JP2011229493A - Combined confectionery - Google Patents
Combined confectionery Download PDFInfo
- Publication number
- JP2011229493A JP2011229493A JP2010104989A JP2010104989A JP2011229493A JP 2011229493 A JP2011229493 A JP 2011229493A JP 2010104989 A JP2010104989 A JP 2010104989A JP 2010104989 A JP2010104989 A JP 2010104989A JP 2011229493 A JP2011229493 A JP 2011229493A
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- JP
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- Prior art keywords
- confectionery
- weight
- chocolate
- oil
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Images
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Abstract
Description
本発明は、生チョコレート様組成物を用いた複合菓子に関する。 The present invention relates to a composite confectionery using a raw chocolate-like composition.
一般に乾き菓子と呼ばれる焼き菓子類は、サクサクした食感と日持ちの良さから世界中で最も親しまれている菓子の一つである。従前、焼き菓子類は粉類に対する油脂類、糖類、水相の種類や配合量、成形方法等を変えることで風味や食感、形状に変化をもたせているが、いずれも瑞々しさには欠けたものであった。また、近年では焼き菓子類にクリーム類をサンド、コーティング、トッピングといった手法で接合させた多種多様な複合菓子が現れ、これらが主流となりつつある。これら複合菓子の特徴として、焼き菓子類のサクサクした食感を維持するため、実質的に水分を含まないクリーム類を接合させていることが挙げられる。そのため、焼き菓子類の風味・食感とともに、それとは異なる風味・食感のものを同時に味わうことが可能となった反面、従前の焼き菓子類と同様に瑞々しさに乏しい菓子であることは否めない。そこで、焼き菓子に瑞々しさを持たせ、かつ焼き菓子への水分移行を抑制して焼き菓子のサクサクした食感を維持する提案がなされてきた。 Baked confectionery, generally called dry confectionery, is one of the most popular confectionery in the world because of its crisp texture and longevity. Traditionally, baked confectionery has changed its flavor, texture, and shape by changing the type and blending amount, molding method, etc. of fats and oils, sugars, aqueous phase, etc., but all are fresh It was lacking. In recent years, a wide variety of composite confections have appeared, in which creams are joined to baked confectioneries by a technique such as sanding, coating, or topping, and these are becoming mainstream. As a feature of these composite confectionery, in order to maintain the crisp texture of baked confectionery, it is mentioned that creams substantially free of moisture are joined. Therefore, it is possible to taste different flavors and textures at the same time with the flavor and texture of baked confectionery, but on the other hand it is not as fresh as baked confectionery. can not deny. Therefore, proposals have been made to maintain freshness of the baked confectionery by adding freshness to the baked confectionery and suppressing moisture transfer to the baked confectionery.
例えば、構成脂肪酸として炭素数20〜24の飽和脂肪酸を15〜70重量%、炭素数16〜22の不飽和脂肪酸を20〜60重量%含有し、かつ1分子中に炭素数20〜24の飽和脂肪酸残基及び炭素数16〜22の不飽和脂肪酸残基を少なくとも各1個以上含有する混酸基トリグリセリドを2〜100重量%含有する油脂組成物を含有するフィリング材(特許文献1参照)が提案されている。しかしながら、このフィリング材の水分含有量は0.1〜10重量%未満であり、焼き菓子への大量の水分の移行は防げるものの、水分含有量そのものが低いため、焼き菓子と組み合わせて食した場合、焼き菓子に瑞々しさを持たせるという点では十分とはいえない。 For example, it contains 15 to 70% by weight of a saturated fatty acid having 20 to 24 carbon atoms and 20 to 60% by weight of an unsaturated fatty acid having 16 to 22 carbon atoms as a constituent fatty acid, and saturated with 20 to 24 carbon atoms in one molecule. A filling material containing an oil and fat composition containing 2 to 100% by weight of a mixed acid group triglyceride containing at least one fatty acid residue and at least one unsaturated fatty acid residue having 16 to 22 carbon atoms is proposed (see Patent Document 1). Has been. However, the moisture content of this filling material is less than 0.1 to 10% by weight, and although a large amount of moisture can be prevented from transferring to the baked confectionery, the moisture content itself is low, so when eaten in combination with baked confectionery In terms of adding freshness to baked goods, it is not enough.
また、実質的に水分を含まない油脂組成物中に特定水分含量かつ特定水分活性の小片状ドライフルーツを分散させる複合菓子が提案されている(特許文献2参照)。この複合菓子では、水分含有量が5〜20重量%であるドライフルーツを、水分を含まないクリーム状の油脂組成物中に1〜20重量%混合しており、クリーム状の油脂組成物の水分含有量は最大でも4%となるため、特許文献1の場合と同様に焼き菓子と組み合わせて食した場合、焼き菓子に瑞々しさを持たせるという点では十分とはいえない。 Moreover, the composite confectionery which disperse | distributes the small dried fruit of specific water content and specific water activity in the fats and oils composition which does not contain water substantially is proposed (refer patent document 2). In this composite confectionery, dried fruit having a water content of 5 to 20% by weight is mixed with 1 to 20% by weight in a creamy oil and fat composition not containing water, and the moisture of the creamy oil and fat composition is mixed. Since the content is 4% at the maximum, when it is eaten in combination with baked confectionery as in the case of Patent Document 1, it is not sufficient in terms of giving freshness to the baked confectionery.
さらに、焼き菓子類にチョコレートや実質的に水分を含まないクリーム類を接合させた複合菓子類も広く流通している。これらの複合菓子類は、製造中あるいは製造後の流通過程や保存中に、焼き菓子部分の表面が白い粉をふいたり、斑点状に変色したり、全体的に白色化したりする現象がしばしば発生し、製品の外観を悪くすることがある。この現象は同時にチョコレートやクリーム類の軟化を伴うことが多く、そのために商品価値が著しく低下したり、外観を損なったりする。 Furthermore, composite confectionery in which baked confectionery is joined with chocolate or cream that does not substantially contain water is also widely distributed. These composite confectioneries often have a phenomenon in which the surface of the baked confectionery part is white powdered, discolored in spots, or entirely whitened during production or after distribution and storage. In addition, the appearance of the product may be deteriorated. At the same time, this phenomenon often involves softening of chocolate and creams, which significantly reduces the commercial value and impairs the appearance.
この現象は、チョコレート、クリーム類をコーティングしないビスケットにおいて従来から認められているビスケットブルーム、すなわちファットブルーム現象とは異なるものであり、その発生メカニズムは十分解明されていないが、以下のように推定される。すなわち、焼き菓子類に練り込まれた油脂は、焼成時に完全に融解しており、冷却過程においてこの融解している油脂から固体脂の結晶化が起こる。固体脂の結晶化は温度の低い表面部分から順に発生し進行していくが、焼き菓子類の焼成後の冷却工程はかなりの徐冷条件で冷却されることが多いため、製品中では油脂は固体脂と液油が分離している固液分離状態で焼き菓子類の表面及び内部に存在している。そこに、チョコレートやクリーム類を接触させると、液油の多い焼き菓子側から、液油の少ないチョコレートやクリーム類側に液油が移行する、いわゆるマイグレーション現象が起こる。とりわけ、焼き菓子中の油脂の固体脂含量が低い場合は、多量の液油が移行することになる。そのため焼き菓子表面の澱粉粒が全体的に露出するので外見上艶がなくなり、全体的に白く見える。 This phenomenon is different from the biscuits bloom that has been recognized in the past in biscuits not coated with chocolate or cream, that is, the fat bloom phenomenon, and the mechanism of its occurrence has not been fully elucidated, but is estimated as follows. The That is, the fats and oils kneaded in the baked confectionery are completely melted at the time of baking, and solid fats are crystallized from the melted fats and oils in the cooling process. Crystallization of solid fat occurs and progresses in order from the surface part where the temperature is low, but since the cooling process after baking of baked confectionery is often cooled under considerably slow cooling conditions, It exists on the surface and inside of baked confectionery in a solid-liquid separation state where solid fat and liquid oil are separated. When chocolate or cream is brought into contact therewith, a so-called migration phenomenon occurs in which the liquid oil moves from the baked confectionery side having a large amount of liquid oil to the chocolate or cream side having a small amount of liquid oil. In particular, when the solid fat content of the fat in the baked confectionery is low, a large amount of liquid oil is transferred. Therefore, since the starch grains on the surface of the baked confectionery are exposed as a whole, the appearance is not glossy and the whole looks white.
この現象は製造中に発生するのみならず、製造後、製品を保存中に温度変化が生じた場合にも観察され、とりわけ温度の変化が大きい場合に顕著に発生する。また、液油の移行により、残った高融点油脂の結晶粗大化によるファットブルーム現象も同時に発生し、これも焼き菓子類の表面状態の変化に関与する。また、チョコレートやクリーム類側から見ると、焼き菓子側から液油が移行してくるため、チョコレートやクリーム類が軟化してしまう。 This phenomenon is observed not only during the production but also when a temperature change occurs during the storage of the product after the production, and particularly occurs when the temperature change is large. In addition, due to the transfer of the liquid oil, a fat bloom phenomenon due to the coarsening of the remaining high melting point oil and fat occurs at the same time, which is also involved in the change in the surface state of the baked confectionery. Moreover, since liquid oil will transfer from a baked confectionery side when it sees from the chocolate or cream side, chocolate and cream will soften.
このため、複合菓子の製造過程及び保存過程において発生することがある油脂移行とブルーム化を抑えることができる複合菓子製品であって、同時にその菓子製品の食感、風味及び外観等を長期間良好な状態に保つことができる菓子製品が望まれており、それに対する提案も多くなされてきた。 For this reason, it is a composite confectionery product that can suppress fat and oil migration and blooming that may occur in the production process and storage process of the composite confectionery, and at the same time, the texture, flavor, appearance, etc. of the confectionery product are good for a long time A confectionery product that can be kept in good condition is desired, and many proposals have been made for it.
例えば、焼き菓子製造用油脂として、25℃における固体脂含量が20重量%以上の常温で固体の油脂と、HLBが3以下であって、構成脂肪酸が炭素数12〜22の飽和脂肪酸20〜80重量%及び炭素数16〜22の不飽和脂肪酸80〜20重量%からなるショ糖脂肪酸エステル又はグリセリン脂肪酸エステルとからなる油脂組成物を使用する複合菓子類の製造方法(特許文献3参照)や、焼き菓子と油脂性菓子とが互いに異なる油脂組成物を含んでなり、かつ該各油脂組成物が、炭素数20〜24の飽和脂肪酸15〜70重量%と、炭素数16〜22の不飽和脂肪酸20〜60重量%とを構成脂肪酸として含有してなり、かつ、1分子中に炭素数20〜24の飽和脂肪酸残基と炭素数16〜22の不飽和脂肪酸残基とを少なくとも各1個以上有する混酸基トリグリセリドを40〜100重量%含有してなる油脂組成物の群から選択される複合菓子(特許文献4参照)が提案されている。これらの提案はいずれも、焼き菓子やクリーム類に使用する油脂を限定することで油脂移行を抑制するものであり、本発明のように焼き菓子に接合させる組成物の組成を規定することで油脂移行を抑制するものとは大きく異なる。 For example, as fats and oils for baked confectionery, solid fats and oils at room temperature having a solid fat content at 25 ° C. of 20% by weight or more, saturated fatty acids having HLB of 3 or less and a constituent fatty acid of 12 to 22 carbon atoms are 20 to 80 The manufacturing method (refer patent document 3) of the composite confectionery using the fats and oils composition which consists of sucrose fatty acid ester or glycerine fatty acid ester which consists of 80-20 weight% of weight% and a C16-22 unsaturated fatty acid, The baked confectionery and the oleaginous confectionery comprise different fat and oil compositions, and each of the fat and oil compositions comprises 15 to 70% by weight of a saturated fatty acid having 20 to 24 carbon atoms and an unsaturated fatty acid having 16 to 22 carbon atoms. 20 to 60% by weight as a constituent fatty acid, and each molecule contains at least one saturated fatty acid residue having 20 to 24 carbon atoms and unsaturated fatty acid residue having 16 to 22 carbon atoms in one molecule. Composite confectionery (see Patent Document 4) it has been proposed that are selected from the group of fat compositions comprising 40 to 100 wt% of the mixed acid groups triglycerides having above. All of these proposals are intended to suppress the transfer of fats and oils by limiting the fats and oils used for baked goods and creams, and by defining the composition of the composition to be joined to the baked goods as in the present invention It is very different from the one that suppresses the transition.
ところで、チョコレートと水系原料を含むチョコレート含有菓子として、ガナッシュが知られている。ガナッシュは、チョコレートにクリームや洋酒等の風味成分及び/又は水等を加え、融解、混合して作られる洋菓子である。このガナッシュは、例えば球形に成形し、表面をココアパウダー等で被覆したトリュフ等の菓子のセンターや、生チョコレートに利用されている。ガナッシュを利用したこれらの菓子は、喫食する際にチョコレートとクリーム又は洋酒等の上品で芳醇な風味が口中に広がる、口どけのよい高級菓子として愛用されている。 By the way, ganache is known as a chocolate containing confectionery containing chocolate and an aqueous raw material. Ganache is a Western confectionery made by adding flavor components such as cream and liquor and / or water to chocolate and melting and mixing them. This ganache is used, for example, in the center of a confectionery such as a truffle whose shape is formed into a spherical shape and whose surface is covered with cocoa powder or the like, or fresh chocolate. These confections using ganache are favored as high-class confectionery that has a refined and rich flavor such as chocolate and cream or Western liquor when eaten.
しかし、ガナッシュは水分を多く含む生菓子であり、水分活性が0.80程度であるため、あまり日持ちがしないという欠点がある。水分活性を0.70未満に抑えることで一般細菌、食中毒菌、酵母菌、カビ、好塩性細菌の増殖を防止することは可能であるが、耐乾性カビや耐浸透圧性酵母、Aspergills ecbinulatus、Monasous bisporusといった種類のカビの増殖を防止するためには、水分活性を0.60未満に抑える必要がある(非特許文献1参照)。 However, ganache is a raw confectionery that contains a lot of water, and its water activity is about 0.80. Although it is possible to prevent the growth of general bacteria, food poisoning bacteria, yeasts, molds, and halophilic bacteria by suppressing the water activity to less than 0.70, drought-resistant molds, osmotic-resistant yeasts, Aspergills ecbinulatus, In order to prevent the growth of molds such as Monasous bisporus, it is necessary to suppress the water activity to less than 0.60 (see Non-Patent Document 1).
一般的な食品の水分含有量と水分活性の関係は図1のように表される(非特許文献2参照)。図1によると、水分含有量が高くなるほど水分活性は大きくなる関係にあり、水分含有量が高い食品ほど長期的に保存させることが困難であることは明確である。もしも水分含有量の高い、高級菓子として愛用されているガナッシュのような食品を長期的に流通させることができれば、年間4,000億円を超えつつも近年伸び悩んでいるチョコレート市場の更なる拡大につながると考えられる。このため、ガナッシュのように水分を多く含む生菓子の長期流通に向けて、保存性を高めるために水分活性を下げる提案がこれまでに数多くなされてきた。 The relationship between the water content and water activity of a general food is expressed as shown in FIG. 1 (see Non-Patent Document 2). According to FIG. 1, it is clear that the higher the water content, the higher the water activity, and the higher the water content, the more difficult it is to store for a long time. If we can distribute foods such as ganache, which has a high moisture content and is loved as a high-class confectionery, in the long term, the chocolate market, which has exceeded 400 billion yen per year but has been sluggish in recent years, will be further expanded. It seems to be connected. For this reason, many proposals have been made so far to reduce the water activity in order to improve the storage stability for long-term distribution of fresh confectionery such as ganache.
例えば、チョコレートにエリスリトール、マンニトール、マルチトール、ラクチトールといった特定の糖アルコールを含有させたものが提案されている(特許文献5参照)。これは、最終水分含有量が2〜15重量%になるように、前記糖アルコールから選ばれる1種又は2種以上の混合物である糖アルコールを、チョコレート組成物中に1質量%以上10質量%未満含有させるものであるが、規定の糖アルコールの中には環状の糖アルコールも含まれる。 For example, a chocolate containing a specific sugar alcohol such as erythritol, mannitol, maltitol, or lactitol has been proposed (see Patent Document 5). This is a mixture of one or two or more sugar alcohols selected from the sugar alcohols so that the final water content is 2 to 15% by weight. Although it is contained in less, the prescribed sugar alcohol includes cyclic sugar alcohols.
また別の提案として、チョコレート生地を50重量%以上使用し、水性成分とHLB値7.0以上の乳化剤を使用し、水分10〜20重量%、全油脂分を15〜25重量%になるように調製した含水チョコレート類の製造方法が提案されている(特許文献6参照)。しかしながら、この提案による含水チョコレートの水分活性は0.75〜0.70付近であり、長期的な流通性が十分にあるとは言い難い。また、転化糖、水飴、果糖、ブドウ糖、ショ糖、液糖及び蜂蜜からなる群から選ばれた1種又は2種以上を含有し、糖度が60以上である水相とチョコレート生地とからなる水中油型乳化チョコレート類も提案されている(特許文献7参照)。ここでは、水相において特定の糖類を用い、さらに糖度を60以上にすることで長期保存性を高めており、15℃で4ヶ月保存しても口どけや風味が良好であるとしているが、常温、常湿での長期流通性については不明である。 As another proposal, use 50% by weight or more of chocolate dough, use an aqueous component and an emulsifier with an HLB value of 7.0 or more, so that the water content is 10 to 20% by weight and the total fat content is 15 to 25% by weight. The manufacturing method of the water-containing chocolates prepared in 1 is proposed (refer patent document 6). However, the water activity of the hydrated chocolate according to this proposal is around 0.75 to 0.70, and it is difficult to say that there is sufficient long-term distribution. In addition, it contains one or more selected from the group consisting of invert sugar, starch syrup, fructose, glucose, sucrose, liquid sugar, and honey, and is composed of an aqueous phase having a sugar content of 60 or more and a chocolate dough. Oil-type emulsified chocolates have also been proposed (see Patent Document 7). Here, specific saccharides are used in the aqueous phase, and the long-term storage stability is improved by further increasing the sugar content to 60 or more, and even if stored at 15 ° C. for 4 months, the mouthfeel and flavor are good. Long-term distribution at normal temperature and humidity is unknown.
その他にも、ガナッシュではないが水中油型乳化物の一種として、油脂、蛋白質、乳化剤、糖及び/又は糖アルコール、及び水を含む起泡性水中油型乳化物があるが(特許文献8参照)、これは粘度上昇を抑え、保型性、離水耐性、組織の安定性に優れたホイップドクリームであり、主とする糖質はガナッシュと類似するものの、直鎖状多価アルコールの1つであるソルビトールの含有量が、糖及び/又は糖アルコールの全量に対して10重量%未満である。また、アミノ酸と糖質によって保存性を高めた水中油型乳化物があるが(特許文献9参照)、5〜10℃の条件化で3ヶ月程度の保存性であり、常温、常湿での長期流通には不十分である。 In addition, although not ganache, there is a foamable oil-in-water emulsion containing a fat, protein, emulsifier, sugar and / or sugar alcohol, and water as one type of oil-in-water emulsion (see Patent Document 8). ) This is a whipped cream that suppresses the increase in viscosity and has excellent shape retention, water separation resistance, and tissue stability. Its main carbohydrate is similar to ganache, but it is one of linear polyhydric alcohols. The sorbitol content is less than 10% by weight with respect to the total amount of sugar and / or sugar alcohol. In addition, there is an oil-in-water emulsion that has improved storage stability with amino acids and sugars (see Patent Document 9), but it has a storage stability of about 3 months under conditions of 5 to 10 ° C., at room temperature and humidity. Insufficient for long-term distribution.
同様にラウリン系油脂をベースとしたカカオバターを含む水中油型乳化物が提案されているが(特許文献10参照)、二糖類以下の糖質及びその含有量についての記載はない。また、長期流通性については具体的な記載がない。 Similarly, an oil-in-water emulsion containing cocoa butter based on lauric fats and oils has been proposed (see Patent Document 10), but there is no description of saccharides below disaccharides and their contents. In addition, there is no specific description about long-term distribution.
さらには、含水チョコレート中の全水分量に対する全油分量が、重量比(水:油)で1:0.8〜3に調製した水中油型チョコレートがあるが(特許文献11参照)、全糖類固形分の50重量%以上がショ糖であり、無脂乳固形分の含有量については何ら明記されていない。 Furthermore, there is an oil-in-water chocolate in which the total amount of oil relative to the total amount of water in the hydrated chocolate is adjusted to a weight ratio (water: oil) of 1: 0.8 to 3 (see Patent Document 11). 50% by weight or more of the solid content is sucrose, and there is no description about the content of the non-fat milk solid content.
また、チョコレート生地に水分活性が0.40〜0.64の範囲である高水分含有素材を添加することによって、チョコレートの水分活性を0.40〜0.64に低下させる方法も提案されているが(特許文献12参照)、これはチョコレート自体に水分を含有させるものではないため、ガナッシュのような生チョコレートとは相違する。また、使用されるチョコレート生地中では、糖類の量が0〜50質量%である。 Moreover, the method of reducing the water activity of chocolate to 0.40-0.64 is also proposed by adding the high water content raw material whose water activity is the range of 0.40-0.64 to chocolate dough. However, since this does not contain moisture in chocolate itself, it is different from raw chocolate such as ganache. Moreover, in the chocolate dough used, the quantity of saccharides is 0-50 mass%.
また、製造方法としては、含水チョコレートを低水分の可食性粉体型に流し込み、可食性粉体中で冷却及びエージングを行うことによって可食性粉体に水分を移行させることにより、含水チョコレートの水分含有量を減少させ水分活性を下げる製造方法が提案されているが(特許文献13参照)、この方法では水分活性を0.70以下に下げることは可能であるが、含水チョコレート自体の水分量が減少するため食感が固くなり好ましくなく、水分を移行させるのにも長時間を要するという欠点がある。 In addition, as a manufacturing method, the moisture content of the moisture-containing chocolate is obtained by pouring the moisture-containing chocolate into a low-moisture edible powder mold, and transferring moisture to the edible powder by cooling and aging in the edible powder. Although the manufacturing method which reduces content and reduces water activity is proposed (refer patent document 13), although water activity can be reduced to 0.70 or less by this method, the water content of the water-containing chocolate itself is low. Since it decreases, the texture becomes hard, which is not preferable, and it takes a long time to transfer moisture.
他にも、チョコレート生地を0.22MTCA可溶率20%以上の蛋白加水分解物を用いて水分含量25重量%以上の安定したO/W型乳化物をまず調製した後、生地の水分を8〜16重量%まで水分蒸発させることによって水分活性を0.70以下に下げる製造方法も提案されているが(特許文献14参照)、水分蒸発に時間を要する他、加熱処理を行うためチョコレートの風味が損なわれる可能性があり好ましくない。 In addition, a stable O / W emulsion having a moisture content of 25% by weight or more was first prepared from a chocolate dough using a protein hydrolyzate having a solubility of 0.22 MTCA of 20% or more. A production method has also been proposed in which the water activity is reduced to 0.70 or less by evaporating water to ˜16% by weight (see Patent Document 14). May be damaged, which is not preferable.
このように、嗜好性の高い生チョコレートを日持ちさせる提案は数多くなされてきたが、1年規模での長期の流通を成功させるには未だ至っていない。また、製造方法によっては水分活性を0.70未満に抑えることも可能であるが、食感が悪くなったり、製造に長時間を要したりする等の問題がある。 As described above, many proposals have been made to keep a highly-preferred raw chocolate for a long time, but it has not yet been successful in long-term distribution on a one-year scale. In addition, although the water activity can be suppressed to less than 0.70 depending on the production method, there are problems such as a poor texture and a long time for production.
本発明は、このような事情に鑑みてなされたものであって、その目的とするところは、水分含有量が8〜18重量%の範囲における水分活性が0.60未満であり、生チョコレートのような風味と食感を有し、かつ1年規模での長期流通を行った場合でも、風味及び食感を良好に維持することができる生チョコレート様組成物をフィリングとして用いて焼き菓子に組み合わせることで、生チョコレート様組成物から焼き菓子への水分や油脂の移行による風味や食感の劣化が顕著に抑えられた、常温での長期流通に適した新規な複合菓子を提供することにある。
なお、1年規模での長期流通とは、常温、常湿の条件下において、生チョコレート様組成物を1年間保存することをいう。
This invention is made | formed in view of such a situation, The place made into the objective is that the water activity in the range whose moisture content is 8 to 18 weight% is less than 0.60, and is a raw chocolate. Combined with a baked confectionery using a raw chocolate-like composition as a filling that has such a flavor and texture and can maintain a good flavor and texture even when long-term distribution on a one-year scale is performed It is to provide a new composite confectionery suitable for long-term distribution at room temperature, in which the deterioration of the flavor and texture due to the transfer of moisture and fats and oils from raw chocolate-like composition to baked confectionery is remarkably suppressed .
In addition, long-term distribution on a one-year scale means storing the raw chocolate-like composition for one year under normal temperature and humidity conditions.
本発明者らは、前記目的を達成するために鋭意研究を重ねた結果、驚くべきことに、二糖類以下の糖質及びハードバターの含有量、さらに前記二糖類以下の糖質として直鎖状多価アルコールの量を調整することによって、得られる組成物の水分含有量が8〜18重量%の範囲で水分活性が0.60未満に抑えられ、かつ生チョコレートのような風味と食感を有することを発見した。そして、前記生チョコレート様組成物を焼き菓子に組み合わせることで、常温で長期保存した場合でも、風味の劣化が顕著に少ない新規な複合菓子を完成するに至った。 As a result of intensive studies to achieve the above object, the present inventors have surprisingly found that the content of saccharides and hard butters below disaccharides, and linear as saccharides below disaccharides. By adjusting the amount of the polyhydric alcohol, the water content of the resulting composition is in the range of 8 to 18% by weight, the water activity is suppressed to less than 0.60, and the flavor and texture like raw chocolate are obtained. Found to have. And by combining the said raw chocolate-like composition with baked confectionery, even when it preserve | saved for a long time at normal temperature, it came to complete the novel composite confectionery with remarkably little deterioration of flavor.
すなわち、本発明は、焼き菓子の内部又は表面に水分値が8〜18重量%である生チョコレート様組成物が充填又は付着された複合菓子であり、該生チョコレート様組成物が、二糖類以下の糖質を40〜70重量%、ハードバターを5〜25重量%含有し、前記二糖類以下の糖質として、直鎖状多価アルコールを5〜25重量%含有することを特徴とする複合菓子に関する。 That is, the present invention is a composite confectionery in which a raw chocolate-like composition having a moisture value of 8 to 18% by weight is filled or adhered inside or on the surface of the baked confectionery, and the raw chocolate-like composition is a disaccharide or less. 40 to 70% by weight of saccharide, 5 to 25% by weight of hard butter, and 5 to 25% by weight of linear polyhydric alcohol as the saccharide below the disaccharide Regarding confectionery.
また、本発明は、前記直鎖状多価アルコールがソルビトールである前記複合菓子に関する。 Moreover, this invention relates to the said composite confectionery whose said linear polyhydric alcohol is sorbitol.
また、本発明は、前記直鎖状多価アルコールがキシリトールである前記複合菓子に関する。 Moreover, this invention relates to the said composite confectionery whose said linear polyhydric alcohol is xylitol.
また、本発明は、前記直鎖状多価アルコールがソルビトールとキシリトールの混合物である前記複合菓子に関する。 The present invention also relates to the composite confectionery, wherein the linear polyhydric alcohol is a mixture of sorbitol and xylitol.
また、本発明は、前記直鎖状多価アルコールがソルビトール及び/又はキシリトールと、ソルビトールとキシリトール以外の直鎖状多価アルコールとの混合物である前記複合菓子に関する。 The present invention also relates to the composite confectionery, wherein the linear polyhydric alcohol is a mixture of sorbitol and / or xylitol and a linear polyhydric alcohol other than sorbitol and xylitol.
また、本発明は、該生チョコレート様組成物中に無脂乳固形分を0.05重量%以上含有する前記複合菓子に関する。 Moreover, this invention relates to the said composite confectionery which contains 0.05 weight% or more of non-fat milk solid content in this raw chocolate-like composition.
本発明により、1年規模での長期流通が可能であり、かつ口どけのよい高級菓子として愛用されている生チョコレートのような風味と食感をもつ生チョコレート様組成物を焼き菓子に組み合わせた新規な複合菓子を提供することが可能となった。 According to the present invention, a raw chocolate-like composition having a taste and texture like raw chocolate that can be distributed for a long time on a one-year scale and is used as a high-quality confectionery with a smooth mouth is combined with a baked confectionery. It became possible to provide new composite confectionery.
本発明は、焼き菓子の内部又は表面に水分値が8〜18重量%である生チョコレート様組成物が充填又は付着された複合菓子であり、該生チョコレート様組成物が、二糖類以下の糖質を40〜70重量%、ハードバターを5〜25重量%含有し、前記二糖類以下の糖質として、直鎖状多価アルコールを5〜25重量%含有することに特徴がある。 The present invention is a composite confectionery in which a raw chocolate-like composition having a moisture value of 8 to 18% by weight is filled or adhered inside or on the surface of a baked confectionery, and the raw chocolate-like composition is a sugar having a disaccharide or less. It is characterized by containing 40 to 70% by weight of quality, 5 to 25% by weight of hard butter, and containing 5 to 25% by weight of linear polyhydric alcohol as the saccharide below the disaccharide.
本発明に使用できる糖質としては、例えば、グルコース、フルクトース、ガラクトース等の単糖類、スクロース、ラクトース、マルトース、トレハロース、セロビオース等の二糖類、これらの二糖類以下の糖類を主成分として含有する砂糖、水飴類等、異性化糖等、前記以外の二糖類以下のオリゴ糖類、キシリトール、エリスリトール、マルチトール、ソルビトール、マンニトール、グリセリン等の糖アルコール等の二糖類以下の糖質が挙げられる。本発明で使用する生チョコレート様組成物では、前記糖質のうち二糖類以下の糖質の含有量は40〜70重量%であり、前記二糖類以下の糖質として直鎖状多価アルコールが5〜25重量%であることが大きな特徴の一つである。直鎖状多価アルコールとは、環状構造をとらず、かつ水酸基を2つ以上持つ糖アルコールのことを示し、例として、キシリトール、エリスリトール、ソルビトール、マンニトール、グリセリン等が挙げられる。二糖類以下の糖質の含有量が40重量%未満では、得られる生チョコレート様組成物の水分活性が高くなり1年規模での長期流通が困難になる。一方、二糖類以下の糖質の含有量が70重量%を超えると、得られる生チョコレート様組成物の水分活性は十分に低いものの非常に甘くなり風味として好ましくない。直鎖状多価アルコールの含有量も同様な理由が当てはまる。 Examples of the saccharide that can be used in the present invention include sugars containing, as a main component, monosaccharides such as glucose, fructose, and galactose, disaccharides such as sucrose, lactose, maltose, trehalose, and cellobiose, and saccharides of these disaccharides or less. , Saccharides and the like, oligosaccharides other than the above disaccharides, saccharides such as saccharides, and the like, and sugars below the disaccharides such as sugar alcohols such as xylitol, erythritol, maltitol, sorbitol, mannitol, and glycerin. In the raw chocolate-like composition used in the present invention, the content of saccharides below the disaccharide in the saccharide is 40 to 70% by weight, and a linear polyhydric alcohol is used as the saccharide below the disaccharide. One of the major features is 5 to 25% by weight. The linear polyhydric alcohol refers to a sugar alcohol having no cyclic structure and having two or more hydroxyl groups, and examples thereof include xylitol, erythritol, sorbitol, mannitol, glycerin and the like. If the content of the saccharides below the disaccharide is less than 40% by weight, the water activity of the obtained raw chocolate-like composition becomes high and long-term distribution on a one-year scale becomes difficult. On the other hand, if the content of saccharides below the disaccharide exceeds 70% by weight, the water activity of the resulting raw chocolate-like composition is sufficiently low, but it becomes very sweet and unfavorable as a flavor. The same reason applies to the content of the linear polyhydric alcohol.
前記生チョコレート様組成物中の二糖類以下の糖質及び直鎖状多価アルコールの適切な含有量の範囲は、水分含有量によって異なり、水分含有量が12〜18重量%の範囲では水分活性が高くなるため、二糖類以下の糖質の割合は55重量%以上が、直鎖状多価アルコールの割合は10重量%以上が好ましく、より好ましい範囲は、二糖類以下の糖質の割合が58〜65重量%、直鎖状多価アルコールの割合が12〜22重量%である。水分含有量が8重量%以上12重量%未満の場合は、風味の点から二糖類以下の糖質の割合は60重量%以下が、直鎖状多価アルコールの割合は15重量%以下が好ましい。また、二糖類以下の糖質については2種以上を組み合わせてもよく、特に限定はないが、例えば、より風味を向上させるために砂糖を20重量%以上、トレハロースを少なくとも直鎖状多価アルコールの5重量%含有させると良い。 The appropriate content range of the saccharides below the disaccharide and the linear polyhydric alcohol in the raw chocolate-like composition varies depending on the water content, and the water activity is in the range of 12 to 18% by weight. Therefore, the proportion of saccharides below the disaccharide is preferably 55% by weight or more, and the proportion of the linear polyhydric alcohol is preferably 10% by weight or more, more preferably the proportion of the saccharide below the disaccharide is 58 to 65% by weight, and the proportion of linear polyhydric alcohol is 12 to 22% by weight. When the water content is 8% by weight or more and less than 12% by weight, from the viewpoint of flavor, the proportion of saccharides below the disaccharide is preferably 60% by weight or less, and the proportion of the linear polyhydric alcohol is preferably 15% by weight or less. . In addition, two or more kinds of carbohydrates of disaccharides or less may be combined, and there is no particular limitation. For example, in order to improve the flavor, sugar is 20% by weight or more, and trehalose is at least a linear polyhydric alcohol. It is preferable to contain 5% by weight.
なお、前記直鎖状多価アルコールは、風味や物性の問題及び製造コストの面からソルビトールであることが好ましい態様である。風味の点では前記直鎖状多価アルコールがキシリトールであることもまた好ましい態様である。また、キシリトールとソルビトールとを併用することによって結晶化等の物性的な問題の解消や製造コストを削減することができ、キシリトール単独で用いるよりも好ましい。マンニトール、エリスリトール、グリセリン等のその他の直鎖状多価アルコールは単独で用いる場合、風味が悪かったり、結晶化が生じたりする等の物性の問題があるが、ソルビトール及び/又はキシリトールと併用することによってこれらの問題は解消できる。なお、風味及び物性に影響を及ぼさない範囲であれば、ソルビトールとキシリトール以外の直鎖状多価アルコールのうち、単独及びそれらの混合物としてのみで使用しても構わない。 In addition, it is a preferable aspect that the said linear polyhydric alcohol is a sorbitol from the surface of the problem of flavor or a physical property, and manufacturing cost. In terms of flavor, it is also a preferred embodiment that the linear polyhydric alcohol is xylitol. In addition, the combined use of xylitol and sorbitol can eliminate physical problems such as crystallization and reduce the production cost, and is preferable to using xylitol alone. When other linear polyhydric alcohols such as mannitol, erythritol, glycerin are used alone, there are problems of physical properties such as bad taste and crystallization, but they should be used in combination with sorbitol and / or xylitol. Can solve these problems. In addition, if it is a range which does not affect a flavor and a physical property, you may use it only as single and those mixtures among linear polyhydric alcohols other than sorbitol and xylitol.
さらに、前記生チョコレート様組成物には、前記二糖類以下の糖質に加えて、食品に添加できる三糖類、四糖類、五糖類以上のオリゴ糖、多糖類等の糖類も含有することができる。これらの食品に添加できる糖類の含有量としては、生チョコレート様組成物の物性、風味、食感に影響を及ぼさなければよく、特に限定はない。 Furthermore, the raw chocolate-like composition can also contain saccharides such as trisaccharides, tetrasaccharides, pentasaccharides or higher oligosaccharides, and polysaccharides that can be added to foods in addition to the sugars below the disaccharides. . The content of sugars that can be added to these foods is not particularly limited as long as they do not affect the physical properties, flavor, and texture of the raw chocolate-like composition.
また、前記生チョコレート様組成物は無脂乳固形分を0.05重量%以上含有することが好ましい。無脂乳固形分を0.05重量%以上含有させることによって、風味や食感に影響を及ぼすことなく水分活性をより低下させることができる。本発明に用いられる無脂乳固形分とは、乳製品の固形分のうち乳脂肪を除いた成分を示し、その含有量は生チョコレート様組成物中において0.05重量%以上であり、チョコレート由来の無脂乳固形分、すなわちミルクチョコレートやホワイトチョコレート等に含有される粉乳成分中の無脂乳固形分は含まれない。また、無脂乳固形分のより好ましい範囲は0.2重量%以上である。また、前記無脂乳固形分の含有量は多すぎると食感にざらつきを生じることから、5重量%以下が好ましい。
なお、無脂乳固形分中に含有される乳糖は二糖類であるが、微量なため乳糖が無脂乳固形分として含まれる場合は前記二糖類以下の糖質としてカウントしない。無脂乳固形分を含むものとして、生クリーム、牛乳、濃縮乳、脱脂粉乳、全粉乳、調製粉乳、練乳、チーズクリーム、ホイップ用クリーム及びコーヒー用クリーム等が挙げられるが、風味の点から生クリームを用いるのが望ましい。また、生クリームを用いる場合は乳脂肪分の含有量が12重量%以下になるように調製するのが風味や食感の点から好ましい。脱脂粉乳、全粉乳、あるいは調製粉乳を用いる場合はこれらの粉乳をメイラード処理したものであっても良い。
Moreover, it is preferable that the said raw chocolate-like composition contains 0.05 weight% or more of non-fat milk solid content. By containing 0.05% by weight or more of the non-fat milk solid content, the water activity can be further reduced without affecting the flavor and texture. The non-fat milk solid content used in the present invention indicates a component excluding milk fat in the solid content of the dairy product, and its content is 0.05% by weight or more in the raw chocolate-like composition, and the chocolate The non-fat milk solid content in the milk powder component contained in the milk-free milk solid content, that is, the milk chocolate or the white chocolate is not included. Moreover, the more preferable range of non-fat milk solid content is 0.2 weight% or more. Further, if the content of the non-fat milk solid content is too large, the texture becomes rough, so 5% by weight or less is preferable.
In addition, although the lactose contained in non-fat milk solid content is a disaccharide, since it is trace amount, when lactose is contained as non-fat milk solid content, it does not count as a carbohydrate below the said disaccharide. Examples of non-fat milk solids include fresh cream, milk, concentrated milk, skimmed milk powder, whole milk powder, prepared milk powder, condensed milk, cheese cream, whipped cream, and coffee cream. It is desirable to use cream. Moreover, when using fresh cream, it is preferable from the point of flavor or food texture to prepare so that content of milk fat may be 12 weight% or less. When skim milk powder, whole milk powder, or prepared milk powder is used, these milk powders may be maillard-treated.
また、本発明におけるハードバターとは、ココアバターとココアバター代用脂の総称を示し、その含有量は生チョコレート様組成物中において5〜25重量%である。ハードバターの含有量が5重量%未満では、液状の物性に近くなり生チョコレート様の食感が得られず、また焼き菓子の内部に充填した際に流れ出してしまう。一方、ハードバターの含有量が25重量%を超えると、食感が硬くなり同じく生チョコレート様の食感が得られない。また、前記ハードバターの含有量は8〜22重量%の範囲が好ましく、特にココアバターを用いるのが好ましい。ココアバター代用脂とは、チョコレートの物性改良や製造コストの節約を目的として、ココアバターの一部又は全部に代えて用いられるもので、主にCBEと称される1、3位飽和、2位不飽和のトリグリセリド型油脂に富むものと、CBRと称されるラウリン系もしくは高エライジン酸タイプのものがある。ココアバター代用脂の油脂原料としては、ナタネ油、大豆油、ヒマワリ油、綿実油、落花生油、米糠油、コーン油、オリーブ油、カポック油、ゴマ油、月見草油、パーム油、パーム核油、ヤシ油、シア脂、サル脂等の植物性油脂及び乳脂、牛脂、ラード、魚油、鯨油等の動物性油脂を例示することができ、上記油脂類もしくは2種以上の混合した油脂、又はそれらの硬化、分別、エステル交換等を施した加工油脂を用いることができる。 Moreover, the hard butter | batter in this invention shows the generic name of cocoa butter and cocoa butter substitute fat, The content is 5-25 weight% in a raw chocolate-like composition. If the content of hard butter is less than 5% by weight, it will be close to liquid physical properties and a raw chocolate-like texture will not be obtained, and will flow out when filled into the baked confectionery. On the other hand, if the content of hard butter exceeds 25% by weight, the texture becomes hard and a texture similar to fresh chocolate cannot be obtained. Further, the content of the hard butter is preferably in the range of 8 to 22% by weight, and it is particularly preferable to use cocoa butter. Cocoa butter substitute is used to replace some or all of cocoa butter for the purpose of improving the physical properties of chocolate and saving manufacturing costs. There are those rich in unsaturated triglyceride type oils and lauric or high elaidic acid type called CBR. Examples of cocoa butter substitute oil include rapeseed oil, soybean oil, sunflower oil, cottonseed oil, peanut oil, rice bran oil, corn oil, olive oil, kapok oil, sesame oil, evening primrose oil, palm oil, palm kernel oil, coconut oil, Examples include vegetable oils and fats such as shea fat and monkey fat, and animal fats such as milk fat, beef fat, lard, fish oil, and whale oil, and the above fats or a mixture of two or more kinds of oils and fats, or curing and separation thereof. Processed fats and oils subjected to transesterification and the like can be used.
また、前記生チョコレート様組成物の水分含有量は8〜18重量%である。水分含有量が18重量%を超えると、得られる生チョコレート様組成物の水分活性が高くなるために長期的な日持ちがせず、また流動性が高くなり生チョコレートのような食感が得られなくなる。一方、水分含有量が8重量%未満では水中油型の乳化が困難である。より好ましい水分含有量の範囲は11〜15重量%である。 Moreover, the moisture content of the said raw chocolate-like composition is 8 to 18 weight%. When the water content exceeds 18% by weight, the water activity of the resulting raw chocolate-like composition is increased, so that it does not last for a long time, and the fluidity is increased, resulting in a texture similar to that of raw chocolate. Disappear. On the other hand, when the water content is less than 8% by weight, oil-in-water emulsification is difficult. A more preferable range of water content is 11 to 15% by weight.
さらに、前記生チョコレート様組成物には、必要により乳化剤、卵、安定剤、呈味成分、洋酒、保存料、塩類、酸味料、抗菌剤、着色料、香料及び酸化防止剤等を加えることができる。 Furthermore, an emulsifier, an egg, a stabilizer, a taste ingredient, a sake, a preservative, a salt, a sour agent, an antibacterial agent, a coloring agent, a fragrance, and an antioxidant may be added to the raw chocolate-like composition as necessary. it can.
乳化剤としては、モノグリセリド、有機酸モノグリセリド、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル及びレシチン等を必要により用いることができる。乳化剤は生チョコレート様組成物中に0.01重量%以上で風味に影響を及ぼさない範囲内で使用するのが好ましい。また、卵としては、全卵、卵黄、卵白、酵素処理卵等を用いることができる。ただし、これらを加えることによって、得られる生チョコレート様組成物の水分活性が減少することはない。 As the emulsifier, monoglyceride, organic acid monoglyceride, polyglycerin fatty acid ester, sucrose fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, lecithin and the like can be used as necessary. The emulsifier is preferably used in the raw chocolate-like composition within a range of 0.01% by weight or more that does not affect the flavor. As the egg, whole egg, egg yolk, egg white, enzyme-treated egg, and the like can be used. However, the water activity of the obtained raw chocolate-like composition is not reduced by adding these.
呈味成分としては、果汁、果肉、ジャム、果汁パウダー、カカオパウダー、コーヒーパウダー、アーモンドペースト及びピーナッツペースト等を必要により用いる。呈味成分を使用する場合は生チョコレート様組成物中に、呈味成分を好ましくは0.1〜25重量%、さらに好ましくは1〜20重量%添加する。但し、前記呈味成分に二糖類以下の糖質が含有される場合には、前記二糖類以下の糖質の含有量としてカウントするため、最終的な含有量が規定範囲内になるように、二糖類以下の糖質及び呈味成分の量を調整する必要がある。 As taste components, fruit juice, pulp, jam, fruit juice powder, cacao powder, coffee powder, almond paste, peanut paste, and the like are used as necessary. When using a taste component, it is preferably 0.1 to 25% by weight, more preferably 1 to 20% by weight, in the raw chocolate-like composition. However, if the taste component contains a saccharide below the disaccharide, to count as the content of the saccharide below the disaccharide, so that the final content is within the specified range, It is necessary to adjust the amount of carbohydrates and taste components below the disaccharide.
洋酒としては、ラム酒やブランデー等が挙げられる。洋酒を使用する場合は、生チョコレート様組成物中に0.1〜5重量%添加するのが好ましい。 Examples of western liquor include rum and brandy. When using Western liquor, it is preferable to add 0.1 to 5 weight% in a raw chocolate-like composition.
塩類としては、塩化ナトリウム、塩化カリウム、塩化マグネシウム、炭酸マグネシウム等が、酸味料としては、クエン酸、リンゴ酸、酒石酸、乳酸等が挙げられる。風味の調整のために塩類や酸味料を添加する場合、前記生チョコレート様組成物中1重量%以下が好ましい。また、塩類には水分活性を下げる効果があるのは既知であるが、前記添加量の範囲では大きな効果は期待できず、酸味料はpHを低くすることによって抗菌性を向上することはできる。但し、pHを低くしすぎることは風味の点であまり好ましくなく、前記生チョコレート様組成物のpHは5.5〜7.5の範囲が好ましい。 Examples of salts include sodium chloride, potassium chloride, magnesium chloride, magnesium carbonate, and examples of acidulants include citric acid, malic acid, tartaric acid, and lactic acid. When adding salt and a sour agent for flavor adjustment, 1 weight% or less is preferable in the said raw chocolate-like composition. Further, it is known that salts have an effect of lowering water activity, but a great effect cannot be expected in the range of the addition amount, and the acidulant can improve antibacterial properties by lowering the pH. However, it is not preferable to make the pH too low in terms of flavor, and the pH of the raw chocolate-like composition is preferably in the range of 5.5 to 7.5.
抗菌剤としては、甘草抽出物、緑茶抽出物、ササエキス、タンニン、リゾチーム等が挙げられ、生チョコレート様組成物中に0.01〜0.5重量%程度で風味に影響が生じない範囲で使用するのが好ましい。 Examples of antibacterial agents include licorice extract, green tea extract, sasa extract, tannin, lysozyme, etc., and used in a range that does not affect the flavor at about 0.01 to 0.5% by weight in a raw chocolate-like composition It is preferable to do this.
また、安定剤、保存料、着色料、フレーバー、酸化防止剤等は、市販のチョコレートに使用されるものであれば、必要に応じて適宜選択して前記生チョコレート様組成物に含有させることができる。 In addition, stabilizers, preservatives, colorants, flavors, antioxidants, and the like may be appropriately selected as needed as long as they are used in commercially available chocolates and included in the raw chocolate-like composition. it can.
本発明に用いられる焼き菓子は、ビスケットに代表されるように、穀粉、澱粉等の原料粉を主原料として、必要に応じて糖類、油脂類、呈味原料、水等の副原料を加え、混合して生地を調製した後、成形、焼成した食品をいう。焼き菓子の生地の配合及び製法については、いわゆるビスケットの規約に制限されない。風味にも特に制限はない。焼き菓子の例としては、ビスケット、クラッカー、パイ等が挙げられる。ビスケットの例としては、プレッツェル、ハードビスケット、ソフトビスケット、クッキー等が挙げられる。本発明で用いられる焼き菓子は、上記の及び他の公知の焼き菓子のいずれでも良い。 The baked confectionery used in the present invention, as typified by biscuits, uses raw materials such as cereal flour and starch as the main raw material, and if necessary, adds auxiliary materials such as sugars, fats and oils, flavoring raw materials, water, A food prepared by mixing and preparing a dough, and then molding and baking. The blending and manufacturing method of the baked confectionery dough is not limited to the so-called biscuit rules. There is no particular restriction on the flavor. Examples of baked goods include biscuits, crackers and pies. Examples of biscuits include pretzels, hard biscuits, soft biscuits, cookies, and the like. The baked confectionery used in the present invention may be any of the above and other known baked confectionery.
穀粉の例としては、小麦粉、ライ麦粉、そば粉、米粉、コーンフラワー、あわ粉、きび粉、はと麦粉、ひえ粉等が挙げられる。 Examples of cereal flours include wheat flour, rye flour, buckwheat flour, rice flour, corn flour, sweet potato flour, acne flour, wheat flour, and millet flour.
澱粉の例としては、馬鈴薯澱粉、タピオカ澱粉、甘藷澱粉、くず澱粉等の地下澱粉、コーンスターチ、小麦澱粉、うるち米澱粉、もち米澱粉等の地上澱粉、ならびに架橋澱粉、エステル化澱粉、エーテル化澱粉等の加工澱粉が挙げられる。 Examples of starch include potato starch, tapioca starch, sweet potato starch, ground starch such as crumb starch, corn starch, wheat starch, ground starch such as glutinous rice starch, glutinous rice starch, cross-linked starch, esterified starch, etherified starch, etc. Processed starch.
糖類の例としては、砂糖、異性化糖、ブドウ糖、麦芽糖、乳糖、トレハロース、マルチトール、パラチニット、水飴やデキストリン等の澱粉分解物、ポリデキストロース等の食物繊維が挙げられる。 Examples of sugars include sugar, isomerized sugar, glucose, maltose, lactose, trehalose, maltitol, palatinit, starch degradation products such as chickenpox and dextrin, and dietary fibers such as polydextrose.
油脂類の例としては、バター、マーガリン、ショートニング、ラード、コーン油、オリーブ油、綿実油、ナタネ油、大豆油、ヤシ油、ゴマ油、ヒマワリ油、ベニバナ油等の各種植物性及び動物性の油脂が挙げられる。 Examples of fats and oils include various vegetable and animal fats such as butter, margarine, shortening, lard, corn oil, olive oil, cottonseed oil, rapeseed oil, soybean oil, coconut oil, sesame oil, sunflower oil, safflower oil, etc. It is done.
呈味原料の例としては、ピーナッツ、アーモンド、マカダミアナッツ、カシューナッツ、栗等の種実類、小豆、えんどう豆、大豆等の豆類、エビ、カニ、鮭、ホタテ、タラコ等の魚介類、ソーセージ、ハム、ベーコン、ミンチ肉等の畜産物質、全卵、卵白、卵黄等の卵類、牛乳、生クリーム、練乳、全粉乳、脱脂粉乳、チーズ、ヨーグルト等の乳類、ニンジン、トマト、オニオン等の野菜類、イチゴ、オレンジ、レーズン、リンゴ、キウイ等の果実類、しいたけ、マッシュルーム等のきのこ類、海苔、昆布、わかめ等の藻類、コーヒー、ココア、ビール、ワイン等の嗜好飲料類、及び食塩、コンソメ、醤油、ソース、カレー粉、胡椒、シナモン等の調味料や香辛料類が挙げられる。 Examples of taste ingredients include peanuts, almonds, macadamia nuts, cashew nuts, chestnuts and other nuts, red beans, peas, soybeans and other beans, shrimp, crabs, sea bream, scallops, taraco and other seafood, sausages, Livestock substances such as ham, bacon, minced meat, eggs such as whole eggs, egg whites, egg yolks, milk, fresh cream, condensed milk, whole milk powder, skim milk powder, cheese, yogurt and other milks, carrots, tomatoes, onions, etc. Fruits such as vegetables, strawberries, oranges, raisins, apples, kiwis, mushrooms such as shiitake mushrooms, algae such as seaweed, kelp, seaweed, beverages such as coffee, cocoa, beer, wine, and salt, Consomme, soy sauce, sauce, curry powder, pepper, cinnamon and other seasonings and spices.
焼き菓子は、当該分野で公知の方法に従って製造される。例えば、まず、焼き菓子の原料を混合して焼き菓子生地を得る。焼き菓子生地の混合は、縦型、横型等の形状を問わず、通常のパン又は菓子の製造過程で用いるミキサーが使用できる。原料が実質的に均一に混合されるのであれば、どのような混合方法を用いても良い。原料の混合順序に特に制限はなく、すべてを一度に入れて混合するいわゆるオールインミックスで良い。特定の原料の添加を他の原料の混合中に行っても良い。油脂類が固形ショートニング等常温固体の場合は、加温融解後に混合する必要が生じる場合がある。その場合、原料粉に加水混合してから添加すると生地粘度の違いにより油脂類と混ざりにくいことがあるため、加水より先に油脂類を軽く混合するか、あるいはオールインミックスの方が望ましい。また果実等の壊れやすい比較的大きな固形物を入れる場合は、生地をほぼ調製してから加えると良い。混合は1〜10分程度の短時間でよく、温度調節、蒸煮、寝かせ時間等は特に必要としない。通常、混合時間が長いほど焼成後の食感がサクサクしたソフトな食感になる傾向があるので、混合時間を調節することによって、目的とする食感に調節することが可能である。特に必要がなければ原料が均一化する最短混合時間で混合して良い。 The baked confectionery is produced according to a method known in the art. For example, first, raw materials for baked confectionery are mixed to obtain a baked confectionery dough. For mixing the baked confectionery dough, regardless of the shape such as a vertical type or a horizontal type, a mixer used in a normal bread or confectionery manufacturing process can be used. Any mixing method may be used as long as the raw materials are mixed substantially uniformly. There is no particular limitation on the mixing order of the raw materials, and so-called all-in-mix in which all are mixed at once may be used. You may add a specific raw material during mixing of another raw material. When the oils and fats are solid at room temperature such as solid shortening, it may be necessary to mix them after heating and melting. In that case, if it is added after being hydrated to the raw material powder, it may be difficult to mix with the fats and oils due to the difference in dough viscosity. Therefore, it is preferable to lightly mix the fats and oils before the addition or all-in-mix. Moreover, when putting comparatively big solids which are easy to break down, such as a fruit, it is good to add, after preparing dough almost. Mixing may be performed in a short time of about 1 to 10 minutes, and temperature control, steaming, laying time, etc. are not particularly required. Usually, the longer the mixing time, the crisp texture after baking tends to be a crisp and soft texture. Therefore, the target texture can be adjusted by adjusting the mixing time. If not particularly necessary, the raw materials may be mixed in the shortest mixing time that makes the materials uniform.
このようにして得られた混合済みの焼き菓子生地を、目的とする形状に成形する。例えば、円形、方形、棒状、円錐状、球状等の目的とする形状及び大きさにするため、デポジッター、押出機、ポンプ等、通常パン及び菓子の製造で用いられる成形機が広く使用できる。 The mixed baked confectionery dough thus obtained is formed into a target shape. For example, in order to obtain a target shape and size such as a circle, a rectangle, a rod, a cone, and a sphere, a molding machine that is usually used in the manufacture of bread and confectionery such as a depositor, an extruder, and a pump can be widely used.
得られた成形済みの焼き菓子生地は、当該分野で公知の任意の焼成条件及び任意の方法で焼成される。焼成のためには、例えば固定オーブン、連続オーブン、ダイレクトオーブン、熱風循環オーブン等いずれも使用可能である。成形済み生地は、必要に応じてスチールベルト、ヘビーメッシュ、ライトメッシュ等を任意に用いて焼成され得る。焼成時間は、成形済みの生地の大きさによって異なるが、通常150〜300℃の範囲において3〜30分間である。 The obtained molded baked confectionery dough is baked by any baking conditions and any method known in the art. For firing, for example, a fixed oven, a continuous oven, a direct oven, a hot air circulation oven, or the like can be used. The shaped fabric can be fired using a steel belt, a heavy mesh, a light mesh or the like as required. Although baking time changes with the magnitude | sizes of the shape | molded material | dough, it is 3 to 30 minutes in the range of 150-300 degreeC normally.
焼き菓子の形状としては、任意の形状を選択することができるが、好ましくは円形もしくは方形である。焼き菓子の大きさはいずれの大きさであってもよいが、好ましくは直径もしくは一辺の長さが1cm〜10cmであり、より好ましくは2cm〜5cmである。大きすぎる場合には保管や喫食の際に割れやすく、小さすぎる場合には手で持って食べる際に食べにくくなりやすい。 As the shape of the baked confectionery, any shape can be selected, but it is preferably circular or square. Although the magnitude | size of baked confectionery may be any magnitude | size, Preferably a diameter or the length of one side is 1 cm-10 cm, More preferably, it is 2 cm-5 cm. When it is too large, it is easy to break during storage and eating, and when it is too small, it is difficult to eat when holding it by hand.
本発明の複合菓子は、前記焼成後の焼き菓子の内部又は表面に、別途調製した水分値が8〜18重量%である生チョコレート様組成物を充填又は付着することで得られる。
前記焼き菓子中への前記生チョコレート様組成物の充填方法としては、一般的な定量充填機や注入機を用いて焼き菓子の内部に任意の量を充填する方法が挙げられる。
また、前記生チョコレート様組成物を前記焼き菓子表面に付着させた場合、付着面とは反対側の生チョコレート様組成物表面にさらに別の焼き菓子を貼付して、焼き菓子の間に生チョコレート様組成物を挟んでもよい。
The composite confectionery of the present invention can be obtained by filling or adhering a freshly prepared chocolate-like composition having a moisture value of 8 to 18% by weight separately prepared inside or on the surface of the baked confectionery after baking.
Examples of a method for filling the baked confectionery in the baked confectionery include a method of filling an arbitrary amount into the baked confectionery using a general quantitative filling machine or an injection machine.
Moreover, when the said raw chocolate-like composition is made to adhere to the said baked confectionery surface, another baked confectionery is stuck on the raw chocolate-like composition surface on the opposite side to an adhesion surface, and fresh chocolate is put between baked confectionery. A like composition may be sandwiched.
次に実施例によって本発明を詳細に説明するが、本発明はこれらの実施例によりなんら制限されるものではない。なお、実施例中の「部」は重量部、「%」は「重量%」を意味する。また、水分活性の測定にはnovasina社の水分活性恒温測定装置「LabMASTER−awBASIC」(商品名)を用いた。 EXAMPLES Next, although an Example demonstrates this invention in detail, this invention is not restrict | limited at all by these Examples. In the examples, “part” means part by weight, and “%” means “% by weight”. In addition, a water activity isothermal measuring device “LabMASTER-awBASIC” (trade name) manufactured by Novasina was used for the water activity measurement.
(チョコレート生地1〜3の作製)
表1に示す配合に従い、ロール掛け及びコンチングを行いチョコレート生地1〜3を得た。
(Preparation of chocolate doughs 1 to 3)
According to the composition shown in Table 1, rolls and conching were performed to obtain chocolate doughs 1 to 3.
製造例1〜14、比較製造例1〜8(生チョコレート様組成物の作製)
表2に示す配合に従い水相成分Aを調製した後、あらかじめ40℃の湯煎で溶かしておいた表2に示す配合の油相成分Bと前記水相成分Aとを、表3に示す割合にて40℃付近で混合乳化し、実施例及び比較製造例の生チョコレート様組成物を得た。得られた実施例及び比較製造例の生チョコレート様組成物の各成分含有量、風味、食感に対する評価、及び水分活性測定値と保存期間の結果を表4に示した。風味及び食感の評価は、各実施例及び比較製造例の生チョコレート様組成物を作製した時点での評価であり、保存期間は、該生チョコレート様組成物を虐待試験(温度35℃、湿度85%)に供し、風味及び食感に影響がないと判断した常温、常湿条件下での換算期間を示した。また、換算期間で1年が経過した後でも、風味及び食感に影響がなかったものは全て12ヶ月と記載した。表中、「◎」は非常に良い、「○」は良い、「×」は悪い、「−」は判定不能を示す。
Production Examples 1 to 14 and Comparative Production Examples 1 to 8 (production of raw chocolate-like compositions)
After preparing the aqueous phase component A according to the formulation shown in Table 2, the oil phase component B and the aqueous phase component A of the formulation shown in Table 2 previously dissolved in a hot water bath at 40 ° C. are in the proportions shown in Table 3. And mixed and emulsified at around 40 ° C. to obtain raw chocolate-like compositions of Examples and Comparative Production Examples. Table 4 shows the content of each component of the raw chocolate-like compositions obtained in the Examples and Comparative Production Examples, the evaluation of the flavor and the texture, and the measured water activity and the storage period. The evaluation of flavor and texture is an evaluation at the time when the raw chocolate-like composition of each Example and Comparative Production Example was prepared, and the storage period was an abuse test (temperature 35 ° C., humidity) 85%), and the conversion period under normal temperature and normal humidity conditions determined to have no effect on flavor and texture. Moreover, even after 1 year passed in the conversion period, all those that did not affect the flavor and texture were described as 12 months. In the table, “◎” indicates very good, “◯” indicates good, “×” indicates bad, and “−” indicates that determination is impossible.
表4に示す結果より、製造例1〜14で得られた生チョコレート様組成物はいずれも風味、食感ともに良く、また水分活性も0.60未満であり、1年経過後でも風味及び食感に何ら影響はなかった。また、製造例1と2を比較するとカラメル化した方が、水分活性はいずれも0.60未満であるがより低く、製造例2と3を比較すると無脂乳固形分を加えた方が、水分活性がより低くなる結果となった。一方、比較製造例1及び2のように、直鎖状多価アルコール、二糖類以下の糖質の含有量が多い場合、保存性は高いものの風味が悪く、比較製造例3〜5のように、直鎖状多価アルコール、二糖類以下の糖質及び水相成分の固形分含有量が規定範囲より少ないもの、また水分含有量が規定範囲より多いものは水分活性が高く、風味が劣化したり表面にカビが発生したりする等1年間の保存性は得られなかった。また、比較製造例6は水分含有量が低すぎるため、水中油型の乳化ができず評価できなかった。さらに、比較製造例7及び8のように、ハードバターの含有量が規定範囲外のものは生チョコレートのような食感が得られなかった。 From the results shown in Table 4, the raw chocolate-like compositions obtained in Production Examples 1 to 14 are both good in flavor and texture, and have a water activity of less than 0.60. There was no effect on the feeling. In addition, when the production examples 1 and 2 are compared, the caramelized one has a water activity of less than 0.60, but when the production examples 2 and 3 are compared, the non-fat milk solid content is added. The result was a lower water activity. On the other hand, as in Comparative Production Examples 1 and 2, when the content of carbohydrates of linear polyhydric alcohols and disaccharides or less is high, the storability is high but the flavor is poor, as in Comparative Production Examples 3-5 , Linear polyhydric alcohols, disaccharides or lower saccharides and water phase components whose solid content is less than the specified range, and those whose water content is higher than the specified range have high water activity and deteriorated flavor. The shelf life of 1 year was not obtained. In Comparative Production Example 6, since the water content was too low, oil-in-water emulsification could not be performed and evaluation could not be performed. Furthermore, as in Comparative Production Examples 7 and 8, when the hard butter content was outside the specified range, the texture of fresh chocolate was not obtained.
(焼き菓子の作製)
薄力粉150部、バター75部、グラニュー糖80部、全卵30部からなる配合で、常法に従い直径30mm、重量3.0gの円形クッキーを作製した。
(Preparation of baked goods)
A round cookie having a diameter of 30 mm and a weight of 3.0 g was prepared according to a conventional method with 150 parts of flour, 75 parts of butter, 80 parts of granulated sugar, and 30 parts of whole egg.
実施例1〜3、比較例1、2(複合菓子の作製)
前記焼き菓子2枚の間にフィリングとして製造例3、9、14の生チョコレート様組成物1.2gを挟むことで焼き菓子と生チョコレート様組成物とを接合し、表6に示す実施例1、2、3の複合菓子を得た。この複合菓子について、28℃と20℃の温度に交互に12時間ずつ晒すサイクルテストを実施し、30サイクル経過後の水分移行及び油脂移行の有無を表5に示した。水分移行に関しては官能による評価を行い、油脂移行に関しては焼き菓子表面の白色化及びチョコレート表面のブルームが生じているかどうかで評価を行った。比較例1、2には、フィリングとして表1に示すチョコレート生地1を使用した複合菓子及び水分値18%に調整した蜂蜜を使用した複合菓子を作製した。これらも同様にサイクルテストを実施し、結果を表5に示した。表中、「○」は評価結果が良い、「×」は評価結果が悪いことを示す。
Examples 1-3, Comparative Examples 1 and 2 (Production of composite confectionery)
The baked confectionery and the raw chocolate-like composition were joined by sandwiching 1.2 g of the raw chocolate-like composition of Production Examples 3, 9, and 14 as a filling between the two baked confectionery, and Example 1 shown in Table 6 A few composite confections were obtained. The composite confectionery was subjected to a cycle test in which it was alternately exposed to 28 ° C. and 20 ° C. for 12 hours, and Table 5 shows the presence or absence of moisture transfer and fat transfer after 30 cycles. The moisture transfer was evaluated by sensory evaluation, and the fat and oil transfer was evaluated based on whether whitening of the baked confectionery surface and blooming of the chocolate surface occurred. In Comparative Examples 1 and 2, composite confectionery using the chocolate confectionery 1 shown in Table 1 as a filling and honey adjusted to a moisture value of 18% were prepared. These were similarly subjected to a cycle test, and the results are shown in Table 5. In the table, “◯” indicates that the evaluation result is good, and “×” indicates that the evaluation result is bad.
表5に示す結果より、製造例3、9、14の生チョコレート様組成物をフィリングとする複合菓子は、いずれも30サイクル経過後の水分移行防止性及び油脂移行防止性ともに優れていることが確認できた。 From the results shown in Table 5, the composite confectionery having the raw chocolate-like compositions of Production Examples 3, 9, and 14 as fillings are excellent in both moisture migration prevention and oil migration prevention after 30 cycles. It could be confirmed.
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