size of the emulsified particles in the oil-in-water emulsified cosmetic of the present invention is essential to be 1 μm or less, and more preferably 0.5 μm or less. When the particle diameter of the emulsified particles exceeds 1 μm, it is impossible to obtain an oil-in-water emulsified cosmetic material that has a good skin feel and better temporal stability.
本発明の水中油型乳化化粧料には、上記必須成分の他に、通常の化粧料に用いられる成分として、アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、水性成分、水溶性高分子、酸化防止剤、紫外線吸収剤、粉体、香料、キレート剤、防腐剤、着色剤、美容成分等を本発明の効果を損なわない範囲にて含有することができる。 In the oil-in-water emulsified cosmetic of the present invention, in addition to the above essential components, as components used in ordinary cosmetics, anionic surfactants, cationic surfactants, amphoteric surfactants, aqueous components, water-soluble high Molecules, antioxidants, ultraviolet absorbers, powders, fragrances, chelating agents, preservatives, colorants, cosmetic ingredients, and the like can be contained within a range that does not impair the effects of the present invention.
本発明の水中油型乳化化粧料は、美容液、乳液、クリーム、パック等の基礎化粧料、ファンデーション、下地料等のメーキャップ化粧料に適用可能である。尚、本発明の水中油型乳化化粧料の形態としては、液状、乳液状、クリーム状、固形状等の何れでも良い。 The oil-in-water emulsified cosmetic of the present invention can be applied to makeup cosmetics such as basic cosmetics such as beauty liquids, milky lotions, creams, packs, foundations, and foundations. The form of the oil-in-water emulsified cosmetic of the present invention may be any of liquid, emulsion, cream, solid and the like.
以下に、実施例を挙げて、本発明を更に詳細に説明する。尚、これらは本発明を何ら限定するものではない。なお、配合量は特記しない限りすべて質量%である。
実施例1〜15及び比較例1〜15
表1〜表6に示す処方で、水中油型乳化化粧料を以下に示す製造方法により調製した。
(製造方法)
(a)ジラウロイルグルタミン酸リシンナトリウム、(b)HLBが14以上のショ糖脂肪酸エステル又はポリオキシエチレンステロールエーテル及び(d)グリセリン及び/又はブチレングリコールを均一混合(表3及び表6処方は80℃に加温)させた中に、80℃で均一混合させた(c)HLBが4以下のショ糖脂肪酸エステルと(e)油剤を少しずつ添加しながら混合し、ゲルを形成し80℃に加温する。80℃に加温した(f)水を添加して乳化した後、冷却して水中油型乳化化粧料を得た。
Hereinafter, the present invention will be described in more detail with reference to examples. Note that these do not limit the present invention. All blending amounts are mass% unless otherwise specified.
Examples 1-15 and Comparative Examples 1-15
With the formulations shown in Tables 1 to 6, oil-in-water emulsified cosmetics were prepared by the production method shown below.
(Production method)
(A) Dilauroyl glutamic acid sodium lysine, (b) HLB 14 or more sucrose fatty acid ester or polyoxyethylene sterol ether and (d) glycerin and / or butylene glycol are uniformly mixed (Tables 3 and 6 are formulated at 80 ° C.) (C) The sucrose fatty acid ester having HLB of 4 or less and (e) the oil agent were mixed little by little and mixed to form a gel and heated to 80 ° C. Warm up. (F) Water heated to 80 ° C. was added to emulsify, and then cooled to obtain an oil-in-water emulsified cosmetic.
得られた水中油型乳化化粧料について、下記試験法により、乳化粒子径、安定性および使用性(みずみずしさ、肌なじみ、肌へのハリ感、保湿効果)を評価した。結果を表1〜表6に示した。 About the obtained oil-in-water type emulsified cosmetic, the emulsion particle diameter, stability and usability (freshness, familiarity with skin, firmness to skin, moisturizing effect) were evaluated by the following test methods. The results are shown in Tables 1-6.
乳化粒子径
乳化粒子径は光散乱法により測定した。測定装置はFPAR−1000(大塚電子株式会社製)を使用した。乳化粒子径は下記の基準に従って判定した。
◎:乳化粒子径が0.5μm以下。
○:乳化粒子径が0.5μmを超え1μm以下。
×:乳化粒子径が1μmを超える。
Emulsion particle diameter The emulsion particle diameter was measured by the light scattering method. As the measuring apparatus, FPAR-1000 (manufactured by Otsuka Electronics Co., Ltd.) was used. The emulsified particle size was determined according to the following criteria.
A: Emulsified particle diameter is 0.5 μm or less.
○: The emulsified particle diameter exceeds 0.5 μm and is 1 μm or less.
X: The emulsified particle diameter exceeds 1 μm.
安定性試験
試料を50℃、1か月間放置後の外観を、目視及び顕微鏡にて観察し、下記の基準に従って判定した。
○:分離・乳化粒子の凝集が全くみられなかった。
△:分離・乳化粒子の凝集がほとんどみられなかった。
×:分離あるいは乳化粒子の凝集が生じた。
Stability test The appearance of the sample after standing for 1 month at 50 ° C. was observed visually and with a microscope, and judged according to the following criteria.
○: No aggregation of separated / emulsified particles was observed.
Δ: Almost no separation / aggregation of emulsified particles was observed.
X: Separation or aggregation of emulsified particles occurred.
使用性(みずみずしさ)
女性専門パネル(20名)による使用試験を実施し、みずみずしさについて、下記の基準に従って評価した。
◎:18名以上が、みずみずしいと判定した。
○:14〜17名が、みずみずしいと判定した。
△:9〜13名が、みずみずしいと判定した。
×:みずみずしいと判定した人が8名以下。
Usability (freshness)
A use test was conducted by a female panel (20 persons), and the freshness was evaluated according to the following criteria.
A: 18 or more people judged fresh.
○: 14 to 17 persons determined to be fresh.
(Triangle | delta): Nine to thirteen people judged that it was fresh.
X: Eight or less people judged to be fresh.
使用性(肌なじみ)
女性専門パネル(20名)による使用試験を実施し、肌へのなじみについて、下記の基準に従って評価した。
◎:18名以上が、肌へのなじみが良いと判定した。
○:14〜17名が、肌へのなじみが良いと判定した。
△:9〜13名が、肌へのなじみが良いと判定した。
×:肌へのなじみが良いと判定した人が8名以下。
Usability (skin familiarity)
A usage test was conducted by a female professional panel (20 persons), and skin familiarity was evaluated according to the following criteria.
A: 18 or more people judged that familiarity with skin was good.
○: 14 to 17 persons determined that familiarity with the skin was good.
(Triangle | delta): Nine to thirteen people judged that familiar with skin was good.
×: Eight or less people determined to be familiar with the skin.
使用性(ハリ感:塗布直後、塗布後3時間)
女性専門パネル(20名)による使用試験を実施し、肌へのハリ感ついて、下記の基準に従って評価した。
◎:18名以上が、ハリ感を感じると判定した。
○:14〜17名が、ハリ感を感じると判定した。
△:9〜13名が、ハリ感を感じると判定した。
×:ハリ感を感じると判定した人が8名以下。
Usability (harness: immediately after application, 3 hours after application)
A use test was conducted by a female professional panel (20 persons), and the firmness of the skin was evaluated according to the following criteria.
A: 18 or more people judged that they felt firmness.
A: It was determined that 14 to 17 people felt a sense of elasticity.
(Triangle | delta): Nine to thirteen people judged having a feeling of elasticity.
X: Eight or less people determined to feel firmness.
使用性(保湿効果:塗布直後、塗布後3時間)
女性専門パネル(20名)による使用試験を実施し、保湿効果について、下記の基準に従って評価した。
◎:18名以上が、保湿効果を感じると判定した。
○:14〜17名が、保湿効果を感じると判定した。
△:9〜13名が、保湿効果を感じると判定した。
×:保湿効果を感じると判定した人が8名以下。
Usability (Moisturizing effect: Immediately after application, 3 hours after application)
A use test was conducted by a female professional panel (20 persons), and the moisturizing effect was evaluated according to the following criteria.
A: 18 or more people judged to feel the moisturizing effect.
○: 14 to 17 persons judged to feel the moisturizing effect.
Δ: It was determined that 9 to 13 people felt a moisturizing effect.
X: Eight or less people determined to feel the moisturizing effect.
なお表1〜3中、以下に示す成分は下記製品を用いた。
In Tables 1 to 3, the following products were used as the components shown below.
ジラウロイルグルタミン酸リシンナトリウム(10%水溶液)*1:旭化成ケミカルズ株式会社製のペリセアLB−10
ショ糖ステアリン酸エステル*2:三菱化学フーズ株式会社製のサーフホープ SE COSME C−1816
ショ糖ペンタヒドロキシステアリン酸エステル*3:クローダジャパン株式会社製のCRODESTA 5−HS
(イソステアリン酸・ベヘン酸)(グリセリル・ポリグリセリル−6)エステルズ*4:阪本薬品工業株式会社製のSフェイス VL−212
ジラウロイルグルタミン酸リシンナトリウム(30%水溶液)*5:旭化成ケミカルズ株式会社製のペリセアL−30
ショ糖パルミチン酸エステル*6:三菱化学フーズ株式会社製のサーフホープ SE COSME C−1616
マカデミアナッツ脂肪酸フィトステリル*7:日本精化株式会社製のPlandool−MAS
ポリオキシエチレン(20)フィトステロール*8:日光ケミカルズ株式会社製のNIKKOL BPS−20
ポリオキシエチレン(25)フィトスタノール*9:日光ケミカルズ株式会社製のNIKKOL BPSH−25
N−ミリストイル−N−メチルβアラニン(フィトステリル・デシルテトラデシル)*10:味の素株式会社製のエルデュウ APS−307
Dilauroyl glutamate ricin sodium (10% aqueous solution) * 1: Perisea LB-10 manufactured by Asahi Kasei Chemicals Corporation
Sucrose stearate * 2: Surf Hope SE COSME C-1816 manufactured by Mitsubishi Chemical Foods Corporation
Sucrose pentahydroxystearic acid ester * 3: CROSESTA 5-HS manufactured by CRODA JAPAN
(Isostearic acid / behenic acid) (Glyceryl / Polyglyceryl-6) Esters * 4: S face VL-212 manufactured by Sakamoto Pharmaceutical Co., Ltd.
Dilauroyl glutamic acid ricin sodium (30% aqueous solution) * 5: Perisea L-30 manufactured by Asahi Kasei Chemicals Corporation
Sucrose palmitate ester * 6: Surf Hope SE COSME C-1616 manufactured by Mitsubishi Chemical Foods Corporation
Macadamia nut fatty acid phytosteryl * 7: Plandool-MAS manufactured by Nippon Seika Co., Ltd.
Polyoxyethylene (20) phytosterol * 8: NIKKOL BPS-20 manufactured by Nikko Chemicals Co., Ltd.
Polyoxyethylene (25) phytostanol * 9: NIKKOL BPSH-25 manufactured by Nikko Chemicals Co., Ltd.
N-myristoyl-N-methyl β-alanine (phytosteryl decyltetradecyl) * 10: Eldue APS-307 manufactured by Ajinomoto Co., Inc.
表1〜3の結果から、本発明に係る実施例1〜15の水中油型乳化化粧料は、乳化粒子径、安定性および使用性(みずみずしさ、肌なじみ、肌へのハリ感、保湿効果)のいずれの効果にも優れることがわかる。一方、本発明の構成要件を充実しない比較例1〜15では、乳化粒子径、安定性および使用性のすべての効果を併せもつことができなかった。 From the results of Tables 1 to 3, the oil-in-water emulsified cosmetics of Examples 1 to 15 according to the present invention have an emulsified particle diameter, stability and usability (freshness, familiarity with the skin, firmness to the skin, moisturizing effect. It can be seen that both of the above effects are excellent. On the other hand, Comparative Examples 1 to 15 which do not satisfy the constituent requirements of the present invention could not have all the effects of the emulsified particle size, stability and usability.
以下に、本発明のその他の実施例を示す。 Other examples of the present invention will be shown below.
(実施例16:クレンジングクリーム)
(配合成分) (質量%)
(1)ジラウロイルグルタミン酸リシンナトリウム(10%水溶液) 1.0
(2)サーフホープ SE COSME C−1816 2.0
(3)グリセリン 10.0
(4)ショ糖ペンタヒドロキシステアリン酸エステル 0.5
(5)メドウフォーム油 18.0
(6)スクワラン 18.0
(7)ミリスチン酸オクチルドデシル 9.0
(8)ステアリルアルコール 0.5
(9)ベヘニルアルコール 0.5
(10)マカデミアナッツ脂肪酸フィトステリル 1.0
(11)パルミチン酸セチル 3.0
(12)精製水 残 余
(13)エデト酸二ナトリウム 0.1
(14)カルボマー 0.8
(15)ジプロピレングリコール 5.0
(16)パラベン 0.1
(17)水酸化カリウム 0.2
(18)香料 0.1
(製法)
(1)〜(3)を均一混合し、あらかじめ80℃にて均一混合しておいた(4)〜(11)をパドルを回転させながら少しずつ添加しゲルを形成する。ゲルを80℃に加温し、一方で均一混合後80℃に加温した(12)〜(18)をパドルを回転させながらゲルにゆっくりと添加し乳化する。乳化が終了したら、35℃まで急冷し、目的のクレンジングクリームを得た。
(評価)
得られたクレンジングクリームについて、上述した試験・評価基準により評価を行ったところ、乳化粒子径、安定性および使用性(みずみずしさ、肌なじみ、肌へのハリ感、保湿効果)のいずれの効果にも優れていた。
(Example 16: Cleansing cream)
(Compounding ingredients) (mass%)
(1) Sodium dilauroylglutamate ricin (10% aqueous solution) 1.0
(2) Surf Hope SE COSME C-1816 2.0
(3) Glycerin 10.0
(4) Sucrose pentahydroxystearate ester 0.5
(5) Meadowfoam oil 18.0
(6) Squalane 18.0
(7) Octyldodecyl myristate 9.0
(8) Stearyl alcohol 0.5
(9) Behenyl alcohol 0.5
(10) Macadamia nut fatty acid phytosteryl 1.0
(11) Cetyl palmitate 3.0
(12) Purified water residue (13) Disodium edetate 0.1
(14) Carbomer 0.8
(15) Dipropylene glycol 5.0
(16) Paraben 0.1
(17) Potassium hydroxide 0.2
(18) Fragrance 0.1
(Manufacturing method)
(1) to (3) are uniformly mixed, and (4) to (11), which are previously uniformly mixed at 80 ° C., are added little by little while rotating the paddle to form a gel. While the gel is heated to 80 ° C., (12) to (18) heated to 80 ° C. after uniform mixing is slowly added to the gel while rotating the paddle and emulsified. When the emulsification was completed, it was rapidly cooled to 35 ° C. to obtain the desired cleansing cream.
(Evaluation)
When the obtained cleansing cream was evaluated according to the above-mentioned test / evaluation criteria, it was effective for any of the emulsified particle size, stability and usability (freshness, familiarity with the skin, firmness to the skin, moisturizing effect). Was also excellent.
(実施例17:乳液)
(配合成分) (質量%)
(1)ジラウロイルグルタミン酸リシンナトリウム(30%水溶液) 2.0
(2)サーフホープ SE COSME C−1616 1.0
(3)グリセリン 15.0
(4)ショ糖ペンタヒドロキシステアリン酸エステル 0.5
(5)メドウフォーム油 10.0
(6)スクワラン 5.0
(7)ジメチコン 1.0
(8)ベヘニルアルコール 0.5
(9)(イソステアリン酸・ベヘン酸)(グリセリル・ポリグリ
セリル−6)エステルズ 1.0
(10)精製水 残 余
(11)メタリン酸ナトリウム 0.1
(12)ベントナイト 0.5
(13)キサンタンガム 0.1
(14)ジプロピレングリコール 10.0
(15)パラベン 0.1
(16)香料 0.1
(製法)
(1)〜(3)を均一混合し、あらかじめ80℃にて均一混合しておいた(4)〜(9)をパドルを回転させながら少しずつ添加しゲルを形成する。ゲルを80℃に加温し、一方で均一混合後80℃に加温した(10)〜(16)をパドルを回転させながらゲルにゆっくりと添加し乳化する。乳化が終了したら、35℃まで急冷し、目的の乳液を得た。
(評価)
得られた乳液について、上述した試験・評価基準により評価を行ったところ、乳化粒子径、安定性および使用性(みずみずしさ、肌なじみ、肌へのハリ感、保湿効果)のいずれの効果にも優れていた。
(Example 17: Latex)
(Compounding ingredients) (mass%)
(1) Dilauroyl glutamic acid sodium lysine (30% aqueous solution) 2.0
(2) Surf Hope SE COSME C-1616 1.0
(3) Glycerin 15.0
(4) Sucrose pentahydroxystearate ester 0.5
(5) Meadowfoam oil 10.0
(6) Squalane 5.0
(7) Dimethicone 1.0
(8) Behenyl alcohol 0.5
(9) (Isostearic acid / behenic acid) (Glyceryl / Polyglycol)
Seryl-6) Esters 1.0
(10) Purified water residue (11) Sodium metaphosphate 0.1
(12) Bentonite 0.5
(13) Xanthan gum 0.1
(14) Dipropylene glycol 10.0
(15) Paraben 0.1
(16) Fragrance 0.1
(Manufacturing method)
(1) to (3) are uniformly mixed, and (4) to (9), which are previously uniformly mixed at 80 ° C., are added little by little while rotating the paddle to form a gel. While the gel is heated to 80 ° C., (10) to (16) heated to 80 ° C. after uniform mixing is slowly added to the gel while rotating the paddle and emulsified. When the emulsification was completed, it was rapidly cooled to 35 ° C. to obtain the desired emulsion.
(Evaluation)
When the obtained emulsion was evaluated according to the above-described test and evaluation criteria, it was found that the emulsion particle size, stability and usability (freshness, familiarity with skin, firmness to the skin, moisturizing effect) It was excellent.
(実施例18:エモリエントクリーム)
(配合成分) (質量%)
(1)ジラウロイルグルタミン酸リシンナトリウム(10%水溶液) 3.0
(2)ポリオキシエチレン(25)フィトスタノール 1.0
(3)1,3−ブチレングリコール 4.0
(4)ショ糖ペンタヒドロキシステアリン酸エステル 0.3
(5)メドウフォーム油 12.0
(6)スクワラン 10.0
(7)ミリスチン酸オクチルドデシル 4.0
(8)パルミチン酸セチル 2.0
(9)ステアリルアルコール 1.5
(10)ベヘニルアルコール 1.5
(11)N−ミリストイル−N−メチルβアラニン(フィトステ
リル・デシルテトラデシル) 3.0
(12)精製水 残 余
(13)エデト酸二ナトリウム 0.1
(14)カルボマー 1.0
(15)キサンタンガム 0.1
(16)プロピレングリコール 5.0
(17)グリセリン 5.0
(18)パラベン 0.1
(19)水酸化カリウム 0.3
(20)香料 0.1
(製法)
(1)〜(3)を均一混合し、あらかじめ80℃にて均一混合しておいた(4)〜(11)をパドルを回転させながら少しずつ添加しゲルを形成する。ゲルを80℃に加温し、一方で均一混合後80℃に加温した(12)〜(20)をパドルを回転させながらゲルにゆっくりと添加し乳化する。乳化が終了したら、35℃まで急冷し、目的のエモリエントクリームを得た。
(評価)
得られたエモリエントクリームについて、上述した試験・評価基準により評価を行ったところ、乳化粒子径、安定性および使用性(みずみずしさ、肌なじみ、肌へのハリ感、保湿効果)のいずれの効果にも優れていた。
(Example 18: Emollient cream)
(Compounding ingredients) (mass%)
(1) Sodium dilauroylglutamate ricin (10% aqueous solution) 3.0
(2) Polyoxyethylene (25) Phytostanol 1.0
(3) 1,3-butylene glycol 4.0
(4) Sucrose pentahydroxystearate 0.3
(5) Meadow foam oil 12.0
(6) Squalane 10.0
(7) Octyldodecyl myristate 4.0
(8) Cetyl palmitate 2.0
(9) Stearyl alcohol 1.5
(10) Behenyl alcohol 1.5
(11) N-myristoyl-N-methyl β-alanine (phytoste
Lil decyl tetradecyl) 3.0
(12) Purified water residue (13) Disodium edetate 0.1
(14) Carbomer 1.0
(15) Xanthan gum 0.1
(16) Propylene glycol 5.0
(17) Glycerin 5.0
(18) Paraben 0.1
(19) Potassium hydroxide 0.3
(20) Fragrance 0.1
(Manufacturing method)
(1) to (3) are uniformly mixed, and (4) to (11), which are previously uniformly mixed at 80 ° C., are added little by little while rotating the paddle to form a gel. While the gel is heated to 80 ° C., (12) to (20) heated to 80 ° C. after uniform mixing is slowly added to the gel while rotating the paddle and emulsified. When the emulsification was completed, it was rapidly cooled to 35 ° C. to obtain the target emollient cream.
(Evaluation)
When the obtained emollient cream was evaluated according to the above-mentioned test / evaluation criteria, the emulsified particle diameter, stability and usability (freshness, familiarity with skin, firmness to the skin, moisturizing effect) Was also excellent.
本発明によれば、みずみずしい使用感で肌なじみがよく、しかも肌のハリ感と保湿効果が長時間持続する水中油型乳化化粧料を提供できる。 According to the present invention, it is possible to provide an oil-in-water emulsified cosmetic that has a fresh feeling of use and is well-familiar with the skin, and that has a firmness and a moisturizing effect for a long time.
Claims (3)
(a)ジラウロイルグルタミン酸リシンナトリウム
(b)HLBが14以上のショ糖脂肪酸エステル及び/又はポリオキシエチレンステロールエーテル
(c)HLBが4以下のショ糖脂肪酸エシテル
(d)グリセリン及び/又は1,3−ブチレングリコール
(e)油剤
(f)水
を含有し、成分(b)及び(c)の総含有量が0.8〜4質量%であり、その含有量比が、質量比で1:0.1〜1:1の範囲であり、更に乳化粒子の粒径が1μm以下であることを特徴とする水中油型乳化化粧料。 The following components (a) to (f);
(A) Sodium dilauroylglutamate ricin (b) sucrose fatty acid ester having an HLB of 14 or more and / or polyoxyethylene sterol ether (c) sucrose fatty acid esitelle having an HLB of 4 or less (d) glycerin and / or 1,3 -Butylene glycol (e) oil agent (f) It contains water, the total content of components (b) and (c) is 0.8 to 4% by mass, and the content ratio is 1: 0 by mass. An oil-in-water emulsified cosmetic, wherein the emulsion particle size is in the range of 1 to 1: 1 and the particle size of the emulsified particles is 1 μm or less.
The oil-in-water emulsified cosmetic according to claim 1 or 2, wherein the component (c) is sucrose pentahydroxystearate.
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JP7312529B2 (en) | 2018-03-30 | 2023-07-21 | 株式会社コーセー | Oil-in-water emulsified cosmetic |
JP2020063222A (en) * | 2018-10-19 | 2020-04-23 | 日本メナード化粧品株式会社 | Oil-in-water emulsion cosmetic |
JP7180272B2 (en) | 2018-10-19 | 2022-11-30 | 日本メナード化粧品株式会社 | Oil-in-water emulsified cosmetic |
JP2020079218A (en) * | 2018-11-14 | 2020-05-28 | ちふれホールディングス株式会社 | Oil-in-water emulsion cosmetic |
JP7240144B2 (en) | 2018-11-14 | 2023-03-15 | ちふれホールディングス株式会社 | Oil-in-water emulsified cosmetic |
JP7539246B2 (en) | 2020-04-03 | 2024-08-23 | 株式会社シーボン | Emulsion-type cleansing cosmetics |
JP2020158539A (en) * | 2020-06-30 | 2020-10-01 | ポーラ化成工業株式会社 | Oil-in-water type emulsion composition |
JP7018477B2 (en) | 2020-06-30 | 2022-02-10 | ポーラ化成工業株式会社 | Oil-in-water emulsification composition |
JP7606734B2 (en) | 2020-09-02 | 2024-12-26 | 日本メナード化粧品株式会社 | Oil-in-water emulsion cosmetics |
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