JP2010259633A - Cleaning sheet and manufacturing method thereof - Google Patents
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Abstract
【課題】使用感と清掃効果を共に満足し、かつ、コスト的にも合理的で、使い捨て用途に適したような不織布からなる清掃シートを提供すること。
【解決手段】易分割型複合繊維を分割して得られた繊度0.01〜0.7dtexの極細繊維10〜90重量%と、繊度1〜7dtexの非分割型繊維90〜10重量%を混合して得られた不織布からなる清掃シート。易分割型複合繊維としては、ポリエステル成分とポリアミド成分からなり、両成分を交互に放射状に貼り合わせた断面形状を有する複合繊維が好ましい。
【選択図】なし
To provide a cleaning sheet made of a non-woven fabric that satisfies both the feeling of use and the cleaning effect, is reasonable in cost, and is suitable for disposable use.
SOLUTION: 10 to 90% by weight of ultrafine fibers having a fineness of 0.01 to 0.7 dtex obtained by dividing an easily splittable composite fiber and 90 to 10% by weight of non-split fibers having a fineness of 1 to 7 dtex are mixed. The cleaning sheet which consists of a nonwoven fabric obtained by doing. As the easily split type composite fiber, a composite fiber composed of a polyester component and a polyamide component and having a cross-sectional shape in which both components are alternately bonded radially is preferable.
[Selection figure] None
Description
本発明は、極細繊維(マイクロファイバー)を含む不織布を用いた、キッチン、トイレ、家具、室内の壁、床等の清掃用のシートと、その製造方法に関する。 The present invention relates to a sheet for cleaning kitchens, toilets, furniture, indoor walls, floors, etc., using a nonwoven fabric containing ultrafine fibers (microfibers), and a method for producing the same.
従来から、清掃用の不織布シートとして、繊度が0.5デニール以下に分割された極細繊維を含むものが知られている。例えば、特許文献1には、繊度10デニール以上の繊維20〜90重量%と、機械的に分割可能な繊維が分割した極細繊維10〜80重量%とからなる不織布ワイパーが開示されている。また、極細繊維を含む、あるいは、極細繊維100%のワイパー用不織布(特許文献2)や、極細繊維を含んでなる布帛で構成された自動車用ワイパー(特許文献3)等も知られている。 2. Description of the Related Art Conventionally, as a nonwoven fabric sheet for cleaning, one containing ultrafine fibers divided into a fineness of 0.5 denier or less is known. For example, Patent Document 1 discloses a nonwoven fabric wiper composed of 20 to 90% by weight of fibers having a fineness of 10 denier or more and 10 to 80% by weight of ultrafine fibers divided by mechanically splittable fibers. Further, a wiper non-woven fabric containing ultrafine fibers or 100% ultrafine fibers (Patent Document 2), an automobile wiper composed of a fabric containing ultrafine fibers (Patent Document 3), and the like are also known.
しかしながら、極細繊維の量が多すぎると、使用時の滑りが悪くなる等の問題があり、また、極細繊維のタイプによっては、適切な不織布を得るのが困難であるという問題等もあった。従って、使用感と清掃効果を共に満足し、かつ、コスト的にも合理的で、使い捨て用途に適したような不織布の開発が望まれていた。 However, if the amount of ultrafine fibers is too large, there are problems such as poor sliding during use, and depending on the type of ultrafine fibers, there is also a problem that it is difficult to obtain an appropriate nonwoven fabric. Accordingly, it has been desired to develop a nonwoven fabric that satisfies both the feeling of use and the cleaning effect, is reasonable in cost, and is suitable for disposable use.
本発明の課題は、使用感と清掃効果を共に満足し、かつ、コスト的にも合理的で、使い捨て用途に適したような不織布からなる清掃シートを提供することにある。 An object of the present invention is to provide a cleaning sheet made of a non-woven fabric that satisfies both the feeling of use and the cleaning effect, is reasonable in cost, and is suitable for disposable use.
本発明者は、上記課題を解決するために、極細繊維の種類、繊維の太さ、組合わせる通常の繊維の太さと割合等を詳細に検討することによって、前記全ての条件を満足する不織布からなる清掃用のシートを開発したものである。 In order to solve the above problems, the present inventor examines in detail the type of ultrafine fiber, the thickness of the fiber, the thickness and the ratio of the normal fiber to be combined, and the like from the nonwoven fabric satisfying all the above conditions. This is the development of a cleaning sheet.
即ち、本発明は、易分割型複合繊維を分割して得られた繊度0.01〜0.7dtexの極細繊維10〜90重量%と、繊度1〜7dtexの非分割型繊維90〜10重量%を混合して得られた不織布からなる清掃シートである。 That is, the present invention provides 10 to 90% by weight of ultrafine fibers having a fineness of 0.01 to 0.7 dtex obtained by dividing an easily splittable composite fiber, and 90 to 10% by weight of non-split type fibers having a fineness of 1 to 7 dtex. It is the cleaning sheet which consists of a nonwoven fabric obtained by mixing.
本発明の他の態様は、易分割型複合繊維を分割して得られた繊度0.01〜0.7dtexの極細繊維10〜90重量%と、繊度1〜7dtexの非分割型の吸湿性の繊維90〜10重量%を混合して得られた不織布に、除菌剤又は防腐剤を含む水が含浸せしめられてなるウェットタイプの清掃シートである。 Another aspect of the present invention is that 10 to 90% by weight of ultrafine fiber having a fineness of 0.01 to 0.7 dtex obtained by dividing an easily splittable composite fiber and a non-split type hygroscopic material having a fineness of 1 to 7 dtex. It is a wet type cleaning sheet in which a nonwoven fabric obtained by mixing 90 to 10% by weight of fibers is impregnated with water containing a disinfectant or a preservative.
本発明のもう一つの態様は、易分割型複合繊維を分割して得られた繊度0.01〜0.7dtexの極細繊維10〜90重量%と、繊度1〜7dtexの非分割型のポリエステル繊維90〜10重量%を混合して得られた不織布に、集塵剤が含浸せしめられてなるドライタイプの清掃シートである。 Another aspect of the present invention is that 10 to 90% by weight of ultrafine fibers having a fineness of 0.01 to 0.7 dtex obtained by dividing an easily splittable composite fiber, and non-split polyester fibers having a fineness of 1 to 7 dtex. It is a dry type cleaning sheet in which a non-woven fabric obtained by mixing 90 to 10% by weight is impregnated with a dust collecting agent.
そして、本発明の更に他の態様は、不織布からなる清掃シートを製造する方法であって、分割されて繊度0.01〜0.7dtexの極細繊維を生成する易分割型複合繊維10〜90重量%と、繊度1〜7dtexの非分割型繊維90〜10重量%を混合し、スパンレース法、スパンボンド法又はニードルパンチ法で不織布を作製することからなる清掃シートの製造方法である。 And the other aspect of this invention is a method of manufacturing the cleaning sheet which consists of a nonwoven fabric, Comprising: 10-90 weight of easily split-type composite fibers which are divided | segmented and produce | generate the ultrafine fiber of the fineness of 0.01-0.7 dtex % And 90 to 10% by weight of non-divided fibers having a fineness of 1 to 7 dtex, and a nonwoven fabric is produced by a spunlace method, a spunbond method or a needle punch method.
本発明によれば、易分割型複合繊維を分割して得られた極細繊維(マイクロファイバー)と、非分割型繊維を混合して得られた不織布からなる清掃シートが得られる。本発明においては、マイクロファイバーの清浄機能を使うことによって、界面活性剤などの洗剤成分を特に用いなくても、汚れ落としができるウェットタイプの清掃シートが得られる。また、ドライタイプでも、マイクロファイバーの分割繊維構造により、ほこり等の汚れを、特に集塵剤(流動パラフィン等)を使用しなくても絡め取ることができる。 According to this invention, the cleaning sheet which consists of the nonwoven fabric obtained by mixing the ultra fine fiber (microfiber) obtained by dividing | segmenting an easily-divided type composite fiber and a non-partition type fiber is obtained. In the present invention, by using the cleaning function of the microfiber, a wet type cleaning sheet capable of removing dirt can be obtained without using a detergent component such as a surfactant. Even in the dry type, dirt such as dust can be entangled without using a dust collecting agent (such as liquid paraffin) due to the split fiber structure of the microfiber.
本発明における不織布は、易分割型複合繊維を分割して得られた繊度0.01〜0.7dtexの極細繊維10〜90重量%と、繊度1〜7dtexの非分割型繊維90〜10重量%を混合して得られるものである。 The nonwoven fabric in the present invention is 10 to 90% by weight of ultrafine fibers having a fineness of 0.01 to 0.7 dtex and 90 to 10% by weight of non-split fibers having a fineness of 1 to 7 dtex obtained by dividing the easily splittable composite fiber. Is obtained by mixing.
易分割型複合繊維とは、機械的な衝撃により分割しやすく、分割することにより繊度が0.01〜0.7dtex程度の極細繊維を与える繊維である。かかる易分割型複合繊維としては、ポリアミド成分とポリエステル成分、ポリアミド成分とポリオレフィン成分、ポリアミド成分とポリアクリロニトリル系ポリマー成分、ポリエステル成分とポリオレフィン成分等の組合せを例示できるが、これら2種類の樹脂成分からなる易分割型繊維に限定されるものではなく、3種類以上の樹脂成分からなる易分割型複合繊維であってもよい。本発明においては、ポリアミド成分とポリエステル成分の組み合わせが好ましい。 The easily split type composite fiber is a fiber that is easily split by mechanical impact and gives a fine fiber having a fineness of about 0.01 to 0.7 dtex by splitting. Examples of such easily splittable composite fibers include polyamide components and polyester components, polyamide components and polyolefin components, polyamide components and polyacrylonitrile-based polymer components, polyester components and polyolefin components, and the like. It is not limited to the easily split-type fibers, and may be easily split composite fibers made of three or more types of resin components. In the present invention, a combination of a polyamide component and a polyester component is preferred.
易分割型複合繊維中の各成分はどのように配置されていても良く、例えば、断面が、両成分を交互に放射状に張り合わせた形状の繊維(中空繊維であってもよい)や、異なる成分を交互に層状に積層したバイメタル型繊維や、一つの成分が放射状に形成され、その間にくさび形の他の成分が配置されているような断面形状を有する繊維等がある。これらの易分割型複合繊維から得られる極細繊維は、鋭利な断面形状部分を有するため、断面がほぼ円形の極細繊維に比べて、油膜などの清浄性により優れている。 Each component in the easily splittable composite fiber may be arranged in any way, for example, a cross-section of a fiber in which both components are alternately bonded in a radial pattern (may be a hollow fiber) or a different component There are bimetallic fibers in which layers are alternately laminated, fibers having a cross-sectional shape in which one component is formed radially and another wedge-shaped component is disposed therebetween. Since the ultrafine fibers obtained from these easily split composite fibers have a sharp cross-sectional shape portion, they are more excellent in cleanliness such as an oil film than the ultrafine fibers having a substantially circular cross section.
本発明において、不織布は、易分割型複合繊維を分割して得られた繊度0.01〜0.7dtex、好ましくは0.05〜0.2dtexの極細繊維10〜90重量%、好ましくは40〜60重量%と、繊度1〜7dtex、好ましくは1〜2dtexの非分割型繊維90〜10重量%、好ましくは60〜40重量%とからなるものである。易分割型複合繊維の量が10重量%未満の場合は、極細繊維による油膜などの清浄性が低下し、逆に、90重量%を越えると、繊維のすべり特性が悪くなり、取扱い性に劣る。また、不織布の嵩高性も低くなり集塵性が悪くなる。非分割型繊維の量が10重量%未満の場合は、あるいは、90重量%を越える場合には、前記と逆の欠点が発生するので不適当である。 In the present invention, the nonwoven fabric has a fineness of 0.01 to 0.7 dtex obtained by dividing an easily split composite fiber, preferably 0.05 to 0.2 dtex, and an ultrafine fiber of 10 to 90% by weight, preferably 40 to 40%. It is composed of 60% by weight and 90 to 10% by weight, preferably 60 to 40% by weight, of non-divided fibers having a fineness of 1 to 7 dtex, preferably 1 to 2 dtex. When the amount of the easily splittable composite fiber is less than 10% by weight, the cleanliness of the oil film or the like by the ultrafine fiber is lowered, and conversely, when it exceeds 90% by weight, the slip property of the fiber is deteriorated and the handling property is inferior. . Moreover, the bulkiness of a nonwoven fabric also becomes low and dust collection property worsens. If the amount of the non-split fiber is less than 10% by weight, or if it exceeds 90% by weight, the disadvantages opposite to those described above occur, which is inappropriate.
繊度1〜7dtexの非分割型繊維としては、特に制限はないが、レーヨンのような再生繊維、絹、羊毛のような動物繊維、アセテート繊維のような半合成繊維、ポリアミド(ナイロン)繊維、ビニロン繊維、アクリル繊維、ポリエステル繊維、ポリ塩化ビニリデン繊維、ポリ塩化ビニル系繊維、ポリウレタン繊維、ポリエチレン繊維、ポリプロピレン繊維などの合成繊維を例示できる。 The non-divided fiber having a fineness of 1 to 7 dtex is not particularly limited, but regenerated fiber such as rayon, animal fiber such as silk and wool, semi-synthetic fiber such as acetate fiber, polyamide (nylon) fiber, vinylon Examples thereof include synthetic fibers such as fiber, acrylic fiber, polyester fiber, polyvinylidene chloride fiber, polyvinyl chloride fiber, polyurethane fiber, polyethylene fiber, and polypropylene fiber.
非分割型繊維として吸湿性の繊維を選択した場合には、得られた不織布に、除菌剤又は防腐剤を含む水を含浸せしめることによってウェットタイプの清掃シートとすることができる。吸湿性の繊維の中では特にレーヨンが好ましい。また、不織布に含浸させる水には、界面活性剤や香料やアルコール等を添加してもよい。 When a hygroscopic fiber is selected as the non-split fiber, a wet type cleaning sheet can be obtained by impregnating the obtained non-woven fabric with water containing a disinfectant or a preservative. Among hygroscopic fibers, rayon is particularly preferable. Moreover, you may add surfactant, a fragrance | flavor, alcohol, etc. to the water impregnated to a nonwoven fabric.
本発明の不織布に、特に何も含浸させることなくそのまま用いると、ドライタイプの清掃シートとすることができる。この場合には、非分割型繊維としてポリエステル繊維を用いるのが好ましい。また、得られた不織布をそのままドライタイプの清掃シートとしてもよいが、不織布に流動パラフィン等の集塵剤を含浸せしめてドライタイプの清掃シートとしてもよい。 When the nonwoven fabric of the present invention is used as it is without impregnating anything, a dry type cleaning sheet can be obtained. In this case, it is preferable to use a polyester fiber as the non-split type fiber. The obtained non-woven fabric may be used as a dry type cleaning sheet as it is, but a non-woven fabric may be impregnated with a dust collecting agent such as liquid paraffin to form a dry type cleaning sheet.
本発明における不織布は、易分割型複合繊維を分割して得られた繊度0.01〜0.7dtexの極細繊維10〜90重量%と、繊度1〜7dtexの非分割型繊維90〜10重量%を混合して得られた不織布である限り、その製法は何ら制限されるものではない。 The nonwoven fabric in the present invention is 10 to 90% by weight of ultrafine fibers having a fineness of 0.01 to 0.7 dtex and 90 to 10% by weight of non-split fibers having a fineness of 1 to 7 dtex obtained by dividing the easily splittable composite fiber. As long as it is a non-woven fabric obtained by mixing, the production method is not limited.
易分割型複合繊維は機械的な容易に分割が可能であるので、繊度1〜7dtexの非分割型繊維と混合し、例えば、カード法によりカード機を通すことで易分割型複合繊維を分割開繊し、非分割型繊維と絡合して繊維ウェブとすることができる。そして、その後、スパンレース法、ニードルパンチ法、スパンボンド法、スプレー法、熱融着性繊維によるサーマルボンド法等の方法により、分割を十分なものとすると共に、繊維間の絡合又は結合を十分なものにすることによって製造することができる。極細繊維が太い非分割型繊維に点的に絡まるため、得られる繊維ウェブは剛性、強度に優れ、太い非分割型繊維による空隙を維持している。 Easy-split composite fibers can be easily mechanically split, so they are mixed with non-split fibers with a fineness of 1 to 7 dtex, and split-opened by, for example, passing through a card machine by the card method. It can be woven and entangled with non-split fibers to form a fiber web. After that, by using a method such as a spunlace method, a needle punch method, a spunbond method, a spray method, or a thermal bond method using a heat-fusible fiber, the division is sufficient, and the entanglement or bonding between fibers is performed. It can be manufactured by making it sufficient. Since the ultrafine fibers are entangled with the thick non-dividing fibers, the resulting fiber web is excellent in rigidity and strength, and maintains the voids due to the thick non-dividing fibers.
本発明においては、スパンレース法、スパンボンド法又はニードルパンチ法が好ましく用いられる。スパンレース法は、湿式法で繊維をウェブ化し、それに高圧柱状水流をあて、繊維を3次元交絡させる方法である。スパンボンド法は、長繊維をシート状にして熱と圧力を加えることにより不織布とするものである。スパンボンド法による不織布は、伸び縮みしないといった特性があるので、紙オムツなどの材料として適している。ニードルパンチ法は、かえしのある針により繊維を結合させてシートを形成する方法である。 In the present invention, a spunlace method, a spunbond method or a needle punch method is preferably used. The spunlace method is a method in which fibers are made into a web by a wet method, and a high-pressure columnar water stream is applied to the fibers to entangle the fibers three-dimensionally. In the spunbond method, long fibers are formed into a sheet shape and heat and pressure are applied to form a nonwoven fabric. Non-woven fabric by the spunbond method is suitable as a material for paper diapers because it does not stretch or shrink. The needle punching method is a method of forming a sheet by binding fibers with a barbed needle.
以下、実施例により本発明を説明するが、本発明は、以下の実施例に限定されるものではない。 EXAMPLES Hereinafter, although an Example demonstrates this invention, this invention is not limited to a following example.
ポリアミド成分をポリエステル成分の間に放射状に配した繊維断面をもち、16分割可能な菊花型の易分割型繊維(繊度2.2dtex、繊維長38mm)を50重量%と、非分割型繊維として繊度1.65dtex、繊維長51mmのレーヨン50重量%とを混綿し、カード機により開繊した後、スパンレーヨン法で絡合して不織布を作製した。得られた不織布の目付は45g/m2、厚みは0.3mm、見掛け密度は0.15g/cm3であった。 It has a fiber cross-section in which polyamide components are arranged radially between polyester components, and it is 50% by weight of 16-divided chrysanthemum-shaped chrysanthemum-type easily-divided fibers (fineness 2.2 dtex, fiber length 38 mm). After blending 1.65 dtex and 50% by weight of rayon having a fiber length of 51 mm, the fiber was opened by a card machine, and then entangled by a span rayon method to produce a nonwoven fabric. The obtained nonwoven fabric had a basis weight of 45 g / m 2 , a thickness of 0.3 mm, and an apparent density of 0.15 g / cm 3 .
かくして得られた不織布は、易分割型繊維を使用しているため、カード機により開繊する過程で易分割型繊維が十分に分割し極細繊維を形成し、油分や汚れの清浄性に優れている。また、非分割型繊維は太い繊維であるので、得られた不織布は空隙のために嵩高いものとなり、優れた吸塵性をも発揮する。従って、得られた不織布は適当なサイズに切断して、そのままドライタイプの清掃シートとして使用することができる。 Since the nonwoven fabric thus obtained uses easily split fibers, the easily split fibers are sufficiently split in the process of opening with a card machine to form ultrafine fibers, and is excellent in cleanliness of oil and dirt. Yes. In addition, since the non-split fiber is a thick fiber, the obtained nonwoven fabric is bulky due to the voids, and exhibits excellent dust absorption. Therefore, the obtained nonwoven fabric can be cut into an appropriate size and used as it is as a dry type cleaning sheet.
実施例1で得られた不織布に、0.5%の市販の除菌剤と5%のエタノールを含む水を、不織布1m2当たり100ml含浸せしめて、清浄性に優れたウェットタイプの清掃シートを得た。 The nonwoven fabric obtained in Example 1 was impregnated with 100 ml of water containing 0.5% commercially available disinfectant and 5% ethanol per 1 m 2 of nonwoven fabric to obtain a wet type cleaning sheet having excellent cleanability. It was.
非分割型繊維として繊度2.2dtex、繊維長38mmのポリエステル繊維50重量%を用いる以外は、実施例1と同様にして、目付、厚み、見掛け密度がそれぞれ45g/m2、0.3mm、0.15g/cm3の不織布を得た。得られた不織布は適当なサイズに切断して、そのまま清浄性と吸塵性に優れたドライタイプの清掃シートとすることができた。
The basis weight, thickness, and apparent density were 45 g / m 2 , 0.3 mm, and 0, respectively, in the same manner as in Example 1 except that 50% by weight of polyester fiber having a fineness of 2.2 dtex and a fiber length of 38 mm was used as the non-split type fiber. A nonwoven fabric of .15 g / cm 3 was obtained. The obtained non-woven fabric was cut into an appropriate size, and a dry type cleaning sheet excellent in cleanliness and dust absorption could be obtained as it was.
Claims (8)
A method for producing a cleaning sheet comprising a non-woven fabric, comprising 10 to 90% by weight of easily splittable composite fibers that are split to produce ultrafine fibers with a fineness of 0.01 to 0.7 dtex, and a non-split type with a fineness of 1 to 7 dtex A method for producing a cleaning sheet, comprising mixing 90 to 10% by weight of fibers and producing a nonwoven fabric by a spunlace method, a spunbond method or a needle punch method.
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JP2009113202A JP2010259633A (en) | 2009-05-08 | 2009-05-08 | Cleaning sheet and manufacturing method thereof |
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JP2009113202A JP2010259633A (en) | 2009-05-08 | 2009-05-08 | Cleaning sheet and manufacturing method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2015000277A (en) * | 2013-06-18 | 2015-01-05 | ダイワボウホールディングス株式会社 | Wiper and method for manufacturing the same |
WO2019071170A1 (en) * | 2017-10-06 | 2019-04-11 | Berry Global, Inc. | Cleaning fabric |
EP3437513B1 (en) | 2016-04-01 | 2020-12-02 | Kolon Industries, Inc. | Nonwoven sheet for facial mask |
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JPH03152255A (en) * | 1989-11-04 | 1991-06-28 | Japan Vilene Co Ltd | Nonwoven fabric cleaning material and production thereof |
JPH0496724A (en) * | 1990-08-10 | 1992-03-30 | Kao Corp | cleaning supplies |
JP2006000625A (en) * | 2004-05-20 | 2006-01-05 | Daiwabo Co Ltd | Wiping sheet |
WO2008117805A1 (en) * | 2007-03-26 | 2008-10-02 | Mitsui Chemicals, Inc. | Mixed continuous fiber nonwoven fabric and process for manufacturing the same |
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2009
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH03152255A (en) * | 1989-11-04 | 1991-06-28 | Japan Vilene Co Ltd | Nonwoven fabric cleaning material and production thereof |
JPH0496724A (en) * | 1990-08-10 | 1992-03-30 | Kao Corp | cleaning supplies |
JP2006000625A (en) * | 2004-05-20 | 2006-01-05 | Daiwabo Co Ltd | Wiping sheet |
WO2008117805A1 (en) * | 2007-03-26 | 2008-10-02 | Mitsui Chemicals, Inc. | Mixed continuous fiber nonwoven fabric and process for manufacturing the same |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015000277A (en) * | 2013-06-18 | 2015-01-05 | ダイワボウホールディングス株式会社 | Wiper and method for manufacturing the same |
EP3437513B1 (en) | 2016-04-01 | 2020-12-02 | Kolon Industries, Inc. | Nonwoven sheet for facial mask |
WO2019071170A1 (en) * | 2017-10-06 | 2019-04-11 | Berry Global, Inc. | Cleaning fabric |
US11105027B2 (en) * | 2017-10-06 | 2021-08-31 | Berry Global, Inc. | Cleaning fabric |
US20210348316A1 (en) * | 2017-10-06 | 2021-11-11 | Berry Global, Inc. | Cleaning Fabric |
US12077890B2 (en) * | 2017-10-06 | 2024-09-03 | Berry Global, Inc. | Cleaning fabric |
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