JP2005027361A - Wind power generation water electrolysis hydrogen production system - Google Patents
Wind power generation water electrolysis hydrogen production system Download PDFInfo
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- JP2005027361A JP2005027361A JP2003186556A JP2003186556A JP2005027361A JP 2005027361 A JP2005027361 A JP 2005027361A JP 2003186556 A JP2003186556 A JP 2003186556A JP 2003186556 A JP2003186556 A JP 2003186556A JP 2005027361 A JP2005027361 A JP 2005027361A
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- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 238000010248 power generation Methods 0.000 title claims abstract description 47
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 38
- 239000001257 hydrogen Substances 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 claims description 2
- 239000000446 fuel Substances 0.000 abstract description 8
- 239000007787 solid Substances 0.000 abstract description 5
- 238000004146 energy storage Methods 0.000 abstract description 4
- 229920000642 polymer Polymers 0.000 abstract description 4
- 230000002708 enhancing effect Effects 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000005518 polymer electrolyte Substances 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/70—Wind energy
- Y02E10/72—Wind turbines with rotation axis in wind direction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E70/00—Other energy conversion or management systems reducing GHG emissions
- Y02E70/30—Systems combining energy storage with energy generation of non-fossil origin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
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- Wind Motors (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Fuel Cell (AREA)
- Control Of Eletrric Generators (AREA)
Abstract
Description
【0001】
【発明の属する技術分野】
気象条件による風況変化に伴い風力発電出力は変動するが、本発明は、その変動する出力において水電解水素を製造し、エネルギーの貯蔵性と自然エネルギーの有効利用を推進するものである。
風力発電は電力系統上の発電を目的とする場合、風力出力の変動より風力立地点の電力系統容量により風力発電の受入量が制約されることがある。風力発電による水素製造は全くその制約を受けることなく、燃料電池自動車の普及などと共に、水素需要に供給してゆくものとする。また、離島などの小規模電力系統においても、系統容量に関せず、大容量風力発電は立地可能になる場合もある。
【0002】
【従来の技術】
従来、国内の水素製造は、苛性ソーダ製造における副産物として製造されていた。海外においては、電力料金の廉価な国では、水電解により水素製造されている。
我が国においては、風力発電は電力系統の発電を目的として開発されてきたが、電力系統の系統容量によって、風力発電の系統での受入量には制約されることがあり、新エネルギーとして風力発電は期待されているが、その開発の阻害要因となる場合もある。
【0003】
【発明が解決しようとする課題】
風力発電出力は、気象条件及び地域による風況変化に伴い変動し、出力が常時変動するため、安定した電力を供給できないという欠点がある。しかし、その変動する出力において水電解水素を製造し、燃料電池によって電力を供給することにより、エネルギーの貯蔵性と自然エネルギーの有効利用を推進するものであり、燃料電池自動車の燃料としての水素需要拡大に対処し得るものとなる。
水電解は固体高分子型としており、固体高分子膜及び電極触媒の高性能化によって水電解効率を向上させ、風力の出力変動に対応して水電解水素製造量を最大にする風力発電水素製造の制御システムを必要とする。
【0004】
【課題を解決するための手段】
上記目的を達成するために、本発明は下記のようになるものである。
風力発電は風速に対応してプロペラ回転数を可変にすると風力発電電力量は、定速回転の風力発電より出力増加するが周波数変動を生ずる。
水電解負荷は直流負荷であり、周波数変動には無関係である。
風力発電の発電出力を直流化して水電解水素製造に利用する場合、水電解装置の定格容量をn個に分割し、n≧3とした電解装置の各々の電解容量は、P1>P2>P3......>Pnの関係を有して、風力発電の定格出力PはP1+P2+P3......+Pn=Pであるとき、風力発電の定格出力Pを発生する定格風速以上の領域においては、電解装置は供給電圧を電解電圧以上として定電流制御とする。
また、定格風速未満の領域においてはn個の電解装置を、風力発電出力に適合するように負荷を分割制御し、その供給電圧は電解電圧以上において定電圧制御し、負荷分割制御における電流密度は定格電流密度を低減して電解効率の向上を図るものとする。
電流密度と水素1Nm3 製造に要す電力量(水素製造電力原単位kWH/Nm3 −H2)との関係の一例を図1に示す。
図1において、水電解電極の電流密度(A/cm2 )±50%の変化において水素1Nm3 製造に要する電力量は±7%の増減を示す。
以上、風速変動による風力発電出力の変化に対応して、負荷を分割制御し、定格風速以下においては発電出力が水電解負荷容量より下回る場合、水電解電流密度を定格電流密度より低減させて、水素製造電力原単位を節減させ、水電解効率の向上を図るものとする。
【0005】
【発明の実施の形態】
以下、本発明の実施の形態を実施例に基づき、図1、図2、図3を参照して説明する。
図2における(A)は、風力発電における風速と発電出力特性を示したものであり、風力出力特性において、風速12m/s 以上においては定格出力100%を発電し、風速25m/s 以上にて、プロペラ回転を停止して発電停止し、風速12m/s 未満においては発電出力は低減し、風速3m/s にて発電停止する特性を有する。
風力発電の定格出力を100%とし、その水電解容量を100%とするとき、水電解容量は、45%、30%、15%、10%の4組で構成し、その容量の総和は、45+30+15+10=100%とする。
図2における(B)は、風速と電解負荷の分割制御の関係を示したものであり、風速12〜25m/s においては、4組の水電解装置の全容量を使用し、風速12m/s 未満においては発電出力50%(風速8m/s 相当)に低減するまでは水電解装置の全容量を負荷とする。その場合、電流密度は1.0〜0.5A/cm2 まで変化することになる。
発電出力50〜35%においては、水電解装置は3組に分割制御し、45+15+10=70%容量として電極の電流密度は0.71〜0.5A/cm2 となる。発電出力35〜30%においては、水電解装置は2組に分割制御し、45+15=60%容量として電流密度は0.58〜0.5A/cm2 となる。
以下発電出力の低減においては表1のように制御される。
【0006】
【表1】
【0007】
以上、4組の水電解装置は負荷を分割制御し、供給電圧は電解電圧以上の電圧において定電圧制御するとき、電流密度は図2における(C)に示す風速と電流密度の関係は定格電流密度を1.0〜0.5A/cm2 に低減することにより図1に示す電極電流密度と水素製造電力原単位の特性より、水素製造に要する電力原単位(電解電力量 kWH/水素1Nm3 )を節減し水電解効率の向上を図るものである。
図3に風力発電水電解水素製造装置の構成図を示す。
図3において、風力発電機1の出力は、負荷時電圧調整機能を有する水電解用変圧器2に供給され、電圧調整された出力は、負荷開閉器3及び整流器4を経て、固体高分子型水電解装置5に供給される。
負荷容量は、P1=45%、P2=30%、P3=15%、P4=10%に分割されて、風力発電の出力に応じて、負荷開閉器3により負荷が分割制御される。
固体高分子型水電解装置5には純水供給装置6より純水が供給され、また、発生した水素は水素供給部7及び水素圧縮機8を経て高圧水素貯溜部9に貯溜される。
以上において固体高分子型水電解装置5の水電解電圧を検出して、水電解用変圧器2に付属している負荷時電圧調整部を制御するものとし、風力発電出力の交流側において電圧調整するものとして、高調波を生じない方式としている。
【0008】
【発明の効果】
本発明は、上述の通り構成されているので、次に記載する効果を奏する。
気象状態により出力変動する風力発電において、風況に対応した水素製造量を最大にする制御システムを確立し、変動する出力において、水電解水素を製造し、燃料電池によって電力を供給することにより、エネルギーの貯蔵性と自然エネルギーの有効利用を推進するものである。
また、無公害の燃料電池自動車の燃料として、水素需要に供給し得る。
【図面の簡単な説明】
【図1】水電解電流密度と水素製造電力原単位の特性を示すグラフである。
【図2】風力発電における風速と風力出力特性の関係と、風速と電解負荷の分割制御の関係と、風速と分割負荷による電極電流密度の関係を示すグラフである。
【図3】風力発電水電解水素製造装置の構成図である。
【符号の説明】
1 風力発電機
2 水電解用変圧器
3 負荷開閉器
4 整流器
5 固体高分子型水電解装置
6 純水供給装置
7 水素供給部
8 水素圧縮機
9 高圧水素貯溜部[0001]
BACKGROUND OF THE INVENTION
Wind power generation output fluctuates with changes in wind conditions due to weather conditions, but the present invention produces water electrolysis hydrogen at the fluctuating output to promote energy storage and effective use of natural energy.
When wind power generation is intended for power generation on the power system, the amount of wind power generation received may be limited by the power system capacity at the wind power location due to fluctuations in wind power output. Hydrogen production by wind power generation will not be restricted at all, and will be supplied to hydrogen demand along with the spread of fuel cell vehicles. Even in small-scale power systems such as remote islands, large-capacity wind power generation may be possible regardless of the system capacity.
[0002]
[Prior art]
Traditionally, domestic hydrogen production has been produced as a by-product in caustic soda production. Overseas, hydrogen is produced by water electrolysis in countries with low electricity prices.
In Japan, wind power generation has been developed for the purpose of power system power generation. However, the capacity of the wind power generation system may be limited by the capacity of the power system. Although expected, it may be an impediment to its development.
[0003]
[Problems to be solved by the invention]
Wind power generation output fluctuates with changes in wind conditions depending on weather conditions and regions, and the output constantly fluctuates, so that there is a drawback that stable power cannot be supplied. However, by producing water electrolysis hydrogen at the fluctuating output and supplying electric power by the fuel cell, it promotes energy storage and effective use of natural energy. Demand for hydrogen as fuel for fuel cell vehicles It can deal with expansion.
Water electrolysis is a solid polymer type, wind power generation hydrogen production that improves water electrolysis efficiency by improving the performance of solid polymer membrane and electrode catalyst, and maximizes water electrolysis hydrogen production in response to wind power fluctuations Requires a control system.
[0004]
[Means for Solving the Problems]
In order to achieve the above object, the present invention is as follows.
In wind power generation, if the propeller rotation speed is made variable in accordance with the wind speed, the amount of wind power generation increases from that of wind power generation at constant speed, but the frequency fluctuates.
The water electrolysis load is a direct current load and is independent of frequency fluctuations.
When the power generation output of wind power generation is converted to direct current and used for water electrolysis hydrogen production, the electrolysis capacity of each electrolysis apparatus in which the rated capacity of the water electrolysis apparatus is divided into n and n ≧ 3 is P1>P2> P3 . . . . . . > Pn, the rated output P of wind power generation is P1 + P2 + P3. . . . . . When + Pn = P, in the region of the rated wind speed or higher that generates the rated output P of wind power generation, the electrolyzer performs constant current control by setting the supply voltage to be equal to or higher than the electrolytic voltage.
Also, in the region below the rated wind speed, the n electrolyzers are divided and controlled so as to match the wind power generation output, and the supply voltage is controlled at a constant voltage above the electrolysis voltage, and the current density in the load division control is The rated current density is reduced to improve electrolytic efficiency.
An example of the relationship between the current density and the
In FIG. 1, when the current density (A / cm 2 ) of the water electrolysis electrode is changed by ± 50%, the amount of power required for producing hydrogen 1Nm 3 shows an increase / decrease of ± 7%.
As described above, the load is divided and controlled in response to the change in the wind power generation output due to the wind speed fluctuation, and when the power generation output is lower than the water electrolysis load capacity below the rated wind speed, the water electrolysis current density is reduced from the rated current density, Reduce the unit of electricity used for hydrogen production to improve water electrolysis efficiency.
[0005]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, embodiments of the present invention will be described based on examples with reference to FIGS. 1, 2, and 3. FIG.
(A) in FIG. 2 shows the wind speed and power generation output characteristics in wind power generation. In the wind power output characteristics, when the wind speed is 12 m / s or more, a rated output of 100% is generated and the wind speed is 25 m / s or more. The propeller rotation is stopped to stop the power generation, and the power generation output is reduced when the wind speed is less than 12 m / s, and the power generation is stopped at the wind speed of 3 m / s.
When the rated output of wind power generation is 100% and the water electrolysis capacity is 100%, the water electrolysis capacity is composed of 4 groups of 45%, 30%, 15%, and 10%. 45 + 30 + 15 + 10 = 100%.
(B) in FIG. 2 shows the relationship between the wind speed and the split control of the electrolytic load. At the wind speed of 12 to 25 m / s, the total capacity of the four sets of water electrolyzers is used, and the wind speed of 12 m / s. If it is less than 50%, the total capacity of the water electrolysis apparatus is used as a load until the power generation output is reduced to 50% (equivalent to a wind speed of 8 m / s). In that case, the current density will vary from 1.0 to 0.5 A / cm 2 .
At the power generation output of 50 to 35%, the water electrolysis apparatus is divided and controlled into three sets, and the current density of the electrode is 0.71 to 0.5 A / cm 2 with 45 + 15 + 10 = 70% capacity. At a power generation output of 35 to 30%, the water electrolysis device is divided and controlled in two sets, and the current density is 0.58 to 0.5 A / cm 2 with 45 + 15 = 60% capacity.
In the following, the power generation output is reduced as shown in Table 1.
[0006]
[Table 1]
[0007]
As described above, when the four sets of water electrolyzer control the load in a divided manner and the supply voltage is controlled at a constant voltage at a voltage higher than the electrolysis voltage, the relationship between the wind speed and the current density shown in FIG. By reducing the density to 1.0 to 0.5 A / cm 2 , the power consumption required for hydrogen production (electrolytic power amount kWh /
FIG. 3 shows a configuration diagram of the wind power generation water electrolysis hydrogen production apparatus.
In FIG. 3, the output of the
The load capacity is divided into P1 = 45%, P2 = 30%, P3 = 15%, and P4 = 10%, and the load is divided and controlled by the
Pure water is supplied to the polymer electrolyte
In the above, the water electrolysis voltage of the polymer electrolyte
[0008]
【The invention's effect】
Since this invention is comprised as mentioned above, there exists an effect described below.
By establishing a control system that maximizes the amount of hydrogen produced in response to wind conditions in wind power generation that fluctuates in output due to weather conditions, by producing water electrolysis hydrogen at fluctuating output and supplying power through a fuel cell, It promotes energy storage and effective use of natural energy.
It can also be supplied to hydrogen demand as a fuel for pollution-free fuel cell vehicles.
[Brief description of the drawings]
FIG. 1 is a graph showing characteristics of water electrolysis current density and hydrogen production power intensity.
FIG. 2 is a graph showing the relationship between wind speed and wind power output characteristics in wind power generation, the relationship between wind speed and electrolytic load division control, and the relationship between wind speed and electrode current density due to the divided load.
FIG. 3 is a configuration diagram of a wind power generation water electrolysis hydrogen production apparatus.
[Explanation of symbols]
DESCRIPTION OF
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JP2008278726A (en) * | 2007-05-07 | 2008-11-13 | Hitachi Ltd | Wind power generation control system and control method thereof |
US7667343B2 (en) | 2006-03-14 | 2010-02-23 | Hitachi, Ltd. | Hydrogen production system using wind turbine generator |
EP1878714A4 (en) * | 2005-05-02 | 2010-03-10 | Hrein Energy Inc | Organic hydride synthesizing apparatus, organic hydride synthesizing system and hydrogen production apparatus |
CN101976853A (en) * | 2010-11-09 | 2011-02-16 | 张建洲 | Wind power hydrogen production regulation, control and grid-connection system |
US8203225B2 (en) | 2007-11-06 | 2012-06-19 | Devine Timothy J | Systems and methods for producing, shipping, distributing, and storing hydrogen |
US8275489B1 (en) | 2009-04-21 | 2012-09-25 | Devine Timothy J | Systems and methods for deployment of wind turbines |
CN103114297A (en) * | 2013-02-18 | 2013-05-22 | 一重集团大连设计研究院有限公司 | Hydrogen production system |
WO2013099524A1 (en) * | 2011-12-28 | 2013-07-04 | 株式会社 日立製作所 | System for converting and storing renewable energy |
JP2014530321A (en) * | 2011-10-11 | 2014-11-17 | ヘイサム, ヤクブHAISAM, Yakoub | Wind energy turbine shell station |
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