JP2006081516A - Baked confectionery - Google Patents
Baked confectionery Download PDFInfo
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- JP2006081516A JP2006081516A JP2004272492A JP2004272492A JP2006081516A JP 2006081516 A JP2006081516 A JP 2006081516A JP 2004272492 A JP2004272492 A JP 2004272492A JP 2004272492 A JP2004272492 A JP 2004272492A JP 2006081516 A JP2006081516 A JP 2006081516A
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- mass
- milk
- baked confectionery
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Landscapes
- Confectionery (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
Abstract
【課題】 保存性が良好であるにもかかわらず、ソフトでしっとりした食感で、風味や保型性が良好な焼菓子類を提供すること。
【解決手段】 水分活性が0.6〜0.75であり、且つ水分含量が9.3〜15質量%であって、好ましくはゲル化剤と乳蛋白質と水とで構成される複合体を混練した生地を焼成することにより得られた焼菓子類。
【選択図】 なし
PROBLEM TO BE SOLVED: To provide a baked confectionery having a soft and moist texture and having a good flavor and shape retaining property despite good storage.
SOLUTION: A complex having a water activity of 0.6 to 0.75 and a water content of 9.3 to 15% by mass, preferably composed of a gelling agent, milk protein and water. Baked confectionery obtained by baking the kneaded dough.
[Selection figure] None
Description
本発明は、保存性が良好であるにもかかわらず、ソフトでしっとりした食感で、風味や保型性が良好な焼菓子類に関する。 The present invention relates to a baked confectionery having a soft and moist texture, and having a good flavor and shape-retaining property in spite of good storage stability.
ソフトな食感と長期貯蔵寿命を有するソフトクッキーとして、特許文献1があげられる。
特許文献1には、ソフトな食感と長期貯蔵寿命を有するソフトクッキーとして、少なくとも6重量%の水分含有率および約0.7未満の水分活性であるソフトクッキーが開示されている。しかし、特許文献1に具体的に記載されている水分活性と水分含有率では、ソフトさやしっとりした食感が乏しいものであった。
Patent Document 1 discloses a soft cookie having a water content of at least 6% by weight and a water activity of less than about 0.7 as a soft cookie having a soft texture and a long shelf life. However, with the water activity and water content specifically described in Patent Document 1, soft and moist texture was poor.
したがって、本発明の目的は、保存性が良好であるにもかかわらず、ソフトでしっとりした食感で、風味や保型性が良好な焼菓子類を提供することにある。 Accordingly, an object of the present invention is to provide a baked confectionery having a soft and moist texture, and having a good flavor and shape retaining property, despite having good storage stability.
本発明は、上記目的を、水分活性が0.6〜0.75であり、且つ水分含量が9.3〜15質量%であることを特徴とする焼菓子類を提供することにより達成したものである。 The present invention has achieved the above object by providing a baked confectionery characterized by having a water activity of 0.6 to 0.75 and a water content of 9.3 to 15% by mass. It is.
本発明によれば、保存性が良好であるにもかかわらず、ソフトでしっとりした食感で、風味や保型性が良好な焼菓子類が得られる。 According to the present invention, baked confectionery having a soft and moist texture and good flavor and shape retention can be obtained despite good storage.
以下、本発明の焼菓子類について詳述する。
本発明の焼菓子類の水分活性は、0.6〜0.75、好ましくは0.62〜0.73、さらに好ましくは0.65〜0.7である。焼菓子類の水分活性が0.6よりも低いと、しっとりとした食感が感じられず、パサパサとした食感となるのでので好ましくない。焼菓子類の水分活性が0.75よりも高いと、保存性が悪くなるため好ましくない。
上記の焼菓子類の水分活性の測定方法としては、特に制限はないが、例えばNOVASINA社製測定機「AW−SPRINT TH−500」(測定温度は25℃)により測定することができる。
Hereinafter, the baked confectionery of the present invention will be described in detail.
The water activity of the baked confectionery of the present invention is 0.6 to 0.75, preferably 0.62 to 0.73, and more preferably 0.65 to 0.7. If the water activity of the baked confectionery is lower than 0.6, it is not preferable because a moist texture is not felt and a texture that is crisp. If the water activity of the baked confectionery is higher than 0.75, the storage stability is deteriorated, which is not preferable.
Although there is no restriction | limiting in particular as a measuring method of the water activity of said baked confectionery, For example, it can measure with the measuring machine "AW-SPLINTH-500" (measurement temperature is 25 degreeC) by NOVASINA.
本発明の焼菓子類の水分含量は、9.3〜15質量%であり、好ましくは9.5〜14質量%、さらに好ましくは10〜13質量%である。焼菓子類の水分含量が9.3質量%よりも低いと、しっとりとした食感が感じられず、パサパサとした食感となるのでので好ましくない。焼菓子類の水分含量が15質量%よりも高いと、保存性が悪くなるため好ましくない。
上記の焼菓子類の水分含量の測定方法としては、特に制限はないが、例えばKett社社製測定機「FD−230」により測定することができる。
The moisture content of the baked confectionery of this invention is 9.3-15 mass%, Preferably it is 9.5-14 mass%, More preferably, it is 10-13 mass%. If the moisture content of the baked confectionery is lower than 9.3% by mass, a moist texture is not felt, and a texture that is papasa is obtained, which is not preferable. If the moisture content of the baked confectionery is higher than 15% by mass, the storage stability is deteriorated, which is not preferable.
Although there is no restriction | limiting in particular as a measuring method of the moisture content of said baked confectionery, For example, it can measure with the measuring machine "FD-230" by a Kett company.
本発明の焼菓子類は、上記の水分活性と水分含量とする必要があり、例えば、ゲル化剤と乳蛋白質と水とで構成される複合体(以下、複合体という)を焼菓子類生地に混練し、該生地を焼成することにより実現することができる。 The baked confectionery of the present invention needs to have the above-mentioned water activity and water content. For example, a baked confectionery dough is a complex composed of a gelling agent, milk protein and water (hereinafter referred to as a complex). It can be realized by kneading and baking the dough.
上記複合体を構成するゲル化剤としては、特に制限はないが、アルギン酸、アルギン酸アンモニウム、アルギン酸カリウム、アルギン酸カルシウム、アルギン酸ナトリウム、アルギン酸プロピレングリコールエステル、ペクチン、LMペクチン、HMペクチン、海藻抽出物、海藻エキス、寒天、グルコマンナン、ローカストビーンガム、グアーガム、ジェランガム、タラガントガム、キサンタンガム、カラギーナン、カードラン、タマリンドシードガム、カラヤガム、タラガム、トラガントガム、アラビアガム等が挙げられ、これらの中から選ばれた1種または2種以上が用いられる。
上記複合体中の上記ゲル化剤の含有量は、好ましくは0.1〜3質量%、さらに好ましくは0.2〜2.5質量%、最も好ましくは0.25〜2.3質量%である。ゲル化剤の含有量が0.1質量%よりも少ない複合体を混練した焼菓子類は、しっとりした食感を感じにくく、ゲル化剤の含有量が3質量%よりも多い複合体を混練した焼菓子類は、口中でべとつきやすく、また口溶けが悪くなりやすい。
The gelling agent constituting the complex is not particularly limited, but alginic acid, ammonium alginate, potassium alginate, calcium alginate, sodium alginate, propylene glycol ester alginate, pectin, LM pectin, HM pectin, seaweed extract, seaweed Extract, agar, glucomannan, locust bean gum, guar gum, gellan gum, tarragant gum, xanthan gum, carrageenan, curdlan, tamarind seed gum, caraya gum, tara gum, tragacanth gum, gum arabic, etc. Or 2 or more types are used.
The content of the gelling agent in the complex is preferably 0.1 to 3% by mass, more preferably 0.2 to 2.5% by mass, and most preferably 0.25 to 2.3% by mass. is there. The baked confectionery kneaded with a complex having a gelling agent content less than 0.1% by mass is less likely to feel a moist texture, and the gelling agent content is greater than 3% by mass. The baked confectionery is easily sticky in the mouth and the mouth melts easily.
上記ゲル化剤として、好ましくはアルギン酸、アルギン酸アンモニウム、アルギン酸カリウム、アルギン酸カルシウム、アルギン酸ナトリウム、LMペクチン、海藻抽出物、海藻エキス、寒天、グルコマンナン、ローカストビーンガム、グアーガムの中から選ばれた1種または2種以上を用いるのがよく、さらに好ましくはアルギン酸、アルギン酸アンモニウム、アルギン酸カリウム、アルギン酸カルシウム、アルギン酸ナトリウム、LMペクチン、海藻抽出物、海藻エキス、寒天、グルコマンナンの中から選ばれた1種または2種以上を用いるのがよく、最も好ましくはアルギン酸、アルギン酸アンモニウム、アルギン酸カリウム、アルギン酸カルシウム、アルギン酸ナトリウム、LMペクチン、海藻抽出物、海藻エキス、寒天、グルコマンナンの中から選ばれた1種または2種以上(以下、ゲル化剤Aという)と、ローカストビーンガム、グアーガム、キサンタンガムの中から選ばれた1種または2種以上(以下、ゲル化剤Bという)を併用して用いるのがよい。
上記のゲル化剤Aとゲル化剤Bとを併用する場合、ゲル化剤A:ゲル化剤Bの重量比率を好ましくは1:0.01〜1、さらに好ましくは1:0.02〜0.5、最も好ましくは1:0.03〜0.3とする。
The gelling agent is preferably one selected from alginic acid, ammonium alginate, potassium alginate, calcium alginate, sodium alginate, LM pectin, seaweed extract, seaweed extract, agar, glucomannan, locust bean gum, guar gum Or two or more kinds may be used, more preferably one selected from alginic acid, ammonium alginate, potassium alginate, calcium alginate, sodium alginate, LM pectin, seaweed extract, seaweed extract, agar, glucomannan or Two or more types should be used, most preferably alginic acid, ammonium alginate, potassium alginate, calcium alginate, sodium alginate, LM pectin, seaweed extract, seaweed extract, agar, glucoma One or more selected from Nan (hereinafter referred to as gelling agent A) and one or more selected from locust bean gum, guar gum and xanthan gum (hereinafter referred to as gelling agent B) In combination).
When the above-mentioned gelling agent A and gelling agent B are used in combination, the weight ratio of gelling agent A: gelling agent B is preferably 1: 0.01 to 1, more preferably 1: 0.02 to 0. .5, most preferably 1: 0.03-0.3.
上記ゲル化剤のアルギン酸やアルギン酸塩(アルギン酸アンモニウム、アルギン酸カリウム、アルギン酸カルシウム、アルギン酸ナトリウム)は、低粘性のもの、中粘性のもの、高粘性のものの中から選ばれた1種または2種以上を用いることができる。
上記の低粘性のアルギン酸や低粘性のアルギン酸塩とは、その1質量%水溶液をB型粘度計でpH7、25℃、30rpmの条件下で測定したときの粘度が、1mPa・s以上10mPa・s未満のものである。
上記の中粘性のアルギン酸や中粘性のアルギン酸塩とは、上記と同じ条件で粘度を測定したときの粘度が、10〜100mPa・sのものである。
上記の高粘性のアルギン酸や高粘性のアルギン酸塩とは、上記と同じ条件で粘度を測定したときの粘度が、100mPa・sを超えるものである。
Alginic acid and alginates (ammonium alginate, potassium alginate, calcium alginate, sodium alginate) of the above gelling agent are one or more selected from low viscosity, medium viscosity, and high viscosity. Can be used.
The low-viscosity alginic acid or the low-viscosity alginate is a viscosity of 1 mPa · s or more and 10 mPa · s when a 1% by mass aqueous solution is measured with a B-type viscometer at pH 7, 25 ° C., 30 rpm. Less than.
The above-mentioned medium-viscosity alginic acid or medium-viscosity alginate has a viscosity of 10 to 100 mPa · s when the viscosity is measured under the same conditions as described above.
The high-viscosity alginic acid or the high-viscosity alginate has a viscosity exceeding 100 mPa · s when the viscosity is measured under the same conditions as described above.
上記複合体中の水の含有量は、好ましくは30〜98質量%、さらに好ましくは35〜90質量%、最も好ましくは40〜90質量%である。なお、ここでいう水とは、水道水や天然水などの水や、牛乳、液糖などの水分を含有する食品中の水分も含めたものである。水の含有量が30質量%よりも少ない複合体を混練した焼菓子類は、口中でべとつきやすく、また口溶けが悪くなりやすい。また水の含有量が98質量%よりも多い複合体を混練した焼菓子類は、しっとり感を感じにくい食感となりやすい。 The water content in the composite is preferably 30 to 98% by mass, more preferably 35 to 90% by mass, and most preferably 40 to 90% by mass. In addition, the water here includes water in foods containing water such as tap water and natural water, and milk and liquid sugar. Baked confectionery kneaded with a composite having a water content of less than 30% by mass tends to be sticky in the mouth and poorly melts in the mouth. In addition, baked confectionery kneaded with a composite having a water content greater than 98% by mass tends to have a moist feeling.
上記複合体を構成する乳蛋白質としては、特に制限されるものではないが、例えば、ホエイ蛋白質、カゼイン蛋白質の中から選ばれた1種または2種以上を用いることができる。本発明では乳蛋白質として、ホエイ蛋白質のみ、カゼイン蛋白質のみ、カゼイン蛋白質とホエイ蛋白質との併用のいずれでもよいが、ホエイ蛋白質とカゼイン蛋白質を併用するのが好ましい。 The milk protein constituting the complex is not particularly limited, and for example, one or more selected from whey protein and casein protein can be used. In the present invention, the milk protein may be either whey protein alone, casein protein alone, or a combination of casein protein and whey protein, but it is preferable to use whey protein and casein protein in combination.
上記カゼイン蛋白質としては、αs1−カゼイン、αs2−カゼイン、β−カゼイン、γ−カゼイン、κ−カゼインの各単体や、これらの混合物、若しくはこれらを含有する食品素材であるアルカリカゼイン(カゼイネート)、酸カゼイン等が挙げられ、これらの中から選ばれた1種または2種以上を用いることができる。 Examples of the casein protein include αs1-casein, αs2-casein, β-casein, γ-casein, κ-casein, a mixture thereof, or an alkaline casein (caseinate) that is a food material containing these, acid Casein etc. are mentioned, The 1 type (s) or 2 or more types selected from these can be used.
上記ホエイ蛋白質としては、ラクトアルブミン、βラクトグロブリン、血清アルブミン、免疫グロブリン、プロテオースペプトンの各単体や、これらの混合物、若しくはこれらを含有する食品素材として、乳清蛋白質、ホエイ、ホエイパウダー、脱乳糖ホエイ、脱乳糖ホエイパウダー、ホエイ蛋白質濃縮物(WPC及び/又はWPI)等が挙げられ、これらの中から選ばれた1種または2種以上を用いることができる。 Examples of the whey protein include lactalbumin, β-lactoglobulin, serum albumin, immunoglobulin, proteose peptone, a mixture thereof, and food materials containing them such as whey protein, whey, whey powder, Examples thereof include lactose whey, delactose whey powder, whey protein concentrate (WPC and / or WPI), and one or more selected from these can be used.
上記複合体中の乳蛋白質の含有量は、好ましくは0.5質量%以上、さらに好ましくは0.5〜15質量%、最も好ましくは0.5〜5質量%である。乳蛋白質の含有量が0.5質量%よりも少ないと、複合体を用いた焼菓子類がソフトとなりにくい。 The content of milk protein in the complex is preferably 0.5% by mass or more, more preferably 0.5 to 15% by mass, and most preferably 0.5 to 5% by mass. When the milk protein content is less than 0.5% by mass, the baked confectionery using the composite is difficult to be soft.
上記乳蛋白質としては、上記カゼイン蛋白質及び上記ホエイ蛋白質の両方を含有する食品素材を用いることも好ましく、斯かる食品素材として、例えば、生乳、牛乳、加糖練乳、加糖脱脂れん乳、無糖れん乳、無糖脱脂れん乳、脱脂乳、濃縮乳、脱脂濃縮乳、バターミルク、バターミルクパウダー、トータルミルクプロテイン(TMP)、脱脂粉乳、全粉乳、ミルクプロテインコンセントレート(MPC)、クリーム、クリームチーズ、ナチュラルチーズ、プロセスチーズ、ヨーグルト、乳酸菌飲料、サワークリ―ム、醗酵乳等が挙げられ、これらの中から選ばれた1種または2種以上を用いることができる。 As the milk protein, it is also preferable to use a food material containing both the casein protein and the whey protein. Examples of the food material include raw milk, milk, sweetened condensed milk, sweetened defatted milk, and sugar-free milk. Sugar free skim milk, skim milk, concentrated milk, skim concentrated milk, butter milk, butter milk powder, total milk protein (TMP), skim milk powder, whole milk powder, milk protein concentrate (MPC), cream, cream cheese, Natural cheese, processed cheese, yogurt, lactic acid bacteria beverages, sawarme, fermented milk and the like can be mentioned, and one or more selected from these can be used.
特に本発明では上記カゼイン蛋白質及び上記ホエイ蛋白質の両方を含有する食品素材であり、乳由来のリン脂質を含有する食品素材(以下、リン脂質含有食品素材という)を用いるのが好ましい。このリン脂質含有食品素材は、乳固形分中のリン脂質の含有量が、好ましくは0.5質量%以上、さらに好ましくは2質量%以上、一層好ましくは4質量%以上、最も好ましくは5〜40質量%であることが望ましい。
上記リン脂質含有食品素材は、液体状でも、粉末状でも、濃縮物でも構わない。但し、溶剤を用いて濃縮した食品素材は、風味上の問題から本発明において用いないのが好ましい。
In particular, in the present invention, it is preferable to use a food material containing both the casein protein and the whey protein, and containing a milk-derived phospholipid (hereinafter referred to as a phospholipid-containing food material). In the phospholipid-containing food material, the phospholipid content in the milk solids is preferably 0.5% by mass or more, more preferably 2% by mass or more, more preferably 4% by mass or more, and most preferably 5 to 5% by mass. It is desirable that it is 40 mass%.
The phospholipid-containing food material may be liquid, powder, or concentrate. However, it is preferable not to use the food material concentrated using a solvent in the present invention because of a problem in flavor.
上記リン脂質含有食品素材は、乳由来のリン脂質を含有する乳原料である牛乳、ヤギ乳、ヒツジ乳、人乳等の乳から製造されたものが好ましく、特に牛乳から製造されたものが好ましい。
上記リン脂質含有食品素材としては、具体的には、クリームからバターを製造する際に生じる水相成分(バターミルク)や、クリーム又はバターからバターオイルを製造する際に生じる水相成分があげられる。
The phospholipid-containing food material is preferably produced from milk such as milk, goat milk, sheep milk, human milk, etc., which are milk raw materials containing milk-derived phospholipids, particularly those produced from milk. .
Specific examples of the phospholipid-containing food material include an aqueous phase component (butter milk) produced when producing butter from cream and an aqueous phase component produced when producing butter oil from cream or butter. .
上記のクリームからバターオイルを製造する際に生じる水相成分の製造方法は、例えば以下の通りである。まず、牛乳を遠心分離して得られる脂肪濃度30〜40質量%のクリームをプレートで加温し、遠心分離機によってクリームの脂肪濃度を70〜95質量%まで高める。次いで、乳化破壊機で乳化を破壊し、再び遠心分離機で処理することによってバターオイルが得られる。本発明で用いられる上記水相成分は、最後の遠心分離の工程でバターオイルの副産物として発生するものである。 A method for producing an aqueous phase component produced when producing butter oil from the above cream is, for example, as follows. First, a cream having a fat concentration of 30 to 40% by mass obtained by centrifuging milk is heated on a plate, and the fat concentration of the cream is increased to 70 to 95% by mass using a centrifuge. Subsequently, the emulsification is broken with an emulsification breaker, and the butter oil is obtained by processing again with a centrifuge. The aqueous phase component used in the present invention is generated as a by-product of butter oil in the final centrifugation step.
上記のバターからバターオイルを製造する際に生じる水相成分の製造方法は、例えば以下の通りである。まず、バターを溶解機で溶解し熱交換機で加温する。これを遠心分離機で分離することによってバターオイルが得られる。本発明で用いられる上記水相成分は、最後の遠心分離の工程でバターオイルの副産物として発生するものである。該バターオイルの製造に用いられるバターとしては、通常のものが用いられる。 A method for producing an aqueous phase component produced when producing butter oil from the butter is as follows, for example. First, butter is melted with a dissolver and heated with a heat exchanger. Butter oil is obtained by separating this with a centrifuge. The aqueous phase component used in the present invention is generated as a by-product of butter oil in the final centrifugation step. As the butter used for producing the butter oil, ordinary ones are used.
本発明では、上記のクリームからバターを製造する際に生じる水相成分(バターミルク)や、クリーム又はバターからバターオイルを製造する際に生じる水相成分を、さらに濃縮したものや乾燥したもの、冷凍処理をしたものなどを用いることも可能である。但し、乳由来のリン脂質は、高温加熱するとその機能が低下するため、加熱する際の温度は、100℃未満であることが好ましい。さらに、溶剤を用いて濃縮したものは、風味上の問題から用いないことが好ましい。 In the present invention, an aqueous phase component (butter milk) produced when producing butter from the above cream, an aqueous phase component produced when producing butter oil from cream or butter, a further concentrated or dried product, It is also possible to use a frozen product. However, since the function of milk-derived phospholipids decreases when heated at high temperatures, the temperature during heating is preferably less than 100 ° C. Furthermore, it is preferable not to use the thing concentrated using the solvent from the problem on flavor.
また、本発明では、上記リン脂質含有食品素材中のリン脂質の一部又は全部がリゾ化されたリゾ化物を使用することもできる。該リゾ化物は、上記リン脂質含有食品素材をそのままリゾ化したものであってもよく、また上記リン脂質含有食品素材を濃縮した後にリゾ化したものであってもよい。また、得られたリゾ化物に、さらに濃縮あるいは噴霧乾燥処理等を施してもよい。 In the present invention, a lysed product obtained by lysing part or all of the phospholipid in the phospholipid-containing food material can also be used. The lysed product may be obtained by lysing the phospholipid-containing food material as it is, or by lysing the phospholipid-containing food material after concentration. Further, the obtained lysate may be further subjected to concentration or spray drying treatment.
上記リン脂質含有食品素材中のリン脂質をリゾ化するには、ホスホリパーゼAで処理すればよい。ホスホリパーゼAは、リン脂質分子のグリセロール部分と脂肪酸残基とを結びつけている結合を切断し、この脂肪酸残基を水酸基で置換する作用を有する酵素である。ホスホリパーゼAは、作用する部位の違いによってホスホリパーゼA1とホスホリパーゼA2とに分かれるが、ホスホリパーゼA2が好ましい。ホスホリパーゼA2の場合、リン脂質分子のグリセロール部分の2位の脂肪酸残基が選択的に切り離される。 In order to lyze the phospholipid in the phospholipid-containing food material, it may be treated with phospholipase A. Phospholipase A is an enzyme having an action of cleaving a bond connecting a glycerol part of a phospholipid molecule and a fatty acid residue and substituting the fatty acid residue with a hydroxyl group. Phospholipase A is divided into phospholipase A1 and phospholipase A2 depending on the site of action, but phospholipase A2 is preferred. In the case of phospholipase A2, the fatty acid residue at position 2 of the glycerol part of the phospholipid molecule is selectively cleaved.
上記リン脂質含有食品素材における乳固形分中のリン脂質の定量は、例えば以下のような方法にて行うことができる。但し、抽出方法等については食品素材の形態等によって適正な方法が異なるため、この定量方法に限定されるものではない。
まず、上記リン脂質含有食品素材の脂質をFolch法を用いて抽出する。図1にFolch法のフローを示す。次いで、抽出した脂質溶液を湿式分解法(日本薬学会編、衛生試験法・注解2000 2.1食品成分試験法に記載の湿式分解法に準じる)にて分解した後、モリブデンブルー吸光度法(日本薬学会編、衛生試験法・注解2000 2.1食品成分試験法に記載のリンのモリブデン酸による定量に準じる)によりリン量を求める。求められたリン量から以下の計算式を用いて食品素材の乳固形分100g中のリン脂質の含有量(g)を求める。
リン脂質(g/100g)=〔リン量(μg)/(食品素材−食品素材の水分(g))〕×25.4×(0.1/1000)
The phospholipid in the milk solid content in the phospholipid-containing food material can be quantified, for example, by the following method. However, the extraction method and the like are not limited to this quantification method because an appropriate method varies depending on the form of the food material.
First, the lipid of the phospholipid-containing food material is extracted using the Folch method. FIG. 1 shows a flow of the Folch method. Next, the extracted lipid solution was decomposed by a wet decomposition method (according to the wet decomposition method described in the Japan Pharmaceutical Association, Sanitary Test Method, Note 2000 2.1 Food Component Test Method), and then the molybdenum blue absorbance method (Japan Pharmaceutical Association). Chapter 2. Hygiene Test Method / Comment 2000 2.1 According to the determination of phosphorus with molybdic acid described in 2.1 Food Composition Test Method), determine the phosphorus content. The content (g) of phospholipid in 100 g of milk solid content of the food material is determined from the determined phosphorus amount using the following calculation formula.
Phospholipid (g / 100 g) = [phosphorus amount (μg) / (food material-water content of food material (g))] × 25.4 × (0.1 / 1000)
また、上記リン脂質含有食品素材は、該食品素材を溶解した水溶液とし、これに乳酸菌を添加して、乳酸醗酵を行い、乳酸醗酵物としてもよい。乳酸醗酵物とすることにより、良好な風味を焼菓子類に付与することができる。
上記乳蛋白質として上記リン脂質含有食品素材を用いる場合、該食品素材を乳固形分として、好ましくは0.1〜8質量%、さらに好ましくは0.5〜7質量%、最も好ましくは0.9〜4質量%を上記複合体中に含有させるのがよい。
Moreover, the said phospholipid containing food material is made into the aqueous solution which melt | dissolved this food material, lactic acid bacteria are added to this, it is good also as a lactic acid fermented product. By using a lactic acid fermentation product, a good flavor can be imparted to baked goods.
When the phospholipid-containing food material is used as the milk protein, the food material is preferably 0.1 to 8% by mass, more preferably 0.5 to 7% by mass, and most preferably 0.9% as the milk solid content. It is good to contain -4 mass% in the said composite_body | complex.
本発明で用いる複合体には、乳化剤、糖類・甘味料、金属イオン封鎖剤、ゼラチン、セルロースやセルロース誘導体、澱粉類、油脂類、穀類、無機塩、有機酸塩、キモシン等の蛋白質分解酵素、トランスグルタミナーゼ、ラクターゼ(β−ガラクトシダーゼ)、グルコアミラーゼ等の糖質分解酵素、ジグリセライド、植物ステロール、植物ステロールエステル、食塩、岩塩、海塩、果汁、濃縮果汁、果汁パウダー、乾燥果実、果肉、野菜、野菜汁、香辛料、香辛料抽出物、ハーブ、直鎖デキストリン・分枝デキストン・環状デキストン等のデキストリン類、卵製品、カカオ及びカカオ製品、コーヒー及びコーヒー製品、その他各種食品素材全般、着香料、苦味料、調味料等の呈味成分、着色料、保存料、酸化防止剤、pH調整剤、強化剤等を配合してもよい。 Complexes used in the present invention include emulsifiers, sugars / sweeteners, sequestering agents, gelatin, cellulose and cellulose derivatives, starches, fats and oils, cereals, inorganic salts, organic acid salts, proteolytic enzymes such as chymosin, Carbolytic enzymes such as transglutaminase, lactase (β-galactosidase), glucoamylase, diglyceride, plant sterol, plant sterol ester, salt, rock salt, sea salt, fruit juice, concentrated fruit juice, fruit juice powder, dried fruit, pulp, vegetable, Vegetable juice, spices, spice extracts, herbs, dextrins such as linear dextrin / branched dextons / cyclic dextones, egg products, cacao and cacao products, coffee and coffee products, other various food ingredients, flavorings, bitters Flavoring ingredients such as seasonings, colorants, preservatives, antioxidants, pH adjusters, strengthening agents, etc. It may be combined.
上記乳化剤としては、レシチン、酵素処理レシチン、グリセリン脂肪酸エステル、グリセリン酢酸脂肪酸エステル、グリセリン乳酸脂肪酸エステル、グリセリンコハク酸脂肪酸エステル、グリセリンジアセチル酒石酸脂肪酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、ショ糖酢酸イソ酪酸エステル、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、プロピレングリコール脂肪酸エステル、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウム、ポリオキシエチレンソルビタン脂肪酸エステル等が挙げられる。本発明で用いる複合体では、風味や、消費者の間に広まっている天然志向に応える観点から、レシチンや酵素処理レシチン以外の合成乳化剤を用いないことが好ましく、さらに好ましくは上記乳化剤を用いないことが望ましい。 Examples of the emulsifier include lecithin, enzyme-treated lecithin, glycerin fatty acid ester, glycerin acetic acid fatty acid ester, glycerin lactate fatty acid ester, glycerin diacetyl tartaric acid ester, sorbitan fatty acid ester, sucrose fatty acid ester, and sucrose acetate isoform. Examples include butyric acid ester, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, propylene glycol fatty acid ester, stearoyl calcium lactate, sodium stearoyl lactate, and polyoxyethylene sorbitan fatty acid ester. In the composite used in the present invention, it is preferable not to use synthetic emulsifiers other than lecithin and enzyme-treated lecithin from the viewpoint of responding to flavor and natural orientation that is widespread among consumers, and more preferably, the above-mentioned emulsifier is not used. It is desirable.
上記糖類としては、特に制限されるものではないが、例えば、ブドウ糖、果糖、ショ糖、麦芽糖、酵素糖化水飴、乳糖、還元澱粉糖化物、異性化液糖、ショ糖結合水飴、オリゴ糖、還元糖ポリデキストロース、ソルビトール、還元乳糖、トレハロース、キシロース、キシリトール、マルチトール、エリスリトール、マンニトール、フラクトオリゴ糖、大豆オリゴ糖、ガラクトオリゴ糖、乳果オリゴ糖、ラフィノース、ラクチュロース、パラチノースオリゴ糖、デキストリン等が挙げられる。また、上記甘味料としては、スクラロース、アセスルファムカリウム、ステビア、アスパルテーム等が挙げられる。本発明で用いる複合体ではこれらの中から選ばれた1種または2種以上を用いることができる。
上記糖類や上記甘味料の含有量は、上記複合体中、糖類や甘味料の総量で好ましくは0〜30質量%とする。
The saccharide is not particularly limited. For example, glucose, fructose, sucrose, maltose, enzymatic saccharified starch syrup, lactose, reduced starch saccharified product, isomerized liquid sugar, sucrose-conjugated starch syrup, oligosaccharide, reduced Examples include sugar polydextrose, sorbitol, reduced lactose, trehalose, xylose, xylitol, maltitol, erythritol, mannitol, fructooligosaccharide, soybean oligosaccharide, galactooligosaccharide, whey oligosaccharide, raffinose, lactulose, palatinose oligosaccharide, dextrin, etc. . Examples of the sweetener include sucralose, acesulfame potassium, stevia, aspartame and the like. In the composite used in the present invention, one or more selected from these can be used.
The content of the saccharide or the sweetener is preferably 0 to 30% by mass in the total amount of the saccharide or the sweetener in the complex.
上記金属イオン封鎖剤は、カルシウムイオン、マグネシウムイオン、鉄イオン等を封鎖するものであり、その具体例としては、ピロリン酸四ナトリウム、ピロリン酸二水素二ナトリウム、ポリリン酸ナトリウム、メタリン酸ナトリウム、メタリン酸カリウム、ウルトラポリリン酸ナトリウム、第三リン酸カリウム等の各種リン酸塩、並びにクエン酸、酒石酸等の有機酸塩類、及び炭酸塩等の無機塩類が挙げられる。本発明で用いる複合体ではこれらの中から選ばれた1種または2種以上を用いることができる。
上記金属イオン封鎖剤の含有量は、上記複合体中、好ましくは0〜1質量%とする。
また、上記ゼラチンの含有量は、上記複合体中、好ましくは0〜1.5質量%とする。
The metal ion sequestering agent sequesters calcium ions, magnesium ions, iron ions, etc., and specific examples thereof include tetrasodium pyrophosphate, disodium dihydrogen pyrophosphate, sodium polyphosphate, sodium metaphosphate, metalin Examples thereof include various phosphates such as potassium acid, sodium ultrapolyphosphate, and potassium tertiary phosphate, and organic acid salts such as citric acid and tartaric acid, and inorganic salts such as carbonate. In the composite used in the present invention, one or more selected from these can be used.
The content of the sequestering agent is preferably 0 to 1% by mass in the composite.
The gelatin content in the composite is preferably 0 to 1.5% by mass.
上記セルロースやセルロース誘導体としては、微小繊維状セルロース、結晶セルロース、粉末セルロース、メチルセルロース、カルボキシメチルセルロース、ヒドロキシプロピルセルロースがあげられ、これらの中から選ばれた1種または2種以上を用いることができる。
上記澱粉類としては、コーンスターチ、ワキシーコーンスターチ、タピオカ澱粉、馬鈴薯澱粉、小麦澱粉、甘藷澱粉、サゴ澱粉、米澱粉、モチ米澱粉などの澱粉や、澱粉をアミラーゼ等の酵素で処理したもの、アセチル化アジピン酸架橋澱粉・アセチル化リン酸架橋澱粉・アセチル化酸化澱粉・オクテニルコハク酸澱粉ナトリウム・ヒドロキシプロピル澱粉・ヒドロキシプロピル化リン酸架橋澱粉・リン酸モノエステル化リン酸架橋澱粉・リン酸化澱粉・酸化澱粉・酢酸澱粉等、澱粉に対し酸処理やアルカリ処理・エステル化・アセチル化・リン酸架橋化・加熱・湿熱等の化学的・物理的処理を行った化工澱粉、更にこれら化工澱粉を水に溶け易い様にあらかじめ加熱処理により糊化させた澱粉が挙げられる。本発明で用いる複合体ではこれらの中から選ばれた1種または2種以上を用いることができる。
上記のセルロースやセルロース誘導体及び澱粉類の含有量は、上記複合体中、セルロースやセルロース誘導体及び澱粉類の総量で好ましくは0〜5質量%とする。
Examples of the cellulose and cellulose derivative include microfibrous cellulose, crystalline cellulose, powdered cellulose, methyl cellulose, carboxymethyl cellulose, and hydroxypropyl cellulose, and one or more selected from these can be used.
The above starches include corn starch, waxy corn starch, tapioca starch, potato starch, wheat starch, sweet potato starch, sago starch, rice starch, waxy rice starch, and other starches treated with enzymes such as amylase, acetylated Adipic acid cross-linked starch, acetylated phosphoric acid cross-linked starch, acetylated oxidized starch, octenyl succinic acid starch sodium, hydroxypropyl starch, hydroxypropylated phosphoric acid cross-linked starch, phosphoric acid monoesterified phosphoric acid cross-linked starch, phosphorylated starch, oxidized starch・ Starch such as acetic acid starch, acid-treated, alkali-treated, esterified, acetylated, phosphoric acid cross-linked, heated, wet and heat treated chemically and physically treated starch, and further dissolved these modified starch in water For ease of use, starch that has been gelatinized by heat treatment in advance can be used. In the composite used in the present invention, one or more selected from these can be used.
Content of said cellulose, a cellulose derivative, and starch is 0-5 mass% preferably by the total amount of a cellulose, a cellulose derivative, and starch in the said composite_body | complex.
また、本発明で用いる複合体は、油脂と混合乳化して、水中油型乳化物、油中水型乳化物、或いは二重乳化物として用いることもできる。本発明では好ましくは水相が外相となる乳化状態である、水中油型乳化物や二重乳化物の複合体を用いるのがよい。
上記油脂としては、例えば、パーム油、パーム核油、ヤシ油、コーン油、綿実油、大豆油、菜種油、米油、ヒマワリ油、サフラワー油、カカオ脂、サル脂、牛脂、豚脂、乳脂、魚油、鯨油等の各種の植物油脂及び動物油脂、並びにこれらに水素添加、分別及びエステル交換から選択された一又は二以上の処理を施した加工油脂や、MCT(中鎖脂肪酸トリグリセリド)等が挙げられる。本発明では、これらの油脂の中から選ばれた1種または2種以上を用いることができる。
上記油脂の含有量は、上記複合体中、好ましくは0〜70質量%、さらに好ましくは0〜65質量%、最も好ましくは0〜60質量%である。
The composite used in the present invention can be mixed and emulsified with fats and oils to be used as an oil-in-water emulsion, a water-in-oil emulsion, or a double emulsion. In the present invention, it is preferable to use an oil-in-water emulsion or a double emulsion composite that is in an emulsified state in which the aqueous phase becomes the outer phase.
Examples of the fats and oils include palm oil, palm kernel oil, coconut oil, corn oil, cottonseed oil, soybean oil, rapeseed oil, rice oil, sunflower oil, safflower oil, cacao fat, monkey fat, beef fat, pork fat, milk fat, Examples include various vegetable oils and animal fats such as fish oil and whale oil, processed oils and fats that have been subjected to one or more treatments selected from hydrogenation, fractionation and transesterification, and MCT (medium chain fatty acid triglycerides). It is done. In this invention, 1 type, or 2 or more types selected from these fats and oils can be used.
The content of the oil is preferably 0 to 70% by mass, more preferably 0 to 65% by mass, and most preferably 0 to 60% by mass in the composite.
本発明で用いる複合体のpHは特に制限はないが、好ましくは2.5〜7、さらに好ましくは3〜7、最も好ましくは3.5〜7の範囲である。 Although there is no restriction | limiting in particular in the pH of the composite_body | complex used by this invention, Preferably it is 2.5-7, More preferably, it is 3-7, Most preferably, it is the range of 3.5-7.
次に本発明で用いる複合体の製造方法の一例について説明する。
まず、水に乳蛋白質、ゲル化剤を添加し混合し、必要によりその他の成分を添加し、水相とする。また別途必要により、油脂とその他の成分を添加した油相を用意し、上記水相と混合し、乳化する。
そして、乳化後、必要に応じて加熱殺菌を行なう。該加熱殺菌の方法としては、インジェクション式、インフュージョン式、マイクロ波等の直接加熱方式、又は、バッチ式、プレート式、チューブラー式、掻き取り式等の間接加熱方式があり、UHT、HTST、LTLT等の60〜160℃の加熱処理を行なえば良い。
Next, an example of a method for producing a composite used in the present invention will be described.
First, milk protein and gelling agent are added to water and mixed, and if necessary, other components are added to form an aqueous phase. If necessary, an oil phase to which oil and fat and other components are added is prepared, mixed with the aqueous phase, and emulsified.
And after emulsification, heat sterilization is performed as needed. The heat sterilization method includes a direct heating method such as an injection method, an infusion method, a microwave, or an indirect heating method such as a batch method, a plate method, a tubular method, a scraping method, UHT, HTST, Heat treatment at 60 to 160 ° C. such as LTLT may be performed.
次に、均質化機にて均質化する。均質化機としては、例えば、ケトル型チーズ乳化釜、ステファンミキサーの様な高速せん断乳化釜、スタティックミキサー、インラインミキサー、ホモゲナイザー、コロイドミル、ディスパーミル等が挙げられる。この均質化処理は、2段式ホモゲナイザーを用いて、例えば、1段目3〜100MPa、2段目0〜5MPaの均質化圧力にて行なっても良い。
均質化後、必要に応じて冷却しても良い。冷却方法は、例えば、ボーテーター、コンビネーター、パーフェクター等の急冷可塑化機にて急冷可塑化処理を行う方法でも良く、チューブラー式、掻取式等の熱交換機によって冷却する方法でも良い。別の方法として、適当な容器に充填した後に、水浴、氷浴、冷蔵庫、冷凍庫等で冷却する方法も挙げられる。
Next, it homogenizes with a homogenizer. Examples of the homogenizer include a kettle type cheese emulsification pot and a high-speed shear emulsification pot such as a stefan mixer, a static mixer, an in-line mixer, a homogenizer, a colloid mill, and a disper mill. This homogenization treatment may be performed using a two-stage homogenizer, for example, at a homogenization pressure of 3 to 100 MPa for the first stage and 0 to 5 MPa for the second stage.
After homogenization, it may be cooled as necessary. The cooling method may be, for example, a method of quenching plasticization with a quenching plasticizer such as a votater, a combinator, or a perfector, or a method of cooling with a heat exchanger such as a tubular type or a scraping type. As another method, a method of cooling in a water bath, an ice bath, a refrigerator, a freezer, etc. after filling an appropriate container can also be mentioned.
このようにして得られた本発明で用いる複合体は、5℃における硬さが好ましくは5〜300g/cm2 、さらに好ましくは10〜250g/cm2 、最も好ましくは20〜200g/cm2 である。
なお上記の硬さは、フドーレオメーター(不動工業(株)製)にてテーブルスピード2cm/分でカード測定用のプランジャー(No.1)が、5cmの複合体に1cm進入したときの応力値を示している。
The composite used in the present invention thus obtained has a hardness at 5 ° C. of preferably 5 to 300 g / cm 2 , more preferably 10 to 250 g / cm 2 , most preferably 20 to 200 g / cm 2 . is there.
The above hardness is the stress when the card measurement plunger (No. 1) enters 1 cm into the 5 cm composite at a table speed of 2 cm / min with a Fudoreometer (Fudo Kogyo Co., Ltd.). The value is shown.
上記複合体を、焼菓子類生地で用いる穀粉類100質量部に対し、好ましくは70〜220質量部、さらに好ましくは80〜200質量部、最も好ましくは90〜190質量部混練した焼菓子類生地を焼成するこにより、本発明の焼菓子類を得ることができる。
上記焼菓子類生地で用いる穀粉類としては、特に限定されるものではないが、小麦粉、薄力粉、中力粉、強力粉、小麦胚芽、全粒粉、小麦ふすま、デュラム粉、大麦粉、米粉、ライ麦粉、ライ麦全粒粉、大豆粉、ハトムギ粉等をあげることができ、これらの中から選ばれた1種または2種以上を用いるのがよい。本発明では、好ましくは薄力粉、全粒粉、デュラム粉、ライ麦粉、ライ麦全粒粉の中から選ばれた1種または2種以上を用いるのが良い。
The baked confectionery dough obtained by kneading the complex with respect to 100 parts by weight of flour used in the baked confectionery dough, preferably 70 to 220 parts by weight, more preferably 80 to 200 parts by weight, and most preferably 90 to 190 parts by weight. By baking, the baked confectionery of the present invention can be obtained.
The flour used in the baked confectionery dough is not particularly limited, but flour, soft flour, medium flour, strong flour, wheat germ, whole wheat flour, wheat bran, durum flour, barley flour, rice flour, rye flour, Rye whole grain flour, soybean flour, pearl barley flour, etc. can be mentioned, and it is preferable to use one or more selected from these. In the present invention, it is preferable to use one or more selected from among flour, whole grain flour, durum flour, rye flour, and rye whole grain flour.
上記焼菓子類生地は、上記の複合体や穀粉類の他に、糖類、甘味料、乳製品、油脂類、膨張剤、卵類、水、食塩、澱粉類、乳化剤、調味料、香辛料、着香料、着色料、ココア、チョコレート、ナッツ類、ヨーグルト、チーズ、抹茶、紅茶、コーヒー、豆腐、黄な粉、豆類、野菜類、果実、果汁、ジャム、フルーツソース、果物、ハーブ、肉類、魚介類、保存料、日持ち向上剤などの材料を適宜用いることができる。 The baked confectionery dough includes sugars, sweeteners, dairy products, fats and oils, swelling agents, eggs, water, salt, starches, emulsifiers, seasonings, spices, clothes, in addition to the above complex and flour. Flavor, Coloring, Cocoa, Chocolate, Nuts, Yogurt, Cheese, Matcha, Tea, Coffee, Tofu, Yellow powder, Beans, Vegetables, Fruit, Juice, Jam, Fruit sauce, Fruits, Herbs, Meat, Seafood A material such as a material and a shelf life improving agent can be used as appropriate.
上記糖類としては、ブドウ糖、果糖、ショ糖、麦芽糖、酵素糖化水飴、乳糖、還元澱粉糖化物、異性化液糖、ショ糖結合水飴、オリゴ糖、還元糖ポリデキストロース、ソルビトール、還元乳糖、トレハロース、キシロース、キシリトール、マルチトール、エリスリトール、マンニトール、フラクトオリゴ糖、大豆オリゴ糖、ガラクトオリゴ糖、乳果オリゴ糖、ラフィノース、ラクチュロース、パラチノースオリゴ糖、デキストリン等を用いることができる。本発明ではこれらの中から選ばれた1種または2種以上を使用することができる。
上記甘味料としては、スクラロース、アセスルファムカリウム、ステビア、アスパルテーム等を用いることができる。本発明ではこれらの中から選ばれた1種または2種以上を使用することができる。
Examples of the sugars include glucose, fructose, sucrose, maltose, enzymatic saccharified starch syrup, lactose, reduced starch saccharified product, isomerized liquid sugar, sucrose-conjugated starch syrup, oligosaccharide, reducing sugar polydextrose, sorbitol, reduced lactose, trehalose, Xylose, xylitol, maltitol, erythritol, mannitol, fructooligosaccharide, soybean oligosaccharide, galactooligosaccharide, dairy oligosaccharide, raffinose, lactulose, palatinose oligosaccharide, dextrin and the like can be used. In the present invention, one or more selected from these can be used.
As the sweetener, sucralose, acesulfame potassium, stevia, aspartame and the like can be used. In the present invention, one or more selected from these can be used.
上記乳製品としては、生乳、牛乳、特別牛乳、生山羊乳、殺菌山羊乳、生めん羊乳、部分脱脂乳、脱脂乳、加工乳、クリーム、チーズ、濃縮ホエイ、アイスクリーム類、濃縮乳、脱脂濃縮乳、無糖れん乳、無糖脱脂れん乳、加糖れん乳、加糖脱脂れん乳、全粉乳、脱脂粉乳、クリームパウダー、ホエイパウダー、蛋白質濃縮ホエイパウダー、バターミルクパウダー、加糖粉乳、調製粉乳、はっ酵乳、乳酸菌飲料、乳飲料、カゼインカルシウム、カゼインナトリウム、カゼインカリウム、カゼインマグネシウム、ホエープロテインコンセートレート、トータルミルクプロテイン等を用いることができる。本発明ではこれらの中から選ばれた1種または2種以上を使用することができる。 The above dairy products include raw milk, cow milk, special milk, raw goat milk, pasteurized goat milk, raw noodle milk, partially skimmed milk, skimmed milk, processed milk, cream, cheese, concentrated whey, ice creams, concentrated milk, skimmed milk Concentrated milk, sugar-free milk, sugar-free skim milk, sweetened milk, sweetened skim milk, whole milk powder, skim milk powder, cream powder, whey powder, protein concentrated whey powder, buttermilk powder, sweetened powdered milk, prepared powdered milk, Fermented milk, lactic acid bacteria beverage, milk beverage, casein calcium, casein sodium, casein potassium, casein magnesium, whey protein concentrate, total milk protein, and the like can be used. In the present invention, one or more selected from these can be used.
上記油脂類としては、マーガリン、ショートニング、バター、粉末油脂、液状油などを用いることができる。本発明ではこれらの中から選ばれた1種または2種以上を使用することができる。
上記膨張剤としては、炭酸水素ナトリウムや炭酸アンモニウムなどの炭酸塩や、これらに、酒石酸、酒石酸水素ナトリウム、第一リン酸ナトリウム、第一リン酸カルシウム、フマル酸、フマル酸ナトリウム、フマル酸カリウム、クエン酸ナトリウム、クエン酸カルシウム、クエン酸アンモニウム、グルコノデルタラクトン、グルコン酸ナトリウム、グルコン酸カリウム、グルコン酸アンモニウム、焼ミヨウバンなどの中から選ばれた1種または2種以上を添加したり、さらに澱粉類を添加したものを用いることができる。また市販のベーキングパウダーを用いることもできる。本発明ではこれらの中から選ばれた1種または2種以上を使用することができる。
上記卵類としては、全卵、生卵黄、殺菌全卵、殺菌卵黄、加塩全卵、加塩卵黄、加糖全卵、加糖卵黄などを用いることができる。本発明ではこれらの中から選ばれた1種または2種以上を使用することができる。
As said fats and oils, margarine, shortening, butter, powdered fats and oils, liquid oils, etc. can be used. In the present invention, one or more selected from these can be used.
Examples of the swelling agent include carbonates such as sodium bicarbonate and ammonium carbonate, and tartaric acid, sodium hydrogen tartrate, monobasic sodium phosphate, monobasic calcium phosphate, fumaric acid, sodium fumarate, potassium fumarate, citric acid. Add one or more selected from sodium, calcium citrate, ammonium citrate, glucono delta lactone, sodium gluconate, potassium gluconate, ammonium gluconate, baked myoban, and starches Can be used. Commercially available baking powder can also be used. In the present invention, one or more selected from these can be used.
Examples of eggs include whole egg, raw egg yolk, sterilized whole egg, sterilized egg yolk, salted whole egg, salted egg yolk, sweetened whole egg, and sugared egg yolk. In the present invention, one or more selected from these can be used.
本発明の焼菓子類は、例えば次のようにして製造される。焼菓子類生地で用いる穀粉類100質量部に対し、好ましくはゲル化剤と乳蛋白質と水とで構成される複合体を70〜220質量部及び必要によりその他の材料を混練して焼菓子類生地とする。得られた焼菓子類生地を焼成することにより焼菓子類を得る。この際、焼成手段としては、直火による焼成、オーブンによる焼成、電子レンジによる焼成、蒸し焼き等が挙げられる。本発明では、上記焼菓子類生地を冷蔵または冷凍して保存した後、これを焼成して本発明の焼菓子類としてもよい。また、本発明の焼菓子類を冷蔵または冷凍してもよく、食する際に焼菓子類を電子レンジで解凍調理することも可能である。
The baked confectionery of this invention is manufactured as follows, for example. For 100 parts by mass of flour used in the baked confectionery dough, preferably 70 to 220 parts by mass of a complex composed of a gelling agent, milk protein and water and, if necessary, other materials are kneaded and baked confectionery Dough. A baked confectionery is obtained by baking the obtained baked confectionery dough. In this case, examples of the baking means include baking by direct fire, baking by an oven, baking by a microwave oven, steaming baking, and the like. In the present invention, the baked confectionery dough may be stored refrigerated or frozen and then baked to obtain the baked confectionery of the present invention. Moreover, the baked confectionery of the present invention may be refrigerated or frozen, and the baked confectionery can be thawed and cooked in a microwave oven when eating.
本発明の焼菓子類としては、カッチングソフトビスケット、ロータリービスケット、ワイヤーカットビスケット、デポジットクッキー、サンドクッキー、各種サンドクッキー、各種包餡クッキー、チョコ複合クッキー、その他のクッキー等、様々なタイプをあげることができる。 Examples of the baked confectionery of the present invention include various types such as cutting soft biscuits, rotary biscuits, wire cut biscuits, deposit cookies, sand cookies, various sand cookies, various wrapping cookies, chocolate composite cookies, and other cookies. be able to.
次に、実施例及び比較例を挙げ、本発明を更に詳細に説明するが、これらは本発明を何ら制限するものではない。
なお下記複合体1〜4の硬さは、フドーレオメーター(不動工業(株)製)にてテーブルスピード2cm/分でカード測定用のプランジャー(No.1)が、5cmの複合体に1cm進入したときの応力値を示すものである。
EXAMPLES Next, although an Example and a comparative example are given and this invention is demonstrated further in detail, these do not limit this invention at all.
In addition, the hardness of the following composites 1 to 4 is 1 cm for a 5 cm composite with a card measurement plunger (No. 1) at a table speed of 2 cm / min using a Fudoreometer (Fudo Kogyo Co., Ltd.). It shows the stress value when entering.
製造例1(複合体1の製造)
ナチュラルチーズ15質量部、クリームからバターオイルを製造する際に生じる水相成分の濃縮物(蛋白質含有量12質量%、乳固形分38質量%、乳固形分中のリン脂質の含有量9.8質量%)3質量部及びホエイパウダー3質量部を水66.8質量部に加え、よく撹拌した。これをプレート式熱交換器にて85℃で3分間加熱殺菌し、乳酸菌スターターを接種し乳酸醗酵を行った。得られた乳酸醗酵物(pH5.3)にサラダ油10質量部、LMペクチン2質量部及びグアーガム0.2質量部を加え、これを掻取式熱交換器にて90℃で180秒間加熱殺菌し、55℃に冷却した。次いで、イズミフードマシナリ製2段式ホモゲナイザーにて1段目20MPa、2段目2MPaの均質化圧力にて均質化後、ポリエチレン袋に密封して静置し、5℃に冷却して、本発明で用いる「ゲル化剤と乳蛋白質と水とで構成される複合体1(水中油型乳化物)」を得た。
得られた複合体1の乳蛋白質の含有量は1.3質量%、ゲル化剤の含有量は2.2質量%、水の含有量は76.9質量%、pH6.2であった。
得られた複合体1を5℃で18時間調温した後に測定した硬さは50g/cm2 であった。
Production Example 1 (Production of Composite 1)
15 mass parts of natural cheese, concentrate of water phase component produced when producing butter oil from cream (protein content 12 mass%, milk solid content 38 mass%, phospholipid content 9.8 in milk solid content) (Mass%) 3 parts by weight and 3 parts by weight of whey powder were added to 66.8 parts by weight of water and stirred well. This was sterilized by heating at 85 ° C. for 3 minutes in a plate heat exchanger, inoculated with a lactic acid bacteria starter, and subjected to lactic acid fermentation. 10 parts by weight of salad oil, 2 parts by weight of LM pectin and 0.2 parts by weight of guar gum are added to the obtained lactic acid fermented product (pH 5.3), and this is sterilized by heating at 90 ° C. for 180 seconds using a scraping heat exchanger. And cooled to 55 ° C. Next, after homogenization at a first stage 20 MPa, second stage 2 MPa homogenization pressure with a two-stage homogenizer made by Izumi Food Machinery, sealed in a polyethylene bag, allowed to stand, and cooled to 5 ° C. The "complex 1 (oil-in-water emulsion) composed of a gelling agent, milk protein and water" was used.
In the obtained complex 1, the milk protein content was 1.3% by mass, the gelling agent content was 2.2% by mass, the water content was 76.9% by mass, and the pH was 6.2.
The hardness of the obtained complex 1 measured after adjusting the temperature at 5 ° C. for 18 hours was 50 g / cm 2 .
製造例2(複合体2の製造)
クリームチーズ20質量部、ホエイパウダー4質量部、クリームからバターオイルを製造する際に生じる水相成分の濃縮物(蛋白質含有量12質量%、乳固形分38質量%、乳固形分中のリン脂質の含有量9.8質量%)2.5質量部、乳糖1.5質量部及びミルクプロテインコンセントレート1.3質量部を水45.6質量部に加え、よく撹拌し、プレート式熱交換器で90℃4分間殺菌した。これを35℃に調温して乳酸菌スターターを添加し、7時間調温して乳酸発酵物を得た。これにLMペクチン1質量部、ローカストビーンガム0.1質量部、クエン酸ナトリウム0.5質量部及び食塩0.5質量部を加え、さらにサラダ油20質量部及びタピオカ由来化工澱粉3質量部を加え、よく撹拌した。これを掻取式熱交換器にて85℃で3分間加熱殺菌し、掻取式熱交換器にて60℃に冷却し、イズミフードマシナリ製2段式ホモゲナイザーにて1段目20MPa、2段目1MPaの均質化圧力にて均質化後、ポリエチレン袋に密封して静置し、5℃に冷却して、本発明で用いる「ゲル化剤と乳蛋白質と水とで構成される複合体2(水中油型乳化物)」を得た。
得られた複合体2の乳蛋白質の含有量は2.4質量%、ゲル化剤の含有量は1.1質量%、水の含有量は55.8質量%、pHは5.1であった。
得られた複合体2を5℃で18時間調温した後に測定した硬さは120g/cm2 であった。
Production Example 2 (Production of Composite 2)
Cream cheese 20 parts by weight, whey powder 4 parts by weight, water phase component concentrate produced when producing butter oil from cream (protein content 12% by weight, milk solids 38% by weight, phospholipids in milk solids Content of 9.8% by mass), 2.5 parts by mass, 1.5 parts by mass of lactose and 1.3 parts by mass of milk protein concentrate are added to 45.6 parts by mass of water, stirred well, and a plate heat exchanger Sterilized at 90 ° C. for 4 minutes. The temperature was adjusted to 35 ° C., a lactic acid bacteria starter was added, and the temperature was adjusted for 7 hours to obtain a lactic acid fermentation product. To this is added 1 part by weight of LM pectin, 0.1 part by weight of locust bean gum, 0.5 part by weight of sodium citrate and 0.5 part by weight of salt, and further 20 parts by weight of salad oil and 3 parts by weight of tapioca-derived modified starch. Stir well. This is sterilized by heating at 85 ° C. for 3 minutes with a scraping heat exchanger, cooled to 60 ° C. with a scraping heat exchanger, and the first stage 20 MPa and the second stage with a two-stage homogenizer made by Izumi Food Machinery. After homogenizing at a homogenization pressure of 1 MPa, sealed in a polyethylene bag, allowed to stand, cooled to 5 ° C., and used in the present invention “complex 2 composed of gelling agent, milk protein and water 2 (Oil-in-water emulsion) ”was obtained.
The obtained complex 2 had a milk protein content of 2.4% by mass, a gelling agent content of 1.1% by mass, water content of 55.8% by mass, and a pH of 5.1. It was.
The hardness of the obtained composite 2 measured after adjusting the temperature at 5 ° C. for 18 hours was 120 g / cm 2 .
製造例3(複合体3の製造)
ホエイパウダー2.5質量部、トータルミルクプロテイン1.5質量部、水飴30質量部、クリームからバターオイルを製造する際に生じる水相成分の濃縮物(蛋白質含有量12質量%、乳固形分38質量%、乳固形分中のリン脂質の含有量4.89質量%)5質量部、大豆油10質量部及び水39.2質量部を混合し、45℃に加熱し、イズミフードマシナリ製2段式ホモゲナイザーにて1段目100MPa、2段目0MPaの均質化圧力にて均質化を行い、水中油型乳化物(1)を調製した。この水中油型乳化物(1)に、中粘性アルギン酸ナトリウム(1質量%水溶液の粘度が30mPa・s)0.5質量部、菜種油10質量部、乳酸0.3質量部及び澱粉1質量部を添加し、配合槽で混合し、水中油型乳化物(2)を調製した。これを掻取式熱交換器にて90℃で5分間加熱殺菌し、掻取式熱交換器にて45℃に冷却した。次いで、イズミフードマシナリ製2段式ホモゲナイザーにて1段目2MPa、2段目10MPaの均質化圧力にて均質化後、ポリエチレン袋に密封して静置し、5℃に冷却して、本発明で用いる「ゲル化剤と乳蛋白質と水とで構成される複合体3(水中油型乳化物)」を得た。
得られた複合体3の乳蛋白質の含有量は2.5質量%、ゲル化剤の含有量は0.5質量%、水の含有量は50.3質量%、pHは5.1であった。
得られた複合体4を5℃で18時間調温した後に測定した硬さは30g/cm2 であった。
Production Example 3 (Production of Composite 3)
2.5 parts by weight of whey powder, 1.5 parts by weight of total milk protein, 30 parts by weight of starch syrup, a concentrate of water phase components produced when producing butter oil from cream (protein content 12% by weight, milk solids 38 5% by mass, content of phospholipid in milk solids 4.89% by mass), 10 parts by mass of soybean oil, and 39.2 parts by mass of water were mixed, heated to 45 ° C., and Izumi Food Machinery 2 Homogenization was performed with a stage homogenizer at a homogenization pressure of 100 MPa in the first stage and 0 MPa in the second stage to prepare an oil-in-water emulsion (1). To this oil-in-water emulsion (1), 0.5 parts by weight of medium-viscosity sodium alginate (1% by weight aqueous solution has a viscosity of 30 mPa · s), 10 parts by weight of rapeseed oil, 0.3 parts by weight of lactic acid and 1 part by weight of starch The mixture was added and mixed in a blending tank to prepare an oil-in-water emulsion (2). This was sterilized by heating at 90 ° C. for 5 minutes with a scraping heat exchanger and cooled to 45 ° C. with a scraping heat exchanger. Next, after homogenization at the first stage 2 MPa, second stage 10 MPa homogenization pressure with a two-stage homogenizer made by Izumi Food Machinery, sealed in a polyethylene bag, allowed to stand and cooled to 5 ° C. The complex 3 (oil-in-water emulsion) composed of a gelling agent, milk protein and water was obtained.
The obtained complex 3 had a milk protein content of 2.5% by mass, a gelling agent content of 0.5% by mass, water content of 50.3% by mass, and a pH of 5.1. It was.
The hardness of the obtained complex 4 measured after adjusting the temperature at 5 ° C. for 18 hours was 30 g / cm 2 .
製造例4(複合体4の製造)
pH5.1の発酵乳76.7質量部及びクリームからバターオイルを製造する際に生じる水相成分の濃縮物(蛋白質含有量12質量%、乳固形分38質量%、乳固形分中のリン脂質の含有量9.8質量%)3質量部を混合し、これにナタネ硬化油(融点15℃) 10質量部、アルギン酸ナトリウム1.2質量部、ローカストビーンガム0.1質量部、タピオカ由来化工澱粉2質量部、メタリン酸ナトリウム0.5質量部、ゼラチン1質量部、乳糖5質量部及び食塩0.5質量部を加えた後よく撹拌した。これをプレート式熱交換器にて85℃で3分間加熱殺菌し、60℃に冷却して、イズミフードマシナリ製2段式ホモゲナイザーにて1段目15MPa、2段目3MPaの均質化圧力にて均質化後、ポリエチレン袋に密封して静置し、5℃に冷却して、本発明で用いる「ゲル化剤と乳蛋白質と水とで構成される複合体4(水中油型乳化物)」を得た。
得られた複合体4の乳蛋白質の含有量は2.3質量%、ゲル化剤の含有量は1.3質量%、油脂の含有量は15.2質量%、水の含有量は71質量%、pHは5.9であった。
得られた複合体4を5℃で18時間調温した後に測定した硬さは200g/cm2 であった。
Production Example 4 (Production of Composite 4)
Concentrate of aqueous phase component produced when producing butter oil from 76.7 parts by mass of fermented milk of pH 5.1 and cream (protein content 12% by mass, milk solids 38% by mass, phospholipids in milk solids) 3 parts by weight of rapeseed oil (melting point 15 ° C.) 10 parts by weight, sodium alginate 1.2 parts by weight, locust bean gum 0.1 part by weight, tapioca-derived chemical After adding 2 parts by weight of starch, 0.5 parts by weight of sodium metaphosphate, 1 part by weight of gelatin, 5 parts by weight of lactose and 0.5 parts by weight of sodium chloride, the mixture was stirred well. This was sterilized by heating at 85 ° C. for 3 minutes in a plate heat exchanger, cooled to 60 ° C., and homogenized at a first stage of 15 MPa and a second stage of 3 MPa with a two-stage homogenizer made by Izumi Food Machinery. After homogenization, sealed in a polyethylene bag, allowed to stand, cooled to 5 ° C., and “complex 4 composed of gelling agent, milk protein and water (oil-in-water emulsion)” used in the present invention. Got.
The content of milk protein in the obtained complex 4 was 2.3% by mass, the content of gelling agent was 1.3% by mass, the content of fats and oils was 15.2% by mass, and the content of water was 71% by mass. %, PH was 5.9.
The hardness of the obtained composite 4 measured after adjusting the temperature at 5 ° C. for 18 hours was 200 g / cm 2 .
実施例1
マーガリン120質量部を溶解後、砂糖120質量部を混合し、上記複合体1を90質量部、全卵60質量部及び食塩0.5質量部をさらに混合し均一にした後、薄力粉70質量部、α化馬鈴薯澱粉20質量部、α化ワキシーコーンスターチ10質量部及びベーキングパウダー1質量部を軽く混合した。得られた生地を室温で15分間放置した後、ワイヤーカット成形をした。この成形生地を180℃で18分間焼成して、焼き菓子を得た。得られた焼き菓子は、水分活性が0.65、水分含量が11質量%でありながら、ソフトでしっとりとした食感で、風味良好に仕上がり、保型性も良好であった。
Example 1
After 120 parts by weight of margarine is dissolved, 120 parts by weight of sugar is mixed, 90 parts by weight of the complex 1 above, 60 parts by weight of whole egg and 0.5 parts by weight of salt are further mixed and made uniform, and then 70 parts by weight of flour. 20 parts by weight of pregelatinized potato starch, 10 parts by weight of pregelatinized waxy corn starch, and 1 part by weight of baking powder were lightly mixed. The obtained dough was allowed to stand at room temperature for 15 minutes, and then wire cut molding was performed. This molded dough was baked at 180 ° C. for 18 minutes to obtain a baked confectionery. The obtained baked confectionery had a water activity of 0.65 and a water content of 11% by mass, and it had a soft and moist texture and finished with a good flavor and good shape retention.
実施例2
上記複合体1の代わりに上記複合体2を70質量部用いた以外は、実施例1と同様にして、焼き菓子を得た。得られた焼き菓子は、水分活性が0.65、水分含量が10質量%でありながら、ソフトでしっとりとした食感で、風味良好に仕上がり、保型性も良好であった。
Example 2
A baked confectionery was obtained in the same manner as in Example 1 except that 70 parts by mass of the complex 2 was used instead of the complex 1. The obtained baked confectionery had a water activity of 0.65 and a water content of 10% by mass, but had a soft and moist texture, finished with a good flavor and good shape retention.
実施例3
上記複合体1の代わりに上記複合体3を130質量部用いた以外は、実施例1と同様にして、焼き菓子を得た。得られた焼き菓子は、水分活性が0.7、水分含量が13質量%でありながら、ソフトでしっとりとした食感で、風味良好に仕上がり、保型性も良好であった。
Example 3
A baked confectionery was obtained in the same manner as in Example 1 except that 130 parts by mass of the complex 3 was used instead of the complex 1. The obtained baked confectionery had a water activity of 0.7 and a water content of 13% by mass, and it had a soft and moist texture and finished with a good flavor and good shape retention.
実施例4
上記複合体1の代わりに上記複合体4を130質量部用いた以外は、実施例1と同様にして、焼き菓子を得た。得られた焼き菓子は、水分活性が0.69、水分含量が13質量%でありながら、ソフトでしっとりとした食感で、風味良好に仕上がり、保型性も良好であった。
Example 4
A baked confectionery was obtained in the same manner as in Example 1 except that 130 parts by mass of the complex 4 was used instead of the complex 1. The obtained baked confectionery had a water activity of 0.69 and a water content of 13% by mass, and it had a soft and moist texture and finished with a good flavor and good shape retention.
比較例1
マーガリン133質量部を溶解後、砂糖120質量部及び乳糖6.5質量部を混合し、全卵60質量部、食塩1.2質量部、水70質量部、発酵乳99.7質量部、クリームからバターオイルを製造する際に生じる水相成分の濃縮物(蛋白質含有量12質量%、乳固形分38質量%、乳固形分中のリン脂質の含有量9.8質量%)3.9質量部をさらに混合し均一にした後、薄力粉70質量部、アルギン酸ナトリウム1.6質量部、ローカストビーンガム0.1質量部、タピオカ由来化工澱粉2.6質量部、メタリン酸ナトリウム0.7質量部、ゼラチン1.3質量部を軽く混合した。得られた生地を室温で15分間放置した後、ワイヤーカット成形をした。この成形生地を180℃で18分間焼成して、焼き菓子を得た。得られた焼き菓子は、水分活性が0.56、水分含量が7質量%であり、ソフトでしっとりとした食感には仕上がらず、パサパサとした食感であり、実施例4の焼き菓子と比較して保型性が悪く、ワイヤーカット成形生地が流れたような形状となってしまった。
Comparative Example 1
After dissolving 133 parts by weight of margarine, 120 parts by weight of sugar and 6.5 parts by weight of lactose are mixed, 60 parts by weight of whole egg, 1.2 parts by weight of salt, 70 parts by weight of water, 99.7 parts by weight of fermented milk, cream Concentrate of aqueous phase component produced when producing butter oil from dairy oil (protein content 12 mass%, milk solid content 38 mass%, phospholipid content 9.8 mass% in milk solid content) 3.9 mass After further mixing and homogenizing parts, 70 parts by weight of flour, 1.6 parts by weight of sodium alginate, 0.1 parts by weight of locust bean gum, 2.6 parts by weight of tapioca-derived modified starch, 0.7 parts by weight of sodium metaphosphate Then, 1.3 parts by weight of gelatin was lightly mixed. The obtained dough was allowed to stand at room temperature for 15 minutes, and then wire cut molding was performed. This molded dough was baked at 180 ° C. for 18 minutes to obtain a baked confectionery. The obtained baked confectionery had a water activity of 0.56, a water content of 7% by mass, did not finish with a soft and moist texture, and had a crisp texture. In comparison, the shape retention was poor, and the wire cut molded fabric flowed.
Claims (5)
The baked confectionery according to any one of claims 2 to 4, wherein the composite is kneaded with 70 to 220 parts by mass with respect to 100 parts by mass of flour used in the baked confectionery dough.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009027956A (en) * | 2007-07-26 | 2009-02-12 | Fuji Oil Co Ltd | Soft baked confectionery having crispy texture |
JP2009100710A (en) * | 2007-10-25 | 2009-05-14 | Adeka Corp | Texture improver and method for producing the same |
JP2016165246A (en) * | 2015-03-09 | 2016-09-15 | 株式会社Adeka | Texture improvement material for baked confectionery |
US11896016B2 (en) * | 2013-10-04 | 2024-02-13 | Generale Biscuit | Soft biscuit with slowly available glucose |
-
2004
- 2004-09-17 JP JP2004272492A patent/JP2006081516A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009027956A (en) * | 2007-07-26 | 2009-02-12 | Fuji Oil Co Ltd | Soft baked confectionery having crispy texture |
JP2009100710A (en) * | 2007-10-25 | 2009-05-14 | Adeka Corp | Texture improver and method for producing the same |
US11896016B2 (en) * | 2013-10-04 | 2024-02-13 | Generale Biscuit | Soft biscuit with slowly available glucose |
JP2016165246A (en) * | 2015-03-09 | 2016-09-15 | 株式会社Adeka | Texture improvement material for baked confectionery |
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