JP2006282512A - Pre-treating agent for hair color - Google Patents
Pre-treating agent for hair color Download PDFInfo
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- JP2006282512A JP2006282512A JP2005100796A JP2005100796A JP2006282512A JP 2006282512 A JP2006282512 A JP 2006282512A JP 2005100796 A JP2005100796 A JP 2005100796A JP 2005100796 A JP2005100796 A JP 2005100796A JP 2006282512 A JP2006282512 A JP 2006282512A
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- 230000037308 hair color Effects 0.000 title claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 30
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 7
- 239000001913 cellulose Substances 0.000 claims abstract description 7
- 229920002678 cellulose Polymers 0.000 claims abstract description 7
- 230000006378 damage Effects 0.000 abstract description 13
- 230000002542 deteriorative effect Effects 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 210000004209 hair Anatomy 0.000 description 23
- 238000011156 evaluation Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 5
- 238000004043 dyeing Methods 0.000 description 4
- -1 fatty acid esters Chemical class 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 102000011782 Keratins Human genes 0.000 description 2
- 108010076876 Keratins Proteins 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 230000003700 hair damage Effects 0.000 description 2
- 239000000118 hair dye Substances 0.000 description 2
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001184 polypeptide Polymers 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 102000004196 processed proteins & peptides Human genes 0.000 description 2
- 108090000765 processed proteins & peptides Proteins 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- PNPGGDMWIMWCAA-UHFFFAOYSA-N [Cl-].CC(=C)C(=O)CC[NH3+] Chemical compound [Cl-].CC(=C)C(=O)CC[NH3+] PNPGGDMWIMWCAA-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 229920006319 cationized starch Polymers 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000004154 testing of material Methods 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
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- Cosmetics (AREA)
Abstract
Description
本発明は、ヘアカラー施術前に使用する前処理剤に関するものである。本発明によれば、ヘアカラー施術における毛髪のダメージを抑制し、さらに、施術後の毛髪のコンディションを改善するのに有効である。 The present invention relates to a pretreatment agent used before hair color treatment. According to the present invention, it is effective to suppress hair damage in hair color treatment and to improve the condition of hair after the treatment.
近年、ヘアカラーは年齢を問わず一般的になってきているが、それと同時にヘアカラーによる毛髪のダメージも深刻化している。ヘアカラーの主流である酸化染毛剤は酸化反応を伴うため、アルカリ剤や酸化剤により毛髪に大きなダメージを与えてしまう。また、ダメージ度合いによりヘアカラーの染色性が異なり、結果として染めムラとなることも問題視されている。 In recent years, hair color has become common regardless of age, but at the same time, damage to hair by hair color has become serious. Oxidative hair dyes, which are the mainstream of hair coloring, are accompanied by an oxidation reaction, so that the hair is seriously damaged by alkaline agents and oxidizing agents. In addition, the dyeing property of the hair color varies depending on the degree of damage, and as a result, dyeing unevenness is also regarded as a problem.
そこで、上記の欠点を解決するために、特開２００４−３２３４２３のようにヘアカラー施術前に主に毛髪内のダメージ部分に動物性、植物性ポリペプチドを補うことでダメージ、染色性を改善させる前処理剤や、特開２００２−１１４６４３のように施術後、ヘアカラーにより受けたダメージをポリペプチドやＣＭＣ擬似成分により補修させる働きを持つ後処理剤が一般的に使用されている。しかし、いずれのものもヘアカラー施術によるダメージを抑制する作用は有していない。 Therefore, in order to solve the above-described drawbacks, as described in JP-A-2004-323423, damage and dyeability are improved by supplementing animal and plant polypeptides mainly in damaged portions in hair before hair color treatment. In general, a pretreatment agent or a posttreatment agent having a function of repairing damage caused by a hair color with a polypeptide or a CMC pseudo component after treatment as disclosed in JP-A No. 2002-114643 is used. However, none of them has an effect of suppressing damage caused by hair coloring treatment.
本発明の課題は、ヘアカラー施術によるダメージを抑制する作用を有すると共に染色性、色味を損ねない特徴を持つものを提供する An object of the present invention is to provide an object that has an effect of suppressing damage caused by hair color treatment and has characteristics that do not impair dyeability and color.
即ち、本発明はカチオン化セルロース０．５〜１０重量％、カチオン界面活性剤０．５〜２０重量％を組み合わせることにより成り立つものである。また、この前処理剤を用いて毛髪を処理するに当たっては、この前処理剤を毛髪に塗布した後、ヘアカラー施術を行なえば良い。 That is, the present invention is realized by combining 0.5 to 10% by weight of cationized cellulose and 0.5 to 20% by weight of a cationic surfactant. Moreover, in treating hair using this pretreatment agent, after applying this pretreatment agent to hair, a hair color treatment may be performed.
本発明のヘアカラー用前処理剤を毛髪に塗布後、通常のヘアカラー処理を行うことによって、毛髪の染色性、色味へ影響を及ぼさず、ヘアカラーによるダメージを抑制することができる。また、ヘアカラーすすぎ時、シャンプーすすぎ時のすべりが非常に優れているため、二次的なダメージをも抑制することが出来る。 By applying the hair color pretreatment agent of the present invention to the hair and then performing a normal hair color treatment, the hair color can be prevented from being damaged without affecting the dyeability and color of the hair. Moreover, since the slip at the time of hair color rinsing and shampoo rinsing is very excellent, secondary damage can be suppressed.
まず、本発明のヘアカラー用前処理剤を詳細に説明する。 First, the hair color pretreatment agent of the present invention will be described in detail.
本発明の処理剤中には、カチオン化セルロース０．５〜１０重量％、カチオン界面活性剤０．５〜２０重量％を組み合わせることにより成り立っている。カチオン化セルロースは０．５〜１０質量％が好ましく、より好ましくは１〜５重量％とするのが良い。０．５重量％以下になるとヘアカラーすすぎ時の感触が悪くなり、また、ダメージ抑制能も低くなる。一方、１０重量％以上添加すると比率が高くなるにつれこの系は成り立たなくなる。カチオン界面活性剤は０．５〜２０重量％が好ましく、より好ましくは２〜１０重量％とするのが良い。２０重量％以上になるとヘアカラーの染色性が悪くなり、色味の変化も生じる。０．５重量％以下であるとヘアカラーすすぎ時、乾燥時の感触が悪くなる。 In the processing agent of this invention, it consists of combining 0.5-10 weight% of cationized cellulose, and 0.5-20 weight% of cationic surfactant. The cationized cellulose is preferably 0.5 to 10% by weight, more preferably 1 to 5% by weight. When the amount is 0.5% by weight or less, the feel when rinsing the hair color is deteriorated, and the damage suppressing ability is also lowered. On the other hand, the addition of 10% by weight or more makes this system impossible as the ratio increases. The cationic surfactant is preferably 0.5 to 20% by weight, more preferably 2 to 10% by weight. If it is 20% by weight or more, the dyeing property of the hair color is deteriorated and the color changes. When it is 0.5% by weight or less, the hair color rinses and feels dry.
カチオン界面活性剤としては、塩化ラウリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化ジステアリルジメチルアンモニウム等が挙げられる。 Examples of the cationic surfactant include lauryl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride and the like.
その他、本発明の前処理剤に加えても良い添加剤として、両性、及び、ノニオン界面活性剤、カチオン性重合体、両性ポリマー、増粘剤、香料、防腐剤、紫外線吸収剤、酸化防止剤、殺菌剤、金属封鎖剤などを効果を損なわない範囲で配合することが出来る。両性界面活性剤としては、アルキルベタイン、アルキルアミドプロピルベタイン、イミダゾリニウムベタイン等が挙げられる。ノニオン界面活性剤としては、ポリグリセリン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンアルキルエーテル等が挙げられる。カチオン性重合体としては、カチオン化グアーガム、カチオン化デンプン、カチオン化ケラチン、カチオン化コラーゲン等が挙げられる。両性ポリマーとしては、塩化メタクリロイルエチルアンモニウムとメタクリル酸からなる共重合体、メタクリロイルオキシエチルカルボキシベタインとメタクリル酸からなる共重合体等が挙げられる。増粘剤としては、キサンタンガム等が挙げられる。 As other additives that may be added to the pretreatment agent of the present invention, amphoteric and nonionic surfactants, cationic polymers, amphoteric polymers, thickeners, fragrances, preservatives, ultraviolet absorbers, antioxidants In addition, a bactericidal agent, a metal sequestering agent and the like can be blended within a range that does not impair the effect. Examples of amphoteric surfactants include alkyl betaines, alkylamidopropyl betaines, imidazolinium betaines, and the like. Nonionic surfactants include polyglycerin fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene alkyl ethers, and the like. Examples of the cationic polymer include cationized guar gum, cationized starch, cationized keratin, and cationized collagen. Examples of the amphoteric polymer include a copolymer composed of methacryloylethylammonium chloride and methacrylic acid, and a copolymer composed of methacryloyloxyethylcarboxybetaine and methacrylic acid. Examples of the thickener include xanthan gum.
以下、本発明を実施例を挙げてより具体的に詳細に説明するが、本発明はこれらの実施例に限定されるものではない。実施例に先立ち、実施例で用いた評価法を説明する。 EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated in detail more concretely, this invention is not limited to these Examples. Prior to the examples, the evaluation methods used in the examples will be described.
（染毛試験）
人毛の毛束１０ｇに対し、実施例、比較例に基づき調製されたヘアカラー用前処理剤を２ｇ塗布し、続いてヘアカラー剤を１０ｇ塗布した。３５℃で３０分間放置してから洗浄し、風乾した。専門パネラー１０名により、それぞれの毛束について目視により染色性、色味の変化を観察した。評価基準は以下の通りである。
(Hair dye test)
2 g of the hair color pretreatment agent prepared based on Examples and Comparative Examples was applied to 10 g of human hair bundles, followed by 10 g of the hair color agent. It was allowed to stand at 35 ° C. for 30 minutes, washed and air dried. Ten professional panelists visually observed changes in the dyeability and color of each hair bundle. The evaluation criteria are as follows.
評価基準［染色性］
◎：染色性が非常に優れている
○：染色性が優れている
△：染色性が劣る
×：染色性が非常に劣る
評価基準［色味の変化］
◎：全く色味の変化が認められない
○：僅かに色味の変化が認められる
△：色味の変化が認められる
×：非常に色味が変化している
（官能評価）
染毛試験を行なう毛束を用いて、ヘアカラーすすぎ時の感触、風乾後の毛髪の感触、傷み具合等を評価した。評価基準は以下の通りである。
Evaluation criteria [dyeability]
◎: Excellent dyeability ○: Excellent dyeability △: Inferior dyeability ×: Very inferior dyeability Evaluation criteria [Change in color]
A: No change in color is observed. O: A slight change in color is observed. Δ: A change in color is observed. X: Very much change in color (sensory evaluation)
Using the hair bundles subjected to the hair dyeing test, the feel when rinsing the hair color, the feel of the hair after air drying, the degree of damage, etc. were evaluated. The evaluation criteria are as follows.
評価基準［コンディショニング効果］
◎：ほとんどひっかかりがなく非常にすべりが良い
○：僅かにひっかかるがすべりが良い
△：ひっかかりがあり、すべりが悪い
×：かなりひっかかり、すべりが非常に悪い
評価基準［毛髪ダメージ］
◎：ほとんど傷んでいない
○：傷みが少ない
△：傷みが認められる
×：かなり傷んでいる
Evaluation criteria [conditioning effect]
◎: Almost no snagging and very good sliding ○: Slightly snagging but good sliding △: There is snagging and poor sliding ×: Quite snagging and very poor sliding Evaluation criteria [Hair damage]
◎: Almost not damaged ○: Little damage △: Damage is recognized ×: Very damaged
以上の各評価については、処理剤を用いずにヘアカラー処理した人毛毛束を比較対照とした。
For each of the above evaluations, a human hair bundle treated with a hair color without using a treatment agent was used as a comparative control.
各評価の結果は、表１、表２の下段に示す通りである。 The results of each evaluation are as shown in the lower part of Tables 1 and 2.
実施例１〜９より明らかなように、本発明のヘアカラー用前処理剤は、いずれも優れた性能を示した。 As is clear from Examples 1 to 9, all the hair color pretreatment agents of the present invention exhibited excellent performance.
一方、カチオン化セルロース、及び、カチオン界面活性剤が本発明の範囲下限以下の場合（比較例１及び４）、また、範囲上限以上の場合（比較例２及び５）、さらに、セルロース以外のカチオン性重合体（比較例３）は、いずれも劣った性能を示し、本発明の目的を達成できなかった。 On the other hand, when the cationized cellulose and the cationic surfactant are below the lower limit of the present invention (Comparative Examples 1 and 4), when they are higher than the upper limit of the range (Comparative Examples 2 and 5), and cations other than cellulose. Each of the functional polymers (Comparative Example 3) showed inferior performance and could not achieve the object of the present invention.
（摩擦係数測定）
下記の処方に基づき調製された前処理剤１、及び、前処理剤２を処理し繰り返しヘアカラー施術を行なった人毛毛束の摩擦係数の測定を行なった。摩擦係数の測定方法は以下に示す通りである。まず、前処理剤１、または２を塗布しヘアカラー処理した毛束のヘアカラーすすぎ時、及び、その後のシャンプーすすぎ時の毛束の摩擦係数を摩擦係数測定機（「摩擦感テスター ＫＥＳ−ＳＥ」カトーテック株式会社）を用いて測定した。測定結果を表３に示す。
［前処理剤１］
塩化Ｏ-[２-ヒドロキシ-３-(トリメチルアン
モニオ)プロピル]ヒドロキシエチルセルロース ２％
塩化セチルトリメチルアンモニウム ３％
メタクリロイルエチルジメチルベタイン・塩化
メタクリロイルエチルトリメチルアンモニウム
メタクリル酸２-ヒドロキシエチル共重合体液 ０．５％
イミダゾリニウムベタイン １％
塩化ヒドロキシプロピルトリモニウムデンプン ０．１％
精製水 残部
［前処理剤２］
加水分解ケラチン液 １０％
パラオキシ安息香酸エステル ０．１％
フェノキシエタノール ０．４％
精製水 残部
(Friction coefficient measurement)
The friction coefficient of the human hair bundle which processed the pre-treatment agent 1 and the pre-treatment agent 2 prepared based on the following prescription and performed the hair color treatment repeatedly was measured. The method for measuring the friction coefficient is as follows. First, the coefficient of friction of the hair bundle at the time of hair color rinsing of the hair bundle that has been pre-treated with the pretreatment agent 1 or 2 and subjected to hair color treatment, and the subsequent shampoo rinse is measured by a friction coefficient measuring machine (“friction feeling tester KES-SE “Catotech Co., Ltd.)”. Table 3 shows the measurement results.
[Pretreatment agent 1]
O- [2-Hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride 2%
Cetyltrimethylammonium chloride 3%
Methacryloylethyldimethylbetaine / methacryloylethyltrimethylammonium chloride 2-hydroxyethyl methacrylate copolymer solution 0.5%
1% imidazolinium betaine
Hydroxypropyltrimonium chloride starch 0.1%
Purified water remainder [Pretreatment agent 2]
Hydrolyzed keratin solution 10%
Paraoxybenzoate 0.1%
Phenoxyethanol 0.4%
Purified water balance
上記の結果からも明らかなように、本発明のヘアカラー用前処理剤（前処理剤１）は前処理なし、前処理剤２に比べ優れたすべりの良さを示した。また、本発明の前処理剤を用い、ヘアカラーを繰り返す度に前処理なし、前処理剤２との差は大きくなり、より優れた性能を有していることが示された。
As is clear from the above results, the hair color pretreatment agent (pretreatment agent 1) of the present invention had no pretreatment and showed superior sliding properties compared to the pretreatment agent 2. In addition, using the pretreatment agent of the present invention, each time the hair color was repeated, there was no pretreatment, and the difference from the pretreatment agent 2 was increased, indicating that it had better performance.
次に、本発明のヘアカラー用前処理剤を用いて繰り返しヘアカラー処理した人毛毛束の破断強度を測定した。測定方法は次の通りである。まず、本発明の前処理剤を用いて、ヘアカラー処理を１２回繰り返した人毛毛束から毛髪１０本を任意に選抜し、引張試験測定機（「卓上型材料試験機 ＳＴＡ−１１５０」オリエンテック株式会社）を用いて毛髪の各部位の破断強伸度を測定し、未処理毛の強度、及び、伸度を１００％としたときのそれぞれの試料の保持率を算出した。実験結果は表４に示す。 Next, the breaking strength of human hair bundles that were repeatedly subjected to hair color treatment using the hair color pretreatment agent of the present invention was measured. The measuring method is as follows. First, using the pretreatment agent of the present invention, 10 hairs were arbitrarily selected from a human hair bundle obtained by repeating the hair color treatment 12 times, and a tensile test measuring machine (“Desktop Material Testing Machine STA-1150” Orientec) Was used to measure the breaking strength and elongation of each part of the hair, and the strength of the untreated hair and the retention rate of each sample when the elongation was 100% were calculated. The experimental results are shown in Table 4.
上記の結果より、本発明の前処理剤はヘアカラーによるダメージを抑制し、毛髪の各部位において破断強伸度の高い保持率を示し、優れた性能を有していることが明らかとなった。
From the above results, it was clarified that the pretreatment agent of the present invention suppresses damage caused by the hair color, exhibits a high retention of breaking strength and elongation at each part of the hair, and has excellent performance. .
Claims (1)
（Ａ）カチオン化セルロース ０．５〜１０重量％
（Ｂ）カチオン界面活性剤 ０．５〜２０重量％
A hair color pretreatment agent comprising the following components (A) and (B):
(A) Cationized cellulose 0.5 to 10% by weight
(B) Cationic surfactant 0.5 to 20% by weight
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005100796A JP2006282512A (en) | 2005-03-31 | 2005-03-31 | Pre-treating agent for hair color |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005100796A JP2006282512A (en) | 2005-03-31 | 2005-03-31 | Pre-treating agent for hair color |
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| Publication Number | Publication Date |
|---|---|
| JP2006282512A true JP2006282512A (en) | 2006-10-19 |
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| JP2005100796A Pending JP2006282512A (en) | 2005-03-31 | 2005-03-31 | Pre-treating agent for hair color |
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| JP (1) | JP2006282512A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010101253A1 (en) | 2009-03-06 | 2010-09-10 | 株式会社 資生堂 | Hair treatment composition |
| JP2011026258A (en) * | 2009-07-28 | 2011-02-10 | Hoyu Co Ltd | Scalp-protecting agent composition |
| JP2013063948A (en) * | 2011-09-01 | 2013-04-11 | Shiseido Co Ltd | Composition for pretreatment for hair coloring |
| WO2015056730A1 (en) * | 2013-10-17 | 2015-04-23 | 資生ケミカル株式会社 | Method for dyeing keratin fibers, keratin fiber dye |
-
2005
- 2005-03-31 JP JP2005100796A patent/JP2006282512A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010101253A1 (en) | 2009-03-06 | 2010-09-10 | 株式会社 資生堂 | Hair treatment composition |
| KR20170048617A (en) | 2009-03-06 | 2017-05-08 | 가부시키가이샤 시세이도 | Hair treatment composition |
| JP2011026258A (en) * | 2009-07-28 | 2011-02-10 | Hoyu Co Ltd | Scalp-protecting agent composition |
| JP2013063948A (en) * | 2011-09-01 | 2013-04-11 | Shiseido Co Ltd | Composition for pretreatment for hair coloring |
| WO2015056730A1 (en) * | 2013-10-17 | 2015-04-23 | 資生ケミカル株式会社 | Method for dyeing keratin fibers, keratin fiber dye |
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