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JP2008173614A - Wastewater treatment method and treatment apparatus - Google Patents

Wastewater treatment method and treatment apparatus Download PDF

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JP2008173614A
JP2008173614A JP2007011947A JP2007011947A JP2008173614A JP 2008173614 A JP2008173614 A JP 2008173614A JP 2007011947 A JP2007011947 A JP 2007011947A JP 2007011947 A JP2007011947 A JP 2007011947A JP 2008173614 A JP2008173614 A JP 2008173614A
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wastewater
treated water
methane fermentation
acid generation
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Hideaki Kageyama
英明 影山
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Asahi Breweries Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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Abstract

<P>PROBLEM TO BE SOLVED: To reduce heating costs required in an acid generation process in wastewater treatment. <P>SOLUTION: A heat exchanger 15 in installed on a wastewater supply pipeline 16a to an acid generation tank 12. A delivery pipeline 16d for water treated in a methane fermentation tank 13 is connected to an aerobic treatment apparatus through the high temperature side 15 of the heat exchanger. Wastewater supplied to the acid generation tank 12 is preheated by heat energy of the treated water treated in the methane fermentation tank 13. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、排水の処理方法及び処理装置に関する。   The present invention relates to a wastewater treatment method and a treatment apparatus.

工場等から排出される排水は、まず、嫌気性微生物を利用した嫌気性処理工程において排水中の有機物をメタンガスに分解することで燃料としての再利用を図った後、好気性微生物を利用した好気性処理工程においてリンや窒素などの無機物を除去し、環境への悪影響を与える化学物質を除去した上で排水される。嫌気性処理工程は、まず酸生成槽において嫌気性の液化菌によって排水中の有機物を蟻酸、酢酸、プロピオン酸などメタン発酵が可能である低分子脂肪酸に分解する酸生成工程と、メタン発酵槽において液化菌とは別の嫌気性微生物であるメタン生成菌によって酸生成工程で生成した低分子脂肪酸をメタンガスと炭酸ガスとにまで分解するメタン発酵工程とから構成される。嫌気性処理工程に続く好気性処理工程では、曝気層において好気性微生物による処理が行われ、沈殿槽において汚泥層が分離され、上澄みとして存在する浄化層が排水される。このよう排水の処理方法及び処理装置は特許文献1に記載されている。   Wastewater discharged from factories, etc. is first recycled as fuel by decomposing organic matter in the wastewater into methane gas in the anaerobic treatment process using anaerobic microorganisms, and then using the aerobic microorganisms. In the tempering process, inorganic substances such as phosphorus and nitrogen are removed, and chemical substances that adversely affect the environment are removed before being drained. The anaerobic treatment process consists of an acid generation process that decomposes organic matter in wastewater into low molecular weight fatty acids that can be fermented with methane, such as formic acid, acetic acid, propionic acid, etc. It consists of a methane fermentation process that decomposes low-molecular-weight fatty acids produced in the acid production process by methane producers, which are anaerobic microorganisms separate from liquefied bacteria, into methane gas and carbon dioxide. In the aerobic treatment process following the anaerobic treatment process, the aerobic layer is treated with aerobic microorganisms, the sludge layer is separated in the settling tank, and the purification layer present as the supernatant is drained. Such a wastewater treatment method and treatment apparatus are described in Patent Document 1.

酸生成工程とメタン発酵工程とをそれぞれ独立させて行うのは、酸生成に作用する液化菌とメタン発酵に作用するメタン生成菌とを各々最適条件下に維持することができるので、高濃度の有機性排水を短時間に処理し、またメタン純度の高いガスを分離回収するためである。
特開2003−71486号公報
The acid generation step and the methane fermentation step are performed independently, because the liquefied bacteria that act on acid generation and the methanogen that acts on methane fermentation can be maintained under optimum conditions, respectively. This is to treat organic wastewater in a short time and to separate and recover gas with high methane purity.
JP 2003-71486 A

酸生成工程では27〜28℃前後において液化菌による反応が効果的に行われる。そこで、蒸気吹き込み等により酸生成槽中の排水を加熱手段によって27〜28℃前後まで加温することが必要であり、加熱コストを要する。特に冬季においては酸生成槽に供給される排水の温度が低いため、より大きな加熱コストを要する。   In the acid production step, the reaction by the liquefied bacteria is effectively performed at around 27 to 28 ° C. Therefore, it is necessary to heat the waste water in the acid generation tank to about 27 to 28 ° C. by heating means by steam blowing or the like, which requires heating costs. Particularly in the winter season, the temperature of the wastewater supplied to the acid generation tank is low, so that a larger heating cost is required.

本発明は、このような事情に鑑みてなされたもので、排水処理における酸生成工程のために必要とする加熱コストを低減することを目的とするものである。   This invention is made | formed in view of such a situation, and it aims at reducing the heating cost required for the acid production | generation process in wastewater treatment.

本発明は、排水に対して酸生成工程とメタン発酵工程と好気性処理工程とを順次行う排水の処理方法において、前記酸生成工程に供給される排水を、前記メタン発酵工程が終了し前記好気性処理工程に送出される処理水と熱交換させることにより予熱することを特徴とする。   The present invention provides a wastewater treatment method for sequentially performing an acid generation process, a methane fermentation process, and an aerobic treatment process on wastewater, and the wastewater supplied to the acid generation process is discharged from the methane fermentation process. It preheats by carrying out heat exchange with the treated water sent to a tempering treatment process.

また、本発明の別の側面は、酸生成槽と、前記酸生成槽の下流側に配置されるメタン発酵槽と、前記メタン発酵槽の下流側に配置される好気性処理装置と、熱交換器とを備える排水の処理装置において、前記熱交換器は、前記酸生成槽に供給される排水と前記メタン発酵槽から前記好気性処理装置に送出される処理水とを熱交換させるものであり、前記酸生成工程に供給される排水が前記熱交換によって予熱されることを特徴とする。   Further, another aspect of the present invention is an acid generator, a methane fermentation tank disposed on the downstream side of the acid generation tank, an aerobic treatment device disposed on the downstream side of the methane fermentation tank, and heat exchange. In the wastewater treatment apparatus comprising a vessel, the heat exchanger exchanges heat between the wastewater supplied to the acid generation tank and the treated water sent from the methane fermentation tank to the aerobic treatment apparatus. The waste water supplied to the acid generation step is preheated by the heat exchange.

本発明によれば、排水処理における酸生成工程で必要とする加熱コストを低減することができる。   ADVANTAGE OF THE INVENTION According to this invention, the heating cost required at the acid production | generation process in waste water treatment can be reduced.

以下、本発明の一実施の形態について図面を参照して説明する。本発明に係る一実施の形態における排水処理装置は、例えばビール工場等から排出される排水の処理に好適であり、嫌気的に排水を処理する嫌気性処理装置10と好気的に排水を処理する好気性処理装置20とを備える。   Hereinafter, an embodiment of the present invention will be described with reference to the drawings. The wastewater treatment apparatus in one embodiment according to the present invention is suitable for the treatment of wastewater discharged from, for example, a beer factory, and anaerobic treatment apparatus 10 that treats wastewater anaerobically and treats wastewater aerobically. An aerobic treatment device 20.

嫌気性処理装置10は、調整槽11と、排水に含まれる有機物を低分子脂肪酸に分解する酸生成槽12と、低分子脂肪酸を分解してメタンガスと炭酸ガスとを発生させるメタン発酵槽13と、メタン発酵後の処理水を貯留する処理水槽14と、熱交換器15とを備える。処理対象となる工場排水は、嫌気性処理装置10において、調整槽11で一旦貯留され、そこから排水供給管路16a、排水移送管路16b及び処理水移送管路16cにより熱交換器15、酸生成槽12、メタン発酵槽13の順に移送され、嫌気性処理の終了した処理水が処理水槽14に貯留される。そして、嫌気性処理の終了した処理水は、処理水槽14から処理水送出管路16dを通して好気性処理装置20の曝気槽21へと移送される。   The anaerobic treatment apparatus 10 includes an adjustment tank 11, an acid generation tank 12 that decomposes organic substances contained in the waste water into low molecular fatty acids, a methane fermentation tank 13 that decomposes the low molecular fatty acids and generates methane gas and carbon dioxide gas. A treated water tank 14 for storing treated water after methane fermentation and a heat exchanger 15 are provided. The factory wastewater to be treated is temporarily stored in the adjustment tank 11 in the anaerobic treatment apparatus 10, and from there, the heat exchanger 15, the acid through the wastewater supply pipe 16 a, the wastewater transfer pipe 16 b and the treated water transfer pipe 16 c. The treated water that has been transferred in the order of the production tank 12 and the methane fermentation tank 13 and has undergone anaerobic treatment is stored in the treated water tank 14. Then, the treated water after the anaerobic treatment is transferred from the treated water tank 14 to the aeration tank 21 of the aerobic treatment apparatus 20 through the treated water delivery line 16d.

調整槽11は、工場から排出される排水が一旦貯留されるタンクであり、酸生成槽12及びメタン発酵槽13における排水の嫌気性処理の程度に合わせ、酸生成槽12に供給する排水量を調整する。調整槽11に貯留される排水の温度は外気温にほぼ等しく、冬季には例えば15℃程度にまで低下する。調整槽11に貯留される排水は排水供給管路16aを通して酸生成槽12に供給される。   The adjustment tank 11 is a tank in which wastewater discharged from the factory is temporarily stored, and the amount of wastewater supplied to the acid generation tank 12 is adjusted according to the degree of anaerobic treatment of the wastewater in the acid generation tank 12 and the methane fermentation tank 13. To do. The temperature of the wastewater stored in the adjustment tank 11 is substantially equal to the outside air temperature, and decreases to, for example, about 15 ° C. in winter. The wastewater stored in the adjustment tank 11 is supplied to the acid generation tank 12 through the drainage supply line 16a.

当該排水供給管路16aを流れる排水は熱交換器15によって加温される。熱交換器15は、処理水槽14から曝気槽21に処理水送出管路16dを通して移送される処理水と排水供給管路16aを通して移送される排水とを熱交換することによって、排水供給管路16aを通して酸生成槽12へ供給される排水を予熱する。熱交換器15を通過する処理水送出管路16dは、処理水移送管路16cと一体化され、メタン発酵槽13から処理水槽14を通過することなく曝気槽21に処理水を移送する管路であってもよい。   The waste water flowing through the waste water supply pipe 16 a is heated by the heat exchanger 15. The heat exchanger 15 exchanges heat between the treated water transferred from the treated water tank 14 to the aeration tank 21 through the treated water delivery pipe line 16d and the wastewater transferred through the drainage supply pipe line 16a, thereby providing a drainage supply pipe line 16a. The waste water supplied to the acid generation tank 12 is preheated. The treated water delivery line 16d that passes through the heat exchanger 15 is integrated with the treated water transfer line 16c, and is a line that transfers treated water from the methane fermentation tank 13 to the aeration tank 21 without passing through the treated water tank 14. It may be.

酸生成槽12では、嫌気性の液化菌によって排水中の有機物が分解され蟻酸、酢酸、プロピオン酸等の低分子脂肪酸に分解される。酸生成槽12は液化菌の最適条件である27〜28℃前後の温度に保持される必要がある。そのために、酸生成槽12は蒸気を吹き込む等によって加熱される。酸生成槽12を加熱する手段としては酸生成槽12に内部加熱器を設けることとしてもよい。酸生成処理の終了した排水は排水移送管路16bによってメタン発酵槽13へ移送される。   In the acid generation tank 12, organic substances in the wastewater are decomposed by anaerobic liquefied bacteria and decomposed into low-molecular fatty acids such as formic acid, acetic acid, propionic acid and the like. The acid production tank 12 needs to be maintained at a temperature of about 27 to 28 ° C., which is the optimum condition for liquefied bacteria. Therefore, the acid generation tank 12 is heated by blowing steam or the like. As a means for heating the acid generation tank 12, an internal heater may be provided in the acid generation tank 12. The wastewater that has been subjected to the acid generation treatment is transferred to the methane fermentation tank 13 through the drainage transfer pipe 16b.

メタン発酵槽13では、嫌気性のメタン生成菌によって排水中の低分子脂肪酸がさらにメタンガスと炭酸ガスとに分解される。メタン発酵槽13で発生したメタンガスと炭酸ガスとは排気管路を介して回収され、燃料等として有効利用されうる。メタン発酵槽13でメタン発酵処理された後の処理水の温度は32℃前後と酸生成槽12中の排水温度より高い。   In the methane fermentation tank 13, the low-molecular-weight fatty acid in the wastewater is further decomposed into methane gas and carbon dioxide gas by anaerobic methanogen. Methane gas and carbon dioxide gas generated in the methane fermentation tank 13 are recovered via the exhaust pipe and can be effectively used as fuel or the like. The temperature of the treated water after being subjected to the methane fermentation treatment in the methane fermentation tank 13 is about 32 ° C. and higher than the drainage temperature in the acid generation tank 12.

メタン発酵槽14によって有機物が除去された処理水は、処理水移送管路16cによって処理水槽14に移送され貯留される。嫌気性処理の次工程である好気性処理の程度に合わせ、処理水送出管路16dによって好気性処理装置へ送出する処理水の量を調整するため、処理水は処理水槽14で一旦貯留される。好気性処理装置へ送出する処理水の量を特に調整する必要がない場合には処理水槽14は備えなくてもよい。   The treated water from which the organic matter has been removed by the methane fermentation tank 14 is transferred to the treated water tank 14 and stored by the treated water transfer pipe 16c. The treated water is temporarily stored in the treated water tank 14 in order to adjust the amount of treated water sent to the aerobic treatment device by the treated water delivery pipe 16d in accordance with the degree of the aerobic treatment which is the next step of the anaerobic treatment. . When there is no need to particularly adjust the amount of treated water sent to the aerobic treatment apparatus, the treated water tank 14 may not be provided.

処理水送出管路16dを流れる32℃前後の処理水は、熱交換器15を介して排水供給管路16aを流れる外気温近くの排水を例えば30℃近くまで加温した後、好気性処理装置20の曝気槽21に送出される。したがって、処理水による予熱分だけ酸生成槽12の加熱コストを低減することができる。   The treated water at around 32 ° C. flowing through the treated water delivery line 16d is heated to about 30 ° C. near the outside temperature flowing through the waste water supply line 16a via the heat exchanger 15, and then an aerobic treatment device. It is sent to 20 aeration tanks 21. Therefore, the heating cost of the acid generation tank 12 can be reduced by the amount preheated by the treated water.

処理水送出管路16dを流れる処理水の水温は排水供給管路16aを流れる排水との熱交換によって例えば30℃近くまで下がる。しかし、好気性処理装置20では特段の温度管理を必要としないので、処理水の温度が数℃低下しても何ら支障は生じない。   The temperature of the treated water flowing through the treated water delivery line 16d is lowered to, for example, close to 30 ° C. by heat exchange with the wastewater flowing through the drainage supply line 16a. However, since the aerobic treatment apparatus 20 does not require any special temperature management, no trouble occurs even if the temperature of the treated water is lowered by several degrees Celsius.

好気性処理装置20は、嫌気性処理の終了した処理水が処理水送出管路16dを介して注入され好気的に処理される曝気槽21と、汚泥層を分離する沈殿槽22とを備え、汚泥槽22で上澄みとして存在する浄化層はそのまま排水され、沈殿した汚泥層は曝気槽21に循環され、余剰分は余剰汚泥として排出される。曝気槽21では、嫌気性処理装置10で処理されなかったリンや窒素等の無機物が好気性微生物の作用により処理水中から除去される。   The aerobic treatment apparatus 20 includes an aeration tank 21 in which treated water having undergone anaerobic treatment is injected through the treated water delivery line 16d and treated aerobically, and a sedimentation tank 22 that separates the sludge layer. The purification layer existing as the supernatant in the sludge tank 22 is drained as it is, the precipitated sludge layer is circulated to the aeration tank 21, and the surplus is discharged as excess sludge. In the aeration tank 21, inorganic substances such as phosphorus and nitrogen that have not been treated by the anaerobic treatment apparatus 10 are removed from the treated water by the action of aerobic microorganisms.

本発明における一実施形態の排水処理装置を示す図である。It is a figure which shows the waste water treatment apparatus of one Embodiment in this invention.

符号の説明Explanation of symbols

10 嫌気性処理装置
11 調整槽
12 酸生成槽
13 メタン発酵槽
14 処理水槽
15 熱交換器
16a 排水供給管路
16b 排水移送管路
16c 処理水移送管路
16d 処理水送出管路
20 好気性処理装置
21 曝気槽
22 沈殿槽
DESCRIPTION OF SYMBOLS 10 Anaerobic processing apparatus 11 Adjustment tank 12 Acid production tank 13 Methane fermentation tank 14 Treated water tank 15 Heat exchanger 16a Drain supply pipe 16b Drain transfer pipe 16c Treated water transfer pipe 16d Treated water delivery pipe 20 Aerobic treatment apparatus 21 Aeration tank 22 Precipitation tank

Claims (2)

排水に対して酸生成工程とメタン発酵工程と好気性処理工程とを順次行う排水の処理方法であって、
前記酸生成工程に供給される排水を、前記メタン発酵工程が終了し前記好気性処理工程に送出される処理水と熱交換させることにより予熱することを特徴とする排水の処理方法。
A wastewater treatment method that sequentially performs an acid generation process, a methane fermentation process, and an aerobic treatment process on wastewater,
A wastewater treatment method, wherein the wastewater supplied to the acid generation step is preheated by exchanging heat with treated water sent to the aerobic treatment step after the methane fermentation step is completed.
酸生成槽と、
前記酸生成槽の下流側に配置されるメタン発酵槽と、
前記メタン発酵槽の下流側に配置される好気性処理装置と、
熱交換器とを備える排水の処理装置であって、
前記熱交換器は、前記酸生成槽に供給される排水と前記メタン発酵槽から前記好気性処理装置に送出される処理水とを熱交換させるものであり、前記酸生成槽に供給される排水が前記熱交換によって予熱されることを特徴とする排水の処理装置。
An acid generator,
A methane fermentation tank disposed downstream of the acid generation tank;
An aerobic treatment device disposed downstream of the methane fermentation tank;
A wastewater treatment apparatus comprising a heat exchanger,
The heat exchanger is for exchanging heat between wastewater supplied to the acid generation tank and treated water sent from the methane fermentation tank to the aerobic treatment apparatus, and wastewater supplied to the acid generation tank Is preheated by the heat exchange.
JP2007011947A 2007-01-22 2007-01-22 Wastewater treatment method and treatment apparatus Withdrawn JP2008173614A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011230007A (en) * 2010-04-23 2011-11-17 Tokyo Electric Power Co Inc:The Sewage treatment system
CN103435162A (en) * 2013-09-04 2013-12-11 武汉兴天宇环境工程有限公司 Method for treating organic wastewater by anaerobic-aerobic combined process
WO2020080244A1 (en) * 2018-10-19 2020-04-23 Dowaエコシステム株式会社 Method for treating object to be treated

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011230007A (en) * 2010-04-23 2011-11-17 Tokyo Electric Power Co Inc:The Sewage treatment system
CN103435162A (en) * 2013-09-04 2013-12-11 武汉兴天宇环境工程有限公司 Method for treating organic wastewater by anaerobic-aerobic combined process
WO2020080244A1 (en) * 2018-10-19 2020-04-23 Dowaエコシステム株式会社 Method for treating object to be treated
JP2020062631A (en) * 2018-10-19 2020-04-23 Dowaテクノロジー株式会社 Treatment method for waste material
JP7226731B2 (en) 2018-10-19 2023-02-21 Dowaテクノロジー株式会社 Processing method of the object to be processed

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