JP2009073787A - Hair cosmetic - Google Patents
Hair cosmetic Download PDFInfo
- Publication number
- JP2009073787A JP2009073787A JP2007245797A JP2007245797A JP2009073787A JP 2009073787 A JP2009073787 A JP 2009073787A JP 2007245797 A JP2007245797 A JP 2007245797A JP 2007245797 A JP2007245797 A JP 2007245797A JP 2009073787 A JP2009073787 A JP 2009073787A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- ether
- hair cosmetic
- lumps
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 32
- -1 alkyl ether sulfate ester salt Chemical class 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000001346 alkyl aryl ethers Chemical class 0.000 claims abstract description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 37
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 claims description 14
- 239000003676 hair preparation Substances 0.000 claims description 9
- 239000000839 emulsion Substances 0.000 claims description 8
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims description 7
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 6
- JYKSTGLAIMQDRA-UHFFFAOYSA-N tetraglycerol Chemical compound OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO JYKSTGLAIMQDRA-UHFFFAOYSA-N 0.000 claims description 4
- 229960000878 docusate sodium Drugs 0.000 claims description 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims description 2
- WOKDXPHSIQRTJF-UHFFFAOYSA-N 3-[3-[3-[3-[3-[3-[3-[3-[3-(2,3-dihydroxypropoxy)-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]propane-1,2-diol Chemical compound OCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)CO WOKDXPHSIQRTJF-UHFFFAOYSA-N 0.000 claims 1
- 239000003945 anionic surfactant Substances 0.000 abstract description 20
- 239000003093 cationic surfactant Substances 0.000 abstract description 18
- 239000002244 precipitate Substances 0.000 abstract description 7
- 238000002360 preparation method Methods 0.000 abstract description 7
- 150000003839 salts Chemical class 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract 1
- 229920000223 polyglycerol Polymers 0.000 abstract 1
- 238000011156 evaluation Methods 0.000 description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 19
- 235000019441 ethanol Nutrition 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- 125000000217 alkyl group Chemical group 0.000 description 12
- 238000009472 formulation Methods 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000004945 emulsification Methods 0.000 description 7
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 239000001993 wax Substances 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 6
- 239000000499 gel Substances 0.000 description 6
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- CDOUZKKFHVEKRI-UHFFFAOYSA-N 3-bromo-n-[(prop-2-enoylamino)methyl]propanamide Chemical compound BrCCC(=O)NCNC(=O)C=C CDOUZKKFHVEKRI-UHFFFAOYSA-N 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 5
- 229940043348 myristyl alcohol Drugs 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 239000008213 purified water Substances 0.000 description 5
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 description 4
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 4
- LTSWUFKUZPPYEG-UHFFFAOYSA-N 1-decoxydecane Chemical compound CCCCCCCCCCOCCCCCCCCCC LTSWUFKUZPPYEG-UHFFFAOYSA-N 0.000 description 4
- HANWHVWXFQSQGJ-UHFFFAOYSA-N 1-tetradecoxytetradecane Chemical compound CCCCCCCCCCCCCCOCCCCCCCCCCCCCC HANWHVWXFQSQGJ-UHFFFAOYSA-N 0.000 description 4
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 4
- 229960005323 phenoxyethanol Drugs 0.000 description 4
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 3
- 229940031723 1,2-octanediol Drugs 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 229960000541 cetyl alcohol Drugs 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 3
- 229940057995 liquid paraffin Drugs 0.000 description 3
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 3
- 229940055577 oleyl alcohol Drugs 0.000 description 3
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 229940012831 stearyl alcohol Drugs 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 2
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000019635 sulfation Effects 0.000 description 2
- 238000005670 sulfation reaction Methods 0.000 description 2
- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 2
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
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- 239000004166 Lanolin Substances 0.000 description 1
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- 229920002125 Sokalan® Polymers 0.000 description 1
- DRRMRHKHTQRWMB-UHFFFAOYSA-N [3-(2-ethylhexanoyloxy)-2,2-bis(2-ethylhexanoyloxymethyl)propyl] 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(COC(=O)C(CC)CCCC)(COC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DRRMRHKHTQRWMB-UHFFFAOYSA-N 0.000 description 1
- YFCGDEUVHLPRCZ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-dimethyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C YFCGDEUVHLPRCZ-UHFFFAOYSA-N 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、毛髪化粧料に関する。 The present invention relates to a hair cosmetic.
毛髪化粧料において、陰イオン性界面活性剤は、毛髪に水分を浸透させ、潤いを付与する。また、陽イオン性界面活性剤は、毛髪に滑らかさ、柔らかさ等を付与し、手触り感や櫛通りを良好とする。 In hair cosmetics, an anionic surfactant permeates moisture into hair and imparts moisture. In addition, the cationic surfactant imparts smoothness and softness to the hair and improves the feeling of touch and combing.
しかし、陰イオン性界面活性剤と陽イオン性界面活性剤を併用して乳化させると、組成物中でコンプレックスを形成し、ダマや塊が生じて、均一に乳化することができず、乳化安定性に劣るといった問題がある。加えて、ざらつき等が生じるため、使用感に劣るといった問題もある。したがって、陰イオン性界面活性剤と陽イオン性界面活性剤を併用した乳化物の製剤化は、乳化安定性および使用感の観点から非常に困難であった。 However, when an anionic surfactant and a cationic surfactant are used together and emulsified, a complex is formed in the composition, resulting in lumps and lumps, which cannot be uniformly emulsified, and the emulsion is stable. There is a problem of inferiority. In addition, since roughness or the like occurs, there is a problem that the feeling of use is inferior. Therefore, it has been very difficult to formulate an emulsion using an anionic surfactant and a cationic surfactant in combination from the viewpoint of emulsion stability and feeling of use.
これまで、製剤の安定性を付与する試みとして、特定の陰イオン性界面活性剤、特定の水溶性高分子、非イオン性界面活性剤、シリコーン化合物およびカチオン界面活性剤を含有する毛髪洗浄剤組成物（例えば、特許文献１を参照）、特定のアニオン界面活性剤、特定のカチオン界面活性剤、特定のアルコールおよび特定の共重合体を含有する毛髪洗浄剤組成物（例えば、特許文献２を参照）等が提案されている。 Up to now, as an attempt to impart stability of the preparation, a hair cleansing composition containing a specific anionic surfactant, a specific water-soluble polymer, a nonionic surfactant, a silicone compound and a cationic surfactant Product (for example, see Patent Document 1), a specific anionic surfactant, a specific cationic surfactant, a specific alcohol, and a specific copolymer and a hair cleanser composition (for example, see Patent Document 2) ) Etc. have been proposed.
しかしながら、これらの試みによって、製剤の安定性は付与することはできるものの、特定の水溶性高分子や特定のアルコール等、他成分への依存が大きく、使用感に劣るといった問題や、使用が制限されるといった問題がある。 However, these trials can provide stability to the formulation, but are highly dependent on other components such as specific water-soluble polymers and specific alcohols, resulting in poor use feeling and limited use. There is a problem of being.
一方、陰イオン性界面活性剤と陽イオン性界面活性剤を併用して透明な化粧料とする場合も上述の如く、沈殿物やダマが発生して白濁してしまい、透明にならないといった問題がある。また、例え、透明とすることができたとしても、経時的に透明性を持続することが困難であった。 On the other hand, as described above, when an anionic surfactant and a cationic surfactant are used in combination to form a transparent cosmetic, there is a problem that precipitates and lumps are generated and become cloudy and not transparent. is there. Moreover, even if it can be made transparent, it has been difficult to maintain transparency over time.
これまで、透明な化粧料において、陰イオン性界面活性剤と陽イオン性界面活性剤を併用する試みがなされている。例えば、モノアルキル型第４級アンモニウム型カチオン界面活性剤と、カルボン酸塩型アニオン界面活性剤と、特定のアルコール類とを含有する透明性ヘアーリンス組成物（例えば、特許文献３を参照）、陽イオン性界面活性剤と、高度にアルコキシル化された陰イオン性界面活性剤を含有する透明なヘアコンディショニング組成物（例えば、特許文献４を参照）等が提案されている。 Until now, attempts have been made to use an anionic surfactant and a cationic surfactant in combination in transparent cosmetics. For example, a transparent hair rinse composition containing a monoalkyl type quaternary ammonium type cationic surfactant, a carboxylate type anionic surfactant, and specific alcohols (see, for example, Patent Document 3), A transparent hair conditioning composition containing a cationic surfactant and a highly alkoxylated anionic surfactant (see, for example, Patent Document 4) has been proposed.
しかしながら、これらの試みによって、一時的に組成物中でコンプレックスの形成を抑制することはできるものの、経時的に沈殿物やダマが生じて製剤の安定性に劣るといった問題や、透明性の持続に劣るといった問題がある。
本発明の課題は、陰イオン性界面活性剤と陽イオン性界面活性剤のコンプレックスによるダマや塊の発生を抑制し、均一に乳化することができ、優れた乳化安定性および使用感を有するとともに、毛髪に優れた滑らかさと水々しい潤いを付与することができる毛髪化粧料を提供することである。 An object of the present invention is to suppress the occurrence of lumps and lumps due to a complex of an anionic surfactant and a cationic surfactant, and to uniformly emulsify, and has excellent emulsification stability and feeling of use. An object of the present invention is to provide a hair cosmetic that can impart excellent smoothness and moisture to hair.
また、本発明の課題は、陰イオン性界面活性剤と陽イオン性界面活性剤のコンプレックスによる沈殿物やダマによる白濁を抑制し、透明性を持続することができ、毛髪に優れた滑らかさと水々しい潤いを付与することができる毛髪化粧料を提供することである。 In addition, the problem of the present invention is that it is possible to suppress sedimentation due to a complex of an anionic surfactant and a cationic surfactant and white turbidity due to lumps, and to maintain transparency. It is providing the hair cosmetics which can give various moisture.
即ち、本発明は、（Ａ）ジアルキルスルホコハク酸塩および／またはアルキルエーテル硫酸エステル塩、（Ｂ）モノアルキル型第４級アンモニウム塩、（Ｃ）ポリグリセリンモノアルキルエーテル、ならびに（Ｄ）水を含有してなる毛髪化粧料に関する。 That is, the present invention contains (A) dialkylsulfosuccinate and / or alkyl ether sulfate ester salt, (B) monoalkyl type quaternary ammonium salt, (C) polyglycerin monoalkyl ether, and (D) water. The present invention relates to a hair cosmetic composition.
本発明の毛髪化粧料を乳化物とした場合、陰イオン性界面活性剤と陽イオン性界面活性剤のコンプレックスによるダマや塊の発生を抑制し、均一に乳化することができ、優れた乳化安定性および使用感を有するという効果を奏するとともに、毛髪に優れた滑らかさと水々しい潤いを付与するという効果を奏する。 When the hair cosmetic composition of the present invention is used as an emulsion, it is possible to suppress the occurrence of lumps and lumps due to a complex of an anionic surfactant and a cationic surfactant, and to uniformly emulsify, thereby providing excellent emulsification stability. In addition to the effect of having a feeling of use and a feeling of use, the effect of imparting excellent smoothness and watery moisture to the hair is exhibited.
また、本発明の毛髪化粧料を透明な化粧料とした場合、陰イオン性界面活性剤と陽イオン性界面活性剤のコンプレックスによる沈殿物やダマによる白濁を抑制し、優れた透明性を持続するという効果を奏するとともに、毛髪に優れた滑らかさと水々しい潤いを付与するという効果を奏する。 In addition, when the hair cosmetic composition of the present invention is a transparent cosmetic composition, it suppresses white turbidity caused by precipitates and lumps due to a complex of an anionic surfactant and a cationic surfactant, and maintains excellent transparency. And the effect of imparting excellent smoothness and moisture to the hair.
本発明の毛髪化粧料に用いられる（Ａ）成分のジアルキルスルホコハク酸塩は、炭素数６〜２２の直鎖または分岐鎖のアルコールと、無水マレイン酸とを反応させてジエステルとした後に、硫酸化することにより得られる陰イオン性界面活性剤である。用いられるアルコールとしては、例えば、ヘキサノール、オクタノール、デカノール、ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、オレイルアルコール、２−エチルヘキサノール、２−メチルドデカノール等を例示することができる。また、ジアルキルスルホコハク酸塩の塩としては、ナトリウム、カリウム等のアルカリ金属；モノエタノールアミン、ジエタノールアミン、トリエタノールアミン等の低級アルカノールアミン；アンモニア等を例示することができ、なかでも、ナトリウム塩を用いることが好ましい。 The dialkylsulfosuccinate of component (A) used in the hair cosmetic composition of the present invention is obtained by reacting a linear or branched alcohol having 6 to 22 carbon atoms with maleic anhydride to form a diester, followed by sulfation. It is an anionic surfactant obtained by doing. Examples of the alcohol used include hexanol, octanol, decanol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, 2-ethylhexanol, 2-methyldodecanol and the like. Examples of the salt of dialkylsulfosuccinate include alkali metals such as sodium and potassium; lower alkanolamines such as monoethanolamine, diethanolamine and triethanolamine; ammonia and the like. Among them, sodium salts are used. It is preferable.
ジアルキルスルホコハク酸塩の具体例としては、例えば、スルホコハク酸ジヘキシルナトリウム、スルホコハク酸ジオクチルナトリウム、スルホコハク酸ジラウリルナトリウム等を例示することができる。 Specific examples of the dialkylsulfosuccinate include dihexyl sodium sulfosuccinate, dioctyl sodium sulfosuccinate, dilauryl sodium sulfosuccinate and the like.
また、アルキルエーテル硫酸エステル塩は、炭素数が８〜１８の直鎖または分岐鎖のアルコールに酸化エチレンを付加重合させ、硫酸化することにより得られる陰イオン性界面活性剤である。用いられるアルコールとしては、例えば、オクタノール、デカノール、ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、オレイルアルコール等を例示することができる。また、酸化エチレンの付加モル数は、特に限定されないが、１〜１０が好ましく、１〜５がより好ましい。また、硫酸エステル塩の塩としては、ナトリウム、カリウム等のアルカリ金属；モノエタノールアミン、ジエタノールアミン、トリエタノールアミン等の低級アルカノールアミン；アンモニア等を例示することができ、中でも、ナトリウム塩、トリエタノールアミン塩を用いることが好ましい。 The alkyl ether sulfate ester salt is an anionic surfactant obtained by addition polymerization of ethylene oxide to a linear or branched alcohol having 8 to 18 carbon atoms and sulfation. Examples of the alcohol used include octanol, decanol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, and the like. Moreover, although the addition mole number of ethylene oxide is not specifically limited, 1-10 are preferable and 1-5 are more preferable. Examples of the sulfate ester salt include alkali metals such as sodium and potassium; lower alkanolamines such as monoethanolamine, diethanolamine and triethanolamine; ammonia and the like. Among them, sodium salts and triethanolamine It is preferable to use a salt.
アルキルエーテル硫酸エステル塩の具体例としては、例えば、ポリオキシエチレン（１）アルキル（１１，１３，１５）エーテル硫酸ナトリウム、ポリオキシエチレン（１）アルキル（１１，１３，１５）エーテル硫酸トリエタノールアミン、ポリオキシエチレン（３）アルキル（１１〜１５）エーテル硫酸ナトリウム、ポリオキシエチレン（２）アルキル（１２，１３）エーテル硫酸ナトリウム、ポリオキシエチレン（３）アルキル（１２〜１４）エーテル硫酸ナトリウム、ポリオキシエチレン（３）アルキル（１２〜１５）エーテル硫酸ナトリウム、ポリオキシエチレン（２）ラウリルエーテル硫酸ナトリウム、ポリオキシエチレン（３）ミリスチルエーテル硫酸ナトリウム等を例示することができる。 Specific examples of the alkyl ether sulfate ester salt include, for example, polyoxyethylene (1) alkyl (11, 13, 15) ether sodium sulfate, polyoxyethylene (1) alkyl (11, 13, 15) ether triethanolamine Polyoxyethylene (3) alkyl (11-15) ether sodium sulfate, polyoxyethylene (2) alkyl (12,13) sodium ether sulfate, polyoxyethylene (3) alkyl (12-14) sodium ether sulfate, poly Examples thereof include sodium oxyethylene (3) alkyl (12 to 15) ether sulfate, polyoxyethylene (2) sodium lauryl ether sulfate, polyoxyethylene (3) sodium myristyl ether sulfate and the like.
上記（Ａ）成分は、単独で又は２種以上を適宜組合せて用いることができる。好適な（Ａ）成分としては、製剤安定性の観点から、スルホコハク酸ジオクチル塩、ポリオキシエチレンラウリルエーテル硫酸塩を用いることが好ましく、なかでも、スルホコハク酸ジオクチルナトリウム、ポリオキシエチレンラウリルエーテル硫酸ナトリウムを用いることがより好ましい。 The said (A) component can be used individually or in combination of 2 or more types as appropriate. As a suitable component (A), it is preferable to use dioctyl sulfosuccinate and polyoxyethylene lauryl ether sulfate from the viewpoint of formulation stability. Among them, dioctyl sodium sulfosuccinate and sodium polyoxyethylene lauryl ether sulfate are preferred. More preferably, it is used.
本発明の成分（Ａ）の市販品としては、例えば、「OTP-75」（スルホコハク酸ジオクチルナトリウム、日光ケミカルズ社製）、「エマール270J」（ポリオキシエチレンラウリルエーテル硫酸ナトリウム、花王社製）等が挙げられる。 As a commercial item of the component (A) of the present invention, for example, “OTP-75” (dioctyl sodium sulfosuccinate, manufactured by Nikko Chemicals), “Emar 270J” (sodium polyoxyethylene lauryl ether sulfate, manufactured by Kao), etc. Is mentioned.
本発明の（Ａ）成分の含有量は、所望の効果が充分に付与されるのであれば特に限定されないが、通常、潤いを付与する観点および製剤安定性の観点から、毛髪化粧料中に、好ましくは０．０１〜２０重量％、より好ましくは０．１〜１５重量％である。 The content of the component (A) of the present invention is not particularly limited as long as the desired effect is sufficiently imparted. Usually, from the viewpoint of imparting moisture and the stability of the preparation, in the hair cosmetic composition, Preferably it is 0.01 to 20 weight%, More preferably, it is 0.1 to 15 weight%.
本発明の毛髪化粧料に用いられる（Ｂ）成分のモノアルキル型第４級アンモニウム塩のアルキルとしては、炭素数６〜２２の直鎖または分岐鎖のアルキル基が挙げられ、具体的には、ヘキシル基、オクチル基、デシル基、ウンデシル基、ラウリル基、ミリスチル基、セチル基、ステアリル基、オレイル基、ベヘニル基等を例示することができる。 Examples of the alkyl of the monoalkyl type quaternary ammonium salt of the component (B) used in the hair cosmetic composition of the present invention include linear or branched alkyl groups having 6 to 22 carbon atoms. Specifically, Examples include hexyl, octyl, decyl, undecyl, lauryl, myristyl, cetyl, stearyl, oleyl, and behenyl groups.
（Ｂ）成分の具体例としては、例えば、塩化ラウリルトリメチルアンモニウム、臭化ラウリルトリメチルアンモニウム、塩化ミリスチルトリメチルアンモニウム、臭化ミリスチルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、臭化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、臭化ステアリルトリメチルアンモニウム、塩化ベへニルトリメチルアンモニウム、塩化アルキル（１６，１８）トリメチルアンモニウム、塩化アルキル（２０〜２２）トリメチルアンモニウム等を例示することができる。上記（Ｂ）成分は、単独で又は２種以上を適宜組合せて用いることができる。好適な（Ｂ）成分としては、製剤安定性の観点から、臭化セチルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、臭化ステアリルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウムを用いることが好ましく、なかでも、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウムを用いることがより好ましい。 Specific examples of the component (B) include, for example, lauryl trimethyl ammonium chloride, lauryl trimethyl ammonium bromide, myristyl trimethyl ammonium chloride, myristyl trimethyl ammonium bromide, cetyl trimethyl ammonium chloride, cetyl trimethyl ammonium bromide, stearyl trimethyl ammonium chloride, Examples include stearyltrimethylammonium bromide, behenyltrimethylammonium chloride, alkyl (16,18) trimethylammonium chloride, and alkyl (20-22) trimethylammonium chloride. The said (B) component can be used individually or in combination of 2 or more types as appropriate. As the preferred component (B), cetyltrimethylammonium bromide, cetyltrimethylammonium chloride, stearyltrimethylammonium bromide, and stearyltrimethylammonium chloride are preferably used from the viewpoint of formulation stability. More preferably, stearyltrimethylammonium chloride is used.
本発明の成分（Ｂ）の市販品としては、例えば、「アーカード16-29」（塩化セチルトリメチルアンモニウム、ライオンアクゾ社製）、「コータミン86W」（塩化ステアリルトリメチルアンモニウム、花王社製）等が挙げられる。 Examples of commercially available components (B) according to the present invention include “Arcade 16-29” (cetyltrimethylammonium chloride, manufactured by Lion Akzo), “Cotamine 86W” (stearyltrimethylammonium chloride, manufactured by Kao), and the like. It is done.
本発明の（Ｂ）成分の含有量は、所望の効果が充分に付与されるのであれば特に限定されないが、通常、滑らかさを付与する観点および製剤安定性の観点から、毛髪化粧料中に、好ましくは０．０１〜２０重量％、より好ましくは０．１〜１５重量％である。 The content of the component (B) of the present invention is not particularly limited as long as the desired effect is sufficiently imparted, but usually from the viewpoint of imparting smoothness and the viewpoint of formulation stability, in the hair cosmetic composition. , Preferably 0.01 to 20% by weight, more preferably 0.1 to 15% by weight.
本発明の毛髪化粧料に用いられる（Ｃ）成分のポリグリセリンモノアルキルエーテルとしては、例えば、下記一般式（１）で表されるものが挙げられる。
Ｒ−（ＯＣＨ２−ＣＨ（ＯＨ）−ＣＨ２）ｎ−ＯＨ （１）
〔式中、Ｒは炭素数８〜２２の直鎖又は分岐鎖の飽和又は不飽和のアルキル基を表し、ｎは２以上の整数を表す。〕
As polyglycerin monoalkyl ether of (C) component used for the hair cosmetics of this invention, what is represented by following General formula (1) is mentioned, for example.
R— (OCH 2 —CH (OH) —CH 2 ) n —OH (1)
[Wherein, R represents a linear or branched saturated or unsaturated alkyl group having 8 to 22 carbon atoms, and n represents an integer of 2 or more. ]
一般式（１）におけるＲのアルキル基の具体例としては、オクチル基、ノニル基、デシル基、ウンデシル基、ドデシル基、トリデシル基、テトラデシル基、ペンタデシル基、ヘキサデシル基、ヘプタデシル基、オクタデシル基、ノナデシル基、イコシル基、ヘンイコシル基、ベヘニル基、オレイル基、イソステアリル基、２−エチルヘキシル基、２−エチルヘキサデシル基等を例示することができる。中でも、炭素数８〜１４の直鎖アルキル基を用いることが好ましい。また、一般式（１）におけるｎは２以上の整数であり、好ましくは２〜２０、より好ましくは４〜１０である。 Specific examples of the alkyl group represented by R in the general formula (1) include octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl Examples thereof include a group, icosyl group, henicosyl group, behenyl group, oleyl group, isostearyl group, 2-ethylhexyl group, 2-ethylhexadecyl group and the like. Among these, it is preferable to use a linear alkyl group having 8 to 14 carbon atoms. Moreover, n in General formula (1) is an integer greater than or equal to 2, Preferably it is 2-20, More preferably, it is 4-10.
また、（Ｃ）成分の具体例としては、例えば、デカグリセリンモノオクチルエーテル、デカグリセリンモノデシルエーテル、デカグリセリンモノラウリルエーテル、デカグリセリンモノミリスチルエーテル、オクタグリセリンモノオクチルエーテル、オクタグリセリンモノデシルエーテル、オクタグリセリンモノラウリルエーテル、オクタグリセリンモノミリスチルエーテル、ヘキサグリセリンモノオクチルエーテル、ヘキサグリセリンモノデシルエーテル、ヘキサグリセリンモノラウリルエーテル、ヘキサグリセリンモノミリスチルエーテル、テトラグリセリンモノオクチルエーテル、テトラグリセリンモノデシルエーテル、テトラグリセリンモノラウリルエーテル、テトラグリセリンモノミリスチルエーテル等を例示することができる。上記（Ｃ）成分は、単独で又は２種以上を適宜組合せて用いることができる。好適な（Ｃ）成分としては、沈殿物、ダマや塊の発生を抑制し、優れた製剤安定性を付与する観点から、デカグリセリンモノラウリルエーテル、テトラグリセリンモノラウリルエーテルを用いることが好ましい。 Specific examples of the component (C) include, for example, decaglycerin monooctyl ether, decaglycerin monodecyl ether, decaglycerin monolauryl ether, decaglycerin monomyristyl ether, octaglycerin monooctyl ether, octaglycerin monodecyl ether, Octaglycerol monolauryl ether, Octaglycerol monomyristyl ether, Hexaglycerol monooctyl ether, Hexaglycerol monodecyl ether, Hexaglycerol monolauryl ether, Hexaglycerol monomyristyl ether, Tetraglycerol monooctyl ether, Tetraglycerol monodecyl ether, Tetraglycerol Examples thereof include monolauryl ether and tetraglycerin monomyristyl ether. The said (C) component can be used individually or in combination of 2 or more types as appropriate. As a suitable component (C), it is preferable to use decaglycerin monolauryl ether and tetraglycerin monolauryl ether from the viewpoint of suppressing the generation of precipitates, lumps and lumps and imparting excellent formulation stability.
本発明の成分（Ｃ）の市販品の具体例としては、サンイーサー Ｌ−４（テトラグリセリンモノラウリルエーテル：太陽化学社製）、サンイーサー Ｌ−１０（デカグリセリンモノラウリルエーテル：太陽化学社製）等を例示することができる。 As a specific example of the commercial item of the component (C) of the present invention, Sun Ether L-4 (tetraglycerin monolauryl ether: manufactured by Taiyo Kagaku Co.), Sun Ether L-10 (decaglycerin monolauryl ether: manufactured by Taiyo Chemical Co., Ltd.) ) And the like.
本発明の（Ｃ）成分の含有量は、所望の効果が充分に付与されるのであれば特に限定されないが、通常、製剤安定性の観点から、毛髪化粧料中に、好ましくは０．０１〜２０重量％、より好ましくは０．１〜１５重量％である。 Although content of (C) component of this invention will not be specifically limited if a desired effect is fully provided, Usually, from a viewpoint of formulation stability, in hair cosmetics, Preferably 0.01- 20% by weight, more preferably 0.1 to 15% by weight.
本発明の毛髪化粧料は、上記の（Ａ）〜（Ｃ）成分以外に（Ｄ）成分として水を含むものである。かかる水の種類には特に限定がなく、一般に、精製水等を用いることができる。 The hair cosmetic composition of the present invention contains water as the component (D) in addition to the components (A) to (C). The type of water is not particularly limited, and generally purified water or the like can be used.
本発明の（Ｄ）成分の含有量は、所望の効果が充分に付与されるのであれば特に限定されないが、通常、溶解性の観点から、毛髪化粧料中に、好ましくは２０〜９５重量％、より好ましくは４０〜９０重量％である。 Although content of (D) component of this invention will not be specifically limited if a desired effect is fully provided, Usually, from a viewpoint of solubility, in hair cosmetics, Preferably it is 20 to 95 weight%. More preferably, it is 40 to 90% by weight.
また、本発明の毛髪化粧料を乳化物とする場合には、油剤が用いられる。用いられる油剤としては、特に限定されないが、例えば、大豆油、オリーブ油、ヤシ油、ヒマシ油、ホホバ油、椿油、ミンク油等の油脂；カルナウバロウ、キャンデリラロウ、ミツロウ、コメヌカロウ、鯨ロウ、ラノリン等のロウ類；セレシン、パラフィン、流動パラフィン、流動イソパラフィン、マイクロクリスタリンワックス、ポリエチレン末、ポリエチレンワックス、ワセリン、スクワラン等の炭化水素油；ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、ベヘニン酸、イソステアリン酸等の高級脂肪酸；ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、オレイルアルコール、ベヘニルアルコール、セトステアリルアルコール等の高級アルコール；ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸ミリスチル、パルミチン酸セチル、ミリスチン酸オクチルドデシル、オレイン酸オクチルドデシル、イソステアリン酸イソプロピル、２−エチルヘキサン酸セチル、２−エチルヘキサン酸セトステアリル、トリ２−エチルヘキサン酸グリセリル、トリイソパルミチン酸グリセリル、テトラ２−エチルヘキサン酸ペンタエリスリトール、イソステアリン酸オクチルドデシル等の脂肪酸エステル；メチルポリシロキサン、高重合メチルポリシロキサン、メチルフェニルポリシロキサン、デカメチルテトラシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、メチルシクロポリシロキサン、アルコール変性シリコーン、アルキル変性シリコーン、アミノ変性シリコーン、エポキシ変性シリコーンなどのシリコーン類等を例示することができる。これら成分は、単独で又は２種以上を適宜組合せて用いることができる。 Moreover, when making the hair cosmetics of this invention into an emulsion, an oil agent is used. The oil used is not particularly limited, but for example, oils such as soybean oil, olive oil, coconut oil, castor oil, jojoba oil, camellia oil, mink oil; carnauba wax, candelilla wax, beeswax, rice bran wax, sperm wax, lanolin, etc. Waxes of ceresin, paraffin, liquid paraffin, liquid isoparaffin, microcrystalline wax, polyethylene powder, polyethylene wax, petroleum jelly, squalane, etc .; lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid Higher fatty acids such as isostearic acid; higher alcohols such as lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, behenyl alcohol, cetostearyl alcohol; Pill, isopropyl palmitate, myristyl myristate, cetyl palmitate, octyldodecyl myristate, octyldodecyl oleate, isopropyl isostearate, cetyl 2-ethylhexanoate, cetostearyl 2-ethylhexanoate, glyceryl tri-2-ethylhexanoate , Fatty acid esters such as glyceryl triisopalmitate, pentaerythritol tetra-2-ethylhexanoate, octyldodecyl isostearate; methylpolysiloxane, highly polymerized methylpolysiloxane, methylphenylpolysiloxane, decamethyltetrasiloxane, octamethylcyclotetrasiloxane , Decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, methylcyclopolysiloxane, alcohol-modified silicone, Alkyl-modified silicones, amino-modified silicones may be exemplified silicone, or the like, such as epoxy-modified silicone. These components can be used individually or in combination of 2 or more types as appropriate.
油剤の含有量は、特に限定されないが、通常、乳化する観点から、毛髪化粧料中に、好ましくは０．５〜６０重量％、より好ましくは１〜５０重量％である。 Although content of an oil agent is not specifically limited, From a viewpoint which emulsifies normally, Preferably it is 0.5-60 weight% in hair cosmetics, More preferably, it is 1-50 weight%.
本発明の毛髪化粧料には、必要により、本発明の目的が阻害されない範囲内で、例えば、皮膜形成剤、低級アルコール、多価アルコール、紫外線吸収剤、増粘剤、香料、色素、防腐剤、キレート剤、抗菌剤、酸化防止剤、保湿剤、清涼剤、ビタミン剤、植物抽出物等を適宜、その用途、目的等に応じて添加することができる。
また、本発明の毛髪化粧料において、（Ａ）〜（Ｄ）成分及び上記成分の残部は、エチルアルコール等のアルコールであることが好ましい。
The hair cosmetic composition of the present invention can be applied to the hair cosmetic composition of the present invention, if necessary, within the range in which the object of the present invention is not hindered. A chelating agent, an antibacterial agent, an antioxidant, a moisturizer, a refreshing agent, a vitamin agent, a plant extract and the like can be appropriately added according to the use, purpose and the like.
In the hair cosmetic composition of the present invention, the components (A) to (D) and the remainder of the components are preferably alcohols such as ethyl alcohol.
尚、本発明の毛髪化粧料は、製剤安定性に優れている観点から、液状、ゲル状、ペースト状、クリーム状、ワックス状、ロウ状等の種々の剤型に適用することができる。具体的には、陰イオン性界面活性剤と陽イオン性界面活性剤のコンプレックスによるダマや塊の発生を抑制し、均一に乳化することができることから、ヘアクリーム、ヘアワックス等の毛髪用乳化化粧料、特に、整髪用乳化化粧料として好適に用いることができる。また、陰イオン性界面活性剤と陽イオン性界面活性剤のコンプレックスによる白濁を抑制し、優れた透明性を維持することもできることから、透明液体整髪剤、所謂、寝癖直し、透明ヘアジェル等の毛髪用透明化粧料、特に、整髪用透明化粧料としても好適に用いることができる。ここで、「透明」とは、該化粧料を通して他の物体を見るとき、その色が変化せずに見える状態をいう。また、「液状」とは、流動性のある液体を含み、一般的な液体またはわずかに粘性のある液体等の状態をいう。 The hair cosmetic composition of the present invention can be applied to various dosage forms such as liquid, gel, paste, cream, wax, and wax from the viewpoint of excellent formulation stability. Specifically, it is possible to suppress the occurrence of lumps and lumps due to the complex of an anionic surfactant and a cationic surfactant, and to uniformly emulsify, so emulsified cosmetics for hair such as hair creams and hair waxes. It can be suitably used as an emulsifying cosmetic for hairdressing. In addition, since it is possible to suppress white turbidity due to the complex of an anionic surfactant and a cationic surfactant and to maintain excellent transparency, it is also possible to maintain a transparent liquid hair styling agent, so-called lie down, transparent hair gel and other hair It can also be suitably used as a transparent cosmetic for hair, especially as a transparent cosmetic for hairdressing. Here, “transparent” refers to a state in which, when another object is viewed through the cosmetic, the color can be seen without change. The term “liquid” includes a fluid liquid and means a general liquid or a slightly viscous liquid.
次に、本発明を実施例に基づいて更に詳細に説明するが、本発明はこれら実施例にのみ限定されるものではない。尚、各配合量は、特記しない限り重量％を表し、純量に換算した。 EXAMPLES Next, although this invention is demonstrated still in detail based on an Example, this invention is not limited only to these Examples. In addition, each compounding quantity represents weight% unless otherwise specified, and converted into a pure quantity.
（試料の調製１）
表１および表２に記した組成に従い実施例１〜８および比較例１〜７の各試料を調製し、下記評価に供した。その結果をそれぞれ表１および表２に併記する。尚、評価はすべて、２３℃、湿度６０％の恒温恒湿の一定条件下で実施した。
(Sample preparation 1)
Each sample of Examples 1-8 and Comparative Examples 1-7 was prepared according to the composition described in Table 1 and Table 2, and it used for the following evaluation. The results are also shown in Table 1 and Table 2, respectively. All evaluations were performed under constant conditions of constant temperature and humidity of 23 ° C. and humidity of 60%.
（試験例１：乳化の均一性および使用感の評価）
各実施例および各比較例で得られた調製直後の試料を手に取り、手のひら上で延ばした時の乳化の均一性および使用感を下記の評価基準に従って目視・官能評価した。
(Test Example 1: Evaluation of uniformity of emulsification and feeling of use)
The samples immediately after preparation obtained in each Example and each Comparative Example were picked up, and the uniformity and usability of emulsification when stretched on the palm were visually and sensorially evaluated according to the following evaluation criteria.
＜乳化の均一性および使用感の評価基準＞
○：ダマや塊がなく、均一で滑らかである
△：ダマや塊が僅かに認められ、滑らかさが損なわれている
×：ダマや塊が明らかに認められ、滑らかさがなく、ざらつく
<Evaluation Criteria for Emulsification Uniformity and Usability>
○: No lumps or lumps, uniform and smooth △: Slight lumps and lumps are observed, and smoothness is impaired. ×: Defects and lumps are clearly recognized, and there is no smoothness and roughness.
（試験例２：乳化安定性および使用感の評価）
各実施例および各比較例で得られた試料を、１２０ｇ容の広口容器に充填し、２３℃、湿度６０％の恒温恒湿室内に２週間保管後、試料を手に取り、手のひら上で延ばした時の乳化安定性および使用感を下記の評価基準に従って目視・官能評価した。
(Test Example 2: Evaluation of emulsion stability and feeling of use)
Samples obtained in each Example and each Comparative Example were filled in a 120 g wide-mouth container, stored in a constant temperature and humidity room at 23 ° C. and 60% humidity for 2 weeks, and then the sample was taken and extended on the palm. The emulsification stability and the feeling during use were visually and sensorially evaluated according to the following evaluation criteria.
＜乳化安定性および使用感の評価基準＞
○：ダマや塊がなく、均一で滑らかである
△：ダマや塊が僅かに認められ、滑らかさが損なわれている
×：ダマや塊が明らかに認められ、滑らかさがなく、ざらつく
<Evaluation criteria for emulsion stability and feeling of use>
○: No lumps or lumps, uniform and smooth △: Slight lumps and lumps are observed, and smoothness is impaired. ×: Defects and lumps are clearly recognized, and there is no smoothness and roughness.
（試験例３：滑らかさおよび潤いの評価）
２３℃、湿度６０％の恒温恒湿下で一晩放置した毛束（長さ１０ｃｍ、幅０．８ｃｍ、重量１ｇ）に各実施例および各比較例で得られた試料を０．４ｇ塗布後、指先でのばして毛束の厚みを均一にした。再度、上記条件下で３０分間放置した後、毛束の滑らかさおよび潤いについて、評価パネル２０名により、下記の評価基準に従って官能評価した。
(Test Example 3: Evaluation of smoothness and moisture)
After applying 0.4 g of the sample obtained in each example and each comparative example to a hair bundle (length 10 cm, width 0.8 cm, weight 1 g) left overnight at 23 ° C. and 60% humidity and constant temperature and humidity The thickness of the hair bundle was made uniform by extending with the fingertip. Again, after leaving for 30 minutes under the above conditions, the evaluation and sensory evaluation of the smoothness and moisture of the hair bundle were performed by 20 evaluation panels according to the following evaluation criteria.
＜滑らかさの評価基準＞
○：２０名中１６名以上が滑らかさがあると回答
△：２０名中１０〜１５名が滑らかさがあると回答
×：２０名中９名以下が滑らかさがあると回答
<Evaluation criteria for smoothness>
○: If 16 or more out of 20 people are smooth, Δ: 10 to 15 out of 20 people answered that there is smooth ×: 9 or less out of 20 people answered that there is smoothness
＜潤いの評価基準＞
○：２０名中１６名以上が潤いに優れると回答
△：２０名中１０〜１５名が潤いに優れると回答
×：２０名中９名以下が潤いに優れると回答
<Evaluation criteria for moisture>
○: Answer that 16 or more of 20 people are excellent in moisture △: Answer that 10 to 15 of 20 people are excellent in moisture ×: Answer that 9 or less of 20 people are excellent in moisture
表１と表２に示される結果の通り、本発明の毛髪化粧料は、陰イオン性界面活性剤と陽イオン性界面活性剤のコンプレックスによるダマや塊の発生を抑制し、均一に乳化することができ、優れた乳化安定性および使用感を有するとともに、毛髪に優れた滑らかさと水々しい潤いを付与することができる。 As shown in Tables 1 and 2, the hair cosmetic composition of the present invention suppresses the generation of lumps and lumps due to the complex of an anionic surfactant and a cationic surfactant, and uniformly emulsifies. It has excellent emulsification stability and usability, and can impart excellent smoothness and moisture to hair.
（試料の調製２）
表３および表４に記した組成に従い実施例９〜１９および比較例８〜１９の試料を調製し、下記評価に供した。その結果をそれぞれ表３および表４に併記する。尚、評価はすべて、２３℃、湿度６０％の恒温恒湿の一定条件下で実施した。
(Sample preparation 2)
Samples of Examples 9 to 19 and Comparative Examples 8 to 19 were prepared according to the compositions described in Table 3 and Table 4, and subjected to the following evaluation. The results are also shown in Table 3 and Table 4, respectively. All evaluations were performed under constant conditions of constant temperature and humidity of 23 ° C. and humidity of 60%.
（試験例４：性状の確認）
各実施例および各比較例で得られた試料の性状を目視にて確認し、下記性状に分類した。
(Test Example 4: Confirmation of properties)
The properties of the samples obtained in each example and each comparative example were visually confirmed and classified into the following properties.
＜性状の分類＞
ａ：透明ゲル状、若しくは透明ペースト状
ｂ：透明微粘性液状
ｃ：透明液状
ｄ：白濁ゲル状、若しくは白濁ペースト状
ｅ：白濁微粘性液状
ｆ：白濁液状
（ただし、ａ、ｄのゲル状、若しくはペースト状とは、流動性のないものを指す。）
<Classification of properties>
a: transparent gel or transparent paste b: transparent slightly viscous liquid c: transparent liquid d: cloudy gel or white cloudy paste e: cloudy slightly viscous liquid f: cloudy liquid (however, a, d gel, (Or paste-like refers to those that do not have fluidity.)
（試験例５：透明性の持続の評価）
各実施例および各比較例で得られた試料を、１２０ｇ容の透明広口容器に充填し、２３℃、湿度６０％の恒温恒湿室内に２週間保管後の透明性の持続を下記の評価基準に従って目視評価した。
(Test Example 5: Evaluation of persistence of transparency)
Samples obtained in each Example and each Comparative Example were filled into a 120 g transparent wide-mouthed container, and the following evaluation criteria were used to maintain the transparency after storage for 2 weeks in a constant temperature and humidity room at 23 ° C. and 60% humidity. According to visual evaluation.
＜透明性の持続の評価基準＞
○：製造直後と変化が認められず、透明性を維持している
△：ダマや沈殿物が僅かに認められ、微濁透明である
×：ダマや沈殿物が明らかに認められ、白濁している
<Evaluation criteria for sustaining transparency>
○: No change is observed immediately after production, and transparency is maintained. Δ: Slightly debris and precipitates are observed, and it is transparent and slightly turbid. Have
（試験例６：滑らかさおよび潤いの評価）
試験例３と同様に滑らかさおよび潤いの評価を実施した。
(Test Example 6: Evaluation of smoothness and moisture)
Similar to Test Example 3, evaluation of smoothness and moisture was performed.
表３と表４に示される結果の通り、本発明の毛髪化粧料は、陰イオン性界面活性剤と陽イオン性界面活性剤のコンプレックスによる沈殿物やダマによる白濁を抑制し、優れた透明性を持続することができるとともに、毛髪に優れた滑らかさと水々しい潤いを付与することができる。 As the results shown in Table 3 and Table 4, the hair cosmetic composition of the present invention suppresses white turbidity caused by precipitates and lumps due to the complex of an anionic surfactant and a cationic surfactant, and excellent transparency. Can be maintained, and can impart excellent smoothness and moisture to the hair.
以下、本発明に係る毛髪化粧料の処方例を示す。尚、含有量は重量％である。 Hereinafter, formulation examples of hair cosmetics according to the present invention will be shown. The content is% by weight.
（処方例１：クリーム状整髪剤）
エタノール １０．０
流動パラフィン ６．０
ワセリン ３．０
スルホコハク酸ジオクチルナトリウム ４．０
塩化セチルトリメチルアンモニウム ４．０
テトラグリセリンモノラウリルエーテル ５．０
ミリスチルアルコール ２．０
ステアリン酸 １．０
ジメチルポリシロキサン ２．０
デカメチルシクロペンタシロキサン １．０
１，３−ブチレングリコール ５．０
アクリル酸・メタクリル酸アルキル共重合体 ０．３
トリエタノールアミン ０．２
フェノキシエタノール ０．１
１，２−オクタンジオール ０．１
精製水 残 部
合 計 １００．０
(Formulation example 1: Cream hairdressing agent)
Ethanol 10.0
Liquid paraffin 6.0
Vaseline 3.0
Dioctyl sodium sulfosuccinate 4.0
Cetyltrimethylammonium chloride 4.0
Tetraglycerin monolauryl ether 5.0
Myristyl alcohol 2.0
Stearic acid 1.0
Dimethylpolysiloxane 2.0
Decamethylcyclopentasiloxane 1.0
1,3-butylene glycol 5.0
Acrylic acid / alkyl methacrylate copolymer 0.3
Triethanolamine 0.2
Phenoxyethanol 0.1
1,2-octanediol 0.1
Purified water balance part Total 100.0
（処方例２：ワックス状整髪剤）
エタノール １０．０
カルナウバロウ ５．０
キャンデリラロウ ５．０
流動パラフィン ６．０
ポリオキシエチレン（２）ラウリルエーテル硫酸ナトリウム ３．０
塩化ステアリルトリメチルアンモニウム ３．０
デカグリセリンモノラウリルエーテル ５．０
ミリスチルアルコール ２．０
ステアリン酸 １．０
ジメチルポリシロキサン ２．０
プロピレンレングリコール ５．０
フェノキシエタノール ０．１
１，２−オクタンジオール ０．１
精製水 残 部
合 計 １００．０
(Formulation Example 2: Wax hair styling agent)
Ethanol 10.0
Carnauba Arrow 5.0
Candelilla Row 5.0
Liquid paraffin 6.0
Polyoxyethylene (2) sodium lauryl ether sulfate 3.0
Stearyltrimethylammonium chloride 3.0
Decaglycerin monolauryl ether 5.0
Myristyl alcohol 2.0
Stearic acid 1.0
Dimethylpolysiloxane 2.0
Propylene glycol 5.0
Phenoxyethanol 0.1
1,2-octanediol 0.1
Purified water balance part Total 100.0
（処方例３：透明ゲル状整髪剤）
エタノール ２０．０
ポリビニルピロリドン ５．０
スルホコハク酸ジオクチルナトリウム ２．０
塩化ステアリルトリメチルアンモニウム ２．０
デカグリセリンモノラウリルエーテル ２．０
マルチトール ５．０
グリセリン ５．０
カルボキシビニルポリマー ０．４
トリエタノールアミン ０．３
フェノキシエタノール ０．１
１，２−ペンタンジオール ０．１
精製水 残 部
合 計 １００．０
(Prescription Example 3: Transparent gel hairdressing agent)
Ethanol 20.0
Polyvinylpyrrolidone 5.0
Dioctyl sodium sulfosuccinate 2.0
Stearyltrimethylammonium chloride 2.0
Decaglycerin monolauryl ether 2.0
Maltitol 5.0
Glycerin 5.0
Carboxyvinyl polymer 0.4
Triethanolamine 0.3
Phenoxyethanol 0.1
1,2-pentanediol 0.1
Purified water balance part Total 100.0
（処方例４：透明液状寝癖直し）
エタノール １０．０
Ｎ−メタクリロイルオキシエチルＮ，Ｎ−ジメチルアンモニウム
−α−Ｎ−メチル・カルボキシベタイン・メタクリル酸アルキル
エステル共重合体 １．０
ポリオキシエチレン（２）ラウリルエーテル硫酸ナトリウム ４．０
塩化セチルトリメチルアンモニウム ４．０
テトラグリセリンモノラウリルエーテル ４．０
イソプレングリコール ４．０
フェノキシエタノール ０．１
１，２−オクタンジオール ０．１
精製水 残 部
合 計 １００．０
(Formulation Example 4: Transparent liquid bed rest)
Ethanol 10.0
N-methacryloyloxyethyl N, N-dimethylammonium-α-N-methyl / carboxybetaine / methacrylic acid alkyl ester copolymer 1.0
Polyoxyethylene (2) sodium lauryl ether sulfate 4.0
Cetyltrimethylammonium chloride 4.0
Tetraglycerin monolauryl ether 4.0
Isoprene glycol 4.0
Phenoxyethanol 0.1
1,2-octanediol 0.1
Purified water balance part Total 100.0
Claims (6)
The hair cosmetic composition according to any one of claims 1 to 4, which is transparent.
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| JP2007245797A JP4896844B2 (en) | 2007-09-21 | 2007-09-21 | Hair cosmetics |
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| EP2145946A1 (en) * | 2008-07-16 | 2010-01-20 | Daicel Chemical Industries, Ltd. | Detergent Composition |
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| JP2015205876A (en) * | 2014-04-17 | 2015-11-19 | エヴォニク インダストリーズ アーゲー | Surfactant composition, and high-oil-content preparation containing the same |
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| CN102573768A (en) * | 2009-10-01 | 2012-07-11 | 株式会社大赛璐 | Oil composition for cosmetics |
| JP2014122200A (en) * | 2012-12-21 | 2014-07-03 | Jm World Co Ltd | Hair cosmetic |
| JP2015205876A (en) * | 2014-04-17 | 2015-11-19 | エヴォニク インダストリーズ アーゲー | Surfactant composition, and high-oil-content preparation containing the same |
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