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Publication number
JP2014175487A5
JP2014175487A5 JP2013047105A JP2013047105A JP2014175487A5 JP 2014175487 A5 JP2014175487 A5 JP 2014175487A5 JP 2013047105 A JP2013047105 A JP 2013047105A JP 2013047105 A JP2013047105 A JP 2013047105A JP 2014175487 A5 JP2014175487 A5 JP 2014175487A5
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Japan
Prior art keywords
raw material
metal element
nitride film
material containing
metal nitride
Prior art date
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JP2013047105A
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Japanese (ja)
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JP6108530B2 (en
JP2014175487A (en
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Priority to JP2013047105A priority Critical patent/JP6108530B2/en
Priority claimed from JP2013047105A external-priority patent/JP6108530B2/en
Priority to US14/187,799 priority patent/US9059089B2/en
Priority to KR1020140023242A priority patent/KR101537946B1/en
Publication of JP2014175487A publication Critical patent/JP2014175487A/en
Priority to US14/708,004 priority patent/US9190281B2/en
Publication of JP2014175487A5 publication Critical patent/JP2014175487A5/ja
Application granted granted Critical
Publication of JP6108530B2 publication Critical patent/JP6108530B2/en
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Claims (9)

高誘電率膜が形成された基板に対して、第1金属元素とハロゲン元素とを含む第1原料と、前記第1金属元素とは異なる第2金属元素とアミンとを含む第2原料とを交互に供給して前記高誘電率膜の上に複合金属窒化膜を形成する工程と、
前記基板に対して、第3金属元素を含む第3原料と、窒素を含む第4原料とを交互に供給して前記複合金属窒化膜の上に金属窒化膜を形成する工程と、
を有する半導体装置の製造方法。
A first raw material containing a first metal element and a halogen element and a second raw material containing a second metal element different from the first metal element and an amine with respect to the substrate on which the high dielectric constant film is formed. Alternately supplying and forming a composite metal nitride film on the high dielectric constant film ;
Forming a metal nitride film on the composite metal nitride film by alternately supplying a third material containing a third metal element and a fourth material containing nitrogen to the substrate; and
A method for manufacturing a semiconductor device comprising:
前記複合金属窒化膜に含まれる前記第1金属元素と前記第2金属元素の組成比を調整することにより、前記複合金属窒化膜の仕事関数を調整する請求項1に記載の半導体装置の製造方法法。2. The method of manufacturing a semiconductor device according to claim 1, wherein a work function of the composite metal nitride film is adjusted by adjusting a composition ratio of the first metal element and the second metal element contained in the composite metal nitride film. Law. 前記複合金属窒化膜を形成する工程における前記基板を加熱する温度と、前記第1原料と前記第2原料を供給する時間を制御することにより、前記第1金属元素と前記第2金属元素の組成比を調整する請求項2に記載の半導体装置の製造方法。The composition of the first metal element and the second metal element is controlled by controlling the temperature at which the substrate is heated in the step of forming the composite metal nitride film and the time for supplying the first material and the second material. The method for manufacturing a semiconductor device according to claim 2, wherein the ratio is adjusted. 前記複合金属窒化膜を形成する工程と、前記金属窒化膜を形成する工程とは、同じ処理室内で行う請求項1もしくは2に記載の半導体装置の製造方法。The method for manufacturing a semiconductor device according to claim 1, wherein the step of forming the composite metal nitride film and the step of forming the metal nitride film are performed in the same processing chamber. 前記第1金属元素、前記第2金属元素、前記第3金属元素は、それぞれ、Ti,W,Ta,Zr,Hf,Ru,Ni,Coからなる群より選択された少なくとも一つの元素を含む請求項1〜4のいずれかに記載の半導体装置の製造方法。The first metal element, the second metal element, and the third metal element each include at least one element selected from the group consisting of Ti, W, Ta, Zr, Hf, Ru, Ni, and Co. Item 5. A method for manufacturing a semiconductor device according to any one of Items 1 to 4. 前記第2原料は、アミンの配位子にエチル、メチル、エチルメチルまたはシクロペンタ系のいずれかを有する請求項1〜5のいずれかに記載の半導体装置の製造方法。  6. The method of manufacturing a semiconductor device according to claim 1, wherein the second raw material has any one of ethyl, methyl, ethylmethyl, and a cyclopenta group as an amine ligand. 前記第1金属元素と前記第3金属元素は同一の金属元素である請求項1〜6のいずれかに記載の半導体装置の製造方法。The method for manufacturing a semiconductor device according to claim 1, wherein the first metal element and the third metal element are the same metal element. 高誘電率膜が形成された基板に対して、第1金属元素とハロゲン元素とを含む第1原料と、前記第1金属元素とは異なる第2金属元素とアミンとを含む第2原料とを交互に供給して前記高誘電率膜の上に複合金属窒化膜を形成する手順と、
前記基板に対して、第3金属元素を含む第3原料と、窒素を含む第4原料とを交互に供給して前記複合金属窒化膜の上に金属窒化膜を形成する手順と、
をコンピュータに実行させるプログラム。
A first raw material containing a first metal element and a halogen element and a second raw material containing a second metal element different from the first metal element and an amine with respect to the substrate on which the high dielectric constant film is formed. A procedure for alternately supplying and forming a composite metal nitride film on the high dielectric constant film ,
A step of alternately supplying a third raw material containing a third metal element and a fourth raw material containing nitrogen to the substrate to form a metal nitride film on the composite metal nitride film;
A program that causes a computer to execute.
板を収容する処理室と、
前記処理室に第1金属元素とハロゲン元素とを含む第1原料を供給する第1原料供給系と、
前記処理室に前記第1金属元素とは異なる第2金属元素とアミンとを含む第2原料を供給する第2原料供給系と、
前記処理室に第3金属元素を含む第3原料を供給する第3原料供給系と、
前記処理室に窒素を含む第4原料を供給する第4原料供給系と、
前記第1原料供給系、前記第2原料供給系、前記第3原料供給系、前記第4原料供給系を制御して、前記処理室に収容された高誘電率膜が形成された基板に対して、前記第1原料と前記第2原料とを交互に供給して前記高誘電率膜の上に複合金属窒化膜を形成する処理と、前記基板に対して、前記第3原料と前記第4原料とを交互に供給して前記複合金属窒化膜の上に金属窒化膜を形成する処理と、行うように構成された制御部と、
を有する基板処理装置。
A processing chamber for accommodating the board,
A first raw material supply system for supplying a first raw material containing a first metal element and a halogen element to the processing chamber;
A second raw material supply system for supplying a second raw material containing a second metal element different from the first metal element and an amine to the processing chamber;
A third raw material supply system for supplying a third raw material containing a third metal element to the processing chamber;
A fourth raw material supply system for supplying a fourth raw material containing nitrogen to the processing chamber;
Controlling the first raw material supply system, the second raw material supply system, the third raw material supply system, and the fourth raw material supply system to a substrate on which a high dielectric constant film accommodated in the processing chamber is formed Te, a process of forming a composite metal nitride film on the high dielectric constant film and said second material and said first material is supplied alternately to the substrate, the said third raw material 4 Processing for alternately supplying raw materials to form a metal nitride film on the composite metal nitride film, and a control unit configured to perform ,
A substrate processing apparatus.
JP2013047105A 2013-02-28 2013-03-08 Semiconductor device manufacturing method, program, and substrate processing apparatus Active JP6108530B2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2013047105A JP6108530B2 (en) 2013-03-08 2013-03-08 Semiconductor device manufacturing method, program, and substrate processing apparatus
US14/187,799 US9059089B2 (en) 2013-02-28 2014-02-24 Method of manufacturing semiconductor device
KR1020140023242A KR101537946B1 (en) 2013-02-28 2014-02-27 Method of manufacturing a semiconductor device, method of processing a substrate, non-transitory computer-readable recording medium and substrate processing apparatus
US14/708,004 US9190281B2 (en) 2013-02-28 2015-05-08 Method of manufacturing semiconductor device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2013047105A JP6108530B2 (en) 2013-03-08 2013-03-08 Semiconductor device manufacturing method, program, and substrate processing apparatus

Publications (3)

Publication Number Publication Date
JP2014175487A JP2014175487A (en) 2014-09-22
JP2014175487A5 true JP2014175487A5 (en) 2016-04-21
JP6108530B2 JP6108530B2 (en) 2017-04-05

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Family Applications (1)

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JP2013047105A Active JP6108530B2 (en) 2013-02-28 2013-03-08 Semiconductor device manufacturing method, program, and substrate processing apparatus

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JP (1) JP6108530B2 (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100368311B1 (en) * 2000-06-27 2003-01-24 주식회사 하이닉스반도체 Method of forming a gate in a semiconductor device
JP5702584B2 (en) * 2010-11-30 2015-04-15 株式会社日立国際電気 Semiconductor device manufacturing method and substrate processing apparatus

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