JP2009155209A - Oil-in-water type emulsion composition and method for producing the same - Google Patents
Oil-in-water type emulsion composition and method for producing the same Download PDFInfo
- Publication number
- JP2009155209A JP2009155209A JP2007331416A JP2007331416A JP2009155209A JP 2009155209 A JP2009155209 A JP 2009155209A JP 2007331416 A JP2007331416 A JP 2007331416A JP 2007331416 A JP2007331416 A JP 2007331416A JP 2009155209 A JP2009155209 A JP 2009155209A
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- Prior art keywords
- oil
- emulsion composition
- powder
- water emulsion
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000203 mixture Substances 0.000 title claims abstract description 81
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- 238000004519 manufacturing process Methods 0.000 title claims description 13
- 239000000839 emulsion Substances 0.000 title abstract description 11
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- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
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- 239000007764 o/w emulsion Substances 0.000 claims description 58
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- 238000000576 coating method Methods 0.000 abstract description 21
- 239000011248 coating agent Substances 0.000 abstract description 20
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
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Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、水中油乳化組成物、更に詳しくは光輝性粉体を多量に含有する水中油乳化組成物に関する。 The present invention relates to an oil-in-water emulsion composition, and more particularly to an oil-in-water emulsion composition containing a large amount of glittering powder.
光輝性粉体は、反射光や干渉反射光に特徴がある薄片状の粉体であり、メークアップ化粧料などに含有して華やかさを演出するのに用いられている。ここで、光輝性粉体とは、マイカや鱗片状ガラスフレークなどの薄片状の粉体を二酸化チタンなどの薄層で被覆処理した粉体で、特有の干渉光を有する粉体、或いはアルミフレークに高分子フィルムなどを積層して干渉光を有する薄片状の粉体を意味する。これらの光輝性粉体を多量に含有した粉体化粧料、油性化粧料或いは水性化粧料は知られている（例えば、特許文献１、特許文献２、特許文献３、特許文献４、特許文献５を参照。）が、演出効果を強調するために光輝性粉体を３０〜７０質量％という多量に含有した水中油型乳化組成物は知られていない。一般に、光輝性粉体を含有する水中油型の乳化組成物を得るには、光輝性粉体を含有する油相を水相で乳化する、或いは予め水中油型乳化組成物を作成しておき、これに光輝性粉体を添加する方法で得ることが行われてきた。しかしながら、３０質量％を超えるような多量の光輝性粉体を含有する油相を乳化するのは困難であったり、水中油型乳化物に多量の光輝性粉体を添加すると乳化粒子が破壊されたりと、多量の光輝性粉体を安定に含有した水中油型乳化組成物を得るのは困難であった。すなわち、華やかな演出効果を高めるために、多量の光輝性粉体を含有しながら、安定な水中油型の乳化組成物が求められていた。 The glitter powder is a flaky powder characterized by reflected light and interference reflected light, and is used to produce glamorousness by being contained in makeup cosmetics. Here, the glittering powder is a powder obtained by coating a flaky powder such as mica or flaky glass flake with a thin layer of titanium dioxide or the like, and a powder having specific interference light or aluminum flake. It means a flaky powder having interference light by laminating a polymer film or the like. Powder cosmetics, oily cosmetics or aqueous cosmetics containing a large amount of these glittering powders are known (for example, Patent Document 1, Patent Document 2, Patent Document 3, Patent Document 4, Patent Document 5). However, an oil-in-water emulsified composition containing a large amount of glittering powder of 30 to 70% by mass in order to emphasize the effect of production is not known. In general, in order to obtain an oil-in-water emulsion composition containing glitter powder, an oil phase containing glitter powder is emulsified with an aqueous phase, or an oil-in-water emulsion composition is prepared in advance. It has been practiced to obtain this by adding glittering powder. However, it is difficult to emulsify an oil phase containing a large amount of glittering powder exceeding 30% by mass, or emulsified particles are destroyed when a large amount of glittering powder is added to an oil-in-water emulsion. However, it has been difficult to obtain an oil-in-water emulsion composition stably containing a large amount of glittering powder. That is, a stable oil-in-water emulsion composition has been demanded while containing a large amount of glittering powder in order to enhance a gorgeous rendering effect.
光輝性粉体を多量に含有してパール効果が高いながら、その製剤系が安定である水中油型の乳化組成物を得ることを課題とした。 An object of the present invention is to obtain an oil-in-water emulsion composition containing a large amount of glittering powder and having a high pearl effect, but having a stable formulation system.
本発明者らは、光輝性粉体を含有する水中油型の乳化組成物において、３０〜７０質量%という多量の光輝性粉体を含有しても安定である水中油型の乳化組成物を求めて鋭意研究した結果、以下のような乳化組成物が安定であることを見出した。すなわち、本願発明は、以下に示すようである。 The present inventors provide an oil-in-water emulsion composition that is stable even if it contains a large amount of glittering powder of 30 to 70% by mass in the oil-in-water emulsion composition containing glittering powder. As a result of earnest research, it was found that the following emulsified composition is stable. That is, the present invention is as follows.
（１） １）光輝性粉体３０〜７０質量％と、２）油剤とを含有することを特徴とする水中油乳化組成物。
（２） 光輝性粉体が、二酸化チタン被覆マイカ及び／又は二酸化チタン被覆鱗片状ガラス末から選択される１種乃至は２種以上であることを特徴とする、（１）に記載の水中油乳化組成物。
（３） 油剤が、シリコーン油を含有することを特徴とする、（１）又は（２）に記載の水中油乳化組成物。
（４） 油剤中のシリコーン油の含有量が５０質量％以上であることを特徴とする、（１）〜（３）何れか１項に記載の水中油乳化組成物。
（５） シリコーン油が、不揮発性のシリコーン油であることを特徴とする、（１）〜（４）何れか１項に記載の水中油乳化組成物。
（６） さらに、親水性高分子を含有することを特徴とする、（１）〜（５）何れか１項に記載の水中油乳化組成物。
（７） 親水性高分子が、カルボキシビニルポリマーであることを特徴とする、（６）に記載の水中油乳化組成物。
（８） 水中油型乳化組成物が化粧料であることを特徴とする、（１）〜（７）何れか１項に記載の水中油乳化組成物。
（９） 光輝性粉体を含有した水中油型乳化組成物の製造方法であって、光輝性粉体の２〜２０質量％の油剤でコーティングした光輝性粉体を、水中油型乳化組成物に添加することを特徴とする、水中油型乳化組成物の製造方法。
（１０） 光輝性粉体の含有量が３０〜７０質量％であることを特徴とする、（９）に記載の水中油型乳化組成物の製造方法。
(1) An oil-in-water emulsion composition comprising 1) 30-70% by mass of glittering powder and 2) an oil agent.
(2) The oil-in-water according to (1), wherein the glittering powder is one or more selected from titanium dioxide-coated mica and / or titanium dioxide-coated glass flakes. Emulsified composition.
(3) The oil-in-water emulsion composition according to (1) or (2), wherein the oil agent contains silicone oil.
(4) The oil-in-water emulsion composition according to any one of (1) to (3), wherein the content of the silicone oil in the oil is 50% by mass or more.
(5) The oil-in-water emulsion composition according to any one of (1) to (4), wherein the silicone oil is a non-volatile silicone oil.
(6) The oil-in-water emulsion composition according to any one of (1) to (5), further comprising a hydrophilic polymer.
(7) The oil-in-water emulsion composition according to (6), wherein the hydrophilic polymer is a carboxyvinyl polymer.
(8) The oil-in-water emulsion composition according to any one of (1) to (7), wherein the oil-in-water emulsion composition is a cosmetic.
(9) A method for producing an oil-in-water emulsion composition containing glitter powder, wherein the glitter powder coated with an oil agent of 2 to 20% by mass of the glitter powder is converted into an oil-in-water emulsion composition. A method for producing an oil-in-water emulsion composition, which is characterized by comprising:
(10) The method for producing an oil-in-water emulsion composition according to (9), wherein the content of the glittering powder is 30 to 70% by mass.
本発明によれば、多量の光輝性粉体を含有しながら、安定性に優れた水中油型の乳化組成物が提供できる。 According to the present invention, an oil-in-water emulsified composition having excellent stability while containing a large amount of glittering powder can be provided.
１） 本発明の水中油型乳化組成物の必須構成成分である光輝性粉体
本発明の水中油型乳化組成物は、光輝性粉体を必須構成成分として含有することを特徴とする。ここで、本発明に係る光輝性粉体とは、反射光沢或いは干渉光沢の著しい偏平粉体であり、化粧料などで使用されているものであれば特段の限定なく使用できる。光輝性粉体としては、エポキシ樹脂薄片やアクリル樹脂薄片を積層し、１〜１０００μｍの大きさに細切した積層樹脂小片と、マイカやセリサイト、薄片状アルミナ、薄片状シリカ、薄片状のガラスフレークなどのアスペクト比の高い薄片状粉体の表面を二酸化チタンの厚さの異なる薄膜で被覆した粉体（パール粉体）に大別できる。本発明ではその何れもが使用可能であるが、その効果の高さからパール粉体を使用することが好ましい。例えば、パール粉体としては、エンジェルハード・コーポレーション（米）から、「フラメンコ（Flamenco；登録商標）レッド１００」、「フラメンコ（Flamenco；登録商標）ゴールド１００」、「フラメンコ（Flamenco；登録商標）グリーン１００」、「フラメンコ（Flamenco；登録商標）ブルー１００」、「クロイゾネ（CLOISONNE；登録商標）ゴールデン ブロンズ」、「ジェムトーン（登録商標）タン オパール」、「フラメンコ（Flamenco；登録商標）スパークルオレンジ３２０Ｊ」などが市販されており、メルク・ジャパン社から、「チミ・スーパーシーンＭＰ１００１」、「チミ・スーパーシルクＭＰ１００５」ＭＰ１００５、「ティミロン（登録商標）スターラストレＭＰ１１５」ＭＰ１１５、「ティミロン（登録商標）ダイアモンドクラスターＭＰ１４９」、「コロロナ（登録商標）ブライトゴールド」、「コロロナ（登録商標）ブロンズファイン」などが市販されており、さらに板状アルミナ系の光輝性粉体としてはメルク・ジャパン社から、「シローナ（Xirona；登録商標）シルバー」が市販されており、またガラスフレーク系の光輝性粉体としては、日本光研（株）より、「プロミネンス（PROMINENCE；登録商標）ＳＦ」、エンジェルハード・コーポレーション（米）から「リフレクスピンポインツオブパール（商標）」などが市販されており、日本板硝子（株）より「メタシャイン（登録商標）ＭＣ１０８０ＲＹＳ１」などが市販されており、これらのものを購入して使用することができ、好ましい。積層樹脂小片としては、ダイヤ工業（株）の「ＤＣグリッター」シリーズ、「ダイヤホログラム」シリーズ、角八魚鱗箔（株）の「オーロラフレーク」シリーズ、エンゲルハード・コーポレーションの「Ｉグリッター」シリーズ等が例示できる。本発明の水中油型乳化組成物に於いては、かかる光輝性粉体は唯一種を含有することも出来るし、二種以上を組み合わせて含有させることも出来る。これらのパール粉体は、その表面をハイドロキシメチルポリシロキサン焼き付け処理、ジメチルポリシロキサン焼き付け処理、シリル化処理、金属セッケン被覆処理、アシルグルタミン酸の金属塩被覆処理、レシチン被覆処理などの表面処理を行った後に用いても良い。本発明の水中油型乳化組成物に於いて、かかる光輝性粉体の好ましい含有量は、総量で水中油型乳化組成物全量に対して、３０〜７０質量％であり、好ましくは３５〜６５質量％であり、更に好ましくは４０〜６０質量％である。これは少なすぎると、光輝性粉体によるパール効果が損なわれる場合があり、多すぎると本願発明の効果が損なわれる場合があるからである。
1) Bright powder which is an essential constituent of the oil-in-water emulsion composition of the present invention The oil-in-water emulsion composition of the present invention is characterized by containing a bright powder as an essential component. Here, the glittering powder according to the present invention is a flat powder with remarkably reflected gloss or interference gloss, and any powder used in cosmetics can be used without any particular limitation. As the glittering powder, epoxy resin flakes and acrylic resin flakes are laminated and laminated resin pieces cut into a size of 1-1000 μm, mica, sericite, flaky alumina, flaky silica, flaky glass The surface of flaky powder having a high aspect ratio such as flakes can be roughly classified into powder (pearl powder) coated with thin films having different thicknesses of titanium dioxide. Any of them can be used in the present invention, but pearl powder is preferably used because of its high effect. For example, as pearl powders, “Flamenco (registered trademark) Red 100”, “Flamenco (registered trademark) Gold 100”, “Flamenco (registered trademark) Green” are available from Angel Hard Corporation (US). "100", "Flamenco (registered trademark) Blue 100", "CLOISONNE (registered trademark) Golden Bronze", "Gemtone (registered trademark) Tan Opal", "Flamenco (registered trademark) Sparkle Orange 320J" Etc. are commercially available from Merck Japan, such as “Chimi Superscene MP1001”, “Chimi Supersilk MP1005” MP1005, “Timilon (registered trademark) Starlast Tre MP115” MP115, and “Timilon (registered trademark) Diamond”. cluster "P149", "Cororona (registered trademark) Bright Gold", "Cororona (registered trademark) Bronze Fine", etc. are commercially available. Further, as a plate-like alumina-based glittering powder, Merck Japan Co., Ltd. Xirona (registered trademark) "Silver" is commercially available, and glass flake-based glittering powders from Nippon Koken Co., Ltd., "PROMINENCE (registered trademark) SF", Angel Hard Corporation (US) ) "Reflex Spin Points of Pearl (trademark)" is commercially available, and "Metashine (registered trademark) MC1080RYS1" is commercially available from Nippon Sheet Glass Co., Ltd. Can be preferred. The laminated resin pieces include the “DC glitter” series, “Diamond Hologram” series from Dia Kogyo Co., “Aurora Flakes” series from Kadoha Fish Scale Co., Ltd., and the “I Glitter” series from Engelhard Corporation. It can be illustrated. In the oil-in-water emulsified composition of the present invention, such glittering powder can contain only a single species or a combination of two or more species. These pearl powders were subjected to surface treatment such as hydroxymethylpolysiloxane baking treatment, dimethylpolysiloxane baking treatment, silylation treatment, metal soap coating treatment, acylglutamic acid metal salt coating treatment, and lecithin coating treatment. It may be used later. In the oil-in-water emulsion composition of the present invention, the preferred content of the glittering powder is 30 to 70% by mass, preferably 35 to 65%, based on the total amount of the oil-in-water emulsion composition. It is mass%, More preferably, it is 40-60 mass%. This is because if the amount is too small, the pearl effect by the glittering powder may be impaired, and if the amount is too large, the effect of the present invention may be impaired.
２）本発明の必須構成成分である油剤
本発明の水中油型乳化組成物は、光輝性粉体に加えて、油剤を必須構成成分として含有することを特徴としている。本発明に係る油剤は、光輝性粉体を予めコーティングしておくためにも用いられるし、光輝性粉体を添加するための水中油型乳化組成物を予め作製しておくのにも用いられる。光輝性粉体を予めコーティングしておくための油剤と予め水中油型乳化組成物を作製しておくための油剤の種類や組成は、特に限定されないが、油剤組成中に、シリコーン油を５０質量％以上含有していることが好ましい。また、光輝性粉体を予めコーティングしておくための油剤と予め水中油型乳化組成物を作製しておくための油剤の種類や組成は、光輝性粉体を含有した乳化組成物中の油剤の組成としてシリコーン油を５０質量％以上含有していれば構わないが、光輝性粉体をコーティングする油剤として、シリコーン油を５０質量％以上含有することが好ましい。このような組成の油剤を用いることにより、本発明の優れた効果が発揮できる。このようなシリコーン油としては、実質的に揮発性を有しないジメチルポリシロキサン、メチルフェニルポリシロキサン、部分架橋型ジメチルポリシロキサンなどが例示できる。ジメチルポリシロキサン、メチルフェニルポリシロキサンとしては、信越化学工業株式会社より、「シリコーンＫＦ９６Ａ−５ｃｓ」、「シリコーンＫＦ９６Ａ−１００ｃｓ」、「シリコーンＫＦ９６Ａ−１０００ｃｓ」などが市販されており、さらに高重合度のシリコーン油として「シリコーンＫＦ９６Ｈ−１０万ｃｓ」、「シリコーンＫＦ９６Ｈ―１００万ｃｓ」、「シリコーンＫＦ−９０２８」などが市販されているので、これらを購入して使用することができ好ましい。部分架橋型ジメチルポリシロキサンとしては、信越化学工業株式会社の「シリコーンＫＳＧ−１５」、「シリコーンＫＳＧ−１６」などが挙げられる。しかしながらシリコーン油として、低重合度シリコーンや環状シリコーンなどの揮発性のシリコーンのみを用いるのは、皮膚に塗布した後に蒸散してしまい、光輝性粉体の付着性が低下するので好ましくない。但し、高重合度シリコーンや部分架橋型のシリコーンに関しては、低重合度シリコーンや環状シリコーンなどの揮発性の高いシリコーン油が溶剤として用いられている場合があり、これらに関しては、溶剤（揮発性シリコーン）が揮発しても、基質としての高重合度シリコーンや部分架橋型のシリコーンが本願発明の効果を発揮するので、このような高重合度シリコーンや部分架橋型シリコーンも本願発明に係る油剤として好ましい。
2) Oil which is an essential constituent of the present invention The oil-in-water emulsion composition of the present invention is characterized by containing an oil as an essential constituent in addition to the glittering powder. The oil agent according to the present invention is used for pre-coating the glitter powder, and is also used for preparing an oil-in-water emulsion composition for adding the glitter powder. . The type and composition of the oil agent for pre-coating the glitter powder and the oil agent for preparing the oil-in-water emulsion composition in advance are not particularly limited, but 50 mass of silicone oil is included in the oil agent composition. % Or more is preferable. The kind and composition of the oil agent for pre-coating the glitter powder and the oil agent for preparing the oil-in-water emulsion composition in advance are the oil agent in the emulsion composition containing the glitter powder. As long as the composition contains 50 mass% or more of silicone oil, it is preferable to contain 50 mass% or more of silicone oil as an oil agent for coating the glittering powder. By using the oil agent having such a composition, the excellent effect of the present invention can be exhibited. Examples of such silicone oils include dimethylpolysiloxane, methylphenylpolysiloxane, and partially crosslinked dimethylpolysiloxane that have substantially no volatility. As dimethylpolysiloxane and methylphenylpolysiloxane, “silicone KF96A-5cs”, “silicone KF96A-100cs”, “silicone KF96A-1000cs”, etc. are commercially available from Shin-Etsu Chemical Co., Ltd. As silicone oils, “silicone KF96H-100,000 cs”, “silicone KF96H-1 million cs”, “silicone KF-9028”, and the like are commercially available, and these are preferable because they can be purchased and used. Examples of the partially crosslinked dimethylpolysiloxane include “silicone KSG-15” and “silicone KSG-16” manufactured by Shin-Etsu Chemical Co., Ltd. However, it is not preferable to use only volatile silicones such as low-polymerization silicones and cyclic silicones as silicone oils, since they will evaporate after being applied to the skin and the adhesion of the glittering powder will be reduced. However, for high-polymerization silicones and partially cross-linked silicones, highly volatile silicone oils such as low-polymerization silicones and cyclic silicones may be used as solvents. ) Is volatilized, high-polymerization silicone or partially-crosslinked silicone as a substrate exerts the effects of the present invention. Therefore, such highly-polymerized silicone and partially-crosslinked silicone are also preferable as the oil according to the present invention. .
４）本発明の水中油型乳化組成物及びその製造方法
本発明の水中油型乳化組成物は、光輝性粉体を３０〜７０質量％含有していながら、安定な水中油型乳化組成物を与えるものであり、さらに、３０〜７０質量％という多量の光輝性粉体を含有しても光輝性粉体の皮膚への付着性が優れているという特徴を有している。本発明の水中油型乳化組成物は、予め光輝性粉体をその２〜２０質量％の油剤でコーティングしておくことが好ましく、５〜１５質量％の油剤でコーティングしておくことがより好ましい。これより少ないと油剤によるコーティングの効果が得られにくく、さらに光輝性粉体の肌への密着性も低下するし、多すぎると光輝性粉体の輝きが低下する場合があるからである。本発明の水中油型乳化組成物は、油剤でコーティングされた光輝性粉体を、別途調整した水中油型乳化組成物に添加することによって得られる。このようにして得られた光輝性粉体を含有する水中油型乳化組成物は、乳化粒子が安定であり、多量の光輝性粉体を水中油型乳化組成物に安定に含有することが可能となる。
4) Oil-in-water emulsion composition of the present invention and method for producing the same The oil-in-water emulsion composition of the present invention comprises a stable oil-in-water emulsion composition containing 30 to 70% by mass of glittering powder. Furthermore, even when a large amount of glittering powder of 30 to 70% by mass is contained, the glittering powder has a feature that the adhesion to the skin is excellent. In the oil-in-water emulsion composition of the present invention, it is preferable that the glittering powder is previously coated with 2 to 20% by mass of the oil agent, more preferably 5 to 15% by mass of the oil agent. . If the amount is less than this, it is difficult to obtain the effect of coating with the oil agent, and further, the adhesion of the glitter powder to the skin is lowered, and if too much, the brightness of the glitter powder may be lowered. The oil-in-water emulsion composition of the present invention can be obtained by adding a glittering powder coated with an oil to a separately prepared oil-in-water emulsion composition. The oil-in-water emulsion composition containing the glittering powder thus obtained has stable emulsion particles, and a large amount of glittering powder can be stably contained in the oil-in-water emulsion composition. It becomes.
本発明に係る光輝性粉体は、予めシリコーン油を５０質量％以上含有する油剤によってコーティング処理をした光輝性粉体を用いることが好ましいが、このような油剤によるコーティング処理は、光輝性粉体と油剤を予め混合することによって行われる。このようなコーティング処理は、光輝性粉体が油剤によって均一にコーティングされれば、その方法は限定されない。例えば、光輝性粉体と油剤をヘンシェルミキサーに入れ、混合することによっても得られる。 The glitter powder according to the present invention is preferably a glitter powder that has been previously coated with an oil containing 50% by mass or more of silicone oil. And an oil agent are mixed in advance. The coating process is not limited as long as the glittering powder is uniformly coated with the oil agent. For example, it can also be obtained by mixing glitter powder and oil into a Henschel mixer.
本発明の水中油型乳化組成物は、さらに親水性の高分子化合物を含有することが好ましい。このような親水性高分子化合物は、乳化物を安定化する効果と共に、多量の光輝性粉体を水中油型乳化物中に安定に留まられておくのに効果的である。このような高分子としては、グアガム、クインスシード、カラギーナン、キサンタンガム、カードラン、メチルセルロース、ヒドロキシエチルセルロース、カルボキシメチルセルロース、メチルヒドロキシプロピルセルロース、ヒアルロン酸、コンドロイチン硫酸、寒天、カルボキシビニルポリマー、アルキル変性されていてもよりカルボキシビニルポリマーなどが例示できる。これらの中では、アルキル変性されていてもよいカルボキシビニルポリマーが好ましく挙げられる。このようなカルボキシビニルポリマー類としては、日本サーファクタント工業株式会社から市販され、炭素数１０〜３０のアルキル基でアルキル変性されている「ペムレン（ＰＥＭＵＲＥＮ；登録商標）ＴＲ−１」、「ペムレン（ＰＥＭＵＲＥＮ；登録商標）ＴＲ−２」、ＢＦグッドリッチ社（米）から市販されている「カーボポール（ＣＡＲＢＯＰＯＬ；登録商標）１３８２」などがあり、アルキル変性されていないカルボキシビニルポリマーとしては、ＢＦグッドリッチ社（米）から市販されている「カーボポール（ＣＡＲＢＯＰＯＬ；登録商標）Ｕｌｔｒｅｚ１０」、「カーボポール（ＣＡＲＢＯＰＯＬ；登録商標）９４０」などがある。このような親水性高分子は、唯一種を用いても、二種以上を組み合わせて用いても構わない。本発明の水中油型乳化組成物は、このような親水性高分子を、０．０５〜１質量％含有することが好ましく、０．０８〜０．５質量％含有することがより好ましい。これより少ないと乳化系が不安定化するし、これより多いと系の粘度が高くなりすぎて、塗布性が悪くなり、パール光沢感が不十分となるからである。 The oil-in-water emulsion composition of the present invention preferably further contains a hydrophilic polymer compound. Such a hydrophilic polymer compound is effective in stabilizing a large amount of the emulsion and keeping a large amount of the glittering powder stably in the oil-in-water emulsion. Such polymers include guar gum, quince seed, carrageenan, xanthan gum, curdlan, methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, methylhydroxypropylcellulose, hyaluronic acid, chondroitin sulfate, agar, carboxyvinyl polymer, alkyl modified. Further, carboxyvinyl polymer and the like can be exemplified. In these, the carboxy vinyl polymer which may be alkyl-modified is mentioned preferably. Such carboxyvinyl polymers are commercially available from Nippon Surfactant Kogyo Co., Ltd., and are “PEMUREN (registered trademark) TR-1” or “PEMUREN” modified with an alkyl group having 10 to 30 carbon atoms. Registered trademark) TR-2 "," Carbopol (registered trademark) 1382 "commercially available from BF Goodrich (USA), and the carboxyvinyl polymer not modified with alkyl includes BF Goodrich. There are “Carbopol (registered trademark) Ultrez 10”, “Carbopol (registered trademark) 940”, and the like which are commercially available from the company (USA). Such hydrophilic polymers may be used alone or in combination of two or more. The oil-in-water emulsion composition of the present invention preferably contains 0.05 to 1% by mass of such a hydrophilic polymer, and more preferably 0.08 to 0.5% by mass. If it is less than this, the emulsification system becomes unstable, and if it is more than this, the viscosity of the system becomes too high, the coating property is deteriorated, and the pearly luster is insufficient.
本発明に係る水中油型乳化組成物は、光輝性粉体を多量に含有していることから、化粧料に適用するのが好ましく、特にメークアップ化粧料に適用することが好ましい。メークアップ化粧料であれば格段の限定は受けないが、光輝性粉体を多量に含有することによる著しいパール感が得られるという演出効果を有効に活かせる化粧料であることが好ましい。このような光輝性粉体を多量に含有するメークアップ化粧料として好ましいものとしては、アイカラー、マスカラ、チークカラーなどのポイントメーク用の化粧料が例示でき、アイカラーに適用するのが特に好ましい。これは、アイカラーが目元を対象とするメークアップ化粧料であり、光輝性粉体の華やかさで演出するのに最も効果的なものであるからである。 Since the oil-in-water emulsion composition according to the present invention contains a large amount of glittering powder, it is preferably applied to cosmetics, and particularly preferably applied to makeup cosmetics. Although it is not particularly limited as long as it is a makeup cosmetic, it is preferably a cosmetic that can effectively make use of the rendering effect that a remarkable pearly feeling is obtained by containing a large amount of glittering powder. Examples of preferable makeup cosmetics containing a large amount of such glittering powder include point makeup cosmetics such as eye color, mascara, and cheek color, and it is particularly preferable to apply to eye color. . This is because the eye color is a makeup cosmetic for the eyes and is the most effective for producing with the gorgeousness of the glittering powder.
本発明の水中油型乳化組成物は、本発明の効果を妨げない範囲で、上記必須構成成分に加えて、通常化粧料などで使用される成分を含有することができる。この様な任意成分としては、例えば、マカデミアナッツ油、アボガド油、トウモロコシ油、オリーブ油、ナタネ油、ゴマ油、ヒマシ油、サフラワー油、綿実油、ホホバ油、ヤシ油、パーム油、液状ラノリン、硬化ヤシ油、硬化油、モクロウ、硬化ヒマシ油、キャンデリラロウ、カルナウバロウ、イボタロウ、ラノリン、還元ラノリン、硬質ラノリン、ホホバロウ等のオイル、ワックス類、流動パラフィン、スクワラン、プリスタン、オゾケライト、パラフィン、セレシン、ワセリン、マイクロクリスタリンワックス等の炭化水素類、オレイン酸、イソステアリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、ウンデシレン酸等の高級脂肪酸類、セチルアルコール、ステアリルアルコール、イソステアリルアルコール、ベヘニルアルコール、オクチルドデカノール、ミリスチルアルコール、セトステアリルアルコール等の高級アルコール等、イソオクタン酸セチル、ミリスチン酸イソプロピル、イソステアリン酸ヘキシルデシル、アジピン酸ジイソプロピル、セバチン酸ジ−２−エチルヘキシル、乳酸セチル、リンゴ酸ジイソステアリル、ジ−２−エチルヘキサン酸エチレングリコール、ジカプリン酸ネオペンチルグリコール、ジ−２−ヘプチルウンデカン酸グリセリン、トリ−２−エチルヘキサン酸グリセリン、トリ−２−エチルヘキサン酸トリメチロールプロパン、トリイソステアリン酸トリメチロールプロパン、テトラ−２−エチルヘキサン酸ペンタンエリトリット等の合成エステル油類、ジフェニルポリシロキサン等の鎖状ポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサンシロキサン等の環状ポリシロキサン、アミノ変性ポリシロキサン、ポリエーテル変性ポリシロキサン、アルキル変性ポリシロキサン、フッ素変性ポリシロキサン等の変性ポリシロキサン等のシリコーン油等の油剤類、脂肪酸セッケン（ラウリン酸ナトリウム、パルミチン酸ナトリウム等）、ラウリル硫酸カリウム、アルキル硫酸トリエタノールアミンエーテル等のアニオン界面活性剤類、塩化ステアリルトリメチルアンモニウム、塩化ベンザルコニウム、ラウリルアミンオキサイド等のカチオン界面活性剤類、イミダゾリン系両性界面活性剤（２−ココイル−２−イミダゾリニウムヒドロキサイド−１−カルボキシエチロキシ２ナトリウム塩等）、ベタイン系界面活性剤（アルキルベタイン、アミドベタイン、スルホベタイン等）、アシルメチルタウリン等の両性界面活性剤類、ソルビタン脂肪酸エステル類（ソルビタンモノステアレート、セスキオレイン酸ソルビタン等）、グリセリン脂肪酸類（モノステアリン酸グリセリン等）、プロピレングリコール脂肪酸エステル類（モノステアリン酸プロピレングリコール等）、硬化ヒマシ油誘導体、グリセリンアルキルエーテル、ＰＯＥソルビタン脂肪酸エステル類（ＰＯＥソルビタンモノオレエート、モノステアリン酸ポリオキシエチレンソルビタン等）、ＰＯＥソルビット脂肪酸エステル類（ＰＯＥ−ソルビットモノラウレート等）、ＰＯＥグリセリン脂肪酸エステル類（ＰＯＥ−グリセリンモノイソステアレート等）、ＰＯＥ脂肪酸エステル類（ポリエチレングリコールモノオレート、ＰＯＥジステアレート等）、ＰＯＥアルキルエーテル類（ＰＯＥ２−オクチルドデシルエーテル等）、ＰＯＥアルキルフェニルエーテル類（ＰＯＥノニルフェニルエーテル等）、プルロニック型類、ＰＯＥ・ＰＯＰアルキルエーテル類（ＰＯＥ・ＰＯＰ２−デシルテトラデシルエーテル等）、テトロニック類、ＰＯＥヒマシ油・硬化ヒマシ油誘導体（ＰＯＥヒマシ油、ＰＯＥ硬化ヒマシ油等）、ショ糖脂肪酸エステル、アルキルグルコシド等の非イオン界面活性剤類、ポリエチレングリコール、グリセリン、１，３−ブチレングリコール、エリスリトール、ソルビトール、キシリトール、マルチトール、プロピレングリコール、ジプロピレングリコール、ジグリセリン、イソプレングリコール、１，２−ペンタンジオール、２，４−ヘキシレングリコール、１，２−ヘキサンジオール、１，２−オクタンジオール等の多価アルコール類、ピロリドンカルボン酸ナトリウム、乳酸、乳酸ナトリウム等の保湿成分類、ガラクタン、アラビアガム、ペクチン、マンナン、デンプン、コンドロイチン硫酸、デルマタン硫酸、グリコーゲン、ヘパラン硫酸、トラガントガム、ケラタン硫酸、コンドロイチン、ムコイチン硫酸、ヒドロキシエチルグアガム、カルボキシメチルグアガム、デキストラン、ケラト硫酸，ローカストビーンガム，サクシノグルカン，カロニン酸，キチン，キトサン、カルボキシメチルキチン、ポリビニルアルコール、ポリビニルピロリドン、ポリエチレングリコール、ベントナイト等の増粘剤、表面を処理されていても良い、マイカ、タルク、カオリン、合成雲母、炭酸カルシウム、炭酸マグネシウム、無水ケイ酸（シリカ）、酸化アルミニウム、硫酸バリウム等の粉体類、表面を処理されていても良い、ベンガラ、黄酸化鉄、黒酸化鉄、酸化コバルト、群青、紺青、酸化チタン、酸化亜鉛の無機顔料類、レーキ化されていても良い赤色２０２号、赤色２２８号、赤色２２６号、黄色４号、青色４０４号、黄色５号、赤色５０５号、赤色２３０号、赤色２２３号、橙色２０１号、赤色２１３号、黄色２０４号、黄色２０３号、青色１号、緑色２０１号、紫色２０１号、赤色２０４号等の有機色素類、ポリエチレン末、ポリメタクリル酸メチル、ナイロン粉末、オルガノポリシロキサンエラストマー等の有機粉体類、パラアミノ安息香酸系紫外線吸収剤、アントラニル酸系紫外線吸収剤、サリチル酸系紫外線吸収剤、桂皮酸系紫外線吸収剤、ベンゾフェノン系紫外線吸収剤、糖系紫外線吸収剤、２−（２’−ヒドロキシ−５’−ｔ−オクチルフェニル)ベンゾトリアゾール、４−メトキシ−４’−ｔ−ブチルジベンゾイルメタン等の紫外線吸収剤類、エタノール、イソプロパノール等の低級アルコール類、ビタミンＡ又はその誘導体、ビタミンＢ６塩酸塩，ビタミンＢ６トリパルミテート，ビタミンＢ６ジオクタノエート，ビタミンＢ２又はその誘導体，ビタミンＢ１２，ビタミンＢ１５又はその誘導体等のビタミンＢ類、α−トコフェロール，β−トコフェロール，γ−トコフェロール，ビタミンＥアセテート等のビタミンＥ類、ビタミンＤ類、ビタミンＨ、パントテン酸、パンテチン、ピロロキノリンキノン等のビタミン類などが好ましく例示できる。 The oil-in-water emulsion composition of the present invention can contain components that are usually used in cosmetics and the like, in addition to the above essential components, within a range that does not interfere with the effects of the present invention. Such optional ingredients include, for example, macadamia nut oil, avocado oil, corn oil, olive oil, rapeseed oil, sesame oil, castor oil, safflower oil, cottonseed oil, jojoba oil, coconut oil, palm oil, liquid lanolin, hydrogenated coconut oil Oils such as hardened oil, mole, castor oil, candelilla wax, carnauba wax, ibotarou, lanolin, reduced lanolin, hard lanolin, jojoba wax, waxes, liquid paraffin, squalane, pristane, ozokerite, paraffin, ceresin, petrolatum, micro Hydrocarbons such as crystallin wax, higher fatty acids such as oleic acid, isostearic acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, undecylenic acid, cetyl alcohol, stearyl alcohol, isostearyl alcohol Higher alcohols such as behenyl alcohol, octyldodecanol, myristyl alcohol, cetostearyl alcohol, cetyl isooctanoate, isopropyl myristate, hexyldecyl isostearate, diisopropyl adipate, di-2-ethylhexyl sebacate, cetyl lactate, diacid malate Isostearyl, ethylene glycol di-2-ethylhexanoate, neopentyl glycol dicaprate, glycerin di-2-heptylundecanoate, glycerin tri-2-ethylhexanoate, tri-2-ethylhexanoate trimethylolpropane, triisostearin Synthetic ester oils such as trimethylol propane acid and pentane erythritol tetra-2-ethylhexanoate, chain polysiloxanes such as diphenyl polysiloxane, oct Silicone oils such as cyclic polysiloxanes such as methylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexanesiloxane, amino-modified polysiloxanes, polyether-modified polysiloxanes, alkyl-modified polysiloxanes, modified polysiloxanes such as fluorine-modified polysiloxanes Oil agents such as fatty acid soap (sodium laurate, sodium palmitate, etc.), anionic surfactants such as potassium lauryl sulfate, alkylethanol triethanolamine ether, stearyltrimethylammonium chloride, benzalkonium chloride, laurylamine oxide, etc. Cationic surfactants, imidazoline amphoteric surfactants (2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt Etc.), betaine surfactants (alkyl betaines, amide betaines, sulfobetaines, etc.), amphoteric surfactants such as acylmethyltaurine, sorbitan fatty acid esters (sorbitan monostearate, sorbitan sesquioleate, etc.), glycerin fatty acids (Glyceryl monostearate, etc.), propylene glycol fatty acid esters (propylene glycol monostearate, etc.), hardened castor oil derivatives, glycerin alkyl ethers, POE sorbitan fatty acid esters (POE sorbitan monooleate, polyoxyethylene monostearate) Sorbitan, etc.), POE sorbite fatty acid esters (POE-sorbite monolaurate, etc.), POE glycerin fatty acid esters (POE-glycerol monoisostearate, etc.), POE fat Acid esters (polyethylene glycol monooleate, POE distearate, etc.), POE alkyl ethers (POE2-octyldodecyl ether, etc.), POE alkyl phenyl ethers (POE nonylphenyl ether, etc.), Pluronic types, POE / POP alkyl ethers (POE / POP2-decyltetradecyl ether, etc.), Tetronics, POE castor oil / hardened castor oil derivatives (POE castor oil, POE hardened castor oil, etc.), nonionic surfactants such as sucrose fatty acid ester, alkyl glucoside Polyethylene glycol, glycerin, 1,3-butylene glycol, erythritol, sorbitol, xylitol, maltitol, propylene glycol, dipropylene glycol, diglycerin, isoprene Moisturizing composition of polyalcohols such as coal, 1,2-pentanediol, 2,4-hexylene glycol, 1,2-hexanediol, 1,2-octanediol, sodium pyrrolidonecarboxylate, lactic acid, sodium lactate Classification, galactan, gum arabic, pectin, mannan, starch, chondroitin sulfate, dermatan sulfate, glycogen, heparan sulfate, tragacanth gum, keratan sulfate, chondroitin, mucoitin sulfate, hydroxyethyl guar gum, carboxymethyl guar gum, dextran, kerato sulfate, locust bean gum , Succinoglucan, caronic acid, chitin, chitosan, carboxymethyl chitin, polyvinyl alcohol, polyvinyl pyrrolidone, polyethylene glycol, bentonite and other thickeners, surface treated Mica, talc, kaolin, synthetic mica, calcium carbonate, magnesium carbonate, silicic anhydride (silica), aluminum oxide, barium sulfate, etc., surface may be treated, bengara, yellow oxidation Iron, black iron oxide, cobalt oxide, ultramarine, bitumen, titanium oxide, zinc oxide inorganic pigments, red 202, red 228, red 226, yellow 4, blue 404, which may be raked, Organics such as yellow 5, red 505, red 230, red 223, orange 201, red 213, yellow 204, yellow 203, blue 1, green 201, purple 201, red 204 Pigments, polyethylene powder, polymethyl methacrylate, nylon powder, organic powders such as organopolysiloxane elastomer, paraaminobenzoic acid UV absorbers, Ntranyl acid UV absorber, salicylic acid UV absorber, cinnamic acid UV absorber, benzophenone UV absorber, sugar UV absorber, 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole UV absorbers such as 4-methoxy-4′-t-butyldibenzoylmethane, lower alcohols such as ethanol and isopropanol, vitamin A or derivatives thereof, vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B6 dioctanoate , Vitamin B2 or derivatives thereof, vitamin B such as vitamin B12, vitamin B15 or derivatives thereof, vitamin E such as α-tocopherol, β-tocopherol, γ-tocopherol, vitamin E acetate, vitamin D, vitamin H, pantothene Acid, panthetin, pyrrolol Including vitamins such as Rinkinon can be preferably exemplified.
本発明の水中油型乳化組成物は、必須構成成分と上記の任意成分とを用いることによって得ることが出来る。かくして得られた本発明に係る水中油型乳化組成物は、多量の光輝性粉体を安定に保持し、多量の光輝性粉体を含有しながら光輝性粉体の皮膚への付着性が優れているという特性を有する。 The oil-in-water emulsion composition of the present invention can be obtained by using essential constituents and the above optional components. The oil-in-water emulsion composition according to the present invention thus obtained stably retains a large amount of glitter powder and has excellent adhesion to the skin of the glitter powder while containing a large amount of glitter powder. It has the characteristic of being.
以下に、実施例を示し、本発明を詳しく説明するが、本発明が係る実施例に限定を受けないことは言うまでもない。 Hereinafter, the present invention will be described in detail with reference to examples, but it goes without saying that the present invention is not limited to the examples.
以下に示す処方に従い、（Ａ）を７５℃で加熱溶解し、撹拌下、これに（Ｂ）を添加して乳化し、３０℃まで冷却した後、さらに（Ｃ）を加えて撹拌し、基本の乳化物を得、最後に（Ｄ）を添加撹拌し、本発明の乳化化粧料１を製造した（基本乳化物は、（Ａ）、（Ｂ）、（Ｃ）からなる）。乳化化粧料１の処方において、予めシリコーン油（「ジメチルポリシロキサンＫＦ９６Ａ−１０ｃｓ」（信越化学工業株式会社製））でコーティングした光輝性粉体を、コーティング無しの光輝性粉体に変え、コーティング用のシリコーン油を、基本の乳化物の油相に組み入れて、最後にコーティング無しの光輝性粉体を添加して製造したものを比較例１として、光輝性粉体コーティング用のシリコーン油を部分架橋型シリコーン（シリコーンＫＳＧ−１５；信越化学工業株式会社製）に置換したものを化粧料２として、光輝性粉体コーティング用のシリコーン油を高重合度メチルポリシロキサン（「シリコーンＫＦ９０２８」；信越化学工業株式会社製）に置換したものを化粧料３として、光輝性粉体コーティング用のシリコーン油を２−エチルヘキサン酸トリグリセライドに置換したものを化粧料４として製造した。 According to the formulation shown below, (A) is heated and dissolved at 75 ° C., and under stirring, (B) is added and emulsified, cooled to 30 ° C., and then (C) is added and stirred. Finally, (D) was added and stirred to produce the emulsified cosmetic 1 of the present invention (the basic emulsion comprises (A), (B), and (C)). In the formulation of the emulsified cosmetic 1, the glitter powder previously coated with silicone oil ("dimethylpolysiloxane KF96A-10cs" (manufactured by Shin-Etsu Chemical Co., Ltd.)) is changed to a glitter powder with no coating. As a comparative example 1, a silicone oil for coating a glittering powder was partially crosslinked by incorporating the silicone oil of No.1 into the oil phase of the basic emulsion and finally adding a glittering powder without coating. Type silicone (silicone KSG-15; manufactured by Shin-Etsu Chemical Co., Ltd.) was used as cosmetic 2, and silicone oil for glittering powder coating was treated with high-polymerization methylpolysiloxane (“silicone KF9028”; Shin-Etsu Chemical) Co., Ltd.) is used as cosmetic 3 and silicone oil for glittering powder coating is 2- Those substituted with Chiruhekisan acid triglyceride was prepared as a cosmetic 4.
（Ａ）
２−エチルヘキサン酸トリグリセライド ３．０ 質量％
「ジメチルポリシロキサンＫＦ９６Ａ−１０ｃｓ」 ３．０ 質量％
ＰＯＥ（２０）ベヘニルエーテル ０．５ 質量％
モノステアリン酸ソルビタン ０．５ 質量％
（Ｂ）
１，３−ブタンジオール ３．０ 質量％
カルボキシビニルポリマー ０．２ 質量％
メチルパラベン ０．３ 質量％
精製水 ３８．５ 質量％
（Ｃ）
１０％水酸化カリウム水溶液 １．０ 質量％
（Ｄ）
油剤コーティング光輝性粉体（＊１） ５０．０ 質量％
(A)
2-Ethylhexanoic acid triglyceride 3.0% by mass
“Dimethylpolysiloxane KF96A-10cs” 3.0 mass%
POE (20) behenyl ether 0.5% by mass
Sorbitan monostearate 0.5% by mass
(B)
1,3-butanediol 3.0% by mass
Carboxyvinyl polymer 0.2% by mass
Methylparaben 0.3 mass%
Purified water 38.5% by mass
(C)
10% aqueous potassium hydroxide solution 1.0% by mass
(D)
Oil coating glitter powder (* 1) 50.0% by mass
油剤コーティング光輝性粉体（＊１）の製造
以下に示す粉体を均一に混合後、油剤を添加した後、さらに均一に混合して、油剤をコーティングした粉体を得た。
（チタンマイカ）
「フラメンコレッド１００」 １０ 重量部
「ジェムトーン タン オパール」 １０ 重量部
「チミ・スターラストレＭＰ１１５」 １０ 重量部
「コロロナブライトゴールド」 ２０ 重量部
「フラメンコスパークルオレンジ３２０Ｊ」 ２０ 重量部
（ガラスフレーク）
「プロミネンスＳＦ」 ２０ 重量部
（油剤）
「ジメチルポリシロキサンＫＦ９６Ａ−１０ｃｓ」 １０ 重量部
Production of Oil Agent-Coated Glittering Powder (* 1) After the powders shown below were uniformly mixed, the oil agent was added and further uniformly mixed to obtain a powder coated with the oil agent.
(Titanium mica)
“Flamenco Red 100” 10 parts by weight “Gemtone Tan Opal” 10 parts by weight “Chimi Starlast Tre MP115” 10 parts by weight “Colorona Bright Gold” 20 parts by weight “Flamen Cospacle Orange 320J” 20 parts by weight (glass flakes)
"Prominence SF" 20 parts by weight (oil)
"Dimethylpolysiloxane KF96A-10cs" 10 parts by weight
＜試験例１＞
各サンプルを、ガラス製のサンプル容器に充填、密栓をし、２０℃、４０℃の高温恒湿室で５例づつ保存し、それぞれ１日後の状態、及び４０℃で３ヶ月後の状態を観察した。上部への油相の分離状態を以下の評点で判定し、評点を平均した。結果を表１に示す。
変化無し ：３
容器を傾けると僅かな油相が確認できる ：２
そのままで、僅かな油相が確認できる ：１
そのままで、明確な油相が確認できる ：０
<Test Example 1>
Each sample is filled into a glass sample container, sealed, and stored in high temperature and humidity chambers at 20 ° C and 40 ° C for 5 cases, and the state after 1 day and the state after 3 months at 40 ° C are observed. did. The separation state of the oil phase to the upper part was judged by the following scores, and the scores were averaged. The results are shown in Table 1.
No change: 3
Slight oil phase can be confirmed by tilting the container: 2
As it is, a slight oil phase can be confirmed: 1
As it is, a clear oil phase can be confirmed: 0
＜試験例２＞
専門パネラー５名によって、製造直後の各サンプルに関して、各サンプルを肌上に延ばした時の光輝性粉体の肌への付着性・パール効果について評価した。結果を表１に示す。
非常に着きがよく、パール効果が高い ：３
やや着きがよい、パール効果が適度 ：２
やや着きが悪い、パール効果がやや低下 ：１
着きが悪く、パール効果が低下 ：０
<Test Example 2>
Five specialist panelists evaluated the adhesion of the glittering powder to the skin and the pearl effect when each sample was spread on the skin for each sample immediately after production. The results are shown in Table 1.
Very good wearing and high pearl effect: 3
Slightly good wearing, moderate pearl effect: 2
Slightly unsatisfactory, slightly reduced pearl effect: 1
Poor wear, pearl effect decreases: 0
表１の結果より、本発明に係る化粧料１は、十分な乳化粒子の安定性を有しており、さらに、肌への光輝性粉体の付着性にも優れていた。これに対して、比較例１では、乳化粒子が破壊されて、油相が直ぐに分離してしまい、製造直後における光輝性粉体の肌への付着性も十分でないことがわかった。光輝性粉体をコーティングする油相を部分架橋型シリコーンや高重合度シリコーンに置換した化粧料２、化粧料３は、化粧料１と同様に、安定な乳化組成物であった。光輝性粉体をコーティングする油相を２−エチルヘキサン酸トリグリセライドに置換した化粧料４は、比較例安定な乳化物を与えたが、安定性、肌への付着性共に化粧料１には若干及ばなかった。 From the results shown in Table 1, the cosmetic 1 according to the present invention has sufficient stability of the emulsified particles, and also has excellent adhesion of the glitter powder to the skin. On the other hand, in Comparative Example 1, it was found that the emulsified particles were broken and the oil phase was immediately separated, and the adhesion of the glitter powder to the skin immediately after production was not sufficient. Cosmetics 2 and 3 in which the oil phase for coating the glittering powder was replaced with partially cross-linked silicone or high-polymerization silicone were stable emulsion compositions like cosmetic 1. The cosmetic 4 in which the oil phase for coating the glittering powder was replaced with 2-ethylhexanoic acid triglyceride gave a stable emulsion in the comparative example. However, the cosmetic 1 has some stability and adhesion to the skin. It did not reach.
表２に示す処方（各組成は、質量％）に従い、実施例１の化粧料１と同様に処理して、本発明の化粧料５〜７、比較例２〜３を製造した。各サンプルに関して、実施例１に記載の試験例１〜試験例２と同様の試験を行った。結果を表２に合わせて示す。 According to the formulation shown in Table 2 (each composition is% by mass), the cosmetics 5 to 7 and Comparative Examples 2 to 3 of the present invention were produced in the same manner as the cosmetic 1 of Example 1. For each sample, a test similar to Test Example 1 and Test Example 2 described in Example 1 was performed. The results are shown in Table 2.
表２の結果より、本発明に係る化粧料５〜７は、十分な乳化粒子の安定性を有しており、さらに、肌への光輝性粉体の付着性にも優れていた。これに対して、油剤コーティング光輝性粉体の含有量の少ない比較例２では、乳化粒子の不安定化は認められなかったが、肌への付着性やパール感が化粧料５〜７に若干及ばず、油剤コーティング光輝性粉体の含有量の多い比較例３では、乳化粒子の安定化効果が、十分ではなかった。 From the results shown in Table 2, the cosmetics 5 to 7 according to the present invention have sufficient stability of the emulsified particles, and also have excellent adhesion of the glitter powder to the skin. On the other hand, in Comparative Example 2 in which the content of the oil agent-coated glittering powder was small, destabilization of the emulsified particles was not observed. Therefore, in Comparative Example 3 in which the content of the oil agent-coated glittering powder was large, the stabilizing effect of the emulsified particles was not sufficient.
以下に示す処方に従い、実施例１の化粧料１と同様に処理して、本発明の乳化化粧料８〜１２を製造した。なお、用いた油剤コーティング光輝性粉体の組成及び製造した乳化組成物の評価結果は、表３に合わせて示した。 According to the prescription shown below, it processed like the cosmetics 1 of Example 1, and manufactured the emulsified cosmetics 8-12 of this invention. The composition of the oil agent-coated glittering powder used and the evaluation results of the produced emulsified composition are shown together in Table 3.
（Ａ）
２−エチルヘキサン酸トリグリセライド ３．０ 質量％
「ジメチルポリシロキサンＫＦ９６Ａ−１０ｃｓ」 ３．０ 質量％
ＰＯＥ（２０）ベヘニルエーテル ０．５ 質量％
モノステアリン酸ソルビタン ０．５ 質量％
（Ｂ）
１，３−ブタンジオール ３．０ 質量％
カルボキシビニルポリマー ０．２ 質量％
メチルパラベン ０．３ 質量％
精製水 ３８．５ 質量％
（Ｃ）
１０％水酸化カリウム水溶液 １．０ 質量％
（Ｄ）
油剤コーティング光輝性粉体（＊２） ５０．０ 重量％
(A)
2-Ethylhexanoic acid triglyceride 3.0% by mass
“Dimethylpolysiloxane KF96A-10cs” 3.0 mass%
POE (20) behenyl ether 0.5% by mass
Sorbitan monostearate 0.5% by mass
(B)
1,3-butanediol 3.0% by mass
Carboxyvinyl polymer 0.2% by mass
Methylparaben 0.3 mass%
Purified water 38.5% by mass
(C)
10% aqueous potassium hydroxide solution 1.0% by mass
(D)
Oil coating glitter powder (* 2) 50.0 wt%
油剤コーティング光輝性粉体（＊２）の製造
以下に示す粉体を均一に混合したものＸ質量％に、油剤（ジメチルポリシロキサンＫＦ９６Ａ−１０ｃｓ；信越化学工業株式会社製）をＹ質量％添加した後、さらにヘンシェルミキサーにて均一に混合して、油剤コーティング光輝性粉体を得た（＊２）。
Production of oil-coated glittering powder (* 2) Y mass% of oil (dimethylpolysiloxane KF96A-10cs; manufactured by Shin-Etsu Chemical Co., Ltd.) was added to X mass% obtained by uniformly mixing the powders shown below. Thereafter, the mixture was further uniformly mixed with a Henschel mixer to obtain an oil-coated glittering powder (* 2).
＜光輝性粉体の仕込み量＞
（チタンマイカ）
「フラメンコレッド１００」 １０ 重量部
「ジェムトン タン オパール」 １０ 重量部
「チミ・スターラストレＭＰ１１５」 １０ 重量部
「コロロナブライトゴールド」 ２０ 重量部
「フラメンコスパークルオレンジ３２０Ｊ」 ２０ 重量部
（ガラスフレーク）
「プロミネンスＳＦ」 ２０ 重量部
<Amount of glitter powder>
(Titanium mica)
"Flamenco Red 100" 10 parts by weight
"Gemton Tan Opal" 10 parts by weight
"Chimi Starlastre MP115" 10 parts by weight
"Colorona Bright Gold" 20 parts by weight
"Flamen Cospark Orange 320J" 20 parts by weight (glass flakes)
"Prominence SF" 20 parts by weight
本願発明の化粧料は、光輝性粉体を予めコーティングする油剤の比率が２〜２０質量％の範囲内で、安定であり、肌への付着性やパール感に優れていることがわかった。さらに、５〜１５質量％の範囲内で、より安定性や肌への付着性に優れていることがわかった。 The cosmetic of the present invention was found to be stable and excellent in adhesion to the skin and pearly feeling when the ratio of the oil agent pre-coated with the glittering powder was in the range of 2 to 20% by mass. Furthermore, it turned out that it is more excellent in stability and the adhesiveness to skin within the range of 5-15 mass%.
本発明により、光輝性粉体を安定に多量に含有した水中油乳化組成物を提供できる。 According to the present invention, it is possible to provide an oil-in-water emulsion composition that stably contains a large amount of glittering powder.
Claims (10)
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| JP2021091677A (en) * | 2019-12-06 | 2021-06-17 | シャネル パフュームズ ビューテ | Cosmetic composition with metallic effect |
| JP7712756B2 (en) | 2019-12-06 | 2025-07-24 | シャネル パフュームズ ビューテ | Cosmetic composition with metallic effect |
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| JP2021091677A (en) * | 2019-12-06 | 2021-06-17 | シャネル パフュームズ ビューテ | Cosmetic composition with metallic effect |
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