JP2005119315A - Mold for molding decoration sheet - Google Patents
Mold for molding decoration sheet Download PDFInfo
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- JP2005119315A JP2005119315A JP2004339462A JP2004339462A JP2005119315A JP 2005119315 A JP2005119315 A JP 2005119315A JP 2004339462 A JP2004339462 A JP 2004339462A JP 2004339462 A JP2004339462 A JP 2004339462A JP 2005119315 A JP2005119315 A JP 2005119315A
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Images
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- Injection Moulding Of Plastics Or The Like (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
Abstract
Description
この発明は、加飾シート成形用金型に関する。 The present invention relates to a decorative sheet molding die.
従来、基体シート上に種々の模様を有する加飾層が形成された加飾シートがあった。 Conventionally, there has been a decorative sheet in which a decorative layer having various patterns is formed on a base sheet.
加飾シートは、通常、平面状から所望の立体形状に変形させて使用される。加飾シートを立体形状に変形させる具体的な方法としては次の2例がある。 The decorative sheet is usually used by being deformed from a flat shape to a desired three-dimensional shape. There are the following two examples of specific methods for deforming the decorative sheet into a three-dimensional shape.
(1)加飾シートを雌型の凹部の周囲の金型面にクランプ材で押し付け、加熱して軟化状態とした加飾シートを真空吸引して雌型の凹部に吸い付けた後、立体形状となった加飾シートを常温に冷却することにより成形加工する方法。 (1) The decorative sheet is pressed against the mold surface around the female recess with a clamp material, heated and softened, the decorative sheet is vacuum sucked and sucked into the female recess, and then the three-dimensional shape A method of forming the decorative sheet by cooling it to room temperature.
(2)加熱して軟化状態とした加飾シートを射出成形用金型の雄型と雌型との間に挟み込んで型締めとともに雄型の凸部により雌型の凹部に押し込むか、あるいは、常温のままの加飾シートを射出成形用金型の雄型と雌型との間に挟み込んで射出された溶融樹脂の熱圧により加飾シートを軟化状態として雌型の凹部に押し込み、加飾シートを常温に冷却することにより成形加工する方法。 (2) The decorative sheet heated and softened is sandwiched between a male mold and a female mold of an injection mold, and clamped and pushed into the female concave portion by the male convex portion, or The decorative sheet at room temperature is sandwiched between the male mold and female mold of the injection mold, and the decorative sheet is softened by the hot pressure of the injected molten resin and pushed into the female mold recess to decorate. A method of forming a sheet by cooling the sheet to room temperature.
しかし、加飾シートが加熱される工程で、熱により加飾シートの基体シート側または加飾層側に付着性が生じ、その付着性が生じた部分が金型面またはクランプ面に接触するときに付着しやすくなり、前記(1)のクランプ材の押し付けや(2)の型締めによる外力がかかると付着はより強固なものとなる。このため、金型面またはこれに対応するクランプ面から加飾シートを引き離す際、加飾シートを構成する基体シートまたは加飾層の一部が凝集破壊または層間剥離して、加飾シートに欠損が生じたり、凝集破壊片が雌型に残留したりするという問題点が生じる(図3参照)。 However, when the decorative sheet is heated, adhesion occurs on the base sheet side or the decorative layer side of the decorative sheet due to heat, and the part where the adhesion occurs contacts the mold surface or the clamp surface When the external force is applied by pressing the clamp material (1) or clamping the mold (2), the adhesion becomes stronger. For this reason, when the decorative sheet is pulled away from the mold surface or the clamp surface corresponding to the mold surface, a part of the base sheet or the decorative layer constituting the decorative sheet is agglomerated or delaminated, resulting in a defect in the decorative sheet. Or cohesive fracture pieces remain in the female mold (see FIG. 3).
なお、「付着性が生じ」るとは、加飾シートの材質中に含まれている可塑剤が熱によって表面に溶出してべとついたり、熱によって加飾シートがやわらかくなったりして金型面に付着しやすくなることをいう。また、金型面に対する付着性の大きさは、基体シート側と加飾層側とでは異なる。その理由は、基体シートと加飾層とでは使用する樹脂の可塑剤の含有量や使用する樹脂の融点(Tm)、軟化温度が異なるからである。 Note that “adhesion occurs” means that the plasticizer contained in the decorative sheet material elutes on the surface due to heat and becomes sticky, or the decorative sheet softens due to heat. It means that it tends to adhere to the mold surface. Moreover, the magnitude | size of the adhesiveness with respect to a metal mold | die surface differs on the base sheet side and the decoration layer side. The reason is that the content of the plasticizer of the resin used, the melting point (Tm) of the resin used, and the softening temperature are different between the base sheet and the decorative layer.
したがって、この発明は上記のような問題ができるだけ少ない加飾シート成形用金型を提供することを目的とする。 Accordingly, an object of the present invention is to provide a decorative sheet-molding mold with as few problems as described above.
この発明は、次のようにした。 The present invention is as follows.
請求項1に記載したように、基体シート上に少なくとも加飾層が形成された加飾シートを金型面にクランプ材で押し付けて固定した状態で、加飾シートに形成された加飾層と金型形状との位置精度を保って成形加工するための加飾シート成形用金型であって、該加飾シートと接触するクランプ面またはこれに対応する金型面の平均表面粗さRaが0.01〜30.0×10−3mmであることを特徴とする加飾シート成形用金型とした。 As described in claim 1, in a state where a decorative sheet having at least a decorative layer formed on a base sheet is pressed against a mold surface with a clamp material and fixed, and a decorative layer formed on the decorative sheet; A mold for decorative sheet molding for molding while maintaining positional accuracy with the mold shape, and an average surface roughness Ra of a clamp surface that contacts the decorative sheet or a mold surface corresponding thereto The decorative sheet-molding mold was 0.01 to 30.0 × 10 −3 mm.
請求項2に記載したように、上記加飾シート成形用金型が樹脂成形品用真空成形金型である加飾シート成形用金型としてもよい。 As described in claim 2, the decorative sheet molding die may be a decorative sheet molding die which is a vacuum molding die for resin molded products.
請求項3に記載したように、基体シート上に少なくとも加飾層が形成された加飾シートを雄型と雌型との間に挟み込み押し付けて固定した状態で、加飾シートに形成された加飾層と金型形状との位置精度を保って成形加工するための加飾シート成形用金型であって、加飾シートを挟み込んだときに加飾シートと接触する雄型または雌型の少なくとも一方の金型面の平均表面粗さRaが0.01〜12.5×10−3mmであることを特徴とする加飾シート成形用金型としてもよい。 The decorative sheet formed on the decorative sheet in a state where the decorative sheet having at least the decorative layer formed on the base sheet is sandwiched between the male mold and the female mold and fixed. A decorative sheet-forming mold for molding while maintaining the positional accuracy of the decorative layer and the mold shape, and at least a male mold or a female mold that comes into contact with the decorative sheet when the decorative sheet is sandwiched One mold surface may have an average surface roughness Ra of 0.01 to 12.5 × 10 −3 mm, and may be a decorative sheet molding mold.
請求項4に記載したように、上記加飾シート成形用金型が樹脂成形品用射出成形金型であである加飾シート成形用金型であってもよい。 According to a fourth aspect of the present invention, the decorative sheet molding die may be an injection mold for a resin molded product.
この発明の加飾シート成形用金型は、基体シート上に少なくとも加飾層が形成された加飾シートを金型面にクランプ材で押し付けて固定した状態で、加飾シートに形成された加飾層と金型形状との位置精度を保って成形加工するための加飾シート成形用金型であって、該加飾シートと接触するクランプ面またはこれに対応する金型面の平均表面粗さRaが0.01〜30.0×10−3mmである。 The decorative sheet-forming mold of the present invention is a decorative sheet formed on a decorative sheet in a state where a decorative sheet having at least a decorative layer formed on a base sheet is pressed against a mold surface with a clamp material and fixed. A decorative sheet molding mold for molding with a positional accuracy between the decorative layer and the mold shape, the average surface roughness of the clamp surface in contact with the decorative sheet or the mold surface corresponding thereto Ra is 0.01-30.0 × 10 −3 mm.
また、この発明の加飾シート成形用金型は、基体シート上に少なくとも加飾層が形成された加飾シートを雄型と雌型との間に挟み込み押し付けて固定した状態で、加飾シートに形成された加飾層と金型形状との位置精度を保って成形加工するための加飾シート成形用金型であって、加飾シートを挟み込んだときに加飾シートと接触する雄型または雌型の少なくとも一方の金型面の平均表面粗さRaが0.01〜12.5×10−3mmである。 The decorative sheet molding die of the present invention is a decorative sheet in a state where a decorative sheet having at least a decorative layer formed on a base sheet is sandwiched between a male mold and a female mold and fixed. A mold for decorative sheet molding for molding while maintaining the positional accuracy between the decorative layer formed on the mold and the mold shape, and a male mold that comes into contact with the decorative sheet when the decorative sheet is sandwiched Alternatively, the average surface roughness Ra of at least one mold surface of the female mold is 0.01 to 12.5 × 10 −3 mm.
したがって、加飾シートが加熱される工程で、熱により加飾シートの基体シート側の表面または加飾層側の表面に付着性が生じ、かつ、クランプ材や型締めによる外力がかかっても、金型面に加飾シートが付着しない。したがって、金型面から加飾シートを引き離す際、加飾シートを構成する基体シートまたは加飾層の一部が凝集破壊や層間剥離して、凝集破壊片が成形用金型に残留したり、加飾シートが欠損したりすることがない。 Therefore, in the process in which the decorative sheet is heated, adhesion occurs on the surface of the decorative sheet on the base sheet side or the surface of the decorative layer side by heat, and even if an external force is applied by the clamping material or mold clamping, The decorative sheet does not adhere to the mold surface. Therefore, when the decorative sheet is pulled away from the mold surface, a part of the base sheet or the decorative layer constituting the decorative sheet is cohesive failure or delamination, cohesive failure pieces remain in the molding die, The decorative sheet is not lost.
この発明の加飾シート成形用金型は、基体シート上に少なくとも加飾層が形成された加飾シートを金型面にクランプ材で押し付けて固定した状態で、加飾シートに形成された加飾層と金型形状との位置精度を保って成形加工するための加飾シート成形用金型であって、該加飾シートと接触するクランプ面またはこれに対応する金型面の平均表面粗さRaが0.01〜30.0×10−3mmである。 The decorative sheet-forming mold of the present invention is a decorative sheet formed on a decorative sheet in a state where a decorative sheet having at least a decorative layer formed on a base sheet is pressed against a mold surface with a clamp material and fixed. A decorative sheet molding mold for molding with a positional accuracy between the decorative layer and the mold shape, the average surface roughness of the clamp surface in contact with the decorative sheet or the mold surface corresponding thereto Ra is 0.01-30.0 × 10 −3 mm.
また、この発明の加飾シート成形用金型は、基体シート上に少なくとも加飾層が形成された加飾シートを雄型と雌型との間に挟み込み押し付けて固定した状態で、加飾シートに形成された加飾層と金型形状との位置精度を保って成形加工するための加飾シート成形用金型であって、加飾シートを挟み込んだときに加飾シートと接触する雄型または雌型の少なくとも一方の金型面の平均表面粗さRaが0.01〜12.5×10−3mmである。 The decorative sheet molding die of the present invention is a decorative sheet in a state where a decorative sheet having at least a decorative layer formed on a base sheet is sandwiched between a male mold and a female mold and fixed. A mold for decorative sheet molding for molding while maintaining the positional accuracy between the decorative layer formed on the mold and the mold shape, and a male mold that comes into contact with the decorative sheet when the decorative sheet is sandwiched Alternatively, the average surface roughness Ra of at least one mold surface of the female mold is 0.01 to 12.5 × 10 −3 mm.
加飾シート成形用金型としては、図1、図2に示すような凹部6を有する雌型5と凸部7を有する雄型4とからなり、プレスにより加飾シート21を成形するプレス成形用金型8がある。また、図4、図5に示すような凹部6を有する雌型5を有する樹脂成形品用真空成形金型9がある。樹脂成形品用真空成形金型9には真空吸引孔22が形成されている。金型面には二の字状のクランプ材3が取付けられている。クランプ材3は、図7に示すように枠状となっていてもよい。なお、加飾シート21を金型面にクランプ材3で押し付けて保持した状態で成形加工するための加飾シート成形用金型としては、前記樹脂成形品用真空成形金型9以外にも、たとえば圧空成形(超高圧成形含む)金型、ブロー成形金型、ハイドロフォーミング金型などがある。 The decorative sheet forming mold includes a female mold 5 having a concave portion 6 and a male mold 4 having a convex portion 7 as shown in FIGS. 1 and 2, and press molding a decorative sheet 21 by pressing. There is a mold 8 for use. Further, there is a vacuum molding die 9 for a resin molded product having a female die 5 having a recess 6 as shown in FIGS. A vacuum suction hole 22 is formed in the vacuum molding die 9 for a resin molded product. A two-shaped clamp member 3 is attached to the mold surface. The clamp member 3 may have a frame shape as shown in FIG. In addition to the vacuum molding die 9 for resin molded products, the decorative sheet molding die for molding the decorative sheet 21 in a state in which the decorative sheet 21 is pressed and held on the mold surface by the clamp material 3, For example, there are pressure forming (including ultra-high pressure forming) molds, blow molding molds, hydroforming molds and the like.
また、図6に示すような凹部6を有する雌型5と雄型4とからなる樹脂成形品用射出成形金型10がある。雌型5には樹脂射出口11が形成されている。 In addition, there is an injection mold 10 for a resin molded product composed of a female mold 5 and a male mold 4 each having a recess 6 as shown in FIG. A resin injection port 11 is formed in the female mold 5.
金型面の平均表面粗さRaを前記の数値にする方法としては、バフ仕上げ、研磨、ヤスリ仕上げ、放電、ホーン仕上げ、研削、タンブリング、圧延などがある。 Examples of the method for setting the average surface roughness Ra of the mold surface to the above values include buffing, polishing, file finishing, electric discharge, horn finishing, grinding, tumbling, rolling and the like.
平均表面粗さRaを前記の数値にする個所は、金型面のうち加飾シート21と接触するクランプ面またはこれに対応する個所である。 The place where the average surface roughness Ra is set to the above-described numerical value is a clamp face in contact with the decorative sheet 21 or a place corresponding to the clamp face.
例えば、樹脂成形品用真空成形金型9を用いる場合は、加飾シート21を金型内に載置しクランプした時に、金型およびクランプ材3に接触する部分である。 For example, when using the vacuum molding die 9 for resin molded products, it is a portion that contacts the die and the clamp material 3 when the decorative sheet 21 is placed and clamped in the die.
樹脂成形品用射出成形金型10を用いる場合は、加飾シート21を雄型4と雌型5の間に載置し、成形機の型締め時に、加飾シート21が雄型4及び雌型5により挟み込まれる部分である。 When the injection mold 10 for resin molded products is used, the decorative sheet 21 is placed between the male mold 4 and the female mold 5, and when the molding machine is clamped, the decorative sheet 21 becomes the male mold 4 and the female mold. It is a portion sandwiched by the mold 5.
平均表面粗さRaを前記の数値にする個所は、少なくとも該加飾シートと接触するクランプ面またはこれに対応する金型面であって、それ以外の個所に形成してもよい。 The place where the average surface roughness Ra is set to the above-described numerical value is at least a clamp face that comes into contact with the decorative sheet or a mold face corresponding thereto, and may be formed at other places.
この発明では、基体シート1の樹脂の種類を替えた加飾シート21について、樹脂成形品用真空成形金型9を用いて、加飾シート21を金型面にクランプ材3で押し付けて保持する場合について、金型面の平均表面粗さRaと加飾シート21との間の動摩擦係数および加飾シート21の付着防止効果の関係を測定し、平均表面粗さRaの適用可能な範囲を選定した。 In this invention, about the decorating sheet 21 which changed the kind of resin of the base sheet 1, the decorating sheet 21 is pressed against the mold surface by the clamp material 3 and held using the vacuum molding die 9 for resin molded products. For the case, the relationship between the coefficient of dynamic friction between the average surface roughness Ra of the mold surface and the decorative sheet 21 and the adhesion preventing effect of the decorative sheet 21 is measured, and the applicable range of the average surface roughness Ra is selected. did.
また、樹脂成形品用射出成形金型10を用いて、雄型4と雌型5との間に加飾シート21を挟み込む場合についても、金型面の平均表面粗さRaと加飾シート21との間の動摩擦係数および加飾シート21の付着防止効果の関係を測定し、平均表面粗さRaの適用可能な範囲を選定した。 Further, when the decorative sheet 21 is sandwiched between the male mold 4 and the female mold 5 using the injection mold 10 for resin molded products, the average surface roughness Ra of the mold surface and the decorative sheet 21 are also included. The relationship between the coefficient of dynamic friction and the adhesion preventing effect of the decorative sheet 21 was measured, and the applicable range of the average surface roughness Ra was selected.
その結果、樹脂成形品用真空成形金型9を用いた場合では、上記加飾シート21のインキ層14と接触する金型面の平均表面粗さRaが30×10−3mm(30μm)以下になるまで金型面を平滑に加工すれば、テストした全ての加飾シート21で付着防止効果が確認された(表1参照)。特に、平均表面粗さRaを6.3×10−3mm(6.3μm)以下にすれば、テストした全ての加飾シート21で付着がなくなった(表1参照)。 As a result, when the vacuum molding die 9 for resin molded products is used, the average surface roughness Ra of the mold surface in contact with the ink layer 14 of the decorative sheet 21 is 30 × 10 −3 mm (30 μm) or less. If the mold surface was processed smoothly until, the adhesion preventing effect was confirmed in all the decorated sheets 21 tested (see Table 1). In particular, when the average surface roughness Ra was 6.3 × 10 −3 mm (6.3 μm) or less, adhesion was lost in all the decorated sheets 21 tested (see Table 1).
このときの金型面と加飾シート21との間の動摩擦係数は、加飾シート21の樹脂によって異なるものの全て、2.4以下であった(表3参照)。 The dynamic friction coefficients between the mold surface and the decorative sheet 21 at this time were all 2.4 or less (see Table 3), although they differ depending on the resin of the decorative sheet 21.
一方、樹脂成形品用射出成形金型10を用いた場合では、上記加飾シート21のインキ層14と接触する金型面の平均表面粗さRaが12.5×10−3mm(12.5μm)以下になるまで金型面を平滑に加工すれば、テストした全ての加飾シート21で付着防止効果が確認された(表2参照)。特に、表面部分の平均表面粗さRaを1.6×10−3mm以下にすれば、テストした全ての加飾シート21で付着がなくなった(表2参照)。 On the other hand, when the injection mold 10 for resin molded products is used, the average surface roughness Ra of the mold surface in contact with the ink layer 14 of the decorative sheet 21 is 12.5 × 10 −3 mm (12. If the mold surface was processed smoothly until it became 5 μm or less, the adhesion preventing effect was confirmed in all the decorative sheets 21 tested (see Table 2). In particular, when the average surface roughness Ra of the surface portion was set to 1.6 × 10 −3 mm or less, adhesion did not occur in all the decorated sheets 21 tested (see Table 2).
このときの金型面と加飾シート21との間の動摩擦係数は、加飾シート21の樹脂によって異なるものの、全て1.0以下であった(表4参照)。 The dynamic friction coefficient between the mold surface and the decorative sheet 21 at this time was 1.0 or less in all cases, although it differs depending on the resin of the decorative sheet 21 (see Table 4).
なお、平均表面粗さRaは、JISB0601−1994に準拠したガウシャンフィルタからなる粗さ計(例えば、小坂研究所F3500D)を用い、表面の断面曲線から平均線(うねり曲線)を差し引くことで粗さ曲線をもとめ、その粗さ曲線から得られる算術平均値とする。 The average surface roughness Ra is obtained by subtracting the average line (waviness curve) from the surface cross-section curve using a roughness meter (for example, Kosaka Laboratory F3500D) made of a Gaussian filter according to JIS B0601-1994. Find the roughness curve and use the arithmetic average value obtained from the roughness curve.
樹脂成形品用真空成形金型9の場合と樹脂成形品用射出成形金型10の場合とでは、各々、加飾シート21が金型面に押し付けられる圧力が異なるため、付着防止効果を奏することができる平均表面粗さRaや動摩擦係数の数値範囲も異なっているのである。 Since the pressure at which the decorative sheet 21 is pressed against the mold surface is different between the case of the vacuum molding die 9 for resin molded products and the case of the injection molding die 10 for resin molded products, the effect of preventing adhesion is exhibited. The average surface roughness Ra and the numerical range of the dynamic friction coefficient are different.
例えば、加飾シート21を樹脂成形品用真空成形金型9に用いる場合は、加飾シート21はクランプ材3によって数N〜数100N(数Kg重〜数10Kg重)の力で金型面に押し付けられるため、元来、金型面に加飾シート21が付着しにくい。よって、平均表面粗さRaは、上限が高いほうへシフトしている。 For example, when the decorative sheet 21 is used for the vacuum molding die 9 for a resin molded product, the decorative sheet 21 is molded with a clamping material 3 with a force of several N to several hundred N (several kilograms to several tens kilograms). Therefore, the decorative sheet 21 is hardly attached to the mold surface from the beginning. Therefore, the average surface roughness Ra is shifted to the higher upper limit.
一方、加飾シート21を樹脂成形品用射出成形金型10やプレス成形用金型8に用いる場合は、雄型4と雌型5との型締め力によって加飾シート21が数百トンの力で金型に挟み込まれるため、金型面に加飾シート21が付着しやすい。よって、平均表面粗さRaは、上限が低いほうへシフトしている。 On the other hand, when the decorative sheet 21 is used for the injection mold 10 for resin molded products or the press mold 8, the decorative sheet 21 is several hundred tons due to the clamping force of the male mold 4 and the female mold 5. Since it is inserted into the mold by force, the decorative sheet 21 is likely to adhere to the mold surface. Therefore, the average surface roughness Ra is shifted toward a lower upper limit.
(加飾シートについて)加飾シートについては、前記数値範囲の平均表面粗さRaを有する金型面との関係を両者間の動摩擦係数でもって相関を取り、付着防止効果を奏する動摩擦係数の数値範囲を選定した。 (About the decorative sheet) For the decorative sheet, the relationship with the mold surface having the average surface roughness Ra in the numerical range is correlated with the dynamic friction coefficient between the two, and the numerical value of the dynamic friction coefficient that exerts an adhesion preventing effect. The range was selected.
なお、この発明で「動摩擦係数」とは、図8に示すように、1cm角で厚さ1mmのプラスチック板12の片面に、両面テープ13を介して加飾シート21を貼付け、平均表面粗さRaの金型面の上に置く。金型面には加色シートのインキ層14(加飾層2)側を接触させる。そのプラスチック板12の反対面に導線15を貼り付け、その上に重さ0.98Nの分銅16を載せ、導線15を介して加飾シート21が貼り付けられているプラスチック板12を、平均表面粗さRaの金型面上で5cm/sの速度で引張り、その時の荷重を測定する。荷重測定は、上記導線15を滑車17を通して引張試験機18の引張りチャック19につなげて引張り駆動体24を移動させたときの荷重データを記録用パソコン20で演算してグラフ上に記録し、その5cm移動時の荷重値の平均値を取る。この平均荷重値(N)を分銅16の重さ0.98Nで割った値を動摩擦係数とする(プラスチック板12や導線15、両面テープ13の重さは0.005N未満となるようにする。)。上記において、プラスチック板12の大きさを1cm角としたのは、平均表面粗さRaの金型面のパターンが小面積でも評価できるようにするためである。また、分銅16の重さを0.98Nとしたのは、装置の誤差を取り除くために前記小面積の試験片に載せられる範囲でできる限り重いものにするためである。なお、測定誤差には、プラスチック板12などの重さの誤差も含まれる。この定義は、加飾シート21の加飾層2と平均表面粗さRaの金型面との関係においても、加飾シート21の基体シート1と平均表面粗さRaの金型面との関係においても同様である。上記各測定値に基づき記録用パソコン20で演算して動摩擦係数の値を算出する。
In the present invention, the “dynamic friction coefficient” means, as shown in FIG. 8, a decorative sheet 21 is pasted on one side of a plastic plate 12 having a 1 cm square and a thickness of 1 mm via a double-sided tape 13 to obtain an average surface roughness. Place on Ra mold surface. The ink layer 14 (decorative layer 2) side of the colored sheet is brought into contact with the mold surface. A conductive wire 15 is attached to the opposite surface of the plastic plate 12, a
この発明において、動摩擦係数の程度は、金型面の物理的粗さと化学的付着力の両方に依存すると考えられる。 In the present invention, the degree of the dynamic friction coefficient is considered to depend on both physical roughness and chemical adhesion of the mold surface.
加飾シート21に要求される動摩擦係数の値は、その加飾シート21が用いられる成形用金型の種類によって異なってくる。成形用金型の種類によって金型面への加飾シート21の押し付け力に大きな違いが出てくるからである。 The value of the dynamic friction coefficient required for the decorative sheet 21 varies depending on the type of molding die in which the decorative sheet 21 is used. This is because there is a great difference in the pressing force of the decorative sheet 21 on the mold surface depending on the type of molding die.
つまり、加飾シート21を樹脂成形品用真空成形金型9に用いる場合は、加飾シート21はクランプ材3によって数N〜数100N(数Kg重〜数10Kg重)の力で金型面に押し付けられるため、元来、金型面に加飾シート21が付着しにくいので、動摩擦係数は比較的大きくてもよい。 That is, when the decorative sheet 21 is used for the vacuum molding die 9 for a resin molded product, the decorative sheet 21 is molded by the clamp material 3 with a force of several N to several hundred N (several kilograms to several tens kilograms). Since the decorative sheet 21 is not likely to adhere to the mold surface, the dynamic friction coefficient may be relatively large.
加飾シート21を樹脂成形品用射出成形金型10やプレス成形用金型8に用いる場合は、雄型4と雌型5との型締め力によって加飾シート21が数百トンの力で金型に挟み込まれるため、金型面に加飾シート21が付着しやすくなるので、動摩擦係数は比較的小さくする必要がある。 When the decorative sheet 21 is used for the injection mold 10 for a resin molded product or the press mold 8, the decorative sheet 21 has a force of several hundred tons by the clamping force of the male mold 4 and the female mold 5. Since the decorative sheet 21 is easily attached to the mold surface because it is sandwiched between the molds, the dynamic friction coefficient needs to be relatively small.
表3は、複数種類の加飾シート21を、樹脂成形品用真空成形金型9に用いた場合の、平均表面粗さRaが30(×10−3mm)の金型面と加飾シート21の基体シート1との間の動摩擦係数を測定し、付着防止効果が発揮される範囲を示した表である(表3参照)。測定方法は図8に示す方法に準じた。 Table 3 shows the mold surface and decorative sheet having an average surface roughness Ra of 30 (× 10 −3 mm) when a plurality of types of decorative sheets 21 are used in the vacuum forming mold 9 for resin molded products. It is the table | surface which showed the range where the dynamic friction coefficient between 21 base-material sheets 1 is measured, and the adhesion prevention effect is exhibited (refer Table 3). The measuring method was based on the method shown in FIG.
表4は、複数種類の加飾シート21を、射出成形用金型に用いた場合の、平均表面粗さRaが12.5(×10−3mm)の金型面と加飾シート21の基体シート1との間の動摩擦係数を測定し、付着防止効果が発揮される範囲を示した表である(表4参照)。測定方法は図8に示す方法に準じた。 Table 4 shows the mold surface and the decorative sheet 21 having an average surface roughness Ra of 12.5 (× 10 −3 mm) when a plurality of types of decorative sheets 21 are used in an injection mold. It is the table | surface which showed the range where the dynamic friction coefficient between the base sheet | seats 1 was measured, and the adhesion prevention effect was exhibited (refer Table 4). The measuring method was based on the method shown in FIG.
なお、この発明に係る加飾シート21は、各種の用途に適用することができる。また、その製品形態としては、立体成形用シート、転写箔、化粧シートなどがある。立体成形用シートとは、立体形状に成形された加飾シート21を完成品として販売するものであったり、または、立体形状に成形された加飾シート21を射出成形用金型内に嵌め込んだ後、射出成形品と一体化接着させたりして用いるものである。転写箔とは、被転写物に転写層を転写し基体シート1を剥離して用いるものである。化粧シートとは、平面状の加飾シート21を樹脂成形用射出成形金型の雄型4と雌型5との間に送り込んで雌型5の凹部6に沿わせた後、挟み込み、キャビティ内に溶融樹脂を射出し、固化させることにより、加飾シート21を立体形状に成形加工するとともに、成形品と一体化接着させて用いるものである。 In addition, the decorative sheet 21 according to the present invention can be applied to various uses. The product forms include a three-dimensional molding sheet, a transfer foil, a decorative sheet, and the like. The three-dimensional molding sheet is to sell the decorative sheet 21 molded into a three-dimensional shape as a finished product, or the decorative sheet 21 molded into a three-dimensional shape is fitted into an injection mold. After that, it is used by being integrally bonded to an injection molded product. The transfer foil is used by transferring a transfer layer to a transfer object and peeling off the substrate sheet 1. The decorative sheet is a flat decorative sheet 21 that is fed between a male mold 4 and a female mold 5 of an injection mold for resin molding, is placed along the concave portion 6 of the female mold 5, and is sandwiched between The decorative sheet 21 is molded into a three-dimensional shape by injecting a molten resin and solidifying it, and is used by being integrally bonded to a molded product.
加飾シート21の構成は、基体シート1上に少なくとも加飾層2が形成されたものであれば、転写箔(基体シート1を剥離するもの)、インサートシート(基体シート1を剥離しないもの)のいずれであってもよい。単なる化粧シートとは、基体シート1上に少なくとも加飾層2が形成されたものであって、接着層を有しないものをいう。 As long as the decorative sheet 21 has at least the decorative layer 2 formed on the base sheet 1, the transfer foil (the base sheet 1 is peeled off) and the insert sheet (the base sheet 1 is not peeled off). Any of these may be used. A simple decorative sheet refers to a sheet in which at least the decorative layer 2 is formed on the base sheet 1 and does not have an adhesive layer.
基体シート1の材質としては、ポリプロピレン系樹脂、ポリエチレン系樹脂、ポリアミド系樹脂、ポリエステル系樹脂、アクリル系樹脂、ポリ塩化ビニル系樹脂などの樹脂シートなど、通常の加飾シート21の基体シート1として用いられるものを用いることができる。 As a material of the base sheet 1, a base sheet 1 of a normal decorative sheet 21 such as a resin sheet such as a polypropylene resin, a polyethylene resin, a polyamide resin, a polyester resin, an acrylic resin, or a polyvinyl chloride resin is used. What is used can be used.
加飾層2は、基体シート1上に、通常は印刷層として形成する。印刷層の材質としては、ポリビニル系樹脂、ポリアミド系樹脂、ポリエステル系樹脂、アクリル系樹脂、ポリウレタン系樹脂、ポリビニルアセタール系樹脂、ポリエステルウレタン系樹脂、セルロースエステル系樹脂、アルキド系樹脂などの樹脂をバインダーとし、適切な色の顔料または染料を着色剤として含有する着色インキを用いるとよい。印刷層の形成方法としては、オフセット印刷法、グラビア印刷法、スクリーン印刷法などの通常の印刷法などを用いるとよい。印刷層は、表現したい図柄に応じて、全面的に形成する場合や部分的に形成する場合もある。 The decorative layer 2 is usually formed on the base sheet 1 as a printing layer. As a material for the printing layer, a binder such as a polyvinyl resin, a polyamide resin, a polyester resin, an acrylic resin, a polyurethane resin, a polyvinyl acetal resin, a polyester urethane resin, a cellulose ester resin, or an alkyd resin is used as a binder. And a color ink containing an appropriate color pigment or dye as a colorant may be used. As a method for forming the printing layer, a normal printing method such as an offset printing method, a gravure printing method, or a screen printing method may be used. The print layer may be formed entirely or partially depending on the pattern to be expressed.
加飾層2は、金属薄膜層からなるもの、あるいは印刷層と金属薄膜層との組み合わせからなるものでもよい。金属薄膜層は、加飾層2として金属光沢を表現するためのものであり、真空蒸着法、スパッターリング法、イオンプレーティング法、鍍金法などで形成するとよい。表現したい金属光沢の色に応じて、アルミニウム、ニッケル、金、白金、クロム、鉄、銅、スズ、インジウム、銀、チタニウム、鉛、亜鉛などの金属、これらの合金または化合物を用いるとよい。金属薄膜層は部分的に形成してもよい。また、金属薄膜層を形成する際の他の層との密着性を向上させるために、アンカー層を形成してもよい。 The decorative layer 2 may be composed of a metal thin film layer or a combination of a printed layer and a metal thin film layer. The metal thin film layer is for expressing the metallic luster as the decorative layer 2 and may be formed by a vacuum deposition method, a sputtering method, an ion plating method, a plating method, or the like. A metal such as aluminum, nickel, gold, platinum, chromium, iron, copper, tin, indium, silver, titanium, lead, or zinc, or an alloy or compound thereof may be used depending on the color of the metallic luster to be expressed. The metal thin film layer may be partially formed. Further, an anchor layer may be formed in order to improve the adhesion with other layers when forming the metal thin film layer.
また、必要に応じて接着層を形成してもよい。接着層は、成形樹脂などの上に加飾シート21を接着するものである。接着層としては、成形樹脂などの素材に適した感熱性あるいは感圧性の樹脂を適宜用いる。たとえば、成形樹脂の材質がアクリル系樹脂の場合はアクリル系樹脂を用いるとよい。また、材質がポリフェニレンオキシド系樹脂、ポリスチレン系樹脂、ポリカーボネート系樹脂、スチレン共重合体系樹脂、ポリスチレン系ブレンド樹脂の場合は、これらの樹脂と親和性のあるアクリル系樹脂、ポリスチレン系樹脂、ポリアミド系樹脂などを用いるとよい。さらに、材質がポリプロピレン樹脂の場合は、塩素化ポリオレフィン樹脂、塩素化エチレン−酢酸ビニル共重合体樹脂、環化ゴム、クマロンインデン樹脂などを用いるとよい。接着層の形成方法としては、グラビアコート法、ロールコート法、コンマコート法などのコート法、グラビア印刷法、スクリーン印刷法などの印刷法がある。また上記材質よりなる接着性を持つシートをラミネート法などにより貼り合せて接着層とすることもできる。 Moreover, you may form an contact bonding layer as needed. The adhesive layer adheres the decorative sheet 21 onto a molded resin or the like. As the adhesive layer, a heat-sensitive or pressure-sensitive resin suitable for a material such as a molding resin is appropriately used. For example, when the material of the molding resin is an acrylic resin, an acrylic resin may be used. If the material is polyphenylene oxide resin, polystyrene resin, polycarbonate resin, styrene copolymer resin, or polystyrene blend resin, acrylic resin, polystyrene resin, polyamide resin that has an affinity for these resins It is good to use. Further, when the material is a polypropylene resin, a chlorinated polyolefin resin, a chlorinated ethylene-vinyl acetate copolymer resin, a cyclized rubber, a coumarone indene resin, or the like may be used. Examples of the method for forming the adhesive layer include a coating method such as a gravure coating method, a roll coating method and a comma coating method, a printing method such as a gravure printing method and a screen printing method. Alternatively, an adhesive sheet made of the above material can be bonded by a laminating method or the like to form an adhesive layer.
また、必要に応じてオーバーコート層を形成してもよい。オーバーコート層は、加飾層2を保護するための層である。オーバーコート層としては、熱硬化性樹脂、紫外線硬化性樹脂、電子線硬化性樹脂などを用いるとよい。 Moreover, you may form an overcoat layer as needed. The overcoat layer is a layer for protecting the decorative layer 2. As the overcoat layer, a thermosetting resin, an ultraviolet curable resin, an electron beam curable resin, or the like may be used.
加飾シート21の構成は、上記した態様に限定されるものではなく、たとえば、加飾層2の材質として成形樹脂との接着性に優れたものを用いる場合には、接着層を省略することができる。また、加飾層2に隠蔽が必要な場合は、隠蔽層を形成してもよい。隠蔽層は、酸化チタン等の顔料を含有した層や、膜厚0.01×10−3mm以上の金属蒸着層などで構成するとよい。 The configuration of the decorative sheet 21 is not limited to the above-described embodiment. For example, when a material having excellent adhesiveness with a molding resin is used as the material of the decorative layer 2, the adhesive layer is omitted. Can do. Moreover, when the decoration layer 2 needs to be concealed, a concealment layer may be formed. The concealing layer is preferably composed of a layer containing a pigment such as titanium oxide or a metal vapor deposition layer having a thickness of 0.01 × 10 −3 mm or more.
(成形された加飾シートの製造方法について)この発明の成形された加飾シートの製造方法は、例えば、上記した樹脂成形品用真空成形金型9および加飾シート21を用いて金型面にクランプ材3で押付けて平面状の加飾シート21を立体形状に成形加工することよりなる(図2、図5参照)。 (About the manufacturing method of the molded decorative sheet) The manufacturing method of the molded decorative sheet according to the present invention is, for example, a mold surface using the vacuum molding die 9 for resin molded products and the decorative sheet 21 described above. The flat decorative sheet 21 is formed into a three-dimensional shape by pressing with a clamp member 3 (see FIGS. 2 and 5).
なお、金型面にクランプ材3で加飾シート21を押付けて加工する成形方法であれば、たとえば圧空成形(超高圧成形含む)、ブロー成形、ハイドロフォーミングなどを適用することが可能である。 In addition, if it is a shaping | molding method which presses and processes the decorating sheet | seat 21 with the clamp material 3 to a metal mold | die surface, it is possible to apply pressure forming (including ultra-high pressure forming), blow molding, hydroforming, etc., for example.
また、この発明の成形された加飾シートの製造方法は、例えば、上記説明した樹脂成形品用射出成形金型10を用いて、雄型4と雌型5との間に加飾シート21を挟み込んだ状態で平面状の加飾シート21を立体形状に成形加工することよりなる(図6参照)。 Moreover, the manufacturing method of the decorative sheet | seat shape | molded of this invention is using the injection mold 10 for resin molded products demonstrated above, for example, and decorating the decorative sheet 21 between the male mold | type 4 and the female mold | type 5. The flat decorative sheet 21 is formed into a three-dimensional shape while being sandwiched (see FIG. 6).
なお、金型に雄型4と雌型5との間に加飾シート21を挟み込んで成形加工する方法であれば、たとえば圧縮成形やプレス成形などを適用することが可能である。前記樹脂成形品用真空成形金型9と樹脂成形用射出成形金型とを組合せたものを用いることも可能である。 For example, compression molding or press molding can be applied as long as the decorative sheet 21 is sandwiched between the male mold 4 and the female mold 5 and molded. It is also possible to use a combination of the vacuum mold 9 for resin molded products and an injection mold for resin molding.
(加飾シート付き成形品の製造方法)前記樹脂成形品用射出成形金型10を用いて、雄型4と雌型5との間に前記加飾シートを挟み込み、キャビティ内に溶融樹脂を射出し、固化させることにより、平面形状の加飾シート21を立体形状に成形加工するとともに加飾シート21と樹脂成形品とを一体化させる。 (Manufacturing method of a molded product with a decorative sheet) Using the injection mold 10 for a resin molded product, the decorative sheet is sandwiched between a male mold 4 and a female mold 5 and molten resin is injected into the cavity. Then, by solidifying, the planar decorative sheet 21 is molded into a three-dimensional shape and the decorative sheet 21 and the resin molded product are integrated.
加飾シート21を成形加工するには、雌型5と加飾シート21との間を真空吸引して行なうとよい。溶融樹脂としては、ポリスチレン系樹脂、ポリオレフィン系樹脂、ABS樹脂、AS樹脂、AN樹脂などの汎用樹脂を挙げることができる。 In order to mold the decorative sheet 21, it is preferable to perform vacuum suction between the female mold 5 and the decorative sheet 21. Examples of the molten resin include general-purpose resins such as polystyrene resin, polyolefin resin, ABS resin, AS resin, and AN resin.
図1、図2に示すような断面コの字形状の凹部を有する雌型、その雌型の凹部に合致する凸部を有する雄型からなるプレス成形用金型の雌型の凹部の外周(平均表面粗さRa=55×10−3mm(55μm))を、研磨により、平均表面粗さRaが1×10−3mm(1μm)になるよう加工した。 The outer periphery of the concave portion of the female die of a press mold comprising a female die having a U-shaped concave portion as shown in FIGS. 1 and 2 and a male die having a convex portion matching the concave portion of the female die ( The average surface roughness Ra = 55 × 10 −3 mm (55 μm)) was processed by polishing so that the average surface roughness Ra was 1 × 10 −3 mm (1 μm).
次に、厚さ2mmの樹脂シートを基体シートとし、その上にウレタン系インキを使用しグラビア印刷によって木目柄の加飾層を形成した。さらに、この上にオーバーコート層として透明のウレタン系樹脂とイソシアネート系樹脂とからなる層が形成された建材用の加飾シートを作成した。 Next, a resin sheet having a thickness of 2 mm was used as a base sheet, and a decorative layer having a wood grain pattern was formed thereon by gravure printing using urethane ink. Furthermore, the decorative sheet for building materials in which the layer which consists of transparent urethane-type resin and isocyanate resin was formed as an overcoat layer on this was created.
この建材用の加飾シートを、前記プレス成形用金型に載置しプレス成形加工したところ、金型面から加飾シートを引き離す際に凝集破壊片が雌型に残留したり、加飾シートに欠損が生じたりすることはなかった。研磨する前の上記プレス成形金型では、雌型の凹部内面の角部と凹部の外周に、オーバーコート層の凝集破壊片の一部がプレス成形用金型に付着していた。 When this decorative sheet for building materials is placed on the press mold and subjected to press molding processing, cohesive fracture pieces remain on the female mold when the decorative sheet is pulled away from the mold surface, or the decorative sheet There was no defect in the case. In the press mold before polishing, some of the cohesive fracture pieces of the overcoat layer were attached to the press mold on the corners of the inner surface of the recess of the female mold and the outer periphery of the recess.
このように成形された加飾シートは、オーバーコート層側ではなく基体シート側に溶融樹脂を接触させて一体化する。 The decorative sheet thus formed is integrated by bringing the molten resin into contact with the base sheet side, not the overcoat layer side.
上記、プレス成形用金型の研磨する前の金型面および研磨した後の金型面のそれぞれと、上記建材用の加飾シートのオーバーコート層の間の動摩擦係数を測定したところ前者が2.9、後者が0.6であった。 When the dynamic friction coefficient between the mold surface before polishing of the press mold and the mold surface after polishing and the overcoat layer of the decorative sheet for building material was measured, the former was 2 .9, the latter being 0.6.
図4、図5に示すような箱形状の凹部をもつ樹脂成形品用真空成形金型の凹部の外周(Ra=65×10−3mm)を研削加工により、金型面の平均表面粗さRaが10×10−3mmになるように加工した。 The average surface roughness of the mold surface is obtained by grinding the outer periphery (Ra = 65 × 10 −3 mm) of the recess of the vacuum molding die for resin molded products having a box-shaped recess as shown in FIGS. It processed so that Ra might be 10x10 <-3> mm.
次に、無色透明のアクリル樹脂フィルムを基体シートとしビニル系インキを印刷して加飾層を形成し、次いでその上に着色軟質塩化ビニル樹脂フィルムを貼り合せ加飾シートを作成した。着色軟質塩化ビニル樹脂フィルムは、剛性の付与とフィルムの割れ防止の機能を持たせるために形成した。 Next, using a colorless and transparent acrylic resin film as a base sheet, a vinyl-based ink was printed to form a decorative layer, and then a colored soft vinyl chloride resin film was bonded thereon to create a decorative sheet. The colored soft vinyl chloride resin film was formed in order to impart rigidity and prevent the film from cracking.
この加飾シートを、上記樹脂成形品用真空成形金型に載置し、金型面にクランプ材で押し付けて保持した状態で真空成形加工したところ、金型面から加飾シートを引き離す際に凝集破壊片が雌型に残留したり、加飾シートに欠損が生じたりすることはなかった。切削加工する前の上記樹脂成形品用真空成形金型では、着色軟質塩化ビニル樹脂フィルムの可塑剤と思われる溶出物が付着していた。 When this decorative sheet is placed on the above vacuum molded mold for resin molded products and vacuum molded while being pressed against the mold surface with a clamp material, the decorative sheet is pulled away from the mold surface. The cohesive fracture pieces did not remain in the female mold and the decorative sheet was not damaged. In the vacuum molding die for a resin molded product before cutting, an eluate that seems to be a plasticizer for a colored soft vinyl chloride resin film was adhered.
上記、樹脂成形品用真空成形金型の研削加工する前の金型面および研削加工後の金型面のそれぞれと、上記加飾シートの着色軟化塩化ビニル樹脂フィルムとの間の動摩擦係数を測定したところ前者が3.3、後者が1.5であった。 Measure the coefficient of dynamic friction between the mold surface before grinding of the vacuum mold for resin molded products and the mold surface after grinding, and the colored softened vinyl chloride resin film of the decorative sheet. As a result, the former was 3.3 and the latter was 1.5.
図6に示すような凹部形状をもつ樹脂成形品用射出成形金型の凹部全面(Ra=50×10−3mm)を放電加工して平均表面粗さRaが0.2×10−3mmになるように加工した。 The entire surface of the recess (Ra = 50 × 10 −3 mm) of the injection mold for resin molded products having the recess shape as shown in FIG. 6 is subjected to electric discharge machining, and the average surface roughness Ra is 0.2 × 10 −3 mm. It was processed to become.
次に、ポリエステル樹脂フィルムを基体シートとし、アクリル系インキを使用して絵柄層を形成し、さらに、この上にビニル樹脂系インキを使用して接着層を形成し、木目模様の転写箔を作成した。 Next, a polyester resin film is used as a base sheet, an acrylic ink is used to form a picture layer, and a vinyl resin ink is used to form an adhesive layer thereon to create a woodgrain pattern transfer foil. did.
この転写箔を、上記樹脂成形品用射出成形金型の雄型と雌型との間に載置し、型締めし、射出成形加工したところ、金型面から転写箔を引き離す際に凝集破壊片が雌型に残留したり、加飾シートに欠損が生じたりすることはなかった。放電加工する前の上記樹脂成形品用射出成形金型では、成形後、雄型表面に転写箔の絵柄層、接着層の一部が付着していた。 This transfer foil was placed between the male mold and female mold of the above injection mold for resin molded products, clamped, and injection molded. When the transfer foil was pulled away from the mold surface, cohesive failure occurred. The piece did not remain in the female mold and the decorative sheet was not damaged. In the above injection molding die for resin molded products before electric discharge machining, a part of the pattern layer and the adhesive layer of the transfer foil adhered to the male mold surface after molding.
上記、樹脂成形品用射出成形金型の放電加工する前の金型面および放電加工後の金型面のそれぞれと、上記転写箔の接着層の間の動摩擦係数を測定したところ前者が2.8、後者が0.4であった When the dynamic friction coefficient between each of the mold surface before the electric discharge machining of the injection mold for resin molded products and the mold surface after the electric discharge machining and the adhesive layer of the transfer foil was measured, the former was 2. 8. The latter was 0.4
この発明は、加飾シート成形用金型に関するものであり産業上有用なものである。 This invention relates to a decorative sheet-forming mold and is industrially useful.
1 基体シート
2 加飾層
3 クランプ材
4 雄型
5 雌型
6 凹部
7 凸部
8 プレス成形用金型
9 樹脂成形品用真空成形金型
10 樹脂成形品用射出成形金型
11 樹脂射出口
12 プラスチック板
13 両面テープ
14 インキ層
15 導線
16 分銅
17 滑車
18 引張試験機
19 引張りチャック
20 記録用パソコン
21 加飾シート
22 真空吸引孔
23 ガード
24 引張り駆動体
DESCRIPTION OF SYMBOLS 1 Base sheet 2 Decorating layer 3 Clamping material 4 Male mold 5 Female mold 6 Concave part 7 Convex part 8 Press molding die 9 Vacuum molding die for resin molded products 10 Injection molding die for resin molded products 11 Resin injection port 12 Plastic plate 13 Double-sided tape 14 Ink layer 15
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JP2004339462A JP2005119315A (en) | 2004-11-24 | 2004-11-24 | Mold for molding decoration sheet |
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JP2001041030A Division JP3652611B2 (en) | 2001-02-16 | 2001-02-16 | Method for producing molded decorative sheet and method for producing molded product with decorative sheet |
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JPH0259307A (en) * | 1988-08-24 | 1990-02-28 | Nissha Printing Co Ltd | Mold for in-mold molding |
JPH03258522A (en) * | 1990-03-07 | 1991-11-18 | Dunlop Ltd | Fabric clamp device for mold use |
JPH05104621A (en) * | 1991-10-15 | 1993-04-27 | Mitsubishi Plastics Ind Ltd | Polyester sheet for thermoforming |
JPH08156023A (en) * | 1994-12-09 | 1996-06-18 | Idemitsu Petrochem Co Ltd | Forming of laminated molding and its die |
JPH08155966A (en) * | 1994-11-29 | 1996-06-18 | Shin Etsu Polymer Co Ltd | Production of mold |
JPH08267498A (en) * | 1995-03-30 | 1996-10-15 | Toyoda Gosei Co Ltd | Method and apparatus for shaping sheet for skin |
JPH10128789A (en) * | 1996-10-30 | 1998-05-19 | Dainippon Printing Co Ltd | Decorative sheet and decorative molded piece, and method for decoration while molding |
JPH1134068A (en) * | 1997-07-23 | 1999-02-09 | Mitsubishi Eng Plast Kk | Nesting, mold assembly and method of manufacturing molded article |
JPH11226990A (en) * | 1998-02-10 | 1999-08-24 | Ube Ind Ltd | Skin integral lamination molding method |
JP2000299335A (en) * | 1998-07-10 | 2000-10-24 | Apic Yamada Corp | Manufacture of semiconductor device and resin-sealing apparatus |
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2004
- 2004-11-24 JP JP2004339462A patent/JP2005119315A/en active Pending
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH0259307A (en) * | 1988-08-24 | 1990-02-28 | Nissha Printing Co Ltd | Mold for in-mold molding |
JPH03258522A (en) * | 1990-03-07 | 1991-11-18 | Dunlop Ltd | Fabric clamp device for mold use |
JPH05104621A (en) * | 1991-10-15 | 1993-04-27 | Mitsubishi Plastics Ind Ltd | Polyester sheet for thermoforming |
JPH08155966A (en) * | 1994-11-29 | 1996-06-18 | Shin Etsu Polymer Co Ltd | Production of mold |
JPH08156023A (en) * | 1994-12-09 | 1996-06-18 | Idemitsu Petrochem Co Ltd | Forming of laminated molding and its die |
JPH08267498A (en) * | 1995-03-30 | 1996-10-15 | Toyoda Gosei Co Ltd | Method and apparatus for shaping sheet for skin |
JPH10128789A (en) * | 1996-10-30 | 1998-05-19 | Dainippon Printing Co Ltd | Decorative sheet and decorative molded piece, and method for decoration while molding |
JPH1134068A (en) * | 1997-07-23 | 1999-02-09 | Mitsubishi Eng Plast Kk | Nesting, mold assembly and method of manufacturing molded article |
JPH11226990A (en) * | 1998-02-10 | 1999-08-24 | Ube Ind Ltd | Skin integral lamination molding method |
JP2000299335A (en) * | 1998-07-10 | 2000-10-24 | Apic Yamada Corp | Manufacture of semiconductor device and resin-sealing apparatus |
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