JP2009019291A - Narrow woven or knitted fabric - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a narrow woven fabric or narrow knitted fabric having high recovery and heat resistance, and providing a product having the functions of preventing slip-in and fraying. <P>SOLUTION: The narrow woven or knitted fabric is obtained by using a polyurethane-urea elastic fiber containing 5-40 wt.% polyurethane compound, and having ≥150°C and ≤180°C of a compression deformation-starting temperature by thermomechanometry (TMA), and ≥30 sec of a time for breakage by heat at 180°C under 50% elongation at least as a part thereof. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

  The present invention relates to a narrow woven knitted fabric and apparel used therefor, and more particularly to a narrow woven fabric or a narrow knitted fabric useful mainly for preventing unraveling and slip-in in which polyurethane elastic fibers are mixed.

  Polyurethane elastic fiber is an elastic fiber with excellent elastic function, such as foundations, socks, pantyhose, swimwear, sportswear, leotards, garments, bandages, supporters, masks, automotive interior materials, nets. It is also widely used in non-clothing fields such as tape. Among them, narrow woven and knitted fabrics with elastic elasticity containing polyurethane elastic fibers are widely used for sports clothing sidelines and suspenders, inner clothing straps and inside belts, medical supporters, corsets, etc. ing. As stretchable narrow woven fabrics, fabrics woven with polyurethane elastic fibers in the warp direction or both warps and wefts are marketed. As narrow knitted fabrics, narrow knitted fabrics woven with polyurethane elastic fibers are marketed. Yes.

  Polyurethane elastic fiber is an elastic fiber mainly composed of segment polyurethane, which is based on a block copolymer mainly composed of high molecular weight polyol, diisocyanate, and chain extender, and has a soft segment that is highly flexible in chemical structure. It consists of hard segments that form crystal structures by strong intermolecular forces due to hydrogen bonding. And according to the kind of chain extender which comprises a hard segment, it can classify | categorize into the polyurethane- urethane type which consists of a urethane- urea type which uses a low molecular weight polyol and a polyurethane- urea type which has a urea bond and a low molecular weight.

  The hydrogen bond strength of the hard segment greatly affects the physical properties such as heat resistance, and the urea bond is stronger than the urethane bond, so the polyurethane-urea type has better heat resistance and is currently produced. It is used in a wide range of fields because it is the mainstream of polyurethane elastic fibers. In the present invention, an elastic fiber mainly composed of such a polyurethane-urea type polymer (hereinafter referred to as a polyurethane urea polymer) is referred to as a polyurethane urea elastic fiber. On the other hand, elastic fibers made of polyurethane-urethane type polymers are inferior in heat resistance and recoverability compared to polyurethane urea elastic fibers, but conversely, they can be set at a relatively low temperature. Has been applied.

The narrow woven knitted fabric containing the polyurethane elastic fiber has a problem that the polyurethane elastic fiber is likely to come off from the end of the cut narrow woven knitted fabric, so-called “slip-in”. This can be solved to some extent by setting a larger number of twists of the partner yarn to be coated, but there is a problem that the texture becomes harder if the number of twists is increased. Furthermore, there is a problem that the end of the narrow knitted knitted fabric is easily unraveled, and this cannot be improved by setting the number of twists of the coated yarn.
Using a polyurethane-urethane type low-melting point polyurethane elastic fiber, knitting other yarns with a plating knitting, and using a knitted fabric with heat-release processing, similarly cut open There has been proposed a garment (see Patent Document 1 or 2).

  However, the polyurethane-urethane type polyurethane elastic fiber is greatly deteriorated in physical properties due to heat in the setting process for dyeing fabrics and products, and in the dyeing process. Under the processing temperature conditions in which polyurethane urea elastic fiber is normally used, There is a problem that the recoverability of the fabric may be lowered, and further, yarn breakage of the polyurethane elastic fiber may occur. In a product using this fabric, there is a problem that processing conditions are thermally limited. In particular, in the case of a combination with polyester fiber, yarn breakage of the polyurethane elastic fiber occurs in the dyeing process at 120 ° C. to 135 ° C., and therefore cannot be used in combination with the polyester fiber.

  Further, for example, a fiber structure using polyurethane elastic fibers spun from a spinning solution containing at least two types of polyurethane components having different melting points on the high temperature side, such as a polyurethane-urethane type and a polyurethane-urea type, There has been proposed a method for producing a stretchable fiber structure that hardly undergoes unraveling by heat treatment at a temperature equal to or higher than the heat distortion temperature of a polyurethane component having a low melting point (see Patent Document 3).

However, the curling and unwinding suppressing effects of the fabric obtained by this production method are not sufficiently satisfactory as compared with the case where the above-described low-melting polyurethane elastic yarn is used. Moreover, the possibility that the basic performance of the elastic fiber such as high recoverability and elongation of the polyurethane-urea type may be reduced by including two or more types of polyurethane components having different structures is considered. Absent.
JP 2005-113349 A JP 2005-350800 A JP 2005-330617 A

  An object of the present invention is to provide a narrow woven or knitted fabric that has high recoverability and heat resistance, is suppressed in slip-in and unraveling, has improved texture, and retains excellent stretch properties.

  As a result of intensive research to solve the above-mentioned problems, the inventors of the present invention contain a specific polyurethane compound as a polyurethane elastic fiber for improving slip-in and unwinding prevention properties of a narrow woven knitted fabric, The present inventors have found that the above problems can be solved by a narrow woven or knitted fabric using a polyurethane urea elastic fiber having deformability and heat resistance, and have made the present invention.

That is, the present invention is as follows.
(1) Thermal cutting at 180 ° C. containing 5% to 40% by weight of a polyurethane compound, having a compression deformation start temperature of 150 ° C. or more and 180 ° C. or less by thermomechanical measurement analysis (TMA), and 50% elongation. A narrow woven or knitted fabric comprising polyurethane urea elastic fibers having a number of seconds of 30 seconds or more at least partially.

(2) The narrow woven or knitted fabric according to (1) above, wherein the polyurethane urea is made from a polyalkylene ether diol composed of one or more alkylene ethers having 2 to 10 carbon atoms.
(3) The narrow woven or knitted fabric according to (1) or (2) above, wherein the polyurethane compound is made from a polyalkylene ether diol composed of one or more alkylene ethers having 2 to 10 carbon atoms.
(4) Thermal cutting seconds at 180 ° C. containing 5% to 40% by weight of a polyurethane compound, the compression deformation starting temperature by thermomechanical measurement analysis (TMA) is 150 ° C. or higher and 180 ° C. or lower, and 50% stretched. A method for producing a narrow-width knitted fabric, characterized in that the polyurethane urea elastic fibers having a number of 30 seconds or more are woven or knitted using at least a part thereof and then heat-treated at 90 ° C to 200 ° C with dry heat or wet heat.

  The narrow-width woven or knitted fabric of the present invention is produced by applying tension, compression, or polyurethane urea elastic fiber to the polyurethane urea elastic fibers in the fabric or between the polyurethane urea elastic fibers and the other yarn in the fabric by heat during processing. Due to its own residual stress, compression deformation of the polyurethaneurea elastic fiber occurs. At this deformation point, the polyurethane urea elastic fibers adhere to each other or to the polyurethane urea elastic fibers, so that the polyurethane urea elastic fibers and the counterpart yarn are difficult to come off from the fabric structure, and slip-in and unraveling are suppressed. A knitted fabric can be obtained. Moreover, since the number of twists of the partner yarn to be coated can be reduced, the texture can be improved. For this reason, the narrow woven or knitted fabric of the present invention is used as a clothing material having an excellent wearing feeling in uses such as a shoulder strap of a brassiere, a strap and an inner belt of an inner garment, a medical supporter, and a corset. .

  In addition, the polyurethane urea elastic fiber used in the narrow woven or knitted fabric of the present invention is excellent in heat resistance and recoverability, so there are few restrictions on thermal conditions in processing, and it is a general fiber product in which polyurethane urea elastic fiber is used. It is possible to provide products that are used in combination with any partner yarn. Also, a combination with polyester fibers that cannot be used with polyurethane-urethane type polyurethane elastic fibers is possible.

Hereinafter, the present invention will be specifically described.
The narrow woven or knitted fabric of the present invention is not particularly limited as long as it has a width corresponding to the intended use, but usually indicates that it is woven or knitted to a width of about 1 to 100 mm.
The narrow woven or knitted fabric of the present invention is characterized in that a specific polyurethane urea elastic fiber described later is used at least in part. Thereby, the effect of the present invention can be achieved.
The polyurethane urea elastic fiber used in the narrow woven or knitted fabric of the present invention is composed of a composition containing a polyurethane urea polymer as a main component. By using a polyurethane urea polymer having high heat resistance as a main component, yarn breakage due to heat during processing is less likely to occur, and a fabric having good stretch properties can be obtained. The content of the polyurethane urea polymer in the polyurethane urea elastic fiber is preferably 60% by weight or more, more preferably 75% by weight or more, from the viewpoint of heat resistance and physical properties of the polyurethane urea elastic fiber and its fabric product. It is.

  The polyurethane urea polymer used in the narrow woven or knitted fabric of the present invention can be obtained, for example, by reacting a high molecular weight polyol, a diisocyanate, a low molecular diamine, and a terminal stopper having a monofunctional active hydrogen atom.

  As the high molecular weight polyol, various diols consisting of a substantially linear homo- or copolymer, for example, polyester diol, polyether diol, polyester amide diol, polyacryl diol, polythioester diol, polythioether diol, polycarbonate diol or A mixture thereof, a copolymer thereof, or the like can be given. Preferred are polyalkylene ether glycols, such as polyoxyethylene glycol, polyoxypropylene glycol, polytetramethylene ether glycol, polyoxypentamethylene glycol, and copolymer polyalkylenes comprising different alkylene ethers having 2 to 10 carbon atoms Ether glycol or a mixture thereof. Among them, polytetramethylene ether glycol exhibiting an excellent elastic function, and copolymerized polyalkylene ether glycols composed of different alkylene ethers having 2 to 10 carbon atoms are preferable, and different alkylene ethers having 2 to 10 carbon atoms. A copolymer polyalkylene ether glycol consisting of is more preferred. Preferable examples of copolymer polyalkylene ether glycols composed of different alkylene ethers having 2 to 10 carbon atoms include copolymer polyether glycols composed of tetramethylene groups and 2,2-dimethylpropylene groups, tetramethylene groups and 3 -Copolymer polyether glycols composed of methyltetramethylene groups. The number average molecular weight of the polymer polyol is preferably 500 to 5,000. A more preferred number average molecular weight is 1,000 to 3,000.

  Examples of the diisocyanate include aliphatic, alicyclic and aromatic diisocyanates. For example, 4,4′-diphenylmethane diisocyanate, 2,4′-diphenylmethane diisocyanate, 2,4- and 2,6-tolylene diisocyanate, m- and p-xylylene diisocyanate, α, α, α ′, α ′ -Tetramethyl-xylylene diisocyanate, 4,4'-diphenyl ether diisocyanate, 4,4'-dicyclohexyl diisocyanate, 1,3- and 1,4-cyclohexylene diisocyanate, 3- (α-isocyanatoethyl) phenyl isocyanate, 1 , 6-hexamethylene diisocyanate, trimethylene diisocyanate, tetramethylene diisocyanate, isophorone diisocyanate, or a mixture thereof, or a copolymer thereof. Preferably, 4,4'-diphenylmethane diisocyanate.

  Examples of the low molecular diamine used as the chain extender include ethylene diamine, 1,2-propylene diamine, 1,3-propylene diamine, 2-methyl-1,5-pentane diamine, triethylene diamine, m-xylylenediamine, and piperazine. , O-, m- and p-phenylenediamine, 1,3-diaminocyclohexane, 1,4-diaminocyclohexane, 1,6-hexamethylenediamine, N, N ′-(methylenedi-4,1-phenylene) bis [ 2- (ethylamino) -urea] and the like. These can be used alone or in combination. Preferably, ethylenediamine alone or an ethylenediamine mixture containing 5 to 40 mol% of at least one selected from the group consisting of 1,2-propylenediamine, 1,3-diaminocyclohexane, and 2-methyl-1,5-pentadiamine. Can be mentioned. More preferably, ethylenediamine alone is used.

  Examples of the terminal terminator having a monofunctional active hydrogen atom include methanol, ethanol, 2-propanol, 2-methyl-2-propanol, 1-butanol, 2-ethyl-1-hexanol, and 3-methyl-1-. Monoalcohols such as butanol, monoalkylamines such as isopropylamine, n-butylamine, t-butylamine, 2-ethylhexylamine, diethylamine, dimethylamine, di-n-butylamine, di-t-butylamine, diisobutylamine, di And dialkylamines such as -2-ethylhexylamine and diisopropylamine. These can be used alone or in combination. Monoalkylamines or dialkylamines that are monofunctional amines are preferred over monoalcohols.

  With respect to the method for producing the polyurethane urea polymer used in the present invention, a known polyurethane reaction technique can be used. For example, a polyalkylene ether glycol and a diisocyanate are reacted under an excess of diisocyanate to synthesize a urethane prepolymer having an isocyanate group at the terminal, and then this urethane prepolymer is subjected to a chain extension reaction with a low molecular diamine to produce a polyurethane urea. A polymer can be obtained. Preferred polymer substrates in the present invention include polytetramethylene ether glycol having a number average molecular weight of 500 to 5000 and / or copolymer polyalkylene ether glycol composed of different alkylene ethers having 2 to 10 carbon atoms in excess equivalent amount of diisocyanate. It is a polyurethaneurea polymer obtained by reacting a narate to synthesize a prepolymer having an isocyanate group at the terminal, and then reacting the prepolymer with a low molecular diamine and a monofunctional amine.

  Regarding the operation of the polyurethane reaction, an amide polar solvent such as dimethylformamide, dimethyl sulfoxide, dimethylacetamide or the like can be used during the synthesis of the urethane prepolymer or the reaction between the urethane prepolymer and the active hydrogen-containing compound. Preferably dimethylacetamide is used.

  The polyurethane urea elastic fiber used in the present invention is characterized by having a compression deformation starting temperature of 150 ° C. or higher and 180 ° C. or lower by thermomechanical analysis (TMA). By being in this temperature range, the desired slip-in and unwinding prevention functions can be obtained under the processing conditions of a normal polyurethane urea elastic fiber mixed fabric product. From the viewpoint of exhibiting slip-in and unwinding prevention functions, it is preferable that the polyurethane urea elastic fiber has a compression deformation start temperature of 175 ° C. or lower, and physical properties such as recoverability of the narrow woven knitted product after heat treatment in the processing step From this point, it is more preferably 160 ° C. or higher.

In addition, the polyurethane urea elastic fiber used in the present invention is obtained when the raw yarn is brought into contact with a heat body at 180 ° C. under 50% elongation from the viewpoint of heat resistance when the narrow woven knitted product is processed. The time until breakage occurs is 30 seconds or longer. Since the polyurethane urea elastic fiber is difficult to break even at high temperatures, it is possible to provide a narrow woven or knitted fabric with less restrictions on temperature conditions during processing.
As described above, the polyurethaneurea elastic fiber used in the narrow woven or knitted fabric of the present invention has excellent heat resistance at high temperatures and is easily compressed and deformed at lower temperatures. Such performance can be expressed by using a polyurethane urea polymer in the fiber substrate and further containing a specific amount of a specific polyurethane compound.

  The polyurethane urea elastic fiber used for the narrow woven or knitted fabric of the present invention contains 5% by weight or more and 40% by weight or less of a polyurethane compound. By making the content of the polyurethane compound 5% by weight or more, it is possible to obtain an effect of preventing slip-in and unraveling, but by making it 40% by weight or less, the breaking strength, power, and recoverability of the elastic fiber A narrow woven or knitted fabric having good stretch properties can be obtained without impairing the above. The content of the polyurethane compound is more preferably 10% by weight or more and 30% by weight or less.

  The polyurethane compound contained in the polyurethaneurea elastic fiber used in the present invention is a polymer having a hard segment composed of a urethane bond, and can be obtained, for example, by reacting a high molecular weight polyol, an isocyanate compound, and a low molecular weight polyol. Moreover, you may make the terminal stopper which has a monofunctional active hydrogen atom react.

  As the high molecular weight polyol, various diols composed of a substantially linear homo- or copolymer, for example, polyester diol, polyether diol, polyester amide diol, polyacryl diol, polythioester diol, polythioether diol, or these diols Examples thereof include a mixture or a copolymer thereof, or a polyol having three or more functional groups in the molecule described later. Polyether glycols composed of substantially linear homo- or copolymers include polyoxyethylene glycol, polyoxypropylene glycol, polytetramethylene ether glycol, polyoxypentamethylene glycol, different carbon numbers of 2 to 10 Copolyalkylene ether glycols composed of alkylene ethers or mixtures thereof. As the polyester diol composed of a substantially linear homo- or copolymer, an adipate system by a condensation dehydration reaction between a dibasic acid such as adipic acid or phthalic acid and a glycol such as ethylene glycol or 1,4-butanediol Polyester diol, polycaprolactone diol, polycarbonate diol and the like by ring-opening polymerization of ε-caprolactone. The polymer polyol preferably has a number average molecular weight of 500 to 2,500. More preferably, it is 600-2,200, Most preferably, it is 800-1,800.

  Examples of the isocyanate compound include aliphatic, alicyclic, and aromatic diisocyanates and isocyanates having three or more functional groups in the molecule described below. Examples of the diisocyanate include 4,4′-diphenylmethane diisocyanate, 2,4′-diphenylmethane diisocyanate, 2,4- and 2,6-tolylene diisocyanate, m- and p-xylylene diisocyanate, α, α, α ', Α'-tetramethyl-xylylene diisocyanate, 4,4'-diphenyl ether diisocyanate, 4,4'-dicyclohexyl diisocyanate, 1,3- and 1,4-cyclohexylene diisocyanate, 3- (α-isocyanatoethyl) Examples thereof include phenyl isocyanate, 1,6-hexamethylene diisocyanate, trimethylene diisocyanate, tetramethylene diisocyanate, isophorone diisocyanate, a mixture thereof, and a copolymer thereof. Preferably, 4,4'-diphenylmethane diisocyanate.

  Examples of the low molecular weight polyol include ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 2,2-dimethyl-1,3-propanediol, 1,4-butanediol, and 1,3-butane. A chain of diol, hexamethylene glycol, diethylene glycol, 1,10-decanediol, 1,3-dimethylolcyclohexane, 1,4-dimethylolcyclohexane or a low molecular polyol having three or more functional groups in the molecule described later It can be used as an extender. The low molecular weight polyol is preferably ethylene glycol, 1,3-propanediol, or 1,4-butanediol.

  With respect to the method for producing the polyurethane compound used in the present invention, a known polyurethane reaction technique can be used. For example, a one-shot method in which three components of a high molecular weight polyol, an isocyanate compound, and a low molecular weight polyol are mixed and reacted. Alternatively, a prepolymer in which a high molecular weight polyol and an isocyanate compound are reacted under an excess of isocyanate groups to synthesize a urethane prepolymer having an isocyanate group at the terminal, and then this urethane prepolymer is subjected to a chain extension reaction with a low molecular weight polyol. Although there is a method, the polyurethane compound may be obtained by any method. Regarding the operation of the polyurethane reaction, an amide polar solvent such as dimethylformamide, dimethyl sulfoxide, dimethylacetamide or the like can be used during the synthesis of the urethane prepolymer in the prepolymer method or during the reaction of the urethane prepolymer with the diol. Preferred is dimethylacetamide.

  The polyurethane compound used in the present invention preferably has a low hardness in order to exhibit the effect of preventing slip-in and unraveling. In order to obtain good fixing performance, the hardness of the polyurethane compound is preferably 80A or less, more preferably 77A or less, as defined in JIS-K6253.

  In the differential scanning calorimetry (DSC), the polyurethane compound used in the present invention preferably has no endothermic peak from 80 ° C. until the decomposition of the polyurethane compound starts. Usually, such an endothermic peak is considered to be caused by melting of a urethane hard segment mainly composed of a low molecular weight polyol and an isocyanate compound in the polyurethane compound polymer. Such polyurethane compounds having no endothermic peak can be expressed with a low hard segment ratio and a loose hard structure. The decomposition temperature of the polyurethane compound is measured at a temperature at which a large heat loss occurs in thermogravimetric analysis (TG). In this temperature range, there is no clear endothermic peak that can be confirmed by DSC measurement, that is, a polyurethane compound that does not cause rapid melting of the hard segment at a specific temperature is contained. Not only can fixing performance be obtained, but there is no sudden structural change in the polyurethane urea elastic fiber at the end of the endothermic peak temperature of the polyurethane compound due to heat during processing. It can have a good recovery property.

  As a polyurethane compound having such performance, when obtaining a polyurethane polymer, there are two kinds of methods such as a method of reducing the ratio of the molecular weight of the hard segment by changing the equivalent ratio of the isocyanate compound to the high molecular weight polyol, and two types of low molecular weight polyols. It can be suitably obtained by a method using a mixture, a method using a cross-linked polyurethane described below, a copolymerized polyalkylene ether glycol as a raw material of a polyurethane polymer described later, and the like.

  The polyurethane compound used in the present invention is more preferably a crosslinked polyurethane compound in order to impart high heat resistance and recoverability to the polyurethane urea elastic fiber. In the present invention, the cross-linked polyurethane compound means that a part of the polyurethane polymer has a three-dimensional network structure due to a branched structure of polyurethane molecules, or an allophanate bond or isocyanurate structure. In order to obtain a cross-linked polyurethane compound, a method using a high molecular weight polyol, an isocyanate compound or a low molecular weight polyol having three or more functional groups in the molecule, a cross-linked structure due to an allophanate bond or isocyanurate is produced during the reaction of diisocyanate. There is a method to make it. From the viewpoint of moldability, those having a crosslinked structure with allophanate bonds are preferred.

  Examples of polyols having three or more functional groups in the molecule include glycerin, hexanetriol, triethanolamine, diglycerin, pentaerythritol, sorbitol, and polyether polyols, polyester polyols, and polymer polyols using these as initiators. It is done. Isocyanates obtained from triphenylmethane triisocyanate, tris (isocyanatephenyl) thiophosphate, lysine ester triisocyanate, 1,6,11-undecane triisocyanate, 1,3,6-hexamethylene triisocyanate, and various isocyanate compounds And allophanate-modified polyisocyanate and polyurethane-modified polyisocyanate.

  For the method of producing a crosslinked type polyurethane compound having the above allophanate bond crosslinked structure, for example, when a chain is extended by a low molecular weight polyol by a prepolymer method, a low molecular weight polyol is added at a functional group ratio in which an isocyanate group remains, thereby extending the chain. A method of carrying out heating and crosslinking until an isocyanate group disappears in a thermostatic bath at 80 ° C. or higher after the heat treatment. Further, for example, there is a method in which an excess diisocyanate compound is added after chain extension with a low molecular weight polyol, followed by crosslinking by heating and holding in the same manner.

  Moreover, as the polyurethane compound used in the present invention, it is more preferable to use a copolymerized polyalkylene ether glycol composed of alkylene ethers having 2 to 10 carbon atoms. Preferable examples of copolymer polyalkylene ether glycols composed of different alkylene ethers having 2 to 10 carbon atoms include copolymer polyether glycols composed of tetramethylene groups and 2,2-dimethylpropylene groups, tetramethylene groups and 3 -Copolymer polyether glycols composed of methyltetramethylene groups. The copolymerization ratio of 2,2-dimethylpropylene group or 3-methyltetramethylene group to tetramethylene group is preferably 5 to 35 mol% and more preferably 5 to 20 mol% from the viewpoint of mechanical properties.

  The polyurethane urea elastic fiber used in the narrow woven knitted fabric of the present invention is preferably produced by dry spinning a polyurethane urea spinning stock solution obtained by dissolving the above-mentioned polyurethane compound and polyurethane urea polymer in an amide polar solvent. can do. Dry spinning is preferable compared to melt spinning or wet spinning because it can form the physical crosslinks by hard-bonding between hard segments most firmly. In addition, by making the polyurethane compound in the elastic fiber 40% by weight or less, in dry spinning, stable production without problems such as yarn breakage at the time of spinning can be achieved, and high-quality polyurethane elasticity with less unevenness in the yarn length direction. Fiber can be obtained. Examples of the amide polar solvent include dimethylformamide, dimethyl sulfoxide, and dimethylacetamide. Any method can be used to contain the polyurethane compound in the polyurethane urea elastic fiber. From the viewpoint of production processability, a polyurethane urea composition in which the polyurethane compound and the polyurethane urea polymer are uniformly mixed is spun. Is preferred.

The method of mixing the polyurethane compound and the polyurethane urea polymer is, for example, a method in which the polyurethane compound and the polyurethane urea polymer synthesized in an amide polar solvent are mixed with each other in order to uniformly mix in the polyurethane composition. A method in which a polyurethane compound polymerized with a solvent is dissolved in an amide polar solvent and then added to a polyurethane urea polymer solution, a method in which a molten polyurethane compound is added to a polyurethane urea polymer solution, a powder or pellet-shaped polyurethane compound Examples thereof include a method of dissolving a polyurethane urea polymer in an amide polar solvent solution.
In this polyurethane urea spinning dope, other compounds usually used for polyurethane urea elastic fibers, such as UV absorbers, antioxidants, light stabilizers, anti-gas coloring agents, chlorine-resistant agents, coloring agents, matting agents, Lubricants, fillers, etc. may be added.

  The polyurethane urea elastic fiber used in the present invention preferably contains 1.0% by weight or more and 6.0% by weight or less of dimethyl silicone. By containing 1.0% by weight or more of dimethylsilicone, when using polyurethaneurea elastic fibers, the yarn from the package has good detackiness, especially after long-term storage of the package. Deterioration can be suppressed. Further, by making the content of dimethyl silicone 6.0% by weight or less, it is possible to prevent the yarn from being unrolled from the package. More preferably, it is 2.5 wt% or more and 5.5 wt% or less.

  The polyurethane urea elastic fiber used in the present invention preferably has a modified silicone content of less than 0.001% by weight. The modified silicone is obtained by modifying the end of the dimethyl silicone chain and the middle side chain with a functional group, and examples thereof include amino-modified silicone, polyether-modified silicone, polyester-modified silicone, alcohol-modified silicone, and alkoxy-modified silicone. By setting the content in the polyurethaneurea elastic fiber to less than 0.001% by weight, higher heat-adhesiveness of the polyurethaneurea elastic fiber can be expressed. More preferably, it does not contain modified silicone.

  In order to contain the above-mentioned dimethyl silicone and modified silicone in the polyurethane urea elastic fiber, it can be obtained by containing an oil agent containing a dimethyl silicone component and made of mineral oil or the like. The oil agent may be added to the polyurethaneurea elastic fiber after dry spinning, or the oil agent may be preliminarily contained in the spinning dope, and dry spinning may be performed. When the oil agent is applied after dry spinning, there is no particular limitation as long as the spinning dope is after dry spinning and fiber formation, but it is preferably immediately before being taken up by a winder.

  The method of applying the oil agent includes the method of bringing the yarn immediately after spinning into contact with the oil film formed on the surface of the metal cylinder rotated in the oil agent bath, the method of attaching the oil agent quantitatively discharged from the nozzle tip with guide to the yarn, etc. A known method can be used. Further, the oil agent may be added to the spinning dope at any time when the spinning dope is produced, and dissolved or dispersed in the spinning dope. The content of the oil agent in the polyurethane urea elastic fiber is preferably 1.0% by weight or more and 6.0% by weight or less.

  As the oil agent, in addition to dimethyl silicone and mineral oil, amino-modified silicone, polyether-modified silicone, polyester-modified silicone, alcohol-modified silicone, alkoxy-modified silicone and other modified silicones may be contained. The total content is preferably less than 1.0% by weight. More preferably, it does not contain modified silicone. In addition, when applied to the polyurethane urea elastic fiber, the dimethyl silicone component is contained in an amount of 1.0% by weight or more and 6.0% by weight or less in accordance with the content of the oil in the polyurethane urea elastic fiber. It is preferable to change the content of the dimethyl silicone component. The content of dimethyl silicone in the oil is preferably 50% by weight or more. In addition, oils include mineral fine particles such as talc and colloidal alumina, higher fatty acid metal salt powders such as magnesium stearate and calcium stearate, higher aliphatic carboxylic acids, higher aliphatic alcohols, paraffin, polyethylene and other solid waxes at room temperature. Etc. may be used alone or in any combination as required.

The fibers combined with the polyurethane urea elastic fiber used in the narrow woven fabric of the present invention are natural fibers such as cotton, wool and hemp, regenerated fibers such as rayon, lyocell and cupra, semi-synthetic fibers such as acetate and triacetate, polyamide One or more selected from synthetic fibers such as fibers, polyester fibers, and acrylic fibers.
The thickness of the yarn used in the configuration of the narrow woven or knitted fabric is preferably in the range of a total fineness of 20 to 2000 dtex. These can be appropriately selected according to the purpose of use.

  The fiber combined with the polyurethane urea elastic fiber may be either a filament yarn or a spun yarn. Further, it may be a composite yarn of filament and spun yarn. The form of the filament yarn may be any of a raw yarn (unprocessed yarn), false twisted yarn, pre-dyed yarn, or a composite yarn thereof. These may be either single or blended ones. These fibers may be any one of mixed use of polyurethane urea elastic fibers or uniform knitting. The polyurethane urea elastic fiber may be used as a bare yarn or a coated elastic yarn.

  Covered elastic yarn is a covering such as FTY, SCY, and DCY that uses polyurethane urea elastic fiber as the core, filament synthetic fiber such as polyester fiber and polyamide fiber, and short fiber such as cotton as sheath components. Examples thereof include a core spun yarn called CSY coated with short fibers such as yarn and cotton, and a coated elastic yarn obtained by twisting a non-elastic fiber and a polyurethane urea elastic fiber. The draft ratio of polyurethane urea elastic fiber and non-elastic fiber of these coated elastic yarns (draft ratio of coated elastic yarn = length of non-elastic fiber when the coated elastic yarn is stretched / polyurethane when the coated elastic yarn is stretched) The length of the urea elastic fiber) can be arbitrarily set, and is preferably set in the range of 1.2 to 4.5. The thickness of the polyurethane urea elastic fiber used for the coated elastic yarn is not limited, but is preferably 20 to 12000 dt. The mixing ratio with the non-elastic fiber is not limited, but is preferably about 5 to 70% by weight, and can be arbitrarily selected depending on the narrow woven fabric or the narrow knitted fabric to be manufactured. The coated elastic yarn may be subjected to a generally known steam set.

  The content of the elastic fiber in the fabric of the narrow woven or knitted fabric is not particularly limited as long as the necessary stretchability can be imparted, and is preferably 1 to 40% from the viewpoint of the coverage and recoverability of the elastic yarn. As the elastic fiber, only the above-mentioned heat-adhesive urethane urea elastic fiber may be used, or a combination of the above-mentioned heat-adhesive polyurethane urea elastic fiber and a conventional polyurethane elastic fiber may be used. The ratio may be any ratio, but in order to achieve the effects of the present invention, it is preferable that the above-mentioned heat-adhesive polyurethaneurea elastic fiber is contained in the narrow woven or knitted fabric in an amount of 5 to 35% by weight.

  In the present invention, when the coated elastic yarn is used, it is necessary to control the coating state to some extent for fixing to other elastic fibers or the other yarn, and the polyurethane that completely constitutes the narrow woven or knitted fabric of the present invention Instead of coating the urea elastic fiber, it is preferable to lower the coverage and expose it partially. It can also be expected to improve the texture of the fabric by lowering the coverage.

For the woven structure of the narrow woven fabric of the present invention, a plain structure, a twill structure, a satin structure, a changed structure derived from these, and the like can be used.
The manufacturing process of the narrow woven fabric of the present invention can use a process of manufacturing a normal narrow woven fabric, that is, a preparation process, a warp process, a weaving process, and a dyeing process.
The preparation step when using the coated elastic yarn for the warp may be a conventionally known step, and a commonly used agent can be used for sizing or wax.

  During the production, not only the above-described composite yarn using the heat-fixable polyurethane urea elastic fiber, but also a composite yarn using an elastic fiber other than the present invention may be used, or a non-elastic fiber may be used. The yarn arrangement method may be a generally known method, and the arrangement method may be appropriately determined depending on the structure and density. For the weaving of the narrow woven fabric of the present invention, a conventionally known narrow tape loom may be used.

The weft may be only a composite yarn using the above-mentioned heat-adhesive polyurethane urea elastic fiber, or may be arranged in combination with a composite yarn or non-elastic yarn of an elastic fiber other than the present invention in the same manner as the warp. . Examples of elastic fibers other than those of the present invention include PBT, PTT, and ordinary polyurethane urea. The coated elastic yarn may be used for the entire narrow woven fabric, or may be in one direction of either a warp or a weft.
The knitting structure that can be used for the narrow knitted fabric of the present invention may be any of basic structures such as chain knitting, denby knitting, cord knitting, atlas knitting, insertion knitting, and the like, or a changed structure obtained by a combination thereof. The polyurethane urea elastic fiber may be knitted on the entire surface, or may be knitted at a desired interval. It is also possible to insert polyurethane urea elastic fibers. The narrow knitted fabric of the present invention can be produced by a warp knitting machine such as a narrow raschel machine.

About the dyeing finish process of the narrow woven fabric or narrow knitted fabric of the present invention, the same process as that of the conventional narrow woven fabric or narrow knitted fabric can be used. Moreover, the process of providing a living machine set can also be employed.
The narrow woven fabric or the narrow knitted fabric in the present invention is obtained by washing the fabric obtained by cross-weaving the above polyurethane urea elastic fiber and / or the coated elastic yarn, the filament yarn and the spun yarn with water before dyeing. It is characterized by being heat treated at 90 ° C. to 200 ° C. after being dipped in a dyeing liquid corresponding to the yarn material. When the temperature of dry heat or wet heat is less than 90 ° C., a sufficient fixing force cannot be obtained after the heat treatment, and a long heat treatment time is required to increase the fixing force. When the heat treatment temperature exceeds 200 ° C., the stretchability and power, which are the characteristics of the stretchable fabric, are lost due to the high temperature treatment, and the characteristics as the stretchable fabric are lost. The product obtained is yellowed, and quality stability cannot be obtained due to the occurrence of stained spots. The same phenomenon occurs even after a long heat treatment. From the above, the dry heat or wet heat treatment temperature in the present invention is 90 to 200 ° C, preferably 120 to 195 ° C, and the treatment time is preferably 30 seconds to 5 minutes.

  If the knitting partner material is polyamide fiber, a soaping process or a fixing process may be performed. If the knitting partner material is a polyester fiber, a reduction cleaning treatment and a soaping treatment may be performed. Furthermore, you may give the weight reduction process normally processed with a polyester fiber. If the mating partner material is cotton, an exposure step with hydrogen peroxide may be performed. As described above, the narrow woven fabric or the narrow knitted fabric of the present invention can be subjected to various treatments according to the knitting partner material in order to improve the fastness and texture of the obtained fabric. Moreover, you may give the post-processing normally given, for example, a softening agent process, a water absorption process, etc.

  As described above, the narrow woven fabric or the narrow knitted fabric of the present invention is difficult to break the cut edge due to the adhesive strength of the polyurethane urea fiber that has been subjected to heat treatment of dry heat or wet heat, and can be sewn as a material such as a brassiere. Sometimes it is not necessary to clean up the edges, which can contribute to simplification of the sewing process. Further, the polyurethane urea elastic fiber can suppress the occurrence of slip-in by increasing the pulling resistance from the narrow woven fabric or the narrow knitted fabric.

The present invention will be described below based on examples, but the present invention is not limited to this range. Various evaluation methods for evaluating the performance of polyurethane urea elastic fibers, narrow knitted fabrics and clothing are described below.
(1) Compression deformation start temperature by thermomechanical analysis (TMA) Polyurethane urea elastic fiber (Comparative Example 2 is polyurethane-urethane elastic fiber) is dried with petroleum ether after removing the oil agent, dissolved in dimethylacetamide to 20% Make a solution. This solution is cast uniformly on a glass plate with a thickness of 0.6 mm using an applicator. At 70 ° C. for 16 hours, dimethylacetamide is removed by drying to obtain a film having a thickness of about 0.12 mm.
The film was heated at a rate of 10 ° C./min from room temperature under a constant load of indentation probe diameter φ1.2 mm and 5 g in a compression mode of a thermomechanical analyzer (Seiko Electronics Co., Ltd. TMA / SS120 type). Let The temperature at the inflection point at which the expansion occurs due to the temperature rise, but shifts from the expansion to the compression deformation due to indentation, is defined as the compression deformation start temperature.

(2) Thermal cutting seconds The polyurethaneurea elastic fiber having an initial length of 14 cm (Comparative Example 2 is polyurethane-urethane elastic fiber) is stretched by 50% to 21 cm, and pressed against a cylindrical heating element having a surface temperature of 180 ° C. and a diameter of 6 cm. A contact (contact part 1 cm) and the number of seconds until cutting is measured.

(3) Differential scanning calorimetry (DSC) of polyurethane compounds
About 10 mg of a polyurethane compound is measured from 20 ° C. to 300 ° C. with a differential scanning calorimeter (DSC210 type, manufactured by Seiko Denshi Kogyo Co., Ltd.) under a flow of nitrogen of 50 ml / min at a rate of temperature increase of 10 ° C./min. .

(4) Recovery rate at the time of recovery of elongation of 300% raw yarn Polyurethane urea elastic fiber (Comparative Example 2 is polyurethane-urethane elastic fiber), a tensile tester (UTM-III-100 type (trademark) manufactured by Orientec Co., Ltd.) When set in a tensile tester with an initial length of 5 cm in an atmosphere of 20 ° C. and 65% RH, and when the elongation / recovery up to 300% elongation is repeated three times at a rate of 1000% / min, the third recovery When the elongation rate at which the stress sometimes becomes 0 is defined as H (%), the recovery rate L (%) = 100−H.

(5) Hardness A flat test piece having a thickness of 6 mm or more of the polyurethane compound is prepared and measured by a method using a durometer (hardness tester) described in JIS-K7311.

(6) Evaluation of unraveling of the fabric A test piece cut in a warp direction of 10 cm along the weft direction opposite to the dyeing of the obtained narrow woven knitted fabric was made by Kao Corporation with 30 L of water in a washing machine. Wash as 15 minutes / time in a washing machine containing 20 g of detergent Attack ™. The test piece is taken out every five times to check whether or not the edge of the test piece is unraveled, and determined by the number of washing repetitions until unraveling occurs.

(7) Slip-in property of the fabric The test piece cut in the warp direction 10cm along the weft direction of the obtained narrow woven knitted fabric is stretched 80% with a dematcher and repeated 10,000 times. Thereafter, the slip-in amount L = 100-A is determined from the length A (mm) of the polyurethane urea elastic fiber (Comparative Example 2 is polyurethane-urethane elastic fiber).

(8) Recovery rate at 80% elongation recovery of fabric Dyeing up of the obtained narrow woven fabric or narrow knitted fabric was performed using a tensile testing machine (UTM-III-100 type (trademark) manufactured by Orientec Co., Ltd.). When set in a tensile tester with a fabric width of 2.5 cm and an initial length of 10 cm under an atmosphere of 20 ° C. and 65% RH, and repeating elongation and recovery up to an elongation of 80% three times at a speed of 300 mm / min, When the elongation rate at which the stress becomes 0 at the third recovery is H ′ (%), the recovery rate L ′ (%) = 100−H ′.

[Example 1]
A polytetramethylene ether glycol (PTMG) having a number average molecular weight of 2000 is reacted with 1.6 times equivalent of 4,4′-diphenylmethane diisocyanate (MDI) at 80 ° C. for 3 hours under stirring in a dry nitrogen atmosphere. Thus, a polyurethane prepolymer whose ends were capped with an isocyanate was obtained. After cooling to room temperature, dimethylacetamide was added and dissolved to obtain a polyurethane prepolymer solution.
On the other hand, a solution in which ethylenediamine (EDA) and diethylamine are dissolved in dry dimethylacetamide is prepared and added to the prepolymer solution at room temperature to obtain a polyurethane solid content concentration of 30% by weight and a viscosity of 450 Pa · s (30 ° C.). A polyurethane urea polymer solution PA1 was obtained.

  Separately, a polytetramethylene ether glycol having a number average molecular weight of 2000 is reacted with 3.0 times equivalent of 4,4′-diphenylmethane diisocyanate under stirring in a dry nitrogen atmosphere at 80 ° C. for 3 hours. Is a polyurethane prepolymer capped with an isocyanate. 1,5-butanediol (1,4-BD) equivalent to 0.95 times equivalent to the isocyanate group in the prepolymer was added to the prepolymer, reacted, and then heated at 80 ° C. for 16 hours to obtain a hardness of 80A. In the DSC, a polyurethane compound having no endothermic peak between 80 ° C. and the decomposition start temperature (282 ° C.) was obtained. Dimethylacetamide was added thereto to obtain a polyurethane solution PU1 having a solid content concentration of 30% by weight.

  The obtained polyurethane urea solution and polyurethane solution were mixed at PA1: PU1 = 80: 20, and 4,4′-butylidenebis (3-methyl-6-t-butylphenol) was added to the solid content of the polyurethane urea and polyurethane. 1% by weight and 2- (2′-hydroxy-3′-tert-butyl-5′-methylphenyl) -5-chlorobenzotriazole 0.5% by weight were mixed with the polyurethane solution to obtain a uniform solution. Thereafter, the mixture was defoamed under reduced pressure at room temperature to obtain a spinning dope.

  This spinning dope is dry-spun at a spinning speed of 800 m / min and a hot air temperature of 310 ° C. Before the resulting polyurethaneurea elastic fiber is wound into a package, 80% by weight of polydimethylsiloxane and 18% by weight of mineral oil are used as finishing agents. % And magnesium stearate 2% by weight was applied to polyurethane elastic fiber 4% by weight, and wound on a paper tube to obtain 33 decitex / 3 filament polyurethane urea elastic fiber.

The bare yarn of polyurethane urea elastic fiber obtained above is Df3.5, 200T / M, single covering yarn wound with nylon 56 dtex / 17 filament in a single layer is used as warp, nylon 78 dtex is used as weft, warp yarn A narrow-width woven fabric machine having a density of 50 / cm, a weft density of 61 / cm, and a width of 16 mm was prepared.
The resulting narrow-width woven fabric machine was continuously scoured at 80 ° C. and continuously dyed with an acid dye at 98 ° C., and then treated at a dry heat temperature of 180 ° C. for 3 minutes. Subsequently, it was washed with water, soaped, and fixed, and dried with a hollow drum at 110 ° C. to obtain a dyeing finish.

[Example 2]
Instead of the polyurethane solution PU1 of Example 1, 2.4 times equivalent of 4,4′-diphenylmethane diisocyanate with respect to polytetramethylene ether glycol having a number average molecular weight of 2000 was added at 80 ° C. for 3 hours under a dry nitrogen atmosphere. The reaction is carried out under stirring to give a polyurethane prepolymer end-capped with an isocyanate. After adding 1.0 times equivalent 1,4-BD to the prepolymer and reacting with the isocyanate group in the prepolymer, 3% by weight of the amount of 4,4′-diphenylmethane diisocyanate added first was further added. In addition to the reaction solution, the mixture was uniformly heated at 80 ° C. for 60 hours to obtain a polyurethane compound having a hardness of 75 A and a DSC having no endothermic peak from 80 ° C. to the decomposition start temperature (253 ° C.). Dimethylacetamide was added thereto to obtain a polyurethane solution PU2 having a solid concentration of 30% by weight.
The obtained polyurethane solution was mixed at PA1: PU2 = 80: 20, and 33 decitex / 3 filament polyurethane urea elastic fiber was obtained in the same manner as in Example 1.
Using the resulting polyurethaneurea elastic fiber, a dyed fabric of a narrow woven fabric was obtained in the same manner as in Example 1.

[Example 3]
A polyurethane urea elastic fiber having 33 dtex / 3 filaments was obtained in the same manner as in Example 1 except that the polyurethane urea solution and the polyurethane solution were mixed at PA1: PU2 = 65: 35. In the same manner as above, a dyeing fabric for a narrow fabric was obtained.

[Example 4]
Instead of the polyurethane solution PU1 of Example 1, a copolymerized polyether consisting of a tetramethylene group having a number average molecular weight of 2000 and a 2,2-dimethylpropylene group, wherein the molar fraction of the 2,2-dimethylpropylene group is 10 mol% 2.4 times equivalent of 4,4′-diphenylmethane diisocyanate to glycol is reacted under stirring in a dry nitrogen atmosphere at 80 ° C. for 3 hours to obtain a polyurethane prepolymer end-capped with isocyanate. 1,5-BD equivalent 0.95 times equivalent to the isocyanate group in the prepolymer was added to the prepolymer and reacted in the same manner, with a hardness of 77 A, DSC from 80 ° C. to the decomposition start temperature (264 ° C.). A polyurethane compound having no endothermic peak was obtained. Dimethylacetamide was added thereto to obtain a polyurethane solution PU3 having a solid content concentration of 30% by weight.
The obtained polyurethane solution was mixed at PA1: PU3 = 80: 20 to obtain 33 decitex / 3 filament polyurethane urea elastic fiber in the same manner as in Example 1, and then in the same manner as in Example 1, a narrow fabric. I got anti-dyeing.

[Example 5]
Instead of the polyurethane solution PU1 of Example 1, 3.0 times equivalent of 4,4′-diphenylmethane diisocyanate to polybutylene adipate diol having a number average molecular weight of 1000 was stirred at 80 ° C. for 3 hours under a dry nitrogen atmosphere. Reacting below gives a polyurethane prepolymer end-capped with an isocyanate. 1,5-BD equivalent 0.95 times equivalent to the isocyanate group in the prepolymer was added to the prepolymer and reacted in the same manner. Hardness 66A, DSC from 80 ° C. to decomposition start temperature (302 ° C.) A polyurethane compound having no endothermic peak was obtained. Dimethylacetamide was added thereto to obtain a polyurethane solution PU4 having a solid content concentration of 30% by weight.
The obtained polyurethane solution was mixed at PA1: PU4 = 80: 20 to obtain a 33 decitex / 3 filament polyurethane urea elastic fiber in the same manner as in Example 1, and then in the same manner as in Example 1, a narrow fabric I got anti-dyeing.

[Example 6]
In Example 2, instead of polytetramethylene glycol having a number average molecular weight of 2000, a copolymerized polyether glycol consisting of a tetramethylene group having a number average molecular weight of 2000 and a 2,2-dimethylpropylene group (of 2,2-dimethylpropylene group) A polyurethane urea polymer solution PA2 obtained in the same manner except that the copolymerization rate was 10 mol% was obtained. A polyurethane elastic fiber of 33 dtex / 3 filament was obtained in the same manner as in Example 2 except that this polyurethane urea polymer solution PA2 was used instead of the polyurethaneurea polymer solution PA1, and then the same as in Example 1. , Anti-dyeing of narrow fabric was obtained.

[Example 7]
After mixing PA2 used in Example 6 and PU3 used in Example 4 at PA2: PU3 = 80: 20, a polyurethane urea elastic fiber having 33 dtex / 3 filaments was obtained in the same manner as in Example 1. In the same manner as in Example 1, a dyeing finish of a narrow woven fabric was obtained.

[Example 8]
In Example 1, the obtained narrow-width woven fabric machine was subjected to a wet-heat treatment at 110 ° C. for 3 minutes under wet heat instead of dry heat treatment, and a dyeing process for a narrow-width woven fabric was obtained in the same manner as in Example 1. .

[Example 9]
Using a double raschel knitting machine (12 gauge, working width 70 inches) manufactured by Yamamoto Machine Co., Ltd., producing stretchable double raschel string by chain knitting at 60 rpm rotation, 9 courses / inch knitting course, and 2 sheets did.
Both of the yarn supplied to the front heel L1 and the yarn supplied to the back heel L2, a coated elastic yarn in which the polyurethane false fiber 33 dtex / 3 filament obtained in Example 1 is wound once with a nylon false twisted yarn 78 dtex, A yarn in which nylon false twisted yarn 330 dtex was aligned was supplied.
In addition, two scissors (L1 and L2) were used for one complete structure, and a chain structure was alternately knitted on the knitting needles of the front and rear two-row needle beds by swinging the front, back, left and right of the scissors. The knot of the chain of the double-row needle bed is such that L1 and L2 move back and forth alternately so that L1 is knitted with the front needle and then the guide is swung to the position of the next adjacent needle for connection. Then, it was knitted into a three-dimensional string-like structure to obtain a double raschel narrow-width knitted fabric production machine.
The obtained narrow knitting raw machine was continuously scoured at 80 ° C. and continuously dyed with an acid dye at 98 ° C., and then treated at a dry heat temperature of 180 ° C. for 3 minutes. Subsequently, it was washed with water, soaped and fixed, and dried with a hollow drum at 110 ° C. to obtain a dyeing finish.

[Comparative Example 1]
Except for not adding the polyurethane compound PU1, in the same manner as in Example 1 (each additive was added in an amount relative to the solid content of PA1), after obtaining 33 decitex / 3-filament polyurethane urea elastic fiber, the same as in Example 1. As a result, a dyeing process for a narrow fabric was obtained.

[Comparative Example 2]
After the polyurethane-urethane elastic fiber of 33 dtex / 3 filament was obtained in the same manner as in Example 2 except that the polyurethaneurea polymer PA1 was not added (each additive was added in an amount relative to the solid content of PU2), Example 1 was obtained. In the same manner as above, a dyeing process of a narrow woven fabric was obtained.

[Comparative Example 3]
Instead of the polyurethane solution PU1 of Example 1, 5.1 times equivalent of 4,4′-diphenylmethane diisocyanate with respect to polytetramethylene ether glycol having a number average molecular weight of 2000 was added at 80 ° C. for 3 hours under a dry nitrogen atmosphere. After reacting under stirring to make a polyurethane prepolymer end-capped with an isocyanate, 1,4-butanediol was added to the prepolymer and reacted, from a decomposition start temperature (290 ° C.) at a hardness of 90 A and DSC. A polyurethane compound having an endothermic peak at a low 230 ° C. was obtained. Dimethylacetamide was added thereto to obtain a polyurethane solution PU5 having a solid content concentration of 30% by weight.
The obtained polyurethane solution was mixed at PA1: PU5 = 80: 20 to obtain a 33 dtex / 3 filament polyurethane elastic fiber in the same manner as in Example 1, and then a dyed fabric of a narrow woven fabric was obtained.
Table 1 shows the composition in each of the above Examples and Comparative Examples, and Table 2 shows the performance of the obtained polyurethane urea elastic fiber and the performance of the obtained narrow woven fabric.

  The narrow woven fabric or narrow knitted fabric using the polyurethane urea elastic fiber produced by the present invention is suppressed from slip-in and unraveling due to heat during processing, and the side line and suspender of sports clothing, the strap and inside of the inner clothing It is useful in applications such as belts, medical supporters and corsets.

Claims (4)

  The polyurethane compound is contained in an amount of 5% to 40% by weight, the compression deformation starting temperature by thermomechanical analysis (TMA) is 150 ° C. or higher and 180 ° C. or lower, and the thermal cutting time at 180 ° C. is 50% under extension. A narrow-width woven or knitted fabric comprising polyurethane urea elastic fibers of 30 seconds or longer at least partially.   The narrow woven or knitted fabric according to claim 1, wherein the polyurethane urea is made from a polyalkylene ether diol composed of one or more alkylene ethers having 2 to 10 carbon atoms.   The narrow woven or knitted fabric according to claim 1 or 2, wherein the polyurethane compound is made from a polyalkylene ether diol composed of one or more alkylene ethers having 2 to 10 carbon atoms.   A polyurethane compound is contained in an amount of 5 to 40% by weight, the compression deformation starting temperature by thermomechanical analysis (TMA) is 150 ° C. or higher and 180 ° C. or lower, and the thermal cutting time at 180 ° C. is 30% under 50% elongation. A method for producing a narrow-width woven knitted fabric, characterized in that, after weaving or knitting at least part of polyurethaneurea elastic fibers of at least a second, heat treatment is performed at 90 ° C to 200 ° C with dry heat or wet heat.