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JP2004176592A - Apparatus and method for purifying exhaust gas of engine - Google Patents

Apparatus and method for purifying exhaust gas of engine Download PDF

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Publication number
JP2004176592A
JP2004176592A JP2002342247A JP2002342247A JP2004176592A JP 2004176592 A JP2004176592 A JP 2004176592A JP 2002342247 A JP2002342247 A JP 2002342247A JP 2002342247 A JP2002342247 A JP 2002342247A JP 2004176592 A JP2004176592 A JP 2004176592A
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JP
Japan
Prior art keywords
catalyst
exhaust gas
electric heater
exhaust
engine
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Pending
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JP2002342247A
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Japanese (ja)
Inventor
Tatsuya Sugimoto
達哉 杉本
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Toyota Industries Corp
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Toyota Industries Corp
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Application filed by Toyota Industries Corp filed Critical Toyota Industries Corp
Priority to JP2002342247A priority Critical patent/JP2004176592A/en
Priority to DE10351520A priority patent/DE10351520B4/en
Priority to FR0313816A priority patent/FR2847618B1/en
Publication of JP2004176592A publication Critical patent/JP2004176592A/en
Pending legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2839Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
    • F01N3/2853Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration using mats or gaskets between catalyst body and housing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2006Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating
    • F01N3/2013Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating using electric or magnetic heating means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2839Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
    • F01N3/2853Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration using mats or gaskets between catalyst body and housing
    • F01N3/2864Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration using mats or gaskets between catalyst body and housing the mats or gaskets comprising two or more insulation layers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Processes For Solid Components From Exhaust (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a technique for holding an electric heater which can stably and rationally hold the electric heater disposed in an exhaust passage in an apparatus for purifying the exhaust gas of an engine having the electric heater for raising catalytic bed temperature. <P>SOLUTION: The apparatus for purifying the exhaust gas of an engine purifies the exhaust gas exhausted from the engine. The catalyst 13 for purifying the exhaust gas is disposed in a catalyst containing case 11. The catalyst 13 for purifying the exhaust gas is supported by a catalyst supporting mat 15 interposed between the surface of the inner wall in the case and the outer peripheral surface of the filter of the catalyst 13 for purifying the exhaust gas. The electric heater 17 is built in this catalyst supporting mat 15 so as to raise the catalytic bed temperature, thereby stably holding the electric heater 17. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は、エンジンから排出される排気ガスを排気浄化用触媒によって浄化処理する排気浄化処理技術に関し、詳しくは触媒床温度を活性温度に保持するために備えられる電熱ヒータの保持技術に関する。
【0002】
【従来の技術】
従来、エンジン、特にディーゼルエンジンにおいて、酸化触媒や三元触媒のような排気浄化用触媒を主体に構成される排気浄化装置を排気通路に設置し、エンジンから排出される排気ガス中の有害成分を浄化処理することが行われている。排気浄化用触媒には、活性温度があり、排気ガス温度が活性温度よりも低いときは、排気ガスの浄化作用が有効に実現されない。この点を考慮して、排気浄化用触媒の周囲に電熱ヒータを配置し、エンジンの運転状態に応じて電熱ヒータを制御することで触媒床温度を活性温度に保持するように構成した排気浄化装置が提案されている(例えば、特許文献1参照。)。
【0003】
【特許文献1】
特開平6−33747号公報(段落番号(0023)、図1参照)
【0004】
【発明が解決しようとする課題】
上述した従来の浄化装置によれば、電熱ヒータの加熱作用によって触媒床温度を活性温度まで高め、エンジンの運転状態の如何に拘わらず、排気浄化用触媒を活性化して浄化作用を向上することができる。しかしながら、電熱ヒータを排気通路内に保持する構造に関しては好適な提案がなされていない。
【0005】
本発明は、上述した従来の問題点に鑑みてなされたものであり、その目的とするところは、触媒床温度を昇温させるための電熱ヒータを有するエンジンの排気浄化装置において、排気通路内に配置される電熱ヒータを安定かつ合理的に保持することが可能な電熱ヒータの保持技術を提供することにある。
【0006】
【課題を解決するための手段】
上記課題を達成するため、本発明に係るエンジンの排気浄化装置は、特許請求の範囲の請求項1〜4に記載の通りに構成される。なお、これら各請求項に係る発明は、排気通路に配置された排気浄化用触媒と、排気通路の内壁面と排気浄化用触媒の外周面との間に配置されて該排気浄化用触媒を支持する触媒支持マットと、排気浄化用触媒の触媒床温度を昇温させる電熱ヒータとを備えたエンジンの排気浄化装置において、排気通路内に配置される電熱ヒータを安定かつ合理的に保持することができるようにした技術である。
【0007】
一般に、排気浄化用触媒は、排気通路の一部を構成する触媒収容ケース内に配置される。そして、触媒収容ケースの内壁面と排気浄化用触媒の外周面との間に介在される触媒支持マットによって支持されている。触媒支持マットは耐熱性、熱膨張性、柔軟性等の性状を有することが好ましく、ケース内壁面と触媒外周面との間の隙間を塞ぎ排気ガスが隙間を通って流出することを防止している。排気浄化用触媒は、例えばハニカム状のフィルター内に排気ガスの浄化機能を有する貴金属を担持することで構成される。
請求項1に記載のエンジンの排気浄化装置では、排気浄化用触媒の構成部材であるフィルターの外周を触媒支持マットが取り巻いて支持していることに着目し、電熱ヒータを触媒支持マット内に組み込むことによって電熱ヒータを保持する構成としている。
したがって、請求項1の発明によれば、触媒支持マットに組み込まれた電熱ヒータで排気浄化用触媒を加熱あるいは保温できるため、始動直後の低温時や排気ガス温度が活性温度まで上昇しないような運転状態であっても、触媒床温度を活性温度まで昇温あるいは保持することができる。そして、電熱ヒータは、触媒支持マットに組み込む構成のため、安定した状態に保持することができるし、例えば排気浄化用触媒と触媒支持マットとの間に電熱ヒータを配置するような構成に比べると、排気通路内のスペースを狭めることがなく、しかも電熱ヒータが存在することで排気浄化用触媒や触媒支持マットの組付け性が損なわれるといった問題も生じない。
【0008】
なお、電熱ヒータの触媒支持マットへの組み込みは、例えば請求項2に記載したように、触媒支持マットを少なくとも2枚のマット材を重ね合わせた積層構造とし、電熱ヒータをマット材間に挟み込むことで保持する構成とすることが好ましい。このような構成を採用すれば、触媒支持マットに対する電熱ヒータの組付け作業性を向上することができる。
【0009】
請求項3に記載のエンジンの排気浄化装置では、排気通路内温度を検出する温度検出手段と、温度検出手段による検出温度に基づいて電熱ヒータに対する通電と通電の中止を制御する制御手段とを備えている。制御手段は、例えば温度検出手段による検出温度が活性温度以下のときには、電熱ヒータに通電させ、検出温度が活性温度以上のときには、電熱ヒータに対する通電を中止するといった形態の制御を行うように構成される。これにより、電熱ヒータに対する通電と中止が繰り返されることで排気浄化用触媒の触媒床温度が活性温度まで高められあるいは保持される。その結果、排気浄化用触媒が活性化され、排気ガスを効果的に浄化処理することができる。
【0010】
なお、排気浄化用触媒は、セラミック製のフィルターに触媒作用を有する貴金属を担持した構成とすることが好ましい(請求項4に対応する。)。また、電熱ヒータは、PTCヒータであることが好ましい(請求項5に対応する。)。
ここで、PTCヒータは、通電によって自己発熱し、その熱で抵抗値が増大して発熱量はさらに増大するが、温度上昇により抵抗値の増大率は減少し、やがて所定の上限温度(発熱量)にて一定の抵抗値となる抵抗素子である。したがって、上限温度として触媒が活性化する活性温度を設定することにより、簡単な構成で低コストの加熱手段を提供することができる。
【0011】
フォークリフトのような産業車両の場合、作業形態の関係で、エンジンを高速回転で連続運転するという使われ方が少なく、排気ガス温度が排気浄化用触媒の活性温度まで上昇しないことが多い。このため、請求項6に記載したように、産業車両のエンジンに適用した場合においては、たとえ、排気バス温度が活性温度まで上昇しないような運転状態で使われたとしても、排気ガスの浄化処理を効果的に行うことができる。
【0012】
請求項7に記載の発明によれば、触媒支持マット内に電熱ヒータを組み込み、排気通路内の排気ガス温度に基づいて電熱ヒータに対する通電と通電の中止を制御することにより、排気浄化用触媒の触媒床温度を活性温度まで高めあるいは保持して排気ガスを合理的に浄化処理することが可能なエンジンの排気浄化方法を提供することができる。
【0013】
【発明の実施の形態】
以下、本発明の実施の形態を図面に基づいて説明する。本実施の形態は、例えばフォークリフトのような産業車両に搭載されているエンジン、特にディーゼルエンジンの排気浄化装置に適用される。図1は本実施の形態に係るエンジンの排気浄化装置を示している。
本実施の形態に係る排気浄化装置10は、ディーゼルエンジンの排気マニホールドに接続される排気通路の下流側、例えば消音器の中に組み込む形態で設けられる。排気浄化装置10は、触媒収容ケース(容器)11と、排気浄化用触媒13と、触媒支持マット15と、電熱ヒータ17とを備えている。
【0014】
触媒収容ケース11は、排気通路の一部を構成するものであり、排気ガスの入口と出口を有する中空状に形成され、その内部に排気浄化用触媒13が配置されている。図には排気ガスの流れ方向が矢印によって示されている。排気浄化用触媒13は、例えばハニカム状に形成されたセラミック製のフィルターに、触媒作用を有する白金、パラジウム等の貴金属を担持した構成であり、触媒支持マット15を介して触媒収容ケース11に支持されている。
触媒支持マット15は、耐熱性、熱膨張性、柔軟性等の性質を有し、排気浄化用触媒13のフィルター外周面のほぼ全面に巻き付いた状態で配置されて排気浄化用触媒13を支持する。すなわち、触媒支持マット15は、触媒収容ケース11の内壁面と排気浄化用触媒13の外周面との間の空間を詰める形態で介在されて排気浄化用触媒13を支持する。したがって、触媒支持マット15は、排気ガスが触媒収容ケース11の内壁面と排気浄化用触媒13の外周面との間を通って下流側へ流出することを防止するシール機能と、フィルターと触媒収容ケース11との直接の接触を回避してセラミック製フィルターの割れを防止する触媒保護機能とを有している。
【0015】
触媒加熱手段としての電熱ヒータ17は、触媒支持マット15の内部全体にわたって組み込まれている。したがって、図示の如く触媒支持マット15が、排気ガスの流れ方向において、排気浄化用触媒13のほぼ全長にわたって介在されているとき、電熱ヒータ17を構成する電熱線(ニクロム線)は、排気ガスの流れ方向に沿う方向に、例えば蛇行状に組み込まれている。すなわち、電熱ヒータ17は、排気浄化用触媒13をガス流れ方向の全体にわたって均一に加熱することができるように配置されている。そして、電熱線の一端にはプラス側のヒータ電極17aが接続され、電熱線の他端にはマイナス側のヒータ電極17bが接続される。また、プラス側のヒータ電極17aは、リレースイッチ19を介してバッテリー21に接続され、マイナス側のヒータ電極17bはボデーアースされている。
なお、電熱ヒータ17の触媒支持マット15内部への組み込みは、例えば図2に示すように、薄板状の2枚のマット材15a,15bを重ね合わせて積層構造の触媒支持マット15を形成する構成とし、そのマット材15a,15bを重ね合わせる際に、合わせ面に電熱線をサンドイッチ状に挟み込むことで安定した保持構造のヒータ付き触媒支持マット15を提供することができる。
【0016】
また、排気浄化装置10は、イグニッションスイッチ23と、排気ガス温度を検出する温度センサ25と、イグニッションスイッチ23および温度センサ25の出力に基づいて電熱ヒータ17に対する通電を制御する電子制御装置27(以下、ECUという)とを有している。温度センサ25は、触媒収容ケース11に取り付けられ、排気浄化用触媒13を通過した直後の排気ガスの温度を検出する。ECU27は、温度センサ25により検出される排気ガス温度が排気浄化用触媒13の活性温度(例えば、300℃)以下であれば、リレースイッチ19をオン状態にし、電熱ヒータ17に通電し、検出温度が活性温度(例えば、300℃)以上であれば、リレースイッチ19をオフ状態にして電熱ヒータ17に対する通電を中止するように構成されている。上記の温度センサ25が本発明でいう温度検出手段に対応し、ECU27が本発明でいう制御手段に対応する。
【0017】
本実施の形態に係るエンジンの排気浄化装置10は、上記のように構成したものである。したがって、イグニッションスイッチ23がオン状態にされてエンジンが始動されると、ECU27は、温度センサ25で検出される排気ガス温度が触媒の活性温度に達するまで、リレースイッチ19をオン状態に保持する。このため、電熱ヒータ17に通電されて排気浄化用触媒13が加熱され、触媒床温度が昇温される。一方、温度センサ25で検出される排気ガス温度が触媒の活性温度に達すると、リレースイッチ19がオフ状態となり、電熱ヒータ17に対する通電が中止される。すなわち、本実施の形態によれば、触媒の活性温度を基準値として、排気ガス温度の変動に基づき電熱ヒータ17に対する通電と通電の中止を繰り返すことによって、排気浄化用触媒13の触媒床温度が活性温度に保持されるように加熱あるいは保温する。このことにより、排気浄化用触媒13が活性化され、排気ガスの浄化作用を向上することができる。
【0018】
ところで、フォークリフトのような産業車両をはじめとする特殊自動車の中には、エンジン付近に排気浄化装置を設置するためのスペースを確保することが車両構造上困難な場合が多々あり、エンジンから離れた位置、例えば消音器の中に触媒を組み込んで装着するといった形態での搭載を余儀なくされている。このため、排気ガスが排気浄化装置に流入するまでの間に冷却されてしまい、十分に熱を利用できないといった傾向にある。また、フォークリフトの場合、作業形態の関係からアイドリングでの長時間放置、始動、停止の繰り返しといった使い方で運転されることが多い。このような場合、排気ガス温度が触媒の活性温度まで上昇しないことがある。本実施の形態によれば、電熱ヒータ17を備えることによって排気浄化用触媒13を加熱しあるいは保温して触媒床温度を活性温度に確保し、エンジンの運転状態の如何に拘わらず、安定した触媒の浄化作用を得ることができる。
【0019】
また、本実施の形態では、触媒支持マット15内に電熱ヒータ17を組み込む構成のため、例えば排気浄化用触媒13のフィルター外周面に電熱ヒータ17を直接取り付けるような場合に比べると、電熱ヒータ17の組付けスペースを容易に確保することができる。また、触媒支持マット15内に電熱ヒータ17を組み込む構成とすることにより、触媒収容ケース11に対する排気浄化用触媒13および触媒支持マット15の組付けに先だって、電熱ヒータ17を触媒支持マット15内に組付けて置くことができる。このことにより、電熱ヒータ17が存在することが原因となって排気浄化用触媒13および触媒支持マット15の触媒収容ケース11内への組付け性が損なわれるといった問題も生じない。
また、図2に示すように、2枚のマット材15a,15bを重ね合わせて積層構造の触媒支持マット15を構成するときは、両マット材15a,15b間に電熱ヒータ17を挟み込むことによってヒータ付き触媒支持マット15を簡単に得ることができる。
【0020】
なお、本発明は上述した実施の形態に限定されるものではなく、その要旨を逸脱しない範囲内で適宜変更することが可能である。
例えば、上述した実施の形態では、電熱ヒータ17として電熱線(ニクロム線)を用いたが、これに代えてPTCヒータを用いてもよい。PTCヒータは、通電によって自己発熱し、その熱で抵抗値が増大して発熱量はさらに増大するが、温度上昇により抵抗値の増大率は減少し、やがて所定の上限温度(発熱量)にて一定の抵抗値となる、いわゆる自己温度制御機能を有する抵抗素子である。したがって、PTCヒータの上限温度として触媒が活性化する活性温度を設定することことにより、自己温度制御機能を利用して排気浄化用触媒13を加熱あるいは保温することができる。これにより、実施の形態で説明したECU27、温度センサ25、リレースイッチ19を廃止できるため、簡単な構成で低コストの触媒加熱手段を提供することができる。
また、上述した実施の形態では、フォークリフトに搭載されるディーゼルエンジンに適用する場合で説明しているが、車両の種類やエンジンの種類については限定するものではない。
また、電熱ヒータ17の触媒支持マット15への組み付けについては、2枚のマット材15a,15bによる挟着構造に限られるものではない。触媒支持マット15を、例えば成形型を用いて成形するような場合であれば、電熱ヒータ17をインサート成形することで触媒支持マット15に組付けることも可能である。その場合、図3に示すように、電熱ヒータ17を構成する電熱線の外表面がマット表面から一部露出するような形で成形し、触媒収容ケース11内への組付け時において電熱線の露出部分が排気浄化用触媒13のフィルター外面に直接接触する構成としてもよい。
また、排気浄化用触媒13は、フィルターがセラミック製であるとしたが、金属製のフィルターであってもよい。
【0021】
【発明の効果】
以上詳述したように、本発明によれば、触媒床温度を昇温させるための電熱ヒータを有するエンジンの排気浄化用装置において、排気通路内に配置される電熱ヒータを安定かつ合理的に保持することが可能なヒータ保持技術を提供することができる。
【図面の簡単な説明】
【図1】本実施の形態に係るエンジンの排気浄化装置を示す図面である。
【図2】電熱ヒータの触媒支持マットへの組付け構造を説明する図面である。
【図3】電熱ヒータの触媒支持マットへの組付け構造の変更例を示す図面である。
【符号の説明】
10 排気浄化装置
11 触媒収容ケース(排気通路)
13 排気浄化用触媒
15 触媒支持マット
17 電熱ヒータ
25 温度センサ(温度検出手段)
27 電子制御装置(制御手段)
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to an exhaust gas purifying technique for purifying exhaust gas discharged from an engine with an exhaust gas purifying catalyst, and more particularly to a technique for holding an electric heater provided to maintain a catalyst bed temperature at an active temperature.
[0002]
[Prior art]
2. Description of the Related Art Conventionally, in an engine, particularly a diesel engine, an exhaust purification device mainly including an exhaust purification catalyst such as an oxidation catalyst or a three-way catalyst is installed in an exhaust passage, and harmful components in exhaust gas exhausted from the engine are removed. Purification processing has been performed. The exhaust gas purifying catalyst has an active temperature, and when the exhaust gas temperature is lower than the active temperature, the exhaust gas purifying action is not effectively realized. In consideration of this point, an exhaust heating device is arranged around the exhaust gas purifying catalyst, and controls the electric heater according to the operating state of the engine to maintain the catalyst bed temperature at the active temperature. Has been proposed (for example, see Patent Document 1).
[0003]
[Patent Document 1]
JP-A-6-33747 (paragraph number (0023), see FIG. 1)
[0004]
[Problems to be solved by the invention]
According to the conventional purification device described above, the catalyst bed temperature is raised to the activation temperature by the heating action of the electric heater, and the exhaust purification catalyst is activated regardless of the operating state of the engine to improve the purification action. it can. However, no suitable proposal has been made for a structure for holding the electric heater in the exhaust passage.
[0005]
The present invention has been made in view of the above-described conventional problems, and an object of the present invention is to provide an exhaust gas purifying apparatus for an engine having an electric heater for raising the temperature of a catalyst bed. An object of the present invention is to provide an electric heater holding technique capable of stably and rationally holding an electric heater to be arranged.
[0006]
[Means for Solving the Problems]
In order to achieve the above object, an exhaust gas purification device for an engine according to the present invention is configured as described in claims 1 to 4 of the claims. It should be noted that the invention according to each of these claims is characterized in that the exhaust purification catalyst is disposed in the exhaust passage, and the exhaust purification catalyst is disposed between the inner wall surface of the exhaust passage and the outer peripheral surface of the exhaust purification catalyst. In an exhaust gas purifying apparatus for an engine including a catalyst supporting mat that performs heating and an electric heater that raises a catalyst bed temperature of an exhaust gas purifying catalyst, it is possible to stably and rationally maintain an electric heater disposed in an exhaust passage. It is a technology that we can do.
[0007]
Generally, the exhaust gas purifying catalyst is disposed in a catalyst housing case that forms a part of an exhaust passage. And it is supported by a catalyst support mat interposed between the inner wall surface of the catalyst housing case and the outer peripheral surface of the exhaust gas purifying catalyst. The catalyst support mat preferably has properties such as heat resistance, thermal expansion properties, and flexibility, and closes the gap between the inner wall surface of the case and the outer peripheral surface of the catalyst to prevent exhaust gas from flowing out through the gap. I have. The exhaust gas purifying catalyst is configured by, for example, carrying a noble metal having a function of purifying exhaust gas in a honeycomb filter.
In the exhaust gas purifying apparatus for an engine according to the first aspect, focusing on the fact that the catalyst support mat surrounds and supports the outer periphery of the filter which is a component of the exhaust gas purification catalyst, the electric heater is incorporated in the catalyst support mat. Thus, the electric heater is held.
Therefore, according to the first aspect of the present invention, the exhaust gas purifying catalyst can be heated or kept warm by the electric heater incorporated in the catalyst supporting mat, so that the operation is performed at a low temperature immediately after the start or the exhaust gas temperature does not rise to the activation temperature. Even in this state, the catalyst bed temperature can be raised or maintained at the activation temperature. Since the electric heater is configured to be incorporated in the catalyst support mat, it can be maintained in a stable state. Compared with a configuration in which the electric heater is disposed between the exhaust purification catalyst and the catalyst support mat, for example, In addition, the space in the exhaust passage is not narrowed, and the presence of the electric heater does not cause a problem that the assemblability of the exhaust purification catalyst and the catalyst supporting mat is impaired.
[0008]
In addition, as for the incorporation of the electric heater into the catalyst supporting mat, for example, as described in claim 2, the catalyst supporting mat has a laminated structure in which at least two mat members are overlapped, and the electric heater is sandwiched between the mat members. It is preferable to adopt a configuration in which the holding is performed. By employing such a configuration, the workability of assembling the electric heater to the catalyst supporting mat can be improved.
[0009]
According to a third aspect of the present invention, there is provided an exhaust gas purifying apparatus for an engine, comprising: temperature detecting means for detecting the temperature in the exhaust passage; and control means for controlling energization of the electric heater and interruption of energization based on the temperature detected by the temperature detecting means. ing. The control unit is configured to perform control such as energizing the electric heater when the temperature detected by the temperature detecting unit is equal to or lower than the activation temperature, and stopping energizing the electric heater when the detected temperature is equal to or higher than the activation temperature. You. As a result, the energization and suspension of the electric heater are repeated, so that the catalyst bed temperature of the exhaust gas purifying catalyst is raised or maintained at the activation temperature. As a result, the exhaust purification catalyst is activated, and the exhaust gas can be effectively purified.
[0010]
The exhaust gas purifying catalyst preferably has a structure in which a noble metal having a catalytic action is supported on a ceramic filter (corresponding to claim 4). Further, the electric heater is preferably a PTC heater (corresponding to claim 5).
Here, the PTC heater self-generates heat by energization, and the heat increases the resistance value to further increase the calorific value. However, the rate of increase in the resistance value decreases due to the temperature rise, and eventually the predetermined upper limit temperature (heat value) ) Is a resistance element having a constant resistance value. Therefore, by setting the activation temperature at which the catalyst is activated as the upper limit temperature, a low-cost heating means with a simple configuration can be provided.
[0011]
In the case of an industrial vehicle such as a forklift, it is rarely used that the engine is continuously operated at a high speed because of the working form, and the exhaust gas temperature does not often rise to the activation temperature of the exhaust purification catalyst. Therefore, when applied to an engine of an industrial vehicle as described in claim 6, even if the exhaust bus is used in an operation state in which the exhaust bus temperature does not rise to the activation temperature, the exhaust gas purification processing is performed. Can be performed effectively.
[0012]
According to the seventh aspect of the present invention, an electric heater is incorporated in the catalyst support mat and energization of the electric heater and stop of energization are controlled based on the temperature of the exhaust gas in the exhaust passage. It is possible to provide an exhaust gas purification method for an engine that can raise or maintain the catalyst bed temperature to the activation temperature and rationally purify the exhaust gas.
[0013]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, embodiments of the present invention will be described with reference to the drawings. The present embodiment is applied to an engine mounted on an industrial vehicle such as a forklift, in particular, to an exhaust purification device of a diesel engine. FIG. 1 shows an exhaust gas purifying apparatus for an engine according to the present embodiment.
The exhaust gas purification apparatus 10 according to the present embodiment is provided in a form that is incorporated in a downstream side of an exhaust passage connected to an exhaust manifold of a diesel engine, for example, in a muffler. The exhaust gas purification device 10 includes a catalyst housing case (container) 11, an exhaust gas purification catalyst 13, a catalyst support mat 15, and an electric heater 17.
[0014]
The catalyst accommodating case 11 forms a part of an exhaust passage, is formed in a hollow shape having an inlet and an outlet for exhaust gas, and has an exhaust purification catalyst 13 disposed therein. In the figure, the flow direction of the exhaust gas is indicated by arrows. The exhaust purification catalyst 13 has a configuration in which a noble metal such as platinum or palladium having a catalytic action is supported on a ceramic filter formed in a honeycomb shape, for example, and is supported on the catalyst housing case 11 via a catalyst support mat 15. Have been.
The catalyst support mat 15 has properties such as heat resistance, thermal expansion properties, and flexibility, and is disposed so as to be wound around almost the entire outer peripheral surface of the filter of the exhaust purification catalyst 13 to support the exhaust purification catalyst 13. . In other words, the catalyst support mat 15 supports the exhaust purification catalyst 13 by being interposed so as to fill the space between the inner wall surface of the catalyst housing case 11 and the outer peripheral surface of the exhaust purification catalyst 13. Therefore, the catalyst supporting mat 15 has a sealing function for preventing exhaust gas from flowing downstream between the inner wall surface of the catalyst accommodating case 11 and the outer peripheral surface of the exhaust gas purifying catalyst 13, and a filter and a catalyst accommodating member. It has a catalyst protection function for preventing direct contact with the case 11 to prevent cracking of the ceramic filter.
[0015]
The electric heater 17 as a catalyst heating means is incorporated over the entire inside of the catalyst support mat 15. Therefore, as shown in the drawing, when the catalyst supporting mat 15 is interposed over substantially the entire length of the exhaust gas purifying catalyst 13 in the flow direction of the exhaust gas, the heating wire (Nichrome wire) constituting the electric heater 17 becomes the exhaust gas. It is integrated in a direction along the flow direction, for example, in a meandering shape. That is, the electric heater 17 is arranged so as to uniformly heat the exhaust purification catalyst 13 over the entire gas flow direction. One end of the heating wire is connected to the heater electrode 17a on the plus side, and the other end of the heating wire is connected to the heater electrode 17b on the minus side. The heater electrode 17a on the plus side is connected to the battery 21 via the relay switch 19, and the heater electrode 17b on the minus side is body-grounded.
In addition, as shown in FIG. 2, for example, the electric heater 17 is incorporated into the inside of the catalyst support mat 15 by laminating two sheet-like mat members 15a and 15b to form the catalyst support mat 15 having a laminated structure. When the mat members 15a and 15b are overlapped, the heating wire is sandwiched between the mating surfaces so that the catalyst supporting mat 15 with a heater having a stable holding structure can be provided.
[0016]
Further, the exhaust gas purification device 10 includes an ignition switch 23, a temperature sensor 25 for detecting exhaust gas temperature, and an electronic control device 27 (hereinafter referred to as an electronic control device 27) for controlling energization to the electric heater 17 based on the outputs of the ignition switch 23 and the temperature sensor 25. , ECU). The temperature sensor 25 is attached to the catalyst housing case 11 and detects the temperature of the exhaust gas immediately after passing through the exhaust purification catalyst 13. If the temperature of the exhaust gas detected by the temperature sensor 25 is equal to or lower than the activation temperature of the exhaust purification catalyst 13 (for example, 300 ° C.), the ECU 27 turns on the relay switch 19, energizes the electric heater 17, and detects the detected temperature. If the temperature is equal to or higher than the activation temperature (for example, 300 ° C.), the relay switch 19 is turned off to stop energizing the electric heater 17. The above-mentioned temperature sensor 25 corresponds to the temperature detecting means according to the present invention, and the ECU 27 corresponds to the control means according to the present invention.
[0017]
The engine exhaust purification device 10 according to the present embodiment is configured as described above. Therefore, when the ignition switch 23 is turned on and the engine is started, the ECU 27 keeps the relay switch 19 on until the exhaust gas temperature detected by the temperature sensor 25 reaches the activation temperature of the catalyst. For this reason, the electric heater 17 is energized to heat the exhaust purification catalyst 13, and the catalyst bed temperature is raised. On the other hand, when the exhaust gas temperature detected by the temperature sensor 25 reaches the activation temperature of the catalyst, the relay switch 19 is turned off, and the power supply to the electric heater 17 is stopped. That is, according to the present embodiment, the activation and de-energization of the electric heater 17 are repeated based on the fluctuation of the exhaust gas temperature with the activation temperature of the catalyst as the reference value, whereby the catalyst bed temperature of the exhaust purification catalyst 13 is reduced. Heat or keep the temperature at the activation temperature. As a result, the exhaust purification catalyst 13 is activated, and the action of purifying the exhaust gas can be improved.
[0018]
By the way, among special vehicles such as industrial vehicles such as forklifts, it is often difficult to secure a space for installing an exhaust gas purification device near an engine due to the structure of the vehicle. It is indispensable to mount the catalyst in a position, for example, by mounting the catalyst in a muffler. For this reason, there is a tendency that the exhaust gas is cooled before flowing into the exhaust gas purification device, and the heat cannot be sufficiently utilized. Further, in the case of a forklift, it is often operated in a manner of being left idle for a long time, repeatedly starting and stopping, because of the work form. In such a case, the exhaust gas temperature may not rise to the activation temperature of the catalyst. According to the present embodiment, by providing the electric heater 17, the exhaust purification catalyst 13 is heated or kept warm to secure the catalyst bed temperature at the activation temperature, and a stable catalyst is obtained regardless of the operating state of the engine. Purifying action can be obtained.
[0019]
Further, in the present embodiment, since the electric heater 17 is incorporated in the catalyst support mat 15, the electric heater 17 is directly attached to the outer peripheral surface of the filter of the exhaust purification catalyst 13, for example. Can be easily secured. In addition, by incorporating the electric heater 17 in the catalyst support mat 15, the electric heater 17 is placed in the catalyst support mat 15 before the exhaust purification catalyst 13 and the catalyst support mat 15 are attached to the catalyst housing case 11. You can put it together. Thus, there is no problem that the presence of the electric heater 17 impairs the assemblability of the exhaust purification catalyst 13 and the catalyst support mat 15 into the catalyst housing case 11.
As shown in FIG. 2, when the two mat members 15a and 15b are overlapped to form the catalyst supporting mat 15 having a laminated structure, the electric heater 17 is sandwiched between the two mat members 15a and 15b. The attached catalyst support mat 15 can be easily obtained.
[0020]
Note that the present invention is not limited to the above-described embodiment, and can be appropriately changed without departing from the gist of the present invention.
For example, in the above-described embodiment, a heating wire (Nichrome wire) is used as the heating heater 17, but a PTC heater may be used instead. The PTC heater self-generates heat when energized, and the heat increases the resistance value to further increase the calorific value. However, the rate of increase in the resistance value decreases due to the temperature rise, and eventually the PTC heater at a predetermined upper limit temperature (calorific value). The resistance element has a constant resistance value and has a so-called self-temperature control function. Therefore, by setting the activation temperature at which the catalyst is activated as the upper limit temperature of the PTC heater, the exhaust purification catalyst 13 can be heated or kept warm using the self-temperature control function. Thus, the ECU 27, the temperature sensor 25, and the relay switch 19 described in the embodiment can be eliminated, so that a low-cost catalyst heating means with a simple configuration can be provided.
Further, in the above-described embodiment, the case where the invention is applied to a diesel engine mounted on a forklift is described, but the type of vehicle and the type of engine are not limited.
Further, the assembling of the electric heater 17 to the catalyst supporting mat 15 is not limited to the sandwiching structure between the two mat members 15a and 15b. If the catalyst support mat 15 is molded using a mold, for example, the electric heater 17 can be assembled to the catalyst support mat 15 by insert molding. In this case, as shown in FIG. 3, the heating wire forming the heating heater 17 is formed so that the outer surface thereof is partially exposed from the mat surface, and the heating wire is assembled at the time of assembling into the catalyst housing case 11. The exposed portion may be configured to directly contact the outer surface of the filter of the exhaust purification catalyst 13.
In the exhaust purification catalyst 13, the filter is made of ceramic, but may be a metal filter.
[0021]
【The invention's effect】
As described in detail above, according to the present invention, in an exhaust gas purifying apparatus for an engine having an electric heater for raising the catalyst bed temperature, the electric heater arranged in the exhaust passage is stably and rationally held. It is possible to provide a heater holding technique capable of performing the following.
[Brief description of the drawings]
FIG. 1 is a drawing showing an engine exhaust purification device according to an embodiment.
FIG. 2 is a diagram illustrating a structure for assembling an electric heater to a catalyst support mat.
FIG. 3 is a view showing a modified example of an assembling structure of an electric heater to a catalyst supporting mat.
[Explanation of symbols]
10 Exhaust gas purification device 11 Catalyst storage case (exhaust passage)
13 Exhaust gas purification catalyst 15 Catalyst support mat 17 Electric heater 25 Temperature sensor (temperature detecting means)
27 Electronic control unit (control means)

Claims (7)

排気通路に配置された排気浄化用触媒と、前記排気通路の内壁面と前記排気浄化用触媒の外周面との間に配置されて該排気浄化用触媒を支持する触媒支持マットと、前記排気浄化用触媒の触媒床温度を昇温させる電熱ヒータとを備えたエンジンの排気浄化装置であって、
前記触媒支持マット内に前記電熱ヒータが組み込まれていることを特徴とするエンジンの排気浄化装置。
An exhaust purification catalyst disposed in an exhaust passage; a catalyst support mat disposed between an inner wall surface of the exhaust passage and an outer peripheral surface of the exhaust purification catalyst to support the exhaust purification catalyst; An exhaust gas purification device for an engine, comprising: an electric heater for raising a catalyst bed temperature of a catalyst for use in an engine.
An exhaust gas purification device for an engine, wherein the electric heater is incorporated in the catalyst support mat.
請求項1に記載のエンジンの排気浄化装置であって、前記触媒支持マットは、少なくとも2枚のマット材を重ね合わせた積層構造とされ、前記電熱ヒータがマット材間に挟持されて保持されていることを特徴とするエンジンの排気浄化装置。2. The exhaust gas purifying apparatus for an engine according to claim 1, wherein the catalyst support mat has a laminated structure in which at least two mat members are overlapped, and the electric heater is held and held between the mat members. 3. An exhaust gas purification device for an engine. 請求項1または2に記載のエンジンの排気浄化装置であって、前記排気通路内温度を検出する温度検出手段と、前記温度検出手段による検出温度に基づいて前記電熱ヒータに対する通電と通電の中止を制御する制御手段とを備えていることを特徴とするエンジンの排気浄化装置。3. The exhaust gas purifying apparatus for an engine according to claim 1, wherein the temperature detecting unit detects the temperature in the exhaust passage, and energizing and discontinuing energizing the electric heater based on the temperature detected by the temperature detecting unit. 4. An exhaust gas purification device for an engine, comprising: control means for controlling the exhaust gas. 請求項1〜3のいずれかに記載のエンジンの排気浄化装置であって、前記排気浄化用触媒は、セラミック製のフィルターに触媒作用を有する貴金属を担持した構成であることを特徴とするエンジンの排気浄化装置。The exhaust gas purifying apparatus according to any one of claims 1 to 3, wherein the exhaust gas purifying catalyst has a structure in which a noble metal having a catalytic action is supported on a ceramic filter. Exhaust gas purification device. 請求項1〜4のいずれかに記載のエンジンの排気浄化装置であって、前記電熱ヒータがPTCヒータであることを特徴とするエンジンの排気浄化装置。The exhaust gas purification device for an engine according to any one of claims 1 to 4, wherein the electric heater is a PTC heater. 請求項1〜5のいずれかに記載のエンジンの排気浄化装置であって、前記エンジンが、産業車両のエンジンであることを特徴とするエンジンの排気浄化装置。The exhaust gas purification device for an engine according to any one of claims 1 to 5, wherein the engine is an engine of an industrial vehicle. 排気通路に配置された排気浄化用触媒と、前記排気通路の内壁面と前記排気浄化用触媒の外周面との間に配置されて該排気浄化用触媒を支持する触媒支持マットと、前記排気浄化用触媒の触媒床温度を昇温させる電熱ヒータとを備えたエンジンの排気浄化方法であって、
前記触媒支持マット内に前記電熱ヒータを組み込み、前記排気通路内に配置された温度検出手段による検出温度が所定値以下のときには、前記電熱ヒータに通電させるステップと、検出温度が所定値以上のときには電熱ヒータに対する通電を中止するステップとを繰り返すことにより前記排気浄化用触媒の触媒床温度を活性温度に保持して排気ガスを浄化処理することを特徴とするエンジンの排気浄化方法。
An exhaust purification catalyst disposed in an exhaust passage; a catalyst support mat disposed between an inner wall surface of the exhaust passage and an outer peripheral surface of the exhaust purification catalyst to support the exhaust purification catalyst; An electric heater for raising the catalyst bed temperature of the catalyst for exhaust gas, comprising:
Incorporating the electric heater in the catalyst support mat, energizing the electric heater when the temperature detected by the temperature detecting means arranged in the exhaust passage is equal to or lower than a predetermined value, and when the detected temperature is equal to or higher than the predetermined value. Repeating the step of stopping the energization of the electric heater to maintain the catalyst bed temperature of the exhaust purification catalyst at an active temperature to purify the exhaust gas.
JP2002342247A 2002-11-26 2002-11-26 Apparatus and method for purifying exhaust gas of engine Pending JP2004176592A (en)

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FR0313816A FR2847618B1 (en) 2002-11-26 2003-11-25 EXHAUST GAS PURIFICATION APPARATUS AND EXHAUST GAS PURIFICATION METHOD FOR AN ENGINE

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