JP2009149830A - Pyrolysis direct oil drainer - Google Patents
Pyrolysis direct oil drainer Download PDFInfo
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- JP2009149830A JP2009149830A JP2007341903A JP2007341903A JP2009149830A JP 2009149830 A JP2009149830 A JP 2009149830A JP 2007341903 A JP2007341903 A JP 2007341903A JP 2007341903 A JP2007341903 A JP 2007341903A JP 2009149830 A JP2009149830 A JP 2009149830A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
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- Mixers Of The Rotary Stirring Type (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
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Abstract
【課題】廃プラスチック及び廃ゴムを分解させて低分子化させた分解油を気化させず、直接分解槽より排出して取り出した液体が常温まで温度を低下させても固形化しない採油方法を提供する。
【解決手段】分解槽内に収容した中空の撹拌軸4に穿孔させて分解槽低位部に設けた軸受5に滑合させ、軸受5に貫通穴を設けることで中空撹拌軸4から軸受5まで分解槽と槽外を連通させることにより、分解された油は穿孔より中空軸4に入って撹拌軸内で加熱されながら軸受5より排出される。
【選択図】図2[PROBLEMS] To provide an oil collection method that does not vaporize cracked oil obtained by decomposing waste plastics and waste rubber, and does not solidify even if the liquid discharged directly from the cracking tank drops to room temperature. To do.
SOLUTION: A hollow agitation shaft 4 accommodated in a decomposition tank is perforated and slides on a bearing 5 provided in a lower part of the decomposition tank, and a through hole is provided in the bearing 5 so that the hollow agitation shaft 4 to the bearing 5 are provided. By making the decomposition tank communicate with the outside of the tank, the decomposed oil enters the hollow shaft 4 through the perforations and is discharged from the bearing 5 while being heated in the stirring shaft.
[Selection] Figure 2
Description
本発明は高分子で作られた廃プラスチックの熱分解において、より低分子化して気化するまでには至らない程度に分解した分解油を液体のまま直接分解槽より抜き取る方法に関する。 The present invention relates to a method for directly removing from a cracking tank, as a liquid, cracked oil that has been decomposed to a level that does not lead to vaporization due to lower molecular weight in the thermal decomposition of waste plastic made of a polymer.
年間760万トンに及ぶプラスチック製品が製造され又廃棄されていく今日、この廃プラスチックの活用は完全とは言えず、多くが焼却や埋立等で処分されている。
これら廃プラスチックよりプラスチック油を取り出すに当たっては熱分解がなされている。Today, 7.6 million tons of plastic products are manufactured and discarded every year, and the use of waste plastic is not complete, and many are disposed of by incineration or landfill.
In removing plastic oil from these waste plastics, thermal decomposition is performed.
廃プラスチックを加熱炉または加熱槽に収容して外部よりバーナー等によって加熱させるのが主な方法で、一部収容させた炉中に加熱ガスを挿入させたりしている文献も見掛ける。
多くの文献はスクリューフィーダーで原料を槽内に供給し、外部加熱で槽を加熱させて分解・気化させた油蒸気をコンデンサーで冷却させることで液化させるタイプが主流である。The main method is to store the waste plastic in a heating furnace or a heating tank and heat it from the outside with a burner or the like, and there are also documents in which heated gas is inserted into a partially stored furnace.
In many literatures, the mainstream is a type in which raw material is supplied into a tank by a screw feeder, and the oil vapor decomposed and vaporized by heating the tank by external heating is liquefied by cooling with a condenser.
熱分解により結合分子の手が切れてゆく過程で、気化し蒸発する前に分解槽内の分解油の抽出を図りたいが、取り出した廃プラスチック油が未分解もしくは分解が不充分であると、徐々に熱交換が進む取出し容器の周囲より油温の低下に伴って固化が進む。 In the process of breaking the binding molecules by thermal decomposition, we want to extract the cracked oil in the cracking tank before vaporizing and evaporating, but if the waste plastic oil taken out is undegraded or insufficiently decomposed, Solidification proceeds as the oil temperature decreases from around the take-out container where heat exchange gradually proceeds.
過剰分解をさせず触媒を用いず分解時に分解油を抜き出すには、プラスチックを分解させる過程で更に加熱し、未分解油との混合を防ぎながら分別引抜きをさせる必要がある。
解決しようとする問題点は廃プラスチック熱分解途上において、分解槽低位部や加熱温度が伝熱により奪われる部分では凝固を起こし、また油蒸気化させて凝縮させた低分子油にすれば凝固はしないが、気化させずに低温加熱によって熱分解した廃プラスチック油を分解槽より抜き出すことは可能か。 The problem to be solved is that during the process of thermal decomposition of waste plastic, solidification occurs in the lower part of the decomposition tank and the part where the heating temperature is deprived by heat transfer. However, is it possible to extract waste plastic oil pyrolyzed by low-temperature heating without vaporizing it from the decomposition tank?
本発明は分解機槽内の撹拌軸を中空とし、中空軸の一部の位置に多孔の穿孔を設けて分解油を中空軸に浸入させる。
中空軸は分解したプラスチック油に浸漬状態で回転させると、分解した油や分解途上の油が中空軸に入って行き、軸の周囲の分解油の伝熱によって更に分解途上の油を分解させ、分解槽低位部の軸受に設けた貫通口より抜き出す。In the present invention, the stirring shaft in the cracker tank is made hollow, and a perforated hole is provided at a part of the hollow shaft so that cracked oil enters the hollow shaft.
When the hollow shaft is rotated while immersed in the decomposed plastic oil, the decomposed oil and the oil under decomposition enter the hollow shaft, and the oil under decomposition is further decomposed by the heat transfer of the decomposed oil around the shaft, Pull out from the through hole provided in the bearing in the lower part of the decomposition tank.
本発明は廃プラスチックの熱分解において、より低分子に分解・気化させたものをコンデンサーによって冷却・液化させた分解油を作らず、固形プラスチックをある程度熱分解させた状態で直接引き抜く。引き抜かれた分解油は常温まで冷却させても凝固しない。 In the present invention, in the thermal decomposition of waste plastics, the solid plastic is directly drawn out in a state where it is thermally decomposed to some extent, without producing a cracked oil that has been decomposed and vaporized to a lower molecule and cooled and liquefied by a condenser. The extracted cracked oil does not solidify even when cooled to room temperature.
分解槽を縦型または斜め置きさせて内部に中空撹拌軸を設け、中空軸の外周に多数分解油が浸入する穴を設けて分解槽低位部にて軸を支える軸受に滑合させ、撹拌軸の中空孔と軸受に設けた貫通穴を連通させる。 The cracking tank is placed vertically or obliquely to provide a hollow stirring shaft inside, and a hole into which a large number of cracked oil enters is provided on the outer periphery of the hollow shaft, and slides into a bearing that supports the shaft at the lower part of the cracking tank. The through hole provided in the bearing is communicated with the hollow hole.
本発明の廃プラスチック分解油化装置の実施形態を図1により説明する。この装置においての熱分解は無酸素状態である。その機構は特願2007−284363に記載されている。 An embodiment of the waste plastic cracking and oiling apparatus of the present invention will be described with reference to FIG. Thermal decomposition in this apparatus is in an oxygen-free state. The mechanism is described in Japanese Patent Application No. 2007-284363.
原料廃プラスチックは1.原料投入口より2.分解槽に供給されて槽内部に収容され、9.高周波電磁誘導加熱により分解温度に保持された10.溶解油中に、4.中空撹拌軸に付帯する羽根によって浸漬される。
溶解油面は分解槽の原料投入開口部よりも上位に位置させ、原料が投入後そのまま溶解油面上に浮遊することを防止する。Raw material waste plastic is 1. From the
The dissolved oil surface is positioned higher than the raw material charging opening of the cracking tank to prevent the raw material from floating on the dissolved oil surface as it is after being charged.
油中に押し込まれた廃プラスチックは溶融して溶解油に同化し、ゆっくり掻き混ぜられながら分解槽内を動く。分解機を構成する前記の槽は傾斜を持って置かれているため傾きの上流側には空間があり、この空間において熱分解によってより低分子化した廃プラスチック油が油面より油蒸気となって蒸散する。 The waste plastic pushed into the oil is melted and assimilated into dissolved oil, and moves in the decomposition tank while being slowly stirred. Since the tank constituting the cracker is placed with an inclination, there is a space on the upstream side of the inclination, and in this space, waste plastic oil whose molecular weight has been reduced by thermal decomposition becomes oil vapor from the oil surface. Evaporate.
蒸散する油蒸気をエジェクターポンプで吸引させて3.排気口より排出し、凝縮器で液体化させて廃プラスチック分解油を採油するが、分解機の原料投入直下は分解不充分な工程で完全に低分子化が行われていない。
原料投入直下の分解槽低位部で溶融した廃プラスチックはさらに熱分解を起こし、熱分解の進行と伴に比重が小さくなるため、撹拌されているなかで比較的分解の進行した分解油が徐々に溶解油中を斜め置き分解槽の上位に移動し、溶解油の上澄み液14.のようになる。さらに上澄みの分解油を溶解油面より上位部の中空撹拌軸に設けた12.小径孔より抜き出す。2. Evaporate oil vapor with an ejector pump. Although it is discharged from the exhaust port and liquefied by a condenser to collect waste plastic cracked oil, the molecular weight is not completely reduced by a process that is insufficiently decomposed immediately under the raw material input of the cracker.
The waste plastic melted in the lower part of the cracking tank just below the raw material is further thermally decomposed, and the specific gravity decreases with the progress of thermal decomposition. 15. Displace the oil in the dissolved oil and move it to the upper part of the decomposition tank. become that way. Furthermore, the supernatant cracked oil was provided on the hollow stirring shaft above the dissolved oil surface. Pull out from small hole.
溶解油は比重の大きいものが望まれるが、廃プラスチックの分解油とほぼ同等のものでも溶解油も分解油も一括で上記のような作用により比重の小さい比較的低分子の分解油が得られる。 Dissolved oil with high specific gravity is desired, but even if it is almost equivalent to the waste plastic cracked oil, both dissolved oil and cracked oil can produce a relatively low molecular weight cracked oil with a small specific gravity by the above action. .
本発明においての分解機の操作は連続的なバッチ式であり、前記小径孔は最初の投入量によって上昇する溶解油面よりも上位に位置させ、更に連続的に投入し分解させることによって、気化するまでには至ってない分解の進行した分解油の油面が小径孔の位置に到達して流れ出す。 The operation of the cracker in the present invention is a continuous batch type, and the small-diameter hole is positioned higher than the dissolved oil surface rising by the initial input amount, and further vaporized by continuously charging and decomposing. The oil level of the cracked oil that has not been reached reaches the position of the small-diameter hole and flows out.
小径孔より中空撹拌軸内に侵入した分解油または分解途上の油は、加熱された溶解油に包まれた軸が更に加熱されることによって、中空軸内の油も加熱される作用で低分子化が図られる。 Decomposed oil that has penetrated into the hollow stirring shaft from the small-diameter hole or is in the process of decomposing has a low molecular weight due to the action of heating the oil enclosed in the heated dissolved oil and heating the oil in the hollow shaft. Is achieved.
前記小径孔より浸入した分解油より油蒸気が発生して中空撹拌軸の空間に溜まるのを防止するため、中空撹拌軸の更に上位部に13.通気孔を設けて油蒸気を中空撹拌軸より排出させる。 In order to prevent generation of oil vapor from the cracked oil that has entered through the small-diameter holes and accumulation in the space of the hollow stirring shaft, 13. Ventilation holes are provided to discharge oil vapor from the hollow stirring shaft.
撹拌軸の低位部位置での軸受は、溶解油中で11.低摩耗性の軸受材で滑合させると溶解油が潤滑油の役割を果たし、潤滑油の中で軸が回転しているため摩耗が少なくなる。 The bearing at the lower position of the stirring shaft is 11. When sliding with a low-abrasion bearing material, the dissolved oil plays the role of lubricating oil, and wear is reduced because the shaft rotates in the lubricating oil.
熱分解槽の低位部に設けた前記軸受に槽外に貫通する貫通口を設け、中空撹拌軸内で低分子化させた廃プラスチック油を抜き出す。抜き出し量の制御は6.バルブまたはタイマーにて行う。 The bearing provided in the lower part of the pyrolysis tank is provided with a through-hole penetrating to the outside of the tank, and the waste plastic oil reduced in molecular weight in the hollow stirring shaft is extracted. The control of the extraction amount is 6. Use a valve or timer.
1 原料投入口
2 分解槽
3 排気口
4 中空撹拌軸
5 槽低位部軸受
6 分解油排出バルブ
7 グランドボックス
8 ギヤードモートル
9 高周波電磁誘導加熱コイル
10 溶解油
11 低摩耗性軸受材
12 分解油浸入小径孔
13 軸通気孔
14 上澄み分解油DESCRIPTION OF SYMBOLS 1
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102703106A (en) * | 2012-06-25 | 2012-10-03 | 徐效奇 | Instant cracking reaction device adopting high-frequency heating and converting oil into membrane |
CN106310997A (en) * | 2015-06-17 | 2017-01-11 | 兴化市田缘基质肥料有限公司 | Matrix mixer |
CN111117675A (en) * | 2020-01-07 | 2020-05-08 | 山东理工大学 | A segmented spiral stirring biomass pyrolysis liquefaction system |
CN111151185A (en) * | 2020-01-21 | 2020-05-15 | 西北化工研究院有限公司 | Lubricating oil blending device and method |
-
2007
- 2007-12-20 JP JP2007341903A patent/JP2009149830A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102703106A (en) * | 2012-06-25 | 2012-10-03 | 徐效奇 | Instant cracking reaction device adopting high-frequency heating and converting oil into membrane |
CN106310997A (en) * | 2015-06-17 | 2017-01-11 | 兴化市田缘基质肥料有限公司 | Matrix mixer |
CN111117675A (en) * | 2020-01-07 | 2020-05-08 | 山东理工大学 | A segmented spiral stirring biomass pyrolysis liquefaction system |
CN111117675B (en) * | 2020-01-07 | 2021-03-19 | 山东理工大学 | A segmented spiral stirring biomass pyrolysis liquefaction system |
CN111151185A (en) * | 2020-01-21 | 2020-05-15 | 西北化工研究院有限公司 | Lubricating oil blending device and method |
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