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JP2008266562A - Detergent comprising mixture of at least four components and water, mainly for removing solid deposit from drinking-water piping - Google Patents

Detergent comprising mixture of at least four components and water, mainly for removing solid deposit from drinking-water piping Download PDF

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JP2008266562A
JP2008266562A JP2007301861A JP2007301861A JP2008266562A JP 2008266562 A JP2008266562 A JP 2008266562A JP 2007301861 A JP2007301861 A JP 2007301861A JP 2007301861 A JP2007301861 A JP 2007301861A JP 2008266562 A JP2008266562 A JP 2008266562A
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water
mixture
components
mass
cleaning agent
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JP4971112B2 (en
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Moesslein Guenter
メスライン ギュンター
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FLORAN GmbH
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/261Alcohols; Phenols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/34Organic compounds containing sulfur
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/36Organic compounds containing phosphorus

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cleaning By Liquid Or Steam (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a mixture comprising such several components in an aqueous solution as to be observed in the proportion among specified components, which mixture brings about at least consistently effective detergency in combination of a publicly known substance with the still unknwoun substance to an expected use and makes no attack against the inside wall of metal piping and has a high-degree adaptability to the environment and no health risk arises from the vapor which might yield, which is different from the case of a detergent containing HCl, and is manufactured by simply and inexpensively. <P>SOLUTION: The detergent comprising a mixture of at least four components and water for the purpose of removing solid deposits from drinking-water piping, is characterized by containing 1-14% by mass of a sulfamic acid, 5-10% by mass of methane sulfonic acid, 0.075-0.15% by mass of phosphonobutane-tricarboxylic acid, 0.3% by mass of 2-propanol, and a soft water in an amount necessary to come up to 100%. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、飲料水配管から固形沈積物(鉄閉塞(iron cloggings))を除去することを主たる目的とする、少なくとも4種の成分と水との混合物からなり、そこに追加の水を添加することができる洗浄剤に関する。   The present invention consists of a mixture of at least four components and water, with the primary purpose of removing solid deposits (iron cloggings) from drinking water piping, to which additional water is added. It relates to a cleaning agent.

金属製の飲料水配管は、圧送出力が一定に保たれても圧力変動が生じて、水の流速に変動がもたらされる理由を突き止めるために定期的に検査せねばならないことは知られている。   It is known that metal drinking water piping must be periodically inspected to find out why pressure fluctuations occur and the fluctuations in the water flow rate occur even if the pumping power is kept constant.

比較的迅速に直すことができる季節的な条件による損傷とは別に、一つの主要な問題は、上述した飲料水配管の内径の減少である。このことが生ずる率は、配管を流れる飲料水の水質によって左右され、かつそれは"鉄閉塞"と呼ばれるものによって引き起こされる。現在利用可能な方法では、これらの沈積物は、公知の装置(配管スクレーパ)を使用して、機械的洗浄、超音波洗浄もしくは化学的洗浄によって、又は配管に洗浄溶液を流すことによって効果的に除去することができるに過ぎず、それは配管系の複数の区間に閉塞を引き起こす。   Apart from damage due to seasonal conditions that can be repaired relatively quickly, one major problem is the reduction in the inner diameter of the drinking water piping described above. The rate at which this occurs depends on the quality of the drinking water flowing through the pipe, and it is caused by what is called "iron blockage". In currently available methods, these deposits are effectively removed using known equipment (pipe scrapers) by mechanical cleaning, ultrasonic cleaning or chemical cleaning, or by flowing a cleaning solution through the piping. It can only be removed and it causes blockage in multiple sections of the piping system.

適切な例は、DE60016414号T2とWO01/42148号A1で提案される解決策であり、その両方は、公知の複数の個々の成分を水溶液において様々に組み合わせることを提案している。固形沈積物は、その溶液を適用して流し去るといった簡単な手段によって除去される。これらの基礎材料は比較的高価であり、また適用と廃棄に費用がかかるので、これらの欠点を克服する代替手段を探さねばならない。   A suitable example is the solution proposed in DE 60016414 T2 and WO 01/42148 A1, both of which propose various combinations of known individual components in aqueous solution. Solid deposits are removed by simple means such as applying the solution and flushing away. Since these base materials are relatively expensive and expensive to apply and dispose of, alternative means to overcome these drawbacks must be sought.

他方、多くの場所で依然として、塩酸(HCl)は、濃縮された形態で、消毒剤、例えば過酸化水素もしくは過酢酸と組み合わせて使用されている。前記の物質混合物がはらむ最大の欠点は、数年後に金属製の配管が非常にひどく腐蝕するので、配管を交換せねばならないということである。   On the other hand, hydrochloric acid (HCl) is still used in concentrated form in combination with disinfectants such as hydrogen peroxide or peracetic acid. The biggest drawback of the substance mixture is that the metal pipes are very badly corroded after several years, so that the pipes must be replaced.

従って、飲料水システム中の金属製配管を維持するための、すなわち洗浄するための高価な物質混合物の製造及び使用と、あまり高価ではないが高い腐蝕作用を有するHClを用いた洗浄法との両方に取って代わる代替的な解決策を探さねばならない。提案される新たな解決策は、現段階の先行技術の欠点を克服することを目的とする。
DE60016414号T2 WO01/42148号A1
Thus, both the production and use of expensive substance mixtures for maintaining metal pipes in drinking water systems, i.e. for cleaning, and cleaning methods using less expensive but highly corrosive HCl. We have to look for alternative solutions to replace it. The proposed new solution aims to overcome the shortcomings of the prior art at this stage.
DE60016414 T2 WO01 / 42148 A1

従って本発明の目的は、公知の物質と予定された用途にまた知られていない物質とを組み合わせて少なくとも一貫して効果的な洗浄作用をもたらし、金属製配管の内壁を攻撃せず、環境との高度の適合性を有し、例えばHClを含有する洗浄剤と同様に生じうる蒸気からの如何なる健康リスクも有さず、かつ製造が簡単かつ廉価であるが、但し、規定された成分の割合が遵守される水溶液中の幾つかの成分からなる混合物を考え出すことである。   Accordingly, the object of the present invention is to combine known materials with materials that are not known for the intended use to at least consistently provide an effective cleaning action, without attacking the inner walls of metal pipes, With a high degree of compatibility, for example, without any health risks from vapors that can occur as well as cleaning agents containing HCl, and simple and inexpensive to manufacture, provided that the proportion of specified ingredients Is to come up with a mixture of several components in an aqueous solution where

前記目的は、飲料水配管から固形沈積物を除去するための、互いに混合でき、均質かつ安定な少なくとも4種の成分と水との混合物からなる洗浄剤において、当該洗浄剤が、1〜14質量%のスルファミン酸と、5〜10質量%のメタンスルホン酸と、0.075〜0.15質量%のホスホノブタン−トリカルボン酸と、0.3質量%の2−プロパノールと、100%までの軟水とを含有することを特徴とする、少なくとも4種の成分と水との混合物からなる洗浄剤により実現される。   The purpose is to remove solid deposits from the drinking water piping and to mix with each other, and to comprise a homogeneous and stable mixture of at least four components and water. % Sulfamic acid, 5-10% by weight methanesulfonic acid, 0.075-0.15% by weight phosphonobutane-tricarboxylic acid, 0.3% by weight 2-propanol, and up to 100% soft water It is realized by a cleaning agent comprising a mixture of at least four components and water.

本発明に関連する基本概念の詳細については、請求項1に参照がなされるべきである。本発明の更なる詳細は、請求項2(請求項1記載の少なくとも4種の成分と水との混合物からなる洗浄剤において、当該洗浄剤が、1〜10質量%の消毒剤が添加された場合に、消毒作用を有することを特徴とする、少なくとも4種の成分と水との混合物からなる洗浄剤。)及び請求項3(請求項2記載の少なくとも4種の成分と水との混合物からなる洗浄剤において、過酸化水素又は過酸化水素を含む物質、例えば過酢酸を、消毒剤として使用することを特徴とする、少なくとも4種の成分と水との混合物からなる洗浄剤。)に示されている。更なる詳細は、本発明がいかにしてそれらの目的を果たしたかをたどるべきである。   Reference should be made to claim 1 for details of the basic concepts relevant to the present invention. Further details of the present invention are as follows. Claim 2 (In the cleaning agent comprising a mixture of at least four components according to claim 1 and water, 1 to 10% by mass of a disinfectant was added to the cleaning agent. A cleaning agent comprising a mixture of at least four components and water, characterized by having an antiseptic action, and claim 3 (from a mixture of at least four components and water according to claim 2) A cleaning agent comprising a mixture of at least four components and water, characterized in that hydrogen peroxide or a substance containing hydrogen peroxide, such as peracetic acid, is used as a disinfectant. Has been. Further details should follow how the present invention served their purpose.

先行技術に従って現在利用可能な洗浄溶液の1つである塩酸、つまりHClは、溶解された固体を除去する効力を完全に満たす調製物によって完全に置き換えられることが立証された。また、そのことは、同様に使用できる他の無機酸にも当てはまる。   One of the cleaning solutions currently available in accordance with the prior art, HCl, has been demonstrated to be completely replaced by a preparation that fully satisfies the efficacy of removing dissolved solids. This is also true for other inorganic acids that can be used as well.

スルファミン酸、メタンスルホン酸、ホスホン酸(ホスホノブタン−トリカルボン酸)、2−プロパノール及び軟水は、固形沈積物(鉄閉塞)及びCaCO3沈積物を除去し、かつ同時に水溶液中で幾つかの個々の成分からなる洗浄性混合物を製造するために特に適した物質である。 Sulfamic acid, methanesulfonic acid, phosphonic acid (phosphonobutane-tricarboxylic acid), 2-propanol and soft water remove solid deposits (iron clogs) and CaCO 3 deposits and at the same time several individual components in aqueous solution It is a particularly suitable material for producing a detersive mixture consisting of

上述の成分を混合して、以下に示される百分率質量:
スルファミン酸、つまりH3NO3S 1%〜14%
メタンスルホン酸 5%〜10%
ホスホノブタン−トリカルボン酸、つまりC7119P 0.075%〜0.15%
2−プロパノール 0.3%
軟水 100%まで
の限界内ですぐに使用可能な溶液を形成させることができる。
Mixing the above ingredients, the percentage mass shown below:
Sulfamic acid, that is, H 3 NO 3 S 1% to 14%
Methanesulfonic acid 5% -10%
Phosphonobutane-tricarboxylic acid, that is, C 7 H 11 O 9 P 0.075% to 0.15%
2-propanol 0.3%
Soft water A ready-to-use solution can be formed within the limits of up to 100%.

従って、本発明を、好適な実施例をもって説明する。   Accordingly, the present invention will be described with a preferred embodiment.

この実施例において、上述した成分の質量割合は、以下のとおりである:
スルファミン酸 5%
メタンスルホン酸 5%
ホスホノブタン−トリカルボン酸 0.15%
2−プロパノール 3%
軟水 89.55%
更にまた、該洗浄剤は、そこに過酸化水素、C22又は過酸化水素を含む物質、例えば過酢酸といった成分を添加することによって、付加的な通常のもしくは同時の消毒機能を果たすこともできる。また、該洗浄剤は、貯水タンクなどの周辺飲料水プラントを処理するために使用してもよい。
In this example, the mass proportions of the components described above are as follows:
Sulfamic acid 5%
Methanesulfonic acid 5%
Phosphonobutane-tricarboxylic acid 0.15%
2-propanol 3%
Soft water 89.55%
Furthermore, the cleaning agent performs an additional normal or simultaneous disinfection function by adding to it a component containing hydrogen peroxide, C 2 H 2 or hydrogen peroxide, eg peracetic acid. You can also. The cleaning agent may also be used to treat peripheral drinking water plants such as water storage tanks.

提案された洗浄剤の利点は、以下のようにまとめることができる:
当該洗浄剤は、飲料水配管中の全ての公知の固形沈積物を溶解する。
The advantages of the proposed cleaning agent can be summarized as follows:
The cleaning agent dissolves all known solid deposits in the drinking water piping.

当該洗浄剤は、生物学的被膜を破壊する。   The cleaning agent destroys the biological coating.

健康を害する塩素ガスを発生しない。   Does not generate chlorine gas that is harmful to health.

当該洗浄剤は、亀裂が形成された金属製もしくはプラスチック製の配管又はセラミック製の配管の内壁を腐蝕しない。   The cleaning agent does not corrode the inner wall of the cracked metal or plastic pipe or ceramic pipe.

当該洗浄剤は、生分解性であり、環境に優しい製品である。   The cleaning agent is a biodegradable and environmentally friendly product.

当該洗浄剤は、定められた間隔で洗浄する必要がある飲料水配管と、他の飲料水プラント、特に金属製の周辺タンクの耐用寿命を延長する。   The cleaning agent extends the service life of drinking water piping and other drinking water plants that need to be cleaned at defined intervals, especially metal peripheral tanks.

Claims (3)

飲料水配管から固形沈積物を除去するための、互いに混合でき、均質かつ安定な少なくとも4種の成分と水との混合物からなる洗浄剤において、当該洗浄剤が、1〜14質量%のスルファミン酸と、5〜10質量%のメタンスルホン酸と、0.075〜0.15質量%のホスホノブタン−トリカルボン酸と、0.3質量%の2−プロパノールと、100%までの軟水とを含有することを特徴とする、少なくとも4種の成分と水との混合物からなる洗浄剤。   In a cleaning agent comprising a mixture of at least four kinds of components that can be mixed with each other, homogeneous and stable, and water for removing solid deposits from drinking water piping, the cleaning agent is 1 to 14% by mass of sulfamic acid. And 5-10 mass% methanesulfonic acid, 0.075-0.15 mass% phosphonobutane-tricarboxylic acid, 0.3 mass% 2-propanol, and up to 100% soft water. A cleaning agent comprising a mixture of at least four components and water. 請求項1記載の少なくとも4種の成分と水との混合物からなる洗浄剤において、当該洗浄剤が、1〜10質量%の消毒剤が添加された場合に、消毒作用を有することを特徴とする、少なくとも4種の成分と水との混合物からなる洗浄剤。   The cleaning agent comprising a mixture of at least four components and water according to claim 1, wherein the cleaning agent has a disinfecting action when 1 to 10% by mass of a disinfectant is added. A cleaning agent comprising a mixture of at least four components and water. 請求項2記載の少なくとも4種の成分と水との混合物からなる洗浄剤において、過酸化水素又は過酸化水素を含む物質、例えば過酢酸を、消毒剤として使用することを特徴とする、少なくとも4種の成分と水との混合物からなる洗浄剤。   A cleaning agent comprising a mixture of at least four components and water according to claim 2, characterized in that hydrogen peroxide or a substance containing hydrogen peroxide, such as peracetic acid, is used as a disinfectant. A detergent consisting of a mixture of seed components and water.
JP2007301861A 2007-04-16 2007-11-21 A cleaning agent comprising a mixture of at least four components and water, the main purpose of which is to remove solid deposits from drinking water piping. Expired - Fee Related JP4971112B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE200720005731 DE202007005731U1 (en) 2007-04-16 2007-04-16 Mixture of a cleaning agent consisting of at least 4 components and water to remove, in particular, solid deposits in drinking water pipes
DE202007005731.8 2007-04-16

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JP2008266562A true JP2008266562A (en) 2008-11-06
JP4971112B2 JP4971112B2 (en) 2012-07-11

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015137289A (en) * 2014-01-21 2015-07-30 深江商事株式会社 Cleaning kit and cleaning method
CN111117800A (en) * 2019-12-26 2020-05-08 南京巨鲨显示科技有限公司 Biological membrane removing cleaning agent and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102015117955B4 (en) * 2015-10-21 2019-05-09 Witty Gmbh & Co. Kg Process for cleaning and disinfecting drinking water tanks

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JPS606798A (en) * 1983-06-24 1985-01-14 栗田工業株式会社 Drinking water-based cleaning composition
JPH0673573A (en) * 1991-11-23 1994-03-15 Fmc Corp Uk Ltd Corrosion- and/or scale-preventive composition
JPH10130783A (en) * 1996-10-28 1998-05-19 Kawasaki Steel Corp Non-heat treated high strength seamless steel tube
US6346217B1 (en) * 1999-06-02 2002-02-12 Water Whole International, Inc. Composition and method for cleaning drink water tanks
JP2003027096A (en) * 2001-07-13 2003-01-29 Niitaka:Kk Aqueous detergent for silverware
JP2005154551A (en) * 2003-11-25 2005-06-16 Amtec Co Ltd Sterilizing cleanser composition

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS606798A (en) * 1983-06-24 1985-01-14 栗田工業株式会社 Drinking water-based cleaning composition
JPH0673573A (en) * 1991-11-23 1994-03-15 Fmc Corp Uk Ltd Corrosion- and/or scale-preventive composition
JPH10130783A (en) * 1996-10-28 1998-05-19 Kawasaki Steel Corp Non-heat treated high strength seamless steel tube
US6346217B1 (en) * 1999-06-02 2002-02-12 Water Whole International, Inc. Composition and method for cleaning drink water tanks
JP2003027096A (en) * 2001-07-13 2003-01-29 Niitaka:Kk Aqueous detergent for silverware
JP2005154551A (en) * 2003-11-25 2005-06-16 Amtec Co Ltd Sterilizing cleanser composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015137289A (en) * 2014-01-21 2015-07-30 深江商事株式会社 Cleaning kit and cleaning method
CN111117800A (en) * 2019-12-26 2020-05-08 南京巨鲨显示科技有限公司 Biological membrane removing cleaning agent and preparation method thereof

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DE202007005731U1 (en) 2007-09-20

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