JP2005073588A - Saponin containing oral product and method for reducing unpleasant taste of saponin - Google Patents
Saponin containing oral product and method for reducing unpleasant taste of saponin Download PDFInfo
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- JP2005073588A JP2005073588A JP2003308323A JP2003308323A JP2005073588A JP 2005073588 A JP2005073588 A JP 2005073588A JP 2003308323 A JP2003308323 A JP 2003308323A JP 2003308323 A JP2003308323 A JP 2003308323A JP 2005073588 A JP2005073588 A JP 2005073588A
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- saponin
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- erythritol
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- 229930182490 saponin Natural products 0.000 title claims abstract description 74
- 150000007949 saponins Chemical class 0.000 title claims abstract description 74
- 239000001397 quillaja saponaria molina bark Substances 0.000 title claims abstract description 62
- 235000019640 taste Nutrition 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 title claims abstract description 19
- 239000013588 oral product Substances 0.000 title claims abstract description 13
- 229940023486 oral product Drugs 0.000 title claims abstract description 10
- 230000001603 reducing effect Effects 0.000 title claims description 13
- 239000004386 Erythritol Substances 0.000 claims abstract description 20
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 claims abstract description 20
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 claims abstract description 20
- 235000019414 erythritol Nutrition 0.000 claims abstract description 20
- 229940009714 erythritol Drugs 0.000 claims abstract description 20
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 claims abstract description 19
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims abstract description 19
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- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 claims abstract description 18
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- 239000008103 glucose Substances 0.000 claims abstract description 17
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 6
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 5
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- 241000196324 Embryophyta Species 0.000 description 3
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- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 3
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- 239000000845 maltitol Substances 0.000 description 3
- 235000010449 maltitol Nutrition 0.000 description 3
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 3
- 229940035436 maltitol Drugs 0.000 description 3
- -1 organic acid salts Chemical class 0.000 description 3
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- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
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- 235000013361 beverage Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 2
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- 230000006872 improvement Effects 0.000 description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- HELXLJCILKEWJH-NCGAPWICSA-N rebaudioside A Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@]12C(=C)C[C@@]3(C1)CC[C@@H]1[C@@](C)(CCC[C@]1([C@@H]3CC2)C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HELXLJCILKEWJH-NCGAPWICSA-N 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 235000010356 sorbitol Nutrition 0.000 description 2
- 235000013322 soy milk Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000005846 sugar alcohols Chemical class 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- 239000000811 xylitol Substances 0.000 description 2
- 235000010447 xylitol Nutrition 0.000 description 2
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 2
- 229960002675 xylitol Drugs 0.000 description 2
- SERLAGPUMNYUCK-DCUALPFSSA-N 1-O-alpha-D-glucopyranosyl-D-mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O SERLAGPUMNYUCK-DCUALPFSSA-N 0.000 description 1
- 108010011485 Aspartame Proteins 0.000 description 1
- 241000258957 Asteroidea Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 239000004278 EU approved seasoning Substances 0.000 description 1
- 239000001653 FEMA 3120 Substances 0.000 description 1
- 240000004670 Glycyrrhiza echinata Species 0.000 description 1
- 235000001453 Glycyrrhiza echinata Nutrition 0.000 description 1
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 description 1
- 235000017382 Glycyrrhiza lepidota Nutrition 0.000 description 1
- 241000251511 Holothuroidea Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 235000017726 Panax vietnamensis Nutrition 0.000 description 1
- 241001527087 Panax vietnamensis Species 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 240000003889 Piper guineense Species 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 235000008184 Piper nigrum Nutrition 0.000 description 1
- 229930187719 Soyasaponin Natural products 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 235000004552 Yucca aloifolia Nutrition 0.000 description 1
- 244000116042 Yucca brevifolia Species 0.000 description 1
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- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- GZCGUPFRVQAUEE-VANKVMQKSA-N aldehydo-L-glucose Chemical compound OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)C=O GZCGUPFRVQAUEE-VANKVMQKSA-N 0.000 description 1
- 230000036436 anti-hiv Effects 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 239000000605 aspartame Substances 0.000 description 1
- 235000010357 aspartame Nutrition 0.000 description 1
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 description 1
- 229960003438 aspartame Drugs 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- OJGDCBLYJGHCIH-UHFFFAOYSA-N bromhexine Chemical compound C1CCCCC1N(C)CC1=CC(Br)=CC(Br)=C1N OJGDCBLYJGHCIH-UHFFFAOYSA-N 0.000 description 1
- 229960003870 bromhexine Drugs 0.000 description 1
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- 239000008370 chocolate flavor Substances 0.000 description 1
- 229960001380 cimetidine Drugs 0.000 description 1
- CCGSUNCLSOWKJO-UHFFFAOYSA-N cimetidine Chemical compound N#CNC(=N/C)\NCCSCC1=NC=N[C]1C CCGSUNCLSOWKJO-UHFFFAOYSA-N 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
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- 235000013325 dietary fiber Nutrition 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229960001596 famotidine Drugs 0.000 description 1
- XUFQPHANEAPEMJ-UHFFFAOYSA-N famotidine Chemical compound NC(N)=NC1=NC(CSCCC(N)=NS(N)(=O)=O)=CS1 XUFQPHANEAPEMJ-UHFFFAOYSA-N 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
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- 238000011835 investigation Methods 0.000 description 1
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- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 1
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- 239000005720 sucrose Substances 0.000 description 1
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- 239000000892 thaumatin Substances 0.000 description 1
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Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Medicines Containing Plant Substances (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- General Preparation And Processing Of Foods (AREA)
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
Abstract
Description
本発明は、サポニンの持つ特有の不快味を軽減させる方法およびサポニン含有経口製品に関する。 The present invention relates to a method for reducing the peculiar unpleasant taste of saponin and an oral product containing saponin.
サポニンは植物に分布する配糖体成分で、その生理作用としては、抗酸化作用をはじめ、抗HIV活性や脂質代謝改善作用、糖吸収抑制作用も報告されており、健康食品などにも利用されつつある。しかしながらサポニンは、特有の苦味、収斂味等の不快味を有しており、食品等経口製品への利用においては風味的に問題があり、飲食物に配合するとその飲食物本来の風味を著しく損なうか、風味の調和をとることが困難となり、広汎な利用が妨げられるという問題があった。 Saponin is a glycoside component distributed in plants, and its physiological effects include anti-oxidation, anti-HIV activity, lipid metabolism improvement, and sugar absorption suppression, and it is also used for health foods. It's getting on. However, saponins have unpleasant tastes such as peculiar bitterness and astringency, and have a problem in flavor when used in oral products such as foods. When they are added to foods and drinks, the original flavors of the foods and drinks are significantly impaired. However, there is a problem that it is difficult to harmonize the flavor, and widespread use is hindered.
サポニンの不快味を改良する方法としては、微生物による発酵処理(特許文献1)やサポニンとアミノ酸を併用させる方法(特許文献2)などが報告されているが、微生物処理に関しては、処理工程はサポニン素材調製時に行う必要があり、最終の食品を調製する際に使用できる方法ではない。また、後者のアミノ酸との併用法については、アミノ酸特有の風味が出てしまい風味改善方法としては汎用性のあるものとは言えないという欠点があった。 As methods for improving the unpleasant taste of saponin, fermentation treatment with microorganisms (Patent Document 1) and a method of using saponins and amino acids in combination (Patent Document 2) have been reported. This method needs to be performed at the time of preparing the material, and is not a method that can be used when preparing the final food. In addition, the combination method with the latter amino acid has a drawback that a flavor peculiar to an amino acid is produced and it cannot be said that the flavor improvement method is versatile.
また、一般的に苦味を有する物質に対しては、甘味を有する糖類や高甘味度甘味料を加え、甘味によって苦味を低減する方法が慣用されてはいる。例えば苦味物質にアスパルテーム単独又は還元麦芽糖を併用して添加する技術(特許文献3、4)、エリスリトールなどの糖アルコールとpH調整剤を併用してシメチジンやファモチジン等の薬物の不快味を低減する技術(特許文献5)、苦味を有するペプチドに有機酸塩類および糖類を添加する技術(特許文献6)、ブロムヘキシンに対してソーマチン及び糖アルコールを添加する技術(特許文献7)などが開示されている。しかしながらこれらの多くの技術は糖類に高甘味度甘味料や他の化合物を併用することが必須であり、糖類のみで苦味を低減することは困難であった。また化合物の種類によって舌に感ずる不快味の呈し方は様々であり、これらの苦味低減技術がすべてサポニンの不快味の低減に適用できるか不明である。また近年の天然志向のため消費者の中には高甘味度甘味料が使用されることに抵抗を感じる人もおり、これを使用せずとも糖類のみでも不快味を低減できれば、それらの消費者にアピールできるという利点も持つ。 In general, for substances having a bitter taste, a method of adding a saccharide having a sweet taste or a high-intensity sweetener and reducing the bitter taste by sweetness is commonly used. For example, aspartame alone or in combination with reduced maltose added to a bitter substance (Patent Documents 3 and 4), a technique for reducing the unpleasant taste of drugs such as cimetidine and famotidine using a sugar alcohol such as erythritol and a pH adjuster (Patent Document 5), a technique for adding organic acid salts and sugars to a peptide having a bitter taste (Patent Document 6), a technique for adding thaumatin and sugar alcohol to bromhexine (Patent Document 7), and the like are disclosed. However, in many of these techniques, it is essential to use a high-intensity sweetener and other compounds in combination with saccharides, and it has been difficult to reduce bitterness with only saccharides. Moreover, there are various ways of presenting an unpleasant taste perceived by the tongue depending on the type of compound, and it is unclear whether all these bitterness reducing techniques can be applied to the reduction of the unpleasant taste of saponins. In addition, some consumers feel resistance to the use of high-intensity sweeteners because of their natural orientation in recent years. It has the advantage that it can appeal to.
(参考文献)
本発明は、サポニンに特有の不快味を容易に軽減でき、幅広い製品に利用可能な汎用性にも優れた方法とサポニン特有の不快味を低減した製品の提供に関する。 The present invention relates to a method that can easily reduce the unpleasant taste peculiar to saponins and is excellent in versatility that can be used for a wide range of products, and a product that reduces unpleasant taste peculiar to saponins.
本発明者らは上記課題解決のため、サポニンが舌に接触したときの不快味の呈し方についてより深く解析した結果、サポニンには舌に最初に接触したときに直ちに感ずる苦味と、後々まで曳くような苦味や収斂味から構成される特有の不快味を呈する知見を得た。そしてサポニンの不快味を糖類によって良好に低減するためには1種類の糖類のみの使用では不十分であり、2種類以上を組み合わせることが重要であること、さらに2種類以上の糖類を組合せても、糖類の種類の選択によって不快味の低減効果が大きく異なることが判明した。そこで、本発明者らはさらなる探求を進めた結果、サポニンに対しては、グルコース又は/及びエリスリトール、並びに、トレハロース又は/及びマルトースを組み合わせて添加することにより、特有の不快味を極めて良好に低減できる知見を見出し、本発明を完成させるに到った。 In order to solve the above-mentioned problems, the present inventors have conducted a deeper analysis on how unpleasant taste appears when saponin comes into contact with the tongue, and as a result, saponin is immediately bitter and feels bitter when it first comes into contact with the tongue. The present inventors obtained knowledge that exhibits a peculiar unpleasant taste composed of bitterness and astringent taste. In order to satisfactorily reduce the unpleasant taste of saponin with saccharides, the use of only one type of saccharide is not sufficient, and it is important to combine two or more types, and even when two or more types of saccharides are combined. It has been found that the effect of reducing unpleasant taste varies greatly depending on the choice of the type of sugar. Therefore, as a result of further investigations, the present inventors have reduced the characteristic unpleasant taste very well by adding glucose or / and erythritol and trehalose or / and maltose in combination to saponin. The present inventors have found a knowledge that can be obtained and have completed the present invention.
すなわち本発明は、
(1)サポニンと共にグルコース又は/及びエリスリトール、並びに、トレハロース又は/及びマルトースが添加されていることを特徴とするサポニン含有経口製品。
(2)サポニンの純品換算で10重量部に対しグルコースもしくはエリスリトールが100重量部〜50000重量部、トレハロースもしくはマルトースが100重量部〜50000重量部添加された(1)に記載のサポニン含有経口製品。
(3)サポニンと共にグルコース又は/及びエリスリトール、並びに、トレハロース又は/及びマルトースを添加することを特徴とする経口製品中のサポニンの不快味低減方法。
を提供するものである。
That is, the present invention
(1) A saponin-containing oral product, wherein glucose or / and erythritol and trehalose or / and maltose are added together with saponin.
(2) The saponin-containing oral product according to (1), wherein 100 parts by weight to 50,000 parts by weight of glucose or erythritol and 100 parts by weight to 50,000 parts by weight of trehalose or maltose are added to 10 parts by weight in terms of pure saponin. .
(3) A method for reducing the unpleasant taste of saponins in oral products, which comprises adding glucose or / and erythritol and trehalose or / and maltose together with saponins.
Is to provide.
サポニンに対して特定の糖類を組み合わせて使用することにより、サポニン特有の不快味を効果的に低減することができる。これにより、他の高甘味度甘味料などのマスキング剤を多量に使用しなくとも、糖類のみを用いて有効にサポニンの不快味を低減した経口製品が得られる。 By using a specific saccharide in combination with saponin, the unpleasant taste peculiar to saponin can be effectively reduced. As a result, an oral product can be obtained in which the unpleasant taste of saponin is effectively reduced using only saccharides without using a large amount of other masking agents such as high intensity sweeteners.
本発明において用いられるサポニンは大豆、茶葉、茶種子、エンジュ、柴胡、甘草、ビート、キラヤ、ユッカ、キキョウ、人参類(田七人参、高麗人参、花旗人参、竹節人参等)などの種々の植物由来、又はヒトデやナマコなどの動物由来のものを用いることができる。サポニンは精製された純品でもよいし、上記動植物から抽出したサポニンを主成分とするサポニン組成物であってもよい。特に大豆由来のソヤサポニン類やそれらの組成物に用いることが好ましい。
サポニン組成物は、サポニンを含有する原料からサポニンを含む画分が抽出された組成物であればよく、例えば大豆由来のサポニンの場合、豆乳でも良いし、大豆や大豆胚軸を脂溶性有機溶媒を用いて脱脂後、水もしくは低級アルコール類を単独または混合して用い抽出し、この抽出液を合成吸着剤と接触させてサポニンを吸着させ、低級アルコールまたは含水低級アルコールで溶離処理して得られたサポニンに富む組成物でもよい。特にサポニン特有の不快味が強調されやすいため、サポニン含量が乾燥固形分中10重量%以上、より好ましくは20重量%以上含まれるサポニン組成物を用いることが適当である。
The saponins used in the present invention include various kinds such as soybeans, tea leaves, tea seeds, Enju, Saiko, licorice, beet, kiraya, yucca, yellow pepper, ginseng (Tanachi ginseng, ginseng, flower flag ginseng, bamboo ginseng, etc.). Plant-derived or animal-derived ones such as starfish and sea cucumber can be used. The purified saponin may be a purified product or a saponin composition mainly composed of saponin extracted from the above-mentioned animals and plants. It is particularly preferred to use soyasaponins derived from soybeans and their compositions.
The saponin composition may be a composition in which a fraction containing saponin is extracted from a saponin-containing raw material. For example, in the case of soybean-derived saponin, soy milk may be used, and soybean or soybean hypocotyl may be used as a fat-soluble organic solvent. Extracted using water or lower alcohols alone or mixed after degreasing, adsorbing saponin by contacting this extract with a synthetic adsorbent, and elution treatment with lower alcohol or hydrous lower alcohol. It may also be a composition rich in saponin. In particular, since the unpleasant taste peculiar to saponin is easily emphasized, it is appropriate to use a saponin composition having a saponin content of 10% by weight or more, more preferably 20% by weight or more in the dry solid content.
サポニンと共に添加すべき糖類の種類としては、グルコース、エリスリトール、トレハロース、マルトースが挙げられ、一般に食品原料として利用されているものが使用できるが、サポニン特有の不快味の低減効果を高めるためには、グルコース又は/及びエリスリトールと、トレハロース又は/及びマルトースを組み合わせて添加することが重要である。グルコース又は/及びエリスリトールのみを添加してもサポニンが舌に接触したときに直ちに感ずる苦味を十分に低減できない。またトレハロース又は/及びマルトースのみを添加してもサポニンが舌に接触してから後味として曳くような苦味や収斂味を十分に低減できない。また上記糖類の組合せを必須とせずに、砂糖、フラクトース、マルチトール、ソルビトール、キシリトール、パラチニットなどの糖類を単独又は併用してもサポニンの不快味の低減効果は十分ではない。 Glucose, erythritol, trehalose, maltose can be used as the type of saccharide to be added together with saponin, and those commonly used as food ingredients can be used.To increase the saponin-specific unpleasant taste reduction effect, It is important to add glucose or / and erythritol in combination with trehalose or / and maltose. Even if only glucose or / and erythritol is added, the bitter taste immediately felt when saponin contacts the tongue cannot be sufficiently reduced. Moreover, even if only trehalose and / or maltose is added, the bitterness and astringent taste that saponifies as a aftertaste after the saponin comes into contact with the tongue cannot be sufficiently reduced. Further, even if saccharides such as sugar, fructose, maltitol, sorbitol, xylitol, and paratinite are used alone or in combination without requiring the combination of the above saccharides, the effect of reducing the unpleasant taste of saponin is not sufficient.
前記糖類の使用量は、サポニン素材の純度、サポニンの濃度、食品の形態、食品に含有されるその他原料によっても異なるが、一般的にはサポニンの純品換算で10重量部あたりグルコース又は/及びエリスリトールの総量を100〜50000重量部、より好ましくは300〜30000重量部、トレハロース又は/及びマルトースの総量を100〜50000重量部、より好ましくは、300〜30000重量部が適当である。当該糖類の添加量が少なすぎると、サポニン素材の不快味低減効果が不十分であり、多すぎると不快味低減効果以外にそれ自体の甘味が強くなりすぎる。 The amount of sugar used varies depending on the purity of the saponin material, the concentration of the saponin, the form of the food, and other ingredients contained in the food, but generally glucose or / and / or 10 parts by weight in terms of pure saponin. The total amount of erythritol is 100 to 50000 parts by weight, more preferably 300 to 30000 parts by weight, and the total amount of trehalose and / or maltose is 100 to 50000 parts by weight, more preferably 300 to 30000 parts by weight. If the amount of the saccharide added is too small, the unpleasant taste reducing effect of the saponin material is insufficient, and if it is too large, the sweetness of the saponin material becomes too strong in addition to the unpleasant taste reducing effect.
グルコース又は/及びエリスリトールと、トレハロース又は/及びマルトースの混合比率は食品の形態や食品の組成などによっても異なるが、おおむね、1:5〜5:1程度が好ましい。 The mixing ratio of glucose or / and erythritol and trehalose or / and maltose varies depending on the form of the food, the composition of the food, etc., but is preferably about 1: 5 to 5: 1.
前記糖類の添加方法に関しては、サポニン含有製品を調製するに際し、サポニンを含有する原料をコーティングするように、又は製品中に偏在するように糖類を添加することも可能であるが、サポニンを含む原料に当該糖類を十分添加混合し、製品中に実質的にサポニンと糖類を均一に分散させておく方がより好ましい。サポニン特有の不快味が舌を刺激する際に、サポニンと共に均一に分散された糖類がその不快味の刺激を効果的に軽減すると考えられるためである。 Regarding the method for adding saccharides, when preparing a saponin-containing product, it is possible to add a saccharide so as to coat a raw material containing saponin or to be unevenly distributed in the product. It is more preferable that the saccharide is sufficiently added and mixed so that the saponin and saccharide are substantially uniformly dispersed in the product. This is because, when an unpleasant taste peculiar to saponin stimulates the tongue, it is considered that sugars uniformly dispersed together with saponin can effectively reduce the unpleasant taste stimulation.
その他、必要に応じて、前記糖類以外の糖質、食物繊維、油脂、乳製品、ビタミン類、ミネラル類、乳化剤、香料等の副原料を添加、混合し、製品を調製すればよい。 In addition, auxiliary products such as saccharides other than the saccharides, dietary fibers, fats and oils, dairy products, vitamins, minerals, emulsifiers, and fragrances may be added and mixed as necessary to prepare the product.
本発明の経口製品は、上記サポニンが添加された飲食品、医薬品、医薬部外品、口腔剤が含まれ、またこれらの製品に添加する原料としてのサポニン製剤をも包含される。飲食品は飲料、タブレット、菓子類、パン類、油脂類、乳製品、豆乳製品、スプレッド、米飯類、麺類、調味料、惣菜類、冷凍食品等、通常の食品形態であり、溶液、混濁液、粉末、固形物など、いずれの形態でも不快味の低減に効果を発揮する。医薬品・医薬部外品としては粉剤、錠剤、ドリンク剤、カプセル剤などが例示でき、口腔剤としては歯磨剤、マウスウォッシュ等が例示できる。 The oral product of the present invention includes foods and drinks, pharmaceuticals, quasi drugs and oral preparations to which the saponin is added, and also includes saponin preparations as raw materials added to these products. Foods and drinks are ordinary food forms such as beverages, tablets, confectionery, breads, fats and oils, dairy products, soy milk products, spreads, cooked rice, noodles, seasonings, side dishes, frozen foods, solutions, turbid liquids In any form, such as powder, solid, etc., it is effective in reducing unpleasant taste. Examples of pharmaceuticals and quasi drugs include powders, tablets, drinks and capsules, and examples of oral agents include dentifrices and mouthwashes.
次に実施例を挙げて本発明の態様を説明するが、本発明がこれらによってその技術的範囲が限定されるものではない。 Next, although an example is given and the aspect of the present invention is explained, the technical scope of the present invention is not limited by these.
[実施例1]
表1に示す配合で液状組成物を調製し、官能評価を実施した。以下の実験にはサポニン組成物として、「ソイヘルスSA」(不二製油株式会社製、サポニン含量:乾燥固形分あたり52重量%)を使用した。なお、官能評価は、試料が舌に接触した時に、最初に感ずる苦味(前味)と後に残る苦味や収斂味(後味)の各々の有無について調べた。不快味のレベルについては、不快味がなく風味がよい場合を○、不快味が感じられる場合を△、不快味が強く風味の劣る場合を×の3段階の評価とした。以降の実施例においても同様の評価方法を用いた。
[Example 1]
A liquid composition was prepared with the formulation shown in Table 1, and sensory evaluation was performed. In the following experiment, “Soy Health SA” (manufactured by Fuji Oil Co., Ltd., saponin content: 52% by weight per dry solid content) was used as a saponin composition. In addition, sensory evaluation investigated the presence or absence of each of the bitter taste (early taste) first felt when the sample contacted a tongue, and the bitter taste and astringent taste (aftertaste) which remain afterward. As for the level of unpleasant taste, a case where there is no unpleasant taste and a good taste was evaluated as “◯”, a case where an unpleasant taste was felt was evaluated as “△”, and a case where the unpleasant taste was strong and the flavor was inferior was evaluated as three levels. The same evaluation method was used in the following examples.
(表1) 単位:重量%
────────────────────────────
NO. 1 2 3 4
────────────────────────────
ソイヘルスSA 0.2 0.2 0.2 0.2
グルコース − 10.0 5.0 −
トレハロース − − 5.0 10.0
水 99.8 89.8 89.8 89.8
────────────────────────────
評価 前味 × × ○ ○
後味 × ○ ○ ×
総合 × △ ○ △
────────────────────────────
(Table 1) Unit:% by weight
────────────────────────────
NO. 1 2 3 4
────────────────────────────
Soi Health SA 0.2 0.2 0.2 0.2
Glucose − 10.0 5.0 −
Trehalose − − 5.0 10.0
Water 99.8 89.8 89.8 89.8
────────────────────────────
Evaluation Forefront × × ○ ○
Aftertaste × ○ ○ ×
General × △ ○ △
────────────────────────────
以上の結果より、グルコースとトレハロースを各々単独で添加するよりも、これらを組み合わせて使用することにより、より一層のサポニンの不快味低減効果が得られる知見を得た。 From the above results, it was found that the use of a combination of glucose and trehalose alone can further reduce the unpleasant taste of saponin.
[実施例2]
表2に示す配合でタブレットを調製し、実施例1と同様に官能評価を実施した。
[Example 2]
Tablets were prepared with the formulation shown in Table 2, and sensory evaluation was performed in the same manner as in Example 1.
(表2) 単位:重量%
──────────────────────
NO. 5 6
──────────────────────
ソイヘルスSA 1.5 1.5
マルトース 38.75 −
グルコース 50.0 −
砂糖 − 88.75
ココアパウダー 6.0 6.0
チョコレートフレーバー 1.0 1.0
ショ糖脂肪酸エステル 2.5 2.5
ステビア 0.25 −
──────────────────────
評価 前味 ○ ×
後味 ○ ×
総合評価 ○ ×
──────────────────────
(Table 2) Unit:% by weight
──────────────────────
NO.5 6
──────────────────────
Soi Health SA 1.5 1.5
Maltose 38.75 −
Glucose 50.0 −
Sugar − 88.75
Cocoa powder 6.0 6.0
Chocolate flavor 1.0 1.0
Sucrose fatty acid ester 2.5 2.5
Stevia 0.25 −
──────────────────────
Evaluation Forefront ○ ×
Aftertaste ○ ×
Overall evaluation ○ ×
──────────────────────
以上の結果より、砂糖を使用したNo.6は甘味はあっても不快味が強かった。一方、No.5は不快味が極めて少なく、良好な風味を示した。 From the above results, No. 6 using sugar had a strong unpleasant taste despite being sweet. On the other hand, No. 5 had very little unpleasant taste and showed a good flavor.
[実施例3]
表3の配合で飲料を作成し、実施例1と同様に官能評価行った。
[Example 3]
Beverages were prepared with the formulations shown in Table 3, and sensory evaluation was performed in the same manner as in Example 1.
(表3) 単位:重量%
──────────────────────────
NO. 7 8 9
──────────────────────────
ソイヘルスSA 0.1 0.1 0.1
エリスリトール 0.1 2.5 10.0
トレハロース 0.1 2.5 10.0
ステビア 0.05 0.02 −
クエン酸 0.2 0.2 0.2
オレンジフレーバー 0.2 0.2 0.2
水 残余 残余 残余
──────────────────────────
評価 前味 △ ○ ○
後味 △ ○ ○
総合評価 △ ○ ○
──────────────────────────
(Table 3) Unit:% by weight
──────────────────────────
NO. 7 8 9
──────────────────────────
Soi Health SA 0.1 0.1 0.1
Erythritol 0.1 2.5 10.0
Trehalose 0.1 2.5 10.0
Stevia 0.05 0.02 −
Citric acid 0.2 0.2 0.2
Orange flavor 0.2 0.2 0.2
Water Residual Residual Residual Residual Residue Residue
Evaluation Forefront △ ○ ○
Aftertaste △ ○ ○
Overall evaluation △ ○ ○
──────────────────────────
以上の結果より、No.7では、高甘味度甘味料で甘味を調整しても、エリスリトール、トレハロースの添加量が少ないと、不快味が感じられた。一方、No.8、No.9では、不快味が極めて少なく、良好な風味を示した。 From the above results, in No. 7, even when the sweetness was adjusted with a high-intensity sweetener, an unpleasant taste was felt when the amount of erythritol or trehalose added was small. On the other hand, No. 8 and No. 9 showed very little unpleasant taste and good taste.
[実施例4]
実施例1〜3の結果を踏まえ、さらにサポニンの不快味を低減できる糖類の組合せを調べた。「ソイヘルスSA」0.2重量%に、表4に示した糖類Aと糖類Bを等分に計8.0重量%混合し、水を加えて100重量%として液状組成物を調製し、実施例1と同様にして官能評価を実施した。結果を表4に示す。
[Example 4]
Based on the results of Examples 1 to 3, combinations of saccharides that can further reduce the unpleasant taste of saponin were examined. “Soy Health SA” was mixed with 0.2% by weight of saccharide A and saccharide B shown in Table 4 in an equal amount of 8.0% by weight, and water was added to prepare a liquid composition to 100% by weight. Then, sensory evaluation was performed. The results are shown in Table 4.
(表4)サポニンの不快味低減に効果を有する糖類の組合せの評価
(Table 4) Evaluation of combinations of saccharides effective in reducing the unpleasant taste of saponins
フラクトース、マルチトール、パラチニット、ソルビトール、キシリトールなどは甘味はあっても不快味は強かった。また、フラクトース、マルチトールをマルトースやエリスリトールと組みあわせても、前味又は後味の一方に不快味が残り、低減効果が不十分であった。またマルトースとトレハロースを組み合わせても後味に不快味が残り、逆にグルコースとエリスリトールを組み合わせても前味の不快味が残り、いずれも総合的な不快味の低減が不十分であった。しかし、マルトースとエリスリトールを組み合わせると、前味と後味のいずれの不快味も低減され、極めて風味良好であった。 Fructose, maltitol, palatinit, sorbitol, xylitol, etc. were sweet but unpleasant. Moreover, even when fructose and maltitol were combined with maltose and erythritol, an unpleasant taste remained in one of the fore taste and aftertaste, and the reduction effect was insufficient. Further, even when maltose and trehalose were combined, an unpleasant taste remained in the aftertaste, and conversely, a combination of glucose and erythritol remained an unpleasant taste of the fore taste, and the overall reduction in unpleasant taste was insufficient. However, when maltose and erythritol were combined, the unpleasant taste of both the fore and aftertaste was reduced, and the flavor was extremely good.
以上実施例1〜4の結果より、サポニンの不快味を低減するには、
(1)グルコース又は/及びエリスリトールと、
(2)マルトース又は/及びトレハロース
を組み合わせることが最も有効であると考えられる。
From the results of Examples 1 to 4 above, in order to reduce the unpleasant taste of saponin,
(1) glucose or / and erythritol;
(2) A combination of maltose and / or trehalose is considered to be most effective.
本発明により、サポニン特有の不快味を効果的に低減することができるため、サポニンを使用した経口製品の製造へ利用することができ、サポニンのより積極的な利用が図られる。以て健康素材であるサポニン関連の産業の発達に寄与することができる。
According to the present invention, the unpleasant taste peculiar to saponins can be effectively reduced, so that it can be used for the production of oral products using saponins, and the saponins can be used more actively. This can contribute to the development of saponin-related industries, which are health materials.
Claims (3)
A method for reducing unpleasant taste of saponin in an oral product, characterized by adding glucose or / and erythritol and trehalose or / and maltose together with saponin.
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JP2007137797A (en) * | 2005-11-16 | 2007-06-07 | Ss Pharmaceut Co Ltd | Oral formulation containing dried walnut extract |
JP2009517036A (en) * | 2005-11-23 | 2009-04-30 | ザ・コカ−コーラ・カンパニー | High-sweetness sweetener composition containing saponin and sweetened composition thereby |
JP2010148425A (en) * | 2008-12-25 | 2010-07-08 | House Foods Corp | Saponin having masked bitter taste |
JP2015091778A (en) * | 2013-10-01 | 2015-05-14 | 大正製薬株式会社 | Internal liquid |
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JP2007137797A (en) * | 2005-11-16 | 2007-06-07 | Ss Pharmaceut Co Ltd | Oral formulation containing dried walnut extract |
JP2009517036A (en) * | 2005-11-23 | 2009-04-30 | ザ・コカ−コーラ・カンパニー | High-sweetness sweetener composition containing saponin and sweetened composition thereby |
JP2010148425A (en) * | 2008-12-25 | 2010-07-08 | House Foods Corp | Saponin having masked bitter taste |
JP2015091778A (en) * | 2013-10-01 | 2015-05-14 | 大正製薬株式会社 | Internal liquid |
JP2017099323A (en) * | 2015-11-30 | 2017-06-08 | サントリー食品インターナショナル株式会社 | Hydroxytyrosol-containing tea beverage |
JP2017099320A (en) * | 2015-11-30 | 2017-06-08 | サントリー食品インターナショナル株式会社 | Tea drink containing grape seed polyphenols |
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