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JP2005082417A - Glass melting furnace - Google Patents

Glass melting furnace Download PDF

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Publication number
JP2005082417A
JP2005082417A JP2003313573A JP2003313573A JP2005082417A JP 2005082417 A JP2005082417 A JP 2005082417A JP 2003313573 A JP2003313573 A JP 2003313573A JP 2003313573 A JP2003313573 A JP 2003313573A JP 2005082417 A JP2005082417 A JP 2005082417A
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glass
melting furnace
brick
electrode
furnace
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Keizo Kojima
慶造 児嶋
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IHI Corp
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Ishikawajima Harima Heavy Industries Co Ltd
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Priority to JP2003313573A priority Critical patent/JP2005082417A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/20Bridges, shoes, throats, or other devices for withholding dirt, foam, or batch
    • C03B5/207Foraminous or mesh screens, e.g. submerged sieves
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/02Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in electric furnaces, e.g. by dielectric heating
    • C03B5/027Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in electric furnaces, e.g. by dielectric heating by passing an electric current between electrodes immersed in the glass bath, i.e. by direct resistance heating
    • C03B5/0275Shaft furnaces
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/26Outlets, e.g. drains, siphons; Overflows, e.g. for supplying the float tank, tweels

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Glass Melting And Manufacturing (AREA)

Abstract

【課題】ガラス溶融炉の炉底部におけるレンガ屑止め下側のガラスを効果的に加熱溶融できるようにする。
【解決手段】耐火レンガ2a製の溶融炉本体2内壁の上下方向中間部に対向配置して相互間での通電により溶融炉本体2内の原料ガラスを加熱溶融する主電極3と、炉底部4のガラス取出口9外周に配置して主電極3との間での通電により炉底部4のガラスを加熱溶融する底部電極5と、炉底部4における底部電極5の上部に配置したレンガ屑止め13とを有するガラス溶融炉において、底部電極5周りの耐火レンガ2a内に高周波加熱コイル14を埋め込んで設けた。
【選択図】図1
An object of the present invention is to make it possible to effectively heat and melt glass under a brick scrap stopper at the bottom of a glass melting furnace.
SOLUTION: A main electrode 3 which is disposed opposite to an intermediate portion in the vertical direction of an inner wall of a melting furnace main body 2 made of refractory bricks 2a and heats and melts the raw glass in the melting furnace main body 2 by energization between them, and a furnace bottom 4 The bottom electrode 5 which is disposed on the outer periphery of the glass outlet 9 and which heats and melts the glass of the furnace bottom 4 by energization with the main electrode 3, and the brick dust stopper 13 which is disposed above the bottom electrode 5 in the furnace bottom 4 The high frequency heating coil 14 was embedded in the refractory brick 2a around the bottom electrode 5 and provided.
[Selection] Figure 1

Description

本発明は、高放射性廃液ガラス固化施設に設置されるガラス溶融炉に関する。   The present invention relates to a glass melting furnace installed in a highly radioactive waste liquid vitrification facility.

原子力施設において発生する高放射性廃液は、高放射性廃液ガラス固化施設のガラス溶融炉により溶融し、ガラス固化体として処理された後、放射性廃棄物保管施設に保管される。   The high radioactive waste liquid generated in the nuclear facility is melted by the glass melting furnace of the high radioactive waste liquid glass solidification facility, treated as a glass solid, and then stored in the radioactive waste storage facility.

上記のガラス固化施設においては、ガラス溶融炉の内部で原料ガラスを溶融する際に高放射性廃液を混入し、この高放射性廃液が混入した溶融ガラスを固化容器に注入し、溶融ガラスを固化させることにより、ガラス固化体を形成している。   In the above-mentioned glass solidification facility, when the raw glass is melted inside the glass melting furnace, the high radioactive waste liquid is mixed, and the molten glass mixed with this high radioactive waste liquid is injected into the solidification container to solidify the molten glass. Thus, a vitrified body is formed.

図2は従来のガラス溶融炉の一例を示す縦断正面図、図3は図2のIII−III方向断面図であり、図2、図3において、2は溶融炉本体であり、該溶融炉本体2は、内部に溶融空間1を形成するように耐蝕性の耐火レンガ2aにより構成されている。   FIG. 2 is a longitudinal front view showing an example of a conventional glass melting furnace, FIG. 3 is a sectional view in the III-III direction of FIG. 2, and in FIGS. 2 and 3, 2 is a melting furnace body, and the melting furnace body 2 is comprised by the corrosion-resistant firebrick 2a so that the fusion | melting space 1 may be formed inside.

溶融炉本体2の上下中間部左右側には、主電極3が対向して設けられていてその内端が溶融空間1に突出しており、又溶融空間1下部の狭くなっている炉底部4には、底部電極5が設けられていてその内端(上端)が溶融空間1に突出している。図2において、6は溶融炉本体2の上部に設けられて原料ガラス、高放射性廃液等を供給するための原料供給口、7は廃ガス取出管、8は廃ガス処理装置、9は溶融したガラスを下部に取り出すためのガラス取出口、10はガラス取出口9を加熱するための高周波コイル、Gは溶融ガラスである。   On the left and right sides of the upper and lower middle part of the melting furnace body 2, a main electrode 3 is provided to face the inner end of the melting furnace body 2, and its inner end protrudes into the melting space 1. The bottom electrode 5 is provided, and the inner end (upper end) projects into the melting space 1. In FIG. 2, 6 is a raw material supply port for supplying raw glass, high radioactive waste liquid, etc. provided at the upper part of the melting furnace body 2, 7 is a waste gas take-out pipe, 8 is a waste gas treatment device, and 9 is molten. A glass outlet for taking out the glass downward, 10 is a high-frequency coil for heating the glass outlet 9, and G is molten glass.

前記ガラス溶融炉においては、溶融空間1を形成している耐火レンガ2aが破損して炉底部4に落下することが考えられる。このようにレンガが落下すると、落下したレンガがガラス取出口9を塞ぐことがあり、この場合にはガラス溶融炉の運転が不能になってしまうという問題がある。そして、このようにレンガが落下してガラス取出口9を閉塞する事態が発生した場合に、ガラス溶融炉は高放射性を有しているために、作業者が近付くことはできず、従ってマニプレータ等を用いて復旧する必要があリ、この復旧作業に多大の時間が掛かるという問題がある。   In the glass melting furnace, it is conceivable that the refractory brick 2a forming the melting space 1 is damaged and falls to the furnace bottom 4. When the brick falls in this way, the dropped brick may block the glass outlet 9, and in this case, there is a problem that the operation of the glass melting furnace becomes impossible. And when the situation where the brick falls and closes the glass outlet 9 in this way occurs, the glass melting furnace has high radiation, so the operator cannot approach, so a manipulator or the like There is a problem that it takes a long time to perform the recovery work.

このような問題を解決するために、近年では、前記底部電極5の内側上部位置に、図2、図3に示すように、ガラス取出口9の上部に位置するリング材11と、該リング材11を底部電極5に固定するフレーム材12とからなるレンガ屑止め13を設けることが実施されている。このレンガ屑止め13は、前記底部電極5と同等の導電材料で構成して底部電極5に一体に固定している。レンガ屑止め13には種々の形状のものが考えられており、図示の場合でもリング材11の開口の大きさ、放射状に設けられるフレーム材12の間隔などが種々選定して用いられる。   In order to solve such a problem, in recent years, a ring member 11 positioned at the upper part of the glass outlet 9 as shown in FIGS. It is practiced to provide a brick waste stopper 13 composed of a frame material 12 that fixes 11 to the bottom electrode 5. The brick scraper 13 is made of a conductive material equivalent to the bottom electrode 5 and is fixed to the bottom electrode 5 integrally. Various types of brick scrapers 13 are conceivable. Even in the illustrated case, the size of the opening of the ring member 11 and the interval between the frame members 12 provided in a radial manner are selected and used.

図2の原料供給口6から高放射性廃液と共に溶融炉本体2内に供給された原料ガラスは、対向配置されている主電極3,3間での通電(放電)によりジュール熱によって溶融される。   The raw material glass supplied into the melting furnace main body 2 together with the high radioactive waste liquid from the raw material supply port 6 in FIG. 2 is melted by Joule heat by energization (discharge) between the main electrodes 3 and 3 arranged opposite to each other.

一方、溶融されたガラスをガラス取出口9から下部に流下させる際には、主電極3と底部電極5との間に通電(放電)して炉底部4のガラスをジュール熱により所定の温度以上に加熱すると共に、高周波コイル10によりガラス取出口9を加熱することにより、ガラスを流動化させて流下させるようにしている。   On the other hand, when the molten glass is caused to flow downward from the glass outlet 9, the main electrode 3 and the bottom electrode 5 are energized (discharged), and the glass at the furnace bottom 4 is heated to a predetermined temperature or more by Joule heat. In addition, the glass outlet 9 is heated by the high-frequency coil 10 to fluidize and flow down the glass.

尚、公知の一般的なガラス溶融炉としては例えば特許文献1に示したものがある。
特開2002−328197公報
In addition, as a well-known general glass melting furnace, there exists what was shown, for example in patent document 1. FIG.
JP 2002-328197 A

しかし、図2に示した如く、主電極3と底部電極5との間に通電して、炉底部4のガラスの温度を高めて流動化させてガラス取出口9から流下させる際に、主電極3の電流が、主電極3との距離が短くなっていて流れ易いレンガ屑止め13に流れてしまうことになる。このために、レンガ屑止め13よりも下側Aにおけるガラスにはジュール熱が付与され難くなり、また下側A部への高周波コイル10による加熱の寄与も小さいことから、ガラス取出口9直上のガラスが加熱されないために有効に流動化されず、ガラス取出口9への流下に支障をきたす恐れがあった。   However, as shown in FIG. 2, when the main electrode 3 and the bottom electrode 5 are energized to increase the temperature of the glass in the furnace bottom 4 to fluidize and flow down from the glass outlet 9, 3 flows to the brick debris stopper 13 that is easy to flow because the distance to the main electrode 3 is short. For this reason, it becomes difficult for Joule heat to be imparted to the glass on the lower side A than the brick debris stopper 13 and the contribution of heating by the high-frequency coil 10 to the lower side A part is small. Since the glass was not heated, it was not fluidized effectively, and there was a risk of hindering the flow down to the glass outlet 9.

本発明は、このような問題を解決し、ガラス溶融炉の炉底部におけるレンガ屑止め下側のガラスを効果的に加熱溶融できるようにしたガラス溶融炉を提供することを目的としている。   An object of the present invention is to provide a glass melting furnace that solves such problems and that can effectively heat and melt the glass below the brick scrap stop at the bottom of the glass melting furnace.

本発明は、耐火レンガ製の溶融炉本体内壁の上下方向中間部に対向配置して相互間での通電により溶融炉本体内の原料ガラスを加熱溶融する主電極と、炉底部のガラス取出口外周に配置して前記主電極との間での通電により炉底部のガラスを加熱溶融する底部電極と、底部電極のガラス取出口上部に配置したレンガ屑止めとを有するガラス溶融炉において、底部電極周りの耐火レンガ内に高周波加熱コイルを埋め込んで設けたことを特徴とするガラス溶融炉、に係るものである。   The present invention comprises a main electrode that is disposed opposite to an intermediate part in the vertical direction of the inner wall of a melting furnace main body made of refractory bricks, and heats and melts the raw glass in the main body of the melting furnace by energization between each other, and a glass outlet outer periphery of the furnace bottom In a glass melting furnace having a bottom electrode that heats and melts the glass at the bottom of the furnace by energization with the main electrode and a brick scrap stopper disposed above the glass outlet of the bottom electrode, The present invention relates to a glass melting furnace characterized in that a high-frequency heating coil is embedded in a refractory brick.

本発明では、底部電極周りの耐火レンガ内に埋め込まれた高周波加熱コイルにより底部電極を加熱する。従って、レンガ屑止め下側の溶融され難いガラスを効果的に加熱溶融して、ガラス取出口から確実に流下させることができる。   In the present invention, the bottom electrode is heated by a high frequency heating coil embedded in a refractory brick around the bottom electrode. Therefore, it is possible to effectively heat and melt the glass that is difficult to be melted on the lower side of the brick scrap stopper and to flow down reliably from the glass outlet.

本発明によれば、底部電極周りの耐火レンガ内に埋め込まれた高周波加熱コイルにより底部電極を加熱し、底部電極を介してレンガ屑止め下側のガラスを加熱するようにしたので、レンガ屑止め下側のガラスを確実に溶融させることができ、よってガラス取出口からの溶融ガラスの流下を確実に行える効果がある。   According to the present invention, the bottom electrode is heated by the high-frequency heating coil embedded in the refractory brick around the bottom electrode, and the glass on the bottom side of the brick scrap stopper is heated via the bottom electrode. The lower glass can be reliably melted, and therefore there is an effect that the molten glass can surely flow down from the glass outlet.

以下、本発明の実施の形態を図面に従って説明する。   Hereinafter, embodiments of the present invention will be described with reference to the drawings.

図1は本発明の実施の形態に係るガラス溶融炉の縦断正面図であり、図中、図2、図3と同一の構成部材には同一の符号を付して説明を省略し、本発明の特徴部分についてのみ詳述する。   FIG. 1 is a longitudinal front view of a glass melting furnace according to an embodiment of the present invention. In the figure, the same components as those in FIGS. Only the characteristic part will be described in detail.

図1に示すように、溶融炉本体2の炉底部に設けられる底部電極5の内側にレンガ屑止め13が一体に取付けられているガラス溶融炉において、底部電極5の周りの耐火レンガ2a内に、高周波加熱コイル14を埋め込んで設ける。図中15は、前記高周波加熱コイル14に接続した高周波電源装置である。   As shown in FIG. 1, in a glass melting furnace in which a brick debris stopper 13 is integrally attached to the inside of a bottom electrode 5 provided at the bottom of the melting furnace body 2, the inside of the refractory brick 2 a around the bottom electrode 5. The high frequency heating coil 14 is embedded and provided. In the figure, reference numeral 15 denotes a high frequency power supply device connected to the high frequency heating coil 14.

次に、上記形態例の動作を説明する。   Next, the operation of the above embodiment will be described.

原料供給口6からは原料ガラス及び放射性廃液が溶融空間1内に供給される。ここで通常時は、対向配置されている主電極3,3間での通電によるジュール熱によって原料ガラスは溶融し、溶融ガラスGとなる。   From the raw material supply port 6, raw material glass and radioactive waste liquid are supplied into the melting space 1. Here, at the normal time, the raw glass is melted by the Joule heat generated by energization between the main electrodes 3 and 3 arranged opposite to each other, and becomes a molten glass G.

また溶融ガラスGの取り出し時には、溶融ガラスGの流下をスムーズに行うために、さらに主電極3と底部電極5との間でも通電してジュール熱を発生させ、また高周波コイル10によりガラス取出口9を加熱する。   Further, at the time of taking out the molten glass G, in order to smoothly flow down the molten glass G, current is further applied between the main electrode 3 and the bottom electrode 5 to generate Joule heat. Heat.

しかし前述したように、底部電極5の内側上部には、導電性のレンガ屑止め13が一体に固定されているために、主電極3の電流が、主電極3に近いために流れ易くなっているレンガ屑止め13に流れてしまうことになり、このためにレンガ屑止め13の下側Aのガラスが溶融し切れない場合がある。   However, as described above, the conductive brick debris stopper 13 is integrally fixed to the inner upper portion of the bottom electrode 5, so that the current of the main electrode 3 is close to the main electrode 3, so that it easily flows. Therefore, the glass on the lower side A of the brick scraper 13 may not be melted completely.

そこで本発明では、底部電極5周りの耐火レンガ2a内に設置した高周波加熱コイル14に通電することにより、底部電極5を加熱する。   Therefore, in the present invention, the bottom electrode 5 is heated by energizing the high-frequency heating coil 14 installed in the refractory brick 2a around the bottom electrode 5.

すると、底部電極5の加熱により、底部電極5を介してレンガ屑止め13の下側Aのガラスが加熱されることになり、よってレンガ屑止め13の下側Aのガラスが確実に溶融されるようになり、この結果、ガラス取出口9からの溶融ガラスGの流下を確実に行えるようになる。   Then, by heating the bottom electrode 5, the glass on the lower side A of the brick scraper 13 is heated via the bottom electrode 5, so that the glass on the lower side A of the brick scraper 13 is reliably melted. As a result, the molten glass G can surely flow down from the glass outlet 9.

本発明の実施の形態に係るガラス溶融炉の縦断正面図である。It is a vertical front view of the glass melting furnace which concerns on embodiment of this invention. 従来のガラス溶融炉の一例を示す縦断正面図である。It is a vertical front view which shows an example of the conventional glass melting furnace. 図2のIII−III方向断面図である。It is the III-III direction sectional view of FIG.

符号の説明Explanation of symbols

1 溶融空間
2 溶融炉本体
2a 耐火レンガ
3 主電極
4 炉底部
5 底部電極
13 レンガ屑止め
14 高周波加熱コイル
DESCRIPTION OF SYMBOLS 1 Melting space 2 Melting furnace main body 2a Refractory brick 3 Main electrode 4 Furnace bottom part 5 Bottom electrode 13 Brick scrap prevention 14 High frequency heating coil

Claims (1)

耐火レンガ製の溶融炉本体内壁の上下方向中間部に対向配置して相互間での通電により溶融炉本体内の原料ガラスを加熱溶融する主電極と、炉底部のガラス取出口外周に配置して前記主電極との間での通電により炉底部のガラスを加熱溶融する底部電極と、底部電極のガラス取出口上部に配置したレンガ屑止めとを有するガラス溶融炉において、底部電極周りの耐火レンガ内に高周波加熱コイルを埋め込んで設けたことを特徴とするガラス溶融炉。   A main electrode that heats and melts the raw glass in the main body of the melting furnace by energizing each other and placed on the outer periphery of the glass outlet at the bottom of the furnace. In a glass melting furnace having a bottom electrode that heats and melts glass at the bottom of the furnace by energization with the main electrode, and a brick scrap stopper disposed above the glass outlet of the bottom electrode, in the refractory brick around the bottom electrode A glass melting furnace characterized in that a high-frequency heating coil is embedded in the glass melting furnace.
JP2003313573A 2003-09-05 2003-09-05 Glass melting furnace Pending JP2005082417A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113480141A (en) * 2021-06-30 2021-10-08 陕西彩虹工业智能科技有限公司 Kiln equipment and method for manufacturing flexible screen substrate glass
CN113511800A (en) * 2021-07-28 2021-10-19 清远南玻节能新材料有限公司 Anti-glass leakage device and glass melting furnace

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113480141A (en) * 2021-06-30 2021-10-08 陕西彩虹工业智能科技有限公司 Kiln equipment and method for manufacturing flexible screen substrate glass
CN113511800A (en) * 2021-07-28 2021-10-19 清远南玻节能新材料有限公司 Anti-glass leakage device and glass melting furnace

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