JP2007009040A - Aqueous paint - Google Patents
Aqueous paint Download PDFInfo
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- JP2007009040A JP2007009040A JP2005190912A JP2005190912A JP2007009040A JP 2007009040 A JP2007009040 A JP 2007009040A JP 2005190912 A JP2005190912 A JP 2005190912A JP 2005190912 A JP2005190912 A JP 2005190912A JP 2007009040 A JP2007009040 A JP 2007009040A
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- resin
- aqueous
- paint
- aqueous paint
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- 239000003973 paint Substances 0.000 title claims abstract description 44
- 229920005989 resin Polymers 0.000 claims abstract description 22
- 239000011347 resin Substances 0.000 claims abstract description 22
- 239000000839 emulsion Substances 0.000 claims abstract description 19
- 239000000049 pigment Substances 0.000 claims abstract description 16
- 239000004606 Fillers/Extenders Substances 0.000 claims abstract description 9
- 229920006243 acrylic copolymer Polymers 0.000 claims abstract description 6
- 229920005792 styrene-acrylic resin Polymers 0.000 claims abstract description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 6
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 6
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 3
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 229920002050 silicone resin Polymers 0.000 claims description 6
- 238000001035 drying Methods 0.000 abstract description 5
- 238000010428 oil painting Methods 0.000 abstract description 4
- 239000000945 filler Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 235000019198 oils Nutrition 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000000454 talc Substances 0.000 description 4
- 229910052623 talc Inorganic materials 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical group O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- -1 aluminum silicates Chemical class 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 235000012243 magnesium silicates Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000011049 pearl Substances 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
本発明は、水性絵具に関する。 The present invention relates to an aqueous paint.
絵具としては、油絵具のような油性絵具や、水彩絵具、アクリル絵具のような水性絵具がある。 Examples of the paint include oil-based paints such as oil paints, water-based paints such as watercolor paints and acrylic paints.
油絵具は、含量を油と補助材とともに練り合わせたもので、空気中の酸素との結合により乾燥するが、乾燥速度が遅く、数時間から数日程度かかる。また、亜麻仁油など用いる油の臭気が強いといった問題がある。アクリル絵具は、アクリルエマルジョンに顔料を溶かしたものであり、乾燥時間は早いが、油絵のような重厚な画面を作ることが難しい。 Oil paints are kneaded together with oil and auxiliary materials, and dry by the combination with oxygen in the air, but the drying speed is slow and takes several hours to several days. There is also a problem that the odor of oil used such as linseed oil is strong. Acrylic paint is made by dissolving a pigment in an acrylic emulsion and has a fast drying time, but it is difficult to make a heavy screen like an oil painting.
水性絵具と油性絵具に併用できる、水分散性アルキド樹脂を有効成分とする絵具が知られている（特許文献１参照）。 There is known a paint having a water-dispersible alkyd resin as an active ingredient that can be used in combination with an aqueous paint and an oil paint (see Patent Document 1).
本発明の目的は、乾燥時間が早く、匂いがないため作業性に優れ、油絵のような厚みのある質感を表現しながら、かつ光沢のない無機質調の仕上がりを演出することが可能な水性絵具を提供することにある。 An object of the present invention is a water-based paint that is excellent in workability because it has a quick drying time and no odor, and can produce a glossy, inorganic finish while expressing a thick texture like an oil painting. Is to provide.
本発明は、水系樹脂エマルション、体質顔料および着色顔料を含む水性絵具に関する。 The present invention relates to an aqueous paint containing an aqueous resin emulsion, an extender pigment, and a color pigment.
本発明により、乾燥時間が早く、匂いがないため作業性に優れ、油絵のような厚みのある質感を表現しながら、かつ光沢のない無機質調の仕上がりを演出することが可能な絵具が得られる。 According to the present invention, there is obtained a paint that can dry quickly and has no odor, is excellent in workability, expresses a thick texture like an oil painting, and produces a glossy inorganic finish. .
本発明の水性絵具は、水系樹脂エマルション、体質顔料および着色顔料を含む。 The aqueous paint of the present invention contains an aqueous resin emulsion, an extender pigment, and a color pigment.
水系樹脂エマルションとしては、例えば、アクリル樹脂、スチレン−アクリル樹脂、酢酸ビニル樹脂、酢酸ビニル−アクリル共重合樹脂、ウレタン樹脂、アルキルシリコン樹脂等の水系樹脂エマルションが挙げられる。これらの中では、接着性および耐水性の観点から、スチレン−アクリル樹脂、酢酸ビニル−アクリル共重合樹脂、アルキルシリコン樹脂の水系樹脂エマルションが好ましい。 Examples of the aqueous resin emulsion include aqueous resin emulsions such as acrylic resin, styrene-acrylic resin, vinyl acetate resin, vinyl acetate-acrylic copolymer resin, urethane resin, and alkyl silicone resin. Among these, from the viewpoint of adhesiveness and water resistance, a water-based resin emulsion of styrene-acrylic resin, vinyl acetate-acrylic copolymer resin, and alkyl silicone resin is preferable.
本発明の水性絵具における前記水系樹脂エマルションの含有量は、水性絵具の全量に対して樹脂固形分として、５〜３０重量％であることが好ましく、７〜２０重量％であることがより好ましい。含有量が５重量％より少ない場合には顔料の分散性や絵具としての接着性が劣り、３０重量％より多い場合に発色性が低下するために好ましくない。 The content of the water-based resin emulsion in the aqueous paint of the present invention is preferably 5 to 30% by weight, more preferably 7 to 20% by weight as the resin solid content with respect to the total amount of the aqueous paint. When the content is less than 5% by weight, the dispersibility of the pigment and the adhesiveness as a paint are inferior.
体質顔料としては特に限定されず、例えば、ベントナイト等のモンモリロナイト系粘土鉱物、シリカ、クレー、カオリン等のケイ酸アルミニウム類、タルク等の珪酸マグネシウム類、炭酸カルシウム、硫酸バリウムなどが挙げられる。これら体質顔料は、それぞれ単独で、あるいは２種以上を併用して用いてもよい。 The extender is not particularly limited, and examples thereof include montmorillonite clay minerals such as bentonite, aluminum silicates such as silica, clay and kaolin, magnesium silicates such as talc, calcium carbonate and barium sulfate. These extender pigments may be used alone or in combination of two or more.
本発明の水性絵具は、適量の体質顔料を含むことにより、前記特徴を有するものである。 The aqueous paint of the present invention has the above-mentioned characteristics by including an appropriate amount of extender pigment.
体質顔料の含有量は、水性絵具の全量に対して２５〜７５重量％であることが好ましく、３５〜６５重量％であることがより好ましい。含有量が２５重量％より少ないと、描画に厚みのある質感がえられず、７５重量％より多い場合には粘度が増加したり、チョーキングするため好ましくない。 The content of the extender is preferably 25 to 75% by weight, more preferably 35 to 65% by weight, based on the total amount of the aqueous paint. If the content is less than 25% by weight, a thick texture cannot be obtained in drawing, and if it is more than 75% by weight, the viscosity increases or choking is not preferable.
着色顔料としては特に限定されず、例えば、無機顔料、有機顔料、パール顔料、蛍光顔料などの公知の顔料を用いることができる。前記着色剤は、水性絵具組成物の全量に対して、１〜３０重量％、好ましくは、３〜２０重量％が用いられる。１重量％より少ないと発色性に劣り、３０重量％より多く用いると発色に濁りが見られる。 The color pigment is not particularly limited, and for example, known pigments such as inorganic pigments, organic pigments, pearl pigments, and fluorescent pigments can be used. The colorant is used in an amount of 1 to 30% by weight, preferably 3 to 20% by weight, based on the total amount of the aqueous paint composition. When the amount is less than 1% by weight, the color developability is inferior.
本発明の絵具には必要に応じて、防腐・防黴剤、消泡剤、紫外線吸収剤、増粘剤等を適量配合してもよい。また、光触媒作用を有する成分を添加することにより、ホルムアルデヒドなどの有害物質の吸着や分解による消臭効果等も期待できる。 The paint of the present invention may contain an appropriate amount of antiseptic / antifungal agents, antifoaming agents, ultraviolet absorbers, thickeners and the like as required. Further, by adding a component having a photocatalytic action, a deodorizing effect due to adsorption or decomposition of harmful substances such as formaldehyde can be expected.
本発明の水性絵具組成物における水の含有量は、通常、水性絵具組成物の全量に対して１０〜５０重量％の範囲である。 The water content in the aqueous paint composition of the present invention is usually in the range of 10 to 50% by weight with respect to the total amount of the aqueous paint composition.
本発明の絵具は、従来の絵具と同様の分散技術により、容易に製造できる。すなわち、ミキサーによる混合分散、ロールミル、ビーズミル等による分散等が挙げられる。 The paint of the present invention can be easily manufactured by a dispersion technique similar to that of a conventional paint. That is, mixing and dispersion by a mixer, dispersion by a roll mill, a bead mill and the like can be mentioned.
以下、実施例によって本発明を具体的に説明する。なお、実施例中「部」とあるのは「重量部」を示す。 Hereinafter, the present invention will be specifically described by way of examples. In the examples, “parts” means “parts by weight”.
実施例１
酸化チタン １０部
炭酸カルシウム ４５部
固形分２０重量％の酢酸ビニル−アクリル共重合樹脂エマルション ４５部
をロールミルで混練し、本発明の白色絵具を得た。
Example 1
10 parts of titanium oxide 45 parts of calcium carbonate 45 parts of a vinyl acetate-acrylic copolymer resin emulsion having a solid content of 20% by weight were kneaded with a roll mill to obtain the white paint of the present invention.
実施例２
カーボンブラック ５部
炭酸カルシウム ３５部
タルク ５部
固形分１８重量％のアルキルシリコン樹脂エマルション ５５部
をロールミルで混練し、本発明の黒色絵具を得た。
Example 2
Carbon black 5 parts Calcium carbonate 35 parts Talc 5 parts 55 parts of an alkyl silicone resin emulsion having a solid content of 18% by weight were kneaded with a roll mill to obtain the black paint of the present invention.
実施例３
ハンザイエロー（ビスマス・バナデート）３部
炭酸カルシウム ３０部
シリカ １０部
固形分２０重量％のスチレン−アクリル樹脂エマルション ５７部
をロールミルで混練し、本発明の黄色絵具を得た。
Example 3
Hansa Yellow (bismuth vanadate) 3 parts Calcium carbonate 30 parts Silica 10 parts Solid content 20 wt% styrene-acrylic resin emulsion 57 parts was kneaded with a roll mill to obtain the yellow paint of the present invention.
実施例４
ベンガラ（天然酸化鉄） ５部
炭酸カルシウム ３０部
タルク ５部
シリカ １０部
固形分２０重量％のスチレン−アクリル樹脂エマルション ２５部
固形分１８重量％のアルキルシリコン樹脂エマルション ２５部
をロールミルで混練し、本発明の赤色絵具を得た。
Example 4
Bengala (natural iron oxide) 5 parts Calcium carbonate 30 parts Talc 5 parts Silica 10 parts Solid content 20% by weight styrene-acrylic resin emulsion 25 parts Solid content 18% by weight alkyl silicone resin emulsion 25 parts are kneaded in a roll mill. An inventive red paint was obtained.
実施例５
群青 ６部
炭酸カルシウム ３５部
タルク １０部
シリカ ５部
固形分２０重量％の酢酸ビニル−アクリル共重合樹脂エマルション ２２部
固形分１８重量％のアルキルシリコン樹脂エマルション ２２部
をロールミルで混練し、本発明の青色絵具を得た。
Example 5
Ultramarine 6 parts Calcium carbonate 35 parts Talc 10 parts Silica 5 parts Solid content 20 wt% vinyl acetate-acrylic copolymer resin emulsion 22 parts Solid content 18 wt% alkyl silicone resin emulsion 22 parts are kneaded in a roll mill. A blue paint was obtained.
以上の実施例１〜５で得られた絵具と、市販の油絵具について比較テストを行った。実施例で得られた絵具は、水で容易に溶け、絵具の混合も簡単で、臭いもなく、また乾燥が速いため、短時間で厚みのある質感で、かつ光沢のない無機質調仕上がりの絵を仕上げることができた。さらに、水で簡単に筆やパレットの洗浄ができるため後始末も簡単であった。これに対し、油絵具では特有の臭いがあり、乾燥までに時間を要した。また、使用後の筆やパレットは溶剤で洗う必要があり、後始末に手間がかかった。 A comparative test was performed on the paints obtained in Examples 1 to 5 above and commercially available oil paints. The paints obtained in the examples dissolve easily in water, are easy to mix, have no odor, and dry quickly, so they have a thick texture in a short time and a glossy inorganic finish. Was able to finish. In addition, the brush and pallet can be easily washed with water, so cleaning up was easy. On the other hand, oil paints had a specific odor and took time to dry. In addition, the brush and palette after use had to be washed with a solvent, and it took time and effort to clean up.
本発明の絵具は、臭いがなく、乾燥時間が早いため、描画材料として好適に用いることができる。
Since the paint of the present invention has no odor and quick drying time, it can be suitably used as a drawing material.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005190912A JP2007009040A (en) | 2005-06-30 | 2005-06-30 | Aqueous paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005190912A JP2007009040A (en) | 2005-06-30 | 2005-06-30 | Aqueous paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007009040A true JP2007009040A (en) | 2007-01-18 |
| JP2007009040A5 JP2007009040A5 (en) | 2008-07-10 |
Family
ID=37747950
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2005190912A Pending JP2007009040A (en) | 2005-06-30 | 2005-06-30 | Aqueous paint |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2007009040A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101348636B (en) * | 2007-07-16 | 2011-03-30 | 韩康城 | Environment-friendly type aqueous paint for marine shrimp pond |
| CN101298529B (en) * | 2007-04-30 | 2011-08-17 | 韩康城 | Physical mildewproof antibiotic waterborne environment-protective paint |
| CN103160198A (en) * | 2011-12-13 | 2013-06-19 | 金甲化工企业(中山)有限公司 | Apple fragrant colorful super wear-resistant oily elastic paint |
| CN105838164A (en) * | 2016-05-19 | 2016-08-10 | 惠州市彩田化工实业有限公司 | Aqueous nano-antibacterial sound absorption coating and preparation method thereof |
| CN105949908A (en) * | 2016-07-01 | 2016-09-21 | 许宏俊 | Aqueous granite coating |
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| JPH07102191A (en) * | 1993-09-30 | 1995-04-18 | Pentel Kk | Aqueous pigment composition |
| JPH08199093A (en) * | 1995-01-26 | 1996-08-06 | Pentel Kk | Aqueous pigment composition |
| JPH08231896A (en) * | 1995-02-27 | 1996-09-10 | Pentel Kk | Aqueous pigment composition |
| JPH09208858A (en) * | 1995-03-30 | 1997-08-12 | Pentel Kk | Compositions such as paints and drawing materials |
| JP2001200208A (en) * | 2000-01-18 | 2001-07-24 | Sakura Color Prod Corp | Glittering emulsion type colors composition |
| JP2002088310A (en) * | 2000-09-13 | 2002-03-27 | Sakura Color Prod Corp | Watercolor composition |
| JP2002192899A (en) * | 2000-12-27 | 2002-07-10 | Asahi Kasei Kogyo Kk | Pigment and undercoating for painting which can be used both for water-based colors and oily-based colors |
| JP2003041127A (en) * | 2001-08-01 | 2003-02-13 | Sakura Color Prod Corp | Resin composition |
| JP2003221552A (en) * | 2002-01-31 | 2003-08-08 | Pentel Corp | Discolorable gloss drawing material |
| JP2004300289A (en) * | 2003-03-31 | 2004-10-28 | Pentel Corp | Liquid drawing material |
| JP2006036966A (en) * | 2004-07-28 | 2006-02-09 | Pentel Corp | Aqueous pigment composition |
| JP2006225534A (en) * | 2005-02-18 | 2006-08-31 | Sakura Color Prod Corp | Aqueous fluorescent paint composition |
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