JP2005198854A - Molding for deodorization and antibacterial use, and manufacturing method therefor - Google Patents
Molding for deodorization and antibacterial use, and manufacturing method therefor Download PDFInfo
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- JP2005198854A JP2005198854A JP2004008710A JP2004008710A JP2005198854A JP 2005198854 A JP2005198854 A JP 2005198854A JP 2004008710 A JP2004008710 A JP 2004008710A JP 2004008710 A JP2004008710 A JP 2004008710A JP 2005198854 A JP2005198854 A JP 2005198854A
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Abstract
Description
本発明は桜の葉や樹皮等の天然素材をベースに、天然由来の芳香、抗菌成分を配合し、屋内にて燃焼させることで、室内環境を清浄化し、空気を爽やかにすると共に春の桜花独特のかぐわしい香りをたたせることができるようになした消臭、抗菌用成形品及びその製造方法に関するものである。 The present invention is based on natural materials such as cherry leaves and bark, blended with naturally derived fragrances and antibacterial ingredients, and burned indoors to clean the indoor environment, refresh the air and make spring cherry blossoms unique The present invention relates to a deodorizing and antibacterial molded product that can give a strong scent and a method for producing the same.
従来、木炭を成分として用い、これに糊料を混合し、水を加えて練合した後成形し、乾燥させて成形品とした線香、お香等の燻蒸物がある。 Conventionally, charcoal is used as a component, paste is mixed with this, kneaded with water, molded, dried, and dried into molded products such as incense and incense.
斯かる従来の燻蒸物の大部分は、一般的な素材の組み合わせに香料を配合して成形したものであり、単に一時的に香りを楽しむためのものである。ところで、毎年のことながら春先からの強風に始まる高温多湿になり易い環境下では屋内居住空間が不快になりがちである。そこで、不快な屋内居住空間を爽やかで快適な状態にしたいと誰しもが願い、このような機能を持った製品の開発が待たれていた。 Most of such conventional fumigation products are formed by blending a fragrance with a combination of general materials, and are merely for temporarily enjoying the scent. By the way, the indoor living space tends to become uncomfortable under the environment where it tends to become hot and humid, starting with the strong wind from early spring. Therefore, everyone wished to make the uncomfortable indoor living space refreshing and comfortable, and the development of a product with such a function was awaited.
本発明は斯かる状況に鑑みてなされたものであって、春先からの高温多湿、強風、多雨が多頻度の環境下にあっても屋内居住空間に快適さをもたらすことができ、加えて桜花独特のかぐわしい香りをたたせて心の安らぎをも得られるようになした消臭、抗菌用成形品及びその製造方法を提供せんとするものである。 The present invention has been made in view of such a situation, and can provide comfort to an indoor living space even under high-temperature, high-humidity, strong wind, and heavy rain from early spring. It is intended to provide a deodorant and antibacterial molded article and a method for producing the same, which can give a peace of mind by giving a unique and aroma.
そこで、上記消臭、抗菌用成形品を得るべく本発明者らが研究を重ねたところ、桜の葉或いは樹皮はそれらに含まれるフラボノイドが抗菌作用及び消臭作用を有し、また炭は吸着作用、消臭作用、清浄作用、吸湿・放湿作用を、更にポリフェノールは抗菌作用、消臭作用を、またクマリンは抗菌作用を夫々有することから、これらを適宜に組み合わせることにより、その相乗効果で強力な消臭、抗菌作用を期待できること、更に桜の葉や樹皮によって桜花独特の香りを付加させることも可能であることを知見し、本発明を完成するに至ったものである。 Therefore, as a result of repeated researches by the present inventors to obtain the above-mentioned deodorant and antibacterial molded products, cherry leaves or bark have antibacterial and deodorant actions of flavonoids contained in them, and charcoal has an adsorption action. , Deodorant action, cleansing action, moisture absorption / dehumidification action, polyphenol has antibacterial action and deodorant action, and coumarin has antibacterial action. As a result, the inventors have found that it is possible to expect a deodorant and antibacterial action, and that it is possible to add a unique scent of cherry blossoms with cherry leaves and bark, and the present invention has been completed.
而して、本発明に係る消臭、抗菌用成形品は、桜、ポリフェノール、炭、クマリンを必須成分として含むことを特徴とするものである。 Thus, the deodorant and antibacterial molded article according to the present invention is characterized by containing cherry, polyphenol, charcoal, and coumarin as essential components.
また、上記消臭、抗菌用成形品における桜は、バラ科(Rosaceae)のヤマザクラ(Prunus jamasakura:Prunus属)、ソメイヨシノ(Prunus yedoensis)等を主体とするサクラ属を起源とするもので、それらの1種以上からなるものである。またこれらは葉又は樹皮を乾燥させて材料とするものである。また、上記消臭、抗菌用成形品における桜の全体に対する含有量は、0.1〜20重量%であることが望ましい。 Also, the cherry in the deodorant and antibacterial molded product originates from the cherry genus mainly composed of Rosaceae's Yamazakura (Prunus jamakura: Prunus genus), Yoshino cherry (Prunus yedoensis), etc. It consists of one or more. These are used by drying leaves or bark. Further, the content of the deodorant and antibacterial molded product with respect to the entire cherry is desirably 0.1 to 20% by weight.
また、上記ポリフェノールは、ペパーミント、緑茶、リンゴ、紫蘇、ブルーベリー、ブドウ、甜茶、ウーロン茶、月見草種子、グアバ、ライチ、クランベリー等の消臭、抗菌効果を有する植物を起源とするものである。そしてこれらは粉末又はエキスとして用いるものである。また、上記消臭、抗菌用成形品におけるこれらの全体に対する含有量は、0.01〜10重量%であることが望ましい。 The polyphenols originate from plants having deodorant and antibacterial effects such as peppermint, green tea, apple, shiso, blueberry, grape, strawberry tea, oolong tea, evening primrose seed, guava, lychee and cranberry. These are used as powders or extracts. In addition, the content of the deodorant and antibacterial molded article relative to the whole is preferably 0.01 to 10% by weight.
また、上記消臭、抗菌用成形品には、所定の割合で炭を配合するが、この炭としては木炭、竹炭、活性炭、黒炭、白炭等のいずれかが用いられる。また、上記消臭、抗菌用成形品におけるこれらの全体に対する含有量は、1〜60重量%であることが望ましい。 The deodorant and antibacterial molded products are mixed with charcoal at a predetermined ratio, and as the charcoal, any of charcoal, bamboo charcoal, activated carbon, black charcoal, white charcoal and the like is used. Moreover, it is desirable that the content of the deodorant and antibacterial molded product with respect to the whole is 1 to 60% by weight.
また、上記クマリンは、天然に広く存在し、桜の葉や花にもβ−グルコシル−オルト−クマール酸として存在し、加工中にクマリンへと変化して匂うものであり、単体は無色の結晶である。また、上記消臭、抗菌用成形品におけるこれの全体に対する含有量は、0.01〜5重量%であることが望ましい。 In addition, the coumarin is widely present in nature, and is also present in cherry leaves and flowers as β-glucosyl-ortho-coumaric acid, which changes to coumarin during processing, and the simple substance is a colorless crystal. is there. In addition, the content of the deodorant and antibacterial molded product relative to the whole is preferably 0.01 to 5% by weight.
また、本発明に係る上記消臭、抗菌用成形品の製造方法は、桜、ポリフェノール、炭、クマリンとに無機物質、糊料、香料、防黴剤、顔料、着色料、溶解剤等を混合し、更に水を加えて均一に練合し,所定の形状に成形することを要旨とするものである。 In addition, the method for producing the above-mentioned deodorant and antibacterial molded product according to the present invention comprises mixing cherry, polyphenol, charcoal, coumarin with inorganic substances, pastes, fragrances, antifungal agents, pigments, colorants, solubilizers, etc. In addition, the gist is to further add water and knead uniformly to form a predetermined shape.
本発明に係る消臭、抗菌用成形品は、これに点火して燃焼させ、加熱によりこれに含まれる成分を拡散させて消臭、抗菌作用、吸湿作用を発揮させるものであり、もって屋内の居住空間を爽やかで快適な環境に維持することができるものである。加えて、桜花独特のかぐわしい香りをたたせて心の安らぎを得られるようにすることもできるものである。 The molded product for deodorization and antibacterial according to the present invention is ignited and burned, diffuses the components contained therein by heating, and exerts deodorization, antibacterial action, moisture absorption action, and therefore indoors The living space can be maintained in a refreshing and comfortable environment. In addition, you can give a peace of mind by giving the cherry blossom a unique fragrance.
また、本発明に係る消臭、抗菌用成形品の製造方法によれば、桜、ポリフェノール、炭、クマリンが有する特性を安定した状態で保持する消臭、抗菌用成形品を製造することができるものである。 In addition, according to the method for producing a deodorant and antibacterial molded product according to the present invention, it is possible to produce a deodorized and antibacterial molded product that maintains the characteristics of cherry, polyphenol, charcoal, and coumarin in a stable state. Is.
本発明に係る消臭、抗菌用成形品は、桜、ポリフェノール、炭、クマリンを必須成分として含み、燃焼させることにより、これらの成分が加熱によって拡散するようにしたものである。 The molded product for deodorant and antibacterial according to the present invention contains cherry, polyphenol, charcoal, and coumarin as essential components, and these components are diffused by heating when burned.
また、本発明に係る上記消臭、抗菌用成形品の製造方法は、桜、ポリフェノール、炭、クマリンとに、無機物質、糊料、香料、防黴剤、顔料、着色料、溶解剤等を混合し、更に水を加えて均一に練合し、所定の形状に成形するものである。 In addition, the method for producing the deodorant and antibacterial molded product according to the present invention includes cherry, polyphenol, charcoal, coumarin, inorganic substances, pastes, fragrances, antifungal agents, pigments, colorants, solubilizers, and the like. Mix, further add water, knead uniformly, and shape into a predetermined shape.
以下、本発明の実施例について説明する。
本発明に係る消臭、抗菌用成形品は、桜、ポリフェノール、炭、クマリンを必須成分として含み、燃焼させることによってこれらの成分が拡散し、もって消臭作用、抗菌作用、吸湿作用等を発揮させるようになしたことを特徴とするものである。
Examples of the present invention will be described below.
The deodorant and antibacterial molded product according to the present invention contains cherry, polyphenol, charcoal, and coumarin as essential components, and these components diffuse when burned, thereby exhibiting a deodorant effect, an antibacterial effect, a hygroscopic effect, etc. It is characterized by having been made to do.
また、本発明に係る製造方法によって製造した消臭、抗菌用成形品によれば、桜、ポリフェノール、炭、クマリンが有する特性を安定した状態で保持させ、空気清浄作用、消臭作用等の機能特性を充分に発揮させることが可能である。 In addition, according to the deodorant and antibacterial molded article produced by the production method according to the present invention, the characteristics of cherry, polyphenol, charcoal, coumarin are kept in a stable state, and functions such as air cleaning action and deodorization action It is possible to fully exhibit the characteristics.
また、上記消臭、抗菌用成形品における桜は、バラ科のヤマザクラ、ソメイヨシノ等であり、これらの新鮮な葉及び/又は樹皮を乾燥させ、これを粉砕し、粉末として用いるものである。葉にはクマリン誘導体のβ−グルコシル−オルト−クマール酸等が含まれ、これは分解してクマリンに変化する。そしてクマリンは桜特有な香りとなる。また、樹皮には、ポリフェノールの一種であるフラバノン誘導体のサクラニン、サクラネチン、グルコゲンカニン等が含まれている。そしてこれらのポリフェノール類には抗菌作用、消臭作用が認められる。 The cherry in the deodorized and antibacterial molded article is a rosaceae mountain cherry, Yoshino cherry, etc., and these fresh leaves and / or bark are dried, pulverized, and used as a powder. The leaves contain the coumarin derivative β-glucosyl-ortho-coumaric acid, etc., which decomposes and changes to coumarin. And coumarin has a unique scent. The bark contains flavanone derivatives such as sakuranin, sakuranetin, and glucogen canine, which are polyphenols. These polyphenols have antibacterial and deodorizing effects.
また、炭は、一般に汎用される木炭、竹炭、活性炭、黒炭、白炭等である。これらの特性から空気清浄作用、消臭作用、吸湿・脱湿作用等の作用が生じる。 The charcoal is generally used charcoal, bamboo charcoal, activated carbon, black charcoal, white charcoal and the like. From these characteristics, actions such as air cleaning action, deodorizing action, moisture absorption / dehumidification action, and the like are generated.
また、ポリフェノールは、ペパーミントから得られたミントポリフェノール、緑茶のカテキン類、リンゴのポリフェノール類(プロアントシアニジン、カテキン、エピカテキン、クロロゲン酸等)、紫蘇のルテオリン、アピゲニン、クリソエリオール等、ブルーベリーのアントシアニジン、ブドウのオリゴメリックプロアントシアニジン等、甜茶のエラグタン、ウーロン茶のカテキン類、月見草種子の没食子酸、カテキン、プロアントシアニジン、エラグ酸、グアバのエラグ酸、エラグタンニン、プロアントシアニジン、ライチのロイコシアニジン、クランベリーのプロアントシアニジン等であり、これらはいずれも抗菌作用、消臭作用、空気清浄作用を有する。 Polyphenols include mint polyphenols obtained from peppermint, green tea catechins, apple polyphenols (proanthocyanidins, catechins, epicatechins, chlorogenic acids, etc.), shiso luteolin, apigenin, chrysoeriol, blueberry anthocyanidins, etc. , Grape Oligomeric Proanthocyanidins, etc. Proanthocyanidins and the like, all of which have antibacterial action, deodorant action, and air cleaning action.
本発明に係る消臭、抗菌用成形品の機能評価の指標として、4大悪臭の内のアンモニアと硫化水素に対する消臭効果の測定及び室内浮遊細菌への抑制効果を測定した。
そして、この結果から本発明に係る消臭、抗菌用成形品の効果を確認した。
As an index of functional evaluation of the deodorant and antibacterial molded product according to the present invention, the deodorizing effect on ammonia and hydrogen sulfide among the four major odors and the inhibiting effect on indoor floating bacteria were measured.
And the effect of the deodorizing and antibacterial molded article which concerns on this invention from this result was confirmed.
以下、本発明に係る消臭、抗菌用成形品の試験例を示す。
成形品1:
桜の樹皮1g、ミントポリフェノール0.5g、木炭12g、クマリン0.1g、タブ粉8g、香料、防黴剤等を混合し、更に水を加えて練合し、円柱状に成形した後乾燥させて製造した。
Hereinafter, test examples of the deodorant and antibacterial molded article according to the present invention will be shown.
Molded product 1:
1g of cherry bark, 0.5g of mint polyphenol, 12g of charcoal, 0.1g of coumarin, 8g of tab powder, fragrance, mildew-proofing agent, etc. are mixed and further kneaded with water, molded into a cylindrical shape and dried. Manufactured.
成形品2:
桜の葉3g、緑茶カテキン1.0g、竹炭7g、活性炭1g、クマリン0.5g、タブ粉5g、合成糊料1.2g、香料、防黴剤等を混合し、更に水を加えて練合し、円柱状に成形した後乾燥させて製造した。
Molded product 2:
3g of cherry leaves, 1.0g of green tea catechin, 7g of bamboo charcoal, 1g of activated charcoal, 0.5g of coumarin, 5g of tub powder, 1.2g of synthetic glue, fragrance, antifungal agent, etc. are mixed and further kneaded with water. Then, it was formed into a cylindrical shape and then dried.
対照試料A:
成形品1において桜の樹皮、ミントポリフェノール、炭、クマリンを含まない処方で同様に製造した。
Control sample A:
The molded product 1 was produced in the same manner with a formulation not containing cherry bark, mint polyphenol, charcoal, and coumarin.
対照試料B:
市販の線香。
Control sample B:
Commercial incense sticks.
対照試料C:
市販の線香。
Control sample C:
Commercial incense sticks.
消臭効果の測定:一辺が約600mmの立方体ボックス内に、悪臭物質溶液の入った容器を30分間開栓して悪臭物質を拡散させ、濃度を測定した。次いで試料3本を同ボックス内で燃焼させ、燃焼終了30分後に残存悪臭物質濃度を測定した。両濃度の差から消臭率(%)を測定した。 Measurement of deodorizing effect: In a cubic box having a side of about 600 mm, the container containing the malodorous substance solution was opened for 30 minutes to diffuse the malodorous substance, and the concentration was measured. Next, three samples were burned in the same box, and the residual malodorous substance concentration was measured 30 minutes after the completion of combustion. The deodorization rate (%) was measured from the difference between the two concentrations.
浮遊微生物の測定:約20m3 の測定室内の中央に、一般細菌用アガーストリップを装着したエアーサンプラー(GSIクレオス)を設置する。測定室内空気160リットルを吸引した後アガーストリップを取り出し、37℃で5日間培養して生育菌数をカウントした(ブランク)。次いで成形品及び対照品をそれぞれ1本測定室中央にて燃焼させる。燃焼後30分後の測定室内の浮遊菌数をブランクと同様に測定した。
ブランクと残存浮遊菌数から試料の燃焼による室内細菌減少率を求めた。
Measurement of airborne microorganisms: An air sampler (GSI Creos) equipped with an agar strip for general bacteria is installed in the center of a measurement chamber of about 20 m 3 . After aspirating 160 liters of measurement room air, the agar strip was taken out and cultured at 37 ° C. for 5 days to count the number of growing bacteria (blank). Next, one molded product and one control product are burned in the center of the measurement chamber. The number of airborne bacteria in the measurement chamber 30 minutes after combustion was measured in the same manner as in the blank.
The rate of indoor bacteria reduction by burning the sample was determined from the blank and the number of remaining floating bacteria.
結果は、表1及び表2に示す通りであり、本発明に係る消臭、抗菌用成形品が、4大悪臭への顕著な消臭作用を有し、更に空気中の浮遊微生物の顕著な低減作用を示すことが明らかである。尚、表1は消臭効果測定の測定結果、表2は抗菌効果測定の測定結果である。 The results are as shown in Tables 1 and 2, and the deodorant and antibacterial molded article according to the present invention has a remarkable deodorizing action on the four major odors, and is further prominent in airborne microorganisms. It is clear that it shows a reducing effect. Table 1 shows the measurement results of the deodorizing effect measurement, and Table 2 shows the measurement results of the antibacterial effect measurement.
Claims (10)
Mixing cherry, polyphenol, charcoal, coumarin with inorganic substances, pastes, fragrances, antifungal agents, pigments, colorants, solubilizers, etc., adding water and kneading them uniformly to form the desired shape Deodorant and antibacterial molded product manufacturing method.
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