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JP2008195633A - Pretreating agent for permanent wave treatment - Google Patents

Pretreating agent for permanent wave treatment Download PDF

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Publication number
JP2008195633A
JP2008195633A JP2007030519A JP2007030519A JP2008195633A JP 2008195633 A JP2008195633 A JP 2008195633A JP 2007030519 A JP2007030519 A JP 2007030519A JP 2007030519 A JP2007030519 A JP 2007030519A JP 2008195633 A JP2008195633 A JP 2008195633A
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Prior art keywords
hair
permanent
wave
permanent wave
rod
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Inventor
Chiemi Konakawa
千絵美 粉川
Shinichi Matsuda
進一 松田
Keiichi Hosoya
佳一 細谷
Osamu Kamegamori
統 亀ヶ森
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NUUSU FIT KK
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NUUSU FIT KK
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Priority to JP2007030519A priority Critical patent/JP2008195633A/en
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Abstract

<P>PROBLEM TO BE SOLVED: To improve the wave efficiency in a permanent wave treatment of water-curling style free from the hand roughening trouble of the operator. <P>SOLUTION: The pretreating composition for permanent wave or curl treatment contains a lactone compound. The wave efficiency of permanent wave treatment is improved by the use of the pretreating agent. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、パーマネント前処理剤及び該前処理剤を用いたパーマネント方法に関する。   The present invention relates to a permanent pretreatment agent and a permanent method using the pretreatment agent.

一般的に「パーマ」と言われる理美容室における技術に用いられる薬剤には、医薬部外品であるパーマネントウェーブ用剤あるいは縮毛矯正剤と、化粧品の範疇に入るカール剤(カール料とも呼ばれる)があり(以下総称して「パーマネント用薬剤」という。)、どちらも毛髪を望みの形状に変形させるために、まず毛髪を還元剤を主たる成分とする薬剤で軟化させた後、酸化剤を主たる成分とする薬剤で固定する方法をとる。
理美容室におけるパーマネント方法には、主に、つけ巻(パーマネントウェーブ用剤を塗布した毛髪をロッドに巻く方法)及び水巻(水で湿らせた毛髪をロッドに巻いて、次いで該ロッドに巻かれた毛髪にパーマネントウェーブ用剤を塗布する方法)がある。
つけ巻においては、毛髪はパーマネントウェーブ用剤が塗布された後にロッドに巻かれるので、毛髪のパーマネントのかかり強さ、即ちウェーブ効率は、つけ巻が、水巻よりも優れている。
しかしながら、つけ巻においては、パーマネント施術者は、しばしば作業効率を上げるために手袋を使用せずに素手で毛髪をロッドで巻く。従って、毛髪をロッドに巻く作業時間の間中パーマネント施術者の手にパーマネントウェーブ用剤が付着するので、該施術者の手の皮膚が激しく荒れるという問題があった。
一方、水巻においては、パーマネントウェーブ用剤が塗布された毛髪をロッドに巻く作業がないので、パーマネント施術者の手にパーマネントウェーブ用剤が付着しないものの、パーマネントのかかりが弱いとの欠点がある。
Drugs that are commonly used in hairdressing salon techniques called “perms” include permanent wave agents or curly hair straighteners that are quasi-drugs, and curling agents (also called curling agents) that fall within the category of cosmetics. (Hereinafter collectively referred to as “permanent agents”), in order to transform the hair into the desired shape, the hair is first softened with an agent containing a reducing agent as a main component, and then an oxidizing agent is added. A method of fixing with a drug as a main ingredient is taken.
Permanent methods in a hairdressing salon are mainly wrapping (a method in which hair coated with a permanent wave agent is wound around a rod) and water winding (wrapping hair dampened with water around a rod and then winding around the rod). There is a method of applying a permanent wave agent to hair.
In the false winding, the hair is wound around the rod after the permanent wave agent is applied, so that the permanent strength of the hair, that is, the wave efficiency, is superior to the water winding.
However, in wrapping, the permanent practitioner often winds the rod with bare hands without using gloves to increase work efficiency. Therefore, since the permanent wave agent adheres to the permanent practitioner's hand during the work time for winding the hair around the rod, the skin of the practitioner's hand is severely roughened.
On the other hand, in the case of water winding, there is no work of winding the hair coated with the permanent wave agent around the rod, so the permanent wave agent does not adhere to the hand of the permanent practitioner, but there is a drawback that the permanent wear is weak.

本発明の目的は、パーマネント作業においてパーマネント施術者の手荒れを生じさせないように、水巻の様式でもパーマネントのかかり強さを高める、即ちウェーブ効率を向上させるパーマネントウェーブ又はカール方法及びそのために有用なパーマネントウェーブ又はカール前処理剤を提供することである。   The object of the present invention is to increase the strength of the permanent even in the water winding mode, that is, to improve the wave efficiency so as not to cause the rough hand of the permanent practitioner in the permanent work, and the permanent wave useful therefor. Or to provide a curl pretreatment agent.

上記目的を達成するために本発明者らが鋭意検討を行った結果、ラクトン化合物を含むパーマネントウェーブ又はカール前処理用組成物を、水巻に使用する水の代わりに塗布した毛髪をロッドに巻き、次いで該ロッドに巻かれた毛髪に従来の一般的なパーマネントウェーブ又はカール用薬剤を塗布することにより、水巻よりもパーマネントウェーブ又はカールのかかり強さが高まり、更にパーマネント施術者の手荒れを生じさせないことを見出し、本発明を完成するに至った。
すなわち、本発明は、ラクトン化合物を含むことを特徴とするパーマネントウェーブ又はカール前処理用組成物を提供する。本発明は、また、該前処理用組成物を使用するパーマネントウェーブ又はカール方法であって、
(1)毛髪に該前処理用組成物を塗布する工程、
(2)該前処理用組成物を塗布された毛髪をロッドに巻く工程、
(3)該ロッドに巻かれた毛髪に還元剤を主たる成分とするパーマネントウェーブ又はカール用薬剤を塗布して放置する工程、及び
(4)該毛髪を洗髪する工程、
を含むことを特徴とする方法を提供する。
As a result of intensive studies by the present inventors in order to achieve the above-mentioned object, a hair obtained by applying a permanent wave or curl pretreatment composition containing a lactone compound to a rod instead of water used for a water roll, Next, by applying a conventional permanent wave or curling agent to the hair wound around the rod, the strength of permanent wave or curl is higher than that of water winding, and the permanent practitioner does not cause rough hands. As a result, the present invention has been completed.
That is, the present invention provides a permanent wave or curl pretreatment composition comprising a lactone compound. The present invention also provides a permanent wave or curl method using the pretreatment composition,
(1) A step of applying the pretreatment composition to hair,
(2) a step of winding the hair coated with the pretreatment composition around a rod;
(3) applying a permanent wave or curling agent containing a reducing agent as a main component to the hair wound around the rod and leaving it alone; and (4) washing the hair.
A method characterized by comprising:

本発明のパーマネントウェーブ又はカール前処理用組成物に用いられるラクトンとしては、好ましくは、炭素数3〜10のラクトン、更に好ましくはγラクトンが挙げられる。特に好ましくは、γ-バレロラクトン、DL-パントイン酸-γ-ラクトン、γ-ヘキサノラクトン及びγ-ブチロラクトンが挙げられるが、これに限定されない。
これらのラクトンの配合量としては、上記前処理用組成物全体に対して、5〜60質量%が好ましく、より好ましくは10〜50質量%である。
本発明の前処理用組成物の残部は水であるが、毛髪保護や感触の改善、ウェーブ又はカール形成効果の長期持続を目的として、油脂類、シリコーン類、ケラチン等タンパク質加水分解物又はその誘導体、多糖類又はその誘導体、多価アルコール類、ビニル系化合物やアクリル系化合物等の合成ポリマー、動植物抽出物、無機電解質、界面活性剤等を、適宜選択され配合してよい。
本発明の前処理用組成物の形態は任意であり、液状、ゲル状、気泡状、乳液状、クリーム状、軟膏状、ムース状、粉末分散状、エアゾール状等の形態を構成することができる。
具体的には、例えば、ヘアクリーム、ヘアスプレー、ヘアトニック、ヘアジェル、ヘアローション、ヘアオイル、ヘアエッセンス、ヘアウォーター、ヘアワックス、ヘアフォームなどが例示できる。
本発明の別の態様にとしては、本発明の前処理用組成物を使用するパーマネントウェーブ又はカール方法であって、
(1)毛髪に該前処理用組成物を塗布する工程、
(2)上記該前処理用組成物を塗布された毛髪をロッドに巻く工程、
(3)上記ロッドに巻かれた毛髪に還元剤を主たる成分とするパーマネントウェーブ又はカール用薬剤を塗布して放置する工程、及び
(4)上記毛髪を洗髪する工程、
を含むことを特徴とする方法である。
必要に応じて、工程(3)と(4)の間に以下の工程:
上記毛髪を水洗した後に、酸化剤を主たる成分とするパーマネントウェーブ又はカール用薬剤を上記毛髪に塗布して、パーマネントウェーブ又はカールを固定する工程、
を加えてよい。
本発明に使用されるロッドは、いかなるパーマネント用ロッドでよい。使用するパーマネントウェーブ又はカール用薬剤に対応する好適なロッドを選んでよい。
本発明の前処理用組成物と組み合わせて使用する事のできるパーマネント用薬剤は、一般的ないかなるパーマネント用薬剤でよい。酸性でもアルカリ性でもよく、具体的には、限定的でないが、アルカリ性条件下で実用的なチオグリコール酸やシステイン、アセチルシステインの塩類などの一般にケラチン還元物質ともいわれる化合物、又は中性から弱酸性条件下で実用的なメルカプトカルボン酸アルコキシエステルやブチロラクトンチオールなどのチオールラクトン化合物等が挙げられる。
パーマネント用薬剤を塗布してから放置する時間は、毛髪の状態に応じていかなる時間でもよい。
The lactone used in the permanent wave or curl pretreatment composition of the present invention is preferably a lactone having 3 to 10 carbon atoms, more preferably γ lactone. Particularly preferable examples include, but are not limited to, γ-valerolactone, DL-pantoic acid-γ-lactone, γ-hexanolactone, and γ-butyrolactone.
As a compounding quantity of these lactones, 5-60 mass% is preferable with respect to the said whole composition for pre-processing, More preferably, it is 10-50 mass%.
The balance of the pretreatment composition of the present invention is water, but for the purpose of protecting hair and improving touch, and maintaining the effect of forming waves or curls over a long period of time, protein hydrolysates such as fats and oils, silicones, keratin, or derivatives thereof Polysaccharides or derivatives thereof, polyhydric alcohols, synthetic polymers such as vinyl compounds and acrylic compounds, animal and plant extracts, inorganic electrolytes, surfactants, and the like may be appropriately selected and blended.
The form of the pretreatment composition of the present invention is arbitrary, and forms such as liquid, gel, foam, emulsion, cream, ointment, mousse, powder dispersion, and aerosol can be configured. .
Specifically, for example, hair cream, hair spray, hair tonic, hair gel, hair lotion, hair oil, hair essence, hair water, hair wax, hair foam and the like can be exemplified.
Another aspect of the present invention is a permanent wave or curl method using the pretreatment composition of the present invention,
(1) A step of applying the pretreatment composition to hair,
(2) a step of winding the hair coated with the pretreatment composition around a rod;
(3) A step of applying a permanent wave or curling agent containing a reducing agent as a main component to the hair wound around the rod, and (4) a step of washing the hair.
It is the method characterized by including.
If necessary, between the steps (3) and (4), the following steps:
After washing the hair with water, a permanent wave or curling agent mainly composed of an oxidizing agent is applied to the hair to fix the permanent wave or curl;
May be added.
The rod used in the present invention may be any permanent rod. A suitable rod may be selected that corresponds to the permanent wave or curling agent used.
The permanent agent that can be used in combination with the pretreatment composition of the present invention may be any general permanent agent. It may be acidic or alkaline. Specifically, but not limited to, compounds generally called keratin reducing substances such as thioglycolic acid, cysteine, and acetylcysteine salts that are practical under alkaline conditions, or neutral to weakly acidic conditions Below, practical examples include mercaptocarboxylic acid alkoxyesters and thiollactone compounds such as butyrolactone thiol.
The time to leave after applying the permanent agent may be any time depending on the condition of the hair.

以下、本発明について、具体的な実施例を示して説明するが、本発明はこれらに限定されるものではない。また、配合量は特に断らない限りmLで示す。
(実施例1〜8)
以下の表1は、使用したパーマネントウェーブ又はカール前処理用組成物(試料1〜8)の組成を示す。




表1

Figure 2008195633
[調製方法]
表1に記載の組成の各パーマネントウェーブ又はカール前処理用組成物を以下の手順で調製した。
室温において、100mLのバイアルに所定量の表1に記載のラクトン及び精製水を注ぎ、均質になるまで攪拌した。

[試験方法]
クセ毛でない直毛の日本人あるいは中国人の健康な黒色毛髪であって、黒毛(未処理毛)と2回ブリーチ毛(14トーン毛)の2種類の毛束(長さ30cm、1g)それぞれに表1に記載の試料1〜8の前処理用組成物0.13mLを塗布し、良くコーミングしてラップに包み室温放置した。次いで室温で5分間放置後、直径9mmのロッドに毛束を巻いて、パーマネントウェーブ用第1液0.39mLを塗布しラップで包み、15分間室温で放置した。1分間流水中でロッドに巻かれた状態の毛束を水洗して、軽く水気を切った後、パーマネントウェーブ用第2液0.39mlを塗布し、15分間室温放置した。1分間流水中で水洗した後、ロッドをはずして、毛束の水気を軽く切り、毛束を吊るした。
パーマネントウェーブ用第1液として使用したチオパーマ第1液及びシステインパーマ第1液、パーマネントウェーブ用第2液として使用したチオパーマ第2液及びシステインパーマ第2液の組成を表2に示す。
表2
Figure 2008195633
[評価方法]
上記試験の手順に従ってパーマネントをかけた毛束のウェーブ1波長の長さ(単位:cm)測定して表3に示した。
ここで、ウェーブ1波長の長さが短いほどウェーブのかかり強さが強いことを示す。前処理組成物として試料1〜8を使用した試験及び評価結果を順に実施例1〜8とした。









表3
Figure 2008195633
*ウェーブ向上度:本発明の前処理剤の使用による水巻の場合に対するパーマネントウェーブのかかり強さの増加度を「ウェーブ向上度」として、下式に従って算出した。
ウェーブ向上度(%)=(水巻のウェーブ1波長の長さ-評価すべきウェーブの1波長の長さ)/水巻のウェーブ1波長の長さx100
以上の結果より、本発明の前処理組成物の使用により全ての実施例でウェーブ効率の向上が得られた。特に実施例2、3、5、7及び8において、水巻のパーマに比べて、黒毛において5%以上のブリーチ毛において10%以上のウェーブ効率の向上が得られた。
更に、試料6〜8は、他と比較して悪臭が少なく、扱いやすいという利点を有する。 Hereinafter, the present invention will be described with reference to specific examples, but the present invention is not limited thereto. Moreover, unless otherwise indicated, the amount is shown in mL.
(Examples 1-8)
Table 1 below shows the compositions of the permanent wave or curl pretreatment compositions used (Samples 1-8).




Table 1
Figure 2008195633
[Preparation method]
Each permanent wave or curl pretreatment composition having the composition shown in Table 1 was prepared by the following procedure.
At room temperature, a predetermined amount of the lactone described in Table 1 and purified water were poured into a 100 mL vial and stirred until homogeneous.

[Test method]
Healthy black hair of straight Japanese or Chinese hair that is not peculiar hair, 2 kinds of hair bundles (length 30cm, 1g) each of black hair (untreated hair) and twice bleached hair (14 tone hair) Then, 0.13 mL of the pretreatment composition for Samples 1 to 8 described in Table 1 was applied, combed well, wrapped in a wrap and allowed to stand at room temperature. Next, after standing at room temperature for 5 minutes, a hair bundle was wound around a rod having a diameter of 9 mm, coated with 0.39 mL of the first permanent wave solution, wrapped in wrap, and left at room temperature for 15 minutes. The hair bundle wound around the rod in running water for 1 minute was washed with water and lightly drained. Then, 0.39 ml of the second permanent wave solution was applied and left at room temperature for 15 minutes. After rinsing in running water for 1 minute, the rod was removed, the hair of the hair bundle was lightly cut, and the hair bundle was suspended.
Table 2 shows the composition of the thioperm first liquid and the cysteine permanent first liquid used as the first liquid for permanent wave, and the thioperm second liquid and the cysteine permanent second liquid used as the second liquid for permanent wave.
Table 2
Figure 2008195633
[Evaluation methods]
The length (unit: cm) of the wave 1 wavelength of the hair bundle to which permanent was applied in accordance with the above test procedure was measured and shown in Table 3.
Here, the shorter the wave 1 wavelength is, the stronger the wave intensity is. Tests and evaluation results using Samples 1 to 8 as the pretreatment composition were sequentially designated as Examples 1 to 8.









Table 3
Figure 2008195633
* Wave improvement degree: The increase degree of the intensity of permanent wave with respect to the case of water roll by using the pretreatment agent of the present invention was calculated as “Wave improvement degree” according to the following formula.
Wave improvement (%) = (length of wave 1 wavelength of water roll-length of 1 wavelength of wave to be evaluated) / length of wave 1 wavelength of water roll x 100
From the above results, improvement of wave efficiency was obtained in all Examples by using the pretreatment composition of the present invention. In particular, in Examples 2, 3, 5, 7, and 8, an improvement in wave efficiency of 10% or more was obtained for bleached hair of 5% or more for black hair as compared to a permanent of water winding.
Furthermore, Samples 6 to 8 have the advantage that they are easy to handle because they have less bad odor than others.

Claims (4)

ラクトン化合物を含むことを特徴とするパーマネントウェーブ又はカール前処理用組成物。   A permanent wave or curl pretreatment composition comprising a lactone compound. ラクトン化合物の炭素数が、3〜10である請求項1記載の組成物。   The composition according to claim 1, wherein the lactone compound has 3 to 10 carbon atoms. ラクトン化合物が、γ-バレロラクトン、DL-パントイン酸-γ-ラクトン、γ-ヘキサノラクトン及びγ-ブチロラクトンからなる群から選択される1種以上である請求項1記載の組成物。   The composition according to claim 1, wherein the lactone compound is at least one selected from the group consisting of γ-valerolactone, DL-pantoic acid-γ-lactone, γ-hexanolactone and γ-butyrolactone. 請求項1に記載の前処理用組成物を使用するパーマネントウェーブ又はカール方法であって、
(1)毛髪に該前処理用組成物を塗布する工程、
(2)該前処理用組成物を塗布された毛髪をロッドに巻く工程、
(3)該ロッドに巻かれた毛髪に還元剤を主たる成分とするパーマネントウェーブ又はカール用薬剤を塗布して放置する工程、及び
(4)該毛髪を洗髪する工程、
を含むことを特徴とする方法。
A permanent wave or curl method using the pretreatment composition according to claim 1,
(1) A step of applying the pretreatment composition to hair,
(2) a step of winding the hair coated with the pretreatment composition around a rod;
(3) applying a permanent wave or curling agent containing a reducing agent as a main component to the hair wound around the rod and leaving it alone; and (4) washing the hair.
A method comprising the steps of:
JP2007030519A 2007-02-09 2007-02-09 Pretreating agent for permanent wave treatment Pending JP2008195633A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012062250A (en) * 2010-09-14 2012-03-29 Nippon Fine Chem Co Ltd Hair cosmetic containing gamma-lactone derivative

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5161642A (en) * 1974-11-18 1976-05-28 Shiseido Co Ltd MOHATSUSHORYOSOSEIBUTSU
JPH0543436A (en) * 1991-08-09 1993-02-23 Nitta Gelatin Inc Hair treating composition for permanent wave, hair pretreating agent for permanent wave and first agent for perming
JPH07330557A (en) * 1994-06-03 1995-12-19 Wella Ag Hair treating agent and its use
JP2000169349A (en) * 1998-12-08 2000-06-20 Saburo Uchikuga Additive for permanent wave lotion
JP2002145743A (en) * 2000-11-09 2002-05-22 Estate Chemical Kk Pretreatment agent for permanent wave

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5161642A (en) * 1974-11-18 1976-05-28 Shiseido Co Ltd MOHATSUSHORYOSOSEIBUTSU
JPH0543436A (en) * 1991-08-09 1993-02-23 Nitta Gelatin Inc Hair treating composition for permanent wave, hair pretreating agent for permanent wave and first agent for perming
JPH07330557A (en) * 1994-06-03 1995-12-19 Wella Ag Hair treating agent and its use
JP2000169349A (en) * 1998-12-08 2000-06-20 Saburo Uchikuga Additive for permanent wave lotion
JP2002145743A (en) * 2000-11-09 2002-05-22 Estate Chemical Kk Pretreatment agent for permanent wave

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012062250A (en) * 2010-09-14 2012-03-29 Nippon Fine Chem Co Ltd Hair cosmetic containing gamma-lactone derivative

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