JP2014214119A - Method for suppressing eclosion of fly - Google Patents
Method for suppressing eclosion of fly Download PDFInfo
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- JP2014214119A JP2014214119A JP2013092073A JP2013092073A JP2014214119A JP 2014214119 A JP2014214119 A JP 2014214119A JP 2013092073 A JP2013092073 A JP 2013092073A JP 2013092073 A JP2013092073 A JP 2013092073A JP 2014214119 A JP2014214119 A JP 2014214119A
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- ethylene
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- 239000004323 potassium nitrate Substances 0.000 description 1
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- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
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- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 description 1
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- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- NWWZPOKUUAIXIW-FLIBITNWSA-N thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
【課題】増殖能力が高いハエの羽化を効果的に抑制する羽化阻害剤を提供する。【解決手段】［２，３，５，６−テトラフルオロ−４−（メトキシメチル）フェニル］メチル＝２，２−ジメチル−３−（１−プロペニル）シクロプロパンカルボキシラート、（２，３，５，６−テトラフルオロ−４−メチルフェニル）メチル＝２，２−ジメチル−３−（１−プロペニル）シクロプロパンカルボキシラート等を有効成分として含有することを特徴とするハエの羽化阻害剤、及び、該羽化阻害剤をハエの幼虫又は蛹に施用することを特徴とするハエの羽化抑制方法。【選択図】なしThe present invention provides an emergence inhibitor that effectively suppresses the emergence of flies with high proliferation ability. [2,3,5,6-tetrafluoro-4- (methoxymethyl) phenyl] methyl = 2,2-dimethyl-3- (1-propenyl) cyclopropanecarboxylate, (2,3,5) , 6-tetrafluoro-4-methylphenyl) methyl = 2,2-dimethyl-3- (1-propenyl) cyclopropanecarboxylate and the like as an active ingredient, and a fly emergence inhibitor, A method for suppressing the emergence of a fly, which comprises applying the emergence inhibitor to a fly larva or a moth. [Selection figure] None
Description
本発明は、ハエの羽化阻害剤、および、該羽化阻害剤を用いたハエの羽化抑制方法に関する。 The present invention relates to a fly emergence inhibitor and a method for suppressing fly emergence using the emergence inhibitor.
ある種のピレスロイド系化合物がイエバエやオオチョウバエ等のハエの成虫に対して、優れた活性を（特許文献１乃至２）有し、該化合物を有効成分とする防除剤が開発され、実用に供されている。しかしながら、ハエは増殖能力が極めて高く、ハエの増殖を抑制するとの観点からは、ハエの成虫のみを防除する方法では増殖を抑制するには不十分であった。特に小型のハエであるショウジョウバエはライフサイクルが短く、増殖力が高い為に、成虫期の前のステージにて防除することが望まれている。
一方、オイゲノールを含む、クローブ油、ピメンタ油、ベイ油、シナモンリーフ油等が、ショウジョウバエに対して羽化阻害効果を有することが記載されている（特許文献３）
Certain pyrethroid compounds have excellent activity against adult flies such as house flies and giant flies (Patent Documents 1 and 2), and a control agent comprising the compound as an active ingredient has been developed and put to practical use. Has been. However, flies have extremely high proliferation ability, and from the viewpoint of suppressing the growth of flies, the method for controlling only adult flies is insufficient for suppressing the proliferation. In particular, Drosophila, which is a small fly, has a short life cycle and high growth potential, so it is desired to control it at the stage before the adult stage.
On the other hand, it is described that clove oil, pimenta oil, bay oil, cinnamon leaf oil and the like containing eugenol have an emergence inhibitory effect on Drosophila (Patent Document 3).
本発明は、ハエの羽化抑制方法、及び、ハエの羽化抑制に適した組成物を含有するハエ羽化阻害剤を提供することを課題とする。 An object of the present invention is to provide a method for suppressing the emergence of flies, and a fly emergence inhibitor containing a composition suitable for suppressing the emergence of flies.
本発明者は、ハエの増殖を効果的に抑制する為に優れた方法を検討した結果、ある種のピレスロイド化合物が、ハエの羽化を抑制することを見出し、本発明を完成させた。
ある種のピレスロイド化合物とは、［２，３，５，６−テトラフルオロ−４−（メトキシメチル）フェニル］メチル＝２，２−ジメチル−３−（１−プロペニル）シクロプロパンカルボキシラート、（２，３，５，６−テトラフルオロ−４−メチルフェニル）メチル＝２，２−ジメチル−３−（１−プロペニル）シクロプロパンカルボキシラート、（２，３，５，６−テトラフルオロフェニル）メチル＝３−（２，２−ジクロロビニル）−２，２−ジメチルシクロプロパンカルボキシラート、又は１−エチニル−２−メチル−２−ペンテン−１−イル＝３−（２−メチル−１−プロペニル）−２，２−ジメチルシクロプロパンカルボキシラート（以下、本エステル化合物と記す。）であり、本エステル化合物を用いることにより、ハエの羽化を抑制できる。
As a result of studying an excellent method for effectively suppressing fly growth, the present inventor has found that certain pyrethroid compounds suppress the emergence of flies, thereby completing the present invention.
Certain pyrethroid compounds include [2,3,5,6-tetrafluoro-4- (methoxymethyl) phenyl] methyl = 2,2-dimethyl-3- (1-propenyl) cyclopropanecarboxylate, (2 , 3,5,6-tetrafluoro-4-methylphenyl) methyl = 2,2-dimethyl-3- (1-propenyl) cyclopropanecarboxylate, (2,3,5,6-tetrafluorophenyl) methyl = 3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate or 1-ethynyl-2-methyl-2-penten-1-yl = 3- (2-methyl-1-propenyl)- 2,2-dimethylcyclopropanecarboxylate (hereinafter referred to as the present ester compound). By using the present ester compound, the emergence of flies It can be suppressed.
即ち、本発明は以下のものである。
［発明１］
本エステル化合物を有効成分として含有することを特徴とするハエの羽化阻害剤。
［発明２］
発明１において、ハエがショウジョウバエ類である羽化阻害剤。
［発明３］
発明１又は発明２記載の羽化阻害剤をハエの幼虫又は蛹に施用することを特徴とするハエの羽化抑制方法。
That is, the present invention is as follows.
[Invention 1]
A fly emergence inhibitor comprising the ester compound as an active ingredient.
[Invention 2]
The emergence inhibitor according to invention 1, wherein the fly is Drosophila.
[Invention 3]
A method for suppressing the emergence of a fly, comprising applying the emergence inhibitor according to the invention 1 or the invention to a fly larva or a moth.
本発明により、例えば、台所等の人間の生活環境に発生するハエの羽化を抑制することができる。 According to the present invention, for example, the emergence of flies occurring in a human living environment such as a kitchen can be suppressed.
本発明のハエの羽化抑制方法は、本エステル化合物の有効量をハエの幼虫又は蛹に施用することにより行われる。 The method for inhibiting the emergence of flies of the present invention is carried out by applying an effective amount of the present ester compound to fly larvae or pupae.
［２，３，５，６−テトラフルオロ−４−（メトキシメチル）フェニル］メチル＝２，２−ジメチル−３−（１−プロペニル）シクロプロパンカルボキシレート（以下、本エステル化合物Ａと記す。）、及び、（２，３，５，６−テトラフルオロ−４−メチルフェニル）メチル＝２，２−ジメチル−３−（１−プロペニル）シクロプロパンカルボキシレート（以下、本エステル化合物Ｂと記す。）は、いずれも公知な化合物であり、例えば特開平１１−２２２４６３号公報に記載された方法で製造することができる。
２，３，５，６−テトラフルオロベンジル＝３−（２，２−ジクロロビニル）−２，２−ジメチルシクロプロパンカルボキシラート（以下、本エステル化合物Ｃと記す。）も、公知な化合物であり、例えば特開昭６３−２０３６４９号公報に記載された方法で製造することができる。
１−エチニル−２−メチル−２−ペンテニル＝３−（２−メチル−１−プロペニル）−２，２−ジメチルシクロプロパンカルボキシラート（以下、本エステル化合物Ｄと記す。も、公知な化合物である。
本エステル化合物Ａ、本エステル化合物Ｂ、本エステル化合物Ｃ及び本エステル化合物Ｄには、いずれも不斉炭素に基づく異性体が存在し、また炭素−炭素二重結合に基づく異性体が存在するが、本発明には活性な異性体のいずれをも使用することができる。
[2,3,5,6-tetrafluoro-4- (methoxymethyl) phenyl] methyl = 2,2-dimethyl-3- (1-propenyl) cyclopropanecarboxylate (hereinafter referred to as ester compound A) And (2,3,5,6-tetrafluoro-4-methylphenyl) methyl = 2,2-dimethyl-3- (1-propenyl) cyclopropanecarboxylate (hereinafter referred to as the present ester compound B). Are known compounds and can be produced, for example, by the method described in JP-A-11-222463.
2,3,5,6-tetrafluorobenzyl = 3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate (hereinafter referred to as the present ester compound C) is also a known compound. For example, it can be produced by the method described in JP-A-63-203649.
1-ethynyl-2-methyl-2-pentenyl = 3- (2-methyl-1-propenyl) -2,2-dimethylcyclopropanecarboxylate (hereinafter referred to as the present ester compound D. Also known compounds) .
The present ester compound A, the present ester compound B, the present ester compound C and the present ester compound D all have an isomer based on an asymmetric carbon and an isomer based on a carbon-carbon double bond. Any active isomer can be used in the present invention.
本発明の羽化阻害剤は、ハエ（イエバエ、クロイエバエ、オオイエバエ、ヒメイエバエ類、オオキモンノミバエ等を含むノミバエ類、キイロショウジョウバエ等を含むショウジョウバエ類、ツヤホソバエ類、クロバエ類、ニクバエ類等）の羽化抑制において優れた防除効力を有する。 The emergence inhibitor of the present invention is the emergence suppression of flies (fly flies, fly flies, flies flies, fly flies including flies, Drosophila flies including Drosophila, etc.) Has excellent control efficacy.
本発明の羽化阻害剤は、本エステル化合物そのままであってもよいが、通常は使用する際のハエの幼虫又は蛹のいる場所、周囲の状況等に応じて、本エステル化合物を含有する以下に記載するような製剤形態にて使用する。その製剤形態としては、例えば油剤、乳剤、水和剤、フロアブル剤（水中懸濁剤、水中乳濁剤等）、マイクロカプセル剤、粉剤、粒剤、錠剤、エアゾール剤、炭酸ガス製剤、加熱蒸散剤（殺虫線香、電気殺虫マット、吸液芯型加熱蒸散殺虫剤等）、ピエゾ式殺虫製剤、加熱燻煙剤（自己燃焼型燻煙剤、化学反応型燻煙剤、多孔セラミック板燻煙剤等）、非加熱蒸散剤（樹脂蒸散剤、紙蒸散剤、不織布蒸散剤、編織物蒸散剤等）、煙霧剤（フォッキング等）、ＵＬＶ剤、接触剤（防虫シート、防虫ネット）及び毒餌が挙げられる。 The emergence inhibitor of the present invention may be the present ester compound as it is, but usually contains the present ester compound depending on the place where the fly larvae or moths are used, the surrounding conditions, etc. Use in formulation form as described. The preparation forms include, for example, oils, emulsions, wettable powders, flowables (suspensions in water, emulsions in water, etc.), microcapsules, powders, granules, tablets, aerosols, carbon dioxide preparations, heat evaporation. Agents (insecticide incense sticks, electric insecticide mats, liquid-absorbing core-type heat transpiration insecticides, etc.), piezo-type insecticides, heated smoke smoke (self-burning smoke smoke, chemical reaction smoke smoke, porous ceramic plate smoke smoke) Etc.), non-heated transpiration agent (resin transpiration agent, paper transpiration agent, non-woven fabric transpiration agent, knitted fabric transpiration agent, etc.), haze agent (hooking etc.), ULV agent, contact agent (insect repellent sheet, insect repellent net) and poison bait Can be mentioned.
製剤化の方法としては、例えば以下の方法を挙げることができる。
（１）本エステル化合物を、固体担体、液体担体、ガス状担体、餌等と混合し、必要であれば界面活性剤その他の製剤用補助剤を添加・加工する方法。
（２）本エステル化合物を、有効成分を含有していない基材に含浸する方法。
（３）本エステル化合物及び基材を混合した後に成形加工する方法。
これらの製剤には、本エステル化合物を通常０．００１〜９８重量％含有する。
Examples of the formulation method include the following methods.
(1) A method in which the present ester compound is mixed with a solid carrier, liquid carrier, gaseous carrier, bait, etc., and if necessary, a surfactant or other formulation adjuvant is added and processed.
(2) A method of impregnating a base material containing no active ingredient with the ester compound.
(3) A method of molding after mixing the ester compound and the substrate.
These preparations usually contain 0.001 to 98% by weight of the present ester compound.
製剤化の際に用いられる固体担体としては、例えば粘土類（カオリンクレー、珪藻土、ベントナイト、フバサミクレー、酸性白土等）、合成含水酸化珪素、タルク、セラミック、その他の無機鉱物（セリサイト、石英、硫黄、活性炭、炭酸カルシウム、水和シリカ等）、化学肥料（硫安、燐安、硝安、塩安、尿素等）等の微粉末及び粒状物、常温で固体の物質（2,4,6−トリイソプロピル−1,3,5−トリオキサン、ナフタリン、ｐ−ジクロロベンゼン、樟脳、アダマンタン等）、並びに羊毛、絹、綿、麻、パルプ、合成樹脂（例えば、低密度ポリエチレン、直鎖状低密度ポリエチレン、高密度ポリエチレン等のポリエチレン系樹脂；エチレン−酢酸ビニル共重合体等のエチレン−ビニルエステル共重合体；エチレン−メタクリル酸メチル共重合体、エチレン−メタクリル酸エチル共重合体等のエチレン−メタクリル酸エステル共重合体；エチレン−アクリル酸メチル共重合体、エチレン−アクリル酸エチル共重合体等のエチレン−アクリル酸エステル共重合体；エチレン−アクリル酸共重合体等のエチレン−ビニルカルボン酸共重合体；エチレン−テトラシクロドデセン共重合体；プロピレン単独重合体、プロピレン−エチレン共重合体等のポリプロピレン系樹脂；ポリ−４−メチルペンテン−１、ポリブテン−１、ポリブタジエン、ポリスチレン；アクリロニトリル−スチレン樹脂；アクリロニトリル−ブタジエン−スチレン樹脂、スチレン−共役ジエンブロック共重合体、スチレン−共役ジエンブロック共重合体水素添加物等のスチレン系エラストマー；フッ素樹脂；ポリメタクリル酸メチル等のアクリル系樹脂；ナイロン６、ナイロン６６等のポリアミド系樹脂；ポリエチレンテレフタレート、ポリエチレンナフタレート、ポリブチレンテレフタレエート、ポリシクロへキシレンジメチレンテレフタレート等のポリエステル系樹脂；ポリカーボネート、ポリアセタール、ポリアクリルサルフォン、ポリアリレート、ヒドロキシ安息香酸ポリエステル、ポリエーテルイミド、ポリエステルカーボネート、ポリフェニレンエーテル樹脂、ポリ塩化ビニル、ポリ塩化ビニリデン、ポリウレタン、発泡ポリウレタン、発泡ポリプロピレン、発泡エチレン等の多孔質樹脂）、ガラス、金属、セラミック等の１種または２種以上からなるフェルト、繊維、布、編物、シート、紙、糸、発泡体、多孔質体及びマルチフィラメントが挙げられる。 Examples of solid carriers used for formulation include clays (kaolin clay, diatomaceous earth, bentonite, fusami clay, acidic clay), synthetic hydrous silicon oxide, talc, ceramics, and other inorganic minerals (sericite, quartz, sulfur). , Activated carbon, calcium carbonate, hydrated silica, etc.), fine powders and particulates such as chemical fertilizers (ammonium sulfate, phosphorous acid, ammonium nitrate, ammonium chloride, urea, etc.), substances that are solid at room temperature (2,4,6-triisopropyl) -1,3,5-trioxane, naphthalene, p-dichlorobenzene, camphor, adamantane, etc.), wool, silk, cotton, hemp, pulp, synthetic resin (for example, low density polyethylene, linear low density polyethylene, high Polyethylene resins such as density polyethylene; ethylene-vinyl ester copolymers such as ethylene-vinyl acetate copolymers; ethylene-methyl methacrylate copolymers; Ethylene-methacrylic acid ester copolymer such as ethylene-ethyl methacrylate copolymer; Ethylene-acrylic acid ester copolymer such as ethylene-methyl acrylate copolymer, ethylene-ethyl acrylate copolymer; ethylene-acrylic Ethylene-vinylcarboxylic acid copolymers such as acid copolymers; ethylene-tetracyclododecene copolymers; polypropylene resins such as propylene homopolymers and propylene-ethylene copolymers; poly-4-methylpentene-1 , Polybutene-1, polybutadiene, polystyrene; acrylonitrile-styrene resin; styrene-based elastomer such as acrylonitrile-butadiene-styrene resin, styrene-conjugated diene block copolymer, hydrogenated styrene-conjugated diene block copolymer; fluorine resin; Polymethacryl Acrylic resins such as methyl; polyamide resins such as nylon 6 and nylon 66; polyester resins such as polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, polycyclohexylene dimethylene terephthalate; polycarbonate, polyacetal, polyacrylic Phon, polyarylate, hydroxybenzoic acid polyester, polyetherimide, polyester carbonate, polyphenylene ether resin, polyvinyl chloride, polyvinylidene chloride, polyurethane, foamed polyurethane, foamed polypropylene, foamed ethylene and other porous resins), glass, metal, Felts, fibers, fabrics, knitted fabrics, sheets, papers, threads, foams, porous bodies and multifilaments composed of one or more ceramics That.
液体担体としては、例えば芳香族または脂肪族炭化水素類（キシレン、トルエン、アルキルナフタレン、フェニルキシリルエタン、ケロシン、軽油、ヘキサン、シクロヘキサン等）、ハロゲン化炭化水素類（クロロベンゼン、ジクロロメタン、ジクロロエタン、トリクロロエタン等）、アルコール類（メタノール、エタノール、イソプロピルアルコール、ブタノール、ヘキサノール、ベンジルアルコール、エチレングリコール等）、エーテル類（ジエチルエーテル、エチレングリコールジメチルエーテル、ジエチレングリコールモノメチルエーテル、ジエチレングリコールモノエチルエーテル、プロピレングリコールモノメチルエーテル、テトラヒドロフラン、ジオキサン等）、エステル類（酢酸エチル、酢酸ブチル等）、ケトン類（アセトン、メチルエチルケトン、メチルイソブチルケトン、シクロヘキサノン等）、ニトリル類（アセトニトリル、イソブチロニトリル等）、スルホキシド類（ジメチルスルホキシド等）、酸アミド類（Ｎ，Ｎ−ジメチルホルムアミド、Ｎ，Ｎ−ジメチルアセトアミド、Ｎ−メチル−ピロリドン等）、炭酸アルキリデン類（炭酸プロピレン等）、植物油（大豆油、綿実油等）、植物精油（オレンジ油、ヒソップ油、レモン油等）、及び水が挙げられる。 Examples of the liquid carrier include aromatic or aliphatic hydrocarbons (xylene, toluene, alkylnaphthalene, phenylxylylethane, kerosene, light oil, hexane, cyclohexane, etc.), halogenated hydrocarbons (chlorobenzene, dichloromethane, dichloroethane, trichloroethane). Etc.), alcohols (methanol, ethanol, isopropyl alcohol, butanol, hexanol, benzyl alcohol, ethylene glycol, etc.), ethers (diethyl ether, ethylene glycol dimethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, propylene glycol monomethyl ether, tetrahydrofuran) , Dioxane, etc.), esters (ethyl acetate, butyl acetate, etc.), ketones (aceto , Methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, etc.), nitriles (acetonitrile, isobutyronitrile, etc.), sulfoxides (dimethyl sulfoxide, etc.), acid amides (N, N-dimethylformamide, N, N-dimethylacetamide, N -Methyl-pyrrolidone etc.), alkylidene carbonates (propylene carbonate etc.), vegetable oils (soybean oil, cottonseed oil etc.), plant essential oils (orange oil, hyssop oil, lemon oil etc.) and water.
ガス状担体としては、例えばブタンガス、フロンガス、液化石油ガス（ＬＰＧ）、ジメチルエーテル、及び炭酸ガスが挙げられる。 Examples of the gaseous carrier include butane gas, freon gas, liquefied petroleum gas (LPG), dimethyl ether, and carbon dioxide gas.
界面活性剤としては、例えばアルキル硫酸エステル塩、アルキルスルホン酸塩、アルキルアリールスルホン酸塩、アルキルアリールエーテル類、アルキルアリールエーテル類のポリオキシエチレン化物、ポリエチレングリコールエーテル類、多価アルコールエステル類及び糖アルコール誘導体が挙げられる。 Surfactants include, for example, alkyl sulfate esters, alkyl sulfonates, alkyl aryl sulfonates, alkyl aryl ethers, polyarylethylenes of alkyl aryl ethers, polyethylene glycol ethers, polyhydric alcohol esters and sugars. Examples include alcohol derivatives.
その他の製剤用補助剤としては、固着剤、分散剤、安定剤、色素等、具体的には例えばカゼイン、ゼラチン、多糖類（でんぷん、アラビアガム、セルロース誘導体、アルギン酸等）、リグニン誘導体、ベントナイト、糖類、合成水溶性高分子（ポリビニルアルコール、ポリビニルピロリドン）、ポリアクリル酸等、ＢＨＴ（２，６−ジ−ｔｅｒｔ−ブチル−４−メチルフェノール）、及びＢＨＡ（２−ｔｅｒｔ−ブチル−４−メトキシフェノールと３−ｔｅｒｔ−ブチル−４−メトキシフェノールとの混合物）が挙げられる。 Examples of other formulation adjuvants include fixing agents, dispersants, stabilizers, pigments, and the like, such as casein, gelatin, polysaccharides (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, bentonite, Sugars, synthetic water-soluble polymers (polyvinyl alcohol, polyvinylpyrrolidone), polyacrylic acid, etc., BHT (2,6-di-tert-butyl-4-methylphenol), and BHA (2-tert-butyl-4-methoxy) A mixture of phenol and 3-tert-butyl-4-methoxyphenol).
殺虫線香の基材としては、例えば木粉、粕粉等の植物性粉末とタブ粉、スターチ、グルティン等の結合剤との混合物が挙げられる。
殺虫電気マットの基材としては、例えばコットンリンターを板状に固めたもの、及びコットンリンターとパルプとの混合物のフィリブルを板状に固めたものが挙げられる。
自己燃焼型の基材としては、例えば、硝酸塩、亜硝酸塩、グウニジン塩、塩素酸カリウム、ニトロセルロース、エチルセルロース、木粉等の燃焼発熱剤、アルカリ金属塩、アルカリ土類金属塩、重クロム酸塩、クロム酸塩等の熱分解刺激剤、硝酸カリウム等の酸素供給剤、メラミン、小麦デンプン等の支燃剤、珪藻土等の増量剤及び合成糊料等の結合剤が挙げられる。
Examples of the insecticidal incense base material include a mixture of a vegetable powder such as wood powder and straw powder and a binder such as tab powder, starch and glutin.
Examples of the base material for the insecticidal electric mat include those obtained by solidifying a cotton linter into a plate shape and those obtained by solidifying a fillable of a mixture of cotton linter and pulp into a plate shape.
Examples of self-burning base materials include nitrate, nitrite, guanidine salt, potassium chlorate, nitrocellulose, ethyl cellulose, wood flour, and other combustion exothermic agents, alkali metal salts, alkaline earth metal salts, and dichromates. And pyrolysis stimulants such as chromate, oxygen supply agents such as potassium nitrate, flame retardants such as melamine and wheat starch, fillers such as diatomaceous earth, and binders such as synthetic pastes.
化学反応型燻煙剤の基材としては、例えば、アルカリ金属の硫化物、多硫化物、水硫化物、酸化カルシウム等の発熱剤、炭素質物質、炭化鉄、活性白土等の触媒剤、アゾジカルボンアミド、ベンゼンスルホニルヒドラジド、ジニトロペンタメチレンテトラミン、ポリスチレン、ポリウレタン等の有機発泡剤、及び、天然繊維片、合成繊維片等の充填剤が挙げられる。 Examples of the base material for the chemical reaction type smoke agent include exothermic agents such as alkali metal sulfides, polysulfides, hydrosulfides and calcium oxide, catalyst materials such as carbonaceous materials, iron carbide and activated clay, azo Examples thereof include organic foaming agents such as dicarbonamide, benzenesulfonyl hydrazide, dinitropentamethylenetetramine, polystyrene and polyurethane, and fillers such as natural fiber pieces and synthetic fiber pieces.
樹脂蒸散剤の基材としては、例えば、低密度ポリエチレン、直鎖状低密度ポリエチレン、高密度ポリエチレン等のポリエチレン系樹脂；エチレン−酢酸ビニル共重合体等のエチレン−ビニルエステル共重合体；エチレン−メタクリル酸メチル共重合体、エチレン−メタクリル酸エチル共重合体等のエチレン−メタクリル酸エステル共重合体；エチレン−アクリル酸メチル共重合体、エチレン−アクリル酸エチル共重合体等のエチレン−アクリル酸エステル共重合体；エチレン−アクリル酸共重合体等のエチレン−ビニルカルボン酸共重合体；エチレン−テトラシクロドデセン共重合体；プロピレン共重合体、プロピレン−エチレン共重合体等のポリプロピレン系樹脂；ポリ−４−メチルペンテン−１、ポリブテン−１、ポリブタジエン、ポリスチレン、アクリロニトリル−スチレン樹脂；アクリロニトリル−ブタジエン−スチレン樹脂、スチレン−共役ジエン共重合体、スチレン−共役ジエンブロック共重合体水素添加物等のスチレン系エラストマー；フッ素樹脂；ポリメタクリル酸メチル等のアクリル酸樹脂；ナイロン６、ナイロン６６等のポリアミド系樹脂；ポリエチレンテレフタレート、ポリエチレンナフタレート、ポリブチレンブタレート、ポリシクロへキシレンジメチレンテレフタレート等のポリエステル系樹脂；ポリカーボネート、ポリアセタール、ポリアクリルサルフォン、ポリアリレート、ヒドロキシ安息香酸ポリエステル、ポリエーテルイミド、ポリエステルカーボネート、ポリフェニレンエーテル樹脂、ポリ塩化ビニル、ポリ塩化ビニリデン、ポリウレタンが挙げられ、これらの基材は、単独で用いても２種以上の混合物として用いても良く、これらの基材には必要によりフタル酸エステル類（フタル酸ジメチル、フタル酸ジオクチル等）、アジピン酸エステル類、ステアリン酸等の可塑剤が添加されていてもよい。
樹脂蒸散剤は、本エステル化合物を上記基材中に混練した後、射出成型、押出成型、プレス成型等により成型することにより得ることができる。得られた本エステル化合物を含有する樹脂を、必要により成型、裁断等の工程を経て、板状、フィルム状、テープ状、網状、ひも状等の形状に加工することもできる。また、該形状に成型された樹脂性基材に本エステル化合物の溶液を塗布又は含浸することにより樹脂蒸散剤を得ることもできる。これらの樹脂蒸散剤は、例えば動物用首輪、動物用イヤータッグ、シート製剤、誘引ひも、園芸用支柱として加工される。
Examples of the base material of the resin transpiration agent include polyethylene resins such as low density polyethylene, linear low density polyethylene, and high density polyethylene; ethylene-vinyl ester copolymers such as ethylene-vinyl acetate copolymers; Ethylene-methacrylic acid ester copolymers such as methyl methacrylate copolymer and ethylene-ethyl methacrylate copolymer; Ethylene-acrylic acid esters such as ethylene-methyl acrylate copolymer and ethylene-ethyl acrylate copolymer Copolymer; ethylene-vinyl carboxylic acid copolymer such as ethylene-acrylic acid copolymer; ethylene-tetracyclododecene copolymer; polypropylene resin such as propylene copolymer, propylene-ethylene copolymer; poly -4-methylpentene-1, polybutene-1, polybutadiene, poly Tylene, acrylonitrile-styrene resin; styrene-based elastomers such as acrylonitrile-butadiene-styrene resin, styrene-conjugated diene copolymer, styrene-conjugated diene block copolymer hydrogenated product; fluororesin; acrylic acid such as polymethyl methacrylate Resins; Polyamide resins such as nylon 6 and nylon 66; Polyester resins such as polyethylene terephthalate, polyethylene naphthalate, polybutylene butarate, polycyclohexylene dimethylene terephthalate; Polycarbonate, polyacetal, polyacrylsulfone, polyarylate, hydroxy Benzoic acid polyester, polyetherimide, polyester carbonate, polyphenylene ether resin, polyvinyl chloride, polyvinylidene chloride, polyurethane These base materials may be used alone or as a mixture of two or more, and these base materials may be used as necessary for phthalic acid esters (dimethyl phthalate, dioctyl phthalate, etc.), adipic acid. Plasticizers such as esters and stearic acid may be added.
The resin transpiration agent can be obtained by kneading the ester compound in the substrate and then molding it by injection molding, extrusion molding, press molding or the like. The obtained resin containing the ester compound can be processed into a plate shape, a film shape, a tape shape, a net shape, a string shape or the like through steps such as molding and cutting, if necessary. Moreover, a resin transpiration agent can also be obtained by apply | coating or impregnating the solution of this ester compound to the resinous base material shape | molded in this shape. These resin transpiration agents are processed, for example, as animal collars, animal ear tags, sheet preparations, attraction strings, and gardening supports.
毒餌の基材としては、例えば、穀物粉、植物油、糖、結晶セルロース等の餌成分、ジブチルヒドロキシトルエン、ノルジヒドログアイアレチン酸等の酸化防止剤、デヒドロ酢酸等の保存料、トウガラシ粉末等の子どもやペットによる誤食防止剤、及びチーズ香料、タマネギ香料、ピーナッツオイル等の害虫誘引性香料があげられる。 Examples of poison bait base materials include bait ingredients such as cereal flour, vegetable oil, sugar, crystalline cellulose, antioxidants such as dibutylhydroxytoluene and nordihydroguaiaretic acid, preservatives such as dehydroacetic acid, and pepper powder. Anti-fouling agents for children and pets, and pest-attracting fragrances such as cheese fragrance, onion fragrance, and peanut oil.
また、本防除組成物を含有する製剤には、必要により共力剤やその他の害虫防除成分を加えていてもよい。
加え得る共力剤としては、例えばビス−（２，３，３，３−テトラクロロプロピル）エ−テル（Ｓ−４２１）、Ｎ−（２−エチルヘキシル）ビシクロ［２．２．１］ヘプト−５−エン−２，３−ジカルボキシイミド（ＭＧＫ２６４）、α−［２−（２−ブトキシエトキシ）エトキシ］−４，５−メチレンジオキシ−２−プロピルトルエン（ＰＢＯ）等が挙げられる。
加え得る他の害虫防除成分としては、例えば、アレスリン、テトラメトリン、レスメトリン、フラメトリン、フタルトリン、ビフェントリン、エトフェンプロックス、フェンバレレート、シラフルオフェン等のピレスロイド化合物；ジクロルボス、フェニトロチオン、テトラクロロビンホス、フェンチオン、クロルピリホス、ダイアジノン等の有機燐化合物；プロポキサー、カルバリル、メトキサジアゾン、フェノブカルブ等のカーバメート化合物；ルフェヌロン、クロルフルアズロン、ヘキサフルムロン、ジフルベンズロン、シロマジン等のキチン形成阻害物質、ピリプロキシフェン、メトプレン、ハイドロプレン、フェノキシカルブ等の幼若ホルモン様物質；クロチアニジン、イミダクロプリド、チアメトキサム、アセタミプリド等のネオニコチノイド系化合物、Ｎ−フェニルピラゾール系化合物；Ｎ，Ｎ−ジエチル−ｍ−トルアミド、リモネン、リナロール、シトロネラール、メントール、メントン、ヒノキチオール、ゲラニオール、ユーカリプトール、インドキサカルブ、カラン−３，４−ジオール、２−ボルナノン（樟脳）、パラジクロロベンゼン、ナフタリン等を挙げることができる。
In addition, a synergist and other pest control components may be added to the preparation containing the present control composition as necessary.
Examples of synergists that can be added include bis- (2,3,3,3-tetrachloropropyl) ether (S-421), N- (2-ethylhexyl) bicyclo [2.2.1] hept- 5-ene-2,3-dicarboximide (MGK264), α- [2- (2-butoxyethoxy) ethoxy] -4,5-methylenedioxy-2-propyltoluene (PBO) and the like.
Other pest control components that can be added include, for example, pyrethroid compounds such as allethrin, tetramethrin, resmethrin, flamethrin, phthaltrin, bifenthrin, etofenprox, fenvalerate, silafluophene; dichlorvos, fenitrothion, tetrachlorobinphos, fenthion, chlorpyrifos, Organic phosphorus compounds such as diazinon; carbamate compounds such as propoxer, carbaryl, methoxadiazone, and fenocarb; chitin formation inhibitors such as lufenuron, chlorfluazuron, hexaflumuurone, diflubenzuron, and cyromazine, pyriproxyfen, metoprene, hydroprene, phenoxy Juvenile hormone-like substances such as carb; neon such as clothianidin, imidacloprid, thiamethoxam, acetamiprid Nicotinoid compounds, N-phenylpyrazole compounds; N, N-diethyl-m-toluamide, limonene, linalool, citronellal, menthol, menthone, hinokitiol, geraniol, eucalyptol, indoxacarb, caran-3,4-diol , 2-bornanone (camphor), paradichlorobenzene, naphthalene and the like.
本発明のハエの羽化抑制方法は、本発明の羽化阻害剤をハエの幼虫又は蛹に対して施用するが、具体的にハエの幼虫や蛹の存在が確認されていない場所でも、幼虫や蛹が生息しているであろう場所に施用する形態も含む。
本発明の羽化阻害剤の施用方法としては、具体的には、例えば以下の方法が挙げられ、羽化阻害剤の形態、使用場所等に応じて適宜選択できる。
（１）本発明の羽化阻害剤をそのままハエの幼虫又は蛹、或いはハエの幼虫又は蛹が存在している場所に散布する方法。
（２）本発明の羽化阻害剤を水等の溶媒で希釈した後に、ハエの幼虫又は蛹、或いはハエの幼虫又は蛹が存在している場所に散布処理する方法。
（３）本発明の羽化阻害剤をハエの幼虫又は蛹が存在している場所で加熱し、有効成分を蒸散させる方法。
（４）本発明の羽化阻害剤をハエの幼虫又は蛹が存在している場所で自然に揮散させる方法。
通常、乳剤、水和剤、フロアブル剤、マイクロカプセル製剤等に製剤化された本発明の羽化阻害剤を、本エステル化合物の濃度が０．０１〜１０００ｐｐｍとなるように希釈する。
本エステル化合物の施用量、施用濃度はいずれも本防除組成物の形態、施用時期、施用場所、施用方法、被害状況等に応じて適宜定めることができる。
本発明の羽化阻害剤の施用量は空間に適用するときは、本エステル化合物の量として通常０．０００１〜１０００ｍｇ／ｍ3であり、平面に適用するときは０．０００１〜１０００ｍｇ／ｍ2である。殺虫線香、電気殺虫マット等はその製剤形態に応じて加熱により有効成分を揮散させて施用する。樹脂製剤、紙製剤、錠剤、不織布製剤、編織物製剤、シート製剤等は例えば施用する空間にそのまま放置する、及び該製剤に送風することにより使用できる。
本発明の羽化阻害剤を使用する空間としては、例えば居間、台所、食堂、食器棚、トイレ、浴場、物置、倉庫、車、クローゼット、押入れ、和ダンス内等が挙げられ、さらに野外の開放空間で施用することもできる。
The fly emergence suppression method of the present invention applies the emergence inhibitor of the present invention to fly larvae or pupae, but the larvae and pupae are specifically used in places where the presence of fly larvae or pupae has not been confirmed. Including forms that are applied to places that would be inhabited.
Specific examples of the application method of the emergence inhibitor of the present invention include the following methods, which can be appropriately selected depending on the form of the emergence inhibitor, the place of use, and the like.
(1) A method of spraying the emergence inhibitor of the present invention as it is to a place where a fly larva or moth or a fly larva or moth exists.
(2) A method in which the emergence inhibitor of the present invention is diluted with a solvent such as water and then sprayed on the fly larvae or pupae or the place where the fly larvae or pupae are present.
(3) A method in which the emergence inhibitor of the present invention is heated in a place where fly larvae or moths are present to evaporate the active ingredient.
(4) A method in which the emergence inhibitor of the present invention is volatilized naturally at a place where fly larvae or moths are present.
Usually, the emergence inhibitor of the present invention formulated into an emulsion, wettable powder, flowable preparation, microcapsule preparation or the like is diluted so that the concentration of the ester compound is 0.01 to 1000 ppm.
The application amount and application concentration of the ester compound can be appropriately determined according to the form, application time, application place, application method, damage situation, etc. of the present control composition.
The application rate of the emergence inhibitor of the present invention is usually 0.0001 to 1000 mg / m 3 as the amount of the ester compound when applied to a space, and 0.0001 to 1000 mg / m 2 when applied to a plane. is there. Insecticidal incense sticks, electric insecticidal mats, and the like are applied by volatilizing active ingredients by heating in accordance with the formulation form. Resin preparations, paper preparations, tablets, nonwoven fabric preparations, knitted fabric preparations, sheet preparations and the like can be used, for example, by leaving them as they are in the space to be applied and blowing them over the preparations.
Examples of the space where the emergence inhibitor of the present invention is used include a living room, kitchen, canteen, cupboard, toilet, bathhouse, storeroom, warehouse, car, closet, closet, Japanese dance, etc. Can also be applied.
以下、製剤例及び試験例等により、本発明をさらに詳しく説明するが、本発明は、これらの例に限定されるものではない。まず、製剤例を示す。尚、実施例において、特に明記しない限り、部は質量部を意味する。 Hereinafter, the present invention will be described in more detail with reference to formulation examples and test examples, but the present invention is not limited to these examples. First, formulation examples are shown. In Examples, unless otherwise specified, parts means parts by mass.
製剤例１
本エステル化合物のいずれか１種０．６部、キシレン５部、脱臭灯油３．４部および乳化剤｛アトモス３００（アトラスケミカル社登録商標名）｝１部を混合溶解したものと純水５０部とをエアゾール容器に充填し、該容器にバルブ部分を取り付け、該バルブ部分を通じて噴射剤（液化石油ガス）４０部を加圧充填して、水性エアゾールを得る。
Formulation Example 1
0.6 parts of any one of the present ester compounds, 5 parts of xylene, 3.4 parts of deodorized kerosene and 1 part of an emulsifier {Atmos 300 (registered trademark of Atlas Chemical Company)} and 50 parts of pure water Is filled in an aerosol container, a valve portion is attached to the container, and 40 parts of a propellant (liquefied petroleum gas) is pressurized and filled through the valve portion to obtain an aqueous aerosol.
製剤例２
本エステル化合物のいずれか１種５．５部をアセトン９４．５部に溶解する。この溶液の適当量を折り畳み可能な構造を有する紙（２０００ｃｍ2）に塗布し、アセトンを風乾して、紙蒸散剤を得る。
Formulation Example 2
5.5 parts of any one of the ester compounds is dissolved in 94.5 parts of acetone. An appropriate amount of this solution is applied to a paper (2000 cm 2 ) having a foldable structure, and acetone is air-dried to obtain a paper transpiration agent.
製剤例３
０．５ｃｍ（厚さ）×６９ｃｍ（長さ）×０．２ｃｍ（幅）のハニカム構造の紙細工片を一方の端から巻いて、直径５．５ｃｍ、高さ０．２ｃｍの略円柱状の担体を作製する。本エステル化合物のいずれか１種５．５部をアセトン９４．５部に溶解した溶液の適量を、前記担体に均一に塗布した後、アセトンを風乾させて、紙蒸散剤を得る。
Formulation Example 3
A paper work piece having a honeycomb structure of 0.5 cm (thickness) × 69 cm (length) × 0.2 cm (width) was wound from one end to form a substantially cylindrical shape having a diameter of 5.5 cm and a height of 0.2 cm. A carrier is prepared. After an appropriate amount of a solution obtained by dissolving 5.5 parts of any one of the present ester compounds in 94.5 parts of acetone is uniformly applied to the carrier, acetone is air-dried to obtain a paper transpiration agent.
製剤例４
立体編地（商品名：フュージョン、型番：ＡＫＥ６９４４０、販売元：旭化成せんい株式会社、厚さ：４．３ｍｍ、目付：３２１ｇ／ｍ2、ポリアミド製）を直径５ｃｍの略円形状に裁断する。本エステル化合物のいずれか１種５．５部をアセトン９４．５部に溶解した溶液の適量を、前記の裁断した立体編地に均一に塗布した後、アセトンを風乾させて、編織物蒸散剤を得る。
Formulation Example 4
A three-dimensional knitted fabric (trade name: Fusion, model number: AKE69440, distributor: Asahi Kasei Fibers Co., Ltd., thickness: 4.3 mm, basis weight: 321 g / m 2 , made of polyamide) is cut into a substantially circular shape having a diameter of 5 cm. An appropriate amount of a solution obtained by dissolving 5.5 parts of any one of these ester compounds in 94.5 parts of acetone is uniformly applied to the cut three-dimensional knitted fabric, and then acetone is air-dried to form a knitted fabric transpiration agent. Get.
製剤例５
エチレン−メタクリル酸メチル共重合体（メタクリル酸メチル含有量：１０重量％、ＭＦＲ＝２〔ｇ／10min〕）９７．８部、本エステル化合物のいずれか１種２．２部を、４５mmφ同方向二軸押出機にて１３０℃で溶融混練し、更に４０mmφ押出機にて１５０℃で溶融混練し、Ｔダイからシート状に押出し、冷却ロールにて冷却して、樹脂蒸散剤を得る。
得る。
Formulation Example 5
97.8 parts of ethylene-methyl methacrylate copolymer (methyl methacrylate content: 10% by weight, MFR = 2 [g / 10 min]), 2.2 parts of any one of these ester compounds, 45 mmφ in the same direction Melting and kneading at 130 ° C. with a twin-screw extruder, further melt-kneading at 150 ° C. with a 40 mmφ extruder, extruding into a sheet form from a T die, and cooling with a cooling roll to obtain a resin transpiration agent.
obtain.
製剤例６
エチレン−メタクリル酸メチル共重合体（共重合体中のメタクリル酸メチルの割合：２５重量％、商品名：アクリフトＷＫ３０７、住友化学株式会社製）２８部、本エステル化合物のいずれか１種５部を密閉式加圧ニーダー（森山製作所製）を用いて溶融混練し、得られた混練物を押出機から押し出しながらホットカットして、ペレットを得る。該ペレット３３部と直鎖状低密度ポリエチレン（エチレンの単独重合体）のペレット６７部とを混合・混練して混練物を得る。
次いで、この混練物を射出成形機から金型を介して成形することにより、縦１０．９ｃｍ。横７．９ｃｍ、厚み４．６ｍｍでかつ縦５．６ｍｍ、横５．２５ｍｍの連続穴が空いている格子状のメッシュシート（開孔率６５％）の樹脂蒸散剤を得る。
Formulation Example 6
Ethylene-methyl methacrylate copolymer (ratio of methyl methacrylate in the copolymer: 25% by weight, trade name: ACRIFT WK307, manufactured by Sumitomo Chemical Co., Ltd.) 28 parts, 5 parts of any one of the ester compounds The mixture is melt-kneaded using a closed pressure kneader (manufactured by Moriyama Seisakusho), and the resulting kneaded product is hot cut while being extruded from an extruder to obtain pellets. 33 parts of the pellets and 67 parts of linear low density polyethylene (ethylene homopolymer) pellets are mixed and kneaded to obtain a kneaded product.
Next, the kneaded product was molded from an injection molding machine through a mold to obtain a length of 10.9 cm. A resin transpiration agent of a grid-like mesh sheet (opening ratio: 65%) having a width of 7.9 cm, a thickness of 4.6 mm, a length of 5.6 mm, and a width of 5.25 mm is obtained.
製剤例７
エチレン−メタクリル酸メチル共重合体（共重合体中のメタクリル酸メチルの割合：１８重量％、商品名：アクリフトＷＨ３０３、住友化学株式会社製）１８部、本エステル化合物のいずれか１種２部を密閉式加圧ニーダー（森山製作所製）を用いて溶融混練し、得られた混練物を押出機から押し出しながらホットカットして、ペレットを得る。このペレット２０部と直鎖状低密度ポリエチレン（エチレンの単独重合体）のペレット８０部とを混合・混練して混練物を得る。
次いで、この混練物を押出機からネット成形用異形ダイスを介して押出すことにより、一辺が約５ｍｍの略ひし形の連続穴を有するネット（ネットを形成するフィラメントの直径は約０．８３ｍｍ、開孔率７０％、５０目、２５ｇ／ｍ）が周囲長約２０ｃｍの円筒形状をした成型体として得る。この成形体を長さ２０ｃｍに切断して樹脂蒸散剤を得る。
Formulation Example 7
18 parts of ethylene-methyl methacrylate copolymer (ratio of methyl methacrylate in the copolymer: 18% by weight, trade name: ACRIFTH WH303, manufactured by Sumitomo Chemical Co., Ltd.), 2 parts of any one of these ester compounds The mixture is melt-kneaded using a closed pressure kneader (manufactured by Moriyama Seisakusho), and the resulting kneaded product is hot cut while being extruded from an extruder to obtain pellets. 20 parts of the pellets and 80 parts of linear low density polyethylene (ethylene homopolymer) pellets are mixed and kneaded to obtain a kneaded product.
Next, the kneaded product is extruded from an extruder through a deformed die for forming a net, so that a net having a substantially rhombic continuous hole having a side of about 5 mm (the diameter of the filament forming the net is about 0.83 mm, open). A porous molded body having a porosity of 70%, 50 meshes, 25 g / m) having a peripheral length of about 20 cm is obtained. This molded body is cut into a length of 20 cm to obtain a resin transpiration agent.
製剤例８
エチレン−メタクリル酸メチル共重合体（共重合体中のメタクリル酸メチルの割合：１０重量％、商品名：アクリフトＷＤ３０１、住友化学株式会社製）９５部、本エステル化合物のいずれか１種５部を密閉式加圧ニーダー（森山製作所製）を用いて溶融混練し、得られた混練物を押出機から押し出しながらホットカットして、ペレットを得る。
次いで、このペレットを練って得た練物を押出成形機からネット成形用異形ダイスを介して押出すことにより、一辺が約５ｍｍの略ひし形の連続穴を有するネット（ネットを形成するフィラメントの直径は約０．８３ｍｍ、開孔率７０％、５０目、２５ｇ／ｍ）が周囲長約２０ｃｍの円筒形状をした成形体として得る。この成形体を長さ１０ｃｍに切断して樹脂蒸散剤を得る。
Formulation Example 8
95 parts of ethylene-methyl methacrylate copolymer (ratio of methyl methacrylate in the copolymer: 10% by weight, trade name: ACRIFT WD301, manufactured by Sumitomo Chemical Co., Ltd.), 5 parts of any one of these ester compounds The mixture is melt-kneaded using a closed pressure kneader (manufactured by Moriyama Seisakusho), and the resulting kneaded product is hot cut while being extruded from an extruder to obtain pellets.
Next, the kneaded material obtained by kneading the pellets is extruded from an extruder through a deformed die for net forming, so that a net having a continuous hole of approximately rhombus with a side of about 5 mm (the diameter of the filament forming the net is A cylindrical shaped body having a circumference of about 20 cm is obtained with an opening ratio of about 0.83 mm, a porosity of 70%, 50 stitches, and 25 g / m. This molded body is cut into a length of 10 cm to obtain a resin transpiration agent.
製剤例９
エチレン−メタクリル酸メチル共重合体（共重合体中のメタクリル酸メチルの割合：２５重量％、商品名：アクリフトＷＫ３０７、住友化学株式会社製）２８部、本エステル化合物のいずれか１種５部を密閉式加圧ニーダー（森山製作所製）を用いて溶融混練し、得られた混練物を押出機から押し出しながらホットカットして、ペレットを得る。このペレット３３部と直鎖状低密度ポリエチレン（エチレンの単独重合体）のペレット６７部とを混合・混練して混練物を得る。
次いで、この混練物を押出成形機からネット成形用異形ダイスを介して押出し、延伸することにより、一辺が約５ｍｍの略ひし形の連続穴を有するネット（ネットを形成するフィラメントの直径は約０．８３ｍｍ、開孔率８２％、８０目、１８ｇ／ｍ）が周囲長約２０ｃｍの円筒形状をした成形体として得る。この成形体を長さ２０ｃｍに切断して樹脂蒸散剤を得る。
Formulation Example 9
Ethylene-methyl methacrylate copolymer (ratio of methyl methacrylate in the copolymer: 25% by weight, trade name: ACRIFT WK307, manufactured by Sumitomo Chemical Co., Ltd.) 28 parts, 5 parts of any one of the ester compounds The mixture is melt-kneaded using a closed pressure kneader (manufactured by Moriyama Seisakusho), and the resulting kneaded product is hot cut while being extruded from an extruder to obtain pellets. 33 parts of the pellets and 67 parts of linear low density polyethylene (ethylene homopolymer) pellets are mixed and kneaded to obtain a kneaded product.
Next, this kneaded product is extruded from an extruder through a deformed die for net forming and stretched, whereby a net having a substantially rhombic continuous hole having a side of about 5 mm (the diameter of the filament forming the net is about 0.00 mm). 83 mm, open area ratio 82%, 80 mesh, 18 g / m) is obtained as a cylindrical molded body having a peripheral length of about 20 cm. This molded body is cut into a length of 20 cm to obtain a resin transpiration agent.
製剤例１０
エチレン−メタクリル酸メチル共重合体（共重合体中のメタクリル酸メチルの割合：１８重量％、商品名：アクリフトＷＨ３０３、住友化学株式会社製）４５部、本エステル化合物のいずれか１種５部を密閉式加圧ニーダー（森山製作所製）を用いて溶融混練し、得られた混練物を押出機から押し出しながらホットカットして、ペレットを得る。このペレット５０部と直鎖状低密度ポリエチレン（エチレンの単独重合体）のペレット５０部とを混合・混練して混練物を得る。
次いで、この混練物を押出成形機からネット成形用異形ダイスを介して押出し、延伸することにより、一辺が約５ｍｍの略ひし形の連続穴を有するネット（ネットを形成するフィラメントの直径は約０．８３ｍｍ、開孔率８２％、８０目、１８ｇ／ｍ）が周囲長約２０ｃｍの円筒形状をした成形体として得る。この成形体を長さ２０ｃｍに切断して樹脂蒸散剤を得る。
Formulation Example 10
45 parts of ethylene-methyl methacrylate copolymer (ratio of methyl methacrylate in the copolymer: 18% by weight, trade name: ACRIFTH WH303, manufactured by Sumitomo Chemical Co., Ltd.), 5 parts of any one of these ester compounds The mixture is melt-kneaded using a closed pressure kneader (manufactured by Moriyama Seisakusho), and the resulting kneaded product is hot cut while being extruded from an extruder to obtain pellets. 50 parts of these pellets and 50 parts of pellets of linear low density polyethylene (ethylene homopolymer) are mixed and kneaded to obtain a kneaded product.
Next, this kneaded product is extruded from an extruder through a deformed die for net forming and stretched, whereby a net having a substantially rhombic continuous hole having a side of about 5 mm (the diameter of the filament forming the net is about 0.00 mm). 83 mm, open area ratio 82%, 80 mesh, 18 g / m) is obtained as a cylindrical molded body having a peripheral length of about 20 cm. This molded body is cut into a length of 20 cm to obtain a resin transpiration agent.
製剤例１１
エチレン−メタクリル酸メチル共重合体（共重合体中のメタクリル酸メチルの割合：２５重量％、商品名：アクリフトＷＫ３０７、住友化学株式会社製）２８部、本エステル化合物のいずれか１種５部を密閉式加圧ニーダー（森山製作所製）を用いて溶融混練し、得られた混練物を押出機から押し出しながらホットカットして、ペレットを得る。このペレット３３部と直鎖状低密度ポリエチレン（エチレンの単独重合体）のペレット６７部とを混合・混練して混練物を得る。
次いで、この混練物を押出成形機からネット成形用異形ダイスを介して押出すことにより、一辺が約２．５ｍｍの略ひし形の連続穴を有するネット（ネットを形成するフィラメントの直径は約０．５ｍｍ、開孔率６４％、１６０目、５５ｇ／ｍ）が周囲長約５０ｃｍの円筒形状をした成形体として得る。この成形体を横２４ｃｍ、縦４０ｃｍのメッシュシート状に切断して樹脂蒸散剤を得る。
Formulation Example 11
Ethylene-methyl methacrylate copolymer (ratio of methyl methacrylate in the copolymer: 25% by weight, trade name: ACRIFT WK307, manufactured by Sumitomo Chemical Co., Ltd.) 28 parts, 5 parts of any one of the ester compounds The mixture is melt-kneaded using a closed pressure kneader (manufactured by Moriyama Seisakusho), and the resulting kneaded product is hot cut while being extruded from an extruder to obtain pellets. 33 parts of the pellets and 67 parts of linear low density polyethylene (ethylene homopolymer) pellets are mixed and kneaded to obtain a kneaded product.
Next, this kneaded product is extruded from an extruder through a deformed die for forming a net, so that a net having a substantially diamond-shaped continuous hole having a side of about 2.5 mm (the diameter of the filament forming the net is about 0.00 mm). 5 mm, hole area ratio 64%, 160 mesh, 55 g / m) is obtained as a cylindrical shaped body having a peripheral length of about 50 cm. The molded body is cut into a mesh sheet having a width of 24 cm and a length of 40 cm to obtain a resin transpiration agent.
製剤例１２
エチレン−メタクリル酸メチル共重合体（共重合体中のメタクリル酸メチルの割合：１８重量％、商品名：アクリフトＷＨ３０３、住友化学株式会社製）１８部、本エステル化合物のいずれか１種２部を密閉式加圧ニーダー（森山製作所製）を用いて溶融混練し、得られた混練物を押出機から押し出しながらホットカットして、ペレットを得る。このペレット２０部と直鎖状低密度ポリエチレン（エチレンの単独重合体）のペレット８ｋｇとを混合・混練して混練物を得る。
次いで、この混練物を押出成形機からネット成形用異形ダイスを介して押出すことにより、一辺が約２．５ｍｍの略ひし形の連続穴を有するネット（ネットを形成するフィラメントの直径は約０．５ｍｍ、開孔率６４％、１６０目、５５ｇ／ｍ）が周囲長約５０ｃｍの円筒形状をした成形体として得る。この成形体を長さ２０ｃｍに切断して樹脂蒸散剤を得る。
Formulation Example 12
18 parts of ethylene-methyl methacrylate copolymer (ratio of methyl methacrylate in the copolymer: 18% by weight, trade name: ACRIFTH WH303, manufactured by Sumitomo Chemical Co., Ltd.), 2 parts of any one of these ester compounds The mixture is melt-kneaded using a closed pressure kneader (manufactured by Moriyama Seisakusho), and the resulting kneaded product is hot cut while being extruded from an extruder to obtain pellets. 20 parts of these pellets and 8 kg of linear low density polyethylene (ethylene homopolymer) pellets are mixed and kneaded to obtain a kneaded product.
Next, this kneaded product is extruded from an extruder through a deformed die for forming a net, so that a net having a substantially diamond-shaped continuous hole having a side of about 2.5 mm (the diameter of the filament forming the net is about 0.00 mm). 5 mm, hole area ratio 64%, 160 mesh, 55 g / m) is obtained as a cylindrical shaped body having a peripheral length of about 50 cm. This molded body is cut into a length of 20 cm to obtain a resin transpiration agent.
製剤例１３
エチレン−メタクリル酸メチル共重合体（共重合体中のメタクリル酸メチルの割合：２５重量％、商品名：アクリフトＷＫ３０７、住友化学株式会社製）２８部、本エステル化合物のいずれか１種５部を密閉式加圧ニーダー（森山製作所製）を用いて溶融混練し、得られた混練物を押出機から押し出しながらホットカットして、ペレットを得る。このペレット３３部と直鎖状低密度ポリエチレン（エチレンの単独重合体）のペレット６７部とを混合・混練して混練物を得る。
次いで、この混練物を押出成形機からネット成形用異形ダイスを介して押出すことにより、一辺が約２．５ｍｍの略ひし形の連続穴を有するネット（ネットを形成するフィラメントの直径は約０．５ｍｍ、開孔率６４％、６０目、１８ｇ／ｍ）が周囲長約２０ｃｍの円筒形状をした成形体として得る。この成型体を切断することにより、幅２３ｃｍの反物状ネットを得る。この成形体を横２３ｃｍ、縦２３ｃｍの正方形のメッシュシート状に切断後、４つの直角二等辺三角形（短辺１５ｃｍ、長辺２３ｃｍ）に切断して樹脂蒸散剤を得る。
Formulation Example 13
Ethylene-methyl methacrylate copolymer (ratio of methyl methacrylate in the copolymer: 25% by weight, trade name: ACRIFT WK307, manufactured by Sumitomo Chemical Co., Ltd.) 28 parts, 5 parts of any one of the ester compounds The mixture is melt-kneaded using a closed pressure kneader (manufactured by Moriyama Seisakusho), and the resulting kneaded product is hot cut while being extruded from an extruder to obtain pellets. 33 parts of the pellets and 67 parts of linear low density polyethylene (ethylene homopolymer) pellets are mixed and kneaded to obtain a kneaded product.
Next, this kneaded product is extruded from an extruder through a deformed die for forming a net, so that a net having a substantially diamond-shaped continuous hole having a side of about 2.5 mm (the diameter of the filament forming the net is about 0.00 mm). 5 mm, open area ratio 64%, 60 mesh, 18 g / m) is obtained as a cylindrical shaped body having a peripheral length of about 20 cm. By cutting this molded body, a cloth-like net having a width of 23 cm is obtained. The molded body is cut into a square mesh sheet having a width of 23 cm and a length of 23 cm, and then cut into four right-angled isosceles triangles (short side 15 cm, long side 23 cm) to obtain a resin transpiration agent.
製剤例１４
エチレン−メタクリル酸メチル共重合体（共重合体中のメタクリル酸メチルの割合：２５重量％、商品名：アクリフトＷＫ３０７、住友化学株式会社製）９５部、本エステル化合物のいずれか１種５部を密閉式加圧ニーダー（森山製作所製）を用いて溶融混練し、得られた混練物を押出機から押し出しながらホットカットして、ペレットを得る。
次いで、このペレットを練って得られた練物を押出成形機からネット成形用異形ダイスを介して押出すことにより、一辺が約５ｍｍの略ひし形の連続穴を有するネット（ネットを形成するフィラメントの直径は約０．８３ｍｍ、開孔率７０％、８０目、１８ｇ／ｍ）が周囲長約２０ｃｍの円筒形状をした成形体として得る。この成形体を長さ１０ｃｍに切断して樹脂蒸散剤を得る。
Formulation Example 14
95 parts of ethylene-methyl methacrylate copolymer (ratio of methyl methacrylate in the copolymer: 25% by weight, trade name: ACLIFT WK307, manufactured by Sumitomo Chemical Co., Ltd.), 5 parts of any one of these ester compounds The mixture is melt-kneaded using a closed pressure kneader (manufactured by Moriyama Seisakusho), and the resulting kneaded product is hot cut while being extruded from an extruder to obtain pellets.
Next, the kneaded material obtained by kneading the pellets is extruded from an extruder through a deformed die for net forming, and thereby a net having a substantially rhombic continuous hole having a side of about 5 mm (diameter of filament forming the net). Can be obtained as a molded body having a cylindrical shape of about 0.83 mm, an aperture ratio of 70%, 80 meshes, and a circumference of about 20 cm. This molded body is cut into a length of 10 cm to obtain a resin transpiration agent.
製剤例１５
エチレン−メタクリル酸メチル共重合体（共重合体中のメタクリル酸メチルの割合：２５重量％、商品名：アクリフトＷＫ３０７、住友化学株式会社製）９５部、本エステル化合物のいずれか１種５部を密閉式加圧ニーダー（森山製作所製）を用いて溶融混練し、得られた混練物を押出機から押し出しながらホットカットして、ペレットを得る。
次いで、このペレットを練って得られた練物を押出成形機からネット成形用異形ダイスを介して押出すことにより、一辺が約５ｍｍの略ひし形の連続穴を有するネット（ネットを形成するフィラメントの直径は約０．８３ｍｍ、開孔率８２％、１２０目、１８ｇ／ｍ）が周囲長約２０ｃｍの円筒形状をした成形体として得る。この成形体を長さ２０ｃｍに切断して樹脂蒸散剤を得る。
Formulation Example 15
95 parts of ethylene-methyl methacrylate copolymer (ratio of methyl methacrylate in the copolymer: 25% by weight, trade name: ACLIFT WK307, manufactured by Sumitomo Chemical Co., Ltd.), 5 parts of any one of these ester compounds The mixture is melt-kneaded using a closed pressure kneader (manufactured by Moriyama Seisakusho), and the resulting kneaded product is hot cut while being extruded from an extruder to obtain pellets.
Next, the kneaded material obtained by kneading the pellets is extruded from an extruder through a deformed die for net forming, and thereby a net having a substantially rhombic continuous hole having a side of about 5 mm (diameter of filament forming the net). Can be obtained as a molded body having a cylindrical shape with a peripheral length of about 20 cm. This molded body is cut into a length of 20 cm to obtain a resin transpiration agent.
製剤例１６
エチレン−メタクリル酸メチル共重合体（共重合体中のメタクリル酸メチルの割合：２５重量％、商品名：アクリフトＷＫ３０７、住友化学株式会社製）４０部、本エステル化合物のいずれか１種１１部を密閉式加圧ニーダー（森山製作所製）を用いて溶融混練し、得られた混練物を押出機から押し出しながらホットカットして、ペレットを得る。このペレット５０部と直鎖状低密度ポリエチレン（エチレンの単独重合体）のペレット５０部とを混合・混練して混練物を得る。
次いで、この混練物を押出機からネット成形用異形ダイスを介して押出すことにより、一辺が約２．５ｍｍの略ひし形の連続穴を有するネット（ネットを形成するフィラメントの直径は約０．５ｍｍ、開孔率７０％、８０目）が周囲長約１６ｃｍの円筒形状をした成型体として得る。この成形体を長さ２０ｃｍに切断して樹脂蒸散剤を得る。
Formulation Example 16
40 parts of ethylene-methyl methacrylate copolymer (ratio of methyl methacrylate in the copolymer: 25% by weight, trade name: ACRIFT WK307, manufactured by Sumitomo Chemical Co., Ltd.), 11 parts of any one of these ester compounds The mixture is melt-kneaded using a closed pressure kneader (manufactured by Moriyama Seisakusho), and the resulting kneaded product is hot cut while being extruded from an extruder to obtain pellets. 50 parts of these pellets and 50 parts of pellets of linear low density polyethylene (ethylene homopolymer) are mixed and kneaded to obtain a kneaded product.
Next, the kneaded product is extruded from an extruder through a deformed die for forming a net, so that a net having a substantially rhombic continuous hole having a side of about 2.5 mm (the diameter of the filament forming the net is about 0.5 mm). , Open area ratio 70%, 80 mesh) is obtained as a cylindrical molded body having a peripheral length of about 16 cm. This molded body is cut into a length of 20 cm to obtain a resin transpiration agent.
次に、本エステル化合物がハエの幼虫又は蛹に対して効果的な羽化抑制効力を有することを試験例として示す。
試験例１及び２では、下記に記載の方法によりキイロショウジョウバエが産卵した昆虫用人口飼料を用いて、本発明の羽化阻害剤による羽化抑制効力について試験を行った。
Next, it is shown as a test example that this ester compound has an effective emergence-inhibiting effect on fly larvae or pupae.
In Test Examples 1 and 2, the insect emergence inhibitory effect of the present invention was used to test the emergence inhibitory effect of an insect artificial feed spawned by Drosophila melanogaster by the method described below.
キイロショウジョウバエの幼虫および蛹を含む昆虫用人口飼料の調製方法
プラスチック製カップ（底部の直径１０ｃｍ、開口部の直径１２.５ｃｍ、高さ９.５ｃｍ、体積９５０ｃｍ３）内に、昆虫用人口飼料（直径５０ｍｍ、厚さ２ｍｍ、インセクタＬＦＳ；Insecta Larva Food Sausage type、日本農産工業株式会社製）と水を入れた。該カップをキイロショウジョウバエ成虫約６００頭が放たれたケージ（枠：５０ｃｍ×５０ｃｍ×５０ｃｍ、ナイロンメッシュ）内の中央に置き、温度２５±２℃下にて保存した。２日後に人口飼料入りカップを該ケージ内より取り出し、以下の試験に用いた（以下、キイロショウジョウバエが産卵した人口飼料を試験用ハエ幼虫含有物と記す）。
試験用ハエ幼虫含有物より、２週間の間に平均して３００頭程度のキイロショウジョウバエの成虫が羽化する。
Method for preparing insect feed including larvae and pupae of Drosophila melanogaster In a plastic cup (bottom diameter 10 cm, opening diameter 12.5 cm, height 9.5 cm, volume 950 cm 3 ) 50 mm in diameter, 2 mm in thickness, in-sector LFS; Insecta Larva Food Sausage type, manufactured by Nippon Agricultural Industry Co., Ltd.) and water were added. The cup was placed in the center of a cage (frame: 50 cm × 50 cm × 50 cm, nylon mesh) from which about 600 adult Drosophila melanogaster were released and stored at a temperature of 25 ± 2 ° C. Two days later, a cup containing artificial feed was removed from the cage and used for the following tests (hereinafter, the artificial feed laid by Drosophila melanogaster is referred to as a test fly larvae-containing material).
On average, about 300 adults of Drosophila melanogaster emerge from the test fly larvae-containing material during two weeks.
試験例１
濾紙（標準用濾紙 Ｎｏ．２、東洋濾紙株式会社製、質量 １２５ｇ／ｍ2、厚さ ０．２６ｍｍ）を４ｃｍ×４ｃｍに裁断し、本エステル化合物Ａ ２０ｍｇのアセトン溶液を該濾紙に均一に塗布した後、アセトンを風乾させて紙蒸散剤（以下、本蒸散剤１と記す。）を得た。
同様にして、本エステル化合物Ｂ ２０ｍｇを担持させた紙蒸散剤（以下、本蒸散剤２と記す。）、本エステル化合物Ｃ ２０ｍｇを担持させた紙蒸散剤（以下、本蒸散剤３と記す。）、及び、本エステル化合物Ｄ ２０ｍｇを担持させた紙蒸散剤（以下、本蒸散剤４と記す。）を作製した。
上記した試験用ハエ幼虫含有物が入ったプラスチック製カップ（底部の直径１０ｃｍ、開口部の直径１２.５ｃｍ、高さ９.５ｃｍ、体積９５０ｃｍ３）内に、本蒸散剤１を設置し、カップに蓋をして、温度２５±２℃にて保存した。（以下、試験区と記す。）
一方、対照区として、本エステル化合物を含有する蒸散剤を入れていない、試験用ハエ幼虫含有物が入ったプラスチック製カップに蓋をして、温度２５±２℃にて保存した。
２週間後に試験区及び対照区で羽化した虫数を数えた。各々の試験区で羽化した虫数から、下記式により、本エステル化合物Ａを有効成分として含有する本発明の羽化阻害剤の羽化抑制率を求めた。本蒸散剤２、本蒸散剤３および本蒸散剤４を用いて同様に試験を行った。結果を表１にまとめた。
Test example 1
Filter paper (standard filter paper No. 2, manufactured by Toyo Roshi Kaisha, Ltd., mass 125 g / m 2 , thickness 0.26 mm) is cut into 4 cm × 4 cm, and 20 mg of this ester compound A 20 mg acetone solution is uniformly applied to the filter paper. Then, acetone was air-dried to obtain a paper transpiration agent (hereinafter referred to as the present transpiration agent 1).
Similarly, a paper transpiration agent carrying 20 mg of the present ester compound B (hereinafter referred to as the present transpiration agent 2) and a paper transpiration agent carrying 20 mg of the present ester compound C (hereinafter referred to as the present transpiration agent 3). And a paper transpiration agent carrying 20 mg of the present ester compound D (hereinafter referred to as the present transpiration agent 4).
The present transpiration agent 1 is placed in a plastic cup (bottom diameter 10 cm, opening diameter 12.5 cm, height 9.5 cm, volume 950 cm 3 ) containing the above-mentioned test fly larvae-containing material. The lid was covered and stored at a temperature of 25 ± 2 ° C. (Hereafter referred to as test zone)
On the other hand, as a control group, a plastic cup containing the test fly larvae containing no transpiration agent containing the present ester compound was capped and stored at a temperature of 25 ± 2 ° C.
Two weeks later, the number of insects emerged in the test group and the control group was counted. From the number of insects that emerged in each test section, the emergence inhibition rate of the emergence inhibitor of the present invention containing the present ester compound A as an active ingredient was determined by the following formula. The same test was conducted using the present transpiration agent 2, the present transpiration agent 3, and the present transpiration agent 4. The results are summarized in Table 1.
羽化抑制率（％）＝ (対照区の羽化数−試験区の羽化数)/対照区の羽化数×100 Rate of emergence inhibition (%) = (number of emergence in control group-number of emergence in test group) / number of emergence in control group x 100
試験例２
製剤例１６に準じて製造された、本エステル化合物Ａが練りこまれた円筒形状ネットの樹脂蒸散剤を円周約１６ｃｍ×１．５ｃｍの形状に裁断し、本エステル化合物Ａ２０ｍｇ含有の樹脂蒸散剤（以下、本蒸散剤５と記す。）を得た。
同様にして、本エステル化合物Ｂ ２０ｍｇ含有の円周約１６ｃｍ×１．５ｃｍの形状の樹脂蒸散剤（以下、本蒸散剤６と記す。）を得た。
上記した試験用ハエ幼虫含有物が入ったプラスチック製カップ（底部の直径１０ｃｍ、開口部の直径１２.５ｃｍ、高さ９.５ｃｍ、体積９５０ｃｍ３）内に、本蒸散剤５を設置し、カップに蓋をして、温度２５±２℃にて２週間保存した。
試験例１と同様に、羽化した虫数から羽化抑制率を求めた。本蒸散剤６を用いて同様に試験を行った。結果を表２にまとめた。
Test example 2
The resin transpiration agent of the cylindrical net manufactured according to Formulation Example 16 and kneaded with the ester compound A is cut into a shape of a circumference of about 16 cm × 1.5 cm, and the resin transpiration agent containing 20 mg of the ester compound A (Hereinafter referred to as the present transpiration agent 5).
Similarly, a resin transpiration agent having a circumference of about 16 cm × 1.5 cm containing 20 mg of the present ester compound B (hereinafter referred to as the present transpiration agent 6) was obtained.
The above-mentioned plastic cup test fly larvae inclusions containing (bottom diameter 10 cm, diameter opening 12.5 cm, height 9.5cm, volume 950 cm 3) in and installing the transpiration formulation 5, the cup The lid was covered and stored at a temperature of 25 ± 2 ° C. for 2 weeks.
In the same manner as in Test Example 1, the rate of emergence inhibition was determined from the number of insects that had emerged. The same test was conducted using the present transpiration agent 6. The results are summarized in Table 2.
本羽化抑制法により、ハエの羽化を効果的に抑制することができる。 The emergence suppression method can effectively suppress the emergence of flies.
Claims (3)
（２，３，５，６−テトラフルオロ−４−メチルフェニル）メチル＝２，２−ジメチル−３−（１−プロペニル）シクロプロパンカルボキシラート、
（２，３，５，６−テトラフルオロフェニル）メチル＝３−（２，２−ジクロロビニル）−２，２−ジメチルシクロプロパンカルボキシラート、又は
１−エチニル−２−メチル−２−ペンテン−１−イル＝３−（２−メチル−１−プロペニル）−２，２−ジメチルシクロプロパンカルボキシラートを有効成分として含有することを特徴とするハエの羽化阻害剤。 [2,3,5,6-tetrafluoro-4- (methoxymethyl) phenyl] methyl = 2,2-dimethyl-3- (1-propenyl) cyclopropanecarboxylate,
(2,3,5,6-tetrafluoro-4-methylphenyl) methyl = 2,2-dimethyl-3- (1-propenyl) cyclopropanecarboxylate,
(2,3,5,6-tetrafluorophenyl) methyl = 3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate or 1-ethynyl-2-methyl-2-pentene-1 A fly emergence inhibitor comprising: -yl = 3- (2-methyl-1-propenyl) -2,2-dimethylcyclopropanecarboxylate as an active ingredient.
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