JP2004203801A - Cleanser composition - Google Patents
Cleanser composition Download PDFInfo
- Publication number
- JP2004203801A JP2004203801A JP2002375905A JP2002375905A JP2004203801A JP 2004203801 A JP2004203801 A JP 2004203801A JP 2002375905 A JP2002375905 A JP 2002375905A JP 2002375905 A JP2002375905 A JP 2002375905A JP 2004203801 A JP2004203801 A JP 2004203801A
- Authority
- JP
- Japan
- Prior art keywords
- cationized
- alkyl
- sulfate
- weight
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 24
- 230000003750 conditioning effect Effects 0.000 claims abstract description 20
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 13
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 8
- 239000000213 tara gum Substances 0.000 claims abstract description 5
- 235000010491 tara gum Nutrition 0.000 claims abstract description 5
- -1 alkyl ether sulfate Chemical class 0.000 claims description 69
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 27
- 229960003237 betaine Drugs 0.000 claims description 14
- 229920001296 polysiloxane Polymers 0.000 claims description 10
- 239000003599 detergent Substances 0.000 claims description 9
- 238000004140 cleaning Methods 0.000 claims description 7
- 235000000346 sugar Nutrition 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 4
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 claims 1
- 239000004471 Glycine Substances 0.000 claims 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 1
- 238000005187 foaming Methods 0.000 abstract description 16
- 150000004676 glycans Chemical class 0.000 abstract description 5
- 229920001282 polysaccharide Polymers 0.000 abstract description 5
- 239000005017 polysaccharide Substances 0.000 abstract description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 18
- 239000000194 fatty acid Substances 0.000 description 18
- 229930195729 fatty acid Natural products 0.000 description 18
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 13
- 235000019441 ethanol Nutrition 0.000 description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 8
- 239000002453 shampoo Substances 0.000 description 8
- 229920002907 Guar gum Polymers 0.000 description 7
- 229920002472 Starch Polymers 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 239000001913 cellulose Substances 0.000 description 7
- 229920002678 cellulose Polymers 0.000 description 7
- 235000010980 cellulose Nutrition 0.000 description 7
- 150000004665 fatty acids Chemical class 0.000 description 7
- 239000000665 guar gum Substances 0.000 description 7
- 235000010417 guar gum Nutrition 0.000 description 7
- 229960002154 guar gum Drugs 0.000 description 7
- 239000008107 starch Substances 0.000 description 7
- 235000019698 starch Nutrition 0.000 description 7
- 150000001298 alcohols Chemical class 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000004166 Lanolin Substances 0.000 description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 235000019388 lanolin Nutrition 0.000 description 5
- 229940039717 lanolin Drugs 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 239000000600 sorbitol Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 229960004418 trolamine Drugs 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 4
- 239000004375 Dextrin Substances 0.000 description 4
- 229920001353 Dextrin Polymers 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 229930006000 Sucrose Natural products 0.000 description 4
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 239000003240 coconut oil Substances 0.000 description 4
- 235000019864 coconut oil Nutrition 0.000 description 4
- 235000019425 dextrin Nutrition 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000284 extract Substances 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000005720 sucrose Substances 0.000 description 4
- 150000005846 sugar alcohols Chemical class 0.000 description 4
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical class ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 3
- RZRILSWMGXWSJY-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;sulfuric acid Chemical compound OS(O)(=O)=O.OCCN(CCO)CCO RZRILSWMGXWSJY-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 229920000926 Galactomannan Polymers 0.000 description 3
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 3
- KCYQMQGPYWZZNJ-BQYQJAHWSA-N hydron;2-[(e)-oct-1-enyl]butanedioate Chemical compound CCCCCC\C=C\C(C(O)=O)CC(O)=O KCYQMQGPYWZZNJ-BQYQJAHWSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229940014800 succinic anhydride Drugs 0.000 description 3
- 229940080117 triethanolamine sulfate Drugs 0.000 description 3
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical group O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- MSWZFWKMSRAUBD-GASJEMHNSA-N 2-amino-2-deoxy-D-galactopyranose Chemical compound N[C@H]1C(O)O[C@H](CO)[C@H](O)[C@@H]1O MSWZFWKMSRAUBD-GASJEMHNSA-N 0.000 description 2
- AEMOLEFTQBMNLQ-UHFFFAOYSA-N 3,4,5,6-tetrahydroxyoxane-2-carboxylic acid Chemical compound OC1OC(C(O)=O)C(O)C(O)C1O AEMOLEFTQBMNLQ-UHFFFAOYSA-N 0.000 description 2
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 239000004435 Oxo alcohol Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 2
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 2
- MSWZFWKMSRAUBD-UHFFFAOYSA-N beta-D-galactosamine Natural products NC1C(O)OC(CO)C(O)C1O MSWZFWKMSRAUBD-UHFFFAOYSA-N 0.000 description 2
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 229920006319 cationized starch Polymers 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 229930182830 galactose Natural products 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 229940074928 isopropyl myristate Drugs 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000002772 monosaccharides Chemical class 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 150000003333 secondary alcohols Chemical class 0.000 description 2
- 239000001384 succinic acid Substances 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 2
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 1
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical class OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- BFPYWIDHMRZLRN-UHFFFAOYSA-N 17alpha-ethynyl estradiol Natural products OC1=CC=C2C3CCC(C)(C(CC4)(O)C#C)C4C3CCC2=C1 BFPYWIDHMRZLRN-UHFFFAOYSA-N 0.000 description 1
- VOXZDWNPVJITMN-ZBRFXRBCSA-N 17β-estradiol Chemical compound OC1=CC=C2[C@H]3CC[C@](C)([C@H](CC4)O)[C@@H]4[C@@H]3CCC2=C1 VOXZDWNPVJITMN-ZBRFXRBCSA-N 0.000 description 1
- JNAYPSWVMNJOPQ-UHFFFAOYSA-N 2,3-bis(16-methylheptadecanoyloxy)propyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C JNAYPSWVMNJOPQ-UHFFFAOYSA-N 0.000 description 1
- XFOQWQKDSMIPHT-UHFFFAOYSA-N 2,3-dichloro-6-(trifluoromethyl)pyridine Chemical compound FC(F)(F)C1=CC=C(Cl)C(Cl)=N1 XFOQWQKDSMIPHT-UHFFFAOYSA-N 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- YRDVCPAITWPMHI-UHFFFAOYSA-N 2-(1-decyl-4,5-dihydroimidazol-1-ium-1-yl)ethanol Chemical compound CCCCCCCCCC[N+]1(CCO)CCN=C1 YRDVCPAITWPMHI-UHFFFAOYSA-N 0.000 description 1
- BKUWWVKLLKXDJK-UHFFFAOYSA-N 2-(dimethylamino)icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCC(N(C)C)C(O)=O BKUWWVKLLKXDJK-UHFFFAOYSA-N 0.000 description 1
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
【０００１】
【発明の属する技術分野】
本発明は、起泡力、コンディショニング性に優れた洗浄剤組成物に関する。
【０００２】
【従来の技術】
従来、化粧品原料として天然物及びその誘導体の使用が一般化され、セルロース、デンプン、グアガムといった天然多糖類のカチオン化物が利用されている。例えば特公昭４７−２０６３５号公報（特許文献１参照）にはカチオン化セルロース、特公昭６０−４２７６３号公報（特許文献２参照）にはカチオン化ヒドロキシアルキルデンプン、特開平７−１７８２５号公報（特許文献３参照）にはカチオン化ヒドロキシアルキルガラクトマンナンとしてカチオン化グアガムやカチオン化ローカストビーンガムの化粧品やシャンプーへの利用が報告されている。しかし、これら発明を洗浄剤組成物に用いた場合、その仕上がり感は十分に満足のいくものではなかった。例えば、カチオン化セルロースは、すすぎ時の指通りに優れているものの、泡立ちを阻害しやすく、かつ乾燥時にきしみ感や硬い感触を与える。またカチオン化グアガムは、泡立ちへの影響は少ないものの、コンディショニング効果としては不十分である。カチオン化デンプンは保湿性にはすぐれるものの、べたつきを生じるという問題点がある。
【０００３】
さらに、特開平１−２１６９１３号公報（特許文献４参照）ではカチオン化セルロースやカチオン化デンプンを含む第四級窒素含有水溶性ポリマーとスルホコハク酸系界面活性剤との組合せ、特開平７−４８２３３号公報（特許文献５参照）ではカチオン化セルロースやカチオン化グアガムを含む高分子と糖系界面活性剤との組合せ、特開２０００−２４７８４７号公報（特許文献６参照）ではカチオン化グアガムと２−ヒドロキシアルキルカルボン酸塩との組合せ、特表２０００−５１０４９１号公報（特許文献７参照）では、カチオン化セルロースやカチオン化グアガムを含むカチオン性高分子とアミドエーテルカルボン酸塩との組合せ、特開２００１−１０９３４号公報（特許文献８参照）ではカチオン化グアガムとエトキシル化カルボン酸型陰イオン界面活性剤との組合せが開示され、シャンプーのコンディショニング技術を高めることが報告されている。しかしながら、これら既知のカチオン化多糖類とアニオン性及び／又は両性界面活性剤とを組み合わせても、その欠点を十分に補うだけの効果は不足していた。また、特開平１０−３６４０３号公報（特許文献９参照）や特開平７−１７３０２９号公報（特許文献１０参照）では、多糖類分解物を用いた低分子量及び低粘度カチオン化誘導体の利用が開示されているが、多糖類分解物のカチオン化誘導体は皮膚や毛髪への吸着性が劣り、コンディショニング性が十分ではなかった。
【０００４】
【特許文献１】
特公昭４７−２０６３５号公報
【特許文献２】
特公昭６０−４２７６３号公報
【特許文献３】
特開平７−１７８２５号公報
【特許文献４】
特開平１−２１６９１３号公報
【特許文献５】
特開平７−４８２３３号公報
【特許文献６】
特開２０００−２４７８４７号公報
【特許文献７】
特表２０００−５１０４９１号公報
【特許文献８】
特開２００１−１０９３４号公報
【特許文献９】
特開平１０−３６４０３号公報
【特許文献１０】
特開平７−１７３０２９号公報
【０００５】
【発明が解決しようとする課題】
本発明の目的は、かかる事情を鑑みてなされたものであり、起泡力、コンディショニング性に優れた洗浄剤組成物を提供するものである。
【０００６】
【課題を解決するための手段】
本発明者らは、上記課題を解決すべく鋭意検討を重ねた結果、アニオン性界面活性剤及び／又は両性界面活性剤と１％水溶液で５００〜３０００ｍＰａ・ｓ粘度を有するカチオン化タラガムとを配合することにより、起泡力、コンディショニング性に優れた洗浄剤組成物が得られることを見出し、本発明を完成するに至った。
【０００７】
【発明の実施の形態】
本発明で用いるアニオン性界面活性剤は特に限定されないが、例えば、アルキルエーテル硫酸エステル塩、アルキル硫酸エステル塩、アルキルエーテルスルホコハク酸塩、アルケニルコハク酸糖エステル塩が挙げられる。アルキルエーテル硫酸エステル塩としては、ポリオキシエチレンラウリルエーテル硫酸アンモニウム（２ＥＯ）、ポリオキシエチレンアルキル（１１，１３，１５）エーテル硫酸ナトリウム（１ＥＯ）、ポリオキシエチレンアルキル（１２〜１４）エーテル硫酸トリエタノールアミン（３ＥＯ）等が挙げられ、中でもポリオキシエチレンラウリルエーテル硫酸ナトリウム（２ＥＯ）、ポリオキシエチレンラウリルエーテル硫酸ナトリウム（３ＥＯ）が好ましい。
アルキル硫酸塩としてはラウリル硫酸マグネシウム、アルキル（１１，１３，１５）硫酸トリエタノールアミン、アルキル（１２〜１４）硫酸トリエタノールアミン、オレイル硫酸ナトリウム、ミリスチル硫酸ナトリウム等が挙げられ、中でもラウリル硫酸ナトリウム、ラウリル硫酸トリエタノールアミンが好ましい。
【０００８】
アルキルエーテルスルホコハク酸塩としては、炭素数が６〜２２の直鎖または分岐鎖のアルキルアルコール、ヒドロキシアルキルアルコール、アルケニルアルコール、糖アルコール等のアルコール類またはそれらのアルキレンオキシド付加物と無水マレイン酸とを反応させた後に、スルホン化を行うことで得られる。これらのアルコール類の例としては、カプリルアルコール、セチルアルコール、ラウリルアルコール、ミリスチルアルコール、ステアリルアルコール、オレイルアルコール等の天然動植物由来の高級アルコールおよびチーグラー法による合成直鎖脂肪族第１級アルコール、２−エチルヘキサノール、２−メチルドデカノール、２−メチルトリデカノール等の通常オキソ合成によって得られる側鎖脂肪族第１級アルコール、ｎ−パラフィンを液相酸化して得られる第２級アルコール、グルコース、マルトース、スクロース等の糖アルコールが挙げられ、特に炭素数が１０〜１６のアルコールが好ましい。アルキレンオキシドおよびヒドロキシアルキレンオキシドは具体的に、エチレンオキシド、プロピレンオキシド、イソプロピレンオキシド、ブチレンオキシド、ヒドロキシエチレンオキシドであり、特にエチレンオキシド、プロピレンオキシドが好ましい。アルキレンオキシドまたはヒドロキシアルキレンオキシドの付加モル数は０〜２０であり、特に０〜９が好ましい。該界面活性剤の中和塩としては、ナトリウム、カリウムに代表されるアルカリ金属、マグネシウム、カルシウムに代表されるアルカリ土類金属、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、モノプロパノールアミンに代表される炭素数２または３のヒドロキシアルキル基を有する低級アルカノールアミン、アンモニア、水素原子が挙げられるが、マグネシウム、カルシウム、ナトリウム、トリエタノールアミンが好ましく、特にマグネシウム、カルシウムが最も好ましい。
【０００９】
このアルキルエーテルスルホコハク酸塩の好適な例としては、ラウリルスルホコハク酸ナトリウム、ポリオキシエチレンラウリルスルホコハク酸ナトリウム（３ＥＯ）、ポリオキシエチレンラウリルスルホコハク酸マグネシウム（３ＥＯ）、炭素数１２〜１４の第２級アルコールから誘導されるポリオキシエチレンモノアルキルスルホコハク酸ナトリウム（７ＥＯ）、炭素数１１〜１３のオキソアルコールから誘導されるポリオキシエチレンモノアルキルスルホコハク酸トリエタノールアミン（５ＥＯ）、オレイルスルホコハク酸カルシウム、ポリオキシエチレンココイルスルホコハク酸ナトリウム（３ＥＯ）等が挙げられる。
【００１０】
アルケニルコハク酸糖エステル塩は、糖類にアルケニル基置換の無水コハク酸を反応させて得られる。出発原料となる糖類としては、グルコース、マンノース、アロース、アルトロース、タロース、ガラクトース、イドース、グロース、フルクトース、タガトース、リボース、アラビノース、キシロース、リキソース、ソルボース、リブロース、キシルロース、アルドヘキソース、ケトヘキソース、ブシコース、ラムノース等の単糖類、ショ糖、マルトデキストリン類、シクロデキストリン類、イソマルトデキストリン類、セロオリゴ糖類、ガラクトオリゴ糖類、マンノオリゴ糖類等のオリゴ糖類、酵素変性デキストリン、等の加水分解澱粉、グルコサミン、ガラクトサミン、コンドロサミン、マンノサミン、グロサミン、カノサミン等のアミノ糖、グルクロン酸、グルロン酸、ガラクチュロン酸、マンニュロン酸等の酸性糖、リビット、アラビット、マンニット、ソルビット、グルシッド、ズルシッド、ボレミッド等の糖アルコール、還元澱粉糖化物（還元水飴）、還元麦芽水飴等が挙げられ、中でもデキストリン、ソルビット、ショ糖、グルコースが好適に用いられる。アルケニル基置換の無水コハク酸としては、炭素数は６〜１８のアルケニル基置換されたものが好ましい。
【００１１】
このアルケニルコハク酸糖エステル塩の好適な例としては、オクテニルコハク酸ソルビットエステルトリエタノールアミン、オクテニルコハク酸デキストリンエステルトリエタノールアミン、オクテニルコハク酸デキストリンエステルナトリウム等が挙げられる。
本発明で用いる両性界面活性剤は特に限定されないが、例えば、グリシン型両性界面活性剤やアミノ酢酸ベタイン型両性界面活性剤が挙げられる。
【００１２】
グリシン型両性界面活性剤としては、２−アルキル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタイン、ヤシ油脂肪酸アシル−Ｎ−カルボキシエチル−Ｎ−ヒドロキシエチルエチレンジアミン二ナトリウム、ヤシ油脂肪酸アシル−Ｎ−カルボキシエトキシエチル−Ｎ−カルボキシエチルエチレンジアミン二ナトリウム、ヤシ油脂肪酸アシル−Ｎ−カルボキシメトキシエチル−Ｎ−カルボキシメチルエチレンジアミン二ナトリウム、ウンデシル−Ｎ−ヒドロキシエチル−Ｎ−カルボキシメチルイミダゾリニウムベタイン、ウンデシルヒドロキシエチルイミダゾリニウムベタインナトリウム、塩化アルキルジアミノエチルグリシン、ラウリルジアミノエチルグリシンナトリウム等が挙げられ、中でも２−アルキル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタインが好ましい。
【００１３】
アミノ酢酸ベタイン型両性界面活性剤としては、ラウリルジメチルアミノ酢酸ベタイン、ヤシ油アルキルベタイン（ヤシ油アルキルジメチルアミノ酢酸ベタイン）、ステアリルジメチルアミノ酢酸ベタイン、ステアリルジメチルベタインナトリウム、ヤシ油脂肪酸アミドプロピルベタイン、パーム油脂肪酸アミドプロピルベタイン、ラウリン酸アミドプロピル酢酸ベタイン、リシノレイン酸アミドプロピルベタイン、ステアリルジヒドロキシエチルベタイン等が挙げら、中でもヤシ油脂肪酸アミドプロピルベタインが好ましい。
【００１４】
これら界面活性剤は、単独または２種以上を任意に組み合わせて用いることができる。配合量は組成物全量に対して、１０〜４０重量％配合することができ、特に１０〜３０重量％が好ましい。配合量が１０重量％に満たないと十分な泡立ちやコンディショニング効果を得ることができず、４０重量％を超えて配合するとゲル化する可能性がある。
【００１５】
本発明で用いるカチオン化タラガムの由来であるタラガムとは、コタタビ科タラの種子に含有される粘液物質である。種子の外皮及び胚芽を除去し、胚乳部分を粉砕、精製して得られる。主成分はガラクトマンナンでガラクトースとマンノースが約1：３の比率で結合している。
【００１６】
本発明で用いるカチオン化タラガムは、タラガム中のガラクトマンナンに含まれる水酸基の一部が第４級窒素含有基で置換された構造である。具体的には、タラガムにグリシジルトリアルキルアンモニウム塩または、３−ハロゲノ−２−ヒドロキシプロピルトリアルキルアンモニウム塩等の第４級窒素含有基を反応させることにより製造することができる。この場合、反応は適当な溶媒、好適には含水アルコール中において、アルカリの存在下で実施される。このような第４級窒素含有基の導入は、従来公知の方法に従って行うことができる。
【００１７】
カチオン化タラガムのカチオン化度、すなわち１単糖当たりに付加する第４級窒素含有基のモル数（窒素測定法より算出）は、特に限定されないが０．１〜０．５が好ましい。０．１未満では毛髪や皮膚に対する吸着量が不十分となり、十分なコンディショニング効果は認められない。また、０．５を越えると、使用時にベトツキ感が生じ且つ起泡性を悪化させる。
【００１８】
なお本発明で用いるカチオン化タラガム水溶液（１重量％）の粘度は、２５℃において５００〜３０００ｍＰａ・ｓ、好ましくは、８００〜２５００ｍＰａ・ｓである（３０ｒｐｍ、ＢＬ型粘度計を用いて測定する時）。粘度が５００ｍＰａ・ｓに満たないとコンディショニング効果が不十分であり、３０００ｍＰａ・ｓを越えると粘性が高くなり、初期の泡立ちを阻害する。
【００１９】
カチオン化タラガムの配合量は特に限定されるものではないが、組成物全量に対して０．１〜３重量％が好ましく、特に０．３〜１．５重量％が好ましい。配合量が０．１重量％に満たないとすすぎ時の使用感や乾燥後の使用感が悪く、３重量％を超えて配合すると使用時にベトツキ感を生じ、かつ起泡性を悪化させる。
【００２０】
さらに、本発明の洗浄剤組成物においては、シリコーンコンディショニング剤を配合するとコンディショニング性を相乗的に向上させることができる。本発明で用いるシリコーンコンディショニング剤としては、次のようなものが挙げられる。
（１）ジメチルポリシロキサン（重合度ｎ＝３〜６５０）
（２）メチルフェニルポリシロキサン（重合度ｎ＝１〜５００）
（３）ポリエ−テル変性ポリシロキサン。
（４）アミノ変性ポリシロキサン。
（５）エポキシ変性ポリシロキサン。
（６）フッ素変性ポリシロキサン。
（７）アルコ−ル変性ポリシロキサン。
（８）アルキル変性ポリシロキサン。
（９）高分子量ジメチルポリシロキサン
（重合度ｎ＝３０００〜２００００）
【００２１】
これらのシリコーンコンディショニング剤は、単独あるいは２種以上を混合して用いることができ、その配合量は特に限定されないが、組成物全量に対し０．１〜５重量％が好ましい。配合量が０．１重量％に満たないと、相乗的なコンディショニング性向上が付与できず、また５重量％を超えると起泡性を損なう。
【００２２】
本発明の洗浄剤組成物は、常法により製造することができ、ｐＨ４．０〜１０．５の洗浄剤として、洗顔剤、クレンジング剤、ボディシャンプー、石鹸、ヘアシャンプー等として提供され、使用部位や使用場面に合わせて、固体、粉体、液体、ジェル、クリーム、エアゾール、フォーム等様々な態様をとることができる。
【００２３】
また、本発明の洗浄剤組成物には、効果を損なわない範囲で公知の成分を適宜配合することができる。公知の成分としては、脂肪酸グリセリンエステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、ポリグリセリン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ペンタエリトリトール脂肪酸エステル、モノグリセリド誘導体、高級アルコール酸化エチレン付加物、ポリオキシエチレンアルキルアリルエーテル、ポリオキシエチレンラノリンアルコール、アルキルフェノールホルマリン縮合物の酸化エチレン誘導体、プルロニック型界面活性剤、ポリオキシエチレンアルキルチオエーテル、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレングリセリンモノ脂肪酸エステル、ポリオキシエチレンプロピレングリコールモノ脂肪酸エステル、ポリオキシエチレンソルビトール脂肪酸エステル、ポリオキシエチレンヒマシ油、硬化ヒマシ油誘導体、ポリオキシエチレンラノリン誘導体、脂肪族アルキル基を含むブロックポリマー、ポリオキシエチレン脂肪酸アミド、ポリオキシエチレンアルキルアミン、アルカノールアミド、アルキルアミンオキシド、アルキルポリグルコシドに代表されるノニオン性界面活性剤、塩化アルキルトリメチルアンモニウム、塩化ジアルキルジメチルアンモニウム、脂肪酸アミドアミン塩、エチル硫酸ラノリン脂肪酸アミノプロピルエチルジメチルアンモニウム、ジココイルエチルヒドロキシエチルモニウムメトサルフェートに代表されるカチオン性界面活性剤が挙げられる。
【００２４】
さらにアボカド油、アルモンド油、オリーブ油、グレープシード油、月見草油、ツバキ油、サザンカ油、マカデミアナッツ油、メドフォーム油、シアバター、卵黄油、馬脂等の油脂類、ホホバ油、カルナウバロウ、キャンデリラロウ、ラノリン、ミツロウ等のロウ類、オゾケライト、流動パラフィン、スクワレン、ワセリン等の炭化水素類、イソステアリルアルコール、オクチルドデカノール、ラノリンアルコール、フィトステロール、セタノール、オレイルアルコール等の高級アルコール類、ミリスチン酸イソプロピル、オレイン酸エチル、ステアリン酸オクチル、２−エチルヘキサン酸セチル、イソノナン酸イソノニル、パルミチン酸オクチル、ジオレイン酸エチレングリコール、トリイソステアリン酸グリセリル、乳酸セチル、アジピン酸ジイソプロピル、イソステアリン酸コレステリル等のエステル油類等、プロピレングリコール、ジプロピレングリコール、ポリプロピレングリコール、ポリエチレングリコール、グリセリン、ジグリセリン、イソプレングリコール、１，３−ブチレングリコール等の多価アルコール、エチルアルコール、イソプロパノール等の低級アルコール、キサンタンガム、グアガム、デンプン等の天然高分子及びその誘導体、ヒドロキシプロピルメチルセルロース、ヒドロキシエチルセルロース、メチルセルロース等のセルロール系高分子、カルボキシビニルポリマーやポリビニルピロリドン等の合成高分子等、ジステアリン酸エチレングリコール、ジステアリン酸トリエチレングリコール等のパール化剤、カオリン、無水ケイ酸、ケイ酸アルミニウムマグネシウム、タルク、マイカ、セルロース末、シルク末、デンプン、ポリエチレン末、ナイロン末、架橋ポリスチレン等の顔料、防腐剤、金属イオン封鎖剤、噴射剤、無機塩、有機酸及びその塩、ピロリドンカルボン酸及びその塩、ヒアルロン酸及びその塩、ソルビトールやマルチトールやトレハロース等の糖類、トリメチルグリシン等の保湿剤、塩化ベンザルコニウム、塩化ベンゼトニウム、イソプロピルメチルフェノール、ピロクトンオラミン、クララエキス、ジンクピリチオン、ヒノキチオール等の殺菌剤、その他、センブリエキス、塩化カプロニウム、セファランチン、サリチル酸、イノシット、ヨウ化ニンニクエキス、レゾルシン、エストラジオール、エチニルエストラジオール、オキセンドロン、パントテン酸及びその誘導体、プラセンタエキス、ビオチン、モノニトログアヤコール、感光素３０１、ウシヘマチン、グリチルリチン酸ジカリウム、塩酸ピリドキシン、冷感剤、温感剤、動植物抽出物、ビタミン、紫外線吸収剤、アミノ酸及びその誘導体、タンパク質及びその誘導体、酸化防止剤、着色剤、香料等である。
【００２５】
【実施例】
つぎに、実施例および比較例を挙げて本発明をさらに詳しく説明するが、言うまでもなく本発明はこれらに限定されるものではない。なお、特にことわらない場合、［％］は［重量％］を示す。
下記のヘアシャンプー基本処方及び表１〜３に示す組成にて、常法によりヘアシャンプーを調製した。調整した各ヘアシャンプーについて、１０名の専門パネルにより、使用時における泡立ち、すすぎ時の指通り、乾燥後の髪のまとまり及び平滑性を、次の基準で評価し、各項目の１０名の積算値及び総合評価を表に示した。
【００２６】
【表１】
【表２】
【表３】
表１〜３の結果が示すように、本発明の各実施例のヘアシャンプーは、各比較例に比べて起泡力、コンディショニング性（すすぎ時の指通り、乾燥後の髪のまとまり及び平滑性）に優れたものであった。
以下、常法により実施例１９〜２５を製造した。
【００３２】
【００３９】
【発明の効果】
本発明によれば、アニオン性界面活性剤及び／又は両性界面活性剤と１％水溶液で５００〜３０００ｍＰａ・ｓ粘度を有するカチオン化タラガムとを配合することにより、起泡力、コンディショニング性に優れた洗浄剤組成物が提供できる。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a detergent composition having excellent foaming power and conditioning property.
[0002]
[Prior art]
Conventionally, the use of natural products and their derivatives as cosmetic raw materials has been generalized, and cations of natural polysaccharides such as cellulose, starch and guar gum have been used. For example, Japanese Patent Publication No. 47-20635 (Patent Document 1) discloses a cationized cellulose, Japanese Patent Publication No. 60-42763 (Patent Document 2) discloses a cationized hydroxyalkyl starch, and JP-A-7-17825 (Patent Document 1). Reference 3) reports the use of cationized guar gum or cationized locust bean gum as a cationized hydroxyalkyl galactomannan in cosmetics and shampoos. However, when these inventions are used in a detergent composition, the finished feeling is not sufficiently satisfactory. For example, cationized cellulose is excellent in fingering during rinsing, but easily inhibits foaming, and gives a squeaky feeling and a hard feeling when dried. Also, cationized guar gum has little effect on foaming, but is insufficient as a conditioning effect. Although cationized starch is excellent in moisturizing properties, it has a problem of causing stickiness.
[0003]
Further, Japanese Patent Application Laid-Open No. 1-216913 (see Patent Document 4) discloses a combination of a quaternary nitrogen-containing water-soluble polymer containing cationized cellulose and cationized starch with a sulfosuccinic acid-based surfactant, and JP-A-7-48233. JP-A-2000-247847 (see Patent Document 6) discloses a combination of a polymer containing cationized cellulose and cationized guar gum with a sugar-based surfactant. In combination with an alkyl carboxylate, Japanese Patent Application Laid-Open No. 2000-510471 (see Patent Document 7), a combination of a cationic polymer containing cationized cellulose or cationized guar gum with an amide ether carboxylate is disclosed in JP-A-2001-2001. Japanese Patent No. 10934 (see Patent Document 8) discloses that cationized guar gum and ethoxylated calcium are used. Discloses a combination of a phosphate type anionic surfactant, it has been reported to increase the shampoo conditioning technology. However, even when these known cationized polysaccharides are combined with an anionic and / or amphoteric surfactant, the effect of sufficiently compensating the drawbacks has been insufficient. Further, JP-A-10-36403 (see Patent Document 9) and JP-A-7-173029 (see Patent Document 10) disclose the use of a low molecular weight and low viscosity cationized derivative using a polysaccharide decomposition product. However, the cationized derivative of the decomposed product of the polysaccharide has poor adsorbability to skin and hair and has insufficient conditioning properties.
[0004]
[Patent Document 1]
JP-B-47-20635 [Patent Document 2]
Japanese Patent Publication No. 60-42763 [Patent Document 3]
JP-A-7-17825 [Patent Document 4]
Japanese Patent Application Laid-Open No. 1-216913 [Patent Document 5]
JP-A-7-48233 [Patent Document 6]
JP 2000-247847 A [Patent Document 7]
JP 2000-51049 A [Patent Document 8]
JP 2001-10934 A [Patent Document 9]
Japanese Patent Application Laid-Open No. 10-36403 [Patent Document 10]
JP-A-7-173029
[Problems to be solved by the invention]
An object of the present invention has been made in view of such circumstances, and provides a cleaning composition having excellent foaming power and conditioning properties.
[0006]
[Means for Solving the Problems]
The present inventors have conducted intensive studies to solve the above problems, and as a result, blended anionic surfactant and / or amphoteric surfactant with cationized tara gum having a viscosity of 500 to 3000 mPa · s in a 1% aqueous solution. By doing so, it was found that a detergent composition having excellent foaming power and conditioning property was obtained, and the present invention was completed.
[0007]
BEST MODE FOR CARRYING OUT THE INVENTION
The anionic surfactant used in the present invention is not particularly limited, and examples thereof include an alkyl ether sulfate, an alkyl sulfate, an alkyl ether sulfosuccinate, and an alkenyl succinate sugar ester. Examples of the alkyl ether sulfates include polyoxyethylene lauryl ether ammonium sulfate (2EO), polyoxyethylene alkyl (11,13,15) ether sodium sulfate (1EO), and polyoxyethylene alkyl (12-14) ether triethanolamine sulfate. (3EO), among which sodium polyoxyethylene lauryl ether sulfate (2EO) and sodium polyoxyethylene lauryl ether sulfate (3EO) are preferable.
Examples of the alkyl sulfate include magnesium lauryl sulfate, alkyl (11, 13, 15) triethanolamine sulfate, alkyl (12 to 14) triethanolamine sulfate, sodium oleyl sulfate, sodium myristyl sulfate, and the like. Triethanolamine lauryl sulfate is preferred.
[0008]
Examples of the alkyl ether sulfosuccinate include alcohols such as linear or branched alkyl alcohols having 6 to 22 carbon atoms, hydroxyalkyl alcohols, alkenyl alcohols, sugar alcohols and the like, or alkylene oxide adducts thereof and maleic anhydride. It is obtained by performing sulfonation after the reaction. Examples of these alcohols include higher alcohols derived from natural animals and plants, such as caprylic alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol, stearyl alcohol, and oleyl alcohol, and linear aliphatic primary alcohols synthesized by the Ziegler method; Ethylhexanol, 2-methyldodecanol, side chain aliphatic primary alcohols usually obtained by oxo synthesis such as 2-methyltridecanol, secondary alcohols obtained by liquid-phase oxidation of n-paraffin, glucose, Examples thereof include sugar alcohols such as maltose and sucrose, and alcohols having 10 to 16 carbon atoms are particularly preferable. The alkylene oxide and the hydroxyalkylene oxide are specifically ethylene oxide, propylene oxide, isopropylene oxide, butylene oxide and hydroxyethylene oxide, with ethylene oxide and propylene oxide being particularly preferred. The number of moles of the alkylene oxide or hydroxyalkylene oxide added is 0 to 20, particularly preferably 0 to 9. Examples of neutralizing salts of the surfactant include alkali metals such as sodium and potassium, alkaline earth metals such as magnesium and calcium, monoethanolamine, diethanolamine, triethanolamine and monopropanolamine. Examples thereof include a lower alkanolamine having a hydroxyalkyl group having 2 or 3 carbon atoms, ammonia, and a hydrogen atom. Of these, magnesium, calcium, sodium, and triethanolamine are preferred, and magnesium and calcium are most preferred.
[0009]
Preferred examples of the alkyl ether sulfosuccinate include sodium lauryl sulfosuccinate, sodium polyoxyethylene lauryl sulfosuccinate (3EO), magnesium magnesium polyoxyethylene lauryl sulfosuccinate (3EO), and secondary alcohols having 12 to 14 carbon atoms. Sodium polyoxyethylene monoalkyl sulfosuccinate (7EO) derived from oxo alcohol having 11 to 13 carbon atoms, triethanolamine (5EO) derived from oxo alcohol having 11 to 13 carbon atoms, calcium oleyl sulfosuccinate, polyoxyethylene And sodium cocoylsulfosuccinate (3EO).
[0010]
The alkenyl succinic acid sugar ester salt is obtained by reacting a saccharide with an alkenyl group-substituted succinic anhydride. The starting sugars include glucose, mannose, allose, altrose, talose, galactose, idose, growth, fructose, tagatose, ribose, arabinose, xylose, lyxose, sorbose, ribulose, xylulose, aldhexose, ketohexose, and bucose. Monosaccharides such as rhamnose, sucrose, maltodextrins, cyclodextrins, isomaltodextrins, cellooligosaccharides, galactooligosaccharides, oligosaccharides such as mannooligosaccharides, hydrolyzed starch such as enzyme-modified dextrin, glucosamine, galactosamine, Amino sugars such as chondrosamine, mannosamine, glosamine, and canosamine; acidic sugars such as glucuronic acid, guluronic acid, galacturonic acid, and mannuronic acid; Tsu DOO, mannitol, sorbitol, Gurushiddo, Zurushiddo, sugar alcohols such as Boremiddo, hydrogenated starch hydrolyzate (reduced starch syrup), reduced malt syrup and the like, among dextrin, sorbitol, sucrose, glucose is preferably used. The alkenyl-substituted succinic anhydride is preferably an alkenyl-substituted succinic anhydride having 6 to 18 carbon atoms.
[0011]
Preferable examples of the alkenyl succinic acid sugar ester salt include octenyl succinic acid sorbitol ester triethanolamine, octenyl succinic acid dextrin ester triethanolamine, and octenyl succinic acid dextrin sodium salt.
The amphoteric surfactant used in the present invention is not particularly limited, and examples thereof include a glycine-type amphoteric surfactant and a betaine aminoacetate-type amphoteric surfactant.
[0012]
Examples of the glycine-type amphoteric surfactant include 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, coconut oil fatty acyl-N-carboxyethyl-N-hydroxyethylethylenediamine disodium, and coconut fatty acid acyl. N-carboxyethoxyethyl-N-carboxyethylethylenediamine disodium, coconut fatty acid acyl-N-carboxymethoxyethyl-N-carboxymethylethylenediamine disodium, undecyl-N-hydroxyethyl-N-carboxymethylimidazolinium betaine, Decyl hydroxyethyl imidazolinium betaine sodium, alkyl diaminoethyl glycine chloride, lauryl diaminoethyl glycine sodium, etc., among which 2-alkyl-N-ca Bokishimechiru -N- hydroxyethyl imidazolinium betaines are preferred.
[0013]
Aminoacetic acid betaine-type amphoteric surfactants include lauryl dimethylaminoacetic acid betaine, coconut oil alkylbetaine (coconut oil alkyldimethylaminoacetic acid betaine), stearyldimethylaminoacetic acid betaine, sodium stearyldimethylbetaine, coconut fatty acid amidopropyl betaine, palm oil Examples include oil fatty acid amidopropyl betaine, lauric acid amidopropyl acetate betaine, ricinoleic acid amidopropyl betaine, and stearyl dihydroxyethyl betaine. Of these, coconut oil fatty acid amidopropyl betaine is preferred.
[0014]
These surfactants can be used alone or in any combination of two or more. The compounding amount can be 10 to 40% by weight, preferably 10 to 30% by weight, based on the total amount of the composition. If the amount is less than 10% by weight, sufficient foaming and conditioning effects cannot be obtained. If the amount exceeds 40% by weight, gelation may occur.
[0015]
The cod gum derived from the cationized cod gum used in the present invention is a mucus substance contained in the seeds of the cod cod family. It is obtained by removing the hull and germ of the seed, pulverizing and purifying the endosperm part. The main component is galactomannan, in which galactose and mannose are bound at a ratio of about 1: 3.
[0016]
The cationized cod gum used in the present invention has a structure in which a part of the hydroxyl group contained in galactomannan in cod gum is substituted with a quaternary nitrogen-containing group. Specifically, it can be produced by reacting cod gum with a quaternary nitrogen-containing group such as a glycidyltrialkylammonium salt or a 3-halogeno-2-hydroxypropyltrialkylammonium salt. In this case, the reaction is carried out in a suitable solvent, preferably aqueous alcohol, in the presence of an alkali. Such a quaternary nitrogen-containing group can be introduced according to a conventionally known method.
[0017]
The degree of cationization of the cationized cod gum, that is, the number of moles of the quaternary nitrogen-containing group added per monosaccharide (calculated by a nitrogen measurement method) is not particularly limited, but is preferably 0.1 to 0.5. If it is less than 0.1, the amount of adsorption to hair and skin becomes insufficient, and a sufficient conditioning effect is not recognized. On the other hand, if it exceeds 0.5, a sticky feeling is generated at the time of use and the foaming property is deteriorated.
[0018]
The viscosity of the aqueous cationized tara gum solution (1% by weight) used in the present invention is 500 to 3000 mPa · s at 25 ° C., and preferably 800 to 2500 mPa · s (when measured using a BL-type viscometer at 30 rpm). ). If the viscosity is less than 500 mPa · s, the conditioning effect is insufficient, and if it exceeds 3000 mPa · s, the viscosity becomes high and the initial foaming is hindered.
[0019]
The amount of the cationized cod gum is not particularly limited, but is preferably 0.1 to 3% by weight, particularly preferably 0.3 to 1.5% by weight based on the total amount of the composition. If the amount is less than 0.1% by weight, the feeling of use during rinsing and the feeling after drying are poor. If the amount exceeds 3% by weight, a sticky feeling occurs at the time of use, and the foaming property is deteriorated.
[0020]
Further, in the cleaning composition of the present invention, if a silicone conditioning agent is blended, conditioning properties can be synergistically improved. Examples of the silicone conditioning agent used in the present invention include the following.
(1) Dimethylpolysiloxane (degree of polymerization n = 3 to 650)
(2) Methylphenylpolysiloxane (degree of polymerization n = 1 to 500)
(3) Polyether-modified polysiloxane.
(4) Amino-modified polysiloxane.
(5) Epoxy-modified polysiloxane.
(6) Fluorine-modified polysiloxane.
(7) alcohol-modified polysiloxane.
(8) Alkyl-modified polysiloxane.
(9) High molecular weight dimethylpolysiloxane (degree of polymerization n = 3000 to 20,000)
[0021]
These silicone conditioning agents can be used singly or as a mixture of two or more, and the amount thereof is not particularly limited, but is preferably 0.1 to 5% by weight based on the total amount of the composition. If the amount is less than 0.1% by weight, a synergistic improvement in conditioning property cannot be provided, and if it exceeds 5% by weight, the foaming property is impaired.
[0022]
The detergent composition of the present invention can be produced by a conventional method, and is provided as a face wash, a cleansing agent, a body shampoo, a soap, a hair shampoo, etc. as a detergent having a pH of 4.0 to 10.5. Various forms such as solids, powders, liquids, gels, creams, aerosols, foams, and the like can be adopted in accordance with the conditions of use.
[0023]
In addition, known components can be appropriately blended into the cleaning composition of the present invention as long as the effects are not impaired. Known components include fatty acid glycerin esters, sorbitan fatty acid esters, sucrose fatty acid esters, polyglycerin fatty acid esters, propylene glycol fatty acid esters, pentaerythritol fatty acid esters, monoglyceride derivatives, higher alcohol ethylene oxide adducts, and polyoxyethylene alkyl allyl ethers. , Polyoxyethylene lanolin alcohol, ethylene oxide derivative of alkylphenol formalin condensate, pluronic surfactant, polyoxyethylene alkyl thioether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerin mono fatty acid ester, poly Oxyethylene propylene glycol monofatty acid ester, polyoxyethylene sorbitol Fatty acid ester, polyoxyethylene castor oil, hydrogenated castor oil derivative, polyoxyethylene lanolin derivative, block polymer containing aliphatic alkyl group, polyoxyethylene fatty acid amide, polyoxyethylene alkylamine, alkanolamide, alkylamine oxide, alkylpoly Nonionic surfactant represented by glucoside, alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, fatty acid amidoamine salt, cationic interface represented by ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium, dicocoylethylhydroxyethylmonium methosulfate Activators.
[0024]
Avocado oil, almond oil, olive oil, grape seed oil, evening primrose oil, camellia oil, sasanqua oil, macadamia nut oil, medofoam oil, shea butter, egg yolk oil, oils such as horse fat, jojoba oil, carnauba wax, candelilla wax , Lanolin, waxes such as beeswax, ozokerite, liquid paraffin, hydrocarbons such as squalene, petrolatum, isostearyl alcohol, octyldodecanol, lanolin alcohol, phytosterols, cetanol, higher alcohols such as oleyl alcohol, isopropyl myristate, isopropyl myristate, Ethyl oleate, octyl stearate, cetyl 2-ethylhexanoate, isononyl isononanoate, octyl palmitate, ethylene glycol dioleate, glyceryl triisostearate, cetyl lactate, adipate Ester oils such as diisopropyl acid, cholesteryl isostearate, etc., polyhydric alcohols such as propylene glycol, dipropylene glycol, polypropylene glycol, polyethylene glycol, glycerin, diglycerin, isoprene glycol, 1,3-butylene glycol, ethyl alcohol, isopropanol Such as lower alcohols, natural polymers such as xanthan gum, guar gum, and starch, and derivatives thereof, hydroxypropylmethylcellulose, hydroxyethylcellulose, cellulose polymers such as methylcellulose, synthetic polymers such as carboxyvinyl polymers and polyvinylpyrrolidone, and ethylene distearate. Pearling agents such as glycol, triethylene glycol distearate, kaolin, silicic anhydride, aluminum silicate Magnesium, talc, mica, cellulose powder, silk powder, starch, polyethylene powder, nylon powder, pigments such as cross-linked polystyrene, preservatives, sequestering agents, propellants, inorganic salts, organic acids and salts thereof, pyrrolidone carboxylic acid And its salts, hyaluronic acid and its salts, saccharides such as sorbitol, maltitol and trehalose, humectants such as trimethylglycine, benzalkonium chloride, benzethonium chloride, isopropylmethylphenol, pyrocton olamine, clara extract, zinc pyrithione, hinokitiol Fungicides, etc., assembly extract, capronium chloride, cepharanthin, salicylic acid, inosit, garlic iodide extract, resorcin, estradiol, ethinyl estradiol, oxendrone, pantothenic acid and its derivatives Body, placenta extract, biotin, mononitroguaiacol, photosensitizer 301, bovine hematin, dipotassium glycyrrhizinate, pyridoxine hydrochloride, cooling sensation, warming sensation, animal and plant extracts, vitamins, ultraviolet absorbers, amino acids and their derivatives, proteins and their Derivatives, antioxidants, coloring agents, fragrances and the like.
[0025]
【Example】
Next, the present invention will be described in more detail with reference to Examples and Comparative Examples, but needless to say, the present invention is not limited to these. Unless otherwise specified, [%] indicates [% by weight].
A hair shampoo was prepared by a conventional method using the following hair shampoo basic formula and the compositions shown in Tables 1 to 3. For each of the adjusted hair shampoos, foaming during use, fingering during rinsing, unity and smoothness of hair after drying were evaluated by the following standard by 10 specialized panels, and the total of 10 persons for each item was evaluated. The values and overall evaluation are shown in the table.
[0026]
[Table 1]
[Table 2]
[Table 3]
As shown in the results of Tables 1 to 3, the hair shampoos of the examples of the present invention have higher foaming power and conditioning properties (finger rinsing, hair lump after drying and smoothness as compared with the comparative examples). ) Was excellent.
Hereinafter, Examples 19 to 25 were produced by a conventional method.
[0032]
[0039]
【The invention's effect】
According to the present invention, by blending an anionic surfactant and / or an amphoteric surfactant with a 1% aqueous solution of a cationized tara gum having a viscosity of 500 to 3000 mPa · s, the foaming power and the conditioning property are excellent. A cleaning composition can be provided.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002375905A JP2004203801A (en) | 2002-12-26 | 2002-12-26 | Cleanser composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002375905A JP2004203801A (en) | 2002-12-26 | 2002-12-26 | Cleanser composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2004203801A true JP2004203801A (en) | 2004-07-22 |
Family
ID=32813495
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002375905A Pending JP2004203801A (en) | 2002-12-26 | 2002-12-26 | Cleanser composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2004203801A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006328325A (en) * | 2005-05-30 | 2006-12-07 | Dai Ichi Kogyo Seiyaku Co Ltd | Detergent composition, and washing agent and cosmetic using the same |
| JP2008001685A (en) * | 2006-05-22 | 2008-01-10 | Kao Corp | Aqueous hair cleanser |
| JP2008001684A (en) * | 2006-05-22 | 2008-01-10 | Kao Corp | Aqueous hair cleanser |
| WO2008029516A1 (en) * | 2006-09-08 | 2008-03-13 | Kao Corporation | Skin or hair cleanser composition |
| JP2008156472A (en) * | 2006-12-22 | 2008-07-10 | Soft99 Corporation | Foam cleaner composition, cleaner, cleaning method, and foam quality improver for foam cleaner |
| WO2008143136A1 (en) * | 2007-05-15 | 2008-11-27 | Nippon Starch Chemical Co., Ltd. | Cleansing preparation containing trehalose octenylsuccinic acid ester salt composition |
| US7947258B2 (en) | 2006-05-22 | 2011-05-24 | Kao Corporation | Aqueous hair cleansing agent |
| JP2011132244A (en) * | 2009-12-23 | 2011-07-07 | L'oreal Sa | Cosmetic composition including at least one organosilicon compound, at least one anionic surfactant, and at least one cationic polymer |
| US20110218326A1 (en) * | 2010-03-03 | 2011-09-08 | Zen-U Biotechnology Co., Ltd. | Plant-protein product and method for preparing the same |
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2002
- 2002-12-26 JP JP2002375905A patent/JP2004203801A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006328325A (en) * | 2005-05-30 | 2006-12-07 | Dai Ichi Kogyo Seiyaku Co Ltd | Detergent composition, and washing agent and cosmetic using the same |
| JP2008001685A (en) * | 2006-05-22 | 2008-01-10 | Kao Corp | Aqueous hair cleanser |
| JP2008001684A (en) * | 2006-05-22 | 2008-01-10 | Kao Corp | Aqueous hair cleanser |
| US7947258B2 (en) | 2006-05-22 | 2011-05-24 | Kao Corporation | Aqueous hair cleansing agent |
| US8039425B2 (en) | 2006-09-08 | 2011-10-18 | Kao Corporation | Skin or hair cleanser composition comprising an alkoxylated C8-C10 alcohol and a siloxane |
| WO2008029516A1 (en) * | 2006-09-08 | 2008-03-13 | Kao Corporation | Skin or hair cleanser composition |
| JP2008063294A (en) * | 2006-09-08 | 2008-03-21 | Kao Corp | Cleaning composition for skin or hair |
| KR101388271B1 (en) * | 2006-09-08 | 2014-04-22 | 카오카부시키가이샤 | Skin or hair cleanser composition |
| EP2062567A4 (en) * | 2006-09-08 | 2013-03-13 | Kao Corp | CLEANING COMPOSITION FOR SKIN OR HAIR |
| JP2008156472A (en) * | 2006-12-22 | 2008-07-10 | Soft99 Corporation | Foam cleaner composition, cleaner, cleaning method, and foam quality improver for foam cleaner |
| WO2008143136A1 (en) * | 2007-05-15 | 2008-11-27 | Nippon Starch Chemical Co., Ltd. | Cleansing preparation containing trehalose octenylsuccinic acid ester salt composition |
| JP5427033B2 (en) * | 2007-05-15 | 2014-02-26 | 日澱化學株式会社 | Detergent composition containing octenyl succinic acid trehalose ester salt composition |
| JP2011132244A (en) * | 2009-12-23 | 2011-07-07 | L'oreal Sa | Cosmetic composition including at least one organosilicon compound, at least one anionic surfactant, and at least one cationic polymer |
| US20110218326A1 (en) * | 2010-03-03 | 2011-09-08 | Zen-U Biotechnology Co., Ltd. | Plant-protein product and method for preparing the same |
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