JP2009278893A - Highly thickening starch adhesive composition and thickening method - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a highly thickening starch adhesive composition comprising a combination of xanthan gum, and Tara gum or Cyamoposis Gum, and showing synergistically excellent thickening properties by overcoming defects such as poor liquid separation, and occurrence of pasty feeling and sticky feeling when the composition is added to food. <P>SOLUTION: This highly thickening starch adhesive composition is obtained by mixing (C) karaya gum with a starch adhesive composition which contains (A) xanthan gum, and (B) Tara gum and/or Cyamoposis Gum. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

  The present invention relates to a high-viscosity paste composition for adding to a water-containing low-viscosity substance and imparting a high viscosity thereto or gelling it, and a thickening method using the same.

In the field of food and cosmetics, a thickening paste is used to improve the viscosity of a low-viscosity substance or to cause gelation.
As such a thickening paste, as a gelling agent for producing a dessert such as pudding, a combination of xanthan gum and starch or tara gum (see Patent Document 1), sauce, dressing, sauce, mousse , Guam gum, locust bean gum, tara gum, xanthan gum, tamarind gum, tragacanth gum, karaya gum, konjac mannan, CMC sodium, for thickening foods such as jelly, and dietary addition for patients who have difficulty chewing or swallowing , Sodium alginate, pectin, azotobacter vinegar gum, carrageenan, modified starch, cassia gum, silium seed gum, CMC, methylcellulose and other additives for thickening (see Patent Document 2), Paste and glycerin, propylene glycol A composition for thickening or gelling containing thiol or ethanol (see Patent Document 3), a combination of the above-mentioned paste and a low-viscosity polysaccharide selected from gum arabic, arabinogalactan, pullulan, and soybean polysaccharide The additive solution for thickening (see Patent Document 4) is also selected from galactomannan, xanthan gum, tamarind seed gum, pectin, carrageenan, gellan gum, agar, soybean water-soluble polysaccharide, glucomannan, sodium alginate, karaya gum Water dispersible cellulose is used to improve the disadvantage that the liquid-disrupting property is poor when added to foods, and that it shows a pasty feeling and a sticky feeling when added to foods. Has been proposed (see Patent Document 5).

  And in said patent document 3, the liquid paste which disperse | distributed xanthan gum and tara gum to the dispersing agent which consists of glycerin and propylene glycol is shown as an Example, and patent document 5 has bad liquid cutting property, A comparative example in which guar gum and xanthan gum are mixed at a mass ratio of 3: 1 is shown as an example of what has the disadvantage of exhibiting a pasty feeling or stickiness when added to food.

  Accordingly, thickeners combining xanthan gum and tara gum or guagum have been known so far, but these thickeners have almost the same viscosity-improving effect as xanthan gum alone, and as described above, When it is added to foods, it has a disadvantage that it produces a pasty feeling or sticky feeling and deteriorates the quality as a food.

JP 47-14345 (Claims and others) JP 2000-41594 A (Claims 1, 0001, 0011, etc.) JP-A-2005-333885 (Claims and others) Japanese Patent Laying-Open No. 2006-166828 (Claim 4 and others) JP 2008-50376 A (Claim 1, 0002, Comparative Example 7 etc.)

  The present invention overcomes the disadvantages of a thickening paste composition composed of a combination of xanthan gum and tara gum or gua gum that overcomes the drawbacks of poor liquidity and produces a pasty or sticky feeling when added to food. The present invention has been made for the purpose of providing a highly thickening paste composition exhibiting excellent thickening.

  In order to develop a novel thickening paste composition that has a synergistic effect and overcomes the disadvantages of a thickening paste composition containing a combination of xanthan gum and tara gum or guar gum as an active ingredient. As a result of intensive research, by adding a certain proportion of Karaya gum to the above thickening paste composition, the liquid drainage associated with the combination of xanthan gum and tara gum or guagum is poor, resulting in a food product. Deterioration of food texture due to pasty feeling and stickiness when added is suppressed, and significant increase in thickening is observed, and this thickening identifies the above components (A) and (B) By using this ratio, it has been found that it becomes more prominent, and the present invention has been made based on this finding.

  That is, the present invention provides (A) a xanthane gum and (B) a tara gum or a guava gum or both, and (C) a high-viscosity glue composition characterized by blending karaya gum, and Provided is a thickening method characterized in that (A) xanthan gum, (B) tara gum and / or guar gum and (C) Karaya gum are mixed in advance or separately added to a low-viscosity substance to improve the viscosity. Is.

  And about the high-viscosity paste composition of this invention, by selecting the composition, 10g was melt | dissolved in the ion-exchange water 100g of temperature 85 degreeC, and it stirred for 1 minute, and prepared by cooling to 30 degreeC. The test solution was a B-type viscometer [manufactured by Tokyo Keiki Co., Ltd., rotational speed 30 rpm, No. This is advantageous because the viscosity when measured by using 4 rotors can be set to 10,000 mPa · s or more.

  Normally, the thickening effect on low-viscosity substances depends on the amount of thickener to be added, but in the case of thickening paste compositions containing polysaccharides as active ingredients so far, in order to give high viscosity 3-10% by mass or more must be blended, but the product thickened by blending a large amount of the paste composition in this way has an unpleasant sensation due to the off-flavors and odors derived from polysaccharides. There was a problem that could not be avoided.

  However, since the high-viscosity paste composition of the present invention can be prepared to have a high viscosity, it can provide the desired high viscosity with a small amount of blending, and thus can solve the above problems. it can.

  In the present invention, xanthan gum used as the component (A) is a water-soluble natural polysaccharide obtained by fermenting starch such as corn with bacteria, and a main chain in which D-glucose is bonded to β-1,4 and this main chain. It is a substance having a structure in which a side chain composed of D-mannose and D-glucuronic acid is bonded to main chain anhydroglucose. A molecular weight of about 2 million to 50 million is known, but any molecular weight can be used in the present invention.

Next, the tara gum used as the component (B) is a polysaccharide obtained by crushing and purifying the endosperm portion of the seed of the codfish family cod, the main component of which is galactomannan, and galactose and mannose are about 1: 3. Gua gum is a mucus substance contained in the endosperm part of the seed of the leguminous plant gua, the main component is galactomannan, and galactose and mannose are combined at a ratio of about 1: 2. Is.
As the component (B), tara gum alone or guagam alone may be used, or both may be used in combination.

In addition, Karaya gum used as component (C) is a polysaccharide containing partially acetylated branches obtained from secretions exuded from the trunk of Karaya trees distributed in the central and northern dry areas of India. Rhamnose and galacto It has a main chain composed of uronic acid, and contains about 40% by mass of uronic acid and 8% by mass or less of acetyl group, and has a molecular weight of about 9,500,000.
In the present invention, a natural product may be used as it is, or a low molecular weight product obtained by hydrolysis may be used.

The blending ratio of the component (C) is usually 30: 1 to 1: 1, preferably 15: 1 to 1: 1 by mass ratio of the total amount of the components (A) and (B) and the component (C). When the range, that is, the total amount of the component (A) and the component (B) is 10, the component (C) is selected within the range of 0.3 to 10, preferably 0.6 to 5. Absent. In general, if the amount of component (C) is small, the thickening effect cannot be improved compared to the case where component (A) and component (B) are added, and the combination of component (A) and component (B). There is a tendency that it is not possible to suppress the disadvantages caused by the addition of, i.e., the loss of liquid cutting property, the pasty feeling, and the sticky feeling. Further, even if the amount of the component (C) is increased too much, the improvement of the effect due to the addition is not recognized, and it is uneconomical to merely increase the cost due to an increase in the amount of expensive karaya gum used.
Further, considering only the thickening effect, only the component (A) and the component (C) may be used.

  On the other hand, the improvement in the thickening effect in the present invention is particularly remarkable when the mixing ratio of the component (A) and the component (B) is 7: 3 to 3: 7, particularly 2: 1 to 1: 2. It is preferable to select a range.

  In addition, as the high-viscosity paste composition of the present invention, it is desirable that a low-viscosity substance can be imparted with a high viscosity, for example, a viscosity of 10,000 mPa · s or more, with as little use amount as possible. 10 g of sample is dissolved in 100 g of ion-exchanged water at a temperature of 85 ° C., stirred for 1 minute, cooled to 30 ° C. to prepare a test solution, and the viscosity when measured with a B-type viscometer is 10000 mPa · s or more. In addition, it is advantageous to select the components and mixing ratios to be used.

  Next, the low-viscosity substance that can be thickened by the high-viscosity paste composition of the present invention is not particularly limited as long as it takes a liquid or paste form at room temperature. Such low-viscosity substances include liquid foods, liquid cosmetics, liquid pharmaceuticals, liquid industrial products, and the like.

  Examples of liquid foods include coffee, tea, green tea, cocoa, juice, juice, soy milk, raw milk, processed milk, lactic acid bacteria beverages, calcium-fortified beverages, dietary fiber-containing beverages, coffee whiteners, whipping Dairy products such as cream, custard cream and soft cream, soups, stews, sauces, sauces, dressings, pastes, pastes, pastes and other liquid foods such as seasonings, fruit sauces, fruit preparations such as fruit preparations, fluidity There may be mentioned foods, liquid or pasty supplements, liquid or pasty pet foods.

  Examples of the above liquid pharmaceuticals include oral preparations, nasal preparations, infusion preparations, tube preparations, ointments, medicinal cosmetics, vitamin-containing health agents, medicinal hair restorers, medicated dentifrices, bath preparations, anthelmintics, Examples include a foul odor preventing agent, a mouth freshener, a biomaterial, a patch, and a skin coating agent.

  Examples of the above liquid cosmetics include skin cosmetics (skin lotion, milky lotion, cosmetic liquid, pack, moisture cream, massage cream, cold cream, cleansing cream, face wash, vanishing cream, emollient cream, hand cream, antiperspirant / Deodorants, sunscreen cosmetics, etc.), cosmetics for finishing (foundation, funny, lipstick, lip balm, blusher, sunscreen cosmetics, eyebrows, mascara and other eyelash cosmetics, nail polish and light removal liquid, etc.) Hair cosmetics (shampoos, hair rinses, hair tonics, hair treatments, pomades, tics, hair creams, balms, hair styling agents, hair styling agents, hair sprays, hair dyes, hair restorers, hair nourishing agents, etc.) and other cleaning products such as hand cleaners Agent, bath cosmetic, shaving Cosmetics, fragrances, toothpaste, ointments, and the like plasters.

  Examples of liquid industrial products include pigments, paints, inks, deodorants and fragrances, antibacterial and antifungal agents, adhesives, coating agents, sealing agents, heat dissipation agents, various oils (cutting oil, lubricating oil, etc.) ), Puncture repair agents, tires, tubes for bicycles and automobiles, surfactants (dispersants), hygiene materials, wetting materials, hygroscopic materials, adsorbing materials, surface protection agents, culture materials, detergents, liquid soaps, etc. it can.

  Next, in order to thicken the low viscosity substance according to the method of the present invention, the high viscosity paste composition of the present invention is added to the low viscosity substance in an amount necessary to obtain a desired viscosity, Stir well while heating and disperse uniformly.

  The addition amount at this time is appropriately selected depending on how much viscosity improvement is required for the low-viscosity substance, but usually 10% by mass or less, so that the quality of the product is not impaired by the addition. A range of 5% by mass or less is preferably selected. For example, in order to give a viscosity of about honey (B-type viscosity of about 1000 mPa · s), it is selected within the range of 0.1 to 1% by mass, and to give a high viscosity of about 10,000 mPa · s. A range of 0.5 to 10% by mass is selected.

  As the heating temperature, a temperature in the range of 60 to 90 ° C, preferably 80 to 85 ° C is used. By this heating, the viscosity once decreases, but when it is cooled to room temperature, for example, 30 ° C. or less, the viscosity increases remarkably. Even if the mixture is simply mixed at room temperature, an excellent viscosity improvement is recognized as compared with the case where the conventional paste composition is used. However, when the mixture is once heated to 80 ° C. and cooled again, a remarkable thickening effect can be obtained. Is done.

As a procedure for increasing the viscosity according to the method of the present invention, necessary amounts of the component (A), the component (B) and the component (C) may be mixed in advance and added to the low-viscosity material, or may be mixed in advance (A ) Component and (B) component may be added to the low-viscosity material, and then component (C) may be added, or component (A), component (B), and component (C) may be added separately in any order. And may be added to low viscosity substances.
However, in order to obtain a simple and stable effect, the components (A), (B) and (C) are mixed in advance, that is, after producing the highly thickening paste composition of the present invention, It is advantageous to dissolve this in water and add it to the low viscosity substance at once.

The high-viscosity paste composition of the present invention can significantly increase the viscosity of low-viscosity substances despite the use of polysaccharides. For example, the same amount of paste composition used so far can be used. A thickened product having a viscosity of 10,000 mPa · s or more can be obtained with a moderate amount of use. Moreover, if it is the viscosity requested | required with respect to the conventional low viscosity substance, since it may be less compared with the usage-amount at the time of using the conventional paste composition, the off-flavor and odor caused by polysaccharide can be suppressed. Therefore, for example, in the field of foods and pharmaceuticals, an excellent effect of not inhibiting the taste is exhibited. Furthermore, according to the present invention, since the amount used can be increased with a small amount, for example, it is possible to increase the amount of a component in a low-viscosity material, or to add other components, In addition to enhancing the functionality of the product, it has the effect of saving resources by reducing the total amount of the product.
Further, according to the method of the present invention, a higher thickening effect can be obtained by heating once and then cooling, and therefore, it is suitably used in the field of foods such as jelly and pudding that are heated during the processing.

  Next, the best mode for carrying out the present invention will be described, but the present invention is not limited to these examples.

B-type viscosity (mPa · s)
The paste composition was added to 100 g of ion-exchanged water at a temperature of 30 ° C. and stirred at 1000 rpm for 60 minutes to prepare a thickened product, and the B-type viscosity of the thickened product was measured. The B-type viscosity was measured using a B-type viscometer (manufactured by Tokyo Keiki Co., Ltd., No. 4 rotor, measured at a rotation speed of 30 rpm for 5 minutes) and heated to 25 ° C, 85 ° C, and 85 ° C , And measured at 3 points after cooling to 25 ° C.

Xanthan gum, tara gum and karaya gum were dissolved in 100 ml of distilled water in the amounts shown in Table 1, and stirred for 60 minutes to prepare nine types of samples.
The temperature of each sample thus obtained was adjusted to 25 ° C. with a water bath, and the B-type viscosity was measured. Next, the temperature of the water bath was raised, each sample was heated to 85 ° C., maintained for 10 minutes, then cooled to 25 ° C. by natural cooling, and the B-type viscosity was measured again.
The measured values for each sample thus obtained are shown in Table 1.

Xanthan gum, tara gum and karaya gum were dissolved in 100 ml of distilled water in the proportions shown in Table 2 as a total amount of 0.2 g, and stirred for 60 minutes.
The solution was adjusted to 25 ° C. with a water bath, and the B-type viscosity was measured.
Subsequently, the temperature of the water bath was raised, the temperature of the sample was adjusted to 85 ° C. and maintained for 10 minutes, then the temperature was lowered to 25 ° C. by natural cooling, and the B-type viscosity was measured again.
Table 2 shows the measured values of the B-type viscosity thus obtained.

  As can be seen from this table, when an equal mixture of the A component and the B component was used, the ratio of the C component to the total amount of the A component and the B component was 10:15, that is, 2: 3 or less, and 85 ° C. After heating to 25 ° C., the B-type viscosity rapidly decreases when cooled to 25 ° C.

In 100 ml of distilled water, xanthan gum, tara gum and karaya gum were each dissolved in the amounts shown in Table 3 in a total amount of 0.2 g and stirred for 60 minutes.
The solution was adjusted to 25 ° C. with a water bath, and the B-type viscosity was measured.
Subsequently, the temperature of the water bath was raised, the temperature of the sample was adjusted to 85 ° C. and maintained for 10 minutes, then the temperature was lowered to 25 ° C. by natural cooling, and the B-type viscosity was measured again.
The measured values of the B-type viscosity thus obtained are shown in Table 3.

  As can be seen from this table, when the amount of the B component is larger than that of the A component, the B-type viscosity tends to decrease as the C component increases in the product cooled after heating.

In 100 ml of distilled water, xanthan gum, tara gum and karaya gum were each dissolved in the amounts shown in Table 4 in a total amount of 0.2 g and stirred for 60 minutes.
The solution was adjusted to 25 ° C. with a water bath, and the B-type viscosity was measured.
Subsequently, the temperature of the water bath was raised, the temperature of the sample was adjusted to 85 ° C. and maintained for 10 minutes, then the temperature was lowered to 25 ° C. by natural cooling, and the B-type viscosity was measured again.
The measured values of the B-type viscosity thus obtained are shown in Table 4.

  As can be seen from this table, it can be seen that when the amount of the A component is larger than that of the B component, the B-type viscosity of the one cooled after heating is higher than that containing no C component. Further, when (A + B): C is 5: 4 or more, the B-type viscosity tends to decrease slightly.

Xanthan gum, tara gum and karaya gum were dissolved in 100 ml of distilled water at a ratio shown in Table 5 as a total amount of 0.2 g and stirred for 60 minutes.
The solution was adjusted to 25 ° C. with a water bath, and the B-type viscosity was measured.
Subsequently, the temperature of the water bath was raised, the temperature of the sample was adjusted to 85 ° C. and maintained for 10 minutes, then the temperature was lowered to 25 ° C. by natural cooling, and the B-type viscosity was measured again.
Table 5 shows the measured values of the B-type viscosity thus obtained.

  As can be seen from this table, when using the three components of component A, component B and component C, the B-type viscosity of both the component at 25 ° C. and the component cooled after heating is higher than the combination of component B and component C. I understand that it is expensive. Further, when (A + B): C is 5: 4 or more, the viscosity tends to decrease.

Reference example 1
A total amount of 0.2 g of each component listed in Table 6 was dissolved in 100 ml of distilled water at a ratio described in the table, and stirred for 60 minutes.
The solution was adjusted to 25 ° C. with a water bath, and the B-type viscosity was measured.
Subsequently, the temperature of the water bath was raised, the temperature of the sample was adjusted to 85 ° C. and maintained for 10 minutes, then the temperature was lowered to 25 ° C. by natural cooling, and the B-type viscosity was measured again.
Table 6 shows the measured values of the B-type viscosity thus obtained.

  As can be seen from this table, when the three components of the A component, the B component and the C component are used, the B-type viscosity of the one cooled after heating is higher than the combination of the A component and the C component.

Reference example 2
A total amount of 0.2 g of each component described in Table 7 was dissolved in 100 ml of distilled water at a ratio described in the table and stirred for 60 minutes.
The solution was adjusted to 25 ° C. with a water bath, and the B-type viscosity was measured.
Subsequently, the temperature of the water bath was raised, the temperature of the sample was adjusted to 85 ° C. and maintained for 10 minutes, then the temperature was lowered to 25 ° C. by natural cooling, and the B-type viscosity was measured again.
Table 7 shows the measured values of the B-type viscosity thus obtained.

  As can be seen from this table, each component alone has a small thickening effect, and compared to the combination of the A component and the B component, those containing the C component tend to have a high thickening effect. It can be seen from 7-6 and 2-1, 7-8 and 3-1, and 7-9 and 4-1.

  The high-viscosity paste composition of the present invention is useful as an additive for improving the viscosity of low-viscosity substances in the fields of food and cosmetics.

Claims (6)

  A high-viscosity paste composition comprising (C) Karaya gum in a paste composition containing (A) xanthan gum and (B) tara gum or guagum or both.   The high-viscosity paste composition according to claim 1, wherein the content ratio of the component (A) and the component (B) is in the range of 7: 3 to 3: 7 by mass ratio.   The high-viscosity paste composition according to claim 1 or 2, wherein the total amount of the component (A) and the component (B) and the mass ratio of the component (C) are in the range of 30: 1 to 1: 1.   (A) Xanthan gum, (B) tara gum and / or guar gum, and (C) Karaya gum are mixed in advance or separately added to a low-viscosity substance to improve the viscosity.   The thickening method according to claim 4, wherein the component (A) and the component (B) are used in a mass ratio of 7: 3 to 3: 7.   The thickening method according to claim 4 or 5, wherein the total amount of the component (A) and the component (B) and the mass ratio of the component (C) are used in a range of 30: 1 to 1: 1.