JP2012041092A - Container for fluid and container filled with fluid using the same - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a container for fluid which is not broken during the storage or transport, excellent in cleanness to contents, easily attached/detached to/from the exterior container of a packaging bag having a spout, and excellent in workability or the like.SOLUTION: The container for fluid includes an exterior container 20 having an opening portion 24 and a packaging bag 10 having a spout with the spout 11 being jointed with a packaging bag body 12. The packaging bag body 12 is accommodated in the exterior container 20, and the spout 11 is attachable to/detachable from the opening portion 24 of the exterior container 20. A joint bracket 30 having a header portion 31 and a cylindrical portion 32 and held by the opening portion 24, and a fluid-squeezing tube 40 having a flange portion 41 on one end side are attached to the spout 11. In the liquid-squeezing tube 40 inserted into the cylindrical part 32 of the joint bracket 30, the flange portion 41 is held while being tightly attached to a top surface of the header portion 31. The packaging bag body 12 forms a bag body while a heat seal portion is formed on outer peripheries of at least two films, and a part of the spout 11 is jointed between sealing surfaces of the heat seal portion.

Description

  The present invention relates to a fluid container for storing and transporting fluid contents in the fields of industrial chemicals, pharmaceuticals and cosmetic raw materials. In particular, the present invention relates to a fluid container in which a packaging bag with a spout is accommodated in an outer container.

  Conventionally, in industrial chemicals, pharmaceuticals, cosmetic raw materials, etc., packaging bags with spouts that store fluid contents are stored inside exterior containers made of aluminum, steel, stainless steel, fiberboard, etc. for storage and transportation. Used containers.

  Such a container can be reused simply by taking a used packaging bag out of the outer container and setting a new packaging bag in the outer container. Compared to filling fluid contents in steel and other exterior containers, it has the advantage of eliminating the hassle of washing, etc., and is widely used as a container for industrial chemicals, pharmaceuticals and cosmetic raw materials (for example, patent documents) 1 and 2).

  The container disclosed in Patent Document 1 has an inner bag for storing a high-purity chemical in the outer container, and the outer container has an opening for taking in and out the high-purity chemical, and a pressure adjusting fluid. The inner bag is composed of an inner bag body and a high-purity chemical outlet, and the outlet is provided in communication with the opening of the hard outer container. Inner pipes for introducing and discharging chemicals are inserted, stoppers are fitted into the two openings, and handles are provided.

  The inner bag disclosed in Patent Document 1 cuts a cylindrical film manufactured using an inflation molding machine into a predetermined length, and opens a hole in the outer periphery of the cylindrical film cut into a predetermined length. It is manufactured by heat-sealing and fixing at the bottom mounting ring portion through the opening / closing port, and then heat-sealing both ends of the film, and has a configuration in which the inner bag body is provided with a loading / unloading port.

  Further, the container disclosed in Patent Document 2 is similar to Patent Document 1 in that a packaging bag provided with an attachment member in an exterior container (a drum can as referred to in Patent Document 2) cuts the attachment member into a first closure. It is inserted into the provided (perforated) plug opening, attached to the first closure body using a threaded ring or the like, and then attached to the drum can body.

As shown in FIG. 7, the inner bag disclosed in Patent Document 1 and the packaging bag referred to in Patent Document 2 are both heat-sealed around the outer peripheral edge to form a heat seal portion 501, and the inner bag (or A hole is made in a part of the surface of the bag on one short side, which is off the center of the packaging bag) 500, and a slot (or attachment member) 502 is inserted into the hole, and a slot (or attachment member) is inserted. The bottom mounting ring 503 provided at the bottom of 502 is heat-sealed and attached.
JP-A-9-95565 Japanese National Patent Publication No. 5-505372

  However, the container of Patent Document 1 has a structure in which the opening / closing opening of the inner bag is inserted into the opening of the outer container and the opening / closing opening is supported by the opening by some fixing means. Is a structure in which an attachment member is inserted into a plug opening cut (perforated) in the first closure and attached to the first closure body using a threaded ring or the like. Alternatively, since the packaging bag is stored and transported in a suspended state supported by a loading / unloading port or mounting member, the weight of the fluid content is applied to the outer peripheral edge of the heat-sealed flange portion or the bottom mounting ring. Therefore, there is a problem that the inner bag or the packaging bag breaks from this portion, and there has been a demand for a solution to this problem. In particular, since the entry / exit port (or attachment member) 502 is usually attached to a substantially central portion near one short edge side of the bag, the heat-sealed flange portion 504 or bottom portion located on the other short edge side is provided. Since the weight of the flowable contents is concentrated on the outer peripheral edge of the mounting ring, there is a problem that a bag breakage due to a pinhole or edge breakage is likely to occur in this portion (region indicated by symbol P in FIG. 7). .

  Therefore, the present invention is a fluid container in which a packaging bag with a spout is accommodated in an outer container, and the weight of fluid content such as a resist solution filled in the packaging bag during storage or transportation is applied. , There is no risk of bag breakage due to pinholes or edge breakage, and there is little leaching of impurities such as impure fine particles (also called particles) and metal ions into the fluid content (cleaning the bag) The degree to which particles etc. leached into the chemical solution from the resin composition is impure and the chemical solution is impure), and the packaging bag with spout can be easily attached to and detached from the outer container, and the workability and hygiene are also improved. It is to provide an excellent fluid container.

  The inventors of the present invention form a bag body by forming a heat seal portion around the outer periphery of at least two films of the packaging bag body to be stored in the outer container, and at a predetermined position of the heat seal portion, It is assumed that a part of the spout is joined between the sealing surfaces of the heat seal part, the packaging bag body can be stored in the outer container, and the spout can be attached to and detached from the opening of the outer container. Therefore, there is no risk of bag breakage even if the weight of the fluid content is increased during storage or transportation, and the fluid content is less contaminated with impurities such as particles and metal ions to maintain a high degree of cleanliness. The present invention has been completed by finding that it can be used, and that it can be reused simply by taking out the used packaging bag from the outer container and setting a new packaging bag in the outer container.

  More specifically, the present invention provides the following.

  (1) A fluid container comprising an outer container having an opening and a packaging bag with a spout used as an inner bag of the outer container and having a spout joined to a packaging bag body, wherein the packaging The bag body can be accommodated in the outer container, the spout can be attached to and detached from the opening of the outer container, and the packaging bag body has a heat seal portion on the outer periphery of at least two or more films. A fluid container which is formed into a bag body, and is a predetermined position of the heat seal portion, and a part of the spout is joined between the seal surfaces of the heat seal portion.

  The fluid container according to the invention of (1) is formed into a bag by forming a heat seal part on the outer periphery of at least two or more films, and at a predetermined position of the heat seal part, Since a packaging bag with a spout, in which a part of the spout is joined between the sealing surfaces, is housed in an outer container and used as an inner bag, such as a resist solution filled in the packaging bag for storage and transportation. Even if the weight of the fluid content is applied, there is no risk of bag breakage due to pinholes or edge breaks. In addition, impurities such as impure fine particles and metal ions are not leached into the fluid content filled inside, and the degree of cleanliness is excellent.

  In addition, the spout of the packaging bag with spout can be attached to and detached from the opening of the outer container, and the splicing position of the spout is not the vicinity of the center of the bag but the heat seal portion. For this reason, handling of the packaging bag with a spout is easy, the attachment or detachment to an exterior container is easy, and there exists the outstanding effect that it is excellent also in workability | operativity and hygiene.

  (2) The fluid container according to (1), wherein the spout is configured to be supported by the opening of the outer container and support the packaging bag body.

  According to the aspect of (2), since the spout is configured to be able to support the packaging bag body by engaging with the opening of the outer container, the packaging bag with the spout can be easily replaced. The used packaging bag can be reused simply by taking it out of the outer container and setting a new packaging bag in the outer container.

  (3) The fluid container according to (1) or (2), wherein the spout is made of a synthetic resin that can be thermally bonded on the sealing surface.

  According to the aspect of (3), since the spout is made of a synthetic resin that can be thermally bonded at the sealing surface of the packaging bag body, the spout is simultaneously formed when the packaging bag body is heat-sealed to form a bag body. It can be heat-bonded and thermally bonded to the packaging bag body, and the packaging bag with spout can be efficiently formed as compared to bonding with an adhesive or the like. Moreover, since it is thermal bonding, since the spout and the film of the packaging bag body are integrated, the sealing property and the adhesiveness are excellent.

  (4) The fluid container according to any one of (1) to (3), wherein a part of the spout includes a spout attachment portion that can be surface-bonded to the seal surface.

  (5) The fluid container according to (4), wherein the spout attachment portion capable of surface bonding forms a columnar body having a convex lens shape in cross section as a whole, and a side surface of the columnar body is a bonding surface.

  (6) Plate-shaped rib portions are formed at both end portions of the convex lens-shaped column bodies before the bonding, and are obtained by performing the bonding including the rib portions (5). Container for fluid.

  According to the aspects of (4) to (6), the spout attachment portion is heat-sealed with the film of the packaging bag main body at the sealing surface of the packaging bag main body and thermally bonded to the packaging bag main body. Since the portion has a convex lens shape, a large bonding area with the inner layer film can be obtained, and fusion can be performed so as not to form a gap when heat-sealing. Furthermore, since the plate-like ribs are provided at both end portions, the plate-like ribs are melted at the time of heat-sealing, so that a further gap is not generated, so that the sealing property between the spout and the bag body is excellent. It will be.

  (7) The fluid container according to any one of (1) to (6), wherein the outer container is a rigid container that can be used repeatedly.

  (8) The fluid container according to (7), wherein the rigid container is a metal container or a synthetic resin container.

  The outer container is preferably made of a strong material so that it can be used repeatedly. Examples of such an outer container include, but are not limited to, a rigid container made of paper such as metal, synthetic resin, and cardboard. The external container has an external thread formed in an opening (also referred to as a cap), and may be easily transported by providing a pair of molded hand portions. By setting it as such an aspect, it becomes the container for fluids which is easy to operate and is suitable for long-term repeated use.

  (9) The fluid container according to (7) or (8), wherein the outer container has a lid portion that can seal the opening and fixes the spout.

  According to the aspect of (9), there is no possibility that the filled liquid leaks during storage and transportation.

  (10) The packaging bag body is formed by stacking multiple films in which at least an outer layer film and an inner layer film are overlapped so that the inner layer films face each other and forming a heat seal portion on the outer periphery (1). (9) The fluid container according to any one of the above.

  According to the aspect of (10), since one surface of the packaging bag main body has a multiple film configuration in which the inner layer film and the outer layer film are at least overlapped, for example, leaching of impure fine particles (particles) into the inner layer film. Uses very few films, and has excellent mechanical strength and cleanliness by using a film with excellent strength such as a stretched film as the outer layer film. Impurity particles (particles) are contained in the resist solution and other contents filled in the packaging bag. Leaching can be extremely reduced. Of course, by increasing the number of layers, it is possible to improve strength such as puncture resistance.

  Each of the inner layer film and the outer layer film may have either a single layer configuration or a multilayer configuration. In particular, the outer layer film has mechanical toughness, bending resistance, puncture resistance, impact resistance, cold resistance, heat resistance, and the like. It is preferable to have a multilayer structure because excellent performance is required in terms of heat resistance, chemical resistance, and the like, and heat fusion is also required.

  (11) The fluid container according to any one of (1) to (10), which is used for storing a resist solution.

  (12) The fluid container according to (11), wherein a volume storage amount of the resist solution is 1 L or more and 250 L or less.

  According to the aspect of (11), the packaging bag with a spout of the present invention is excellent in strength and can be easily attached to and detached from the outer container. In addition, it has high chemical durability against solvents. For this reason, it is particularly suitable for storing a resist solution. In this case, the storage amount of the resist solution is, for example, 1 L or more and 250 L or less. However, the packaging bag of the present invention is excellent in strength, particularly excellent in sealing strength between the spout and the packaging bag body. It is particularly preferably used for storing such heavy objects.

  (13) The packaging bag with a spout is mounted in the outer container constituting the fluid container according to any one of (1) to (12), and fluid is stored in the packaging bag, A fluid-filled container in which the spout is sealed and the spout is fixed to the opening.

  (14) The spout is sealed directly or indirectly by the lid that seals and covers the opening, and the spout is fixed directly or indirectly to the opening (13 ) The fluid-filled container described.

  In the inventions of (13) and (14), the fluid container of (1) to (12) is developed as a fluid-containing container using the same. According to the present invention, the effects (1) to (12) can be obtained as a fluid-filled container. If necessary, even if the weight of the flowable contents such as a resist solution filled in the packaging bag during storage or transportation is applied, there is no possibility of causing bag breakage due to pinholes or broken edges. In addition, impurities such as impure fine particles and metal ions are not leached into the fluid content, and the cleanness is excellent. Furthermore, the packaging bag with spout can be easily attached to and detached from the outer container, and is excellent in workability and hygiene. In addition, according to this invention, injection | pouring and discharge | emission of a liquid can also be easily performed by using the coupling brat mentioned later. In the present invention, the term “directly or indirectly” means that the spout is substantially directly sealed and fixed directly by the lid portion or via an O-ring, and other members. This also includes a case where the spout is indirectly sealed and fixed via a joint bracket 30 or a first lid 50 (described later, for example).

  The fluid container according to the present invention has the structure according to any one of claims 1 to 15, so that the weight of the fluid content such as a resist solution filled in the packaging bag during storage or transportation is applied. There is no risk of bag breakage due to pinholes or broken edges. In addition, when the stored packaging bag with spout has a multiple film structure in which at least two films are laminated on one side, the packaging bag body has toughness, bending resistance, puncture resistance, and impact resistance. In addition to being excellent in mechanical strength such as property, there is little leaching of impurities such as particles and metal ions into the filled contents, and it is possible to maintain an excellent effect of maintaining a high degree of cleanliness. Moreover, since the packaging bag with a spout accommodated in the exterior container can be easily attached to and detached from the exterior container, it is excellent in workability and hygiene. Furthermore, in storage and transportation, there is no risk of leakage of the filled liquid, and liquid can be easily injected and discharged by attaching a joint to the joint brat described later, or using a liquid discharge tube also described later. Can be done.

  The best mode for carrying out the present invention will be described below with reference to the drawings.

<Overall configuration>
FIG. 1 is a longitudinal sectional view showing an embodiment of a fluid container according to the present invention, FIG. 2 is an enlarged sectional view showing an opening of the fluid container according to the embodiment, and FIG. FIG. 4 is a cross-sectional exploded view of the opening portion of the fluid container according to the embodiment, and FIG. 4 is a plan view showing an embodiment of a packaging bag with a spout accommodated in the exterior container of the fluid container according to the embodiment; FIG. 5 is a view showing a spout of a packaging bag with a spout accommodated in the outer container of the fluid container according to the embodiment, wherein (a) is a longitudinal sectional view (a cross section taken along line BB in FIG. 5 (b)). ), (B) are bottom views as seen from the spout attachment portion side.

  First, the configuration of the fluid container according to the present invention will be described. As shown in FIGS. 1 to 3, the fluid container 1 includes a flexible packaging bag 10 with a spout, an exterior container 20 having an opening 24, and a cylindrical joint bracket held in the opening 24. 30, a liquid discharge tube 40 inserted into the tubular portion 32 of the joint bracket 30, and an annular first lid that is screwed into the opening 24 and holds the spout 11 and the joint bracket 30 in the opening 24. 50 and a second lid 60 having a bush 62 protruding inside. The spout-equipped packaging bag 10 has a spout 11 that opens so that liquid can be injected, and a packaging bag body 12 that fills the fluid content. The exterior container 20 can support the spout 11 with the opening 24 and store the spout-equipped packaging bag 10. The packaging bag 10 with a spout has been previously washed and stored in the outer container 20. After the liquid is discharged from the spout-equipped packaging bag 10, the spout-equipped packaging bag 10 is discarded, and a new spout-equipped packaging bag 10 is stored in the outer container 20. The fluid container 1 according to the present invention is a double retractable container in which the outer container 20 is repeatedly used and a new packaging bag with a spout is used each time.

<Packaging bag with spout>
As shown in FIG. 4, the packaging bag 10 with a spout is heat-sealed by heat-sealing four sides of the multiple film 121 in which at least the outer film 121a and the inner film 121b are overlapped so that the inner films 121b face each other. An injection-molded spout 11 that is preliminarily heat-sealed between the inner layer film 121b of the packaging bag body 12 in which the portion 122 is formed and the heat seal portion 122 (upper side in FIG. 4) on one side of the packaging bag body 12. And.

  In addition, the packaging bag main body 12 may form the heat seal part 122 on the three sides of the outer periphery which overlapped, after folding the multiple film 121 so that the inner layer films 121b face each other. Further, the inner edge corner portion of the heat seal portion 122 may have an inner edge formed in an arc shape. As a result, the fluid content is unlikely to remain at the corners.

<Outlet>
The spout 11 includes a spout mounting portion 111 and a spout engaging portion 112 connected to one side of the spout mounting portion 111. As shown in FIG. It is heat-sealed between the films 121b. Note the heat-sealed portion 122 which includes an outlet mounting portion 111, Note than the sealing width of the sealing portion A ₁ of the outlet mounting portion 111, the sealing portion A ₁ other than the right and left sealing portions A ₂ of the seal width overall is A taper (or a step) T ₁ is formed so as to be wide. The taper T _1, the internal pressure of the bag according to the direction of the arrow in FIG. 4, can be received in sealing sides A ₂₁ of the sealing portion A _2. Thus, note pressure on the outlet mounting portion 111, and in particular reduce the pressure exerted in the vicinity of both end portions X of the seal sides A _11, repeated vibrations due to occurring during transport, it is possible to prevent edge tear or the like.

  As shown in FIGS. 5 (a) and 5 (b), the spout attachment portion 111 of the spout 11 is a column having a convex lens shape and a first through hole 111a at the center, and has both end portions. Are provided with a pair of plate-like ribs 111b. Usually, when the spout 11 is heat-sealed between the inner layer films 121b of the multiple film 121 by the spout attachment part 111, the two parts surrounded by the inner film 121b and the end part of the spout attachment part 111 are used. In order to prevent this from occurring, gaps are formed in the region, and plate-like ribs 111b are provided at both ends, and the plate-like ribs 111b are melted at the time of heat-sealing so that no gaps are formed.

In addition, in this embodiment, as shown to Fig.5 (a), the step part so that it may become narrower than the width | variety of the height direction of the spout attachment part 111 in the corner part Y of the both lower sides of the plate-shaped rib 111b. T ₂ is provided. The stepped portion T _2, the spout 11 corner Y after adhesion, even out the resin reservoir such as PE (polyethylene), corner Y are considered as not become sharp corners. Thereby, the edge cut | disconnection of the corner | angular part Y by the repetitive vibration etc. which arise during transport can be prevented like the above.

  As shown in FIG. 5A, the spout engaging portion 112 includes a cylindrical portion 112a having a substantially U-shaped cross section, and a flange portion 112b at the upper peripheral edge thereof. A plurality of openings may be formed at the bottom of the cylindrical portion 112a. Thereby, ventilation can be ensured between the packaging bag with a spout 10 and the inside of the outer container 20. That is, when pumping out fluid during use, pressure is applied from the outside of the packaging bag body 12 by sealing gas between the packaging bag with spout 10 and the exterior container 20 through this opening. The internal fluid can be pumped out smoothly.

  The flange portion 112b is formed by the substantially cylindrical opening 24 at a position shorter than the height direction dimension of the spout engaging portion 112 formed in the outer container 20 that accommodates the spout engaging portion 112 of the spout 11. By contacting and locking with the upper peripheral end, the packaging bag with spout 10 is supported in the outer container 20 (see FIG. 6).

  The spout 11 is preferably manufactured by an injection molding method. The resin used for this is not particularly limited as long as it is a resin that can be injection-molded. In order to be bonded to the resin constituting the inner surface of the inner layer film 121b of the multi-layer film 121 by thermal bonding to form the packaging bag 10 with a spout, it is necessary to appropriately select the resin constituting the inner surface of the inner layer film 121b. High-density polyethylene is preferable because it has rigidity even at high temperatures and hardly embrittles at low temperatures.

  Further, as the spout 11 and the inner layer film 121b, in addition to the above high-density polyethylene, for example, tetrafluoroethylene / perfluoroalkyl vinyl ether copolymer having heat resistance, chemical resistance, non-stickiness, and excellent low-temperature characteristics. Fluorine resins such as coalescence (hereinafter abbreviated as PFA) and polytetrafluoroethylene (hereinafter abbreviated as PTFE) may also be used. In this case, it is preferable to use a PTFE film as the film 121 constituting the packaging bag body 12.

<Packaging bag body>
In this embodiment, the multiple film 121 includes at least an outer layer film 121a and an inner layer film 121b.

<Outer layer film>
The outer layer film 121a may have either a single layer structure or a multilayer structure, but is excellent in mechanical toughness, bending resistance, puncture resistance, impact resistance, cold resistance, heat resistance, chemical resistance, and the like. Since performance and heat sealability with respect to the inner layer film 121b are required, a multilayer structure is preferable from the viewpoint of selection of materials and cost.

  In addition, when the inner volume of the packaging bag 10 with a spout is small and the mechanical strength is not so required because the weight of the contents to be filled is small, a single layer configuration may be used.

  In the case of a multi-layer structure, a base material layer and a heat-adhesive resin layer are used. As the base material layer, a film made of a polyester-based, polyamide-based, polypropylene-based, polyethylene-based, or polyacetal-based resin is used. A stretched film stretched in a uniaxial direction or particularly in a biaxial direction is suitable, but the packaging bag with a spout 10 is stored and transported by being stored in the outer container 20, and in particular, it is fluid in transportation. In order for the contents to oscillate violently in the bag, it is necessary to prevent pinholes and cracks generated by the oscillation, and a biaxially stretched polyamide film is preferred. The thickness of the film may be a thickness that can be held to the minimum necessary with respect to strength, rigidity, etc. as a base material, and may be determined in consideration of cost and the like.

  Examples of the heat-adhesive resin layer include low-density polyethylene, medium-density polyethylene, high-density polyethylene, linear (linear) low-density polyethylene, polypropylene, ethylene-α olefin copolymer, and ethylene-propylene copolymer. Examples of the resin include one or more resins such as a polymer, an ethylene-vinyl acetate copolymer, an ionomer resin, an ethylene-acrylic acid copolymer, an ethylene-methyl acrylate copolymer, and an ethylene-methacrylic acid copolymer. In general, polyethylene is preferable because of its excellent low-temperature sealability, and furthermore, the molecular weight distribution is narrow and the heat seal strength is excellent. Straight chain polymerized using a metallocene catalyst that has little impact on fluid content ( Jo) low density polyethylene.

  Moreover, in order to provide gas barrier properties, such as oxygen and water vapor | steam, in the said outer layer film 121a, you may provide an intermediate | middle layer between a base material layer and a thermoadhesive resin layer as needed. As a material constituting this intermediate layer, for example, a metal foil such as aluminum, iron, copper, tin, or a film such as polyvinyl alcohol, ethylene-vinyl alcohol copolymer, polyvinylidene chloride, polyester, polyamide, Polyethylene, polypropylene, ethylene-propylene copolymer and other polyolefin films, vinyl alcohol, etc. films coated with polyvinylidene chloride, or deposition of inorganic substances such as aluminum, silicon oxide, aluminum oxide, indium oxide, tin oxide, zirconium oxide A layered film or the like can be used.

  This intermediate layer not only provides the above-mentioned gas barrier properties, but also functions such as mechanical toughness, bending resistance, puncture resistance, impact resistance, cold resistance, heat resistance, chemical resistance, etc. Can be granted. It may be used in combination with the above-described material imparting gas barrier properties and a film of polyolefin such as polyester, polyamide, polyethylene, polypropylene, and ethylene-propylene copolymer.

  In addition, as the base material layer, a film obtained by applying polyvinylidene chloride to the above-described film or a film in which a vapor deposition layer of an inorganic material such as silicon oxide, aluminum oxide, indium oxide, tin oxide, or zirconium oxide is formed may be used.

  Moreover, as a lamination method for laminating each layer of the outer layer film 121a, for example, an anchor coating agent such as an organic titanate, a polyethyleneimine derivative, a silane coupling agent, or an isocyanate compound was applied and dried on one surface of the base material layer. Later, the heat-adhesive resin layer may be laminated by heating and extruding with a T-die extruder, or the heat-adhesive resin layer may be prepared in a film state and laminated by a sandwich lamination method. Alternatively, a two-component curable polyurethane adhesive composed of a polyol component and an isocyanate component may be used to laminate by a known dry lamination method. As a matter of course, an easy adhesion treatment such as a corona discharge treatment, an ozone treatment, a plasma treatment or the like may be performed on a necessary surface of each layer as necessary.

<Inner layer film>
On the other hand, the inner layer film 121b may have a single layer structure, or from the meaning of preventing pinholes and cracks in cooperation with the outer layer film 121a, or a packaging bag with a spout formed of the multiple film 121 It is good also as a multilayer structure from the meaning which improves intensity | strength, such as the tensile strength of 10 itself, and heat seal intensity | strength.

  In the case of a single layer configuration, the resin needs to be heat-bondable with the heat-adhesive resin layer of the outer film 121a, and may be appropriately selected and used depending on the type of resin used for the heat-adhesive resin layer. For the reason described in the heat-adhesive resin layer of the outer layer film 121a, polyethylene and further linear (linear) low density polyethylene polymerized using a metallocene catalyst are preferred.

  As described above, the spout 11 is usually made of high-density polyethylene that is rigid even at high temperatures and hardly embrittles at low temperatures. In this sense, the thermal adhesiveness that constitutes the inner surface of the inner layer film 121b is suitable. The resin layer is preferably polyethylene, and further linear (linear) low-density polyethylene polymerized using a metallocene catalyst.

  Linear (linear) low density polyethylene polymerized using a metallocene catalyst, that is, an ethylene-α-olefin copolymer polymerized using a metallocene catalyst is, for example, a combination of zirconocene dichloride and methylalumoxane. It is possible to use an ethylene-α-olefin copolymer obtained by copolymerizing ethylene and an α-olefin using a metallocene catalyst such as a catalyst obtained by combining alumoxane with a metallocene catalyst, that is, a metallocene catalyst. The above metallocene catalyst is also called a single-site catalyst because the current catalyst is called a multi-site catalyst with non-uniform active sites (below, the active sites are uniform). The metallocene catalyst has the same meaning as the single-site catalyst.) Specifically, as an ethylene-α / olefin copolymer polymerized using a metallocene catalyst, trade name “Kernel” manufactured by Mitsubishi Chemical Corporation, trade name “Evolue” manufactured by Mitsui Petrochemical Co., Ltd., Product name “EXACT” manufactured by Exxon Chemical Co., USA, product name “AFFINITY” manufactured by Dow Chemical Co., USA, product name “ENGAGE”, etc. An ethylene-α-olefin copolymer polymerized using a metallocene catalyst can be used.

  The ethylene-α / olefin copolymer polymerized using the metallocene catalyst will be described in more detail. Specifically, for example, a catalyst comprising a combination of a metallocene-based transition metal compound and an organoaluminum compound, that is, a metallocene catalyst ( An ethylene-α-olefin copolymer obtained by copolymerizing ethylene and an α-olefin can be used. In addition, said metallocene catalyst may be supported and used for an inorganic substance. In the above, examples of the metallocene transition metal compound include a transition metal selected from group IVB, specifically, titanium (Ti), zirconium (Zr), hafnium (Hf), cyclopentadienyl group, substituted cyclohexane. 1 to 2 pentadienyl group, indenyl group, substituted indenyl group, tetrahydroindenyl group, substituted tetrahydroindenyl group, fluoronyl group or substituted fluorenyl group are bonded, or two of these groups are shared Those bonded by bonding are bonded, and in addition, hydrogen atom, oxygen atom, halogen atom, alkyl group, alkoxy group, aryl group, acetylacetonate group, carbonyl group, nitrogen molecule, oxygen molecule, Lewis base, silicon atom Having a substituent such as an unsaturated hydrocarbon or a substituent containingIn the above, as the organoaluminum compound, alkylaluminum, chain-like or cyclic aluminoxane, or the like can be used. Here, as the alkylaluminum, for example, triethylaluminum, triisobutylaluminum, dimethylaluminum chloride, diethylaluminum chloride, methylaluminum dichloride, ethylaluminum dichloride, dimethylaluminum fluoride, diisobutylaluminum hydride, diethylaluminum hydride, ethylaluminum sesquichloride. Etc. can be used. The chain or cyclic aluminoxane can be produced, for example, by bringing alkyl aluminum into contact with water. For example, it can be produced by adding alkylaluminum at the time of polymerization and adding water later, or by reacting crystallization water of a complex salt or adsorbed water of an organic / inorganic compound with alkylaluminum. Next, in the above, as the inorganic material for supporting the metallocene catalyst, for example, silica gel, zeolite, silicon earth or the like can be used.

Next, in the above, as the polymerization method, for example, various polymerization methods such as bulk polymerization, solution polymerization, suspension polymerization, and gas phase polymerization can be used. In addition, the polymerization may be any method such as a batch method or a continuous method. In the above, the polymerization conditions are polymerization temperature, −100 to 250 ° C., polymerization time, 5 minutes to 10 hours, reaction pressure, normal pressure to 300 Kg / cm ² . Furthermore, in the present invention, examples of the α-olefin that is a comonomer copolymerized with ethylene include propylene, 1-butene, 3-methyl-1-butene, 4-methyl-1-pentene, 1-hexene, 1 -Octene, decene, etc. can be used. The above α · olefin fin may be used alone or in combination of two or more. Moreover, the mixing ratio of the above-mentioned α · olefin fin is, for example, 1 to 50% by weight, preferably 10 to 30% by weight. In the present invention, the physical properties of the ethylene-α-olefin copolymer polymerized using the metallocene catalyst are, for example, molecular weight, 5 × 10 ^{3 to} 5 × 10 ⁶ , density, 0.890 to 0.930 g / cm. ^3. Melt flow rate (MFR), 0.1-50 g / 10th order. In the present invention, the ethylene-α / olefin copolymer polymerized using the above metallocene catalyst includes, for example, an antioxidant, an ultraviolet absorber, an antistatic agent, an antiblocking agent, a lubricant (fatty acid amide, etc.). ), Flame retardants, inorganic or organic fillers, dyes, pigments and the like can be optionally added and used.

  In the case of a multi-layer structure, the core layer and both surfaces thereof are heat-adhesive resin layers, and the core layer is similar to the base layer of the outer layer film 121a in mechanical toughness, bending resistance, and puncture resistance. It is preferable that it has excellent performance in terms of heat resistance, impact resistance, cold resistance, heat resistance, chemical resistance, etc., and examples include layers made of polyester, polyamide, polypropylene, polyethylene, polyacetal resins, etc. It is done. Further, it may be unstretched or may be a layer made of a resin stretched in a uniaxial direction or biaxial direction, but is preferably a layer made of polyamide like the base material layer 200 of the outer layer film 121a. In particular, a configuration in which a heat-adhesive resin layer is provided on both sides of the polyamide layer is particularly preferable.

  One of the heat-adhesive resin layers provided on both surfaces of the core layer can be thermally bonded to the heat-adhesive resin layer of the outer film 121a, and the other is thermally bonded to the spout 11 made of the above-described high-density polyethylene. It is premised that it is made of a resin that can be used, and for the reason described in the heat-adhesive resin layer of the outer film 121a, polyethylene is suitable, and further, linear (linear) polymerized using a metallocene catalyst. Low density polyethylene is preferred.

  As a method of laminating the inner layer film 121b in the case of a multilayer structure, each layer may be laminated by the laminating method described for the outer layer film 121a, but for reasons such as reducing the manufacturing cost, five layers are possible. It is preferable to laminate by using a co-extrusion method in which (thermal adhesive resin layer / adhesive layer / core layer / adhesive layer / thermal adhesive resin layer) can be laminated at a time.

  When the heat-adhesive resin layer is a polyolefin represented by polyethylene or polypropylene, the adhesive layer is a polyolefin graft-modified with an unsaturated carboxylic acid, such as Admer [Mitsui Petrochemical Co., Ltd .: trade name], Modic [Mitsubishi Chemical Co., Ltd .: trade name], Polytack [Idemitsu Petrochemical Co., Ltd .: trade name] can be preferably used.

<Other configurations>
In addition, although not shown, an intermediate layer film may be provided between the outer layer film 121a and the inner layer film 121b to form a multiple film 121 having three or more layers. As an intermediate | middle layer film, it is provided according to the physical property calculated | required by the packaging bag 10 with a spout, For example, even if it uses the film of the single layer which consists of resin demonstrated with the heat adhesive resin layer of the outer layer film 121a, It is also possible to use a structure in which a heat-adhesive resin layer is laminated on the surface of the outer layer film 121a on which the base material layer is exposed, or a layer structure described in the inner layer film 121b. It may be. In any case, it is preferable that the thermally adhesive resin layers facing each other of the outer layer film 121a, the intermediate layer film, and the inner layer film 121b are a combination of resins that can be thermally bonded to each other.

  In addition, the film which comprises the packaging bag main body 12 in this invention does not necessarily need to be a multiple film, if the innermost surfaces are heat sealable, for example, the normal film which used only one pair of outer layer films 121a, for example It may be a configuration.

  Further, as the spout 11 and the inner layer film 121b, in addition to the above high-density polyethylene, for example, heat-resistant, chemical-resistant, non-adhesive, and a fluorine-based resin such as PFA or PTFE having excellent low-temperature characteristics is used. May be. In this case, it is preferable to use a PTFE film as the film constituting the packaging bag body 12.

<Exterior container>
As shown in FIG. 1, the outer container 20 includes a bottom plate 21, a side wall 22, and a top plate 23 with a raised center, and a steel container in which an opening 24 is formed at a substantially central portion of the top plate 23. Is preferably used. A male screw 24 a is formed on the outer peripheral surface of the opening 24. Moreover, you may make conveyance easy by providing a pair of hand part 25 (refer FIG. 6) in the position above the top plate 23 of the side wall 22. As shown in FIG.

  Examples of the outer container 20 include, but are not limited to, a rigid container made of paper such as metal, synthetic resin, and cardboard.

  As shown in FIGS. 2 and 3, a flange portion 112 b is formed on the opening side of the spout 11 of the spouted packaging bag 10, while a step is provided on the inner wall of the opening 24. The spout 11 is supported by the opening part 24 by 112b latching to a level | step difference. The packaging bag 10 with spout is preferably nitrogen after the packaging bag 10 with spout is stored in the outer container 20 and the spout 11 joined to the packaging bag 10 with spout is supported by the opening 24 of the outer container 20. Or it is expanded by compressed air. Then, the liquid is injected into the packaging bag with spout 10 from the first through hole 111a (see FIG. 2 or FIG. 3).

<Container fitting>
The container joint according to the present invention includes a cylindrical joint bracket 30 and a liquid discharge tube 40 (see FIG. 2 or FIG. 3). In FIG. 2, the joint bracket 30 is held in the opening 24. In addition, the joint bracket 30 has a substantially cylindrical header portion 31 on one end side and a cylindrical portion 32 on the other end side. Further, the joint bracket 30 has a second through hole 33 that penetrates from one end side to the other end side. The header portion 31 is raised from the cylindrical bottom of the joint bracket 30. The cylindrical portion 32 is fitted into the first through hole 111a of the spout 11 (see FIG. 3).

  2 or 3, the liquid discharge tube 40 has a flange 41 that is in close contact with the top surface 311 of the header portion 31 of the joint bracket 30 on one end side. Further, the other end side of the liquid discharge tube 40 is inserted into the second through hole 33 of the joint bracket 30. The liquid discharge tube 40 has a fluid passage 42 extending from one end to the other end, and the liquid in the spout-equipped packaging bag 10 is discharged through the fluid passage 42 (see FIG. 1).

  The outer diameter of the joint bracket 30 is slightly smaller than the inner diameter of the spout 11, and the joint bracket 30 is fitted to the spout 11 supported by the opening 24 (see FIG. 2). A flange 34 having an outer diameter slightly smaller than the inner diameter of the opening 24 is provided at one end of the joint bracket 30, and an O-ring is supported on the flange 34 to seal the opening 24 (see FIG. 2 or (See FIG. 3).

  The joint bracket 30 is held in the opening 24 together with the spout 11 when the first lid 50 is fastened to the opening 24 (see FIG. 2). A predetermined gap is provided between the bottom outer wall of the joint bracket 30 and the bottom inner wall of the tubular portion 112a of the spout 11 (see FIG. 2).

  In FIG. 3, the cylindrical portion 32 is provided so as to protrude from the bottom portion of the joint bracket 30, and the cylindrical portion 32 is fitted into the first through hole 111 a of the spout 11. An O-ring is carried inside the first through hole 111a of the spout 11, and the O-ring is in close contact with the outer periphery of the cylindrical portion 32, whereby the gas in the spout-equipped packaging bag 10 can be sealed ( Not shown). The second through hole 33 penetrates from the upper end of the header portion 31 to the lower end of the cylindrical portion 32, and the liquid discharge tube 40 is inserted into the second through hole 33 (see FIG. 2). A gap is provided in the outer periphery of the second through hole 33 and the liquid discharge tube 40 so that the gas in the spout-equipped packaging bag 10 can be vented to the plurality of second openings 43 (see FIG. 2).

  The joint of the container according to the present invention includes a first ventilation means capable of venting gas from the inside of the outer container 20 to the opening 24 and a second ventilation capable of venting gas from the inside of the packaging bag 10 with a spout to the opening 24. Means and a second lid 60 for sealing the opening 24. The first ventilation means has a plurality of first openings 35 of the joint bracket 30. The plurality of first openings 35 communicate with the top surface 311 of the header portion 31 from the periphery of the cylindrical portion 32. The second ventilation means has a plurality of second openings 43. The plurality of second openings 43 are provided in the flange 41 of the liquid discharge tube 40, and communicate the opening 24 and the inside of the second through hole 33 of the joint bracket 30 (see FIGS. 2 and 3).

  And the joint of the container by this invention prevents that a liquid and gas flow out from the opening part 24, when the 2nd cover 60 is attached. Further, when the second lid 60 is removed, before the liquid in the liquid discharge tube 40 is discharged to the opening 24, the gas in the outer container 20 and the gas in the spout-equipped packaging bag 10 are first changed. It escapes out of the opening 24 through the first and second ventilation means.

  The first opening 35 may be a slit that penetrates from the periphery of the cylindrical portion 32 to the top surface 311 of the header portion 31, and is provided between the cylindrical portion 32 and the header portion 31. The first opening 35 substantially communicates the gap provided between the joint bracket 30 and the spout 11 and the atmosphere (see FIGS. 2 and 3).

  As shown in FIG. 2, the second opening 43 is a through hole formed in the flange 41 of the liquid discharge tube 40, and penetrates from the upper surface of the flange 41 around the liquid discharge tube 40. In FIG. 2, an O-ring is supported on the lower surface of the flange portion 41, and the O-ring is in close contact with the top surface 311 of the header portion 31, thereby sealing the second through hole 33. The second opening 43 substantially communicates the gap provided in the inner wall of the second through hole 33 and the outer wall of the liquid discharge tube 40 with the atmosphere (see FIGS. 2 and 3). As described above, this gap can be vented to the internal space of the packaging bag 10 with the spout.

<Lid>
2 or 3, a first lid 50 that is screwed with the opening 24 of the outer container 20 and a second lid 60 that is screwed with the first lid 50 are provided.

  The first lid 50 has a female or synthetic resin lid body 51 formed with a female screw threadedly engaged with the outer surface of the opening 24 of the outer container 20 on the inner side surface and a male screw formed on the outer side surface. A fourth opening 52 having a size substantially the same as the outer size of is formed concentrically. The joint bracket 30 is held by screwing and tightening the first lid 50 to the opening 24.

  The second lid 60 includes a light-blocking closure main body 61 that is screwed into the first lid 50 provided in the opening 24, and a corrosion-resistant bush 62 that protrudes into the closure main body 61. The bush 62 includes an O-ring 63 that is in close contact with the surface of the flange portion 41 and seals ventilation from the fluid passage 42.

  The closure main body 61 is made of metal or synthetic resin, and a female screw that is screwed into the first lid 50 is provided on the inner periphery of the closure main body 61. When the second lid 60 is tightened, the inner wall of the closure main body 61 is in contact with the top surface 311 of the joint bracket 30. The closure main body 61 has a light shielding property so that the chemical stored in the spout-equipped packaging bag 10 does not change chemically. The bush 62 is preferably made of a synthetic resin having corrosion resistance because there is a high possibility that the bush 62 may come into contact with the chemical stored in the packaging bag 10 with a spout. One end of the bush 62 is press-fitted into the closure main body 61 so that the bush 62 and the closure main body 61 are integrated (see FIG. 3). The other end side of the bush 62 protrudes into the closure main body 61 and carries an O-ring 63 on the tip surface. The O-ring 63 is in close contact with the surface of the flange 41 and can prevent both liquid and gas from flowing out from the fluid passage 42.

  Further, when the screwing with the first lid 50 is released on the side periphery of the closure main body 61, before the liquid in the liquid discharge tube 40 is discharged to the opening 24, the gas in the outer container 20 and the injection One or more ventilation holes 64 through which the gas in the packaging bag with outlet 10 escapes to the outside of the opening 24 through the first and second ventilation means are provided (see FIG. 2 or FIG. 3). Thus, by providing the vent hole 64 on the side periphery of the closure main body 61, when the second lid 60 is loosened, the close contact between the O-ring 63 and the surface of the flange 41 is released, and at least a plurality of second The gas in the opening 43 is discharged from the vent hole 64 to the outside. And it can prevent that the liquid in the liquid discharge tube 40 spouts.

  1 or 2, when the second lid 60 is removed, before the liquid in the liquid discharge tube 40 is discharged to the opening 24, the gas in the outer container 20 and the inside of the packaging bag 10 with the spout The gas in the liquid discharge tube 40 can be prevented from being discharged out of the opening 24 because each of the gases escapes from the opening 24 through the first and second ventilation means.

  In the joint of the container according to the present invention, the gas in the liquid discharge tube 40, the gas in the outer container 20, and the gas in the spout-equipped packaging bag 10 are individually sealed with the second lid 60. When the second lid 60 is removed, the pressure in the liquid discharge tube 40, the pressure in the outer container 20, and the pressure in the spout-equipped packaging bag 10 immediately coincide with the atmospheric pressure. The liquid inside can be prevented from being discharged out of the opening 24.

  Further, as shown in FIG. 3, the liquid discharge tube 40 is joined to the tube 44 on the way from one end side having the flange 41 to the other end side. The liquid discharge tube 40 can thermally weld the tube 44 by ultrasonic vibration on the way from one end side having the flange 41 to the other end side. In the joint of the container according to the present invention, since the liquid discharge tube 40 has an integral structure, it is possible to eliminate the trouble of removing the chemical that has permeated into the gap between the press-fitting portions of the separate pump tube as in the prior art.

<Storage method>
The fluid container 1 of the present invention is inserted into the exterior container 20 from the opening 24 of the exterior container 20 as shown in FIG. 6 (a), and the spout 11 is formed as shown in FIG. 6 (b). Attached to the opening 24 of the outer container 20. At this time, the opening 24 of the outer container 20 has a substantially cylindrical protruding shape that is shorter than the dimension in the height direction of the spout engaging portion 112, and the flange portion 112 b of FIG. By contacting the upper peripheral end of the step formed on the side surface, the spout-equipped packaging bag 10 is supported in the outer container 20.

  Thereafter, in this state, the fluid as the content is introduced from the spout 11 by a predetermined method, and then the joint bracket 30 is inserted into the spout 11, and then the first lid 50 is screwed into the opening 24. The spout 11 and the joint bracket 30 are fixed to support the packaging bag 10 with the spout. Thereafter, the tube 44 of the liquid discharge tube 40 is inserted into the second through-hole 33 of the joint bracket 30 and the liquid discharge tube 40 is mounted. Then, the second lid 60 is screwed onto the first lid 50 to discharge the liquid discharge tube. The top surface of 40 is sealed to cover the opening 24. As a result, the fluid container 1 is in a state in which the opening 24 and the spout 11 are sealed and can be distributed and transferred.

  When the fluid is used, that is, when the fluid is pumped out, it can be pumped out from the spout 11 through the liquid discharge tube 40.

  As described above, the fluid container of the present invention can be used for storage and transportation of fluid contents in the industrial chemical field, the pharmaceutical and cosmetic raw material fields, and the like. Among them, a resist container that is repeatedly transferred between a resist manufacturer and a device manufacturer such as a semiconductor is required to have high strength and hygiene, and the transfer form varies from about 1 L to about 250 L. It is necessary to cope with the capacity.

  In this regard, the fluid container of the present invention can appropriately cope with variations in various capacities by appropriately selecting an outer container and a packaging bag with a spout that is internally provided. Moreover, since the packaging bag with a spout can be easily attached to and detached from the outer container, it is excellent in workability and hygiene.

  EXAMPLES Next, although an Example is given and this invention is demonstrated in more detail below, this invention is not limited to these Examples.

  As the structure of the packaging bag used in the examples and comparative examples described below, as the outer layer film, an ON (biaxially stretched polyamide) film 25 μm / urethane adhesive 3 μm / LLDPE film 40 μm is used as an inner layer film. A five-layer coextruded film consisting of LLDPE layer 25 μm / adhesive layer 10 μm / nylon layer 15 μm / adhesive layer 10 μm / LLDPE layer 20 μm was used. In addition, as the LLDPE film of the outer layer film, a linear low density polyethylene film (“SR-UEN” manufactured by DNP Techno Film Co., Ltd.) polymerized using a metallocene catalyst was used. In addition, as the LLDPE layer of the inner layer film, a linear low density polyethylene resin polymerized using a metallocene catalyst (UBE Super Polyethylene “Umerit” manufactured by Ube Industries, Ltd.) was used.

[Example 1]
The inner dimension shown in FIG. 4 is 380 mm, consisting of a double film attached by heat-sealing a high-density polyethylene spout on one short side so that the 25 μm-thick LLDPE layer of the inner film is on the contents side. A packaging bag with a spout of a × 715 mm four-side seal type was produced. The outer peripheral diameter of the flange portion of the spout engaging portion of the high-density polyethylene spout is 53.9 mm, the thickness of the flange portion is 2.5 mm, and the outer peripheral diameter immediately below the flange portion of the spout engaging portion is 50.mm. 8 mm and the height of the spout engaging portion is 32 mm.

[Comparative Example 1]
By heat-sealing at the bottom mounting ring through a hole made of high-density polyethylene with a 25 μm-thick LLDPE layer of the inner layer film on the content side and through a hole opened on one short side A packaging bag with a spout as a comparative example 1 of a four-sided seal type with an inner dimension of 380 mm × 715 mm shown in FIG. 4 made of an attached double film was produced. The outer diameter of the flange portion of the high-density polyethylene outlet is 53.9 mm, the thickness of the flange portion is 2.5 mm, the outer diameter immediately below the flange portion is 50.8 mm, and the length between the flange portion and the bottom mounting ring. Is 25 mm.

  The packaging bag with a spout of Example 1 and Comparative Example 1 produced above has a thread bottom on the bottom surface of a substantially cylindrical shape having a diameter of 227.6 mm and a height of 500 mm, and an inner diameter of 50.8 mm at the center of the top plate. Inserted from the cylindrical opening of a stainless steel container having a cylindrical opening with a protruding length of 15.0 mm, and set the flange portion in contact with the upper peripheral surface of the stepped portion of the cylindrical opening Then, 18 L of water was injected from the spout, and the cylindrical opening was appropriately sealed with a sealing means (lid) to prepare 10 containers each for a drop test.

  The container prepared above was dropped once from the height of 70 cm in the order of the vertical direction and the horizontal direction, and the presence / absence of water leakage and the broken bag were visually confirmed. Table 1 shows the results.

  As is clear from Table 1, the fluid container containing the packaging bag having the spout attached to the heat seal portion on one side of Example 1 is a packaging in which the spout is attached to the short side of Comparative Example 1. Compared to the container for fluid containing the bag, the result was that there was no fear of breaking the packaging bag due to drop impact.

  From this result, it was confirmed that the fluid container of the present invention hardly breaks the packaging bag stored in the outer container when storing, transporting and handling a liquid such as a resist.

[Comparative Example 2]
The packaging bag of the following structure used conventionally is set as the comparative example 2, and the packaging bag of Example 1 and the comparative example 2 examined the physical property of the packaging bag, the cleanliness, and the degree of leaching of particles. The structure of the conventional packaging bag is as follows: the outer layer film is a three-layer coextruded film of PE15 μm / PE35 μm / PE20 μm, and the inner layer film is a five-layer film of LLDPE15 μm / PE10 μm / NY20 μm / PE10 μm / PE10 μm (content side is LLDPE). Heavy film configuration.

  For Example 1 and Comparative Example 2 prepared above, the sealing strength of the heat seal portion of the packaging bag, the adhesive strength between the spout and the packaging bag, the puncture strength and gel resistance of the packaging bag, and the particles were measured, and Table 2 It was shown to. In addition, when the packaging bag is filled with a chemical solution, the amount of minute impure solids in the chemical solution, the amount of water, the amount of metal impurities eluted, the amount of ionic components, the amount of non-volatiles, changes in the viscosity of the chemical solution over time, and the chemical solution after a predetermined time has elapsed The film thickness of the coating film formed during the measurement was measured and the results are shown in Table 3. Various strengths and other measurements were measured by the following methods. Moreover, a photoresist composition (trade name: TFR-790PL, manufactured by Tokyo Ohka Kogyo Co., Ltd.) was used as the chemical solution.

<Measurement of seal strength>
A tensile test specimen having a width of 15 mm was collected from a substantially central portion of the remaining heat seal portion other than the heat seal portion fused to the spout of the packaging bag, and measured according to JIS-Z1707. In addition, the test piece was extract | collected so that the heat seal part might be included in the intermediate part of the both sides and bottom side of the heat seal part 122 of FIG.

<Measurement of adhesive strength between spout and packaging bag body>
A specimen having a width of 15 mm was taken in a direction perpendicular to the heat seal portion so that the spout and the packaging bag body were heat-sealed, and measured according to JIS-Z1707.

<Measurement of puncture strength>
Measured according to Ministry of Health and Welfare Notification No. 20, “Testing methods for instruments or containers and packaging in general” in 1982. It measured from the inner layer side and the outer layer side in the state which accumulated the inner layer film and the outer layer film.

<Measurement of gel resistance>
A gelbo test (tester: gelboflex tester) was performed in a state where the inner layer film and the outer layer film were overlapped, and the number of pinholes in each of the inner layer film and the outer layer film was counted after 1000 times and 2000 times of gelbo. The test was conducted in an environment of normal temperature and normal humidity.

<Measurement of particles>
Put ultrapure water into the sample, shake gently for 10 seconds so that the ultrapure water spreads in the bag, and then let stand for 20 minutes. The liquid subjected to the treatment was measured with a liquid particle counter.

<Measurement of amount of minute impure solids in chemical solution>
The number of particles was measured using a particle counter (manufactured by Rion, product name: Particle Sensor KS-41).

<Measurement of water content in chemicals>
Measured with a Karl Fischer moisture meter.

<Measurement of metal impurity elution amount, ionic component amount, and nonvolatile content in chemical solution>
The amount of metal impurities eluted was measured with an ICP emission spectrophotometer. The amount of ionic components was measured by ion chromatography. The non-volatile content is the rate of increase in weight after evaporation relative to the initial value.

<Measurement of viscosity of chemical solution>
Measured with a Cannon Fenceke viscometer.

<Measurement of coating film thickness>
The film thickness of a coating film formed by spin coating (3000 rpm) on a 6-inch silicon wafer and drying on a hot plate at 190 ° C. for 90 seconds was measured.

  As shown in Table 2, the packaging bag of Example 1 was compared with the packaging bag of Comparative Example 2 in all of the sealing strength of the heat seal part, the adhesive strength between the spout and the packaging bag, and the puncture strength of the packaging bag. Excellent results. In addition, the number of pinholes and the number of particles were small.

  Further, even when the chemical solution is filled as shown in Table 3, Comparative Example 2 shows any change in the particle, metal impurity elution, ionic component, non-volatile content leaching degree, chemical solution viscosity, and water content in the chemical solution. It was almost equivalent.

  From these results, the packaging bag of the present invention is excellent in mechanical strength, hardly breaks when storing, transporting and handling the contents such as a resist solution, and leaching of particles and the like into the chemical solution. It was confirmed that there were few.

It is a longitudinal section showing one embodiment of the fluid container concerning the present invention. It is an expanded sectional view which expands and shows the opening part of the container for fluids by the said embodiment. It is a cross-sectional exploded view of the opening part of the fluid container according to the embodiment. It is a top view which shows one Embodiment of the packaging bag with a spout accommodated in the exterior container of the container for fluids by the said embodiment. It is a figure which shows the spout of the packaging bag with a spout accommodated in the exterior container of the container for fluids by the said embodiment, (a) is a longitudinal cross-sectional view, (b) is the bottom view seen from the spout attachment part side FIG. It is a figure which shows the accommodation state to the exterior container of the packaging bag with a spout by the said embodiment, (a) is a partial perspective view which shows the state which inserts the packaging bag with a spout into an exterior container, (b) is an exterior container. It is a fragmentary perspective view which shows the state after the packaging bag with a spout was accommodated in. It is a perspective view which shows one Example of the conventional packaging bag with a spout.

DESCRIPTION OF SYMBOLS 1 Fluid container 10 Outlet packaging bag 11 Outlet 111 Outlet attachment part 111b Plate-shaped rib 12 Packaging bag main body 121 (Multiple) film 121a Outer layer film 121b Inner layer film 122 Heat seal part 20 Outer container 24 Opening part 50 1st Lid 60 Second Lid

Claims (15)

An exterior container having an opening;
It is used as an inner bag of this outer container, and is a packaging container with a spout formed by joining a spout to the packaging bag body, and a fluid container comprising:
The packaging bag body can be stored in the outer container, and the spout is detachable from the opening of the outer container,
The spout has a substantially cylindrical header portion and a tubular portion on one end side and the other end side, respectively, and a joint bracket that is held in the opening, and is inserted into the tubular portion of the joint bracket, on one end side And a liquid discharge tube having a flange portion that is in close contact with the top surface of the header portion of the joint bracket,
The liquid discharge tube inserted into the tube portion of the joint bracket is held in a state where the flange portion is in close contact with the top surface of the header portion of the joint bracket,
The packaging bag body is formed into a bag body by forming a heat seal portion on the outer periphery of at least two or more films, and at a predetermined position of the heat seal portion, between the sealing surfaces of the heat seal portion. A fluid container to which a part of the spout is joined.   The fluid container according to claim 1, wherein the liquid discharge tube inserted into the cylindrical portion of the joint bracket is held in a state where movement in a radial direction is restricted by an inner peripheral surface of the cylindrical portion.   The fluid container according to claim 1, wherein the spout is configured to be able to support the packaging bag body by being locked to the opening of the outer container.   The fluid container according to any one of claims 1 to 3, wherein the spout is made of a synthetic resin that can be thermally bonded on the sealing surface.   5. The fluid container according to claim 1, wherein a part of the spout includes a spout mounting portion that can be surface-bonded to the seal surface.   The fluid container according to claim 5, wherein the spout attachment portion capable of surface bonding forms a column having a convex lens shape as a whole in cross section, and a side surface of the column is a bonding surface.   The plate-shaped rib part is extended and formed in both the terminal parts of the said convex lens-shaped column body before the said joining, The fluid use of Claim 6 obtained by performing the said joining including this rib part container.   The fluid container according to claim 1, wherein the outer container is a rigid container that can be used repeatedly.   The fluid container according to claim 8, wherein the rigid container is a metal container or a synthetic resin container.   10. The fluid container according to claim 8, wherein the outer container has a lid for fixing the spout while allowing the opening to be sealed.   11. The packaging bag body according to any one of claims 1 to 10, wherein a multilayer film in which at least an outer layer film and an inner layer film are overlapped is overlapped so that the inner layer films face each other to form a heat seal portion on the outer periphery. Or a container for fluid.   The fluid container according to claim 1, which is used for containing a resist solution.   The fluid container according to claim 12, wherein a volume capacity of the resist solution is 1 L or more and 250 L or less.   The packaging bag with a spout is mounted in the outer container constituting the fluid container according to any one of claims 1 to 13, wherein fluid is contained in the packaging bag, and the spout is sealed. And a fluid-filled container in which the spout is fixed to the opening.   15. The spout is sealed directly or indirectly by a lid portion that seals and covers the opening, and the spout is fixed directly or indirectly to the opening. Container with fluid.

Images