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JP2009241971A - Synthetic resin-made square bottle - Google Patents

Synthetic resin-made square bottle Download PDF

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Publication number
JP2009241971A
JP2009241971A JP2008092860A JP2008092860A JP2009241971A JP 2009241971 A JP2009241971 A JP 2009241971A JP 2008092860 A JP2008092860 A JP 2008092860A JP 2008092860 A JP2008092860 A JP 2008092860A JP 2009241971 A JP2009241971 A JP 2009241971A
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Prior art keywords
bottle
corner
synthetic resin
corner surface
roughened
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Inventor
Hiromichi Saito
浩通 斉藤
Toyoji Kato
豊治 加藤
Tadashi Hayakawa
忠司 早川
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Yoshino Kogyosho Co Ltd
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Yoshino Kogyosho Co Ltd
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Priority to JP2008092860A priority Critical patent/JP2009241971A/en
Publication of JP2009241971A publication Critical patent/JP2009241971A/en
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a synthetic resin-made square bottle capable of suppressing any dent of a corner surface part to a non-restorable degree even when the bottle is thin-walled. <P>SOLUTION: The synthetic resin-made square bottle 10 has a barrel portion 11, in which a panel surface part 15 and a corner surface part 16 are alternately and continuously provided along the bottle circumference. The outer surface of at least the corner surface part 16 of the barrel portion 11 forms a roughened surface 11a formed by a die surface subjected to the surface roughing. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、合成樹脂製の角型ボトルに関するものである。   The present invention relates to a square bottle made of synthetic resin.

従来から、例えば下記特許文献1に示されるような、ボトル周方向に沿ってパネル面部とコーナ面部とが交互に連設されてなる胴部を有する合成樹脂製の角型ボトルが知られている。
特開2005−8153号公報
2. Description of the Related Art Conventionally, a square bottle made of a synthetic resin having a body portion in which panel surface portions and corner surface portions are alternately arranged along the circumferential direction of a bottle as shown in, for example, Patent Document 1 below is known. .
JP 2005-8153 A

ところで近年では、この種のボトルにおいては、例えば環境対策や低コスト化等の観点から合成樹脂の使用量を低減した薄肉化が検討されているが、このような薄肉のボトルでは、例えばボトルを把持したとき、あるいは充填工程や梱包工程等の搬送時、さらにはボトル内の減圧時等に、ヒケが生じた部分を起点として復元不能な程度までへこみ易くなるおそれがあった。
特に、角型ボトルでは、コーナ面部がボトルの最大径部分を有しているため、このコーナ面部に外力が加わり易く、しかもコーナ面部の面積がパネル面部の面積より小さくなっているので、コーナ面部に力が直接作用した場合のみならず、パネル面部に作用した力がコーナ面部とパネル面部との間の稜線部を越えてコーナ面部に伝播した場合にも、コーナ面部が復元不能な程度までへこみ易くなるおそれがあった。
By the way, in recent years, in this type of bottle, for example, from the viewpoint of environmental measures and cost reduction, a reduction in the thickness of the synthetic resin used has been studied. When gripping, transporting in a filling process, packing process, etc., or when the inside of a bottle is decompressed, there is a possibility that it becomes easy to dent to the extent that it cannot be restored starting from the part where the sink mark has occurred.
In particular, in the case of a square bottle, since the corner surface portion has the maximum diameter portion of the bottle, an external force is likely to be applied to the corner surface portion, and the corner surface portion is smaller than the area of the panel surface portion. Not only when the force acts directly on the panel surface, but also when the force acting on the panel surface part propagates to the corner surface part beyond the ridge line part between the corner surface part and the panel surface part, the corner surface part is dented to such an extent that it cannot be restored. There was a risk of becoming easier.

本発明は、このような事情を考慮してなされたもので、薄肉に形成してもコーナ面部が復元不能な程度までへこむのを抑制することができる合成樹脂製角型ボトルを提供することを目的とする。   The present invention has been made in consideration of such circumstances, and it is intended to provide a square bottle made of synthetic resin that can prevent the corner surface portion from being dented to the extent that it cannot be restored even if formed thin. Objective.

上記課題を解決して、このような目的を達成するために、本発明の合成樹脂製角型ボトルは、ボトル周方向に沿ってパネル面部とコーナ面部とが交互に連設されてなる胴部を有する合成樹脂製の角型ボトルであって、前記胴部のうち少なくとも前記コーナ面部の外表面は、粗面加工が施された金型面で成形された粗面化処理面となっていることを特徴とする。   In order to solve the above-described problems and achieve such an object, the synthetic resin square bottle of the present invention has a body portion in which panel surface portions and corner surface portions are alternately arranged along the peripheral direction of the bottle. A square bottle made of synthetic resin having at least the outer surface of the corner surface portion of the body portion is a roughened surface formed by a roughened die surface. It is characterized by that.

この発明では、コーナ面部の外表面が前記粗面化処理面となっているので、このコーナ面部の外表面側に柔軟性を具備させて弾性力を発揮させ易くすることが可能になる。したがって、コーナ面部に力が作用しても、このコーナ面部を復元不能な程度までへこませることなくこの力をコーナ面部で吸収することができる。
さらに、コーナ面部の外表面が粗面加工の施された金型面で成形されているので、コーナ面部の外表面が前記金型面に密着するのを抑制することが可能になり、このボトルの金型からの離型性を向上させることができる。したがって、型開き時にコーナ面部に作用する力を低減することが可能になり、コーナ面部でヒケが生ずるのを抑制することができる。
以上より、この角型ボトルを薄肉に形成してもコーナ面部が復元不能な程度までへこむのを抑制することができる。
In this invention, since the outer surface of the corner surface portion is the roughened surface, the outer surface side of the corner surface portion can be provided with flexibility to easily exert an elastic force. Accordingly, even if a force acts on the corner surface portion, the corner surface portion can absorb this force without causing the corner surface portion to be dented to an extent that cannot be restored.
Furthermore, since the outer surface of the corner surface portion is molded with a roughened mold surface, it is possible to suppress the outer surface of the corner surface portion from being in close contact with the mold surface. The mold releasability from the mold can be improved. Therefore, it is possible to reduce the force acting on the corner surface portion when the mold is opened, and it is possible to suppress the occurrence of sink marks at the corner surface portion.
As described above, even if the square bottle is formed thin, it is possible to prevent the corner surface portion from being dented to the extent that it cannot be restored.

ここで、前記パネル面部とコーナ面部とは稜線部を介してボトル周方向に沿って交互に連設され、前記粗面化処理面は、前記稜線部の外表面をボトル周方向に跨いでもよい。
この場合、粗面化処理面がパネル面部とコーナ面部との間の稜線部の外表面をボトル周方向に跨いでいるので、パネル面部に作用した力が稜線部を越えてコーナ面部に伝播しようとしたときに、この力を稜線部の外表面側で吸収することができる。
Here, the panel surface portion and the corner surface portion may be alternately arranged along the circumferential direction of the bottle via the ridge line portion, and the roughening treatment surface may straddle the outer surface of the ridge line portion in the bottle circumferential direction. .
In this case, since the roughened surface straddles the outer surface of the ridge line part between the panel surface part and the corner surface part in the bottle circumferential direction, the force acting on the panel surface part will propagate to the corner surface part beyond the ridge line part. This force can be absorbed on the outer surface side of the ridge line portion.

この発明に係る合成樹脂製角型ボトルによれば、薄肉に形成してもコーナ面部が復元不能な程度までへこむのを抑制することができる。   According to the square bottle made of synthetic resin according to the present invention, it is possible to prevent the corner surface portion from being dented to the extent that it cannot be restored even if it is formed thin.

以下、図面を参照し、この発明の実施の形態について説明する。本実施形態に係る合成樹脂製角型ボトル10は、底部12、胴部11、肩部13および口部14がボトル軸線O方向に沿ってこの順に連設されるとともに、例えばポリエチレンテレフタレートやポリプロピレン等の合成樹脂で一体に形成されている。また、これらの底部12、胴部11、肩部13および口部14がボトル軸線Oと同軸上に配置されている。なお、この角型ボトル10は例えば2軸延伸ブロー成形により形成される。また、図示の例では、胴部11と肩部13とは、胴部11の外表面に対する傾斜角度が肩部13よりも小さいテーパ部19を介して連結されている。
以下、ボトル軸線O方向に沿って底部12側を下側といい、口部14側を上側という。
Embodiments of the present invention will be described below with reference to the drawings. In the synthetic resin square bottle 10 according to the present embodiment, a bottom portion 12, a body portion 11, a shoulder portion 13 and a mouth portion 14 are provided in this order along the bottle axis O direction, and for example, polyethylene terephthalate, polypropylene, or the like. The synthetic resin is integrally formed. Further, the bottom portion 12, the trunk portion 11, the shoulder portion 13, and the mouth portion 14 are arranged coaxially with the bottle axis O. The square bottle 10 is formed by biaxial stretch blow molding, for example. Further, in the illustrated example, the trunk portion 11 and the shoulder portion 13 are connected via a taper portion 19 whose inclination angle with respect to the outer surface of the trunk portion 11 is smaller than that of the shoulder portion 13.
Hereinafter, the bottom 12 side is referred to as the lower side along the bottle axis O direction, and the mouth 14 side is referred to as the upper side.

そして、ボトル軸線O方向に沿って底部12から肩部13にわたった部分は、パネル面部15と、このパネル面部15の幅、つまりボトル周方向の大きさより幅の狭いコーナ面部16と、が稜線部17を介してボトル周方向に沿って交互に連設されて構成されている。これにより、このボトル10の上面視形状および底面視形状は、図2および図3に示されるような多角形状となっている。   A portion extending from the bottom portion 12 to the shoulder portion 13 along the bottle axis O direction has a panel surface portion 15 and a corner surface portion 16 narrower than the width of the panel surface portion 15, that is, the size in the bottle circumferential direction. It is configured to be alternately arranged along the circumferential direction of the bottle via the portion 17. Thereby, the top view shape and the bottom view shape of the bottle 10 are polygonal shapes as shown in FIGS. 2 and 3.

なお、底部12の底面12aには、その外周縁部に位置する平坦な接地面12bと、この接地面12bのボトル径方向内側に位置しこのボトル10の内側に向けて窪む窪み部12cと、が形成されている。また、窪み部12cの表面には、ボトル軸線O回りに間隔をあけて複数の補強凸リブ12dが形成されている。   The bottom surface 12a of the bottom portion 12 has a flat ground surface 12b located at the outer peripheral edge thereof, and a recessed portion 12c that is located on the inner side of the ground surface 12b in the bottle radial direction and is recessed toward the inside of the bottle 10. , Is formed. In addition, a plurality of reinforcing convex ribs 12d are formed on the surface of the recess 12c at intervals around the bottle axis O.

また、パネル面部15およびコーナ面部16はそれぞれ4つずつ備えられている。そして、それぞれのパネル面部15はボトル径方向で他のパネル面部15と対向するように配置されている。また、各コーナ面部16もボトル径方向で他のコーナ面部16と対向するように配置されている。   Further, four panel surface portions 15 and four corner surface portions 16 are provided. And each panel surface part 15 is arrange | positioned so that the other panel surface part 15 may be opposed in a bottle radial direction. Each corner surface portion 16 is also arranged so as to face another corner surface portion 16 in the bottle radial direction.

ここで、胴部11の下部には、全周にわたって延びる環状凹リブ18が形成されている。また、胴部11において環状凹リブ18の上側に位置する部分は、環状凹リブ18の下側に位置する部分よりもボトル軸線O方向に沿った長さが長くなっている。そして、胴部11のパネル面部15には、環状凹リブ18の上側に位置する部分および下側に位置する部分にそれぞれ、減圧吸収パネル部15cが形成されている。   Here, an annular concave rib 18 extending over the entire circumference is formed in the lower portion of the body portion 11. Further, the length of the body portion 11 located above the annular concave rib 18 is longer in the bottle axis O direction than the portion located below the annular concave rib 18. And the decompression absorption panel part 15c is formed in the panel surface part 15 of the trunk | drum 11 in the part located in the upper part of the cyclic | annular concave rib 18, and the part located in the lower part, respectively.

そして、本実施形態では、胴部11のうち少なくともコーナ面部16の外表面は、粗面加工が施された金型面で成形された粗面化処理面11aとなっている。図示の例では、この粗面化処理面11aは、図1にハッチングで示されるように、胴部11の外表面のうち環状凹リブ18の上側に位置する部分において、減圧吸収パネル部15cを除く全域となっている。   In the present embodiment, at least the outer surface of the corner surface portion 16 of the body portion 11 is a roughened surface 11a formed by a roughened die surface. In the example shown in the drawing, the roughened surface 11a has a reduced pressure absorbing panel 15c at the portion located on the upper side of the annular concave rib 18 on the outer surface of the body 11 as shown by hatching in FIG. Except for the entire area.

ここで、前記金型面に施す粗面加工としては、例えばシボ加工やブラスト加工等が挙げられる。また、粗面化処理面11aは図4に示されるように微小な凹凸部が多数形成されて構成されている。さらに、この粗面化処理面11aの表面粗さは、キーエンス社製レーザーフォーカス変位計(LT−8010)を使用して測定した。本実施形態における前記表面粗さは55μm〜75μmとなっており、平均で65μmであった(JIS B0601の最大高さRzに相当)。   Here, examples of the rough surface processing applied to the mold surface include a texture processing and a blast processing. Further, the roughened surface 11a is configured by forming a large number of minute uneven portions as shown in FIG. Furthermore, the surface roughness of the roughened surface 11a was measured using a laser focus displacement meter (LT-8010) manufactured by Keyence Corporation. The surface roughness in the present embodiment was 55 μm to 75 μm, and was 65 μm on average (corresponding to the maximum height Rz of JIS B0601).

以上説明したように本実施形態に係る合成樹脂製角型ボトル10によれば、コーナ面部16の外表面が粗面化処理面11aとなっているので、このコーナ面部16の外表面側に柔軟性を具備させて弾性力を発揮させ易くすることが可能になる。したがって、コーナ面部16に力が作用しても、このコーナ面部16を復元不能な程度までへこませることなくこの力をコーナ面部16で吸収することができる。   As described above, according to the synthetic resin square bottle 10 according to the present embodiment, the outer surface of the corner surface portion 16 is the roughened surface 11a, so that the outer surface side of the corner surface portion 16 is flexible. It becomes possible to make it easy to exhibit elasticity by providing the property. Therefore, even if a force is applied to the corner surface portion 16, the corner surface portion 16 can absorb this force without causing the corner surface portion 16 to be dented to the extent that it cannot be restored.

さらに、コーナ面部16の外表面が粗面加工の施された金型面で成形されているので、コーナ面部16の外表面が前記金型面に密着するのを抑制することが可能になり、このボトル10の金型からの離型性を向上させることができる。したがって、型開き時にコーナ面部16に作用する力を低減することが可能になり、コーナ面部16でヒケが生ずるのを抑制することができる。
以上より、この角型ボトル10を薄肉に形成してもコーナ面部16が復元不能な程度までへこむのを抑制することができる。
Furthermore, since the outer surface of the corner surface portion 16 is molded with a roughened mold surface, it is possible to suppress the outer surface of the corner surface portion 16 from being in close contact with the mold surface, The releasability of the bottle 10 from the mold can be improved. Therefore, it is possible to reduce the force acting on the corner surface portion 16 when the mold is opened, and it is possible to suppress the occurrence of sink marks on the corner surface portion 16.
As mentioned above, even if this square bottle 10 is formed thin, it can suppress that the corner surface part 16 is dented to the extent which cannot be restored | restored.

また、本実施形態では、胴部11の外表面のうち環状凹リブ18の上側に位置する部分において、減圧吸収パネル部15cを除く全域が粗面化処理面11aとなっていて、この粗面化処理面11aが稜線部17の外表面をボトル周方向に跨いでいるので、パネル面部15に作用した力が稜線部17を越えてコーナ面部16に伝播しようとしたときに、この力を稜線部17の外表面側で吸収することができる。   Moreover, in this embodiment, in the part located in the upper part of the annular concave rib 18 among the outer surfaces of the trunk | drum 11, the whole area except the decompression absorption panel part 15c becomes the roughening process surface 11a, This rough surface Since the process surface 11a straddles the outer surface of the ridge line portion 17 in the bottle circumferential direction, when the force acting on the panel surface portion 15 tries to propagate to the corner surface portion 16 beyond the ridge line portion 17, this force is applied to the ridge line. It can be absorbed on the outer surface side of the portion 17.

なお、本発明の技術的範囲は前記実施の形態に限定されるものではなく、本発明の趣旨を逸脱しない範囲において種々の変更を加えることが可能である。
例えば、前記実施形態では、胴部11の外表面のうち環状凹リブ18の上側に位置する部分において、減圧吸収パネル部15cを除く全域を粗面化処理面11aとしたが、前記上側に位置する部分のうち、コーナ面部16だけを粗面化処理面11aとしてもよい。
また、これに代えて、胴部11の外表面のうち環状凹リブ18の下側に位置する部分において、減圧吸収パネル部15cを除く全域を粗面化処理面11aとしてもよいし、さらにこの場合、前記下側に位置する部分のうち、コーナ面部16だけを粗面化処理面11aとしてもよい。
The technical scope of the present invention is not limited to the above embodiment, and various modifications can be made without departing from the spirit of the present invention.
For example, in the above-described embodiment, in the portion located on the upper side of the annular concave rib 18 in the outer surface of the body portion 11, the entire area excluding the reduced pressure absorption panel portion 15c is the roughened surface 11a. Of the portions to be processed, only the corner surface portion 16 may be the roughened surface 11a.
Alternatively, the entire surface of the outer surface of the body portion 11 except for the reduced pressure absorption panel portion 15c may be used as the roughened surface 11a in the portion located below the annular concave rib 18. In this case, only the corner surface portion 16 among the portions located on the lower side may be the roughened surface 11a.

さらにまた、胴部11におけるコーナ面部16の外表面を、環状凹リブ18を除く全域にわたって粗面化処理面11aにしてもよい。
また、胴部11におけるコーナ面部16の外表面を粗面化処理面11aにする場合には、この粗面化処理面11aは、コーナ面部16のみならずこのコーナ面部16にボトル周方向で連なる一対の稜線部17の外表面にも形成するのが好ましい。
Furthermore, the outer surface of the corner surface portion 16 in the body portion 11 may be a roughened surface 11 a over the entire area excluding the annular concave rib 18.
Further, when the outer surface of the corner surface portion 16 in the body portion 11 is a roughened surface 11a, the roughened surface 11a is connected not only to the corner surface portion 16 but also to the corner surface portion 16 in the bottle circumferential direction. It is preferable to form also on the outer surface of a pair of ridgeline part 17. FIG.

さらに前記実施形態では、胴部11と肩部13とがテーパ部19を介して連結された構成を示したが、このテーパ部19を有しない角型ボトルを採用してもよい。
また、前記実施形態では、胴部11に環状凹リブ18を形成したが、この環状凹リブ18は形成しなくてもよい。そして、胴部11におけるコーナ面部16の外表面を全域にわたって粗面化処理面11aにしてもよい。
Furthermore, in the said embodiment, although the trunk | drum 11 and the shoulder part 13 were connected via the taper part 19, the square bottle which does not have this taper part 19 may be employ | adopted.
Moreover, in the said embodiment, although the annular concave rib 18 was formed in the trunk | drum 11, this annular concave rib 18 does not need to be formed. And you may make the outer surface of the corner surface part 16 in the trunk | drum 11 into the roughening process surface 11a over the whole region.

薄肉に形成してもコーナ面部が復元不能な程度までへこむのを抑制することができる。   Even if it is formed to be thin, it is possible to prevent the corner surface portion from being dented to the extent that it cannot be restored.

本発明に係る一実施形態として示した合成樹脂製角型ボトルの正面図である。It is a front view of the square bottle made from a synthetic resin shown as one embodiment concerning the present invention. 図1に示す合成樹脂製角型ボトルの上面図である。It is a top view of the synthetic resin square-shaped bottle shown in FIG. 図1に示す合成樹脂製角型ボトルの底面図である。It is a bottom view of the synthetic resin square bottle shown in FIG. 図1に示す合成樹脂製角型ボトルの一部拡大縦断面図である。It is a partially expanded longitudinal cross-sectional view of the synthetic resin square bottle shown in FIG.

符号の説明Explanation of symbols

10 合成樹脂製角型ボトル
11 胴部
11a 粗面化処理面
12 底部
13 肩部
14 口部
15 パネル面部
16 コーナ面部
17 稜線部
O ボトル軸線
DESCRIPTION OF SYMBOLS 10 Synthetic resin square bottle 11 Body 11a Roughening surface 12 Bottom 13 Shoulder 14 Mouth 15 Panel surface 16 Corner surface 17 Edge line O Bottle axis

Claims (2)

ボトル周方向に沿ってパネル面部とコーナ面部とが交互に連設されてなる胴部を有する合成樹脂製の角型ボトルであって、
前記胴部のうち少なくとも前記コーナ面部の外表面は、粗面加工が施された金型面で成形された粗面化処理面となっていることを特徴とする合成樹脂製角型ボトル。
A square bottle made of synthetic resin having a body portion in which panel surface portions and corner surface portions are alternately arranged along the circumferential direction of the bottle,
A synthetic resin square bottle characterized in that at least the outer surface of the corner surface portion of the body portion is a roughened surface formed by a roughened mold surface.
請求項1記載の合成樹脂製角型ボトルであって、
前記パネル面部とコーナ面部とは稜線部を介してボトル周方向に沿って交互に連設され、
前記粗面化処理面は、前記稜線部の外表面をボトル周方向に跨いでいることを特徴とする合成樹脂製角型ボトル。
The square bottle made of synthetic resin according to claim 1,
The panel surface portion and the corner surface portion are alternately arranged along the circumferential direction of the bottle via the ridge line portion,
The synthetic resin square bottle characterized in that the roughened surface is straddling the outer surface of the ridge line portion in the bottle circumferential direction.
JP2008092860A 2008-03-31 2008-03-31 Synthetic resin-made square bottle Pending JP2009241971A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9382029B2 (en) 2011-11-09 2016-07-05 Toyo Seikan Group Holdings, Ltd Angular resin container and blow molding die
JP2017065712A (en) * 2015-09-29 2017-04-06 北海製罐株式会社 Synthetic resin multiple bottles
JP2017100330A (en) * 2015-12-01 2017-06-08 三笠産業株式会社 Container production method and container
JPWO2018051509A1 (en) * 2016-09-16 2019-06-27 サントリーホールディングス株式会社 Resin bottle
JP2021008295A (en) * 2019-06-28 2021-01-28 株式会社吉野工業所 Flat bottle and manufacturing method of the same
JP2021070493A (en) * 2019-10-31 2021-05-06 株式会社吉野工業所 Square bottle
US11840367B2 (en) 2016-03-22 2023-12-12 Hokkai Can Co., Ltd. Synthetic resin multilayer bottle

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3088764U (en) * 2002-03-22 2002-09-27 東洋硝器株式会社 Resin container
JP2005008153A (en) * 2003-06-16 2005-01-13 Dainippon Printing Co Ltd Bottle made of synthetic resin
JP2007021962A (en) * 2005-07-19 2007-02-01 Toyo Seikan Kaisha Ltd Two step blow molding process for flat container

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3088764U (en) * 2002-03-22 2002-09-27 東洋硝器株式会社 Resin container
JP2005008153A (en) * 2003-06-16 2005-01-13 Dainippon Printing Co Ltd Bottle made of synthetic resin
JP2007021962A (en) * 2005-07-19 2007-02-01 Toyo Seikan Kaisha Ltd Two step blow molding process for flat container

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9382029B2 (en) 2011-11-09 2016-07-05 Toyo Seikan Group Holdings, Ltd Angular resin container and blow molding die
JP2017065712A (en) * 2015-09-29 2017-04-06 北海製罐株式会社 Synthetic resin multiple bottles
JP2017100330A (en) * 2015-12-01 2017-06-08 三笠産業株式会社 Container production method and container
US11840367B2 (en) 2016-03-22 2023-12-12 Hokkai Can Co., Ltd. Synthetic resin multilayer bottle
JPWO2018051509A1 (en) * 2016-09-16 2019-06-27 サントリーホールディングス株式会社 Resin bottle
JP2021008295A (en) * 2019-06-28 2021-01-28 株式会社吉野工業所 Flat bottle and manufacturing method of the same
JP2021070493A (en) * 2019-10-31 2021-05-06 株式会社吉野工業所 Square bottle
JP7345358B2 (en) 2019-10-31 2023-09-15 株式会社吉野工業所 square bottle

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