JP2007204666A - Heat-resistant resin products, methods for producing heat-resistant resin products, use of granular materials - Google Patents

Abstract

The present invention provides a heat-resistant resin product with more functionality, a method for producing the heat-resistant resin product, and the use of granular materials.
A heat-resistant resin product having more functionality by dispersing at least one of a liposome having a particle size of 20 to 800 nm and a liposome as a dispersed substance in a heat-resistant resin as a dispersion medium. Can provide. Moreover, the manufacturing method of a heat resistant resin product and use of the granular material used for this are provided.
[Selection figure] None

Description

  The present invention relates to a heat-resistant resin product with more functionality, a method for producing the heat-resistant resin product, and the use of granular materials.

  In recent years, problems that will contribute to the future of humankind, such as global environmental problems, have been seriously discussed and researched and reported on a global level as international problems. For example, examples of problems that will contribute to the future of humankind include the depletion of resources such as petroleum, the problem of global warming due to the emission of carbon dioxide, the impact on the human health due to environmental hormones, and the ultraviolet rays caused by the destruction of the ozone layer. The influence of. There is no need to prove how serious these are.

  In addition, modern society has to work hard to eliminate employment and social unrest, and to do so, it must quickly introduce new industries. Next-generation industries include next-generation displays, RFID technology, information industry, precision technology industry, semiconductor industry, medical technology, gene conversion technology, and so on.

  In response to such a social background, techniques for improving resin products can be cited as techniques to be passed on to the next generation. Resin products are indispensable for our daily lives, and naturally exist in the information industry, precision technology industry, semiconductor industry, medical technology as well as manufacturing, distribution and sales industries. However, the significance of its existence can be said to be extremely large.

  For example, among resins, heat-resistant resins are used in the automotive field, electrical / electronic field, injection molding field, extrusion molding field, general machine field, film / sheet, home appliances, and the like.

  In order to improve the function when a heat-resistant resin is used as a dispersion medium, a method of providing a resin material by dispersing a filler or the like as a dispersed phase is known. As a means of improving the physical properties of polymer materials, two or more types of polymers are mixed together (polymer blend), or a method of making a composite material by adding a filler is used. The phase of the polymer portion of the composite material is used. A device has been devised to express desired material properties by controlling the separation structure and the dispersion state of the filler. There are several types of polymer blend-based composite products with fillers, such as a sea-island structure, a co-continuous structure, and a salami structure as the phase separation structure of the polymer part. The filler dispersion state is uniform in each phase. In addition to the dispersed state, there is a state in which the filler is unevenly distributed in one phase or a plurality of phases. That is, various structures exist according to the combination of the polymer phase separation structure and the filler dispersion state. In the development of such filler-added polymer blend heat-resistant resin products, research on the structure that provides the desired physical properties and the development of materials that provide excellent physical properties are continued.

  As described above, a method for improving the function of the heat-resistant resin is known. However, a heat-resistant resin product with higher functionality and a manufacturing method for manufacturing the heat-resistant resin product are desired.

  The present invention has been made in view of solving at least one of the above-mentioned problems. A heat-resistant resin product rich in functionality that can contribute to the next generation global environment, industry, and the like, and Its main purpose is to provide a manufacturing method and the use of granules.

  The present invention is a heat-resistant resin product including a resin layer in which particles having a particle diameter of 20 to 800 nm are dispersed.

  In the heat resistant resin product, the granular material is preferably a capsule composed of a core material and an outer shell material including the core material.

  The heat-resistant resin product, wherein the outer shell material includes a resin affinity material having an affinity for the resin rather than the nuclear material, and a nuclear material affinity material having an affinity for the nuclear material than the resin. It is preferable that the affinity substance contains.

  The present invention is characterized by being a heat-resistant resin product including a resin layer in which liposomes are dispersed as particulates.

  In the heat-resistant resin product, the liposome preferably has a particle size of 20 to 800 nm.

  In the heat resistant resin product, it is preferable that the granular material includes a functional material.

  In the heat-resistant resin product, it is preferable that the granular material includes at least one of a metal porphyrin complex and a redox polymer.

  In the heat-resistant resin product, it is preferable that at least one of the metal porphyrin complex and the redox polymer is contained as a nuclear substance.

  In addition, the present invention is characterized in that it includes a dispersion step of dispersing at least one of those having a particle size of 20 to 800 nm and particles having a particle size of 20 to 800 nm as a granular material as a dispersed phase in a resin layer as a dispersion medium.

  In the method for producing the heat-resistant resin product, it is preferable that the granular material is a capsule composed of a core material and an outer shell material including the core material.

  The heat-resistant resin product manufacturing method, wherein the outer shell material has a resin affinity material having an affinity for the resin rather than the nuclear material, and a nuclear material affinity for the nuclear material more than the resin. It is preferable that the substance contains an affinity substance.

  In the method for manufacturing the heat resistant resin product, it is preferable that the granular material includes a functional material.

  In the method for producing the heat-resistant resin product, it is preferable that the carrying step for carrying the particulate matter on a carrier and the dispersing step by dispersing the carrier on which the particulate matter is carried.

  A method for producing the heat-resistant resin product, wherein a tableting step using the granular material or a carrier on which the granular material is supported as a tablet, and after the tableting step, the tablet is dispersed in the resin to disperse the tablet. It is preferable to perform the process.

  In the method for producing the heat resistant resin product, it is preferable that the granular material includes at least one of a metal porphyrin complex and a redox polymer.

  In the method for producing the heat resistant resin product, it is preferable that at least one of the metal porphyrin complex and the redox polymer is contained as a nuclear substance.

  Moreover, this invention is characterized by use of the granular material which uses at least one among the thing which has a particle size of 20-800 nm and a liposome as manufacture of a heat resistant resin product.

  It is preferable to use the granular material, and the granular material is preferably a capsule composed of a core material and an outer shell material containing the core material.

  Use of the granular material, wherein the outer shell material includes a resin affinity material having an affinity for the resin rather than the nuclear material, and a nuclear material affinity material having an affinity for the nuclear material than the resin. It is preferable that the affinity substance contains.

  It is preferable to use the granular material, and the granular material preferably contains a functional material.

  Preferably, the granular material is used, and the granular material is supported on a carrier.

  It is preferable to use the granular material, and the granular material is a tablet.

  It is preferable to use the granular material, and the granular material preferably includes at least one of a metal porphyrin complex and a redox polymer.

  Preferably, the granular material is used, and at least one of the metal porphyrin complex and the redox polymer is contained as a nuclear material.

  It is possible to provide a heat-resistant resin product with more functionality, a method for producing the heat-resistant resin product, and use of granular materials.

Hereinafter, the heat resistant resin product according to the present embodiment, the method for producing the heat resistant resin product, and the use of the granular material will be described. In addition, this embodiment is only one form for implementing this invention, and this invention is not limited by this embodiment.
"Heat-resistant resin products"
The present inventor makes at least one of the liposome and the granular material having a particle size of 20 to 800 nm as a dispersed phase, and when dispersed in a heat-resistant resin as a dispersion medium, We found that heat-resistant resin products with various functions can be realized. If particles of this size are dispersed, the characteristics of each granular material can be remarkably imparted to the heat resistant resin product. This is considered to be an improvement in uniform dispersibility for a reason. The “heat resistance” is a concept including all of heat resistance deterioration, heat distortion resistance, and heat decomposition resistance.

  In addition, use in manufacture of a heat resistant resin product includes use for dispersion | distribution etc. in the previous step used as resin generally considered as each heat resistant resin, and dispersion | distribution to the heat resistant resin which became solid. In other words, it may be used for dispersion, etc. even before the resin material such as crude oil and naphtha (petroleum products), which are raw materials for heat-resistant resin materials, and olefin monomer (petrochemical raw material) before polymerization. In addition, the particulate matter may be used for dispersion or the like after becoming a solid from the fluidized state.

  In addition, the viscous resin product may include at least one resin layer in which particulate matter is dispersed, may include a resin layer in which particulate matter is not dispersed, and further is a material combined with other materials such as metal. It is good also as a structure. Of course, you may be comprised only from the resin layer in which the granular material was disperse | distributed.

  Such a heat-resistant resin product in which the particulate matter is dispersed can be a strong heat-resistant resin product excellent in tensile strength, elongation at break and the like. This reason is considered as an example, and it may be possible that the crystallinity of the resin has some influence, but another reason cannot be denied.

  The method for dispersing the particulate matter with respect to the dispersion medium is not limited to the case where the dispersion medium is in a fluid state. The dispersion medium may be a solid. If the granular material is a particle size of 20 to 800 nm or a liposome, the resin is not in a fluid state and often infiltrates even if it is solid.

  Furthermore, it is preferable to select the material of the granular material so that the chemical action of the granular material itself can be obtained as the granular material.

  Furthermore, as the material of the granular material, for example, crystallization accelerator, antistatic agent, carbon dioxide reducing agent, antioxidant, ultraviolet absorber, conductive agent, colorant, metallic brightener, lubricant, mold release agent, photopolymerization start Agent, photosensitizer, light stabilizer, filler, foaming agent, flame retardant, lubricant, plasticizer, stabilizer, surfactant, thermal stabilizer, leveling agent, antifoaming agent, viscosity modifier, molecular weight regulator It is preferable to include a functional material that adds a function to a resin having functions such as a polymer chain distributor, a radical-forming polymerization initiator, a coupling agent, a photocatalyst, and a modifier.

  For example, when the granular material of the present embodiment contains a crystallization accelerator matched to a resin, a heat-resistant resin product according to crystallization can be provided by the chemical crystallization promotion effect of the crystallization accelerator.

  In the heat resistant resin product in which the granular material according to the present embodiment includes an antistatic agent added, it is possible to provide a heat resistant resin product that can prevent electrostatic charge. The antistatic agent can be appropriately selected and used. For example, a quaternary ammonium salt, polyoxyethylene alkylamine, polyglycol ether, sodium p-styrenesulfonate, a substance selected from the following surfactants, and the like are examples. Can be mentioned.

  In the heat resistant resin product in which the granular material of the present embodiment contains a carbon dioxide reducing agent, the amount of carbon dioxide emitted can be reduced when the resin product is incinerated. Carbon dioxide emissions are determined according to the Kyoto Protocol (the protocol adopted at the 3rd Conference of the Parties (COP3) held in Kyoto in December 1997 to achieve the objectives of the Framework Convention on Climate Change). % Reduction is urgently needed. If carbon dioxide emissions are suppressed during incineration of heat-resistant resin products, it can greatly contribute to the reduction of carbon dioxide.

  Examples of the carbon dioxide reducing agent include metal porphyrin complexes and redox polymers. These are considered to be those in which carbon dioxide is reduced by inhibiting the binding of carbon and oxygen, or by reducing the generated carbon dioxide and decomposing it into carbon and oxygen.

  The metal porphyrin complex is a substance represented by the following chemical formulas (I) and (II).

（式中、Ｍは、鉄、マンガン、モリブデン、銅、コバルト、クロム、イリジウム、アルミニウムから選ばれる金属を示し、４つのＲのうち少なくとも１つは、チオフリル基、ピロリル基、フリル基、メルカプトフェニル基、アミノフェニル基、ヒドロキシフェニル基から選ばれるいずれかの基であり、他のＲは、前記のいずれかの基またはアルキル基、アリール（ａｒｙｌ）基もしくは水素を示す）

(In the formula, M represents a metal selected from iron, manganese, molybdenum, copper, cobalt, chromium, iridium, and aluminum, and at least one of the four Rs is a thiofuryl group, a pyrrolyl group, a furyl group, or a mercaptophenyl. Any group selected from a group, an aminophenyl group, and a hydroxyphenyl group, and the other R represents any one of the above groups, an alkyl group, an aryl group, or hydrogen)

金属ポルフィリン錯体を形成するポルフィリン化合物は特に限られることなく、適宜選択して用いることができるが、例えば、５，１０，１５，２０−テトラキス（２−チオフリル）ポルフィリン、５，１０，１５，２０−テトラキス（３−チオフリル）ポルフィリン、５，１０，１５，２０−テトラキス（２−ピロリル）ポルフィリン、５，１０，１５，２０−テトラキス（３−ピロリル）ポルフィリン、５，１０，１５，２０−テトラキス（２−フリル）ポルフィリン、５，１０，１５，２０−テトラキス（３−フリル）ポルフィリン、５，１０，１５，２０−テトラキス（２−メルカプトフェニル）ポルフィリン、５，１０，１５，２０−テトラキス（３−メルカプトフェニル）ポルフィリン、５，１０，１５，２０−テトラキス（４−メルカプトフェニル）ポルフィリン、５，１０，１５，２０−テトラキス（２−アミノフェニル）ポルフィリン、５，１０，１５，２０−テトラキス（３−アミノフェニル）ポルフィリン、５，１０，１５，２０−テトラキス（４−アミノフェニル）ポルフィリン、５，１０，１５，２０−テトラキス（２−ヒドロキシフェニル）ポルフィリン、５，１０，１５，２０−テトラキス（３−ヒドロキシフェニル）ポルフィリン、５，１０，１５，２０−テトラキス（４−ヒドロキシフェニル）ポルフィリン、［５，１０，１５−トリス（２−チオフリル）−２０−モノ（フェニル）］ポルフィリン、［５，１０，１５−トリス（３−チオフリル）−２０−モノ（フェニル）］ポルフィリン、［５，１０−ビス（２−チオフリル）−１５，２０−ジ（フェニル）］ポルフィリン、［５，１０−ビス（３−チオフリル）−１５，２０−ジ（フェニル）］ポルフィリン、［５，１５−ビス（２−チオフリル）−１５，２０−ジ（フェニル）］ポルフィリン、［５，１５−ビス（３−チオフリル）−１５，２０−ジ（フェニル）］ポルフィリン、［５−モノ（２−チオフリル）−１０，１５，２０−トリ（フェニル）］ポルフィリン、［５−モノ（３−チオフリル）−１０，１５，２０−トリ（フェニル）］ポルフィリンなどを好適例として挙げることができる。

The porphyrin compound forming the metal porphyrin complex is not particularly limited and can be appropriately selected and used. For example, 5,10,15,20-tetrakis (2-thiofuryl) porphyrin, 5,10,15,20 Tetrakis (3-thiofuryl) porphyrin, 5,10,15,20-tetrakis (2-pyrrolyl) porphyrin, 5,10,15,20-tetrakis (3-pyrrolyl) porphyrin, 5,10,15,20-tetrakis (2-furyl) porphyrin, 5,10,15,20-tetrakis (3-furyl) porphyrin, 5,10,15,20-tetrakis (2-mercaptophenyl) porphyrin, 5,10,15,20-tetrakis ( 3-mercaptophenyl) porphyrin, 5,10,15,20-tetrakis (4 Mercaptophenyl) porphyrin, 5,10,15,20-tetrakis (2-aminophenyl) porphyrin, 5,10,15,20-tetrakis (3-aminophenyl) porphyrin, 5,10,15,20-tetrakis (4 -Aminophenyl) porphyrin, 5,10,15,20-tetrakis (2-hydroxyphenyl) porphyrin, 5,10,15,20-tetrakis (3-hydroxyphenyl) porphyrin, 5,10,15,20-tetrakis ( 4-hydroxyphenyl) porphyrin, [5,10,15-tris (2-thiofuryl) -20-mono (phenyl)] porphyrin, [5,10,15-tris (3-thiofuryl) -20-mono (phenyl) ] Porphyrin, [5,10-bis (2-thiofuryl) -15,20 Di (phenyl)] porphyrin, [5,10-bis (3-thiofuryl) -15,20-di (phenyl)] porphyrin, [5,15-bis (2-thiofuryl) -15,20-di (phenyl) ] Porphyrin, [5,15-bis (3-thiofuryl) -15,20-di (phenyl)] porphyrin, [5-mono (2-thiofuryl) -10,15,20-tri (phenyl)] porphyrin, [ A preferred example is 5-mono (3-thiofuryl) -10,15,20-tri (phenyl)] porphyrin.

  The ligand represented by the compound L represented by the chemical formula (II) can be appropriately selected and used. For example, imidazole derivatives, pyridine derivatives, aniline derivatives, histidine derivatives, trimethylamine derivatives, thiophenol derivatives. Examples include cysteine derivatives, methionine derivatives, benzoic acid derivatives, acetic acid derivatives, phenol derivatives, and aliphatic alcohol derivatives.

  The imidazole derivative is not particularly limited and can be appropriately selected and used. Examples thereof include methylimidazole, ethylimidazole, propioimidazole, dimethylimidazole, and benzimidazole.

  The pyridine derivative is not particularly limited and can be appropriately selected and used. Examples thereof include methylpyridine, methylpyridine acetate, nicotinamide, pyridazine, pyrimidine, pyrazine, and triazine.

  The aniline derivative is not particularly limited and can be appropriately selected and used. Examples thereof include aminophenol and diaminobenzene.

  The histidine derivative is not particularly limited and can be appropriately selected and used. Examples thereof include histidine methyl ester, histamine, hipryl-histidine-leucine and the like.

  The trimethylamine derivative is not particularly limited and can be appropriately selected and used. Examples thereof include triethylamine and tripropylamine.

  The thiophenol derivative is not particularly limited and can be appropriately selected and used. Examples thereof include thiocresol, mercaptobenzoic acid, aminothiophenol, benzenedithiol, and methylbenzenedithiol.

  The cysteine derivative is not particularly limited and can be appropriately selected and used. Examples thereof include cysteine methyl ester and cysteine ethyl ester.

  The methionine derivative is not particularly limited and can be appropriately selected and used. Examples thereof include methionine methyl ester and methionine ethyl ester.

  The benzoic acid derivative is not particularly limited and can be appropriately selected and used. Examples thereof include salicylic acid, phthalic acid, isophthalic acid, terephthalic acid and the like.

  The acetic acid derivative is not particularly limited and can be appropriately selected and used. Examples thereof include trifluoroacetic acid, mercaptoacetic acid, propionic acid, and tangled acid.

  The phenol derivative is not particularly limited and can be appropriately selected and used. Examples thereof include cresol and dihydroxybenzene.

  The aliphatic alcohol derivative is not particularly limited and can be appropriately selected and used. Examples thereof include ethyl alcohol and propyl alcohol.

  The method for obtaining the porphyrin compound may be appropriately selected without particular limitation, such as purchase from the market, synthesis, and the like. For example, the porphyrin compound may be obtained by the synthesis method described in WO2003 / 045436 as an example. .

  In the heat resistant resin product in which the granular material of the present embodiment is added with a material containing an ultraviolet absorber, the ultraviolet rays can be absorbed and reduced. By using such a heat-resistant resin product to separate from the human body, various harmful effects caused by ultraviolet rays, such as skin cancer and adverse effects on eyes, can be greatly reduced. In addition, since ultraviolet rays are various factors that alter and decompose substances, shielding them is a major issue. However, by using this heat-resistant resin product to block ultraviolet rays from target substances, the substances can be altered by ultraviolet rays. Can be protected from disassembly.

  As an ultraviolet absorber, it can select and use suitably, For example, a benzophenone type, a benzotriazole type, and a cyanoacrylate type are preferable. Examples of the benzophenone compounds include 2,3′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone and 2,2 ′, 4,4′-tetrahydroxybenzophenone. Can be cited as an example.

  Examples of the benzotriazole type include 2- (2'-hydroxy-5'-methylphenyl) benzotriazole, 2- (2'-hydroxy-5'-methylphenyl) -5,6- Dichlorobenzotriazole), 2- (2'-hydroxy-5'-t-butylphenyl), benzotriazole, 2- (2'-hydroxy-3'-methyl-5'-t-butylphenyl) ) Benzotriazole, 2- (2'-hydroxy-3 ', 5'-di-t-butylphenyl) -5-chloro-benzotriazole and 2- (2'-hydroxy-5'-phenylphenyl)- 5-chlorobenzotriazole, 2- (2'-hydroxy-3 ', 5'-di-t-butylphenyl) -5-chlorobenzotriazole, 2- (2'-hydroxy-3) '-T-bu -5'-methylphenyl) -5-chlorobenzotriazole, 2- (2'-hydroxy-3 ', 5'-di-t-amylphenyl) benzotriazole, 2- (2'-hydroxy) -3 ', 5'-di-t-butylphenyl) benzotriazole, 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole, 2- {2'-hydroxy-3'-( 3 ″, 4 ″, 5 ″, 6 ″ -tetrahydrophthalimidomethyl) -5′-methylphenyl} benzotriazole, 2- {2-hydroxy-3,5-bis (α, α′-dimethylbenzyl) phenyl} And 2-hydroxybenzotriazole, 2- (2-hydroxy-4-octyloxyphenyl) -2H-benzotriazole, and the like. Examples of the cyanoacrylate type include ethyl-2-cyano-3,3-diphenyl acrylate, 2-ethylhexyl-2-cyano-3,3-diphenyl acrylate, and the like. it can.

  In the heat resistant resin product in which the conductive material is added to the granular material of the present embodiment, various functions can be produced by imparting conductivity. Moreover, the electromagnetic wave shielding effect | action can also be provided to resin by providing electroconductivity.

  The conductive agent can be appropriately selected and used, but may be any one that can impart conductivity, for example, metal particles such as gold, silver, copper, stainless steel, aluminum, zinc, tin, indium, antimony, nickel, Conductive pigments such as carbon black and graphite, metal oxides such as zinc oxide, tin oxide, indium oxide, and titanium oxide, and fine carbon fibers such as carbon nanotubes and fullerenes are used. The shape of the conductive powder is not particularly limited, and spherical, elliptical, scale-like, and needle-like conductive powders can be used. Organic metal compounds include organic silver compounds such as methyl silver, butyl silver, and phenyl silver, monoalkyl (aryl) gold derivatives (such as gold gold dibromide and phenyl gold dichloride), dialkyl gold derivatives, and trialkyl gold derivatives. The organic gold compound is used. As the organic conductive resin, an organic compound having a π-conjugated bond such as polyaniline or polythiophene may be used. For example, metals such as aluminum, gold, silver, copper, alloys, oxides, and ceramics (for example, elements such as heavy metals, light metals, noble metals, base metals, transition metals, non-transition metal metals) may be used. Includes or includes mainly.

  In the heat resistant resin product in which the granular material of the present embodiment contains a colorant, various functions can be produced by the coloring action. For example, ultraviolet rays can be blocked by coloring, and visual effects such as various design properties can be imparted.

  The colorant can be appropriately selected and used. For example, both a dye and a pigment can be used as the colorant. Various pigments can be used regardless of whether they are organic or inorganic. For example, bright pigments such as aluminum, brass, evaporated powder, pearl pigment (white, gold, etc.), rhodamine lake B, insoluble azo red pigment (naphthol) (eg, brilliant carmel BS, lake carmel FB, lake red 4B) , First Red FGR, Lake Bold 5B, Toluidine Marlon), Insoluble azo red pigment (anilide type) (eg, pyrazole red), Soluble azo red pigment (eg, Lake Orange, Brilliant Carmel 3B, Brilliant Carmel 6B, Brilliant Scarlet G) , Lake Red C, Lake Red D, Lake Red R, Lake Bold 10B, Bonmarlon L, Bonmarlon M) and other red pigments, Heiza Yellow A, inert azo yellow pigments (anilides) (eg, Fast Yellow G, First Yellow pigments such as yellow 10G, diazo orange), dye lake yellow pigments (eg, yellow lake), phthalocyanine blue pigments (eg, phthalocyanine blue, first sky blue), dyed lake blue pigments (eg, violet) Lake, Blue Lake), blue pigments such as other pigments (eg, alkali blue), black pigments such as carbon black, acetylene black, lamp black, aniline black, oxidation that can be either rutile titanium oxide or anatase titanium oxide Examples thereof include inorganic fillers such as titanium, silica, alumina, clay, talc, calcium carbonate, and barium sulfate, and white pigments such as zinc oxide. These colorants can be selected from carbon black, organic pigments, inorganic pigments and the like according to the required color tone, and used alone or in combination of two or more to obtain a desired hue. It can also be used after adjustment.

  In the heat-resistant resin product in which the granular material according to the present embodiment includes a metal gloss agent, various functions can be produced by the effect of the metal gloss. For example, it is possible to impart visual effects such as various design properties such as metallic gloss by metallic luster.

  Also, as a result of applying metal reflection characteristics to resin, it is used for shielding objects and human bodies that reflect and shield infrared light, visible light, ultraviolet light, short wavelength light, electromagnetic waves, etc. from light and electromagnetic waves It will be possible. Such uses are effective in improving the health exemplified above to protect the human body from harmful rays such as ultraviolet rays, as well as improving the preservability of preventing the decomposition and alteration of the object exemplified above. Can contribute.

The metallic brightener can be selected and used as appropriate. For example, metals having metallic luster in general, metallic metals such as silver or gold to which metal pigments such as aluminum paste and aluminum powder are added even if they are not metals. In the heat-resistant resin product obtained by adding a release agent and a lubricant to the granular material of this embodiment, the wear resistance is reduced, the opponent attack is reduced, and the friction resistance is reduced. Reduction, improvement of blocking resistance, and scratch resistance can be remarkably improved.

  A release agent and a lubricant can be appropriately selected and used. For example, those suitable for improving the processability of embossing are selected. Polyolefins, stearic acid, stearates, stearyl alcohol, petrolatum, polyglycol esters of fatty acids, and the like can be used as examples. Examples of the wax include microcrystalline wax, carbana wax, and paraffin wax. In addition, Fischer-Tropsch wax, various low molecular weight polyethylene, wood wax, beeswax, ibota wax, wool wax, cerax wax, candelilla wax, petrolactam, polyester wax, partially modified wax, fatty acid ester, fatty acid amide, etc. A wax etc. can be mentioned.

  In the heat-resistant resin product obtained by adding a photopolymerization initiator, a photosensitizer, and a light stabilizer to the granular material of the present embodiment, the characteristics of the functional material that effectively plays a role by controlling light are remarkably improved. . It is possible to provide a new generation heat-resistant resin product using light that can efficiently use a small amount of light.

  The photopolymerization initiator and the photosensitizer can be appropriately selected and used. For example, as the photopolymerization initiator, acetophenones, benzophenones, Michler benzoylbenzoate, α-amyloxime ester, tetramethylthiuram As monosulfide, thioxanthone, and / or photosensitizer, n-butylamine, triethylamine, tri-n-butylphosphine and the like can be mixed and used.

  In the heat-resistant resin product in which the filler containing the filler is added to the granular material of the present embodiment, the effect of preventing deterioration and reinforcing can be remarkably improved by enhancing the dispersibility or cohesiveness of the filler. it can. According to such a heat-resistant resin product, the strength performance equivalent to that of a metal plate can be secured, and the functionality is remarkable as a new generation heat-resistant resin product.

  The filler can be appropriately selected and used. For example, inorganic fillers or general inorganic fillers such as calcium carbonate, aluminum hydroxide, magnesium hydroxide, calcium hydroxide, zinc borate, zinc oxide, magnesium oxide Examples thereof include inorganic spheres, organic hollow spheres, barium metaborate, calcium carbonate, barium sulfate, talc, carion, and clay.

  A high-quality foamed resin body can be formed in a heat-resistant resin product obtained by adding a foaming agent to the granular material of this embodiment. In the foamed resin body, it is difficult to reduce the nonuniformity of foaming, the size of each foamed foam, and to provide a fine foam. In contrast, this heat-resistant resin product can ensure foaming uniformity that was unthinkable in the past, and the size of each foam can be reduced. Therefore, it is possible to provide a new foamed resin body with fine details, and the functionality is remarkable as a new generation heat-resistant resin product.

  The foaming agent can be appropriately selected and used, and for example, any of a heating foaming agent that foams by heating, a pyrolytic foaming agent, and a capsule foaming agent can be used. As a component of the foaming agent, nitropentamethylenetetramine, azodicarbonamide, toluenesulfonylhydrazine, azobisisobutylnitrile, benzenesulfonylhydrazine and the like can be used. The capsule foaming agent is a microsphere having a particle size of 10 to 30 μm in which a low boiling point solvent is encapsulated with a coating or shell of a thermoplastic polymer material. As the shell material, an acrylonitrile / vinylidene chloride copolymer, an acrylonitrile / acrylic copolymer, a nitrile copolymer, or the like is used. Examples of the encapsulated gas include pentane, isopentane, isobutane, and butane. Examples of the capsule foaming agent include a high-temperature foaming agent that can be heated at 140 (160) to 190 ° C. for 1 minute to obtain the maximum magnification, the shell material being a nitrile copolymer, and the inclusion gas being pentane. It is done. For example, as a blowing agent, propane, normal butane, isobutane, normal pentane, isopentane, cyclopentane, hexane and other aliphatic hydrocarbons, trichlorofluoromethane, dichlorofluoromethane, dichlorodifluoromethane, dichlorotetrafluoro, etc. A halogenated hydrocarbon is mentioned. These foaming agents may be used alone or in combination of two or more.

  In the heat-resistant resin product obtained by adding the flame retardant to the granular material of the present embodiment, a flame retardant material that cannot be considered as a resin can be formed.

  The flame retardant can be appropriately selected and used. For example, inorganic fillers or general inorganic fillers such as calcium carbonate, aluminum hydroxide, magnesium hydroxide, calcium hydroxide, zinc borate, zinc oxide, magnesium oxide Examples thereof include inorganic spheres, organic hollow spheres, barium metaborate, calcium carbonate, barium sulfate, talc, carion, and clay.

  Furthermore, if it is a heat resistant resin product that is appropriately selected and added with other functional materials or the like to the granular material of the present embodiment, the functional characteristics can be remarkably obtained. Therefore, it is possible to secure an economic profit together with a great number of new uses, and to produce a remarkable economic effect.

  Examples of the antioxidant include a phenolic antioxidant, an organic phosphite antioxidant, a thioether antioxidant, a hindered amine antioxidant, and the like. Examples of the antiblocking agent include aluminum oxide, fine powder silica, polymethyl methacrylate powder, and silicon resin.

  Examples of the slip agent include bisamides such as ethylene bisstearamide, higher fatty acid amides such as oleic acid amide and erucic acid amide. Examples of the lubricant include higher fatty acid metal salts such as calcium stearate, zinc stearate, and metal montanate, and polyolefin waxes such as polyethylene wax and polypropylene wax. Examples of the nucleating agent include rosin nucleating agents such as dibenzylidene sorbitol and partial metal salts of rosin acid, aluminum nucleating agents, and talc.

  Plasticizers can be appropriately selected and used. For example, dioctyl phthalate, dibutyl phthalate, butyl benzyl phthalate, etc., phthalate ester, phosphate ester, chlorinated fatty acid ester, chlorinated paraffin, epoxy , Polyester-based, adipate-based plasticizer, stearic acid triglyceride, palmitic acid triglyceride, lauric acid triglyceride, stearic acid diglyceride, fatty acid glycerides such as stearic acid monoglyceride, vegetable oils such as coconut oil, palm oil, palm kernel oil Organic hydrocarbons such as cyclohexane, toluene, xylene and liquid paraffin are used. These may be used in combination.

  Examples of the polymerization initiator include polymerization initiators generally used for radical polymerization of styrene monomers such as benzoyl peroxide, t-butyl peroxybenzoate, lauroyl peroxide, isopropyl-t-butyl peroxycarbonate, peroxycarbonate, Organic peroxides such as butyl benzoate and 1,1-bis (t-butylperoxy) 3,3,5-trimethylcyclohexane and azo compounds such as azobisisobutyronitrile and azobisdimethylvaleronitrile are used. it can. These polymerization initiators may be used alone or in combination of two or more.

  Stabilizers can be appropriately selected and used. For example, composite stabilizers such as cadmium, barium and zinc, lead stabilizers, tin stabilizers, calcium stabilizers and the like can be used as examples. .

  Surfactants, emulsifiers, and wetting agents can be appropriately selected and used, but those suitable for emulsification are preferable. For example, phosphoric acid monoester, phosphoric diester, polyoxyethylene sorbitan monooleate Examples thereof include polyoxyethylene lauryl ether, polyethylene glycol monolaurate, and quaternary ammonium salts. Polylactic acid, rice wax, soybean lecithin, and phospholipid are preferred.

  For example, oleic acid, fatty acid polyhydric alcohol ester type nonionic surfactant such as sorbitan monolaurate, monooleate, monostearate or monopalmitate, sorbitan tristearate or trioleate, polyoxy of fatty acid polyhydric alcohol ester Ethylene adducts, polyacrylic acid, polymethacrylic acid, copolymers of polyacrylic acid and polymethacrylic acid, water-soluble polymers containing sulfonic acid groups such as sulfoethyl acrylate, sulfoethyl methacrylate or sulfopropyl methacrylate. And polymers of N- (sulfoethyl) -maleimide, 2-acrylamido-2-alkylsulfonic acid, styrene sulfonic acid and vinyl sulfonic acid, polyoxyethylene sorbitan Nolaurate, monooleate, monostearate, monopalmitate, tristearate or trioleate, polyethylene glycol fatty acid esters such as polyoxyethyl stearate, polyethylene glycol 400 stearate, polyethylene glycol 2000 stearate, D-α-tocopherol, DL- α-tocopherol, D-α-tocopherol acetate, DL-α-tocopherol acetate, ascorbyl palmitate, vitamin F glycerides; vitamin Ds, especially vitamin D2 and vitamin D3; retinol, retinol esters (palmitic acid retinol esters and Propionic acid retinol ester), β-carotene, D-panthenol, farnesol, farnesyl acetate; Rich oils, in particular jojoba oil and blackcursis oil; 5-n-octanoylsalicylic acid, salicylic acid; α-hydroxy acids such as alkyl esters of citric acid, lactic acid and glycolic acid; asiatic acid, madagascar acid ), Asiaticoside, whole extract of Centella asiatica, β-glycyrrhetinic acid, α-bisabolol; ceramides, especially 2-oleoylamino-1,3-octadecane; phytanetriol, sphingo from milk Myelin, phospholipids derived from marine products rich in polyunsaturated essential fatty acids, ethoxyquin, mannen wax extract, perfume oil extract, quercetin, etc., short chain (C1-C6) alcohols such as ethanol; polyols such as Recall, in particular 1,3-butylene glycol, propylene glycol, dipropylene glycol, isoprene glycol, or hexylene glycol can be exemplified glycerine, polyglycerol and sorbitol and the like.

  Examples of lipophilic surfactants include sucrose distearate, diglyceryl distearate, tetraglyceryl tristearate, decaglyceryl destearate, diglyceryl monostearate, hexaglyceryl tristearate, decaglycerin pentastearate, Sorbitan monostearate, sorbitan tristearate, diethylene glycol monostearate, esters of glycerin, palmitic acid and stearic acid, polyoxyethylene 2EO monostearate (ie containing two ethylene oxide units), mono- and dibehenic acid Glycerin and pentaerythritol tetrastearate.

  Examples of hydrophilic surfactants include the following compounds: polyoxyethylene sorbitan 4EO monostearate, 20 EO polyoxyethylene sorbitan tristearate, polyoxyethylene 8EO monostearate, hexaglyceryl monostearate, monostearate Mention may be made of the acid polyoxyethylene 10EO, polyoxyethylene 12 EO distearate and polyoxyethylene methylglucose 20EO distearate.

Nonionic, anionic, cationic and amphoteric surfactants.
Nonionic surfactants include, for example, EO addition type nonionic surfactants [for example, higher alcohols (C8-18, the same shall apply hereinafter), higher fatty acids (C8-24, the same shall apply hereinafter) or higher alkylamines (C8-24). ) EO adduct (molecular weight 158 to Mn 200,000); higher fatty acid ester of polyalkylene glycol (molecular weight 120 to Mn 6,000) which is an EO adduct of glycol; polyhydric alcohol (C2-18 divalent to octavalent) Or higher, eg, ethylene glycol, propylene glycol, glycerin, pentaerythritol and sorbitan) EO adducts of higher fatty acid esters (molecular weight 220-Mn 30,000); EO adducts of higher fatty acid amides (molecular weight 200-Mn 30,000); And polyhydric alcohols (as described above) (C3-60) ether EO adduct (molecular weight 120-Mn30,000)], and polyhydric alcohol (C3-60) type nonionic surfactant [for example, fatty acid (C3-60) of polyhydric alcohol Ester, alkyl (C3-60) ether of polyhydric alcohol and fatty acid (C3-60) alkanolamide].

The surfactant may be anionic, cationic or amphoteric.
Examples of the anionic surfactant include compounds other than the above (C1), such as carboxylic acids (for example, C8-22 saturated or unsaturated fatty acids and ether carboxylic acids) or salts thereof; sulfate salts [for example, higher alcohol sulfate salts ( For example, sulfate esters of C8-18 aliphatic alcohols) and higher alkyl ether sulfate esters [eg sulfate esters of EO (1-10 mol) adducts of C8-18 aliphatic alcohols]]; sulfonates [ C10-20, such as alkyl benzene sulfonates (eg sodium dodecylbenzene sulfonate), alkyl sulfonates, alkyl naphthalene sulfonates, dialkyl ester sulfosuccinates, hydrocarbon (eg alkane, α-olefin) sulfonates and Igepon T type] And phosphoric acid ester salts [e.g. higher alcohol (C8~60) EO adduct phosphoric acid ester salts and alkyl (C4~60) phenol EO adduct phosphoric acid ester salts], and. Examples of the salts include alkali metal salts, alkaline earth metal salts, ammonium salts, alkylamine (C1-20) salts and alkanolamine (C2-12, such as mono-, di- and triethanolamine) salts. It is done.

  Cationic surfactants include quaternary ammonium salt types [eg, tetraalkyl (C4-100) ammonium salts (eg, lauryltrimethylammonium chloride, didecyldimethylammonium chloride, dioctyldimethylammonium bromide and stearyltrimethylammonium bromide), Alkyl (C3-80) benzylammonium salts (eg lauryldimethylbenzylammonium chloride (benzalkonium chloride), alkyl (C2-60) pyridinium salts (eg cetylpyridinium chloride), polyoxyalkylene (C2-4) trialkylammonium salts (Eg, polyoxyethylenetrimethylammonium chloride) and sapamine type quaternary ammonium salts (eg, stearamide ester) Rudiethylmethyl ammonium methosulfate)]; and amine salt forms [eg higher aliphatic amines (C12-60, eg laurylamine, stearylamine, cetylamine, hardened tallow amine and rosinamine) inorganic acids (eg hydrochloric acid, sulfuric acid, nitric acid and Phosphoric acid) salts or organic acids (C2-22, eg acetic acid, propionic acid, lauric acid, oleic acid, benzoic acid, succinic acid, adipic acid and azelaic acid) salts, EO adducts of aliphatic amines (C1-30) Inorganic acids (above) or organic acids (above) and tertiary amines (C3-30, eg triethanolamine monostearate and stearamide ethyl diethyl methylethanolamine) Or salt of organic acid (above)].

  Examples of amphoteric surfactants include amino acid-type amphoteric surfactants [for example, higher alkylamine (C8-24) sodium propionate], betaine-type amphoteric surfactants [for example, alkyl (C12-18) dimethylbetaine], sulfate esters Type amphoteric surfactants [e.g. sulfate sodium salts and hydroxyethyl imidazoline sulfate sodium salts of higher alkylamines (C8-24)], sulfonate type amphoteric surfactants (e.g. pentadecyl sulfotaurine and imidazoline sulfonic acid) and Phosphate ester type amphoteric surfactants [for example, phosphate ester amine salts of glycerin higher fatty acid (C8-24) esterified products].

  The molecular weight regulator or the polymer chain transfer agent can be appropriately selected and used. For example, mercaptan, mercaptoethanol, mercaptopropanol, mercaptobutanol, n-dodecyl mercaptan, mercaptosuccinic acid, mercaptopropionic acid, mercaptoglycerin, Mercaptoacetic acid, thioglycolic acid ester such as hexyl thioglycolate, mercaptoglycol silane such as 3-mercaptopropyltrimethoxysilane and 3-mercaptopropyl-methyldimethoxysilane, ether, dioxane, tetrahydrofuran, tetrahydrofurfuryl alcohol, tetrahydrofuracetic acid Furyl esters, alcohols such as isopropanol, n-butanol and n-decanol and aromatic hydrocarbons such as iso It can be cited as an example Ropirubenzoru.

  The radical-forming polymerization initiator can be appropriately selected and used. For example, t-butylperoxyneodecanoate, t-amylperoxypivalate, dilauroyl peroxide, t-amylperoxy-2-ethylhexanoate 2,2'-azobis- (2,4-dimethyl) valeronitrile, 2,2'-azobis- (2-methoxybutyronitrile), dibenzoyl peroxide, t-butylper-2-ethylhexanoate, di T-butyl hydroperoxide, 2,5-dimethyl-2,5-di (t-butylperoxy) hexane and cumol hydroperoxide. The radical initiators used with preference are di (3,5,5-trimethylhexanoyl) -peroxide, 4,4′-azobisisobutyronitrile, t-butylperpivalate and dimethyl-2,2 ′. An example is azobisisobutyrate.

  The granular material is preferably a capsule made of a core material and an outer shell material containing the core material. By doing in this way, the said granular material increases the case where it disperses | distributes uniformly in a heat resistant resin product. In order to disperse more preferably, the outer shell material includes a resin affinity material having an affinity for the resin rather than the nuclear material, and a nuclear material affinity material having an affinity for the nuclear material than the resin. An affinity substance containing is preferable because it contributes to uniform dispersion.

  When the uniform dispersibility is improved, it is possible to reduce the amount of granular materials used for obtaining the same effect. Therefore, a significant reduction in cost can be realized due to a significant reduction in the amount of granular material used, and a great economic contribution effect can be obtained. Further, when it is desired to refrain from using the granular material as much as possible, for example, when the particulate matter has some influence on the environment, it greatly contributes to the reduction of the amount of use, and it can also make a great contribution to solving the global environmental problem.

  Such substances include amphiphilic lipids having surface active properties. The amphiphilic lipid is selected from the group consisting of neutralized anionic lipids, amphoteric lipids and alkylsulfonic acid derivatives, and examples thereof include phospholipids and glycolipids described later.

  Neutralized anionic lipids are, for example, alkali metal salts of dicetyl phosphate, in particular sodium and potassium salts; alkali metal salts of dimyristyl phosphate, in particular sodium and potassium salts; alkali metal salts of cholesterol sulfonate, in particular Sodium salt; alkali metal salt of cholesterol phosphate, especially sodium salt; monosodium salt or disodium salt of acylglutamic acid, especially monosodium salt or disodium salt of N-stearoylglutamic acid; and sodium phosphatidic acid Things.

  When the above-mentioned functional material is a capsule containing the core material, the functional material is uniformly dispersed by the capsule, so the amount of the functional material used to obtain the same function can be reduced. It will be possible to provide a great economic contribution and a great contribution to solving global environmental problems.

  In addition, if a heat-resistant resin product in which capsules containing a metal porphyrin complex or a redox polymer as a functional material and containing these as a core material are dispersed is generated when the heat-resistant resin product is burned. A smaller amount of metal porphyrin complex and redox polymer can be used compared to the case of not encapsulating to reduce carbon dioxide. These functional materials are usually expensive, and the most important proposition is to reduce the amount used and to reduce the price. Thus, since the amount of use can be reduced and the price can be reduced, the capsule-dispersed heat-resistant resin product can be provided at a low price, and dominates the distribution market. Thereby, since the heat-resistant resin product on the market is replaced with this heat-resistant resin product, it can greatly contribute to the reduction effect of carbon dioxide.

  Such capsules are preferably liposomes. If it is a liposome, the particle size will not be limited. Furthermore, it can contribute to uniform dispersion, and can further enhance the environmental, economic and physical effects. It is preferable that the functional material is contained as a nuclear substance in the liposome. More preferably, it is preferable that a metal porphyrin complex or a redox polymer as a carbon dioxide reducing agent is included in the liposome. By ensuring the dispersibility with liposomes, the amount of functional materials used can be further reduced and the price can be reduced. Therefore, heat-resistant resin products in which liposomes are dispersed can be provided at a low price, and the distribution market. Will be further swept. As a result, the heat-resistant resin product on the market is further replaced with this heat-resistant resin product, which greatly contributes to the reduction effect of carbon dioxide, and the environmental and economic benefits due to the reduction of carbon dioxide are further remarkable. Liposomes are used as cosmetics and foods, and can provide heat-resistant resin products that can contribute to the next-generation environmental society with little impact on health and the environment.

  In the present embodiment, the heat-resistant resin serving as the dispersion medium is not particularly limited as long as it is a resin that has the concept of heat resistance, and may be appropriately selected. For example, polyimide resin in general (fully aromatic polyimide resin, bismaleimide polyimide resin, thermoplastic polyimide, etc.), polyamideimide resin, polyetherimide resin, poly-p-phenylene resin, poly-p-xylylene resin, polyphenylene sulfide resin , Polyphenylene oxide resin, polysulfone resin, polyether sulfone resin, polyether ether ketone resin, polyarylate resin, wholly aromatic polyester resin, aramid resin, polybenzimidazole resin, polybenzothiazole resin, polyphenylquinoxaline resin, polyparabanic acid, Fluorine resin in general (polytetrafluoroethylene resin, polychlorotrifluoroethylene resin, polyvinylidene fluoride resin, polyvinyl fluoride resin, tetrafluoroethylene-hex Fluoropropylene copolymer, tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer, ethylene-chlorotrifluoroethylene copolymer, tetrafluoroethylene-hexafluoropropylene-perfluoroalkyl vinyl ether copolymer, etc.), polyamide resin, polyacetal Examples thereof include resins, polycarbonate resins, modified polyphenylene oxide resins, polybutylene terephthalate resins, engineering plastics, super engineering plastics, epoxy resins, phenol resins, cyanate resins, and thermosetting resins.

  The above-described configuration is preferable for a heat-resistant resin product as a specific example of a heat-resistant resin product, and examples thereof include a vehicle fan attached to an automobile or the like.

  Various additives can be added to the heat-resistant resin as the dispersion medium, if necessary.

  In this embodiment, the particles used as the dispersed phase and the contents thereof are the above functional materials, resins in general and derivatives thereof, combinations thereof, polymers, inorganic substances, carbons (graphite, carbon black, carbon nanotubes). , Carbon nanohorn, fullerene, etc.), polymer liquid crystals, polymer pharmaceuticals, DNA, proteins, layered clay minerals, metals and oxides thereof, and inorganic pigments. As the state thereof, any state such as a liquid, a solid or an intermediate thereof can be adopted.

  The granular material as a dispersed phase to be dispersed in the heat-resistant resin as a dispersion medium and the resin used for the contents can be appropriately selected. For example, thermoplastic resin, thermosetting resin, electron beam curable resin, ultraviolet curable resin It can be employed regardless of resin. These resins may be used alone or in combination of two or more.

  The thermoplastic resin is not particularly limited and can be appropriately selected and employed. However, an aqueous emulsion resin (various emulsions can be used, but examples include ethylene-vinyl acetate, an acrylic resin alone or a blend, Polymer, etc.), polyethylene resin, polyacrylic resin, polyvinyl acetate resin, polyurethane resin, polystyrene resin, poly heat resistant resin synthetic rubber and the like can be used. For example, polyethylene resin is advantageous in that it is advantageous in that it is less likely to generate dioxins when it is burned as waste and has less harm to the environment. Common polyolefin-based resins such as polyethylene and polybutadiene are listed. The polypropylene resin may be either a homopolymer that is a homopolymer of propylene or a copolymer type, and may be either a random copolymer or a block copolymer. It is preferable to use a random copolymer having excellent impact resistance and transparency at room temperature. Moreover, you may mix an elastomer component with the said component. Although it does not specifically limit as an elastomer component, For example, an olefin type elastomer, a styrene type elastomer, a polystyrene resin, a polyacryl resin, a vinyl resin, a polycarbonate resin, a polyacetal resin, a modified polyphenylene ether resin, a biodegradable resin etc. are mentioned as an example. .

  The biodegradable resin may be either fully degradable or partially degradable. As the biodegradable component, polylactic acid, microbial production resin, natural polymer resin, or chemically synthesized resin can be used. .

  Examples of the microbial production resin include Biopol, Biofan, Biogreen and the like.

  Examples of natural polymer resins include nobon, matterby, and drone.

  As an example of the chemically synthesized resin, cell green, bionore, PCL, lacti, lunale, lacia and the like can be exemplified.

  The thermosetting resin can be selected as appropriate, and examples thereof include an epoxy resin, a phenol resin, and a cyanate resin.

  The ultraviolet curable resin can be selected as appropriate, and examples thereof include an acrylate compound, an epoxy resin, and an oxetane compound.

  The electron beam curable resin can be appropriately selected and used. Specifically, a composition curable by an electron beam having a radically polymerizable unsaturated bond or a cationically polymerizable functional group in the molecule and appropriately mixed with prepolymers (including so-called oligomers) and / or monomers. Preferably it is used. These prepolymers or monomers may be used alone or in combination. Further, the curing is usually a crosslinking curing, and the crosslinking curing is preferable from the viewpoint of durability such as abrasion resistance. Specifically, the prepolymer or monomer is a compound having a radically polymerizable unsaturated group such as a (meth) acryloyl group or (meth) acryloyloxy group, a cationically polymerizable functional group such as an epoxy group in the molecule. Become. A polyene / thiol-based prepolymer based on a combination of polyene and polythiol may also be preferably used.

  In addition, the particles used as the dispersed phase and the resin used for the contents thereof include, for example, polylactic acid, polyethylene terephthalate, polypropylene, polyethylene, polyester, polycarbonate, polymethyl methacrylate, polystyrene, nylon, polysulfone, polyether ether ketone, poly Oxymethylene, polyimide, polyurethane, polysaccharide, starch, poly (N-vinylpyrrolidone), and their copolymers, acrylic resin, cellulose resin, melamine resin, polyester resin, polyamide resin, acrylic Resins, styrene resins, polyamides, ethylene-vinyl acetate copolymers, vinyl chloride-vinyl acetate copolymers, thermoplastic elastomers such as styrene-butadiene rubber, and the like may be used. When a urethane resin is used, for example, polyoxyalkylated diol or polyol, tackifier having a softening point of 40 ° C to 140 ° C, aliphatic or aromatic diisocyanate, or polyisocyanate can be used. Examples of the vinyl resin include resins made of vinyl ether such as vinyl chloride-vinyl acetate copolymer, vinyl acetate polymer, polyvinyl butyral, and polyalkyl vinyl ether. Furthermore, examples of the silicone resin include rubber-like polysiloxane and resin-like polysiloxane. The resin described in the present embodiment can be used alone or as a copolymer comprising two or more of these and a mixture thereof.

  Further, the granular material as the dispersed phase and the contents thereof are low molecular organic compounds such as phthalocyanine, azo, anthraquinone, quinacridone or perylene pigments or dyes, plasticizers such as long chain esters, phosphate esters And a release agent such as, an antioxidant, an ultraviolet absorber, a pharmaceutical, an amino acid, DNA / protein, and a fragment thereof.

  Moreover, an inorganic layered compound can be used for the granular material which becomes a dispersed phase. Among these, clay minerals having swelling properties are preferable, and clay-based minerals include a type having a two-layer structure in which an octahedral layer having aluminum, magnesium, or the like as a central metal is formed above a tetrahedral layer of silica, and 4 of silica. The face layer is classified into a type having a three-layer structure in which an octahedron layer having aluminum, magnesium, or the like as a central metal is sandwiched from both sides. Examples of the former include the kaolinite group and the antigolite group, and examples of the latter include the smectite group, vermiculite group, and mica group depending on the number of interlayer cations. Specifically, kaolinite, dickite, nacrite, halloysite, antigolite, chrysotile, pyrophyllite, montmorillonite, hectorite, tetrasilic mica, sodium teniolite, muscovite, margarite, talc, vermiculite, phlogopite , Xanthophyllite, chlorite and the like. Furthermore, it is preferable to use a granular material obtained by swelling the inorganic layered compound. The solvent used for swelling is not particularly limited. For example, in the case of natural swelling clay minerals, water, methanol, ethanol, propanol, isopropanol, ethylene glycol, diethylene glycol, and other alcohols, dimethylformamide, dimethyl sulfoxide, acetone, and the like. And alcohols such as water and methanol are preferred.

  For example, the granular material that becomes the dispersed phase is Pt, Au, W, Ru, Ir, Al, Sc, Ti, V, Mn, Fe, Co, Ni, Zn, Ga, Y, Zr, Nb, Mo, Tc, Rh, Pd, Ag, Cd, Ln, Sn, Ta, Re, Os, Tl, Pb, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, It is also possible to employ a single metal such as Lu or a laminate or a compound thereof.

Moreover, a metal oxide can also be employ | adopted for the granular material used as a dispersed phase. Metal oxides include LiOx, LiNx, NaOx, KOx, RbOx, CsOx, BeOx, MgOx, MgNx, CaOx, CaNx, SrOx, BaOx, ScOx, YOx, YNx, LaOx, LaNx, CeOx, PrOx, Nx, PrOx, Nx, EuOx, GdOx, TbOx, DyOx, HoOx, ErOx, TmOx, YbOx, LuOx, TiOx, TiNx, ZrOx, ZrNx, HfOx, HfNx, ThOx, VOx, VNx, NbOx, TaOx, TaOx, TaOx WOx, WNx, MnOx, ReOx, FeOx, FeNx, RuOx, OsOx, CoOx, RhOx, IrOx, NiOx, PdOx, PtOx, CuOx, CuNx, AgOx, AuOx, ZnOx, dOx, HgOx, BOx, BNx, AlOx, AlNx, GaOx, GaNx, InOx, TiOx, TiNx, SiNx, GeOx, SnOx, PbOx, POx, PNx, AsOx, SbOx, SeOx, metal oxides such as TeOx and, LiAlO ₂ , Li ₂ SiO ₃ , Li ₂ TiO ₃ , Na ₂ Al ₂₂ O ₃₄ , NaFeO ₂ , Na ₄ SiO ₄ , K ₂ SiO ₃ , K ₂ TiO ₃ , K ₂ WO ₄ , Rb ₂ CrO ₄ , Cs ₂ CrO _{4 , MgAl 2 O 4, MgFe 2} O 4, MgTiO 3, CaTiO 3, CaWO 4, CaZrO 3, SrFe 12 O 19, SrTiO 3, SrZrO 3, BaAl 2 O 4, BaFe 12 O 19, BaTiO 3, Y 3 A _{l5 O 12, Y 3 Fe 5} O 12 _{LaFeO 3, La 3 Fe 5 O} 12, La 2 Ti 2 O 7, CeSnO 4, CeTiO 4, Sm 3 Fe 5 O 12, EuFeO 3, Eu 3 Fe 5 O 12, GdFeO 3, Gd 3 Fe 5 O 12, _{DyFeO 3, Dy 3 Fe 5 O} 12, HoFeO 3, Ho 3 Fe 5 O 12, ErFeO 3, Er 3 Fe 5 O 12, Tm 3 Fe 5 O 12, LuFeO 3, Lu 3 Fe 5 O 12, NiTiO 3, _{al 2 TiO 3, FeTiO 3,} BaZrO 3, LiZrO 3, MgZrO 3, HfTiO 4, NH 4 VO 3, AgVO 3, LiVO 3, BaNb 2 O 6, NaNbO 3, SrNb 2 O 6, KTaO 3, NaTaO 3, _{SrTa 2 O 6, CuCr 2 O} 4, Ag 2 CrO 4 _{, BaCrO 4, K 2 MoO 4} , Na 2 MoO 4, NiMoO 4, BaWO 4, Na 2 WO 4, SrWO 4, MnCr 2 O 4, MnFe 2 O 4, MnTiO 3, MnWO 4, CoFe 2 O 4, ZnFe _{2 O 4, FeWO 4, CoMoO} 4, CuTiO 3, CuWO 4, Ag 2 MoO 4, Ag 2 WO 4, ZnAl 2 O 4, ZnMoO 4, ZnWO 4, CdSnO 3, CdTiO 3, CdMoO 4, CdWO 4, NaAlO ₂ , MgAl ₂ O ₄ , SrAl ₂ O ₄ , Gd ₃ Ga ₅ O ₁₂ , InFeO ₃ , MgIn ₂ O ₄ , Al ₂ TiO ₅ , FeTiO ₃ , MgTiO ₃ , Na ₂ SiO ₃ , CaSiO ₃ , ZrSiO ₄ , K _{2 GeO 3, Li 2 GeO 3} , Na 2 _{eO 3, Bi 2 Sn 3 O} 9, MgSnO 3, SrSnO 3, PbSiO 3, PbMoO 4, PbTiO 3, SnO 2 -Sb 2 O 3, CuSeO 4, Na 2 SeO 3, ZnSeO 3, K 2 TeO 3, K Metal composite oxides such as ₂ TeO ₄ , Na ₂ TeO ₃ , and Na ₂ TeO ₄ can also be mentioned.

Further, sulfides such as FeS, Al ₂ S ₃ , MgS, and ZnS, fluorides such as LiF, MgF ₂ , and SmF ₃ , chlorides such as HgCl, FeCl ₂ , and CrCl ₃ , bromides such as AgBr, CuBr, and MnBr ₂ , PbI ₂ , CuI, FeI _2, etc. or metal oxynitrides such as SiAlON are not particularly limited. Also, not limited to metals and metal compounds, organic materials such as polymer materials such as polyimide, polyamide, polyester, polyacrylate, epoxy resin, phenol resin, polyvinyl alcohol, polymer, metal oxides such as resin ITO and IZO Organic conductive materials containing conjugated polymer compounds such as polyanilines, polythiophenes, and polypyrroles can also be used.

Organic materials using semiconductor characteristics may be used, for example, phthalocyanine derivatives, naphthalocyanine derivatives, azo compound derivatives, perylene derivatives, indigo derivatives, quinacridone derivatives, anthraquinones and other polycyclic quinone derivatives, cyanine derivatives , Fullerene derivatives, or nitrogen-containing cyclic compound derivatives such as indole, carbazole, oxazole, inoxazole, thiazole, imidazole, pyrazole, oxadiazole, pyrazoline, thiathiazole, triazole, hydrazine derivative, triphenylamine derivative, triphenyl Quinone compound derivatives such as methane derivatives, stilbenes, anthraquinone diphenoquinone, polycyclic aromatic compound derivatives such as anthracene, bilene, phenanthrene, coronene, etc. Structures used in the main chain of polymers such as polyethylene chain, polysiloxane chain, polyether chain, polyester chain, polyamide chain, polyimide chain, etc. or those linked in pendant form as side chains, or polyparaphenylene, etc. Aromatic conjugated polymers, aliphatic conjugated polymers such as polyacetylene, heterocyclic conjugated polymers with polypinol and polythiophene ratios, heteroatom-conjugated polymers such as polyanilines and polyphenylene sulfide, poly ( Carbon-based conjugated polymers such as composite conjugated polymers having a structure in which structural units of conjugated polymers such as phenylene vinylene), poly (annelen vinylene), and poly (chenylene vinylene) are alternately bonded are used. . In addition, oligosilanes such as polysilanes, disilanylene arylene polymers, (disilanylene) ethenylene polymers, and disilanylene carbon-based polymer structures such as (disilanylene) ethynylene polymers alternate with carbon-based conjugated structures. Polymers linked to are used. In addition, polymer chains composed of inorganic elements such as phosphorus and nitrogen may be used, and polymers having aromatic chain ligands such as phthalocyanate polysiloxane coordinated, perylenetetracarboxylic Polymers in which perylenes such as acids are subjected to heat treatment and condensed, ladder-type polymers obtained by heat-treating polyethylene derivatives having a cyano group such as polyacrylonitrile, and organic compounds intercalated in perovskites The composite material etc. which were made can also be used.
"Method for manufacturing heat-resistant resin products"
Next, as an example of a functional material that is a granular material, a liposome having a particle size of 20 to 800 nm with a metal porphyrin complex as a core substance is used as a capsule, and a method of dispersing this in a resin is exemplified. A manufacturing method will be described. That is, since it is suitable in the present embodiment, the following supercritical carbon dioxide method is used to disperse this in a heat-resistant resin using a metalloporphyrin complex as an encapsulating substance as a core substance and a liposome as a capsule consisting of a lipid as an outer shell substance. Let
(Preparation of liposome)
First, a liposome having a particle size of 20 to 800 nm dispersed in an aqueous phase as an aqueous solution is prepared. The outer shell material of the liposome is a lipid or a fat, which can be appropriately selected from these, and is preferably a phospholipid or a glycolipid. More preferably, the phospholipid or glycolipid is a compound capable of forming a lipid bilayer. The lipid is an affinity substance including a resin affinity substance having an affinity for the resin rather than a nuclear substance and a nuclear substance affinity substance having an affinity for the nuclear substance rather than the resin. Representative examples of the affinity substance include the above-mentioned surfactants and surfactants such as emulsifiers.

  Phospholipids are also referred to as phosphatides, and it is considered as a general definition of a group of substances having a phosphate ester and a CP bond among complex lipids. Examples of phospholipids include phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidic acid, phosphatidylglycerol, phosphatidylinositol, cardiopine, egg yolk lecithin, hydrogenated egg yolk lecithin, glycerophospholipid such as soybean lecithin, hydrogenated soybean lecithin, sphingomyelin And sphingophospholipids such as ceramide phosphorylethanolamine and ceramide phosphorylglycerol.

  Examples of glycolipids include, for example, glycerolipids such as digalactosyl diglyceride and galactosyl diglyceride sulfate, galactosylceramide, galactosylceramide sulfate, lactosylceramide, ganglioside G7, ganglioside G6, ganglioside G4 and other sphingoglycolipids. Can do.

  In addition, as an outer shell material, for example, polylactic acid, rice wax, or the like can be used. Rice wax is preferable from the viewpoint of cost reduction.

  It is preferable that the encapsulated substance as the core substance of the liposome is a lipophilic or hydrophilic substance. In the present embodiment, a metal porphyrin complex is exemplified as a lipophilic or hydrophilic encapsulating material, but other materials such as other functional materials can be used as the encapsulating material. The state of the encapsulating substance may be any of gas, liquid, and solid.

  Examples of the encapsulated substance include pharmacologically active ingredients and the like in addition to the above functional materials. Examples of the pharmacologically active component include L-ascorbyl magnesium phosphate, ascorbic acid glycoside, dipotassium glycyrrhizinate, β-glycyrrhetinic acid, ammonium glycyrrhetinate, stearyl glycyrrhetinate, estine, esculin, pantothenic alcohol, pantothenic acid and salts thereof, Examples include thiamine, flavin, folic acid or antibiotics, at least one non-steroidal anti-inflammatory drug, ketoprofen, ibuprofen, bufexamac or indomethacin. Examples of the encapsulating substance include the following water-soluble dyes as the encapsulating substance. Examples of water-soluble dyes include red No. 104, red No. 2, red No. 3, blue No. 1, blue No. 2, yellow No. 4, yellow No. 5, green No. 3, carmine, Casamin, red yeast rice pigment, gardenia pigment, Anthocyanin pigment or chlorophyll can be mentioned.

The method for producing the liposome can be selected as appropriate, but for example, the following method can be employed as an example.
(1) An ultrasonic treatment method in which a lipid suspension is treated with ultrasonic waves.
(2) A surfactant removal method in which a mixed micelle of lipid and surfactant is formed to remove the surfactant.
(3) An organic solvent injection method in which lipids dissolved in an organic solvent are injected into a water tank to form liposomes at the interface between water and the organic solvent.
(4) A freeze-thaw method in which an aqueous solution in which lipids are suspended is frozen and then melted to form a lipid bilayer membrane, which is further freeze-thawed to form liposomes.
(5) A reverse phase evaporation method in which a small amount of an aqueous solvent is added to an organic solvent that does not dissolve in water, ultrasonic waves are applied to form a W / O emulsion (reverse micelle), and the organic solvent is removed under reduced pressure.
(6) A method using a supercritical fluid. The supercritical fluid is not particularly limited, and examples thereof include carbon dioxide, water, ethane, ethylene, propane, and nitrous oxide. A supercritical carbon dioxide method in which lipid is dissolved in a mixed fluid of carbon dioxide and ethanol, and an aqueous solution to be retained is stirred and injected in a decompression process is suitable.

  The supercritical carbon dioxide method can take various forms, but one example of this method will be described. Supercritical carbon dioxide and a co-solvent, if necessary, are pumped and passed through a column filled with phospholipids. . The phospholipid is transported to the pressure reducing valve in a state of being dissolved in a mixed fluid of carbon dioxide and a cosolvent, and is depressurized. Phospholipids precipitate during the depressurization process. At this time, an aqueous phase containing a substance to be retained (in this embodiment, a metal porphyrin complex) is allowed to flow in via a pump, and the mixture is stirred in a mixer, whereby liposomes are contained in the mixer. The method of forming is mentioned.

  In addition, an aqueous phase containing an encapsulating substance (in this embodiment, a metalloporphyrin complex) is added to a homogeneous mixed fluid of carbon dioxide and phospholipid or glycolipid under supercritical state or temperature or pressure conditions above the critical point. It is preferable that the liposome is produced by a supercritical carbon dioxide method enclosing a characteristic encapsulated substance. In this method, an aqueous phase containing a water-soluble or hydrophilic encapsulating substance is added to a mixture in which phospholipid is uniformly dissolved in carbon dioxide in a supercritical state or a temperature or pressure condition above the critical point, The object is to produce liposomes that encapsulate the encapsulated substance in one stage. Since the liposome produced by this method has high retention efficiency, it can encapsulate a larger amount of encapsulated substance than conventional liposomes. The carbon dioxide in the supercritical state means carbon dioxide in a supercritical state at a critical temperature (30.98 ° C.) and a critical pressure (7.3773 ± 0.0030 MPa), Carbon dioxide under pressure means carbon dioxide under a condition where only the critical temperature or only the critical pressure exceeds the critical condition (however, the other does not exceed the critical condition). Hereinafter, it is considered as a temporary definition that carbon dioxide under supercritical conditions or temperature or pressure conditions above the critical point is collectively referred to as “supercritical carbon dioxide”.

  The homogeneously mixed fluid that was initially transparent gradually becomes cloudy with the introduction of the aqueous phase (it is considered that reverse micelles are formed), and when the aqueous phase is further introduced, the water into the supercritical carbon dioxide (and reverse micelles) When the solubility limit is exceeded, a cloudy aqueous phase is formed at the bottom of the reaction vessel. After injecting the predetermined aqueous phase, a uniform liposome can be obtained by reducing the pressure.

  In preparing a homogeneous mixture of phospholipid and supercritical carbon dioxide, it is preferable to use a co-solvent. By adding a cosolvent to the system, it is possible to increase the solubility of the poorly soluble encapsulated material in supercritical carbon dioxide. Examples of the co-solvent include ethyl alcohol, polar solvent, dichloroethane, dichloromethane, and the like. Particularly, dichloroethane, dichloromethane, and the like are suitable for solubility when a metal porphyrin is used as an encapsulating substance.

What is necessary is just to select the addition amount of a water phase suitably in the range which can flow in a water phase with fluidity | liquidity, and the formation of a liposome is not inhibited. In addition, the metal porphyrin complex dissolved in the co-solvent without using the aqueous phase may be used, and further, a system that adds other than the aqueous phase such as an oil phase may be used. The aqueous phase is merely illustrative and does not prevent it from being replaced by anything other than the aqueous phase. The water phase is composed of water, tap water, distilled water, pure water, deep ocean water, ultrafiltration water, filtered water, groundwater, underground water, desalted water, purified water (RO water, membrane treated water). Rain water, well water, neutralized water, electrolyzed water, aqueous solution, and the like.
(Mixture of liposome and resin)
In this embodiment, an excellent heat-resistant resin product could be provided by a novel attempt to disperse liposomes that have been conventionally used in fields such as medical and cosmetics in completely different heat-resistant resin materials. . A mixing method by the dispersion will be described.

  The prepared liposome may be dried to form a solid capsule, but if it is used in the next step in a form dispersed in a liquid such as an aqueous phase, it is suitable for reducing the number of steps.

  The method of drying into solid capsules can be selected and used as appropriate. For example, interfacial deposition method, interfacial reaction method, phase separation method, submerged drying method, melt dispersion cooling method, spray drying method, panning method Examples thereof include a coating method, a freeze-drying method, an air suspension coating method, a powder bed method, an interfacial polymerization method, an in-situ polymerization method, a liquid curing coating method, an orifice method, and an interfacial reaction method.

  In the present embodiment, a description will be given in a mode in which liposomes are dispersed in a liquid such as an aqueous phase without being a solid capsule. A dispersion is prepared in which liposomes containing a metalloporphyrin complex as a functional material as a core substance are dispersed in an aqueous phase.

  The liquid in which the liposome is dispersed is not particularly limited, but is preferably a liquid generated in the liposome production process because it can be used as it is. The liquid is preferably a liquid that imparts functionality to a volatile liquid or a heat-resistant resin product that volatilizes or disappears during dispersion with a resin, heating in a molding process, decompression, or the like.

  The dispersion may be directly mixed into the resin serving as a dispersion medium and molded, but before mixing, the liposome is supported on a carrier, and the carrier on which the liposome is supported is a heat resistant resin serving as a dispersion medium. It is preferable to mix in and mold. Alternatively, it is preferable that the liposome or the carrier on which the liposome is supported is tableted as a dispersion medium before mixing, and the tablets are mixed as pellets into a resin serving as the dispersion medium and molded. The material to be tableted is not particularly limited. For example, in the case of a resin, it is preferable that the resin is a resin different from the resin serving as a dispersion medium or the same resin. In addition, it is preferable to use a resin having a good dispersibility with a resin as a dispersion medium, for example, the same resin as the resin as a dispersion medium or a similar resin. Such pellets formed into tablets can be sold alone and can provide great economic benefits. In addition, it may replace with a liposome and may use the granular material which has a particle size of 20-800 nm.

  The carrier can be appropriately selected and used, and examples thereof include waste paper, newspaper, porous material, fiber material, cellulose, zeolite, calcium carbonate and the like.

  The mixing method with the resin and the molding method can be appropriately selected and used.

  The mixing method can be appropriately selected and used. For example, a method of dispersing and mixing in a dispersion solvent using a ball mill, a sand mill, a triple roll, an attritor, a kneader or the like. Moreover, you may melt and mix with a heating type 3 roll, a heat-pressure kneader, a Banbury mixer, etc., without using a solvent etc. Here, as the dispersion solvent used for dissolution, dispersion, mixing, etc., for example, methyl ethyl ketone, cyclohexane, toluene, ethyl acetate, tetrahydrofuran, acetone, xylene, methyl isobutyl ketone, isopropyl alcohol, ethanol and the like can be used. Furthermore, a dispersion aid can be used for dispersion in order to improve dispersibility. Suitable dispersing aids include higher alcohol sulfates such as sodium lauryl sulfate, polyoxyalkylene alkyl sulfates such as sodium polyoxyethylene lauryl sulfate, and sodium n-dodecylbenzenesulfonate. Nonionics such as polyalkylene alkyl sulfonates, anionic surfactants, polyoxyalkylene higher fatty acid esters such as polyoxyethylene monolaurate, and polyoxyalkylene alkyl phenyl ethers such as polyoxyethylene nonylphenyl ether Use of a surfactant.

  Such a solvent is not particularly limited, for example, water-insoluble organic solvents such as toluene, xylene, ethyl acetate, butyl acetate, methyl ethyl ketone, methyl isobutyl ketone, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether Water-soluble organic solvents such as methanol, ethanol, isopropyl alcohol, and normal propyl alcohol, water, or mixed solvents thereof are used.

As a solvent for the aqueous coating agent, water-soluble organic solvents such as water and alcohol can be used. As the water, ordinary industrial water can be used. Further, as a water-soluble organic solvent composed of water and alcohol, it can be prepared using water, lower alcohols such as methanol, ethanol, isopropyl alcohol and N-propyl alcohol, glycols and esters thereof, and the like. . The solvent of the solvent-based coating agent is not particularly limited, and examples thereof include non-toxic solvents such as toluene, xylene, ethyl acetate, butyl acetate, methyl ethyl ketone, methyl isobutyl ketone, ethylene glycol monomethyl ether, and ethylene glycol monoethyl ether. A water-soluble organic solvent or a mixed solvent thereof may be used. (Method for molding heat-resistant resin products)
The molding method for the heat-resistant resin product can be appropriately selected and used. For example, compression molding, injection molding, stamping molding, blow molding, inflation molding, extrusion molding, extrusion lamination molding, rotational molding (Engel molding) , Calendar molding, sheet winding, injection molding, vacuum molding, spray-up method, slush molding, laminating molding, casting method, injection molding, manual molding, low-pressure molding, transfer molding, foam molding, Hayashi molding, hand lay-up method , Filament winding method, powder molding, matched die molding, reaction injection molding, SMC method (sheet molding molding compound method), T die method, axial stretching method (uniaxial stretching, biaxial stretching) and the like.
(Use of heat-resistant resin products)
The heat-resistant resin product according to the present embodiment can be applied to various uses, and the use is not limited. For example, the automotive field, the electric / electronic field, the injection molding field, the extrusion molding field, the general machine field, the film・ Can be used in fields such as seats and home appliances.

  For example, in the automotive field, radiator tanks, fans, radiator fans and other vehicle fans, fasteners, wheel caps, cylinder head covers, door handles, seat belt parts, instrument panels, electrical parts, bumpers, valves, etc. Can be mentioned.

  For example, in the electric / electronic field, connectors, coil bobbins, switch parts, washing machines, telephones, timers, compact disks, optical disks, signal tubes, terminal blocks, dryers, nozzles, OA equipment, chassis, relays, sockets, capacitors, A trans bobbin can be mentioned.

  Other examples include sash parts, sports equipment, screws, gears, rack and pinions, springs, bearings, films, monofilament products (fishnets, Tegs, etc.), printers, facsimiles, copiers, housings, cooling fans, keyboards, etc. Can do.

  Furthermore, various molded products, various films, various sheets, decorative molding sheets, decorative sheets, various bags such as plastic bags, garbage bags, and food bags, various disks such as compact discs and digital versatile disks, recording media, and contacts Lenses, glasses, glass substitute plastic products, packaging containers, everyday goods / food packs, containers in general, various plastic bottles, various vehicle products, aviation industry, airplane, space industry, ships, various interior / exterior products, toys ( Toys), various electrical appliances, rubber products, various leisure goods (fishing lines, etc.), FRP, synthetic fibers, transparent plates, optical lenses, substrates for liquid crystal display elements, substrates for color filters, substrates for organic EL display elements, solar cell substrates , Touch panel, optical element, optical waveguide, LED sealing material, transparent sheet, plasma display Spray, furniture, refrigerator, washing machine, vacuum cleaner, bed, agricultural product, fishery product, clothes, shoes, personal computer, packing product, cushioning material, filling material, bicycle, frame, various bodies, cosmetics, cosmetic packaging Car parts including containers, advertising films, motorcycles, gears, pulleys, shafts, bobbins, valves, bearings, electric parts, fan blades, lighter containers, adhesives, paints, fishing rods, connector covers, tableware, makeup Plates, fans, cases, switches, flexible disks and hubs, drive units, coil bobbins, connectors, carburetors, gas caps, protective walls, lighting fixtures, traffic light lenses, bottles, chemical plants, copy parts, heat-resistant water products, Interior materials such as aircraft interior materials, medical equipment, heat-resistant rollers, copying machines Products, camera parts, syringes, food industry valves, recording tapes, sockets, handles, coil bobbins, IC sockets, piston rings, bushings, optical fibers, lenses, optical disks, taillights, gears, cams, motor parts, fasteners, home kitchens Supplies, carburetors, high firing products, gaskets, packing, irons, frying pans, agricultural films, pipes, hoses, electric wires, insulation materials, rubber rolls, pot parts, sealing materials, condensers, roll covers, bumpers, artificial bones, fishing boats, boats , Yachts, bathtubs, tanks, axially stretched films, sliding parts (door wheels, gears, bearings, etc.), nets, tubes, metal substitutes, windshields, TV front covers, watch glasses, sandals, slippers, etc. , In place of conventional resin products You can use.

Hereinafter, the embodiment will be described in more detail.
"Example 1"
As a dispersion phase, a granular material or liposome having a particle size of 20 to 800 nm exemplified in the above embodiment is prepared, and a combination in which these are dispersed in a heat resistant resin as a dispersion medium exemplified in the above embodiment is described in JIS Z 1702. The specified strength test (tensile test and breaking elongation test, hereinafter the strength test conforms to this) was conducted.

As a result, the strength was improved in the heat resistant resin products using the respective resins. Since the same strength can be realized, the amount of resin can be reduced to half or less, and a heat-resistant resin product and a resin product having a reduced thickness can be obtained.
"Example 2"
In Example 1, the granular material as a dispersed phase was used as a core material, and a capsule composed of an outer shell material containing the core material was used.

As a result, in the heat resistant resin products using the respective resins, at least the strength of the heat resistant resin products was higher than that of Example 1.
"Example 3"
In Example 2, the outer shell material has an affinity including a resin affinity material having an affinity for the resin more than the nuclear material and a nuclear material affinity material having an affinity for the nuclear material more than the resin. Substance. A surfactant was used as the affinity substance.

As a result, in the heat resistant resin product using each resin, at least the strength of the heat resistant resin product was higher than that of Example 2.
Example 4
In Example 3, a functional material was included as a nuclear material. Functional materials are antistatic agents, carbon dioxide reducing agents, antioxidants, UV absorbers, conductive agents, colorants, metallic brighteners, lubricants, mold release agents, photopolymerization initiators, photosensitizers, and light stabilizers. , Fillers, foaming agents, flame retardants, lubricants, plasticizers, stabilizers, surfactants, thermal stabilizers, leveling agents, antifoaming agents, viscosity modifiers, molecular weight regulators, polymerization chain mediators, radical formation polymerization An initiator was used.

As a result, it was possible to provide a heat-resistant resin product in which each functional characteristic was remarkably improved.
"Example 5"
In Example 4, using the metalloporphyrin complex as a core substance, the manufactured heat-resistant resin product was burned by the method defined in JIS K 7217, and measured by gas chromatography (GC-TCD).

As a result, a carbon dioxide reduction effect was further obtained as compared with Example 4.
"Example 6"
In Example 5, a system containing a metalloporphyrin complex in liposome was burned by the method defined in JIS K 7217 and measured by gas chromatography (GC-TCD).

As a result, a carbon dioxide reduction effect was further obtained as compared with Example 4.
"Example 7"
Antistatic agent, carbon dioxide reducing agent, antioxidant, ultraviolet absorber, conductive agent, colorant, metallic brightener, lubricant, mold release agent, photopolymerization initiator, photosensitizer, as functional material in liposome Light stabilizer, Filler, Foaming agent, Flame retardant, Lubricant, Plasticizer, Stabilizer, Surfactant, Thermal stabilizer, Leveling agent, Antifoaming agent, Viscosity modifier, Molecular weight regulator, Polymer chain chain, A radical-forming polymerization initiator was included.

As a result, it was possible to provide a heat-resistant resin product in which each functional characteristic was improved as compared with Example 4.
"Example 8"
A vehicle fan is manufactured as the heat-resistant resin product of Examples 1 to 7, a strength test specified in JIS Z 1702 is performed on the vehicle fan, and a metal porphyrin complex is included in JIS K 7217. The amount of carbon dioxide was measured by gas chromatography (GC-TCD).

  Compared with the vehicle fan in which the particulate matter according to the present embodiment is not dispersed, the strength is improved as compared with the conventional product, and the carbon dioxide amount is reduced in the measured system.

Claims (24)

  A heat-resistant resin product comprising a resin layer in which particles having a particle size of 20 to 800 nm are dispersed. The heat resistant resin product according to claim 1,
The granular material is a heat-resistant resin product which is a capsule composed of a core material and an outer shell material containing the core material. The heat resistant resin product according to claim 2,
The outer shell material is
A heat-resistant resin product which is an affinity substance including a resin affinity substance having an affinity for the resin rather than the nuclear substance and a nuclear substance affinity substance having an affinity for the nuclear substance than the resin.   A heat-resistant resin product comprising a resin layer in which liposomes are dispersed as particulates. The heat resistant resin product according to claim 4,
The liposome is a heat-resistant resin product having a particle size of 20 to 800 nm. The heat-resistant resin product according to any one of claims 1 to 5,
The granular material is a heat-resistant resin product containing a functional material. The heat-resistant resin product according to any one of claims 1 to 4,
The granular material is a heat-resistant resin product containing at least one of a metal porphyrin complex and a redox polymer. The heat-resistant resin product according to claim 7,
A heat-resistant resin product in which at least one of the metal porphyrin complex and the redox polymer is contained as a nuclear substance.   A method for producing a heat-resistant resin product, comprising a dispersion step of dispersing at least one of particles having a particle diameter of 20 to 800 nm and particles having a particle size of 20 to 800 nm as a granular material as a dispersion phase in a resin layer as a dispersion medium. It is a manufacturing method of the heat resistant resin product according to claim 9,
The method for producing a heat-resistant resin product, wherein the granular material is a capsule including a core material and an outer shell material including the core material. It is a manufacturing method of the heat resistant resin product according to claim 10,
The outer shell material is
A method for producing a heat-resistant resin product, which is an affinity substance including a resin affinity substance having an affinity for the resin rather than the nuclear substance and a nuclear substance affinity substance having an affinity for the nuclear substance than the resin. It is a manufacturing method of the heat resistant resin product according to any one of claims 9 to 11,
The said granular material is a manufacturing method of the heat resistant resin product containing a functional material. It is a manufacturing method of the heat resistant resin product according to any one of claims 9 to 11,
A supporting step of supporting the granular material on a support;
A method for producing a heat-resistant resin product, wherein the dispersing step is performed by dispersing a carrier on which the particulate matter is carried. A method for producing a heat resistant resin product according to any one of claims 9 to 13,
A tableting step in which the granular material or a carrier on which the granular material is carried is used as a tablet;
The manufacturing method of the heat resistant resin product which performs the said dispersion | distribution process by disperse | distributing the said tablet in the said resin after the said tableting process. A method for producing a heat resistant resin product according to any one of claims 9 to 14,
The said granular material is a manufacturing method of the heat resistant resin product containing at least one among a metal porphyrin complex and a redox polymer. A method for producing a heat resistant resin product according to any one of claims 9 to 14,
A method for producing a heat-resistant resin product, wherein at least one of the metalloporphyrin complex and the redox polymer is contained as a nuclear substance.   Use of the granular material which uses at least one among the thing which has a particle size of 20-800 nm, and a liposome about manufacture of a heat resistant resin product as a granular material. Use of the granular material according to claim 17,
Use of a granular material, wherein the granular material is a capsule composed of a core material and an outer shell material containing the core material. Use of the granular material according to claim 18,
The outer shell material is
Use of a granular material which is an affinity substance containing a resin affinity substance having an affinity for the resin rather than the nuclear substance and a nuclear substance affinity substance having an affinity for the nuclear substance rather than the resin. Use of the granulate according to any one of claims 17 to 19, comprising
The granular material is a granular material containing a functional material. Use of the granulate according to any one of claims 17 to 20, comprising
Use of a granular material for supporting the granular material on a support. Use of the granulate according to any one of claims 17 to 21, comprising
Use of a granular material in which the granular material is a tablet. Use of the granular material according to any one of claims 17 to 22,
The granular material is a granular material containing at least one of a metalloporphyrin complex and a redox polymer. Use of the granulate according to any one of claims 17 to 23,
Use of a granular material in which at least one of the metal porphyrin complex and the redox polymer is contained as a nuclear material.