JP2003517882A - Disposable articles including perforated laminated webs - Google Patents

Abstract

(57) SUMMARY Disposable articles suitable for multiple uses are disclosed. The article comprises a perforated laminated web including a first extensible web having a first degree of elongation to break, and a second extensible web connected to the first extensible web at a plurality of bonding sites. Wherein the second extensible web has a second degree of elongation to break. A third web material is disposed between the first and second nonwoven fabrics, and the third web material has an elongation to third break less than the elongation to both first and second breaks. Having. In a further embodiment, the perforated laminated web of the article includes a third and a non-woven web disposed between the first and second extensible webs and the first and second nonwoven webs connected at a discontinuous bond site. Material. The first and second nonwoven webs are in liquid communication through the holes and are identifiable regions distinguished by at least one property selected from the group consisting of basis weight, fiber orientation, thickness, and density. Having.

Description

Detailed Description of the Invention       [0001]     [Industrial applications]   FIELD OF THE INVENTION The present invention relates to a disposable article including a multi-layer laminated web having holes and a beneficial component.
It       [0002]     [Problems to be Solved by the Invention]   Laminated web formed by connecting separate webs in a layered relationship
Disposable articles containing are well known for various applications. For example, laminated non-woven fabric
Webs are disposable absorbent articles (eg diapers, adult incontinence products), cleaning products.
It is often used for polishing and polishing products. Additional bulk or softness to web components
Nonwovens and nonwoven laminates are also used to provide the properties. Similarly, the film
/ Film laminated web combines various film features in a layered relationship
Profit can be provided by doing. Laminated webs are also called composite webs
be able to.       [0003]   Examples of less common laminates include laminates of different materials.
Materials may differ in mechanical tension properties, thermal properties or visual / tactile properties
Yes. For example, by connecting a non-woven fabric to a relatively stiff fabric, the fabric feels like a soft surface.
The same may be provided. Different elements depending on fusion bonding, adhesive bonding, ultrasonic bonding, etc.
You may connect materials. The bonding method is often decided by the material itself, but the bonding
Agent bonding is often required. For example, laminated or composite materials with significantly different melting properties
May require an adhesive layer between the layers of the laminate. Non-woven materials and thermoplastic fibers
Undesirable delamination, even for materials with similar melting properties, such as rum material
It is often tied with an adhesive as a suitable bond to prevent This processing method is
, Can be expensive with the addition of adhesive, depending on the level of adhesive added.
The resulting laminate is often relatively stiff.       [0004]   Perforated laminated webs can be made by methods in the art. Non-woven
One of the useful ways to perforate a fabric web is, for example, commonly sold rice.
National Patent No. 5,916,661 (issued June 29, 1999, Benson
) Et al.). This patent describes, for example, at least one layer of meltblown
Less bonded to a web, bonded card web, or other suitable material
Both teach laminate materials having one layer of spunbonded web. Or
The apertured web is useful as a topsheet for disposable absorbent products. However
However, Benson's 661 has a completely different material (eg, different
Perforated laminate containing materials from different material classes or materials with different material properties)
I'm not teaching Web.       [0005]   As mentioned above, nonwoven webs are used in diapers, incontinence briefs, and training pads.
As disposable absorbent products such as sanitary products and feminine sanitary products, as well as disposable wet towels.
Of personal care cleaning products such as all or substantial dry wipes
It is beneficial in. Nonwovens are also used for disposable clothing, surgical products (eg, comforters).
, Surgical clothing, etc.), durable clothing, automobile parts, car care products, upholstered chairs, filtration
Media, household care products (eg polishing wipes, dust removal wipes
Goods etc.) and other components of other goods such as consumer goods or goods.
There is also. Nonwoven fabrics used in these and other applications have a wide range of
Benefits from visual and tactile properties. However, when used alone
, Single-layer non-woven fabrics have limited known manufacturing methods, especially compared to woven or knitted fabrics
A range of useful properties, including visual, tactile, strength surface or absorption properties
Is limited.       [0006]   Therefore, it can be used up containing laminated webs with component webs of different material properties.
It is desirable to have all the articles.   Therefore, a laminated web formed by joining constituent layers without adhesive
It is desirable to obtain a disposable article containing.   In addition, visually identifiable areas that give a cloth-like or knit-like appearance and feel
It would be desirable to have a disposable article containing a perforated laminated web to obtain.       [0007]     [Means for Solving the Problems]   Disposable items:   a) A laminated web having a plurality of holes, wherein the laminated web is:     1) a first stretchable web having a first degree of elongation to break;     2) A second stretchable web that joins the first stretchable web at a plurality of bond sites.
A second extensible web having a second degree of elongation to break; and     3) a third web material disposed between the first web and the second web
Therefore, a third elongation less than the elongations up to the first and second fractures is used.
Including the third web having;   b) Includes a beneficial ingredient disposed adjacent to the laminated web.       [0008]   In another embodiment, the first and second junctions join at multiple distinct binding sites.
Has a stretchable web and a third material disposed between the first and second nonwoven webs.
A perforated laminated web is disclosed. The first and second non-woven webs are through holes
In liquid communication and selected from the group consisting of basis weight, fiber orientation, thickness, and density
It has identifiable regions that are distinguished by at least one characteristic.       [0009]   The specification concludes with claims, which particularly point out and distinctly claim the invention.
However, the present invention is not limited to the accompanying specification in which the components are also given the same reference numbers.
In addition, it will be better understood by the following drawings.       [0010]   As used herein, the term "absorbent article" is a liquid (e.g., water, crease).
Hands that absorb and contain leaning agents, conditioners, brighteners, body exudates)
It means a step. In a particular example, the phrase absorbs the various exudates that are expelled from the body.
A device that is placed against or near the body of the wearer to contain and contain.
In another example, the phrase remains until the consumer uses the article for its intended purpose.
An article that has the ability to absorb and retain beneficial components.       [0011]   The term "disposable" is used herein to wash or otherwise restore
Not intended to be reused or reused many times (ie, preferably 25 times
After use, more preferably about 10 times, and even more preferably about 5 times.
Intended to dispose of them after use, and most preferably after about a single use
Used to describe the articles of the present invention. Such disposable articles are environmentally friendly
It is preferably recycled in a combined manner, composted or otherwise treated.
Good "Integral" disposable items are separated by separate holders or liners.
Together to form a complete set so that no operating parts are required
A disposable article formed from separate parts that are united together.       [0012]   As used herein, the term "nonwoven web" is internally superposed.
However, it has a structure of individual fibers or threads that is not in any regular or repeating manner
Refers to the web. Nonwoven webs have been used in the past, for example, in meltblown processes,
By various methods such as spunbonding process and bonded card web process
Has been formed.       [0013]   As used herein, the term "fibril" is greater than about 100 microns.
Refers to small diameter fibers having a non-average diameter.       [0014]   As used herein, the term "meltblown fiber" refers to a plurality of microscopic
, Usually circular, melted thermoplastic material melted through a mold capillary tube or filament
Element is formed by extruding into a high-speed air stream (for example, air),
This thins the melted filament of thermoplastic material to reduce its diameter,
A fiber that may be the diameter of a microfiber. Therefore, meltblown fibers are high speed
Carried by a stream of air, deposited on the surface to be sampled and dispersed randomly
Forming a web of unwoven fiber.       [0015]   As used herein, the term "spunbond fiber" refers to a plurality of spinnerets.
Melted heat from a capillary with a small, usually round, extruded filament diameter of
Extruding a plastic material as a filament and then rapidly shrinking it by drawing
A small diameter fiber formed by.       [0016]   As used herein, the term "polymer" generally refers to homopolymers,
For example, copolymers such as block, graft, random and alternating copolymers.
, Terpolymers, etc., and mixtures and modifications thereof.
Not limited. Further, unless otherwise limited, the term "polymer" refers to the material
It must include all possible geometric arrangements. In such an arrangement,
These include isotactic, syndiotactic and random symmetry.
Not limited.       [0017]   As used herein, the term "retractable" refers to the application of a biased force.
Elastic, that is, at least about 60 percent (ie, pull
At least about 160 of relaxed, unbiased length as opposed to stretched and biased length
Percent) Stretchable, stretch, less stretch when released
Any material that recovers at least 55 percent. At least one hypothetical example
． Extendable to 60 inches and when extended to 1.60 inches and released 1.
1 inch sample material returning to a length of no more than 27 inches. Multiple telescopic
Material exceeds 60 percent (ie 160 percent of the loosened length
(Extremely over)), e.g. 100% or more
, Many of such materials substantially return to their original relaxed length, for example stretched
If the force is loosened, it returns to within 105 percent of the originally loosened length.       [0018]   As used herein, the term "non-stretchable" refers to "stretchable" above.
Any material that does not fall within the definition of.   As used herein, the term "stretchable" means that when a biased force is applied.
In this case, it can be stretched by at least about 50 percent without experiencing catastrophic failure.
Refers to all materials.   The article of the present invention comprises the following essential ingredients.       [0019]Laminated web   As shown in FIG. 1, the laminated web 10 of the article of the present invention has a face-to-face layered structure.
It comprises at least three layers, webs or piles arranged in relation. Layers are books
It should be thin enough to be processed as described in the specification, but the actual thickness
(Ie calipers) are quite limited. First outer layer and second outer layer 2
0 and 40 are respectively a first extensible web having a first degree of elongation to break and
Known as a second stretchable web having a second degree of elongation to break. Outside the second
The layer preferably comprises the same material as the first outer layer, but may be a different material. Few
At least one third central layer 30 is disposed between the two outer layers. Laminated web 1
0 is a layer which is a component which is processed by the thermal calendering method described below.
Serves to combine layers 20, 30 and 40 to form a single web
, Provides a plurality of fusion binding sites 50. The laminated web 10 is mainly a non-woven web
And laminated with the composite material, but in principle the laminated web 10 is
Any web that meets the requirements (eg, fusion properties, stretchability) as indicated
It can also be made from materials. For example, the constituent layers are film, microporous
Examples of the film include a film and a perforated film.       [0020]   Preferably, the first and second outer layers are non-woven fabrics. Suitable for the first and second outer layers
Suitable non-woven materials include cellulosics, sponges (ie, natural and synthetic bilayers).
), Molded films, stuffed cotton, and combinations thereof.
I can't. Preferably, the first and second outer layers are each a cellulosic non-woven fabric.
Shaped film, wadding, foam, sponge, reticulated foam, vacuum-formed laminate, screen
And a material selected from the group consisting of combinations thereof.       [0021]   The first and second layers may include various natural and synthetic fibers or materials.
. As used herein, "natural" means that the material is a plant, animal, insect, or plant, animal or animal.
It means that it is derived from a product and an insect by-product. Conventional basic starting materials are usually
Fibers, including fibers of any common synthetic or natural woven length, or combinations thereof.
It is a web of textiles.       [0022]   Non-limiting examples of natural materials useful in the layers of laminated webs include silk fibers.
, Keratin fibers, and cellulosic fibers, but are not limited thereto.
Non-limiting examples of keratin fibers include the group consisting of wool fibers, camel fibers, etc.
What is selected is. Non-limiting examples of cellulosic fibers include wood
Wood pulp fiber, cotton fiber, hemp fiber, jute fiber, flax fiber, and combinations thereof
One selected from the group consisting of: In the present invention, cellulose
Fiber materials are preferred.       [0023]   Non-limiting examples of synthetic materials useful in the layers of laminated webs include acetate
Fiber, acrylic fiber, cellulose ester fiber, acrylic fiber, polyamide fiber
Fiber, polyester fiber, polyolefin fiber, polyvinyl alcohol fiber, ray
Yong fiber, polyethylene foam, polyurethane foam, and combinations thereof
One selected from the group consisting of: Examples of suitable synthetic materials include acrylics.
Acrylic products such as orchid, cress orchid and acrylonitrile fiber, auron
; Cellulose, such as cellulose acetate, arnell and acele
Ester fiber; and nylon (for example, nylon 6, nylon 66, nylon 61)
Polyamides such as 0; etc.); fault rails, codels, and polyethylene teref
Polyester like Talate Fiber, Polybutylene Terephthalate Fiber, Dacron
Polyolefins such as polypropylene and polyethylene; polyvinyl acetate
Fiber; polyurethane foam and combinations thereof. Key from them
Such and other suitable fibers and non-woven fabrics made are generally Riedel (
Riedel), "Methods and Materials for Nonwoven Bonding," The World of Nonwovens (1987); Amelie
Ka Encyclopedia Americana Vol. 11, pp. 147-153
And 26, pages 566-581 (1984); U.S. Pat. No. 4,891,891.
227 (Thaman et al., Issued Jan. 2, 1990); and US Pat.
, 891,228, which is incorporated herein by reference in its entirety.
Be done.       [0024]   Nonwoven fabrics made from natural materials are fine wires made from a liquid suspension of fibers.
It consists of the most commonly formed fabric or sheet on a clean. References
Which is incorporated herein by reference in its entirety. A. Hampel et al. (CA Hampel
) The Encyclopedia of Chemistry, Third Edition, 1973, 793.
~ 795 (1973); The Encyclopedia Ameri
cana) 21: 376-383 (1984); A. Smooth
(Smook), Pulp and Paper Technology Handbook, Pulp and Paper Industry Association (
1986).       [0025]   Nonwovens of natural materials useful in the laminated web of the present invention are available from a wide variety of commercial sources.
You can hand it. Examples of suitable commercially available paper layers useful herein include James Li
Commercially available from James River, Green Bay, Wisconsin
Embossed, dry formed cellulosic having a basis weight of about 71 gsy
Compound layer Airtex (registered trademark), and WalkieSoft U. S. A.
(Walkisoft U.S.A.) (Mount Holly, NC)
Embossed, dry formed cellulos having a basis weight of about 75 gsy commercially available from
Examples include the alkionic compound Walkisoft (registered trademark).
Is not limited to       [0026]   Additional suitable non-woven materials include US Pat. No. 4,447,294 (1984).
Issued May 8, Osborn; No. 4,603,176 (1986).
July 29, 2013, Bjorkquist); No. 4,981,55
No. 7 (issued January 1, 1991, Bjorkquist); No. 5,
Issue 085, 736 (published February 4, 1992, Bjorkquist)
); No. 5,138,002 (issued August 8, 1992, Bujolquist (
Bjorkquist)); No. 5,262,007 (issued November 16, 1993, F
No. 5,264,082 (issued November 23, 1993, Phan et al.).
Phan et al .; No. 4,637,859 (issued January 20, 1987,
Trokhan; 4,529,480 (June 16, 1985)
Published by Trokhan; No. 4,687,153 (August 1987).
Issued 18th, McNeil; No. 5,223,096 (1993)
Issued June 29, 2014, Phan et al. And No. 5,679,222 (199).
Issued October 21, 1995, Rasch et al .; No. 5,628,097 (
Benson et al., Issued May 13, 1997; No. 5,916,661.
No. and No. 5,658,639 (both issued June 29, 1999, Benson
(Benson) et al.) But are not limited to:
Which is incorporated herein by reference in its entirety.       [0027]   Methods of making non-woven fabrics are well known in the art. Generally, these nonwovens are
Dry layer formation, wet layer formation, melt blow molding, coforming, spunbond, or
Can be created by carding methods, and in these methods,
First, cut fibers or filaments from long ones to the desired length and pass them in a stream of water or air.
After that, it is deposited on a screen through which air or water containing fibers is passed. Done
The layers form a self-supporting web, regardless of production or composition.
A few bonding processes to keep the individual fibers together so that
Both receive one process. In the present invention, air entanglement, hydroentanglement, thermal coupling, and
Non-woven fabrics can be formed by various processes including, but not limited to, combinations of such processes.
A layer containing can be prepared.       [0028]   The third core layer, which is less stretchable, may also be a non-woven fabric as described above.
Moreover, the central layer 30 itself need not be thermally compatible with the outer layers. Central layer 30
Need not be further melt processable. For example, paper, tissue,
Cellulosic materials such as paper towels and paper napkins; metal materials such as metal foils
Woven or knitted materials such as cotton or rayon blends; or polyester or
It can be a thermosetting material such as an aromatic polyamide film. Central layer 30
Is another non-woven having suitable properties for processing into a perforated layer
You can If the central layer 30 has a melting point, it is at least about 20 ° C. higher than the outer layer
Is preferred. However, the central layer 30 need not have a melting point,
It suffices to simply soften at the temperature of the calendering method required for joining. Metal hoi
In certain core layer materials such as
Absent.       [0029]   One of the unexpected advantages of the present invention is the selection of the central layer 30 located between the two outer layers.
It is a discovery that new web characteristics can be demonstrated by choice. Preferably
, The material of the central layer is cellulosic material, thermoplastic cotton, metal foil, metal cotton,
It is selected from the group consisting of sponges, molded films, and combinations thereof. center
Suitable materials for the layers may include those discussed above. However, the center
The layer has a third degree of breakage less than both the first and second outer layers.
is important. The wide range of materials that can be used as the central layer is due to the structure of the present invention.
Bringing incredible variety, each beneficially applied to a wide variety of end uses
It For example, if an outer layer of non-woven fabric is used with a central layer of metal foil,
The laminate is a flexible, soft, formable metallic web that can be folded and
It is relatively quiet when it is rolled, rolled, or otherwise deformed.
Such materials can be used, for example, in applications requiring electrostatic shielding. Tit
If a center layer of supaper is used, the resulting laminate will be soft and bulky.
It is an expropriation web. Such a laminate is suitable for use as, for example, a wiping tool.
is there. In addition, the laminated web 10 is formed without a thermoplastic adhesive to ensure durability.
It is possible to obtain clothing-like characteristics. Until such a stack can no longer be used
Can be washed many times.       [0030]   As shown in FIG. 2, the central layer 30 has the following web-constituting layers of the laminated web 10.
The interface 5 between the two materials of the fusion bond site 50 when processed as detailed below.
At 2 the fusion bond site 5 is provided so that the first layer 20 can be fusion bonded directly to the second outer layer.
The areas of the central layer 30 are chosen to be separated in the region of zero. Bound to theory
Not shearing, cutting or otherwise breaking the central layer
And the material of the central layer must be sufficiently replaced to allow thermal bonding of the two outer layers.
And facilitate such separation of the central layer 30. Therefore, the thermal bond site region 50
The central layer 30 is relatively low so that it can be "squeezed" from the
Such cuts such as high extensibility, relatively high fracture resistance, or relatively high deformability.
It should be selected to have properties that allow it to open.       [0031]   Without being bound by theory, one achieves the bonding of the layers of the laminated web and subsequently forms the holes therein.
Narrow width dimension W by the point calendering by the heat described below to make
And it is believed that thermal bond sites with high aspect ratio should be formed.
For example, FIG. 3 has a narrow width dimension W and a high aspect ratio, ie, length L is width W.
A fusion region of a single fusion bond site 50 much larger than is shown. Length L is appropriate
Of the binding site (see below).
The ridges used to form the
Cutting, shearing or otherwise severing layer 30 in the area of the mating site
Narrow enough to allow Width W is about 0.003 inch and 0.020 inch
However, in a preferred embodiment, it is between about 0.005 inch and 0.
It is between 010 inches and may be adjusted by the properties of layer 30. Preferred fruit
In an embodiment, the outer layer is bonded without pores, but the central layer is voided after bonding.
Only the layer 30 is divided as described above. However, used to form the binding site
The raised ridges penetrate all layers, 20, 30, 40 at some or all binding sites.
Cutting, shearing, splitting, or otherwise forming an opening
May be preferable for the end use requirements of       [0032]   It is considered that the aspect ratio may be as low as about 3 (that is, the L / W ratio is equal to 3/1).
Has been. It may be between about 4 and 20. In a preferred embodiment
Has an aspect ratio of about 10. The aspect ratio of the fusion bond site 50 is as described below.
Limited only by the corresponding aspect ratio of the point bond ridges of the calendering roller
It       [0033]   In a preferred embodiment, each binding portion directionally corresponding to the longitudinal direction of the binding site 50.
The vertical axis of the order is regularly arranged and generally faces the direction of the machine, that is, the MD shown in FIG.
Repeat the pattern you had. However, the binding sites are regularly arranged and the machine crosses
Repeats a randomly oriented pattern of directions, or a mixture of cross and machine directions
. For example, the binding sites 50 can be arranged in a “sugi pattern” pattern.
.       [0034]   Another advantage of the present invention is that the heat-bonded laminated web described above melts.
The binding site 50 is elongated or stretched in a generally diagonal direction relative to the longitudinal axis, l.
Obtained when The melt bond at the melt bond site 50 is a web at the bond site.
Tends to make weak spots locally. Therefore, the vertical axis 1 of the binding site 50 is
As a portion of the web 10 is stretched in a diagonal direction to the
The material loses tension and a hole is formed. Relative height and width of fusion bond site 50
The ratio allows relatively large pores to be formed on full extension. product
When the layer web 10 is pulled uniformly, the result is a pattern of melt bond sites 50.
A regular pattern of a plurality of holes 60 corresponding to a cone is obtained.       [0035]   FIG. 4 illustrates a partial cutaway surface of a perforated laminated web useful in the present invention.
There is. As shown, each cut in the plan view is partially cropped.
You can see the layers or folds. The laminated web 10 shown in FIG. 4 was thermally bonded.
The laminate is oriented diagonally to the longitudinal axis of the fusion bond site, in this case crossing the machine.
Direction, CD, and then manufactured. Relative, as shown
As the weak binding site loses tension, the formerly melted binding site 50,
A hole 60 is created. As also shown, the center layer 30 is dependent on the material properties of the center layer 30.
Dependent, it generally remains uniformly distributed in the stack.       [0036]   When the holes 60 are formed, the heat-bonded portions of the layers 20, 30, 40 are primarily
Remains at the periphery of the hole corresponding to the length dimension of the binding site 50. Servant
Therefore, each hole 60 is not a heat-bonding material all around, but as shown by 62 in FIG.
A small portion remains bound. One of the beneficial properties of such laminated webs is
The perforation is to facilitate fluid communication with the central layer. Therefore, two
An absorbent central layer 30 may be used between the relatively non-absorbent outer layers of the
The layer body 10 should be an absorbent wipe that has a relatively dry feel to the outer surface.
You can       [0037]   FIG. 5 is a schematic view of the cross section shown in FIG. Laminated, as shown
When the body is stretched in the T direction, holes 60 form.       [0038]   In certain preferred embodiments, the laminated web comprises from about 10% to about 20% of the surface area.
It is characterized by having a surface area that is a "perforated area". Used here
The "perforated area" is the amount of material needed to cover a particular area.
As minimized due to web stretching that occurs after stretch / ring roll
It means that the web is perforated or contains holes. More preferably,
The perforated area of the web is about 11% to about 17%.       [0039]   Another of the inventive articles derived when the laminated web is stretched with reference to FIG.
The benefit of is that the central layer 30, which has a weaker fracture extensibility than the two outer layers, has either outer layer
Loss of tension with less stretchability. Therefore, the laminate has a fusion bond site.
The outer layers 20 and 40 when stretched generally diagonally with respect to the longitudinal axis l of 50
Extend to form pores. However, it has a weaker fracture extensibility than the outer layer
After stretching, the core layer 30 also extends over the non-perforated areas of the laminated web 10 such that the center layer 30 extends.
It breaks with sufficient elongation so that it is not evenly distributed.       [0040]   Of an embodiment of a web having a central layer that has a weaker stretch extensibility than the two outer layers.
One example is the partial cutaway shown in FIG. Partial cut
Ripping allows you to see each layer or fold in the plan view. Shown
As such, after stretching, the central layer 30 will fragment and form discontinuous regions of the central layer material.
. Such discontinuities are separated relatively evenly as in the row shown in FIG.
May be woven or depending on the pattern of fusion bond sites 50 and the extension method employed.
However, the distribution may be relatively random. A structure similar to that shown in FIG.
One example of web 10 having is a relatively low stretch tissue paper.
Is a web having a non-woven outer layer that is relatively extensible with a central layer of.       [0041]   The surprising benefits of the laminated web structure described in FIG. 6 are basis weight, thickness, density, and
Distinguished by at least one property selected from the group consisting of combinations thereof
Presence of identifiable areas in the non-perforated portion of the web. Crossing of Figure 7
As shown in the plane, several such areas are distinguished. In a preferred embodiment, the area
Are visually distinctive and have an aesthetically pleasing appearance on the laminated web and the articles of the invention.
And feel particularly useful. The area can also be a garment-like layer on the laminate.
May give a knitted texture.       [0042]   Referring to FIG. 7, several structurally identifiable regions are shown in the cross section shown.
Is determined. The area indicated by 64 corresponds to the hole 60. In the non-perforated areas of the web
The area 66 is an area including the central layer 30 and having a relatively high basis weight. Area 68 is medium
The core layer 30 is broken and separated, i.e. no longer completely present,
1 represents a portion of a laminated web that forms a relatively low basis weight area of a hood 10. In general,
The higher the basis weight, the higher the density, and the higher the density.
You don't have to. For example, forming multiple density areas in addition to multiple basis weight areas
Therefore, an embossing process after stretching can be applied. High basis weight or high density
Differences in any of the areas can be identified by simply rubbing between the fingers.
There are many.       [0043]   Generally having parallel rows of fusion bond sites 50 extending in the machine direction MD,
Generally parallel rows of holes when stretched correspondingly, and lower than the outer layer
For a laminated web 10 having a central layer with break extensibility, the resulting stretched
, The perforated laminated web 10 has a machine direction MD, such as area 68 in FIGS. 6 and 7.
Are characterized by generally low basis weight, low density regions between the pores at. Similarly,
The web 10 is adjacent to the machine direction CD, eg, in area 66 of FIG.
It features relatively high basis weight, dense areas between rows of holes. Center layer material 30 and
And possible operations after lamination, for example by selecting the embossing process, the laminated web
The thickness of the can be varied as well, with thicker regions generally corresponding to higher density regions.
Hit       [0044]   Another embodiment of a laminated web useful in the present invention is where the outer layers are oriented in the direction of the fibers.
Utilizing non-woven webs when featuring distinguishable areas that are differentiated by
Is. Gives a limited area in the web that undergoes greater stretching than other areas
By doing so, the orientation of the fibers can be differentiated. For example, area 6 in FIG.
Locally pulling the web 10 more strongly in the area corresponding to 8
Results in the formation of significantly reoriented regions of fibers. Such local pulling
Is possible by the method of the invention described below.       [0045]   FIG. 8 shows a region 6 where the fibers have been stretched to form pores and locally stretched to reorient the fibers.
9 is a photomicrograph showing a magnified detailed web of the invention that produced No. 8. Seen in Figure 8
Stretches a portion of the web locally to a greater extent than others
By doing so, the holes formed thereby can differ in size. Servant
Thus, the area generally designated as 70 in FIG. 8 is greater than the area designated by 72.
Undergoes even more strain (ie, local stretching). Therefore, in area 70
The pores are larger than those in area 72 and
The basis weight of the material is less than the basis weight of the nonwoven web material in region 70. Localized
In addition to the difference in basis weight due to strain discrimination, the laminated web of the present invention has fibers reoriented.
The identified identifiable region 68 can also be shown. In such areas, the fibers are
It reorients from a general random direction to a dominant direction in the stretch direction.       [0046]   To make the web 10 as seen in FIG. 6, the central layer 30 is provided with a number of different layers.
Any of the above materials may be used. For example, the outer layers 20 and 40 have relatively high damage
In the case of a stretchable nonwoven web, the central layer 30 is relatively
Paper, tissue paper, thermoplastic film, metal with relatively low breaking elongation
Can be foil, closed or open cell foam, or any other material
Yes. That the central layer is not relatively stretchable in the stretch direction to form the pores
The outer layer material may itself be different, subject only to the constraints.       [0047]   In addition, using more than one central layer 30 has beneficial results. example
For example, a cellulosic tissue core layer and an additional core layer including a polymeric film.
A laminated web having both central layers disposed between the first and second outer layers of nonwoven fabric,
, Manufacture absorbent wipes where one is relatively more absorbent than the other
be able to. If the central layer of the additional polymer film is a three-dimensional molded film
The film side has an added texture to the laminate, which is beneficial in multiple wipes
Can be given. Microscopically expanded three-dimensional suitable for use in the present invention
No. 3,929,135 (1), which is commonly assigned.
Thompson, December 30, 975, and US Pat.
42,314 (issued August 3, 1982, Radel et al.).
, Both of which are incorporated herein by reference.       [0048]   The central layer may be an elastomer, such as "a drop-resistant porous stretchable wafer.
Filed on March 14, 1997 by Curro et al.
As described in US patent application Ser. No. 08 / 816,106 assigned to
Microscopically Stretched and Vacuum Formed Three-Dimensional Elastomer Molded Film
, Which is incorporated herein by reference. Furthermore, the center
The layers are commonly assigned U.S. Patents, both of which are incorporated herein by reference.
No. 4,629,643 (issued December 16, 1986, Curro et al.)
And No. 4,609,518 (issued September 2, 1986, Claw et al.).
It can be a three-dimensional molded film having minute pores.       [0049]   The central layer is US Pat. No. 5,518,801, which is hereby incorporated by reference.
(Published May 21, 1996, Chappell et al.)
It can be a web material having a different stretchable network. Such web
Formed by embossing, for example by matching plates or rolls
Can be a structurally elastic rubber-like film (SELF).       [0050]   The center layer can be an absorbent, perforated cell foam web material. Oh
An absorbent foam that is particularly suitable for high performance absorbent articles such as diapers has a high internal phase emulsion.
(Hereinafter referred to as "HIPE"). For example, US Pat.
No. 60,345 (DesMarais et al., Issued November 9, 1993)
, And US Pat. No. 5,268,224 (December 7, 1993, Desmari
(DesMarais et al.), Hereby incorporated by reference.
. Such an absorbent HIPE foam is (a) ejected for subsequent containment.
Foam to absorb absorbed urine or other bodily fluids from the original shock zone
Relatively good wicking and liquid distribution characteristics for transfer to other areas of the structure; and
(B) With a relatively high liquid storage capacity under load, that is, under compressive force
It also provides desirable liquid handling properties, including relatively high storage capacity.       [0051]   The central layer 30 may further include an absorbent gelling material. For example, the laminate of the present invention
When the web is used as an absorbent wipe or a disposable absorbent article of the present invention
, Superabsorbents or hydrogel materials may provide good absorbency. True spirit
When used in textbooks, "hydrogels" absorb water-based liquids and absorb moderate pressure.
By an inorganic or organic compound capable of holding it under force. Good results
For, the hydrogel should be water insoluble. An example is like silica gel
Inorganic materials and organic compounds such as crosslinked polymers. Crosslinks are covalent bonds,
It may be an on bond, a van der Waals bond, or a hydrogen bond. Of polymer
Examples are polyacrylamide, polyvinyl alcohol, ethylene maleic anhydride.
Copolymer, polyvinyl ether, hydroxypropyl cellulose, carboxy
Methyl cellulose, polyvinyl pyridine, etc. are mentioned. A suitable gelling material is
Described below under "Optional Ingredients" for the personal care articles of the present invention. Shi
However, such gelling materials do not impair the intended use of the article, regardless of its intended use.
It should be understood that it may be utilized in each of the light articles.       [0052]   You can make webs from different materials without using adhesives for bonding
Thus, the structure of the laminated web is particularly useful in the assembly of the articles of the present invention. Multiple melting
The bond sites 50 are sufficient to hold the component webs together in the stack, and
Because of its laminated web, it behaves as a single web for advanced integrity and use.
, No unwanted delamination. However, some implementations and certain elements
For materials, where it is beneficial to apply an adhesive between at least two constituent layers.
There is a match.       [0053]   Method for manufacturing laminated web   Referring to FIG. 9, a method of manufacturing a laminated web of the article is schematically illustrated at 100.
It is explained.   A first relatively stretchable web 120 is unwound from the supply roll 104,
So that the feed roll 104 rotates in the direction indicated by the arrow associated with it
Go in the direction indicated by the arrow. Similarly, a second relatively extensible web
The sleeve 140 is rewound from the supply roll 105. The central layer 130 is also a supply layer.
It is pulled out from Le 107. Use three components (or more than one central layer)
In that case, more than one) is formed by the rollers 110 and 112.
It passes through the roll gap of the roller arrangement 108.       [0054]   Either outer layer is commonly assigned, both of which are incorporated herein by reference.
U.S. Pat. No. 4,629,643 (issued December 16, 1986, Claw (
Curro) et al., And No. 4,609,518 (issued September 2, 1986, Claw
Molding film such as a three-dimensional molded film having minute holes as described in
Can include Rum.       [0055]   In a preferred embodiment, both outer layers comprise non-woven material and may be the same.
The non-woven material may be prepared by a known method such as the known melt blown method or the known rotational bonding method.
It may be formed by a known non-woven extrusion method, first bonded onto a supply roll.
Pass directly through the roll gap 106 without being stored and / or stored
. However, in a preferred embodiment, the nonwoven web itself is
Above is a commercially available heat point-bonded web.       [0056]   If the third central layer is more extensible than both the first and second outer layers, then the non-woven fabric is
The outer layer of the web may be elastic or non-elastic. Nonwoven web is rotationally bonded
Melt-fusible, including web, meltblown web or bonded card web
It can be any web. The nonwoven web is a meltblown fiber web
If present, meltblown microfibers may be included. Nonwoven webs are, for example,
It may be made from fiber-forming polymers such as liolefins. Illustrative polio
One or more polypropylene, polyethylene, ethylene copolymer,
Propylene copolymers and butene copolymers are included. The nonwoven web is
Between about 10 and about 60 grams / square (gsm), and more preferably between about 15 and about
It can have a basis weight of 30 gsm.       [0057]   Each of the outer layers of the non-woven fabric may itself be, for example, a meltblown web, a bonded car.
D-web, or a few rotational connections to at least one layer of other suitable material
It may be a multi-layer material having at least one layer. For example, a nonwoven web is about
Spunbonded polyps having a basis weight of 0.2 to about 8 ounces per square yard
A first layer of ropylene, a melt having a basis weight of about 0.2 to about 4 ounces per square yard.
Layer of blown polypropylene and basis weight of about 0.2 to about 8 ounces per square yard
A multi-layer wafer having a second layer of spunbonded polypropylene having
It may be bubu. Alternatively, the nonwoven web may be from about 0.2 to about 10 ounces.
Spunbonded web having a basis weight of about s / square yard or from about 0.2 to about
Single piece of meltblown web-like material having a basis weight of 8 ounces / square yard
It may be a layer.       [0058]   The outer layer of the nonwoven web is a mixture or fibers of two or more different fibers.
And a composite of a mixture of particles. Such mixtures are mixed together
Fibers and other materials such as wood pulp, primary fibers and particles
Meltblown fibers or spin knots so that the fibers are intimately entangled before the fibers gather.
Shaped by adding fibers and / or particulate matter to the air stream in which the synthetic fibers are carried.
May be done.       [0059]   Prior to processing the laminated web as described herein, the fibers of each layer
The outer covers of the can be joined by bonding to form an interfering web structure.
Wear. Suitable bonding techniques include point calendering, hydroentanglement, and needling.
Such as, but not limited to, chemical bonding, ultrasonic bonding, and thermal bonding.       [0060]   With reference to FIGS. 9 and 10, the non-woven thermal bond roller arrangement 108 is preferably padded.
Includes a turned calendar roller 110 and a smooth anvil roll 112
Mu. Patterned calendar roller 110 and smooth anvil roll 11
One or both of the two may be heated to simultaneously place the central layer 30 at the bond site.
Alternatively, the desired temperature (if any) to melt bond the two outer layers at multiple binding sites.
) And pressure, the pressure between the two rollers can be adjusted by known means.
Good.       [0061]   The patterned calendar roller 110 has a circular cylindrical surface 114 and a front surface.
Constructed to have a plurality of ridges or pattern elements 116 extending from the surface 114 to the outer surface.
Is made. The ridges 116 have a predetermined pattern with each of the ridges 116 that make up the ridge.
Placed in turns, replacing the central layer 30 at fusion-bonding sites and
The two outer layers are arranged to be fusion bonded. The pattern of ridges is shown in FIG. Indication
As can be seen, the ridge 116 is between about 0.003 inch and 0.020 inch.
But a relatively small width of about 0.010 inches in the preferred embodiment,
Have a WP. The ridge has a length L of between about 0.030 inch and about 0.200 inch.
P, and in a preferred embodiment has a length of about 0.100 inches.
Have. In the preferred embodiment, the ridges have an aspect ratio of 10. Putter shown
Is a regular repeating pattern of alternating ridges, typically in rows, of approximately 0
． Row spacing between 010 inches and approximately 0.200 inches, separated by RS
Be done. In the preferred embodiment, the row spacing RS is about 0.060 inches. Prominent
The spacing allows the ridges to be spaced apart in the row, and PS is generally a ridge.
Is equal to the length LP of. However, the spacing and pattern will depend on the desired end product.
It can vary in different ways.       [0062]   As shown in FIG. 10, the patterned calendar roller 110 has a front surface.
It may have a repeating pattern of ridges 116 that extend over substantially the entire surface 114.
Alternatively, the ridges 116 extend around or over a portion of the surface 114.
You may. Similarly, the ridges 116 face a non-repeating pattern or random orientation.
It may be a repeating pattern of raised ridges.       [0063]   The ridges 116 preferably extend radially outward from the surface 114 and are rectangular or curved.
It is frustoconical in shape with a terminal elliptical final surface 117. This is the starting point
Although it is not intended to limit the extent of light to the ridges of this configuration only, see FIG.
As indicated above, the ridges also have a narrow width and a high vertical length at the terminal end surface 117.
It is believed that only a high aspect ratio of the fusion bond site 50 can be achieved if it has an aspect ratio.
Currently considered. Without being bound by theory, suitable for the terminal end surface 117
Other shapes include circles, squares, rectangles, etc.
It is considered to be not limited to these as long as it facilitates the connection and perforation of the web.
There is. The roller 110 is preferably such that all of the end surface 117 is roller 110.
Finished so that it is located inside a cylinder that is imaginary and rotates to the right, which is coaxial with the rotation axis of
Be done.       [0064]   The height of the ridges should be selected based on the thickness of the laminate to be bonded. In general
The height dimension of the calendering process is such that a proper bond occurs at the bond site.
It should be greater than the maximum thickness of the laminated web only between and at the bond sites.       [0065]   The anvil roller 112 is preferably a smooth surface and has a right hand steer.
It is a circular cylinder.       [0066]   After passing through the roller gap 106, the three (or more) component webs 120
, 130, and 140 are formed in the laminated web 10. Figure at this point in the process
As shown in FIG. 1 and FIG. 2, the outer layers are thermally bonded and the holes are not perforated.
The central layer 30 from the web 130 is taken up by the ridges 116 at the roller gap 106.
A hole can be made by being replaced.       [0067]   Laminated web 10 is a web of webs in a diagonal direction relative to axis I of bond site 50.
Further processed to form holes in the partially stretched laminated web
Good. It is during this process that the perforated areas of the web are formed. 9 and 10
The axis I is generally parallel to the machine direction MD of the web to be processed, as indicated by
It Therefore, the stretching in the crossing direction CD at the bonded portion is
Are torn and the pores are punctured, creating a binding site 50 that forms the pores.       [0068]   One method of forming holes across the web is to at least some extent to each other.
Using opposing pressure devices, 134 and 136, having three-dimensional surfaces that are complementary,
Web passes through roller gap 130 formed by advancing and stretching system 132
Is Rukoto. Stretching of laminated webs, including tenter ring or by hand
It may be achieved by other known methods. However, across the web
To achieve uniform pull levels, especially local pull discrimination is desired.
For example, the progressive stretching system disclosed herein is preferred.       [0069]   Referring now to FIG. 12, a progressive stretching system including progressive stretching rollers 134 and 136.
A fragmentary close-up of 132 is shown. The progressive extension roller 134 is a roller 134.
It includes a plurality of teeth 160 and corresponding grooves 161 that extend generally. Progressive stretch roller
-136 includes a plurality of teeth 162 and a corresponding plurality of grooves 163. roller
The teeth 160 on 134 engage or interlock with the grooves 163 on the roller 136,
On the other hand, does the tooth 162 on the roller 136 engage with the groove 161 on the roller 134?
Or interlock. The teeth of each roller are triangular in shape, as shown in FIG. Finish
Tooth vertices may be slightly rounded if a particular effect on the raised web is desired
.       [0070]   Referring to FIG. 13, teeth 160 and 162 of rollers 134 and 136, respectively.
The interlocking part of is shown. As used herein, the term "pitch" refers to
The distance between the vertices of adjacent teeth. The pitch is about 0.02 to about 0.30 inches
It may be between about 0.05 and about 0.15 inches.
Tooth height (or depth) is measured from the tooth base to the tooth apex and is preferably the total
Equal for all teeth. The tooth height is between about 0.10 and 0.90 inches
And preferably between about 0.25 and 0.50 inches.       [0071]   The teeth 160 in one roll are the teeth in one roll (eg, teeth 16
0) will engage grooves (eg, groove 163) between the teeth on the mated rolls.
Can be made up of ½ pitch from another roll tooth 162. Mutual
When there is a roller in the position where it is “interlocked” or engaged and operated in relation to
, The two rollers can be engaged by the compensation. Preferred fruit
In embodiments, the teeth of each roller only partially engage. Opposing rollers
The degree to which the upper teeth are meshed is referred to herein as the "mesh depth" or "DOE" of the teeth.
". As shown in FIG. 13, DOE and E are the tops of the teeth on the respective rollers.
One row from the position indicated by plane P1 (0% meshing) where the points are in the same plane
The flat tops of the teeth of the le that extend inwardly beyond the plane P1 toward the opposite groove of the roll.
It is the distance to the position indicated by the plane P2. Optimal for a particular laminated web
Or effective DOE depends on tooth height and pitch and web material.       [0072]   In other embodiments, the teeth of the mating rolls are aligned with the grooves of the opposing rolls.
There is no need to put it. That is, the teeth are from light mesh to large mesh.
To some extent outside the phase with the groove.       [0073]   Laminated web 10 having melt bond location 50 passes through progressive stretching system 132.
As such, the laminated web 10 is subject to pulling in the CD or cross machine direction.
Then, the laminated web 10 stretches in the CD direction. Alternatively or in addition, the product
The layer web 10 may be pulled in the MD (machine direction). Laminated web 1
The pulling force on 0 causes it to separate or break the melt bond locations 50 and cause lamination.
Arranged to create a plurality of holes 60 in the web 10 that coincide with fusion bond locations 50
Can be done (eg, by adjusting the DOE). However,
The fusion bonded portion of laminated web 10 is shown by portion 62 in FIG.
As such, even after the melt bond sites have been ruptured.
Keep the web consistent.       [0074]   After subjecting to the pulling force applied by the progressive stretching system 132, the laminating
The web 10 includes a plurality of holes 60 that match the melt-bonded regions 50 of the laminated web.
. As mentioned above, the peripheral edge portion of the hole 60 contains the remainder of the fusion bond region 60.
To do. The remaining portion 60 resists further tearing or delamination of the laminated web.
Is believed to help.       [0075]   Instead of two substantially identical rolls 134 and 136, one or both rolls
Can be modified to create extensions and additional patterns. For example, in FIG.
As shown by roll 236. Modify one or both rolls to create a roll table
The tooth can be cut into several evenly spaced thin planar grooves 246 on the surface.
It In FIG. 14, another novel stretching system including novel stretching rollers 234 and 236 is shown.
An enlarged view of the frame 232 is shown. The novel stretching roller 234 is the roller 234.
A plurality of teeth 260 and corresponding grooves 261 that extend about the entire circumference of the. Progressive extension
The tension roller 236 includes a plurality of teeth 262 and a corresponding plurality of grooves 263.
The teeth 260 on the roller 234 mesh with the grooves 263 on the roller 236, or
The teeth 262 on the roller 236 are interlocked with each other, such as the grooves 261 on the roller 234.
Match or work together. Area of laminated web material that did not deform remains as it is after stretching
The teeth on one or both rollers are formed by machining
A groove 246 can be included. A suitable pattern for rolls is US Pat.
No. 18,801 (Departed May 21, 1996 in the name of Chappell)
Line), the disclosure of which is incorporated herein by reference.       [0076]   Similarly, the progressive stretch is oriented by the mating rolls as in FIG.
. Such a roll comprises a series of rolls running parallel to axis A of rolls 334 or 336, respectively.
Includes ridges 360,362 and valleys 361,363. Multiple ridges on the surface of the roll
To form triangular shaped teeth. Either or both of the rolls may be wrapped around a cylindrical roll.
It may have a series of empty channels 346 directed to the enclosure. Shown
The rolled roll is generally flat in the machine cross direction (CD) of the web as it is processed.
Incrementally stretching a laminate having a binding site 50 with an axis I oriented in a row
Is effective.       [0077]   In one embodiment, a method of making a laminated web of an article of the present invention comprises a CD and
It may include progressive stretching of the MD. As shown in FIG. 16, a pair (shown in FIG. 16
232) which contains a series of open channels 246 as shown in FIG.
Tension, and two pairs of progressive stretching rolls are used so that the other pair 332 stretches the MD.
Can be used in a straight line. Many interesting fabric-like structures by this method
Can be incorporated into the articles of the present invention. Depending on the tactile and visual appearance obtained
Thus, such fabric-like webs are ideal for use in the articles of the present invention.       [0078]Beneficial ingredients   The articles of the present invention further include a benefit component disposed adjacent to the laminated web. Book
The articles of the invention can be used in a number of areas, such as personal care and household care.
Suitable for use as a benefit component, the cleaning component, the conditioning component, the
A group consisting of cosmetic ingredients, cleaning ingredients, polishing / cleaning ingredients, and combinations thereof.
May be selected from       [0079]Cleansing ingredients   Suitable benefit ingredients that are cleansing ingredients preferably include one or more surfactants.
Including. The cleansing component is placed adjacent to the laminated web. Specific embodiment
Then, the cleansing component is impregnated into the layers of the laminated web. In other embodiments
The cleansing components are deposited on one or more surfaces of the layers / pleats of the laminated web.
The articles of the present invention, preferably from about 10% to about 1,000%, based on the weight of the laminated web.
Preferably about 50% to about 600%, and more preferably about 100% to about 250%.
Contains surface active agents. Also, the articles of the present invention preferably have a reduced mass relative to the weight of the laminated web.
At least about 1 g of surfactant. Therefore, the cleansing component is
It may be added to the web without the need for a drying step.       [0080]   The cleansing component surfactant is preferably a foaming surfactant. True spirit
"Effervescent surfactant" used in the detailed text means when mechanically mixed with water.
In addition, it means a surfactant that generates foam or foam. Such surfactants are
For this reason, it is important that the increase of bubbles is an important factor for showing the cleansing effect.
. In certain personal care embodiments, a surfactant or combination of surfactants
Is preferably calm. As used herein, the term "gentle" means
Ordinary bar-shaped soap matrix, which is usually a combination of natural soap and synthetic surfactant (eg,
Than Lever (registered trademark) 2000 and Zest (registered trademark))
To the skin, the surfactants and articles of the invention are at least more mild.
It means that The mildness of articles containing surfactant or vice versa
The method of measuring the aggressiveness is based on the skin barrier destruction test. In this test, surface activity
The milder the agent, the less the skin barrier is destroyed. Skin barrier destruction
Passing from the test solution through the epidermis of the skin to the physiological buffer in the diffuser chamber
Radioactive labeling (tritium labeling) water (3H-H₂O) Measure the relative amount. This
The test of T. J. Franz's Journal Investigator
64. pp. 190-195 of "J. Invest. Dermatol"
(1975); and U.S. Pat. No. 4,673,525 (June 16, 1987).
Issued by Small et al.)
Incorporated herein. It is well known to those skilled in the art to measure the mildness of surfactants.
Other test methods can also be used.       [0081]   A wide variety of effervescent surfactants are useful in the present invention, and
For, anionic foaming surfactant, nonionic foaming surfactant, cation
-Based foaming surfactant, zwitterionic foaming surfactant, and mixtures thereof
Those selected from the group consisting of:       [0082]Anionic foaming surfactant   Non-limiting examples of anionic foaming surfactants useful in the cleansing components of articles include:
McCarcheon's Detergents and Emulsifiers, North American
Rica Edition (1986), Alled Publishing Corporation (allu
Published by red Publishing Corporation; McCarcheon's "Functional Material (
Functional Materials) ", North American Edition (1992); US Pat. No. 3,929.
, 678 (issued December 30, 1975, Laughlin et al.)
Each of which is incorporated herein by reference in its entirety.       [0083]   A wide variety of anionic surfactants are potentially useful in the present invention. Yin Yi
Non-limiting examples of on-type foaming surfactants include alkyl and alkyl ethers.
Lusulfates, sulfated monoglycerides, sulfonated olefins
, Alkylaryl sulfonates, primary or secondary alkane sulfonates,
Rukylsulfosuccinates, acyl taurates, acyl isethionates,
Rukyl glyceryl ether sulfonate, sulfonated methyl esters, sulfo
Fatty acids, alkyl phosphates, ethoxylated alkyl phosphates
, Acylglutamates, acyl sarcosinates, alkyl sulfoacetates
, Acylated peptides, alkyl ether carboxylates, acyl lacti
Group consisting of rates, anionic fluorosurfactants, and combinations thereof
Those selected from are listed. The combination of anionic surfactants is the present invention.
Can be effectively used in.       [0084]   Anionic surfactants used as cleansing ingredients include alkyl and
Examples include alkyl ether sulfates. Each of these substances has the formula:
R10-SO3M and R1 (CH2H4O) x-O-SO3M. In the formula,
R1 is a saturated or unsaturated, branched or unbranched, alkyl of from about 8 to about 24 carbon atoms.
Group, x is 1 to 10, M is ammonium, sodium, potassium
, Magnesium, triethanolamine, diethanolamine and monoethanol
It is a water-soluble cation such as ruamine. Alkyl sulphates are typically trioxide
Sulfation of monohydric alcohols (having about 8 to about 24 carbon atoms) with sulfur, or other known methods
Manufactured by sulfation technology. Alkyl ether sulfates are usually ethylene oxide.
Produced by sulphating the condensation product of xide and monohydric alcohol (C8 to C24)
Is built. These alcohols can be derived from fats such as palm oil and tallow.
It can be synthesized or synthesized. Archi that can be used as a cleansing ingredient
Specific examples of lusulfate include lauryl or myristyl sulfate, natri
There are um, ammonium, potassium, magnesium or TEA salts. Can be used
Examples of alkyl ether sulfates include ammonium, sodium,
Gnesium or TEA laureth-3 sulphate.       [0085]   Another suitable class of anionic surfactants is the formula R1CO-O-CH2-C (O
H) H-CH2-O-S03M sulfated monoglyceride. In the formula, R1 is
A saturated or unsaturated, branched or unbranched alkyl group having about 8 to about 24 carbon atoms
Yes, M is ammonium, sodium, potassium, magnesium, triethano
Water-soluble cations such as alcohol, diethanolamine and monoethanolamine
Is. These are usually obtained by reacting glycerin with fatty acids (C8 to C24).
To form monoglyceride, which is then sulphated with sulfur trioxide.
Is manufactured by Examples of sulphated monoglycerides include coco monogulphate
There is lyseridic sodium.       [0086]   Other suitable anionic surfactants include olefins of the formula: R1SO3M
Examples include ruphonate. In the formula, R1 is a monoolefin having about 12 to about 24 carbon atoms.
And M is ammonium, sodium, potassium, magnesium, trieta
Water-soluble cations such as nolamine, diethanolamine and monoethanolamine
It is These compounds use α-olefins with uncomplexed sulfur trioxide.
After sulfonation, any sultone formed by the reaction is hydrolyzed
The acid reaction mixture is treated under conditions such that the corresponding hydroxyalkane sulfonate is obtained.
It can be produced by neutralization. Examples of sulfonated olefins include:
There is C14 / C16 α-sodium olefin sulfonate.       [0087]   Other suitable anionic surfactants are the linear amines of the formula R1-C6H4-SO3M.
It is ruquil benzene sulfonate. In the formula, R1 is a saturated carbon atom having 8 to 24 carbon atoms.
A saturated or unsaturated, branched or unbranched alkyl group, M being ammonium
, Sodium, potassium, magnesium, triethanolamine, diethanol
Water-soluble cations such as amines and monoethanolamine. These are straight chain al
It is formed by sulfonation of killbenzene with sulfur trioxide. This shade
An example of the ionic surfactant is sodium dodecylbenzene sulfonate.       [0088]   Still other anionic surfactants suitable for this cleansing component include those of formula R
1SO3M primary or secondary alkane sulfonates may be mentioned. In the formula, R1
Is a saturated or unsaturated, branched or unbranched alkyl having about 8 to about 24 carbon atoms.
Chain, M is ammonium, sodium, potassium, magnesium, trier
Water-soluble positive solvents such as tanolamine, diethanolamine and monoethanolamine
Is on. They are usually treated with sulfur dioxide in the presence of chlorine and UV light.
It is formed by sulfonation of raffin, or another known sulfonation method. Su
Rufonization can occur at the 2 or 1 position of the alkyl chain. Al useful in the present invention
Examples of cansulfonates include alkali metal or ammonium C13-C17 para.
There is a fin sulfonate.       [0089]   Still other suitable anionic surfactants are alkyl sulfosuccinates,
N-octadecyl sulfosuccinate disodium, lauryl sulfosuccinate dianion
Monium, N- (1,2-dicarboxyethyl) -N-octadecylsulfocoha
Tetrasodium citrate, Diamyl ester of sodium sulfosuccinate, Sulfocoh
Dihexyl ester of sodium citrate and dioctyl sodium sulfosuccinate
Examples include chill esters.       [0090]   Tauric acid based on taurine, also known as 2-aminoethanesulfonic acid
Salt is also useful. All examples of taurates are incorporated herein by reference.
Dodecylamine, as detailed in US Pat. No. 2,658,072
N-alkyl tau, such as those produced by reacting sodium with isethionate
Examples include phosphorus. Other examples based on taurine include n-methyl taurine and
Acyl taurines formed by reaction with fatty acids (having about 8 to about 24 carbon atoms)
Is mentioned.       [0091]   As another class of anionic surfactant suitable for use as a cleansing ingredient
Is an acyl isethionate. Acyl isethionates are usually of the formula: R1CO-
With O-CH2CH2SO3M. In the formula, R1 has about 10 to about 30 carbon atoms
A saturated or unsaturated, branched or unbranched alkyl group, M being a cation
. These are usually fatty acids (C8-C30) and isethionate alkali metal salts.
Formed by reaction with. Non-limiting examples of these acyl isethionates and
Ammonium cocoylisethionate, sodium cocoylisethionate
, Sodium lauroyl isethionate and mixtures thereof.       [0092]   Still other suitable anionic surfactants include those of the formula R1-OCH2-C (O
H) H-CH2-SO3M alkyl glyceryl ether sulfonate.
In the formula, R1 is a saturated or unsaturated, branched or unbranched C 8 to C 24
Is an alkyl group of, M is ammonium, sodium, potassium, magnesium
Such as triethanolamine, triethanolamine, diethanolamine and monoethanolamine
It is a water-soluble cation. These are epichlorohydrin, sodium bisulfite
By reaction with an aliphatic alcohol (having about 8 to about 24 carbon atoms) or other known method.
Can be formed. An example is cocoglyceryl ether sulfonate Natri
Umm.       [0093]   Other suitable anionic surfactants include the formula: R1-CH (SO4) -CO.
Sulfonated fatty acids of OH and of the formula: R1-CH (SO4) -CO-O-CH3
Examples include sulfonated methyl ester. In the formula, R1 has about 8 to about 24 carbon atoms.
A saturated or unsaturated, branched or unbranched alkyl group. These are triacids
Of sulfurized fatty acids (having about 8 to about 24 carbon atoms) or alkyl methyl esters
It can be prepared by sulfonation, or another known sulfonation technique. example
Examples include α-sulfonated coconut fatty acid and lauryl methyl ester.       [0094]   Other anionic substances include branched or unbranched monovalent compounds having about 8 to about 24 carbon atoms.
Monoalkyl, dialky, formed by the reaction of alcohol with phosphorus pentoxide.
And phosphates such as trialkyl phosphates. These are also other public
It is formed by a known phosphorylation method. Examples of this class of surfactants include mono or
Is sodium dilauryl phosphate. Such phosphates may be ethoxylated, for example
It may also be an ethoxylated monoalkyl phosphate.       [0095]   Other anionic substances include the formula: R1CO-N (COOH) -CH2CH2.
Examples include acylglutamates corresponding to —CO 2 M. In the formula, R1 is the carbon number
About 8 to about 24 saturated or unsaturated, branched or unbranched, alkyl or ar.
It is a alkenyl group and M is a water-soluble cation. Non-limiting examples of them are:
Sodium lauroyl glutamate and sodium cocoyl glutamate are listed.
You can       [0096]   As another anionic substance, a compound represented by the formula: R1CON (CH3) -CH2CH2-C
Alkanoyl sarcosinates corresponding to O2M are mentioned. In the formula, R1 is carbon
From about 10 to about 20 saturated or unsaturated, branched or unbranched alkyl or
It is an alkenyl group and M is a water-soluble cation. As a non-limiting example of them
Is sodium lauroyl sarcosinate, sodium cocoyl sarcosinate, and
And ammonium lauroyl sarcosinate.       [0097]   As another anionic substance, a compound represented by the formula: R1- (OCH2CH2) x-OCH2-
Alkyl ether carboxylates corresponding to CO2M are mentioned. Where R
1 is a saturated or unsaturated, branched or unbranched, alkyl of about 8 to about 24 carbon atoms.
Is a alkenyl or alkenyl group, x is 1-10, and M is a water-soluble cation.
Non-limiting examples thereof include sodium laureth carboxylate.       [0098]   As another anionic substance, a compound represented by the formula: R1CO- [O-CH (CH3) -CO]
An acyl lactylate corresponding to x-CO2M can be mentioned. In the formula, R1 is the carbon number
About 8 to about 24 saturated or unsaturated, branched or unbranched, alkyl or ar.
It is a alkenyl group, x is 3 and M is a water-soluble cation. Non-limiting of them
An example is cocoyl lactylate sodium.       [0099]   Other anionic materials include carboxylates, non-limiting examples of which
As, sodium lauroylcarboxylate, sodium cocoylcarboxylate,
And ammonium lauroylcarboxylate. Also, anionic fluorine
A system surfactant can also be used.       [0100]   Other anionic substances are derived from saponification of plant and / or animal oils and fats.
Natural soaps are mentioned, examples of which are sodium laurate, myristin
Sodium acid, palmitate, stearate, tallow, cocoate
Be done.       [0101]   Any counter cation M can be used as the anionic surfactant. Preferred
The counter cations are sodium, potassium, ammonium and monoethanolamine.
Selected from the group consisting of min, diethanolamine, and triethanolamine.
It More preferably, the counter cation is ammonium.       [0102]   Nonionic foaming surfactant   Non-limiting nonionic effervescent surfactants used in the cleansing ingredients of the article
A typical example is "Detergents and Emulsifiers.
) ”, North American version (1986), Allred Publishing Corp.
Published by Allured Publishing Corporation; and "McCacheon
"Functional Materials" published in North America (1992)
Both of which are incorporated herein by reference in their entirety.       [0103]   Nonionic effervescent surfactants useful herein include alkyl groups.
Coside, alkyl polyglucoside, polyhydroxy fatty acid amide, alkoxyl
Fatty acid ester, sucrose ester, amine oxide, and mixtures thereof
One selected from the group consisting of:       [0104]   Alkyl glucosides and alkyl polyglucosides are useful herein.
Long-chain alcohols such as sugars or starch or sugars or starch poly
Condensation of C8-30 alcohols with mer, ie glycosides or polyglycosides
It can be broadly defined as a product. These compounds have the formula (S)_n-OR
Where S is glucose, fructose, mannose, and
A sugar moiety such as lactose; n is an integer from about 1 to about 1000, R
Is a C8-30 alkyl group. Examples of long chain alcohols from which alkyl groups can be derived
Examples include decyl alcohol, cetyl alcohol, stearyl alcohol, and laur.
Examples thereof include ril alcohol, myristyl alcohol, and oleyl alcohol.
Preferred examples of such a surfactant include S for a glucose moiety and R for C8-20.
Alkyl groups and those where n is an integer from about 1 to about 9. This
Commercially available examples of such surfactants include decyl polyglucoside (from Henkel
Commercially available as APG325CS) and lauryl polyglucoside (from Henkel AP
Commercially available as G600CS and 625CS). Also, sucrose Coco
Sucrose ester surfactants such as ates and sucrose laurate are also useful
It       [0105]   Other useful nonionic surfactants include polyhydroxy fatty acid amide interfacial
An activator is included, and in its specific example, glucosamide corresponding to the following structural formula is included.
Included:   [Chemical 1]       [0106] In the formula: R¹Is H, C₁~ C_FourAlkyl group, 2-hydroxyethyl, 2-hydro
Xyl-propyl, preferably C₁~ C_FourAn alkyl group of, more preferably methyl
A group or an ethyl group, most preferably a methyl group; R²Is C_Five~ C₃₁The archi
Group or alkenyl group, preferably C₇~ C₁₉Alkyl group or alkenyl
Group, more preferably C₉~ C₁₇Most preferably an alkyl group or an alkenyl group of
Is C₁₁~ C₁₅Is an alkyl group or an alkenyl group; and Z is at least 3
Having a linear hydrocarbyl chain in which one hydroxyl group is directly attached to the chain
Hydrocarbyl moieties, or alkoxylated derivatives thereof (preferably ethoxylated or
Is propoxylated). Z is preferably glucose, fructose, malt
Tose, lactose, galactose, mannose, xylose, and mixtures thereof.
It is a sugar moiety selected from the group consisting of compounds. Especially preferred corresponding to the above structure
The surfactant is a coconut alkyl N-methylglucoside amide (ie, in the formula
R²The CO-moiety is derived from coconut oil fatty acid). Polyhydroxy fatty acid
Methods of making compositions containing amides are described, for example, in Thomas Hedley (Thomas H.
edley) published on February 18, 1959 by British Patent Specification No. 809,
060; U.S. Pat. No. 2,965,576 (issued Dec. 20, 1960, E
． R. Wilson; US Pat. No. 2,703,798 (1955)
Published March 8, A. M. Schwartz); and US Pat. No. 1,985.
, 424 (issued December 25, 1934, Piggott).
Each of which is incorporated herein by reference in its entirety.       [0107]   Other examples of nonionic surfactants include amine oxides. A
Minoxide has the general formula R₁R₂R₃Equivalent to N → O, R in the formula₁Is about 8 to about 18
Alkyl, alkenyl or monohydroxyalkyl groups with 4 carbon atoms
, 0 to about 10 ethylene oxide moieties, and 0 to about 1 glyceryl moieties.
Have, R₂And R₃Is, for example, methyl, ethyl, propyl, hydroxyethyl,
Or about 1 to about 3 carbon atoms and 0 to about 1 such as a hydroxypropyl group
It contains a hydroxy group. The arrow in the formula is the usual notation for a semipolar bond. The present invention
Examples of amine oxides suitable for use in dimethyl-dodecylamine
Oxide, oleyldi (2-hydroxyethyl) amine oxide, dimethyloctane
Cylamine oxide, dimethyldecylamine oxide, dimethyltetradecyl amine
Min oxide, 3,6,9-trioxaheptadecyldiethylamine oxide,
Di (2-hydroxyethyl) tetradecylamine oxide, 2-dodecoxyethyl
Dimethylamine oxide, 3-dodecoxy-2-hydroxypropyl di (3-
Hydroxypropyl) amine oxide, dimethyl hexadecyl amine oxide
Can be mentioned.       [0108]   Non-limiting examples of preferred nonionic surfactants used in the present invention include
, C8-C14 glucose amides, C8-C14 alkyl polyglucosides,
Sucrose Cocoate, Sucrose Laurate, Lauramine Oxide, Cocoa
Some of which are selected from the group consisting of oxides, and mixtures thereof.       [0109]   Cationic foaming surfactant   Cationic foaming surfactants are also useful in the cleansing ingredients of the articles of the invention.
Is. Suitable cationic effervescent surfactants include aliphatic amines, di-fatty groups.
Quaternary amine, tri-fatty quaternary amine, imidazolinium quaternary amine, and this
But not limited thereto. With a suitable aliphatic amine
Is a monoalkyl quaternary amine such as cetyl trimethyl ammonium bromide
Is mentioned. The preferred quaternary amine is dialkylamidoethyl hydroxyethyl ester.
It is lumonium methosulfate. However, aliphatic amines are preferred. Sun
Ionic foaming surfactants are the main foaming surfactants for cleansing ingredients
In this case, it is preferable to use a foaming accelerator. In addition, nonionic surfactant
Are particularly useful in combination with such cationic effervescent surfactants.
I know there is.       [0110]   Zwitterionic foaming surfactant   As used herein, the term "amphoteric foaming surfactant" refers to zwitterionic surfactants.
The zwitterionic surfactant is a zwitterionic surfactant.
Busset is well known to those skilled in the art.   A wide range of amphoteric effervescent surfactants should be used in the cleansing ingredients of the present invention.
You can Particularly useful are a wide variety of derivatives of aliphatic secondary and tertiary amines.
Preferably in this case the nitrogen is in the cation state.
, The aliphatic groups can be straight or branched, and one of the groups is, for example,
Ions such as rubox, sulfonate, sulfate, phosphate, or phosphonate
It contains a solubilizable water-soluble group.       [0111]   Non-limiting examples of zwitterionic surfactants useful in the components of the present invention include "macroionic surfactants".
"Kercheon's Detergents and Emulsifiers"
), North American version (1986), Allred Publishing Corp.
Published by John; and "The Functional Material of McCarcheon" (McCutcheon's, Functio)
nal Materials) North American version (1992).
Both are incorporated herein by reference in their entirety.       [0112]   Non-limiting examples of amphoteric or zwitterionic surfactants include betaines, sultaines, hyaluronan.
Droxysultaines, alkyliminoacetates, iminodialkanoates
Also selected from the group consisting of: amino acids, aminoalkanoates, and mixtures thereof.
There is       [0113]   Examples of betaines include cocodimethylcarboxymethyl betaine, lauryl
Dimethyl carboxymethyl betaine, lauryl dimethyl alpha carboxyethyl
Rubetaine, cetyl dimethyl carboxymethyl betaine, cetyl dimethyl betaine
Marketed under the name Lonzaine 16SP by Lonza Corp.
), Lauryl bis- (2-hydroxyethyl) carboxymethyl betay
Oleyl dimethyl gamma-carboxypropyl betaine, lauryl bis- (
2-hydroxypropyl) alpha-carboxyethyl betaine, cocodimethyl
Sulfopropyl betaine, lauryl dimethyl sulfoethyl betaine, lauryl bi
Su- (2-hydroxyethyl) sulfopropylbetaine, amidobetaines and
Amidosulfobetaines (where free radicals RCONH (CH₂)₃Is betaine nitrogen
Bonded to atoms), oleyl betaine (Henkel to amphoteric velvet
Commercially available as Velvetex OLB-50), and cocamidopropyl betaine
(Commercially available from Henkel as Velvetex BK-35 and BA-35)
Examples thereof include primary alkyl betaines.       [0114]   Examples of sultaines and hydroxysultaines include cocamidopropyl
Droxysultaine (Rhone Poulenc to Miratein (Mir
ataine) commercially available as CBS) and the like.       [0115]   Preferred for use in the present invention are zwitterionic surfactants having the following structure.
Is a sex agent:   [Chemical 2]       [0116] R in the formula¹Is an unsubstituted, saturated or unsaturated, straight or branched chain alkyl group containing about 9
~ Having about 22 carbon atoms. Preferred R¹About 11 to about 18
More preferably from about 12 to about 18 carbon atoms;
More preferably it has from about 14 to about 18 carbon atoms; m is an integer from 1 to about 3.
More preferably an integer of from about 2 to about 3, more preferably about 3; n is
0 or 1, preferably 1; R²And R³Is 1 to about 3 carbon atoms
From an alkyl group having, not substituted or mono-substituted with a hydroxy group
Independently selected from the group consisting of, preferably R²And R³Is CH₃And X is
, CO₂, SO₃And SO_FourSelect from the group consisting of; R^FourIs saturated or tired
Summed, straight-chain or branched, unsubstituted or mono-substituted with hydroxy groups
Selected from the group consisting of alkyl groups having 1 to about 5 carbon atoms.
X is CO₂If R^FourPreferably has 1 or 3 carbon atoms, and more preferably
Or has one carbon atom. X is SO₃Or SO_FourIf R^FourIs preferably about
It has from 2 to about 4 carbon atoms, and more preferably has 3 carbon atoms.       [0117]   Examples of zwitterionic surfactants of the present invention include the following compounds:   [Chemical 3]       [0118]   Examples of other useful zwitterionic surfactants include the formula RN [CH₂)_mCO₂M]₂Over
And RNH (CH₂)_mCO₂M alkyliminoacetates, and iminodiars
There are cinnoates and aminoalkanoates, where m is 1 to 4 and R is C₈
~ C_{twenty two}Alkyl group or alkenyl group, M is hydrogen, alkali metal, alkali
It is an earth metal ammonium or alkanol ammonium. Also, imida
Also included are zolinium and ammonium derivatives. Suitable zwitterionic surfactant
Specific examples of agents include sodium 3-dodecyl-aminopropionate and 3-dodecyl.
Sodium aminopropane sulfonate, incorporated herein by reference in its entirety
N such as those manufactured in accordance with the teachings of US Pat. No. 2,438,091
-Higher alkyl aspartic acid; and sold under the brand name of "Milan", for reference
As described in US Pat. No. 2,528,378, which is hereby incorporated by reference in its entirety.
The products that are used are listed. Other examples of useful zwitterionic surfactants include
, Coamidopropyl chloride PG-dimonium phosphate (Mona Corp
commercially available as Monaquat PTC from P.) and other amphoteric phosphorus.
Examples thereof include acid salts. Lauroamphodiacetate disodium, Lauroamphoacetate Natri
Amphoacetic acids such as um, and mixtures thereof are also useful.       [0119]   Preferred effervescent surfactants are ammonium lauroyl sarcosinate, tridecane.
Sodium cesulfate, Sodium lauroyl sarcosinate, Ammo laureth sulfate
Ni, sodium laureth sulfate, ammonium lauryl sulfate, sodium lauryl sulfate
Thorium, ammonium cocoylisethionate, sodium cocoylisethionate
, Sodium lauroyl isethionate, sodium cetyl sulfate, monolauryl
Sodium phosphate, ethoxylated monoalkyl phosphoric acid, cocoglyceryl ethers
Sodium ruphonate, C₉~ C_{twenty two}From sodium soap and combinations of these
Anionic foaming surfactant selected from the group consisting of: lauramin oxide, coco
Amine oxide, decyl polyglucose, lauryl polyglucose, sucrose
Cocoate, C12-14 glucosamide, sucrose laurate, and these
A nonionic effervescent surfactant selected from the group consisting of:
Min, di-fatty quaternary amine, tri-fatty quaternary amine, imidazolinium quaternary amine
Cationic foaming interface selected from the group consisting of Min, and combinations thereof
Activator: disodium lauroamphodiacetate, sodium lauroamphoacetate, cetii
Rudimethyl betaine, cocoamidopropyl betaine, cocoamidopropyl hydro
Zwitterion selected from the group consisting of xysultane and combinations thereof.
It is a surfactant.       [0120]Conditioning ingredients   In a particular embodiment of the invention, the article is a conditioning ingredient beneficial
Contains essentially the ingredients. This conditioning component is placed adjacent to the water-insoluble substrate.
About 10% to about 1000%, more preferably about 10% by weight of the laminated web.
Wt% to about 500 wt%, and most preferably about 10 wt% to about 250 wt%.
Contains conditioning ingredients. Preferably, the conditioning components are laminated
Located on the surface of one or more layers of the web. Even more preferably, the condition
The ninging component is disposed on one or more outer surfaces of the resulting laminated web. Preferred
The conditioning agents include hydrophobic conditioning agents and hydrophilic conditioning agents.
Consisting of conditioning agents, structured conditioning agents, and combinations thereof
Selected from the group.       [0121]Hydrophobic conditioning agent   The article of the present invention has a conditioning effect on the skin and hair during use of the article.
One or more hydrophobic conditioning agents useful in providing fruit may be included.
The article of the present invention preferably comprises from about 0.5% by weight to about 1, based on the weight of the laminated web.
000 wt%, more preferably about 1 wt% to about 200 wt%, most preferably about
10% to about 100% by weight of hydrophobic conditioning agent.       [0122]   Hydrophobic conditioning agents have an arithmetic weighted average solubility parameter of 10.
It may be selected from one or more hydrophobic conditioning agents, such as 5 or less.
If one of the compounds has an independent solubility parameter greater than 10.5, then the solubility
Based on this mathematical definition of the resolution parameter, for example, including two or more compounds
An arithmetically weighted average solubility parameter required for the hydrophobic conditioning agent comprising
That is, it is recognized that it is possible to achieve 10.5 or less.       [0123]   Solubility parameters are well known in the art of chemists involved in formulation
It is well known in the art and is used as a guide for determining the compatibility and solubility of substances during the compounding process.
Used regularly.   The solubility parameter δ of a chemical compound is the cohesive energy for that compound.
Defined as the square root of the density. Generally, the solubility parameter for a compound is
Using the following equation, the values listed in the table of addition groups that contribute to the heat of vaporization
Calculate from the molar volumes of the ingredients of the compound:       [0124]   [Equation 1] Where Σ_iE_iIs the total heat of vaporization of the additional groups that contribute, Σ_im_iIs the total molar volume of the additional groups that contribute.       [0125]   Marks of heat of vaporization and molar volume of contributing addition groups for a wide variety of atoms and groups of atoms.
A quasi-list is Burton A. F. M. Solubility parameter handbook, CRC
Edition, Chapter 6, Table 3, pages 64-66 (1985), all for reference
Incorporated herein. The solubility parameter equation above is given by R.S. F. Fedor
Fedors, “A Method for Calculating Both Solubility Parameters and Molar Volumes of Liquids (A Me
thod for Estimating Both the Solubility Parameters and Molar Volumes of
Liquids) "Polymer Engineering and Science Volume 14
No. 2, pp. 147-154 (February 1974), for reference only.
Incorporated herein.       [0126]   The solubility parameter follows the law of mixture and the solubility parameter for the mixture of substances is
The data is the average calculated by weighting the solubility parameter for each component of the mixture.
(Ie weighted average). In this specification, it is referred to in its entirety.
Chemistry and Physics Handbook, 57th Edition, CRC Publishing, C726 pages (19
76-1977).       [0127]   Chemists involved in the formulation are generally (cal / cm³)^1/2Solubility parameter using
To report. The values in the list of contributions of the additional groups to the heat of vaporization are the solubility parameter
Handbook reports kJ / mol. However, like this
The tabulated values are easily converted to cal / mol using the following well known relationship: 1 J / mOl = 0.239006 cal / mOl and 1000 J = 1 KJ       [0128]   Reference is made to A. J. Gordon et al.
The Chemist's Companion "by John Willie & Sun
n Wiley & Sons) 456-463 (1972).       [0129]   Solubility parameters are also summarized in a list for a wide variety of chemicals.
A list of solubility parameters can be found in the solubility parameter handbook quoted above (
See Handbook of Solubility Parameters). Also, as a reference the whole
C. is incorporated herein. D. Vaughan "Products, Packaging, Penetration
And Solubility Effects In Product, Package, Pe
netration, And Preservation) "Cosmetics and Toiletry
iletries) (Vol. 103, October 1988, pages 47-69).
.       [0130]   Non-limiting examples of hydrophobic conditioning agents include mineral oils, petrolatum and
Citin, hydrogenated lecithin, lanolin, lanolin derivatives, C7-C40 branched chains
Hydrocarbons, C1-C30 carboxylic acid C1-C30 alcohol esters, C
2-C30 dicarboxylic acid C1-C30 alcohol ester, C1-C30
Carboxylic acid monoglyceride, C1-C30 carboxylic acid diglyceride, C
1-C30 carboxylic acid triglyceride, C1-C30 carboxylic acid ethyl
Glycol monoester, C1-C30 carboxylic acid ethylene glycol diester
Ester, propylene glycol monoester of C1-C30 carboxylic acid, C
1 to C30 carboxylic acid propylene glycol diester, C1 to C30 carboxylic acid
Rubonic acid monoesters and sugar polyesters, polydialkylsiloxanes,
Lydiaryl siloxanes, polyalkaryl siloxanes, 3-9 silicons
Cyclomethicones having atoms, vegetable oil, hydrogenated vegetable oil, polypropylene glyco
C4 to C20 alkyl ether, di (C8 to C30 alkyl) ether, and
One selected from the group consisting of these combinations.       [0131]   Mineral oil, known as liquid petrolatum, is a mixture of liquid hydrocarbons obtained from petroleum.
Is. The Merck Index, which is hereby incorporated by reference in its entirety,
Index) (10th edition, entries 7048, 1033 pages, 1983) and
International Cosmetic Ingredient Dictionary (5th
Edition, Volume 1, 415-417, 1993).       [0132]   Vaseline, also known as petroleum jelly, is a non-linear solid hydrocarbon and high-boiling liquid.
A colloidal system of hydrocarbons, with most liquid hydrocarbons inside the micelles. Mel
Index, 10th Edition, heading items 7047, 1033 pages (1983)
); 89 volumes of the drug and cosmetics industry (Drug. Cosmet. Ind) by Schindler
, 36-37, 76, 78-80 and 82 (1961); and international makeup.
International Cosmetic Ingredient Dictionary, 5th edition, 1st edition
Volume 537 (1993). These are books based on the whole
Incorporated in the description.       [0133]   Lecithin is also useful as a hydrophobic conditioning agent. Lecithin
, A naturally derived mixture of diglycerides of specific fatty acids, and choline ester of phosphoric acid
Is bound to       [0134]   Included herein are straight and branched chain hydrocarbons having from about 7 to about 40 carbon atoms.
It is for. Non-limiting examples of these hydrocarbon substances include dodecane and isododecane.
Can, squalane, cholesterol, hydrogenated polyisobutylene, docosane (immediately
Chi C_{twenty two}Hydrocarbon), hexadecane, isohexadecane (Permethyl (registered trademark)
101A, a South Plainfield, New Jersey, USA
Hydrocarbons commercially available from Presperse). C7-C
Also useful are the C7 to C40 isoparaffins, which are 40 branched chain hydrocarbons. Branched
The liquid hydrocarbon polydecene is also useful herein, and is mobile.
・ Commercialized from Mobile Chemical (Edison, NJ, USA)
Product name Puresyn 100 (registered trademark) and Pressin 3000 (registered trademark)
) Is sold at.       [0135]   C1-C30 carboxylic acids including straight and branched chains as well as aromatic derivatives and
C1-C30 alcohol esters of C2-C30 dicarboxylic acids are also useful. C
1-C30 carboxylic acid monoglyceride, C1-C30 carboxylic acid diglyceride
C, C1-C30 carboxylic acid triglyceride, C1-C30 carboxylic acid ethi
Len glycol monoester, C1-C30 carboxylic acid ethylene glycol die
Stell, propylene glycol monoester of C1-C30 carboxylic acid, and C
There are also esters such as propylene glycol diesters of 1-C30 carboxylic acids.
It is for. Included herein are straight chain, branched chain, and aryl carboxylic acids. This
Also useful are propoxylated and ethoxylated derivatives of such substances. Non-limiting
Examples include diisopropyl sebacate, diisopropyl adipate, myristin
Isopropyl acid, isopropyl palmitate, myristyl propionate, diste
Ethylene glycol acrylate, 2-ethylhexyl palmitic acid, isodecylne
Opentanoic acid, di-2-ethylhexyl maleic acid, cetyl palmitate, milli
Myristyl stearate, stearyl stearate, cetyl stearate, behenyl
Behenate, dioctyl maleate, dioctyl sebacate, diiso adipate
Propyl, cetyl octanoate, diisopropyl dilinoleate, capryl / capri
Triglyceride, PEG-6 capryl / caprin triglyceride, PEG-8
There are capryl / caprin triglycerides, and mixtures thereof.       [0136]   Many C1-C30 monoesters of sugars and related substances and polyesters are also useful
Is. Such esters are sugars or polyhydric alcohol moieties and one or more caps.
It comes from the rubic acid part. Depending on the constituent acids and sugars, these esters
Can be liquid or solid at room temperature. Examples of liquid esters are: gluco
Glucose tetraester of soybean oil fatty acid (unsaturated),
Mixed soybean oil fatty acid mannose tetraester, oleic acid galactose stet
Laester, arabinose tetraester of linoleic acid, xylose tetralino
Rate, galactose pentaoleate, sorbitol tetraoleate, satiety
Soybean oil fatty acid sorbitol hexaester, xylitol pentaoleate
, Sucrose tetraoleate, sucrose pentaoleate, sucrose hex
Saoleate, sucrose heptaoleate, sucrose octaoleate, and
And mixtures thereof. Examples of solid esters are: carboxylic acid esters
Sorbitol in which the parts are palmitooleate and arachidate in a molar ratio of 1: 2
Hexaester; the carboxylic acid ester moiety is in a molar ratio of 1: 3 and linoleate and
Octaester of raffinose which is a nate; esterified carboxylic acid moiety is 3:
Sunflower seed oil fatty acid and lignocerate maltose hepta in a molar ratio of 4
Ester; esterified carboxylic acid moieties in the molar ratio of 2; 6 oleate and behenene
Octaester of sucrose, which is a carboxylic acid; and the esterified carboxylic acid moiety is 1: 3.
Of sucrose, which is a laurate, linoleate, and behenate in a molar ratio of 4: 1.
Examples include a ester. A preferred solid substance has a degree of esterification of 7 to 8
The fatty acid moieties are C18 mono- and / or di-unsaturated and behenic acid, the unsaturated:
It is a sucrose polyester in which the molar ratio of henic acid is 1: 7 to 3: 5. Especially good
A good solid sugar polyester has about 7 behen fatty acid moieties and about 1 olein in the molecule.
It is an octaester of sucrose with an inic acid moiety. Other substances include
Includes fatty acid esters of loin cottonseed oil or soybean oil. About ester material
Is further disclosed in US Pat. No. 2,831,854 issued January 25, 1977.
(Jandacek), US Pat. No. 4,005,196; 1977.
U.S. Pat. No. 4,005,195 issued Jan. 25 (Jandasec, Ja
ndacek), US Pat. No. 5,306,516, issued April 26, 1994.
(Retton et al.); US Pat. No. 5,306,5 issued Apr. 26, 1994.
15 (Retton et al.); US Pat. No. 5,30, issued April 26, 1994.
5,514 (Retton et al.); U.S. Pat. No. 4, issued January 10, 1989.
, 797,300 (Jandacek); on June 15, 1976.
Issued US Pat. No. 3,963,699 (Rizzi et al., Rizzi); 1985.
U.S. Pat. No. 4,518,772 issued May 21, (Bolpehein et al., Vo
lpenhein); and U.S. Pat. No. 4,517,3 issued May 21, 1985.
No. 60 (Volpenhein et al., Volpenhein);
Incorporated herein by reference.       [0137]   Polydialkyl siloxanes, polydiaryl siloxanes, and polyalkalis
Nonvolatile silicones such as rilsiloxanes are also useful oils. like this
Silicone is US Pat. No. 5,069,89 issued Dec. 3, 1991.
No. 7 (all), all of which are incorporated herein by reference.
To do. Polyalkylsiloxane has the general chemical formula R₃SiO [R₂SiO]_xSiR₃ In which R is an alkyl group (preferably R is a methyl or ethyl group,
More preferably a methyl group) and x is an integer of up to about 500, the desired molecule
Selected to achieve quantity. As a commercially available polyalkyl siloxane
Include polydimethylsiloxane, which is also known as dimethicone.
Non-limiting example of Vikasil sold by General Electric
(Vicasil) (registered trademark) series and Dow Corning Corporation
The Dow Corning (registered trademark) 200 series sold is included. True spirit
Specific examples of polydimethylsiloxanes useful in the text include a viscosity of 10 centistokes.
Corning® 225 liquid having a boiling point of more than 200 ° C. and 200 ° C.,
And Dow Corning® 200 fluid at 50, 350, and 12 respectively
, Those with a viscosity of 500 centistokes and boiling points above 200 ° C.
You can General chemical formula [(CH₂)₃SiO_1/2]_x[SiO₂] Y (where x is approximately
1 to about 500 and y is an integer from about 1 to about 500)
Materials such as the mer material trimethylsiloxysilicate are also useful. Commercially available
Trimethylsiloxysilicate is a Dow Corning® 593 solution
Then it is sold as a mixture with dimethicone. Dimes with hydroxy ends
The dimethiconol, which is a chill silicone, is also useful herein. Such an element
Material is general chemical formula R₃SiO [R₂SiO]_xSiR₂OH and HOR₂SiO [R₂S
iO]_xSiR₂It can be represented by OH, where R is an alkyl group (preferably R is
Methyl or ethyl, more preferably methyl) and x have the desired molecular weight
It is an integer up to about 500 selected to achieve. The commercially available dimethiconol is
, Usually in mixtures with dimethicone or cyclomethicone (eg Dow Corning
(Registered trademark) 1401, 1402 and 1403 liquids). 25
Polymethylphenyl white with a viscosity of about 15 to about 65 centistokes at ℃
Polyalkylaryl siloxanes are also useful herein along with the xane. This
For example, SF1075 methylphenyl solution (General Electric)
Marketed by the company) and 556 cosmetic grade phenyl trime
Chicon liquid (sold by Dow Corning Corporation)
You can get it. Methyl decyl silicone and methyl octyl silico
Alkylated silicones such as amines are useful in the present invention and are
Sold by Trick. Further, the alkyl chain has 10 to 50 carbon atoms,
Alkyl-modified siloxanes such as alkylmethicone and alkyldimethicone are also available.
Useful in the invention. Such a siloxane is known as Aville Wax
(ABIL WAX) 9810 (C₂4-C₂8 alkyl methicone) (Gold Schmi
Sold by Goldschmidt) and SF1632 (cetearylmethicone) (
Sold by General Electric).       [0138]   Vegetable oils and hydrogenated vegetable oils are also useful in the present invention. Vegetable oil and hardening
Examples of vegetable oils are safflower oil, castor oil, coconut oil, cottonseed oil, menhaden oil.
, Palm kernel oil, palm oil, peanut oil, soybean oil, rapeseed oil, linseed oil, rice bran oil, pine
Root oil, sesame oil, sunflower seed oil, hydrogenated safflower oil, hydrogenated castor oil, hydrogenated coconut oil,
Hardened cottonseed oil, hardened Menhaden oil, hardened palm kernel oil, hardened palm oil, hardened pea
Oil, hydrogenated soybean oil, hydrogenated rapeseed oil, hydrogenated linseed oil, hydrogenated bran oil, hydrogenated sesame oil, hydrogenated oil
Sunflower seed oil, and mixtures thereof.       [0139]   In addition, C4 to C20 alkyl ether of polypropylene glycol, polypropylene
C1-C20 carboxylic acid ester of pyrene glycol, and di-C8-C30
Lucyl ether is also useful. A non-limiting example of such a material is PPG.
-14 butyl ether, PPG-15 stearyl ether, dioctyl ether
, Dodecyl octyl ether, and mixtures thereof.       [0140]   In addition, a hydrophobic chelating agent is also included in the present invention as a hydrophobic conditioning agent.
Useful. Suitable agents are disclosed in US Pat. No. 4,387,244 (1983).
Issued June 7, Scanlon et al., And US patent co-pending application No.
No. 09 / 258,747 and No. 09 / 259,485 (Schwartz (Sc
hwartz) et al., filed February 26, 1999).       [0141]   Preferred hydrophobic conditioning agents are mineral oil, petrolatum, lecithin, hydrogen.
Added lecithin, lanolin, lanolin derivatives, C7 to C40 branched chain hydrocarbons, C
1-C30 carboxylic acid C1-C30 alcohol ester, C2-C30
C1-C30 alcohol ester of dicarboxylic acid, C1-C30 carboxylic acid
Monoglyceride, C1-C30 carboxylic acid diglyceride, C1-C30
Carboxylic acid triglyceride, C1-C30 carboxylic acid ethylene glycol
Monoester, C1-C30 carboxylic acid ethylene glycol diester, C
1-C30 carboxylic acid propylene glycol monoester, C1-C30
Propylene glycol diester of carboxylic acid, C1-C30 carboxylic acid mono
Ester and sugar polyesters, polydialkylsiloxanes, polydiaryls
Siloxane, polyalkylaryl siloxane, having 3 to 9 silicon atoms
Cyclomethicone, vegetable oil, hydrogenated vegetable oil, polypropylene glycol C4 ~
C20 alkyl ethers, di (C8-C30 alkyl) ethers, and their
Selected from the group consisting of combinations.       [0142]Hydrophilic conditioning agent   The articles of the present invention also include a beneficial ingredient that includes one or more hydrophilic conditioning agents.
Including. Non-limiting examples of hydrophilic conditioning agents include polyhydric alcohols,
Polypropylene glycol, polyethylene glycol, ureas, pyrrolidone cal
Boronic acid, ethoxylated and / or propoxylated C3-C6 diol and trio
, Α-hydroxy C2-C6 carboxylic acid, ethoxylated and / or propoxy
Silylated sugar, polyacrylic acid copolymer, sugar having about 12 or less carbon atoms, about 12 or more carbon atoms
And those selected from the group consisting of sugar alcohols below, and mixtures thereof.
Be done. Specific examples of useful hydrophilic conditioning agents include urea; guanyl
Gin; glycolic acid and glycolates (eg, ammonium and quaternary alcohols)
Kylammonium); lactic acid and lactate salts (eg, ammonium and quaternary alkyl
Lumonium); sucrose, fructose, glucose, erthrose, d
Lithritol, sorbitol, mannitol, glycerol, hexanetrio
, Propylene glycol, butylene glycol, hexylene glycol, etc .; P
Polyethylene glycos such as EG-2, PEG-3, PEG-30, PEG-50
, PPG-9, PPG-12, PPG-15, PPG-17, PPG-20,
Polypropylene glycol such as PPG-26, PPG-30, PPG-34;
Lucoxylated glucose; Hyaluronic acid; Cationic skin conditioning
Polymers (eg, quaternary ammonium polymers such as polyquaternium polymers)
); And substances such as mixtures thereof. In the article of the present invention,
Glycerol is the preferred hydrophilic conditioning agent. Also, all species
Various forms of aloe vera (eg aloe vera gel), chitosan and chitosa
Derivatives such as chitosan lactate, lactamide monoethanolamine; aceto
Materials such as amidomonoethanolamine; and mixtures thereof are also useful. reference
No. 4,976,953 (19), which is hereby incorporated by reference in its entirety.
Propoxylated Glyce described in Orr et al., Issued December 11, 1990.
Also useful are propoxylated glycerol as described for cerol.       [0143]   The beneficial component can be prepared in various forms. In one aspect of the invention,
The benefit component is in the form of an emulsion. In the present invention, for example, oil-in-water type, oil
Water-in-water, water-in-oil-in-water and silicone oil-in-water emulsions are useful. D
As used in this context of Marshall, "water" means not only water, but water.
It may also represent a water soluble or water miscible material such as glycerin.       [0144]   A preferred benefit component comprises an emulsion, which further comprises an aqueous phase and an oil.
Including phases. As one of ordinary skill in the art will appreciate, any component may be a therapeutically beneficial agent in this component.
Depending on the solubility / dispersibility of the, first it is distributed in either the aqueous or oil phase. One
In an embodiment, the oil phase comprises one or more hydrophobic conditioning agents. Another aspect
In, the aqueous phase contains one or more hydrophilic conditioning agents.       [0145]   The beneficial component of the present invention is in the form of an emulsion and generally comprises an aqueous phase and an oil phase or
Contains a lipid phase. Suitable oils or lipids may be derived from animals, plants or petroleum.
In addition, it may be natural or synthetic (that is, artificial). Suitable oil and water phase components are
Are discussed in. A preferred emulsion form is a water-in-oil emulsion
, Water-in-silicone emulsions, and other inverse emulsions. Addition
Thus, a preferred emulsion is such that a glycerin-in-oil emulsion results.
Also included are hydrophilic conditioning agents such as glycerin.       [0146]   The beneficial ingredients of the present invention in emulsion form, especially the conditioning ingredients,
Preferably about 1% to about 10%, more preferably about 2% by weight of the beneficial ingredient.
% To about 5% by weight emulsifier (ie, surfactant). The emulsifier is
It may be nonionic, anionic or cationic. A suitable emulsifier is 197
US Patent 3,755 by Dickert et al., Issued August 28, 3
No. 560; US patent by Dixon et al., Issued December 20, 1983.
Xu 4,421,769; and "McCutcheon's D
etergents and Emulsifiers) ”North American version, pages 317-324 (1986).
As disclosed above. Also, beneficial ingredients in emulsion form are suitable for skin.
An antifoaming agent may be included to minimize foaming during use. As an antifoaming agent
, High molecular weight silicones, and other materials known for such use.
You can       [0147]   Also, the benefit component may be in the form of a microemulsion. As used herein
The "microemulsion" is stabilized by a surfactant, which is an amphipathic molecule.
Thermodynamically stable of two immiscible solvents (one non-polar and the other polar)
Refers to the mixture. A preferred microemulsion is a water-in-oil microemulsion.
You can mention       [0148]Structured conditioning agents   Beneficial ingredients that are conditioning ingredients also include structured conditioning agents.
It doesn't matter. Suitable structured conditioning agents include ceramide and liposomes.
Examples thereof include, but are not limited to, vesicular structures such as mucus.       [0149]   In another embodiment, the benefit ingredient conditioning agent is a coacervation agent.
To-forming composition. Preferably, the coacervate-foam composition is a positive composition.
Ionic polymers, anionic surfactants, and their polymers and surfactants
Includes a dermatologically acceptable carrier of the agent. Cationic polymers are mainly natural
Chain quaternary ammonium polymer, synthetic main chain quaternary ammonium polymer, heaven
Natural backbone amphoteric polymers, synthetic backbone amphoteric polymers, and combinations thereof
May be selected from the group consisting of:       [0150]   More preferably, the cationic polymer is polyquaternium-4, polyquater.
Ternium-10, Polyquaternium-24, PG-Hydroxyethyl Cellulo
S-alkyldimonium chloride, guar hydroxypropyltrimo
Nium chloride, hydroxypropyl guar hydroxypropyltrimonium
The fourth of the natural backbones selected from the group consisting of chloride and combinations thereof.
Quaternary ammonium polymer; polyquaternium-2, polyquaternium-6,
Polyquaternium-7, Polyquaternium-11, Polyquaternium-1
6, polyquaternium-17, polyquaternium-18, polyquaternium
Mu-28, polyquaternium-32, polyquaternium-37, polyquate
Runium-43, Polyquaternium-44, Polyquaternium-46, Poly
Methacrylamidopropyltrimonium chloride, acrylamidopropyl
Limonium chloride / acrylamide copolymers, and combinations thereof
Synthetic backbone quaternary ammonium polymers selected from the group consisting of: chitosan, tetra
From the group consisting of graded protein, hydrolyzed protein, and combinations thereof
Amphoteric polymers of natural backbone selected; polyquaternium-22, polyquate
Lunium-39, Polyquaternium-47, Adipic acid / Dimethylaminohydride
Roxypropyldiethylenetriamine copolymer, polyvinylpyrrolidone / dime
Cylaminoethyl methacrylate copolymer, vinyl caprolactam / polyvinyl chloride
Lupyrrolidone / Dimethylaminoethyl Methacrylate Copolymer, Vinaricapro
Lactam / Polyvinylpyrrolidone / Dimethylaminopropyl methacrylamide
-Polymer, polyvinylpyrrolidone / dimethylaminopropylmethacrylamide
A compound selected from the group consisting of copolymers, polyamines, and combinations thereof.
Selected from the group consisting of main chain amphoteric polymers; and combinations thereof.
. More preferably, the cationic polymer is a synthetic backbone amphoteric polymer. Change
Most preferably, the cationic polymer is a polyamine.       [0151]   If the cationic polymer is a polyamine, the cationic polyamine polymer
Is polyethyleneimine, polyvinylamine, polypropyleneimine, polylysine
It is preferred that it is selected from the group consisting of Even better
Preferably, the cationic polyamine polymer is polyethyleneimine.       [0152]   In certain embodiments where the cationic polymer is a polyamine, the polyamine is hydrophobic.
Or may be hydrophilically modified. In this example, the cationic polyamine poly
Mer is benzylated polyamine, ethoxylated polyamine, propoxylated polyamine
Amine, alkylated polyamine, amidated polyamine, esterified polyamine,
And a combination thereof. Coacervate forming composition
Is about 0.01 wt% to about 20 wt% based on the weight of the coacervate-forming composition.
%, More preferably about 0.05% to about 10%, most preferably about 0.1%.
% To about 5% by weight of cationic polymer.       [0153]   Suitable anionic surfactants for use in the context of coacervate-forming include
, Those discussed above as regards "cleansing ingredients". Good
More preferably, the anionic surfactant for the coacervate-forming composition is
Cosinate, glutamate, sodium alkylsulfate, ammonium sulfate alkylsulfate
, Sodium alkylesulfate, ammonium alkylesulfate, laureth-n-
Ammonium sulfate, laureth-n-sodium sulfate, isethionate, glycerin
Group consisting of ruthenium sulfonates, sulfosuccinates and combinations thereof
Selected from. More preferably, the anionic surfactant is lauroyl sarcosine.
Sodium phosphate, monosodium lauroyl glutamate, Natri alkyl sulfate
Um, ammonium alkylsulfate, sodium alkylesulfate, alkylesulfate
Selected from the group consisting of ammonium and combinations thereof.       [0154]   Suitable coacervate-forming compositions are further described in each of 16 September 1999.
Desired co-pending US patent application Ser. No. 09 / 397,747, Schwartz et al .;
09 / 397,746, Heinrich et al .; 09 / 397,71.
No. 2, Schwartz et al .; 09 / 397,723, Heinrich et al.
And No. 09 / 397,722, Venkitaraman et al.
It is listed.       [0155]   Alternatively, the coacervate-forming composition comprises an anionic polymer, a cationic polymer.
Surfactants and dermatologically acceptable carriers of polymers and surfactants
May be included. Anionic polymers include polyacrylic acid polymers and polyacrylic acid polymers.
Acrylamide polymer, acrylic acid, acrylamide, and other natural or synthetic
Copolymers of polymers (eg polystyrene, polybutene, polyurethane, etc.)
, Naturally occurring rubber, and combinations thereof.
Suitable gums include alginates (eg, propylene glycol alginate).
), Pectin, chitosan (eg, chitosan lactate), and modified gum (eg,
Starch octenyl succinate), and combinations thereof. Even better
Preferably, the anionic polymer is a polyacrylic acid polymer or polyacrylic amine.
Selected from the group consisting of depolymer, pectin, chitosan, and combinations thereof
To be done. Preferred articles of the present invention, based on the weight of the coacervate-forming composition,
About 0.01 to about 20% by weight, more preferably about 0.05 to about 10% by weight,
Most preferably it contains from about 0.1% to about 5% by weight of anionic polymer. Suitable
Examples of suitable cationic surfactants include those described herein.
Not limited to.       [0156]Cosmetic ingredients   In the personal care area, the beneficial ingredient of this product is a conditioning agent.
Not only deodorant / antiperspirant, anti-acne active substance, anti-wrinkle active substance, antibacterial active substance
, Antifungal active substances, anti-inflammatory active substances, local anesthetic active substances, artificial tanning agents and stimulants
Promoting agents, antiviral agents, enzymes, sunscreen active substances, antioxidants, skin peeling agents,
And various agents including but not limited to combinations of the above.
Suitable for providing therapeutic or aesthetic skin or hair benefits from surface deposits
. Such additional active ingredients are described in further detail below under the section "Optional Ingredients".       [0157]   Additional cosmetic ingredients suitable for inclusion in the article include foundations,
Red colours, stain-curing compositions, and other typical cosmetic coloring products. Scarecrow
Ingredients actually make the articles of the invention suitable for make-up.       [0158]   To form one unit of beneficial component with indistinguishable components and multiple functions
In the method, the beneficial ingredients are cleansing ingredients, conditioning ingredients, cosmetic ingredients.
It is reasonable to say that a combination of product components, cleaning components, polishing components, etc. may be included.
Should be understood.       [0159]Cleaning ingredients   For home care use, the benefit component of this article may be a household area, for example,
Provides cleaning effects on hard surfaces such as untops, walls, washbasins, bathtubs, floors, windows, etc.
It is suitable for Hereinafter, such a beneficial component is referred to as a cleaning component. Preferred
It can be easily applied as an undiluted solution to hard areas and in concentrated form.
The cleaning component is liquid. However, when using them
Solid cleaning ingredients are acceptable as long as is soluble in water or another liquid
Is. Preferably the cleaning component of the present invention renders the surface to be treated hydrophilic.
A safe and effective amount of a relatively hydrophilic polymer. This increase in hydrophilicity
Provide "sheeting" of water from the surface and / or diffusion of water from the surface
Thereby providing an improved final appearance, this effect preferably resulting in
It is seen when wet and even after rewet and then dry.       [0160]   To such articles of the invention intended for use in everyday shower products
The "sheeting" effect is special because most of the treated surfaces are vertical.
It is worth noting. Therefore, the benefits are moistened like glass, ceramic and enamel.
Attention is paid to the stronger surface. Water is even on the surface like a "sheet"
If it falls on the surface and / or diffuses to the surface, for example, "hard water formed when dried.
Minimize the formation of "stains". Can be used in the background of floor cleaning agents
For contemplated articles of the invention, the polymer improves surface wetting and provides a cleaner.
Helps leaning performance.       [0161]   The substantial nature of the polymer is beneficial as it prolongs the sheeting and cleaning effect.
Is. Another important feature of the preferred polymers is that they lack residue when dry
That is. Compositions containing the preferred polymers have little or no haze.
Dry more evenly on the floor, promoting the undesired end result.       [0162]   Many materials can provide sheeting and stain removal effects, but are preferred.
A preferred material is a polymer containing amine oxide hydrophilic groups. Sulfonate,
Contains pyrrolidone and / or other hydrophilic groups such as carboxylate groups
Polymers can also be used. Examples of desirable poly-sulfonate polymers
Include polyvinyl sulfonate, and more preferably, monomer-polymer.
Dajac (19053 Bus, Festerville, PA)
Polystyrene like that sold by Treton Pike 1675)
Sulfonate. A typical formula is:       [0163]   -[CH (C₆H_FourSO₃Na) -CH₂]_n-CH (C₆H_Five) -CH₂− In the formula, n is a number that gives an appropriate molecular weight as described below.       [0164]   Typical molecular weights are from about 10,000 to about 1,000,000, preferably about 2
It is from 0,000 to about 700,000. Preferred containing pyrrolidone functionality
Polymers include polyvinylpyrrolidone, quaternized pyrrolidone derivatives (eg,
Gaffquat 755N) from the National Specialty Products line up
Polyvinylpyrrolidone / dimethylaminoethyl methacrylate (obtained from ISP)
Available) and polyvinylpyrrolidone / acrylate (available from BASF)
Mention may be made of copolymers containing such pyrrolidone. Positive io also containing hydrophilic groups
Other materials, including polymers and polymers containing multiple ether linkages
It can provide dyeability and hydrophilicity. Cation-based materials include cation-based materials
Sugar and / or starch derivatives, including polypropylene oxide and ethylene
Typical block copolymer cleaning properties based on a mixture of oxides
Surfactants are typical of polyether materials. However,
Tell materials are less practical.       [0165]   Preferred polymers contain water soluble amine oxide moieties. Amine oxide
Partial positive charge acts to attach the polymer to the surface of the surface substrate
It is believed that water is more likely to become a "sheet" because it can. Aminoki
The sid part is also a ceramic tile, glass, fiberglass, enamel, linoleu.
Film, wax-free tiles, and other hard surfaces commonly encountered in consumer homes.
It is capable of hydrogen bonding with such hard surface substrates. The polymer adhesion is even more
High molecular weight materials are preferred to the extent that they promote "ting". Due to high molecular weight
Thus, the efficiency and effectiveness of amine oxide-based polymers is improved. Book
Preferred polymers of the invention are one or more containing at least one N-oxide group.
Of monomer units. At least about 10%, preferably greater than about 50%
And more preferably, more than about 90% of the monomers forming the polymer are
Contains amine oxide groups. The following general formula describes such polymers
Can be:       [0166]   P (B)   Where P is a homopolymerizable and copolyether that binds to form the polymer backbone.
Mer-formable moieties, preferably vinyl moieties such as C (R) 2--C (R) 2.
Then, at that time, R is H, C₁~ C₁₂(Preferably C.sub.1 to C.sub.4)
Alkyl (alkylene), C₆~ C₁₂With aryl (arylene) and / or B
B is substituted and unsubstituted, linear and cyclic C₁~
C₁₂Alkyl, C₁~ C₁₂Alkylene, C₁~ C₁₂Heterocycle, aromatic C₆~ C_{1 2} Is a moiety selected from the group
At least one existing amine oxide (-NSYMBOL 174 \ f "Symbol" \ s 12O
) Groups; u contains at least about 10% to about 90% amine oxide groups.
T is the number that provides the monomer;
About 500,000, preferably about 5,000 to about 250,000, more preferably
The number is about 7,500 to about 200,000.       [0167]   The preferred polymers useful in the cleaning component make the surface substrate attractive to consumers.
Expected to be substantive, leaving no visible residue to discourage
It has the characteristic of not doing. Preferred polymers include poly (4-vinylpyridine N-o
Xide) polymer (PVNO), for example by polymerization of a monomer containing the following moieties:
These include:   [Chemical 4]       [0168]   Wherein the average molecular weight of the polymer is about 2,000 to about 500,000, preferably
Is about 5,000 to about 400,000, more preferably about 7,500 to about 300.
1,000. High molecular weight polymers are generally preferred. High molecular weight poly
Mars often allow the use of polymers for low levels of wetting
Cleaning products can provide benefits. Desirability of Polymers Useful in the Invention
The preferable molecular weight range is 400,000 to 1,500,000.
Molecular weight polycarboxylate, polystyrene sulfonate, and polyether
In contrast to what is found in the art for polymer-based additives.
Is located in. Preferred poly-amine oxide polymers of the invention are smaller
Amount is extremely difficult to produce these higher molecular weight polymers
It depends.       [0169]   The level of amine oxide polymer is typically about 0.5 of the end use composition / solution.
Less than wt%, preferably from about 0.005 wt% to about 0.4 wt%, more preferably
Is about 0.01% to about 0.3% by weight.       [0170]   Homopolymers and copolymers that can be used as the water-soluble polymer of the present invention
Some non-limiting examples of mers are: adipic acid / dimethylamino hydroxypropyl die
Tylene triamine copolymer; adipic acid / epoxypropyl diethylene tria
Min Copolymer; Polyvinyl Alcohol; Methacryloyl Ethyl Betaine / Meta
Acrylate copolymer; ethyl acrylate / methyl methacrylate / methacrylate
Acid / acrylic acid copolymers; polyamine resins; and polyquaternized amine resins;
Li (ethenylformamide); poly (vinylamine) hydrochloride; poly (vinylalcohol)
Cole-co-6% vinylamine); poly (vinyl alcohol-co-12% vinyl)
Amine); poly (vinyl alcohol-co-6% vinylamine hydrochloride); and poly
(Vinyl alcohol-co-12% vinylamine hydrochloride). Preferably before
The above-mentioned copolymer and / or homopolymer are adipic acid / dimethylaminohydroxy.
Cypropyldiethylenetriamine copolymer; poly (vinylpyrrolidone / methac)
Dimethylaminoethyl phosphate); Polyvinyl alcohol; Ethyl acrylate /
Ethyl methacrylate / methacrylic acid / acrylic acid copolymer; methacryloyl
Ethyl betaine / methacrylate copolymer; polyquaternized amine resin; poly (d
(Tenylformamide); poly (vinylamine) hydrochloride; poly (vinyl alcohol)
-Co-6% vinylamine); poly (vinyl alcohol-co-12% vinylamine)
); Poly (vinyl alcohol-co-6% vinylamine hydrochloride); and poly (vinyl)
Rualcohol-co-12% vinylamine hydrochloride).       [0171]   The polymers useful in the cleaning component of the present invention are copolymers of hydrophilic monomers.
Can be selected from the group consisting of The polymer may be linear random or
Block copolymers, and mixtures thereof. The term "hydrophilic"
, As used herein, consistent with its standard meaning of having an affinity for water.
As used herein with respect to polymeric materials including monomer units and copolymers
Sometimes "hydrophilic" means substantially water-soluble. In this respect, "substantially water-soluble
Means a distillation (at 25 ° C. and a concentration of 0.2% by mass, preferably 1% by mass).
(Or equivalent) a water-soluble substance. To that end, the term "soluble
, "Solubility", etc., as applicable to water, as is well understood by those of skill in the art.
Or a monomer or a poiy which can be dissolved in another solvent to form a uniform solution.
Corresponds to the maximum concentration of limers.       [0172]   Non-limiting examples of useful hydrophilic monomers are acrylic acid, methacrylic acid, crotonic acid.
Unsaturated maleates such as maleic acid and its half-esters, itaconic acid, and
Polycarboxylic acid; unsaturated alcohol such as vinyl alcohol and allyl alcohol
A pole such as vinyl caprolactam, vinyl pyridine, vinyl imidazole
Vinyl Heterocyclic Compounds; Vinylamines; Vinylsulfonates; Acrylamide
, N, N-dimethylacrylamide, Nt-butylacrylamide
Unsaturated amides such as; hydroxyethyl methacrylate; dimethymethacrylate
Ruaminoethyl; salts of the acids and amines listed above; other; and mixtures thereof
Is. Some of the preferred hydrophilic monomers are acrylic acid, methacrylic acid, N, N
-Dimethylacrylamide, N.I. N-dimethylmethacrylamide, Nt-butyl
With luacrylamide, dimethylaminoethyl methacrylate, and mixtures thereof
is there.       [0173]   Polycarboxylate polymers at least partially contain carboxy functionality
It is formed by polymerization of the monomer. Common monomers include
Acrylic acid, maleic acid, ethylene, vinylpyrrolidone, methacrylic acid, methacrylic acid
Examples include roylethyl betaine. The preferred polymer for dyeability is
In addition, it has a high molecular weight. For example, having a molecular weight of less than about 10,000
The polyacrylic acid to be used is not particularly substantial, and therefore, usually higher levels and
Specific surfactants such as / or amphoteric and / or zwitterionic detersive surfactants
Providing hydrophilicity, even with a sexualizing agent, by rewetting 3 times with any composition
No, but a molecular weight reduced to about 1000 can provide some results
It Generally, the polymer is greater than about 10,000, preferably about 20,000.
More preferably above about 300,000, even more preferably above
It should have a molecular weight of greater than about 400,000. Higher molecular weight poly
Mers, eg, those having a molecular weight above 3,000,000, are formulated
Extremely low molecular weight polymer in providing a stain removal effect
It is also known to be less effective than. Therefore, the molecular weight is usually
For relates, about 20,000 to about 3,000,000; preferably about 2
50,000 to about 2,500,000; more preferably about 300,000 to about 2
,, 000,000; and even more preferably from about 400,000 to about 1,500.
Should be 1,000.       [0174]   The advantage of some polycarboxylate polymers is that such polymers have detergent detergents.
The effectiveness of Ruder. Such polymers, like other detergent builders, have
Film-forming / streaking, but containing particulate matter, typical
Provides enhanced cleaning effectiveness against static and common "hard to remove" stains
To do.       [0175]   Certain polymers, especially polycarboxylate polymers, have compositions that are aqueous solutions.
Thickens. This may be preferable. However, the trigger spray
-When the composition is placed in a container with the device, the composition may require excessive trigger pressure.
It's not rich. Generally, the viscosity under shear is less than about 200 cp, preferably
It should be less than about 100 cp, more preferably less than about 50 cp. However
However, it has a rich composition to stop the composition from flowing out to the surface, especially the vertical surface.
It is desirable to do.       [0176]   Non-limiting examples of polymers for use in the present invention include: ISP
Poly, sold under the name "Acrylidone" (registered trademark)
(Vinylpyrrolidone / acrylic acid) and the name "Accumer" (registered trader
Poly (Acrylic) sold by Rohm & Haas under
acid). Other suitable materials include Versaflex®.
, Especially National Starch & Chemical under the name Versaflex 7000
・ Sulfonated polystyrene polymer sold by the company
.       [0177]   The level of polymeric material is typically less than about 0.5%, preferably from about 0.01% to about.
0.4%, more preferably about 0.01% to about 0.3%. Generally small molecules
Low molecular weight substances such as poly (acrylic acid), eg less than about 10,000
, And especially those having a molecular weight of about 2,000, are particularly low levels, eg about
When rewetting with 0.02%, good stain removal effect cannot be obtained. At lower levels
Only more effective substances should be used. To use low molecular weight substances
To add a group that improves adhesion to the surface, for example a cationic group.
Dyeability should be increased by, or to a high level, for example about 0.05%
Substances should be used.       [0178]   Preferred polymers in the cleaning component are polystyrene sulfonates;
Polyvinylpyrrolidone; Polyvinylpyrrolidone acrylic acid copolymer; Polyvinyl chloride
Lupyrrolidone sodium salt of acrylic acid copolymer; polyvinylpyrrolidone ac
Potassium salt of phosphoric acid copolymer; polyvinylpyrrolidone-vinylimidazoline;
Polyvinyl pyridine; polyvinyl pyridine n-oxide; and combinations thereof
Is selected from the group consisting of: The preferred polymer is polyvinyl pyridine n-oxy.
It is       [0179]   Another embodiment of the cleaning component is an effective amount that is not a polymer as described above.
Of the detersive surfactant. A suitable detersive surfactant is included in the cleansing ingredients.
Suitable inclusions include those which are discussed above for foaming.       [0180]   Preferred surfactants for use herein are US Pat. No. 5,776,87.
No. 2 (Giret et al., Issued July 7, 1998); ibid., 5,883,0
No. 59 (issued March 16, 1999, Furman et al.); 5,88.
No. 3,062 (Addison et al., Issued March 16, 1999); and ibid.
No. 5,906,973 (issued May 25, 1999, Ouzounis)
Et al.) Alkylpolysaccharides.       [0181]   Suitable alkyl polysaccharides for use herein are US Pat. No. 4,565,6
No. 47 (issued January 21, 1986, Llenado)
Sparsely containing about 6 to about 30 carbon atoms, preferably about 10 to about 16 carbon atoms.
It has an aqueous group and a hydrophilic group of a polysaccharide, such as a polyglycoside. soot
Acidic or alkaline cleaning suite suitable for use in a tight process
For products / solutions, the preferred alkyl polysaccharides contain a wide distribution of chain lengths.
Are preferred, as they will remain after wetting, cleaning and drying.
Provides the best combination of low distillate. This "wide distribution" is about 1
A mixture of at least about 50% chain length containing from 0 carbon atoms to about 16 carbon atoms.
Is defined as Preferably, the alkyl group of the alkyl polysaccharide is preferably about 6
To a chain length of from about 18 carbon atoms, more preferably from about 8 to about 16 carbon atoms, and
Of hydrophilic groups containing about 1 to about 1.5 sugar groups, preferably glucoside groups, per child.
Composed of a mixture. This "broad chain length distribution" refers to about 10 carbon atoms to about 16 carbon atoms.
Defined by a chain length mixture of at least about 50% including atoms. Wide chain length
Some mixtures, especially C₈~ C₁₆Is particularly low compared to even narrower chain length mixtures.
Yes (ie C₈~ C_TenOr C₈~ C₁₂) Chain length alkyl polyglucoside mixture
Highly desirable compared to. Preferred C_8-16The alkyl polyglucoside of is C₈ ~ C₁₄As with other preferred surfactants containing alkyl ethoxylates of
Much improved over lower and narrower chain length alkyl polyglucosides
It has also been found to provide enhanced perfume solubility. For example, glucose, galactose
Any reducing sugar containing 5 or 6 carbon atoms such as sugar can be used.
The tososyl moiety can be replaced with a glucosyl moiety. (Optionally 2 hydrophobic groups
It binds to the position such as-, 3-, 4- and opposes to glucoside or galactoside.
It produces glucose or galactose. ) The inter-sugar linkage is, for example, an additional sugar
Between one position of the position and positions 2, 3, 4 and / or 6 of the existing sugar units. Glico
The sill is preferably derived from glucose.       [0182]   In some cases, although not always desirable, joins the hydrophobic and polysaccharide moieties.
Polyalkylene oxide chains can be present. Preferred alkylene oxide is ethylene
Oxide. Typical hydrophobic groups include 8 to 18 carbon atoms, preferably 10 carbon atoms.
There are saturated or unsaturated branched or straight chain alkyl groups having -16. Preferably
The alkyl group is a linear saturated alkyl group. Alkyl groups should have about 3 or less hydroxyl groups
Contained and / or polyalkylene oxide chain within about 10, preferably less than 5
Can contain an alkylene oxide moiety of The preferred alkyl polysaccharide is
Cutyl, nonyldecyl, undecyldodecyl, tridecyl, tetradecyl, pen
Tadecyl, hexadecyl, heptadecyl, octadecyl, di, tri, tetra, pe
And hexaglucosides, and / or galactoses. Suitable mixing
Examples include coconut alkyl, di-, tri-, tetra- and penta-glucosides and tallow.
There are alkyl, tetra, penta and hexaglucosides.       [0183]   To produce these compounds, alcohols or alkyl polyethoxy alcohols
First formed and then reacted with glucose or a glucose source.
Form a glucoside (bonded at position 1). The additional glycosyl units are then those
Position 1 and positions 2, 3, 4 and / or 6 of existing glycosyl units, preferably predominantly position 2
Can be combined with.       [0184]   In alkyl polyglycosides, the sugar moiety is created from hydrolyzed polysaccharides.
However, the alkyl moieties are derived from fats, oils or chemically produced alcohols.
You can Alkyl polyglycosides are relatively hydrophilic with aliphatic alcohols.
Condensation formation of sugars such as glucose, with the number of glucose units defining sex
It is a thing. As discussed above, either before or after reaction with the fatty alcohol
The sugar units can be alkoxylated there. For example, such alkyl poly
Glycosides are described in detail in WO86 / 05199. Typical
Lucyl polyglycosides are generally not molecularly homogeneous products, but alkyl
It represents a mixture of groups and a mixture of monosaccharides and other oligopolysaccharides. Alkyl polyglyco
Sids (sometimes referred to as “APG”), compared to other surfactants
Preferred for the purpose of the invention, as it offers additional improvements in surface appearance
Yes. The glycoside moiety is preferably a glucose moiety. Alkyl substituents are preferred
Preferably it contains from about 8 to about 18 carbon atoms, preferably from about 8 to about 10 carbon atoms.
A saturated or unsaturated alkyl moiety, or a mixture of such alkyl moieties.
C₈~ C₁₆Alkyl polyglucosides are available from Seppic Corporation.
Corporation) (75 Quai d'Orsay, France, 75321 Paris, Cedex 7)
Commercially available from, for example, Simusol® surfactants.
And Glucopon® 425 available from Henkel
. However, the purity of the alkyl polyglucoside depends on its performance, especially in everyday showers.
It has been found that it can also affect the end result of certain products, including product technology
. In the present invention, preferred alkyl polyglucosides are personal cleansing agents.
It has been sufficiently purified to be used in. The most preferable one is
Cosmetic grade "alkyl polyglucosides, especially C₈~ C₁₆The alkyl
Polyglucosides, such as Henkel Corpo
ration) (Postfach 101100, D Düsseldorf D40191, Germany)
Plantaren 200 available from Postfaq 101100)
0 (registered trademark), Plantarene 2000N (registered trademark), and Plantaren 20
00NUP (registered trademark). Therefore, even if such a surfactant is used,
When used in a null care product, it is preferably used in a cleansing ingredient.       [0185]   Another preferred nonionic surfactant for floors, counters, walls, etc.
Is a class of alkyl ethoxylates. Alkyl ethoxylates of the present invention
Is either linear or branched and has from about 8 to about 14 carbon atoms and from about 4 to about 2
Contains 5 ethylene oxide units. Examples of alkyl ethoxylates include
Shell Corporation (Sherry, Houston, Texas)
Neodol (registered trademark) supplied from Le Plaza, PO Box 2463)
91-6, Neodol 91-8 (registered trademark), and Vista Corporation (Vi
sta Corporation) (Thread Needle 900 Houston Houston Texas)
Alfonic® 810 supplied from box 19029)
-60 can be mentioned. More preferred surfactants are from about 9 to about 12 carbon atoms,
And alkyl ethoxylates containing from about 4 to about 8 ethylene oxide units.
. Such surfactants provide excellent cleaning effect and require the required parent
Works synergistically with aqueous polymers. The most preferred alkyl ethoxylates are commercial
Shell Chemical Company under the standard Neodol (registered trademark) 1-5
C available from (Shell Chemical Company)₁₁EO_FiveIs. This surfactant
Has been found to provide desirable wetting and cleaning properties, and
C preferred in matrix containing light wet polymer_8-16Alkylpo
It can be advantageously combined with lyglucoside. To be limited by theory
I don't want, but C_8-16Alkyl polyglucosides are additionally preferred alkyl
Compositions containing ethoxylates, especially the preferred alkyl ethoxides for excellent cleaning
Excellent end result (ie less haze) when sylate is desired
Is believed to be able to provide. Preferred C_8-16Alkyl polyg
Lucoside also improves the perfume solubility of compositions containing alkyl ethoxylates
I know that. Higher levels of perfume are favorable for consumers to accept
is there.       [0186]   More preferred detersive surfactants are from about 8 to about 18 carbon atoms, more preferably
Or an alkyl group containing from about 8 to about 16 carbon atoms, and from about 1 to about 4 per molecule.
Alkyl polysaccharide detersive surfactants preferably having about 1 to about 1.5 sugar moieties and
And / or about 8 to about 16 carbon atoms and about 4 to about 25 oxyethylene units.
About 8 to about 18 carbon atoms, more preferably about 8 carbon atoms with the rukyi ethoxylate.
An alkyl group containing from about 16 to about 16 carbon atoms, and from about 1 to about 4, preferably per molecule.
Is a set of alkyl polysaccharide detersive surfactants having about 1 to about 1.5 sugar moieties
Selected from the group consisting of combinations and combinations thereof.       [0187]   The liquid cleaning component according to the invention together with relatively low levels of active substance
Is prepared. Generally, such cleaning components are adequately bound as discussed below.
Includes surface-active agents and optional solvents, when hard surfaced detergents are still economical.
They are therefore effective; therefore, they usually account for about 0.005% to about 0.5% of the composition amount.
Surfactants, preferably alkyl polyglycosides and / or C_8-14The alkyl
Ethoxylate surfactants, more preferably from about 0.01% to about 0.4% interfacial.
An active agent, and even more preferably from about 0.01% to about 0.3% surfactant.
It Low levels of surfactant rather than high levels favor overall end effect
It is known that Alkyl ethoxide preferred major surfactant system
When including silates, the spiders finally obtained with a special cosurfactant
It has also been found that the risk will be alleviated. A preferred cosurfactant is C₈Su
Rufonate and Poly-Tergent CS-1.       [0188]   The articles of the present invention may be particularly useful in the field of household care. For example, a book
Put the items in a storage bag with clothes, then put the storage bag in a dryer and
It may be used as an inside cleaning and / or refreshing article for clothing.
Against this background, the articles of the present invention may be substantially dry or wet.
Good. Preferably, the articles of the present invention suitable for cleaning in a dryer are water and water.
And surfactants, fragrances, preservatives, bleaches, cleaning aids, organic solvents and those
A member selected from the group consisting of mixtures of The preferred organic solvent is glyco
And ethers such as methoxypropoxypropanol and ethoxy.
Propoxy propanol, propoxy propoxy propanol, butoxy propo
Xypropanol, butoxypropanol and mixtures thereof. Surface activity
The agent is preferably an ethoxylated alcohol or an ethoxylated alkylphenol.
Non-ionic surfactants such as
Present up to 2% by weight. Typical cleaners suitable for fabric cleaning herein
The ingredient is at least about 80% by weight of water, preferably at least about 90% by weight.
More preferably at least about 95% by weight water.       [0189]   Suitable organic solvents and surface active agents that can be contained in the cleaning component of the present invention
Stabilizers, fragrances, preservatives, bleaches and cleaning aids are described in US Pat. No. 5,789,368.
(You, et al., Issued Aug. 4, 1998), and US Pat. No. 5,591,2.
No. 36 (issued January 7, 1997, Roetker et al.)
it can. The entire disclosures of the Yu and et al. Patents are incorporated herein by reference.
Be done. In addition, US patent copending application 08 / 789,171 (Trin
h) et al., submitted on January 24, 1997) is a suitable cleaning ingredient.
Certain additional compositions are described. This disclosure is based on the entire disclosure of the application of Trin et al.
Incorporate in the detailed document.       [0190]   In the context of fabric cleaning / refreshing, the inventive cleaning solution
The component is preferably ethylene glycol, all isomers of propanediol,
All isomers of tandiol, all isomers of pentanediol, hexanediol
Selected from the group consisting of all isomers of and mixtures thereof, more preferably
Neopentyl glycol, polyethylene glycol, 1,2-propanediol
, 1,3-butanediol, 1-octanol and mixtures thereof
It is preferred to include a shrinkage reducing composition selected from: Shrinkage reducing compositions are preferred
Preferred is neopentyl glycol or 1,2-propanediol, and
Preferred is 1,2-propanediol. Shrinkage reducing composition and cleaning composition
The ratio of minutes is preferably about 1: 2 to about 1: 5, preferably about 1: 2 to about 1: 4.
It is preferably about 1: 3 to about 1: 4, and most preferably about 1: 3.6.   In addition to the above ingredients, the cleaning ingredients are optionally bleaching agents, preferably peroxide water.
It may include elements.       [0191]Polishing / cleaning ingredients   The benefit component of the presently disclosed articles may be a polishing / cleaning component. Starting
The polishing / cleaning effect of a bright article is the same as any polishing / cleaning effect that enhances the adhesion of dirt to this article.
By treating the fibers of the sheet with a sweeping ingredient, especially by treating the surface
It can be further increased. When used, enhances the ability of this article to attach dirt
The polishing / cleaning ingredients of the article are added at a level sufficient to But Naga
The surface is polished or cleaned so that it is visually acceptable to the consumer.
Additive levels to minimize the amount of residue left on the surface to be
And type must be selected. Such additives are preferably at least about
0.01 wt%, more preferably at least about 0.1 wt%, more preferably
Is at least about 0.5% by weight, more preferably at least about 1% by weight, and
More preferably at least about 3% by weight, even more preferably at least about 4% by weight.
It is applied to this article in the amount of addition amount of%. Generally, the amount added is from about 0.1 to about
25% by weight, more preferably about 0.5 to about 20% by weight, still more preferably about 1
To about 15% by weight, even more preferably about 2 to about 10% by weight, even more preferred.
Or about 4 to about 8% by weight, and most preferably about 4 to about 6% by weight.       [0192]   The preferred polishing / cleaning ingredients are waxes, oils, and combinations thereof
Including substances selected from Suitable waxes include various types of hydrocarbons,
Esters of certain fatty acids (eg saturated triglycerides) and fatty alcohols
Is mentioned. They are derived from natural sources (ie animals, plants or minerals)
It can also be synthesized. Mixtures of such various waxes are also used.
You can Representative animal waxes and plants that can be used in the present invention
Some of the waxes include beeswax, carnauba, spermaceti, lanolin, shellac wax, and can.
Delilah etc. are mentioned. Representatives derived from mineral resources that can be used in the present invention
Typical waxes are petroleum-based such as paraffin, petrolatum and microcrystalline wax.
Such as whitened wax, white ceresin wax, yellow ceresin wax, white ground wax, etc.
Stone or soil wax may be mentioned. Representative syntheses that can be used in the present invention
For wax, ethylene polymer such as polyethylene wax, fisher
"Halo wax", charcoal made by Fischer-Tropsch synthesis
Examples thereof include chlorinated naphthalene such as hydrogenated wax. Other preferred
The polishing / cleaning ingredient is supplied as a mixture of wax and oil such as petrolatum.       [0193]   A preferred polishing / cleaning ingredient comprises a mixture of wax and mineral oil, which is the present article.
Particles from the surface while minimizing the amount of residue left on the surface being wiped with
Enhances the ability of the article to capture and retain child matter. Mineral oil and wax mixture
Is utilized, the component is preferably from about 1:99 to about 7: 3, more preferably
Is about 1:99 to about 3: 2, and even more preferably about 1:99 to about 2: 3 oil and wax.
Are mixed in a mass ratio of x. In a particularly preferred embodiment, the mass of oil and wax
The ratio is about 1: 1 and the additive is applied at a loading of about 5% by weight. Polish / Clean
The preferred mixture as a component is a 1: 1 mixture of mineral oil and paraffin wax.
.       [0194]   Of waxes such as paraffin wax as a polishing / cleaning ingredient in this article
You can also use only If the wax is a polishing / cleaning ingredient only, this article
Are preferably composed of synthetic fibers, so that the article still has electrostatic properties.
Maintains and enhances capture and retention of particulate matter. Book in any event
If the laminated web of the article contains natural and / or synthetic fibers, is it essentially waxy?
A polishing / cleaning component comprising less than about 4% by weight of the article, preferably less than about 3% by weight.
, More preferably less than about 2% by weight, and even more preferably less than about 1% by weight.
It is usually applied to a laminated web in an addition amount of. Wax is accumulated at a higher level
When applied to a layered web, the electrostatic properties of the article are reduced and thus the overall article
Such a level is preferable because the polishing / cleaning effect is also reduced.       [0195]   It is also possible to utilize only mineral oil as the polishing / cleaning component in the article. Essence
Polishing / scavenging ingredients, which consist essentially of mineral oil, are less than about 4% by weight of the article, preferably about 3%.
Less than 1% by weight, more preferably less than about 2% by weight, and even more preferably about 1% by weight.
It is usually applied to laminated webs at loadings of less than wt%.       [0196]   The additive is at an effective level, and preferably at least one independent
Such low levels are particularly desirable when applied to a continuous area in a substantially uniform manner.
Good Especially, a polishing / cleaning component which improves the adhesion of dirt to an article is preferably low in level.
The use of this product improves the adhesion of dirt to the product and prevents dust in the air.
Suppressing, positive consumer impression, especially tactile impression, in addition to polishing / cleaning success
Minerals are used as fragrances, pest control ingredients, antibacterial agents, including antifungal agents, and many other beneficial ingredients.
Provides a means to incorporate and bind components, especially those that are soluble or dispersible in additives
To do. Such benefits are for illustrative purposes only.       [0197]   Preferably, the polishing / cleaning component is not used for polishing and / or dust removal.
If not, it does not significantly reduce the electrostatic properties of the article. The article of the present invention is particulate
This is used to facilitate the capture and retention of substances, especially fine dust particles.
When used in such a background, it is preferable to have electrostatic properties.       [0198]   Polishing / cleaning ingredients can be applied to the article via a variety of application methods.
Such methods include manual rolling, mechanical rolling, vertical milling, ultrasonic
Examples include play, pressure spray, pump spray, dipping and the like. Shine /
The preferred method of applying the cleaning component to the article is ultrasonic spraying. Polish / Clean
The components are preferably evenly sprayed onto the laminated web of the article.       [0199]   Another preferred method of applying polishing / cleaning ingredients to the article is mechanical rolling.
It is Gu. Coated with polishing / cleaning ingredients to be applied during the manufacturing process of the article
They are fed through a series of rollers. In a pot or container containing the ingredients
By spinning it can be coated with a polishing / cleaning ingredient. Through the roller
When delivered to the article, the components transfer from the rollers to the article. Shine / clear
If the scavenging component is a mixture of wax and mineral oil, especially with a wax to mineral oil ratio of 1: 1,
In order to keep the polishing / cleaning ingredient in a liquid state, a pot or a volume containing the polishing / cleaning ingredient
Heating the vessel to a temperature of about 32 ° C to about 98 ° C, preferably about 40 ° C to about 65 ° C.
preferable. In such situations, a temperature similar to that of the hot component in the liquid state is preferred.
Heat the roller every time. Generally, the temperature of the ingredient mixture and the roller is
At least about 5 ° C to about 10 ° C above the melting point of.       [0200]   For small-scale manufacturing of this article, use hand-operable rollers and roll the ingredients.
Roller, including rolling the roller and rolling the roller across the surface of the article.
The components can be applied to the article via the ring.       [0201]Moisture retention measurement method   As noted above, in certain embodiments, the articles of the present invention are "substantially dry".
It is believed that As used herein, "substantially dry" refers to the invention.
The moisture retention value of the article is less than about 0.95 gms, preferably less than about 0.75 gms,
More preferably less than about 0.5 gms, more preferably less than about 0.25 gms,
Still preferably less than about 0.15 gms, most preferably less than about 0.1 gms.
Means that. Moisture retention value is perceived when a user touches a particular article of the invention.
It exhibits a dry feel, which is the opposite of that of a "wet" wipe.       [0202]   On the other hand, there are articles of the invention that are "substantially wet". As used herein
“Substantially wet” means that the product feels wet to the touch of the consumer.
Means and. That is, such articles exhibit moisturizing values greater than about 0.95 gms.
You       [0203]   To quantify the moisturizing value of this article and other disposable substrate-based products,
The following equipment and materials are required:   [Table 1]       [0204]   Then weigh the two paper towels separately and record each weight. 1 sheet of paper
-Place the towel on a flat surface (eg laboratory bench). Sample items,
Place it on the towel. Place another towel on the sample article. next,
On top of the sample article on the sandwich, lexein, and 2000 g of main
Place Wait 1 minute. After 1 minute, remove the weight and lexain. Top and bottom
Weigh a paper towel and record the weight.       [0205]   Start with final mass (after 1 minute) for both top and bottom paper towels
Moisture retention value is calculated by subtracting the weight of the paper towel. Top and bottom
Add the mass difference obtained for the paper towels. Tested on a large number of articles
Assuming that the total mass difference is averaged to obtain the moisturization value.       [0206]Optional ingredients suitable for inclusion in the personal care products of the present invention   Articles of the present invention that are suitable for personal care applications may not tolerate the benefits of the present invention.
Like conventional use in a given product form, provided that it does not change
, May contain various other ingredients. These optional ingredients are applied to human skin and hair.
Should be suitable for application, i.e., having the correct medical
Excessive toxicity, incompatibility, instability, allergy within the judgment of the common sense or the formulator
It should be suitable for use in contact with human skin without reaction or the like. CT
FA Cosmetic Ingredient Handbook (CTFA CosmeticIngredientHandbook), 2nd Edition
(1992) includes various non-standard products commonly used in the skin care industry.
Limited cosmetic and pharmaceutical components are described, which are articles of the invention.
Suitable for use in.       [0207]   In the personal care area, examples of suitable optional ingredients are: enzymes; abrasives; skins.
Skin peeling agents; Absorbents; Perfumes, pigments, colorants / colorants, essential oils, skin irritants, astringents
Cosmetic ingredients such as agents (eg clove oil, menthol, camphor, eucalyptus oil)
, Eugenol, menthyl lactate, dianthus genus); anti-acne agents (eg
, Resorcinol, sulfur, salicylic acid, erythromycin, zinc, etc.);
Antifoaming agent; Antifoaming agent; Additional antibacterial agent (eg, iodopropyl butyl carbamate)
Antioxidants; Binders; Biological additives; Buffers; Fillers; Chelating agents; Chemistry
Additives; Colorants; Astringents for cosmetics; Disinfectants for cosmetics; Modifiers; Astringents for medicines;
Pain; film-forming agent or material such as film-forming property and direct dyeing property of the above composition
Supporting polymers (eg copolymers of eicosene and vinylpyrrolidone);
Moisturizers; opacifiers; pH adjusters; propellants; reducing agents; sequestering agents; skin bleaching agents
(Or whitening agent) (eg hydroquinone, kojic acid, ascorbic acid, ascor
Magnesium phosphate phosphate, ascorbyl glucosamine); skin soothing agent and / or
Is a therapeutic agent (eg panthenol and derivatives (eg ethyl panthenol),
Aloe vera, pantothenic acid and its derivatives, allantoin, bisabolol, and
And dipotassium glycyrrhizinate); skin wrinkle inhibitors, retarders, inhibitors, and
And / or rejuvenating agents such as skin treating agents (eg, α-hydrides such as lactic acid and glycolic acid).
Β-hydroxy acids such as roxy acid and salicylic acid); thickeners; hydrocolloids;
Certain zeolites, and vitamins and their derivatives (eg tocofellow)
, Tocopherol sorbate, tocopherol acetate, β-carotene,
Tinoic acid, retinol, retinoid, retinyl palmitate, niacin, ni
Cotinamide and the like). The article of the present invention comprises carrier components as known
May be included. Such carriers are suitable for application to the skin or hair.
, One or more compatible liquid or solid extending diluents or vehicles.       [0208]   The articles of the present invention may optionally contain one or more such optional ingredients. Par
Preferred articles of the invention that are suitable for personal care applications include vitamin compounds, skin treatments.
Treatment agent, anti-acne agent, anti-wrinkle agent, anti-skin atrophy agent, anti-inflammatory agent, local anesthetic, artificial sunburn
Sunscreen and sunscreen, antimicrobial, antifungal, sunscreen, antioxidant, skin
A therapeutic benefit agent selected from the group consisting of depigmenting agents and combinations thereof.
Optionally comprising a safe and effective amount of a therapeutically beneficial ingredient. Used in this specification
“Safe and effective amount” is sufficient to cause a significant effect or benefit.
But avoid serious side effects (eg excessive toxicity or allergic reactions)
Is small enough, i.e. within reasonable medical decency, there is a reasonable interest rate for risk.
By an amount of a compound or ingredient that provides a benefit.       [0209]   The optional ingredients useful in the present invention are predicated on their therapeutic or aesthetic benefit or premise.
It can be classified according to the mode of action. However, in this specification
Useful optional ingredients may, in some cases, provide multiple therapeutic or aesthetic benefits, or
It should be understood that it works through a mode of action. Therefore, in this specification
Classification is for convenience only and should be limited to specific or listed applications of the ingredient.
It's not something to try. Also, where applicable, the ingredients are pharmaceutically acceptable.
Salts are also useful in the present invention.       [0210]Vitamin compounds   Articles of the present invention may include vitamin compounds, precursors, and derivatives thereof
. Such vitamin compounds may be in natural or synthetic form.
Suitable vitamin compounds include vitamin A (eg beta carotene, retino
In acid, retinol, retinoid, retinyl palmitate, reti proprionate
Nil), vitamin B (eg, nicotinic acid, nicotinic acid amide, riboflavin)
, Pantothenic acid, etc.), vitamin C (eg, ascorbic acid, etc.), vitamin D (
For example, ergosterol, ergocalciferol, cholecalciferol, etc.
), Vitamin E (eg, tocopherol acetate, etc.), and vitamin K (eg,
For example, phytonadione, menadione, futhiochol, etc.
Not limited to.       [0211]   In particular, the article of the present invention provides a safe and effective amount of vitamin B.₃A compound may be included.
Vitamin B₃The compounds are incorporated herein by reference in their entirety, 1997
US Patent Co-pending Application No. 08 / 834,010, filed April 11
Issue (International Publication WO97 / 39733A1 published on October 30, 1997)
Is particularly useful for regulating the condition of the skin as described in (1). Book
The therapeutic component of the invention is preferably about 0.01 to about 50% by weight, more preferably about 0.
． 1 to about 10% by weight, even more preferably about 0.5 to about 10% by weight, even more preferably
Preferably about 1 to about 5% by weight, most preferably about 2 to about 5% by weight of vitamin B.₃Compound
Including things.       [0212]   As used herein, "vitamin B₃“Compound” means a compound having the following structural formula.
Taste:   [Chemical 5] In the formula, R is -CONH₂(That is, nicotinic acid amide), -COOH (that is, nicotine
(Tinic acid) or -CH₂OH (ie nicotinyl alcohol); derivatives thereof
And any one of the above salts.       [0213]   Vitamin B₃Derivatives of compounds include non-vasodilators of nicotinic acid.
, Nicotinyl amino acid, nicotinyl alcohol ester of carboxylic acid, nicotine
Nicotinic acid esters such as acid N-oxide and nicotinic acid amide N-oxide
Can be mentioned.       [0214]   Suitable vitamin B₃Examples of compounds are well known to the person skilled in the art, for example Sigma Chemica
Sigma Chemical Company (St. Louis, MO); ICN
Biomedicals (Irvine, CA) and Aldrich Chemica
Many like Le Company (Milwaukee, WI)
Are available from commercial sources.       [0215]   Vitamin compounds can be used as a substantially pure ingredient or as a natural (eg, plant) source.
An extract obtained by suitable physical and / or chemical separation from the ingredients,
May be included.       [0216]Skin treatment agent   The articles of the present invention may contain one or more skin treatment agents. A suitable skin treatment agent is
Effective in preventing, delaying, stopping and / or overcoming skin wrinkles
Including things. Examples of suitable skin treatment agents include agents such as lactic acid and glycolic acid.
Beta-hydroxy acids such as rufa-hydroxy acid and salicylic acid may be mentioned.
However, it is not limited to this.       [0217]Anti-acne agent   Examples of anti-acne agents useful in the articles of the present invention include salicylic acid (o-hydroxy).
Benzoic acid), derivatives of salicylic acid such as 5-octanoylsalicylic acid, and resor
Keratolytic agents such as cinol; retinoic acid and its derivatives (eg cis and trans)
) And the like; sulfur-containing D-type and L-type amino acids and their derivatives
And salts, especially their N-acetyl derivatives, preferred examples being N-acetyl
-L-cysteine; lipoic acid; benzoyl peroxide, octopirox, tetracy
Cleanse, 2,4,4'-trichloro-2'-hydroxydiphenyl ether, 3
, 4,4'-trichlorovanillide, azelaic acid and its derivatives, phenoxy
Ethanol, phenoxypropanol, phenoxyisopropanol, ethyl acetate
And clindamycin and meclocycline antibiotics and antibacterial agents; flavono
Sevostat such as id; and cymnol sulfate and its derivatives, deoxychol
Acids and bile salts such as cholic acid are included, but are not limited to.       [0218]Anti-wrinkle agent and anti-skin atrophy agent   Examples of anti-wrinkle and anti-skin atrophy agents useful in the articles of the invention include retinoic acid and its anti-wrinkle agents.
Derivatives (eg cis and trans); retinol; retinyl ester; nicotine
Acid amide, salicylic acid and its derivatives; sulfur-containing D and L amino acids
And its derivatives and salts, in particular its N-acetyl derivative, preferred examples being N
-Acetyl-L-cysteine; thiols such as ethanethiol; terpene al
Kohl (eg farnesol); hydroxy acid, phytic acid, lipoic acid; lyso
Examples include phosphatidic acid and skin peeling agents (such as phenol).
It is not limited to this.       [0219]Non-steroidal anti-inflammatory drug (NSAIDS)   Examples of NSAIDS useful in the articles of the invention include, but are not limited to:
Lower categories: Propionic acid derivatives; Acetic acid derivatives; Phenamic acid derivatives; Bif
Phenyl carboxylic acid derivatives; and oxicam. Such NSAID
All S are U.S. Pat. No. 4,985,459 issued by Jan. 15, 1991
All et al.), All of which are incorporated herein by reference.
Examples of useful NSAIDS include acetylsalicylic acid, ibuprofen, naps
Loxene, benoxaprofen, flurbiprofen, fenoprofen, fe
Nbufen, ketoprofen, indoprofen, peerprofen, carprof
En, oxaprozin, pranoprofen, microprofen, tioxaprof
Enene, suprofen, aluminoprofen, thiaprofenic acid, fluprofen
And bacloxylic acid. In addition, steroids including hydrocortisone etc.
Anti-inflammatory drugs are also useful.       [0220]Local anesthetic   Examples of anesthetics useful in the articles of the invention include benzocaine, lidocaine, bupine.
Bakaine, chlorprocaine, dibucaine, etidocaine, mepivacaine, tet
Racaine, dyclonine, hexylcaine, procaine, cocaine, ketamine,
Ramoxins, phenols, and pharmaceutically acceptable salts thereof, including
It is not limited to this.       [0221]Artificial tanning agents and promoters   Examples of artificial tanning agents and promoters useful in the articles of the present invention include dihydroxy alcohols.
Seton, tyrosine, tyrosine esters such as ethyl tyrosinate, and phospho-D
Examples include, but are not limited to OPA.       [0222]Antibacterial and antifungal agents   Examples of antibacterial and antifungal agents useful in the articles of the invention include beta-lactam agents.
, Quinolones, ciprofloxacin, norfloxacin, tetracycline, d
Lithromycin, amikacin, 2,4,4'-trichloro-2'-hydroxydi
Phenyl ether, 3,4,4'-trichlorocarbanilide, phenoxyethano
, Phenoxypropanol, phenoxyisopropanol, doxycycline
, Capreomycin, chlorhexidine, chlortetracycline, oxyte
Tracycline, clindamycin, ethambutol, hexamide isethionate
, Metronidazole, pentamidine, gentamicin, kanamycin, lineo
Mycin, metacycline, methenamine, minocycline, neomycin, neti
Lumicin, paromomycin, streptomycin, tobramycin, miconazo
, Tetracycline hydrochloride, erythromycin, zinc erythromycin, erythr
Romycin estrato, erythromycin stearate, amikacin sulfate, salt
Acid doxycycline, capreomycin sulfate, chlorhexidine gluconate, salt
Chlorhexidine acid, chlortetracycline hydrochloride, oxytetracycline hydrochloride
, Clindamycin hydrochloride, ethambutol hydrochloride, metronidazole hydrochloride, hydrochloric acid
Pentamidine, gentamicin sulfate, kanamycin sulfate, lineomycin,
Metacycline hydrochloride, methenamine hippurate, methenamine mandelic acid, minosa hydrochloride
Iclin, neomycin sulfate, netilmicin sulfate, paromomycin sulfate, sulphate sulfate
Treptomycin, tobramycin sulfate, miconazole hydrochloride, amanfazi hydrochloride
, Amanfazine sulfate, octopirox, parachlorometaxylenol, sodium
Includes isatin, tolnaftate, zinc pyrithione and clotrimazole
However, it is not limited to this.       [0223]Antiviral agent   The articles of the present invention may further comprise one or more antiviral agents. Suitable anti-virus
Examples of the agent include metal salts (eg, silver nitrate, copper sulfate, iron chloride, etc.) and organic acids (eg,
Examples include malic acid, salicylic acid, succinic acid, benzoic acid, etc.
Not limited. Specific compositions containing additional suitable antiviral agents are each
U.S. Patent Co-pending Application No. 09 /
421,084 (Beerse et al.); 09 / 421,131 (Bi
Biedermann et al .; id 09 / 420,646 (Morgan
) Et al .; and No. 09 / 421,179 (Page et al.)
One of them is.enzyme       [0224]   Articles of the invention may optionally include one or more enzymes. Preferably like this
Different enzymes are dermatologically acceptable. Suitable enzymes include keratinase, pro
Examples include thease, amylase, subtilisin, and other peptides.
It is not limited to these.       [0225]   Without limitation, di-, tri-, tetra-, and pentapep
Peptides such as tide and their derivatives are present in safe and effective amounts for the components of the present invention.
May be included. As used herein, the term "peptide" refers to the natural
And both synthetic peptides. Also useful herein
There are naturally occurring and commercially available compositions containing peptides.       [0226]   Suitable dipeptides for use herein include Carnosine,
Beta-ala-his). Tripe suitable for use herein
The peptide is gly-his-lys, arg-lys-arg, his-gly.
-Gly. The presently preferred tripeptides and their derivatives include:
Lumitoyl-gly-his-lys, biopeptide CL (registered trademark, palmi
Sederma (Ted-gly-his-lys 100 ppm)
Lance); peptide CK (arg-lys-arg); pep
Cide CK + (ac-arg-lys-arg-NH₂); And Sigma
Commercially available as Iamine from St. Louis, Missouri, USA
Examples thereof include a copper derivative of -gly. Suitable tetrapeptides for use in the present invention
Includes peptide E, arg-ser-arg-lys (SEQ ID NO: 1)
. Pentapeptides suitable for use in the present invention include lys-thr-thr-lys.
-Ser is included. Preferred commercially available pentapeptide derivative compositions are
Trixyl (Matrixyl®), which is palmitoyl-lys-thr-
thr-lys-ser 100 ppm (SEQ ID NO: 2, Sederma, Fra
Commercially available)) is included.       [0227]   Preferably the peptide is palmitoyl-lys-thr-thr-lys-s.
er, palmitoyl-gly-his-lys, beta-ala-his, it
Selected from these derivatives, and combinations thereof. Peptides are more preferred
Is palmitoyl-lys-thr-thr-lys-ser, palmitoyl-g
selected from ly-his-lys, their derivatives, and combinations thereof.
It Even more preferably, the peptide is palmitoyl-lys-thr-thr-.
selected from lys-ser and its derivatives.       [0228]   When included in the components of the present invention, the peptide has a mass of the components preferably
About 1 x 10^-6% To about 10%, more preferably about 1 × 10^-6% To about 0.1%, and
More preferably about 1 × 10^-Five% To about 0.01%. The above peptide
However, for certain ingredients where Carnosine® is the ingredient is preferably that ingredient
Of the peptide is about 0.1 to about 5% by weight. Matrixil
ixyl, registered trademark), and / or biopeptide CL (Biopeptide, registered trademark)
In the example of other peptide-containing components included, the components are preferably about 0.
1 to about 10% of Matricel® and / or biopeptide CL (registered)
Registered trademark).       [0229]Sunscreen activator   Sunscreens are also useful in the present invention. A wide variety of sunscreens
US Pat. No. 5,087,445 (issued February 11, 1992, Haffey
) Et al .; U.S. Pat. No. 5,073,372 (issued December 17, 1991, Tar
Turner et al .; US Pat. No. 5,073,371 (December 17, 1991).
Published by Turner et al .; and Segarin et al., “Cosmetics
189 of Chapter VIII of "Cosmetics Science and Technology"
It is described in the following pages, all of which are incorporated herein by reference in their entirety.
Put in. Non-limiting examples of sunscreens useful in the compositions of the present invention include 2-
Ethylhexyl p-methoxycinnamic acid ester, 2-ethylhexyl N, N-dime
Tiru-p-aminobenzoic acid ester, p-aminobenzoic acid, 2-phenylbenz
Imidazole-5-sulfonic acid, octocrylene, oxybenzene, homomethyl
Salicylic acid, octyl salicylate, 4,4'-methoxy-t-butyldibenzoi
Lumethane, 4-isopropyldibenzoylmethane, 3-benzylidene camphor
, 3- (4-methylbenzylidene) camphor, titanium dioxide, zinc oxide, silyl
Some are selected from the group consisting of mosquitoes, iron oxides, and mixtures thereof. Still
Other useful sunscreens are available from Sabatell (June 26, 1990).
i) US Pat. No. 4,937,370 and Sabaté issued March 12, 1991.
As disclosed in U.S. Pat. No. 4,999,186 to Sabatelli et al.
Yes, all of these two references are incorporated herein by reference. like this
As a particularly preferable example of the sunscreen agent, 2,4-dihydroxybenzopheno
4-N, N- (2-ethylhexyl) methylaminobenzoic acid ester, 4-
4-N, N- (2-ethylhexyl) methyl with hydroxydibenzoylmethane
Aminobenzoic acid ester, 2-hydroxy-4- (2-hydroxyethoxy) be
Nzophenone 4-N, N- (2-ethylhexyl) methylaminobenzoic acid
Ter, 4-N, N- (2 of 4- (2-hydroxyethoxy) dibenzoylmethane
-Ethylhexyl) methylaminobenzoic acid ester, and mixtures thereof.
And those selected from the group. The exact sunscreen that can be used
The amount depends on the sunscreen chosen and the desired sun protection factor (SPF) achieved.
Exist and change. SPF is a commonly used sunscreen for erythema
It is a protection index. In this specification, the Federal Register, which is incorporated by reference in its entirety (Vol. 43,
NO. 166, pages 38206-38269, August 25, 1978).
That.       [0230]Hydrocolloid   Hydrocolloids may also optionally be included in the articles of the invention. Hydrocoloy
Are well known in the art, and the article may be used for at least one complete shower or shower.
Usefulness of surfactants included in the cleansing ingredients of the present invention to last for the duration of the bath
It is effective for extending the period. Suitable hydrocolloids include xanthan
Gum, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxyl
Propyl cellulose, methyl and ethyl cellulose, natural rubber, gadras (gudr
as) guar gum, bean gum, natural starch, deionized starch (eg
Examples thereof include starch octyl succinic acid) and the like, but are not limited thereto.       [0231]Pyrogenic zeolite   Zeolites and other compounds that undergo an exothermic reaction when mixed with water are also of the invention.
It may optionally be included in the article.       [0232]Oil-soluble polymer gelling agent   Articles of the present invention are preferably oil-soluble and hydrophobic materials of therapeutically beneficial ingredients (
For example, one or more polymeric materials that form a gel with an oil). Such poly
Ma structured such materials resulting in improved stability and shear resistance.
And is beneficial for producing a soft gel.       [0233]   If a hydrophobic gel is present, the article preferably comprises a polymeric gelling agent dry matter.
From about 0.05% to about 100% by weight of the substrate sheet, calculated on the basis of the amount
More preferably from about 0.1% to about 20%, and most preferably about 1%.
To about 10% by weight oil-soluble polymer gelling agent.       [0234]   Particularly suitable is an oil-soluble high content of at least partially crosslinked with a softening point <160 ° C.
It is a child substance. Suitable materials are PE (polyethylene), PVA (polyvinyl alcohol)
Cole) and derivatives, PVP (polyvinylpyrrolidone) and derivatives, PVP / A
Lucene Copolymer, PVP / VA Copolymer, PVM / MA (Methyl Vinyl A)
Ter / maleic anhydride) copolymers and their esters and ethers, especially poly
(Alkyl vinyl ether-co-maleic anhydride) copolymer, ethylene / VA
Copolymer, styrene / isoprene, styrene / ethylene / butylene, styrene
/ Ethylene / propylene, styrene / ethylene / butyl / styrene and styrene
/ Butadiene copolymer chemistry. Suitable substances are eg
For example, DuPont (ELVAX (registered trademark) type), BASF (LUVISKOL (registered trademark)
(Registered trademark) type), shell (KRATON (registered trademark) polymer) and ISP (PV
Available from P, GANTREZ® and GANEX® types)
Is.       [0235]Hydrogel-forming polymer gelling agent   In a particular embodiment of the present invention, the article is a hydrogel-forming polymeric gelling agent.
And optionally a water-based gel formed from water, or a "hydrogel". Change
Specifically, hydrogels are among the cleansing or therapeutic benefit components of the article.
Contained in. When an aqueous gel is present, the article is based on the weight of the water-insoluble substrate.
Then, the hydrogel-forming polymer gelling agent is preferably about 0.1 in terms of dry mass.
Wt% to about 100 wt%, more preferably about 3 wt% to about 50 wt%, most preferably
Specifically, the content is about 5% by mass to about 35% by mass.       [0236]   Generally, the hydrogel-forming polymeric gellant materials of the present invention are water-soluble or hydrous.
Prepared from a polymerizable unsaturated acid-containing monomer that becomes water-soluble upon decomposition,
It is a polymer that is at least partially crosslinked. As these substances,
Both unsaturated acids with olefins containing one carbon-carbon olefinic double bond
And at least one hydrophilic group, such as (but not limited to)
Examples include monoethylenically unsaturated compounds. For these monomers, water soluble
The term "property" means that the monomer is at least about 0.2% in deionized water at 25 ° C, preferably
Means that at least about 1.0% is dissolved.       [0237]   Upon polymerization, monomer units such as those described above are generally incorporated into the acid-containing monomer
About 25 mol% to 99.99 mol of the margelling agent material (on a dry polymer weight basis)
%, More preferably from about 50 mol% to 99.99 mol%, most preferably at least
Also constitutes about 75 mol%.       [0238]   The hydrogel-forming polymer gelling agent in the present invention is preferably obtained from
Sufficient to ensure that the limmer does not exhibit a glass transition temperature (Tg) below about 140 ° C
Is partially cross-linked to the "hydrogel formation" as used herein.
The term "polymeric gelling agent" means a polymer that meets this parameter.
To do. Preferably, the hydrogel-forming polymeric gelling agent has a Tg of about 180 ° C or less.
Less preferably, and more preferably at temperatures above about 300 ° C., the Tg is a polymer.
Does not precede the disassembly of. Tg is 20.0 ° C./min using a sample of 5 mg or less
It can be measured by differential scanning calorimetry (DSC), which is performed at a heating rate.
Wear. Tg is the onset of heat flow change corresponding to the glass transition on the DSC heat capacity curve and
Calculated as the midpoint of the end. The use of DSC to determine Tg is known to those of ordinary skill in the art.
Knowledge, B. Cassel and M.M. P. “Positive” by DiVito
Use of DSC to Obtain Accurate Thermodynamic and Kinetic Data "(Use of DSC To
American Laboratory in Obtain Accurate Thermodynamic and Kinetic Data)
Tori Journal, January 1994, pp. 14-19, and B. one
“Thermal Analysis” by Wunderlich (Academy
Cook Press, 1990).       [0239]   Hydrogel-forming polymeric materials are characterized by high absorption and
Water can be retained in the state or "gel" state. Preferred hydrogens of the invention
The polymer-forming gelling agent is at least about 40 g / g gelling agent, preferably
Or at least about 60 g / g, more preferably at least about 80 g / g
Ionization) can be absorbed. This is called "absorption capacity" in this specification.
These values can be quantified according to the procedure of the absorption capacity "tea bag" test described above.
it can.       [0240]   The hydrogel-forming polymeric gelling agents of the present invention are generally at least partially
It is cross-linked. Suitable crosslinkers are well known to those skilled in the art and include, for example, (1) at least
A compound having two polymerizable double bonds; (2) at least one polymerizable
Compound having double bond and at least one acid-containing monomeric substance-reactive functional group
(3) a compound having at least two acid-containing monomeric substance-reactive functional groups; and
And (4) polyvalent metal compounds capable of forming ionic crosslinks.       [0241]   Examples of the cross-linking agent having at least two polymerizable double bonds include (i) divinyl vinyl ester.
Di- or polyvinyl compounds such as benzene and divinyltoluene; (ii) eg
Ethylene glycol, trimethylolpropane, glycerin, or polyoxyethylene
Polyethers containing di- or triacrylates of polyols such as ethylene glycol.
Diols and polyesters of lyols and unsaturated mono- or polycarboxylic acids; (iii)
Bisacrylamides such as N, N-methylenebisacrylamide; (iv) Poly
It can be obtained by reacting a cyanate with a hydroxyl group-containing monomer.
Carbamyl ester; (v) di- or polyallyl ether of polyol; (vi)
) Di- or poly-carboxylic acids such as diallyl phthalate and diallyl adipate
Allyl ester; (vii) Activator of polyethylene glycol monoallyl ether
Monoallyl esters of polyols, such as phosphoric acid esters, and unsaturated mono or
Esters of polycarboxylic acids; (viii) di- or triallylamine
It       [0242]   At least one polymerizable double bond and at least one acid containing monomer
Examples of the cross-linking agent having a reactive functional group include N-methylol acrylamide and green.
Examples include sidyl acrylate. Reaction of at least two acid-containing monomeric substances
Suitable cross-linking agents having a functional group include glyoxal; ethylene glycol
And polyols such as glycerol; alkylenediamines (eg, ethylenedia
Min), polyalkylene polyamine, polyepoxide, di- or polyglycidyl
Examples include polyamines such as ether. The ability to form ionic crosslinks
Suitable polyvalent metal cross-linking agents include, for example, calcium oxide and zinc diacetate.
Lucari earth metals (eg calcium, magnesium) and zinc oxides, hydroxides
Compounds and weak acid salts (for example, carbonates, acetates, etc.).       [0243]   Many of the types of cross-linking agents mentioned above are incorporated by reference in the US
Patent No. 4,076,663 (issued February 28, 1978, Masuda et al.), And rice
National Patent No. 4,861,539 (issued August 29, 1989, Allen)
Et al.). The preferred crosslinking agent is a polyol
Saturated mono- or polycarboxylic acid monoallyl ester di- or polyester, bi
Examples include sacrylamide, and di- or triallylamine. Particularly preferred
Specific examples of the cross-linking agent include N, N'-methylenebisacrylamide and trimethylamine.
Examples include roll propane triacrylate.       [0244]   The crosslinker is generally about 0.001 of the resulting hydrogel-forming polymeric material.
It constitutes from 5 mol% to 5 mol%. More generally, crosslinking agents are used in the present invention.
Comprises about 0.01 mol% to 3 mol% of the hydrogel-forming polymer gelling agent used
To do.       [0245]   The hydrogel-forming polymeric gelling agent of the present invention can be used in a partially neutralized form.
Good. For purposes of the present invention, such materials are not used to form polymers.
At least 25 mol%, preferably at least 50 mol% of the monomers
In the case of an acid group-containing monomer that has been neutralized with
Conceivable. Suitable neutralizing base cations include alkali and alkaline earth metals.
Hydroxides (eg, KOH, NaOH), ammonium, substituted ammonium,
And amino alcohols (eg, 2-amino-2-methyl-1,3-propanediene)
All, diethanolamine, and 2-amino-2-methyl-1-propanol
) And the like. In all the monomers used, neutralized acid group-containing
This percentage of monomeric content is referred to herein as the "degree of neutralization." Degree of neutralization
Preferably does not exceed 98%.       [0246]   Suitable hydrogel-forming polymeric gelling agents for use herein are those skilled in the art.
Well-known, for example, U.S. Pat. No. 4,076,663 (February 28, 1978).
Published by Masuda et al.); US Pat. No. 4,062,817 (December 13, 1977)
Published by Westerman; US Pat. No. 4,286,082 (1
Tsubakimoto et al., Issued August 25, 981); US Pat. No. 5,061,259 (
Goldman et al., Issued October 29, 1991, and US Patent No.
No. 4,654,039 (Published March 31, 1987, Brandt et al.)
Each of which is incorporated herein by reference in its entirety.       [0247]   Hydrogel-forming polymeric gelling agents suitable for use herein include US patents
Xu 4,731,067 (issued March 15, 1988, Le-Khac)
), U.S. Pat. No. 4,743,244 (Lukack, issued May 10, 1988).
U.S. Pat. No. 4,813,945 (Lukack, issued March 21, 1989),
U.S. Pat. No. 4,880,868 (Lukack, issued Nov. 14, 1989),
U.S. Pat. No. 4,892,533 (Lukack, issued January 9, 1990), USA
Patent No. 5,026,784 (Lukack, issued June 25, 1991), US patent
Xu 5,079,306 (Lukack, issued January 7, 1992), US Patent No.
5,151,465 (Lukack, issued September 29, 1992), US Patent No. 4
, 861, 539 (issued August 29, 1989, Allen, Farrah)
(Farrer) and Flesher), and U.S. Pat. No. 4,962.
Issue 172 (issued October 9, 1990, Allen, Farrer
), And Flesher).
Incorporated herein by reference.       [0248]   Suitable hydrogel-forming polymer gelling agents in particle form are available from Virginia, USA
Hoechst Celanese Corporation of Portsmouth
Sanwet ™ super-absorbent polymer), Japanese Nippon Shokubai (Aquaric (
Aqualic ™, eg L-75, L-76) and Mid, Michigan, USA
Dow Chemical Company of Midland
Commercially available from Dry Tech (TM).       [0249]   Fiber-form hydrogel-forming polymer gelling agents are commercially available from Res. Massachusetts, USA.
Leominster's Camelot Techno
logies Inc. ) (Fibersorb ™, eg SA72
00H, SA7200M, SA7000L, SA7000, and SA7300)
More commercially available.       [0250]   The articles of the present invention may also include other hydrophilic gelling agents. As these
, Cellulose ethers (eg hydroxyethyl cellulose, methyl cellulose)
, Hydroxypropylmethylcellulose), polyvinylpyrrolidone, polyvinyl chloride
Alcohol, guar gum, hydroxypropyl guar gum and xanthan gum
Various other water-soluble or colloidal water-soluble polymers, as well as relatively cross-linked
Other than the above-mentioned ones, such as those mentioned above, which have a Tg of less than 140 ° C,
Examples include rubonic acid-containing polymers. Preferred among these additional hydrophilic gelling agents
Preferred are acid containing polymers, especially carboxylic acid containing polymers. Especially preferred
Some are polyhydric alcohols and optionally acrylate esters or polyfunctional vinyl
Water-soluble poly (acrylic acid) cross-linked with polyalkenyl polyether of den monomer
It includes a mar.       [0251]   Preferred copolymers useful in the present invention are acrylic acid, methacrylic acid and ethacrylic acid.
95-99% by weight of olefinic hydrocarbon selected from the group consisting of phosphoric acid.
A monomer mixture containing saturated carboxyl monomers; about 1 to about 3.5 mass parts.
Acrylate ester of the following formula:       [0252]   [Chemical 6] In the formula, R is an alkyl group containing 10 to 30 carbon atoms, and R₁Is
Hydrogen, methyl or ethyl; and the parent polyhydric alcohol must have at least 3 carbon atoms and
And more than one alkenyl ether containing at least 3 hydroxyl groups per molecule
0.1 to 0.6% by mass of a polyhydric alcohol containing a group capable of being polymerized.
It is a bridge polyalkenyl polyether.       [0253]   Preferably, these polymers are from about 96 to about 97.9 wt% acrylic acid,
And about 2.5 to about 3.5% by weight of acrylic acid ester, wherein the alkyl group is carbon.
R including prime numbers 12 to 22₁Is methyl, most preferably ac
The phosphoric acid ester is stearyl methacrylate. Preferably crosslinked polyal
The amount of kenyl polyether monomer is about 0.2-0.4% by weight. Preferred rack
Bridge polyalkenyl polyether monomers include allyl pentaerythritol, tri-
It is methylolpropane diallyl ether or allyl sucrose. like this
The polymer is described in US Pat. No. 4,509,949 (issued April 5, 1985, fa
Huang et al., Which is incorporated herein by reference.
Insert       [0254]   Other preferred copolymers useful in the present invention are at least two monopolymers.
A polymer containing a mer component, one of which is the monomeric olefinically unsaturated carboxylic acid
Acids and polyalkenyls and polyethers of polyhydric alcohols. add to
The optional monomeric material is optionally present in the monomer mixture in a major proportion.
Good.       [0255]   At least the first monomer component useful in the production of these carboxylic acid polymers is
Also one activated carbon-carbon olefinic double bond, and at least one carbohydrate.
It is an olefinically unsaturated carboxylic acid containing a xyl group. Preferred carboxylic acid
Nomers are acrylic acids having the following general structure:       [0256]   [Chemical 7] Where R²Is hydrogen, halogen, and dicyan group (-C = N), monovalent alkyl
A group, a monovalent alkaryl group and a monovalent cycloaliphatic group.
It is a substituent. Of this category, acrylic, methacrylic, and ethacrylic acid are the most
Is also preferable. Another useful carboxylic acid monomer is maleic anhydride or maleic acid.
Is. The amount of acid used is about 95.5 to about 98.9% by weight.       [0257]   The second monomer component useful in making these carboxylic acid polymers is an olefin.
Methylene group is a terminal methylene group: CH₂Alkenyl group and the like which is present by linking to ═C <
Polyalkenyl poly having more than one alkenyl ether group per molecule
It is ether.       [0258]   Additional monomeric substances that may be present in the polymer include, for example, butadiene.
Amine, isoprene, divinylbenzene, divinylnaphthalene, allyl acrylate
At least two terminal CHs, such as₂Include polyfunctional vinylidene monomers containing groups
Be done. These polymers are available from Brown rice issued July 2, 1957.
It is fully described in National Patent No. 2,798,053, all of which are for reference only.
Incorporated herein.       [0259]   Examples of carboxylic acid copolymers useful in the present invention include Carbomer 934
, Carbomer 941, Carbomer 950, Carbomer 951, Carbomer 954
, Carbomer 980, Carbomer 981, Carbomer 1342, Acrylate /
C10-30 alkyl acrylate cross-linked polymer (BF Goodrich
From Goodrich, Carbopol 934, Carbopol 941, Carbopol
950, Carbopol 951, Carbopol 954, Carbopol 980, Cal
Bopol 981, Carbopol 1342, and Pemulen series
Available as).       [0260]   Other carboxylic acid copolymers useful in the present invention include the registered trademark hostaselene (
Hostaceren) PN73 under Hoechst Celanese Corporation (Hoec
hst Celanese Corporation)
Mention may be made of the sodium salt of the polymer. In addition, the registered trademark HYPAN hydrogel
Hydrogels originally sold by Lipo Chemicals Inc.
Polymers are also included. These hydrogels contain carboxyls, amides, and
A crystalline pre-form of nitrate on a C-C backbone with various other pendant groups such as a midine.
It consists of plicks. As an example, Lipo Chemicals I
HYPAN SA100H, a polymer powder available from nc.
You can       [0261]   The neutralizing agents used to neutralize the acidic groups of these polymers are those mentioned above.
Is mentioned.       [0262]Highly malleable oil   Another optional ingredient in the beneficial component of the articles of the present invention is "highly malleable oil".
. Vitamin B₃If the compound is included in the beneficial ingredient, this highly malleable oil is included
Is particularly preferred. Highly preferred conditioning ingredients of the present invention further include
3 to 10%, preferably about 3 to about 8%, more preferably about 4 to about 6% of:
Including highly malleable oils selected from       [0263]   i) a branched chain hydrocarbon having a weight average molecular weight of about 100 to about 1000 and   ii) Liquid ester emollients of formula I       [0264]   [Chemical 8] Where R¹Is H or CH₃Selected from R², R³, R^FourAre each independently C₁~
C₂₀Selected from straight or branched chain alkyl, and x is an integer from 1 to 20
.   These highly malleable oils are vitamin B₃Useful for delivering the compound to the skin.       [0265]   Suitable examples of the branched chain hydrocarbon include isododecane, isohexadecane and isohexadecane.
Eikosan is included. Preferred is isohexadecane. Poly (Alpha
(Olefin) anti-adhesives are described in further detail herein below,
It is generally a branched chain hydrocarbon. When these anti-adhesives are used,
Those amounts are considered to be included in the above-mentioned highly malleable oil concentrations.       [0266]   Suitable ester emollients of formula I above include methyl isostearate, iso
Isopropyl stearate, isostearyl neopentanoate, isononyl ester
Sononanoate, isodecyl octanoate, isodecyl isononanoate,
Lydecyl isononanoate, myristyl octanoate, octyl pelargone
Tol, octyl isononanoate, myristyl myristate, myristyl neopen
Tanoate, isostearyl neopentanoate, myristyl octanoate,
Myristyl propionate, isopropyl myristate and their mixtures
Can be mentioned. The preferred ester emollients for use herein are isononylisolone
Nonanoate, isostearyl neopentanoate, methyl isostearate,
Isopropyl isostearate, isopropyl stearate, isomyristate
Propyl and mixtures thereof.       [0267]   Particularly preferred highly malleable oils for use herein are isohexadecane, isononi
Luisononanoate, methyl isostearate, isopropyl isostearate
, Or a mixture thereof. Even more preferred for use herein is iso-
A mixture of highly malleable oils containing xadecane and isopropyl isostearate.
Such a mixture is particularly preferred when the composition of the invention contains a high concentration of glycerin.
Good The ester emollient is preferably present in the composition at about 0.1% by weight of the composition.
1 to about 10%, preferably about 0.1 to about 8%, particularly preferably about 0.5 to about
Present at a concentration of 5%.       [0268]Anti-adhesive   Vitamin B₃If a compound is also present, one or more of the beneficial ingredients of the invention may be present.
Such beneficial ingredients, which preferably include anti-adhesive agents, are present at about 0.3 to about 4%, preferably.
Preferably about 0.5 to about 2.5%, and even more preferably about 1 to about 2% of a molecular weight of about 2.
Anti-adhesive agent selected from poly (alpha olefins) having 60 to about 1000
And petroleum jelly, cetyl ricinoleate and lanolin.
Without being limited by theory, with poly (alpha-olefin) anti-adhesives, occlusive
Despite the fact that it works by a different mechanism than anti-adhesives
, Both have high levels of vitamin B₃Reduces the stickiness of skin that is closely related to compounds
Effective to reduce. A mixture of anti-adhesives is not excluded, but anti-sticking
A better effect is obtained when the adhesive is selected from one of the two.       [0269]   Suitable poly (alpha olefins), such as those mentioned above, contain from about 6 to about 14 carbon atoms.
A child, preferably one having from about 6 to about 12 carbon atoms, especially from about 8 to about 12 carbon atoms.
It can be derived from alkene monomers. Poly (Alf) useful herein
Olefins are preferably hydrogenated poly (alpha olefin) oligomers
It is a kind. Preparation of Polyalpha Olefin Oligomers Here
Examples of useful 1-alkene monomers for 1-hexene, 1-octene, 1-decene
Such as sen, 1-dodecene, 1-tetradecene, 4-methyl-1-pentene
Branched chain isomers, and combinations thereof are included. Most preferred is 1-octene
To 1-dodecene oligomer or a combination thereof. Especially preferred
The new one is polydecene. A suitable polydecene oil is Mobil Chem.
ical Company, New Jersey 08818, Edison, PO Box 3140
) Under the trade name Puresyn 4 (registered trademark) and BP Amoco (BP
Amoco, Illinois 60601-7125, Chicago, Randolph Drive, 200
E) under the trade name Silk Flow 364NF (Silkflo 364NF) (registered trademark)
It is sold. The most preferred anti-sticking agent is petrolatum.       [0270]Inorganic matting agent   Inorganic delustering agents such as titanium oxide or zinc oxide are useful as beneficial ingredients in the article.
is there. Matting agents, when present in the present invention, are undesirable skin whitening or unnatural
Use at a concentration of 3% or less to avoid a “dull” appearance. Use of the invention
Particularly preferred is titanium dioxide and especially anatase titanium dioxide.       [0271]   Anatase type titanium dioxide has a density of about 3.90 g / cm³And square
It has a cubic close-packed structure. Anatase type titanium dioxide has a refractive index of 2.55.
It Anatase type titanium dioxide is a trade name of Kobo Products Inc.
With Kobo BTD11S2, Whittaker, Clark, and Daniel (Whittake
r, Clark, Daniels) (New Jersey, USA, South Plainfield (New
 Jersey, South Plainfield)) product name TiO₂9729, Cardre (Ca
rdre Inc., South Plainfield, NJ, USA)
It is commercially available from Lud 70429.       [0272]   The invention in terms of skin feel, skin appearance, and compatibility with emulsions
A preferred matting agent for use in is a surface-treated pigment. The pigment is Rishi
Amino acids such as silicone, lauroyl, collagen, polyethylene,
It may be treated with compounds such as cytin and ester oils. Most preferred matte
The agent is an organic silicone (polysiloxane) -treated pigment, for example, a polysiloxane-treated pigment.
Titanium oxide. Most preferred is polysiloxane treated anatase type titanium dioxide.
It's Tan. The function of surface treatment is to modify the pigment to be hydrophobic so that the pigment
It becomes "wettable" in the oil phase of the oil-in-water emulsion.       [0273]   The total concentration of inorganic matting agent is about 0 to about 3%, and preferably about 0.1 to about 2.
It may be 5%, preferably about 0.25% to about 2%.       [0274]Cationic surfactant   Cationic surfactants are typically classified as non-effervescent surfactants.
, If it does not negatively affect the desired benefit of the article of the invention,
May be used.       [0275]   Non-limiting examples of cationic surfactants useful herein are "McCarcheon's
Detergents and Emulsifiers ", North American version
(1986), Allred Publishing Corporation (allured Pu
blishing Corporation); and "McChaCherons Functional Material (McCu
tcheon's Functional Materials) "North American Edition (1992);
Both of which are incorporated herein by reference in their entirety.       [0276]   Non-limiting examples of cationic surfactants useful herein include cations such as
Alkyl ammonium salts include: R₁R₂R₃R_FourN⁺X^- R in the formula₁Is an alkyl group having about 12 to about 18 carbon atoms, or about 12 to
Aromatic groups, aryl groups or alkaryl groups having about 18 carbon atoms; R₂, R₃,
And R_FourIs hydrogen, an alkyl group having from about 1 to about 18 carbon atoms, or about 1
~ Separately from aromatic, aryl or alkaryl groups having about 18 carbon atoms
X is an anion, preferably chloride, bromide, iodide, acetate
, Phosphate, nitrate, sulfate, methyl sulfate, ethyl sulfate, tosylate
, Lactate, citrate, glycol, and mixtures thereof.
Be done. Further, the alkyl group is also a substituent of an ether bond or a hydroxyl group or an amino group.
Can also be included (for example, where the alkyl group is polyethylene glycol and
It may contain a propylene glycol moiety).       [0277]   More preferably, R₁Is an alkyl group having about 12 to about 18 carbon atoms; R₂Is
Hydrogen or an alkyl group having from about 1 to about 18 carbon atoms; R₃And R_FourIs that
Is hydrogen or an alkyl group having from about 1 to about 3 carbon atoms; and X is in the preceding paragraph.
As stated.       [0278]   Most preferably R₁Is an alkyl group having about 12 to about 18 carbon atoms; R₂, R ₃ , And R_FourIs selected from hydrogen or an alkyl group having from about 1 to about 3 carbon atoms; and X
Is as described above.       [0279]   Alternatively, other useful cationic surfactants include amino-amides,
Where the above structure R₁Instead of R_FiveCO- (CH₂)_n−, And in the formula, R_FiveIs
, An alkyl group having about 12 to about 22 carbon atoms, n being about 2 to about 6,
Is preferably an integer of about 2 to about 4, and most preferably about 2 to about 3. This
Non-limiting examples of such cation emulsifiers include stearoamidopropyl PG-dimoni
Umm chloride phosphate, stearoamido propyl ethyl dimonium esosal
Fate, stearoamidopropyl dimethyl (myristyl acetate) ammonium chloride
Monium, stearoamidopropyl dimethyl cetearyl ammonium tosylate
, Stearoamidopropyl dimethyl ammonium chloride, stearoamidopropyl
Dimethyl ammonium lactate and mixtures thereof are included.       [0280]   Non-limiting examples of quaternary ammonium salt cationic surfactants include cetyl salts.
Ammonium bromide, cetyl ammonium bromide, lauryl ammonium chloride, lauri
Ammonium bromide, stearyl ammonium chloride, stearyl ammonium bromide
System, cetyl dimethyl ammonium chloride, cetyl dimethyl ammonium bromide, lau
Ryl dimethyl ammonium chloride, lauryl dimethyl ammonium bromide, steari
Rudimethyl ammonium chloride, stearyl dimethyl ammonium bromide, cetyl
Limethyl ammonium chloride, cetyl trimethyl ammonium bromide, lauryl tri
Methyl ammonium chloride, lauryl trimethyl ammonium bromide, stearylt
Limethyl ammonium chloride, stearyl trimethyl ammonium bromide, lauryl
Dimethyl ammonium chloride, stearyl dimethyl cetyl ditallow dimethyl chloride
Ammonium, dicetyl ammonium chloride, dicetyl ammonium bromide, dilauri
Ammonium chloride, dilauryl ammonium bromide, distearyl ammonium chloride
Um, distearyl ammonium bromide, dicetylmethyl ammonium chloride, dice
Cylmethyl ammonium bromide, dilauryl methyl ammonium chloride, dilauryl
Methyl ammonium bromide, distearyl methyl ammonium chloride, distearyl
Dimethyl ammonium chloride, distearyl methyl ammonium bromide and their
And those selected from the group consisting of mixtures. With quaternary ammonium salt
The C12-C22 alkyl carbon chain is tallow fatty acid or coconut fatty acid
Those derived from. The term "tallow" generally refers to C16-C18.
Tallow fatty acids (usually hydrogenated tallows) with a mixture of alkyl chains in the range of
Alkyl group derived from (fatty acid). The term "coconut" is
Coconut fat, generally with a mixture of alkyl chains in the C12 to C14 range.
It means an alkyl group derived from an acid. Four like tallow and coconut
Examples of primary ammonium salts include ditallow dimethyl ammonium chloride, ditallow
Dimethyl ammonium methyl sulfate, di (hydrogenated tallow) dimethyl chloride
Ammonium, di (hydrogenated tallow) dimethyl ammonium acetate, ditallow zip
Ammonium ropyl phosphate, ditallow dimethyl ammonium nitrate, di (coconut
Tualkyl) dimethyl ammonium chloride, di (coconut alkyl) dimethyl odor
Ammonium chloride, tallow ammonium chloride, coconut ammonium chloride, starch
Aloamidopropyl chloride PG-dimonium phosphate, stearoamide propionate
Ruethyldimonium esulfate, stearoamidopropyl dimethyl (milli
Stille acetate) Ammonium chloride, stearoamido propyl dimethyl cettea
Rylammonium tosylate, stearoamidopropyldimethyl ammonium chloride
, Stearoamidopropyl dimethyl ammonium lactate, and mixtures thereof.
Can be mentioned.       [0281]   Preferred cationic surfactants useful in the present invention include dilauryl di
Methyl ammonium chloride, distearyl dimethyl ammonium chloride, dimyristi
Rudiethyl ammonium chloride, dipalmityldimethyl ammonium chloride, diste
Selected from the group consisting of allyldimethyl ammonium chloride, and mixtures thereof.
There are some.       [0282]Chelators   The articles of the present invention also include a safe and effective amount of a chelating agent, or chelating agent.
Good. As used herein, a “chelating agent” means that a metal ion can easily undergo a chemical reaction.
By forming a complex so that it does not participate or catalyze chemical reactions
By an active substance capable of removing metal ions from the system. Chelating agent included
Is UV irradiation that contributes to scaling or tissue changes in the stratum corneum?
And other environmental chemicals that could cause skin damage.
Especially useful for.       [0283]   A safe and effective amount of chelating agent may be added to the compositions of the subject invention, preferably
Is from about 0.1% to about 10% by weight of the composition, more preferably from about 1% to about 5% by weight.
Amount% may be added. An example of a chelating agent useful herein is vice versa.
U.S. Pat. No. 5,487,884 to Bissett (January 30, 1996).
Published); International Publication No. 91/16035 of Bush et al. (1995 1
Published 31 January; and Bush et al., WO 91/16034 (
(Published October 31, 1995). Used in the composition of the subject invention
Preferred chelating agents include furyldioxime, furyldioxime derivatives, and furyldioxime derivatives.
Rumonooxime, furyl monooxime derivatives, and combinations thereof.       [0284]Flavonoid   The articles of the present invention may optionally include flavonoid compounds. Flavonoids
Broadly disclosed in US Pat. Nos. 5,686,082 and 5,686,367.
Both of which are incorporated herein by reference. Used in the present invention
Suitable flavonoids for are unsubstituted flavanones, mono-substituted flavanones and
Flavanones selected from the group consisting of these mixtures; unsubstituted chalcones, mono-
From substituted chalcones, di-substituted chalcones, tri-substituted chalcones and mixtures thereof
A chalcone selected from the group consisting of: an unsubstituted flavone, a mono-substituted flavone, a di-position
A flavone selected from the group consisting of a modified flavone and mixtures thereof;
More isoflavones; unsubstituted coumarins, mono-substituted coumarins, di-substituted coumarins
Coumarins selected from the group consisting of marine and mixtures thereof; unsubstituted chromones
, Mono-substituted chromones, di-substituted chromones and mixtures thereof.
Chromone selected; one or more dicoumarols; one or more
Kuromanon; one or more chromanol; these isomers (eg
Cis / trans isomers); and mixtures thereof. As used herein
The term “substituted” means that one or more hydrogen atoms of a flavonoid are independent.
Then, hydroxyl, C1-C8 alkyl, C1-C4 alkoxyl, O-glyc
It means a flavonoid substituted with coside or the like or a mixture of these substituents.       [0285]   Examples of suitable flavonoids include unsubstituted flavanones and monohydroxy flavanes.
Non (eg, 2'-hydroxyflavanone, 6-hydroxyflavanone, 7-
Hydroxyflavanone, etc.), monoalkoxyflavanone (eg, 5-methoxy)
Flavanone, 6-methoxyflavanone, 7-methoxyflavanone, 4'-methoxy
Siflavanone, etc.), unsubstituted chalcones (especially unsubstituted transchalcones), monohydride
Roxychalcone (eg 2'-hydroxychalcone, 4'-hydroxychalcone
Etc.), dihydroxychalcone (for example, 2 ', 4-dihydroxychalcone, 2
', 4'-dihydroxychalcone, 2,2'-dihydroxychalcone, 2', 3
-Dihydroxychalcone, 2 ', 5'-dihydroxychalcone, etc.) and trich
Droxychalcone (eg, 2 ', 3', 4'-trihydroxychalcone, 4,
2 ', 4'-trihydroxychalcone, 2,2', 4'-trihydroxychalcone
Etc.), unsubstituted flavones, 7,2'-dihydroxyflavones, 3 ', 4'-dihi
Droxynaphthoflavone, 4'-hydroxyflavone, 5,6-benzoflavone
, And 7,8-benzoflavone, unsubstituted isoflavone, daidzein
(7,4'-dihydroxyisoflavone), 5,7-dihydroxy-4'-meth
Xyisoflavone, soy isoflavone (extract mixture derived from soybean), unsubstituted Kumari
4-hydroxycoumarin, 7-hydroxycoumarin, 6-hydroxy-4-
Methylcoumarin, unsubstituted chromone, 3-formyl chromone, 3-formyl-6-
Isopropyl chromone, unsubstituted dicoumarol, unsubstituted chromanone, unsubstituted chroma
Examples include, but are not limited to, nols, and mixtures thereof.       [0286]   Preferred for use in the present invention are the unsubstituted flavanones, methoxyflavano.
And unsubstituted chalcones, 2 ', 4-dihydroxychalcones and mixtures thereof.
It Most preferred are unsubstituted flavanones, unsubstituted chalcones (especially trans variants).
And the mixture thereof.       [0287]   These may be synthetic or extracted from natural sources (eg plants).
Can be obtained. Naturally derived substances can also be further derivatized (eg,
Glycoside, ester or ether derivative produced after extraction from natural products)
. Flavonoid compounds useful in the present invention can be obtained from a number of sources, such as India
Indofine Chemical Company, Inc. (New Jersey, USA)
Somerville, S.A., Steraloids, Inc. (New Hampshire, USA)
Wilton, USA and Aldrich Chemical Company
, Inc.) (Milwaukee, Wisconsin, USA).   Mixtures of the above flavonoid compounds may be used.       [0288]   The flavonoid compounds described herein are preferably in the present invention about 0.
01% to about 20%, more preferably about 0.1% to about 10%, and most
It is preferably present at a concentration of about 0.5% up to about 5%.       [0289]Sterol   Articles of the present invention may include a safe and effective amount of one or more sterol compounds.
. Examples of useful sterol compounds include sitosterol, stigmasterol.
, Campesterol, brassicasterol, lanosterol
, 7-dehydrocholesterol, and mixtures thereof. They are,
Extraction from synthetic or natural sources, for example from plants
It may be the exit mixture (eg phytosterol).Anti-cellulite       [0290]   The article of the present invention comprises a safe and effective amount of an anti-cellulite agent in a beneficial component.
Good. Suitable agents include xanthine compounds (eg, caffeine, theophylline).
Phosphorus, theobromine, and aminophylline) can be mentioned.
Is not limited to       [0291]Skin whitening agent   The article of the present invention may include a skin lightening agent. When used, the composition is a composition
Of about 0.1% to about 10% by weight, more preferably about 0.2% by weight.
Wt% to about 5 wt%, more preferably about 0.5 wt% to about 2 wt% skin lightening agent.
including. Suitable skin lightening agents include kojic acid, arbutin, ascorbic acid and
And their derivatives such as magnesium ascorbate phosphate or ascorbi
To those skilled in the art, such as sodium phosphate phosphate or other salts of ascorbic phosphate.
The one of knowledge is mentioned. Further, as a skin lightening agent suitable for use in the present invention,
Co-pending Application No. 08 filed July 7, 1995 by Hillebrand
/ 479,935, PCT application number US 95 / filed June 12, 1995
Corresponding to 07432; and Kalla L. Kvalnes,
Michelle A. DeLong, Burton J. Bradbet
Barton J. Bradbury, Curtis B. Motley
Filed on February 24, 1995 by John D. Carter
No. 08 / 390,152, filed March 1, 1995, 199
Described in PCT application number US 95/02809 equivalent published on September 8, 1993
The ones that have been done are listed.       [0292]Binder   The articles of the present invention may optionally include a binder. The binder or binding substance is
Useful for sealing the various layers of a light article together and maintaining the integrity of the article
Is. Binders can be in various forms such as sprays, webs, separate layers, binding fibers, etc.
However, the present invention is not limited to these. Suitable binders are latex, polyamide,
It may include polyesters, polyolefins, and combinations thereof.       [0293]Optional ingredients suitable for inclusion in the present invention in household products (eg, cleaning hard surfaces) Organic cleaning solvent   The cleaning components of the disclosed disposable articles are typically cleaning components.
Less than about 0.25% by weight and, in increasing order of preference, at least about 0.5% by weight
And about 3.0% by mass, and in order of increasing preference, about 7% by mass and about 5% by mass.
May contain an effective amount of one or more organic cleaning solvents.       [0294]   Surfactants have good cleaning properties even in the absence of hydrophobic cleaning solvents.
And / or wettability. However, use the correct organic cleaning solvent.
When used, the cleaning property can usually be further improved. Organic
The cleaning solvent helps the surfactant and removes dirt that is often seen in the bathroom.
Means an agent that leaves. The organic cleaning solvent will form a viscosity as needed.
, And increase the stability of the composition. C if a solvent is present _8-16 Alkyl polyglucosides and C_8-14Containing alkyl ethoxylates of
The composition having also low foamability. Therefore, simply control the level of hydrophobic solvent in the formulation.
By doing so, the foam properties can be controlled to a large extent.       [0295]   Such solvents are usually 1-3 ethylene glycol or propylene glycol moieties.
C at the end that binds to the₃~ C₆With a suitable degree of hydrophobicity and preferred
Specifically, it provides surface activity. Commercially available ethylene glycol chemical
Examples of the hydrophobic cleaning solvents of are mono-ethylene glycol n-hexyl
Ether (hexyl cellosolve available from Union Carbide (Cellosol
ve) (registered trademark)). Based on propylene glycol chemicals
Examples of commercially available hydrophobic cleaning solvents include propyl and butyl alcohols.
Di- and tri-propylene glycol derivatives are mentioned, including Arcosolv (Arcosolve).
solv) (registered trademark) and Dowanol (registered trademark)
Alco Chemicals (19073 Wens, Newton Square, PA)
Tochester Pike 3801) and Dow Chemical (Midra, MI)
, Suede Road N1691).       [0296]   In the context of the present invention, the preferred solvent is mono-propylene glycol mono-
Propyl ether, di-propylene glycol mono-propyl ether, mono-
Propylene glycol monobutyl ether, di-propylene glycol monop
Ropyl ether, di-propylene glycol monobutyl ether; tri-propyi
Len glycol monobutyl ether; Ethylene glycol monobutyl ether;
Diethylene glycol monobutyl ether, ethylene glycol monohexyl ether
Ether and di-ethylene glycol monohexyl ether, and mixtures thereof
Is selected from the group consisting of: "Butyl" means both normal butyl and isobutyl
And a tertiary butyl group. Mono-propylene glycol and mono-propyi
Lenglycol monobutyl ether is the most preferred cleaning solvent,
Dowanol DPnP® and Dowanol DPnB (registered)
It is available under the trade name of (registered trademark). Di-propylene glycol mono-t
-Butyl ether is a product of the trade name of Arcosolv PTB®.
Originally marketed by Arco Chemical.       [0297]   The amount of organic cleaning solvent depends on the amount of other ingredients present in the composition.
Can change. Hydrophobic cleaning solvents are usually floor cleaning products
Helps to obtain good cleanability in such items.       [0298]   For cleaning in confined spaces, the solvent is an unwanted small suction
Compositions that can form droplets and are therefore used to treat such spaces
The / solution should preferably be substantially free of such solvent, and more preferably completely.
I'm sorry.       [0299]Co-activator   The cleaning component of this article should contain a small amount of anionic and / or nonionic cream.
A surface-active agent may be included. Such anionic surfactants are
Usually, it contains from about 8 to about 18 carbon atoms, preferably from about 8 to about 16 carbon atoms.
It contains an aqueous chain and usually contains a hydrophilic head group of sulfonate or carboxylate.
Including. In general, any of the compositions herein, for example, anionic, surfactant,
The level of stiffening agent is from about 0.01% to about 0.25% by weight of the cleaning component,
More preferably from about 0.01% to about 0.2%, most preferably about 0.01%.
% To about 0.1% by weight.       [0300]   For floor, counter and other surface applications both type and level
The choice of co-activator for selection can be critical. C₈~ C₁₄Alkyl Etoki
For cleaning ingredients containing silates, low levels of C₈The sulfonate is
It has been found that the end result can be improved by providing a "color" effect.
Has been done. Toning means to improve the final visual appearance, which
It is due to reducing haze. If present, C₈The sulfonate is preferably
, Weight ratio to major surfactant, about 1:10 to about 1: 1. C₈
Sulfonate is a commercial product of Bio-Terge PAS-8®.
From Stepan, also known as Witconate NAS-8
It is commercially available from Witco Corporation under the trade name of (registered trademark). Book
Another excellent "toning" surfactant useful in the invention is available from BASF.
Poly-Tergent CS-1 capable of If it exists
, Poly-Tergent CS-1 is preferably the major surfactant.
It is used at a mass ratio of about 1:20 to about 1: 1 with respect to the sexual agent.       [0301]   Less desirable, but other fields usually available at lower levels
For surface active agent, C₈~ C₁₈Alkyl sulfonate of Hoechst (Germany, Franc
Hostapur S of Kuhult, Aktiengesellschaft, D-6230)
AS (registered trademark), C_Ten~ C₁₄Linear or branched alkylbenzene sulphonate of
Cards, C₉~ C₁₅Detergent Surfactants of Alkylethoxycarboxylates
(Neodox available from Shell Chemical Corporation
Registered trademark) surfactant), C_{10 ~ 14}Alkylsulfates and ethoxysulfs
(For example, Stepanol AM (registered trademark) of Stepan)
Can be mentioned. Alkyl ethoxycarboxylates are polar to dissolve perfume.
It can be advantageously used at a very low level (about 0.01% or less). this child
Is an important benefit and as the most effective household cleaning article
Low levels of actives required for the present invention are provided.       [0302]   Another nonionic detersive surfactant used herein is generally an alcohol.
Alkoxylated alcohols containing from about 6 to about 16 carbon atoms in the hydrophobic alkyl chain of
Is. Usually, alkoxylated groups are combined with propoxy or ethoxy groups.
It is a propoxy group. Such a compound is known as Rhodia (08512).
A wide variety of chains available from Cranberry PO Box 425, New Jersey
Trade name Antarox (registered trademark) with long and alkoxylation degree
It is marketed under. Block copolymer of ethylene oxide and propylene oxide
Polymers can also be used, BAS under the trade name Pluronic (registered trademark)
Available from F. Preferred nonionic detersive interface for use herein
The activator is an alkyl group having R having about 6 to about 16, preferably about 8 to about 12 carbon atoms.
A killed chain and X is propoxy or a mixture of ethoxy and propoxy groups
, N is an integer of about 4 to about 30, preferably about 5 to about 8 R (X)_nObey H
. Other nonionic surfactants that can be used include natural substances such as sugars.
Sources include C₈~ C₁₆N-alkyl glucose amide interface
Activators may be mentioned. If present, the concentration of the alternative nonionic surfactant is
About 0.01% by mass to about 0.2% by mass, more preferably about 0.0% by mass of the burning component.
It is 1% by mass to about 0.1% by mass.       [0303]Mono- or polycarboxylic acid   For the purpose of removing the dirt of soap and the stain of hard water, the cleaning component of this article is about 2
It can be acidified to a pH of from about 5, more preferably about 3. Less than about 5, good
More preferably at least part through the use of one or more organic acids having a pKa of less than about 4.
In part, acidity is achieved. Such organic acids may help form a phase for thickening.
And can provide stain removal properties for hard water if desired. Of the present invention
Within the framework of the composition, organic acids are effective in improving the properties of hard water removal.
It has been found to be extremely efficient. Of low pH and one or more suitable acids
The use has also proved to be advantageous for the disinfecting effect.       [0304]   Examples of suitable mono-carboxylic acids include acetic acid, glycolic acid or β-hydroxyprotic acid.
Examples include ropionic acid. Examples of suitable polycarboxylic acids include citric acid, tartaric acid
, Succinic acid, glutaric acid, adipic acid, and mixtures thereof. Scarecrow
Acids are readily available commercially. More preferred polycarboxylic acids, especially non-
Examples of polymerizable polycarboxylic acids include citric acid (Milwaukee, WI)
, Aldrich Corporation at 1001 West Saint Paul Avenue
Available as "Purified AGS dibasic acid" from DuPont (Dela
Succinic acid, glutaric acid and adipine available from Wilmington, Ware)
A mixture of acids, maleic acid (available from Aldrich), and mixtures thereof
Can be mentioned. Especially for products requiring cleaning of soap residue, use citric acid.
Is most preferred. Of glycolic acid and adipic acid, glutaric acid and succinic acid
The mixture offers even greater benefits for hard water removal. In the composition of the present specification
The amount of organic acid in the cleaning component is about 0.01% to about 1% by weight of the cleaning component, and
Preferably about 0.01% to about 0.5%, most preferably about 0.025%.
It can be from% by weight to about 0.25% by weight.       [0305]Odor control agent   Cyclodextrins may be used in the cleaning component of the present invention. True spirit
The term "cyclodextrin" as used in the specification includes 6-12
Known cyclodextrins, such as unsubstituted cyclodextrins containing glucose units.
Kistrin, especially α-cyclodextrin, β-cyclodextrin, γ-six
Any of rodextrin and / or derivatives thereof, and / or mixtures thereof
Is included. α-Cyclodextrin consists of 6 glucose units, β-cyclodextrin
Cyclodextrin consists of 7 glucose units, and γ-cyclodextrin
Consists of 8 glucose units arranged in a donut-shaped ring. Specific
Depending on the coupling and the arrangement of glucose units, with a hollow interior of a certain volume
In addition, an inflexible, conical molecular structure is given to cyclodextrins.
The "lining" of each internal cavity is due to the hydrogen atoms and the glycosidic-bonded oxygen atoms.
Formed; thus this surface is completely hydrophobic. Unique shape and physics of the cavity
The chemical properties are that the cyclodextrin molecule is an organic component that can attach to the cavity.
Absorption of a part of a child or an organic molecule (with which an inclusion complex is formed)
It is possible. Including many malodorous molecules and fragrance molecules,
The child can attach to the cavity. Therefore, cyclodextrin, especially different
Mixtures of cyclodextrins with sized cavities contain reactive functional groups.
Controls the odor caused by the broad spectrum of fragrant organic substances that may or may not be present.
It can be used to control. Complex of cyclodextrin and odorous molecules
Somatization occurs rapidly in the presence of water. However, the degree of complex formation is absorbed.
It also depends on the polarity of the molecule. In aqueous solution, highly hydrophilic molecules (very water soluble)
Is only partially absorbed. Therefore, some extremely low molecules
When low amounts of organic amines and acids are present on wet surfaces, cyclodext
Strings do not effectively complex with them. However, the water was removed
, For example, when the surface is dried, some low molecular weight organic amines and acids can
It has a large affinity and makes it easier to complex with cyclodextrins.
It       [0306]   Cyclodextrin has various odor molecules when the solution of the present invention is applied to the surface.
The cavities in the cyclodextrin in the solution are
Essentially unsatisfied (unless cyclodextrin is complexed)
Under-derivatized (normal) β-cyclodext which should remain
Phosphorus is about 1.85% (about 1.85 grams in 100 grams of water) at room temperature.
It can be present at levels up to the solubility limit. β-cyclodextrin is water
Preferred for ingredients requiring higher levels of cyclodextrin than their solubility limit
Absent. Underivatized β-cyclodextrin was generally derivatized
Most preferred surfactants that are compatible with cyclodextrin are surface active
It has an adverse effect and is not preferred when the component contains a surfactant.       [0307]   Preferably, the aqueous cleaning component of the present invention is transparent. As defined herein
The term "transparent" as viewed refers to through a layer having a thickness of less than about 10 cm.
When transparent, it means transparent or translucent, preferably “colorless and transparent”.       [0308]   Preferably, the cyclodextrin used in the present invention is α-cyclodextrin.
Phosphorus and / or their derivatives, γ-cyclodextrin and / or their derivatives
Of conductors, derivatized β-cyclodextrins, and / or mixtures thereof
As such, it is highly water soluble. Cyclodextrin derivatives mainly contain some of the OH groups.
It consists of a molecule converted to an OR group. Cyclodextrin derivatives include, for example,
Cylated cyclodextrins and ethylated cyclodextrins such as
A cyclodextrin having a short-chain alkyl group, wherein R is a methyl group or
Cyclodextrin which is an ethyl group; hydroxypropyl cyclodextrin and
And / or hydroxyalkyl substitution such as hydroxyethyl cyclodextrin
Having a group, in which R is -CH₂-CH (OH) -CH₃Or^-CH₂ CH₂-OH; branched forms such as maltose-bonded cyclodextrins
Cyclodextrin; 2-hydroxy-3- (dimethylamino) propyl ether
And R is CH, which is a low pH cation.₂-CH (OH) -C
H₂-N (CH₃)₂A cationic cyclodextrin which is; for example, 2-hydroxy
Ci-3- (trimethylammonio) propyl ether chloride group, wherein
When R is CH₂-CH (OH) -CH₂-N⁺(CH₃)₃Cl^-Is a quaternary ammonium
Carboxymethyl cyclodextrin, cyclodextrin sulfate,
And anion ion cyclodextrins such as cyclodextrin succinylate
Phosphorus; amphoteric system such as carboxymethyl / quaternary ammonium cyclodextrin
Clodextrin; "Cyclodextrin, incorporated herein by reference.
"Optimal Performances with Minimal"
 chemical Modification of Cyclodextrins "), F. Daidini Pillard (F.
 Diedaini-Pilard) and B.I. B. Perly, 7th International Cyclodex
Cyclodex disclosed in the Trin Symposium Essentials (April 1994, p. 49)
A stringin, wherein at least one glucopyranose unit is 3-6-
Anhydrous-cyclomalto structure, for example having mono-3-6-anhydrocyclodextrin
Cyclodextrin; and mixtures thereof. Other cyclodes
Kistrin is described in US Pat. No. 3,426,011 (Parmerter et al.
, Issued February 4, 1969); No. 3,453,257; No. 3,453,258.
No. 3,453,259; and No. 3,453,260 (all permata (
Parmerter) et al., All issued on July 1, 1969; No. 3,459,731
Gramera et al., Issued August 5, 1969; No. 3,553,191 (
Parmerter et al., Issued January 5, 1971); 3,565,88
No. 7 (Parmerter et al., Issued February 23, 1971); No. 4,53
No. 5,152 (Szejtli et al., Issued August 13, 1985); Nos. 4,6
No. 16,008 (Hirai et al., Issued October 7, 1986); No. 4,678,59.
No. 8 (Ogino et al., Issued July 7, 1987); No. 4,638,058 (Blanc
Brandt et al., Issued January 20, 1987; and No. 4,746,734 (
Tsuchiyama et al., Issued May 24, 1988), all of the above patents are referenced.
Incorporated by reference.       [0309]   Highly water-soluble cyclodextrin has a solubility in water of 100 ml at room temperature.
At least about 10 g in water, preferably at least about 20 g in 100 ml water,
More preferably at least about 25 g of cyclodex in 100 ml of water at room temperature.
It is a string. Availability of solubilized uncomplexed cyclodextrin is effective
And essential for efficient odor control performance. Solubilized, water-soluble cyclodex
Trin is more efficient than water-insoluble cyclodextrin when deposited on the surface
It can exhibit excellent odor control performance.       [0310]   Examples of preferred water soluble cyclodextrin derivatives suitable for use herein are:
Hydroxypropyl α-cyclodextrin, methylated α-cyclodextrin
, Methylated β-cyclodextrin, hydroxyethyl β-cyclodextrin
, And hydroxypropyl β-cyclodextrin. Hydroxyalkyl
The cyclodextrin derivative is preferably about 1 to about 14, more preferably about 1.
Having a degree of substitution of 5 to about 7, where the total number of OR groups per cyclodextrin is
It is defined as the degree of substitution. The methylated cyclodextrin derivative is usually about 1 to about
It has a degree of substitution of 18, preferably about 3 to about 16. Known methylated β-cyclode
Kistrin is a heptakis-2,6-di-o, commonly known as DIMEB.
-Methyl-β-cyclodextrin, wherein each glucose unit has about 1
It has about 2 methyl groups with a degree of substitution of 4. Preferred, even commercially available,
Methylated β-cyclodextrins usually have different degrees of substitution of about 12.6
Randomly methylated β-cyclodex, commonly known as RAMEB
It is Trin. DIMEB is preferred to RAMEB for surface activity of preferred surfactants.
RAMEB is preferable to DIMEB because it also has a large effect. preferable
Cyclodextrins are commercially available, for example, from Cerestar USA and Wacker.
It is available from Wacker Chemicals (USA).       [0311]   It is preferred to use a mixture of cyclodextrins in the cleaning ingredient.
May be Such mixtures have a broader range of molecular sizes and are even more
Absorbs a wider range of odors by forming a complex with a wide range of aromatic molecules
To do. Preferably, at least a portion of the cyclodextrin is α-cyclodextrin.
Strin and / or derivative thereof, γ-cyclodextrin and / or derivative thereof
, And / or derivatized β-cyclodextrin, more preferably
, Derivatized with α-cyclodextrin, or an α-cyclodextrin derivative
Β-cyclodextrin, and even more preferably derivatized.
Of Derivatized β-Cyclodextrin with Derived α-Cyclodextrin
And most preferably hydroxypropyl α-cyclodextrin and hydro
Mixtures of xylpropyl β-cyclodextrin, and / or methylated α-cyclo
It is a mixture of dextrin and methylated β-cyclodextrin.       [0312]   In a particular embodiment, the cleaning components of the present invention may be used at levels of normal use to the eye.
It may contain low levels of cyclodextrin so that no visible residue appears.
preferable. Cleaning ingredients used to treat surfaces under conditions of use
Are preferably visually indistinguishable when dry. Use under conditions of use
Typical levels of cyclodextrin in the composition are about 0.01% of the cleaning ingredients.
Wt% to about 1 wt%, preferably about 0.05 wt% to about 0.75 wt%,
It is preferably about 0.1% by mass to about 0.5% by mass. Higher concentrations of ingredients
May leave unacceptable visible residue.       [0313]Source of hydrogen peroxide   The cleaning ingredients of this article are for further disinfection, fungicidal and fungicidal effect
It may contain hydrogen peroxide or a source of hydrogen peroxide. Cleaning success
The minute component is substantially compatible with the use of hydrogen peroxide. Preferred hydrogen peroxide
, Benzoyl peroxide and hydrogen peroxide. Among the compositions herein
About 0.05% to about 5%, more preferably about 0.1% to about 3%, most preferably
Can optionally be present at a level of about 0.2% to about 1.5%.       [0314]   If peroxides are present, it is desirable to provide a stabilizing system. Suitable
Stabilization systems are known. The preferred stabilization system is for cleaning ingredients.
About 0.01% to about 0.5% by weight, more preferably about 0.01% to about 0%.
． 25% by weight, most preferably about 0.01% to about 0.1% by weight.
It consists of existing radical scavengers and / or metal chelators. Radicals
Examples of cavengers are propyl gallate, butylated hydroxytoluene (BH
T), butylated hydroxyanisole (BHA) and the like.
Be done. Suitable metal chelating agents include diethylenetriamine penta-acetate,
Diethylenetriamine penta-methylene phosphate, hydroxyethyldiphos
Examples include fate.       [0315]Thickener polymer   Using low levels of polymer to thicken the cleaning component of the present invention
You can In general, the level of thickener polymer interferes with the properties of the end result of the product.
Keep it as low as possible so that it doesn't. When used at low concentrations, it also improves the properties of the final result.
Xanthan gum is a particularly preferred thickener because it can Thickening polymer agent
Is about 0.001% to about 0.1% by weight of the cleaning component, more preferably
Is from about 0.0025% to about 0.05%, most preferably about 0.005%
% To about 0.025% by weight.       [0316]Aqueous solvent system   A cleaning component that is aqueous is at least about 80% by weight of the component of an aqueous solvent,
More preferably, it comprises from about 80% to more than 99% by weight of the components of an aqueous solvent.
The aqueous component is usually in the form of micelles and is a water-insoluble component that induces significant micelle swelling.
Do not incorporate minutes at a substantial level.       [0317]   Aqueous solvent systems have low molecular weight and high water content typically found in cleaning compositions.
It may contain a soluble solvent such as ethanol, isopropanol and the like. This
Solvents such as should be used to impart disinfecting properties to otherwise less active ingredients.
You can In addition, they are particularly useful in ingredients where the total level of perfume is very low.
Can be In fact, highly volatile solvents can provide "lift".
The characteristics of the fragrance can be enhanced. Highly volatile solvents, if present, are commonly used.
Usually about 0.25% to about 5% by weight of the component, more preferably about 0.5% by weight.
About 3% by weight, most preferably about 0.5% to about 2% by weight is present. Such solvent
Examples of methanol, ethanol, isopropanol, n-butanol, iso
-Butanol, 2-butanol, pentanol, 2-methyl-1-butanol,
Methoxymethanol, methoxyethanol, methoxypropanol, and them
A mixture of   The cleaning component of the present invention is capable of removing other solvents, especially bubbles created by the component.
It also includes paraffins and isoparaffins that can be substantially reduced.
it can.       [0318]Suds suppressor   Suitable silicone suds suppressors for use herein are any silicone
And silica-silicone mixtures. Silicones are generally alkylated
Silica is usually referred to as a silica aeroge, although it can be represented as a lisiloxane material.
And xerogels and finely divided fractions exemplified by various types of hydrophobic silica
Used in split form. In industrial practice, the term "silicone" means
Various relatively high molecular weight porosities containing sun units and various hydrocarbyl groups.
It is a generic term including the limmer. In fact, silicone compounds are widely used in the art.
, U.S. Pat. No. 4,076,648;
, 021, 365; 4,749,740; 4,983,316.
And European patents: EP 150,872; EP 217,501; and EP 499.
, 364. Each of the above patents is incorporated herein by reference
. Preferred has trimethylsilyl endblock units and is 5x1 at 25 ° C.
0^-Fivem²/S-0.1m²/ S, i.e., the value of n is 40 to 1500
A polydiorganosiloxane such as polydimethylsiloxane
It These are preferred because of their ready availability and relatively low cost
.       [0319]   Preferred classes of silicone compounds useful in the cleaning components herein
Is a mixture of alkylated siloxanes of the type disclosed above and solid silica.
Including. Solid silica is made by fumigated silica, precipitated silica or gel-forming techniques.
Silica may be used. Bonded directly onto silica or to silicone resin
Therefore, treat the silica particles with dialkylsilyl groups and / or trialkylsilane groups.
By doing so, the silica particles can be made hydrophobic. Preferred silicone
The compound has a particle size ranging from 10 mm to 20 mm and 50 m²Ratio exceeding / g
Hydrophobic, silanized, most preferably trimethylsilanized with a surface area
Included silica. Silicone compounds suitable for use in the composition according to the invention
The average viscosity is 2x10^-Fourm²/ S-1m²Results with silicone compounds having / s
1 to 30% by mass (more preferably 2.0 to 15% by mass) of the total mass generated as
With an amount of silica in the range of. Preferred silicone compound is 5x10^-3 m²/S-0.1m²It can have a viscosity in the range of / s. Especially suitable is
2x10^-2m²/ S ~ 4.5x10^-2m²A silicone compound with a viscosity of / s
It       [0320]   Suitable silicone compounds for use herein are Rhone Poulenc (Rhon
from various companies including e Poulenc), Fueller and Dow Corning
It is commercially available. Examples of silicone compounds for use herein are both
Silicone DB® 100 and Si available from Dow Corning
Recone emulsion 2-3597 (registered trademark).       [0321]Fragrance   The cleaning component of the article may include one or more perfumes. Used here
When added, the fragrance is added primarily to contribute to the sense of smell and is better than ethanol.
Includes perfume components that are often supplemented by the use of volatile organic solvents such as
It       [0322]   Most hard surface detergent products contain some fragrance to provide olfactory aesthetic benefits.
Provide and mask any of the "chemical" odors the product may have.
. Extremely volatile, low boiling (low boiling) scents of such fragrances
The main function of the ingredients is to influence the subsequent odor of the surface being cleaned.
Rather, it is to improve the aroma of the product itself. However, some
Low-volatility, high-boiling perfume ingredients provide a fresh and clean impression on the surface
It may be desirable that the components are deposited and present on a dry surface
.       [0323]   The perfume is preferably more water soluble to minimize spotting and film formation.
And / or volatile. Fragrances useful herein are described in US Pat.
, 108,660 (issued April 28, 1992, Michael),
Column 8 at lines 48-68, Column 9 at lines 1-68, and Column 10 at 1-2.
It is described in more detail on line 4, see the patent and especially the special part.
Incorporate as       [0324]   Fragrance ingredients are natural products such as aromatic oils, anhydrides, resins, resins, condensates, etc.
And / or containing saturated and unsaturated compounds, aliphatic, carbocyclic and heterocyclic compounds
Hydrocarbons, alcohols, aldehydes, ketones, ethers, acids, acetone
It may be a synthetic perfume ingredient such as tars, ketals, nitriles and the like. Or
Examples of fragrant fragrance ingredients are: graniol, granyl acetate, linalool, linari.
Luacetate, tetrahydrolinalool, citronellol, citronellyl acete
, Dihydromyrcerol, dihydromyrcenyl acetate, terpinerol
, Terpinyl acetate, 2-phenylretanol, 2-phenylethylacetate
, Benzyl alcohol, benzyl acetate, benzyl salicylate, benzene
Dilbenzoate, styrylyl acetate, amyl salicylate, dimethylben
Zircarbinol, trichloromethylphenylcarbinyl acetate, p-third
Grade. Butyl-cyclohexyl acetate, isononyl acetate, α-n-ami
Lucyanamic aldehyde, α-hexyl-cinnamyl aldehyde, 2-methyl
-3- (p-tertiary.butylphenyl) -propanal, 2-methyl-3 (p-
Isopropylphenyl) propanal, 3- (p-tertiary.butylphenyl) p
Ropanal, tricyclodecenyl acetate, tricyclodecenyl propione
4- (4-hydroxy-4-methylphenyl) -3-cyclohexanecarba
Aldehyde, 4- (4-methyl-3-pentenyl) -3 cyclohexanecarba
Aldehyde, 4-acetoxy-3-pentyl-tetrahydropyran, methyl dihydride
Rojasmonate, 2-n-heptyl-cyclopentanone, 3-methyl-2-pe
N-cyclopentanone, n-decaneal, n-dodecanal, 9-decenol
Ru-1, phenoxyethyl isobutyrate, phenylacetaldehyde acetate
, Phenylacetaldehyde dicetyl acetal, geranonitrile, citrone
Ronitrile, cedolyl acetate, 3-isocamphyl-cyclohexanol,
Cedolyl ether, isolongiforanone, orvepin nitrile, orvepin,
Heliotropin, coumarin, eugenol, vanillin, diphenyl oxide, hi
Droxy citronellal, ionones, methylionones, isomethylionone
, Irons, cis-3-hexanol and their esters, indane musk, te
Musk syrup, musk scent of isochroman, macrocyclic ketones, musk of lactone, ethi
Renbula rate, an aromatic nitro musk. The cleaning ingredients in this document are
Usually, 0.1% by mass to 2% by mass, preferably 0.1% by mass to 1% of the cleaning component.
It contains mass% of perfume ingredients or mixtures thereof. Preferred embodiment containing hydrogen peroxide
As such, the perfume must be selected to be compatible with the oxide.       [0325]   In one implementation, the perfume component of the cleaning component is hydrophobic and volatile.
High, eg, less than about 260 ° C., preferably less than about 255 ° C .; and more preferably
Preferably, it has a boiling point of less than about 250 ° C. and at least about 3, preferably more than about 3.1.
, Even more preferably a component having a ClogP of greater than about 3.2.       [0326]   Many component logPs have been reported, for example, Daylight Chemical
Information Systems (Daylight CIS, Irby, CA)
(Daylight Chemical Information Systems, Inc .; Daylight CIS)
The Pomona92 database available is based on a citation from the original document.
It may contain many logPs. However, the logP value is
Calculated by the "CLOGP" program available from CIS. This blog
Ram also has an experimental logP value for the data in the Pomona92 database.
I have a list. "Calculated logP" is the disconnection of Hansch and Leo
Determined by the one-sided approach (C. Hansch, incorporated herein by reference,
Leo, P.G.Sammens, J.B. Taylor and C.A. Ramsden, `` Comprehensive Pharmaceuticalization
29 in Comprehensive Medicinal Chemistry No. 4 (1990)
(See page 5). Fractionation is based on the chemical structure of each constituent and
Consider the number and type of atoms, atomic bonding and chemical bonding. The ClogP value is the most reliable
And is widely used for evaluation of physicochemical properties, and is preferably used in the present invention.
It is used in place of the experimental logP value in the selection of various major solvent components. Clog
Other methods that can be used to calculate P include, for example, the clip-pen (
Crippen) in 1987, J. Chem. Inf. Comput. Sci Volume 27
The fragmentation method disclosed on page 21; Viswanadhan, 1989.
J. Chem. Inf. Comput. Sci Vol. 29, page 163
Fragmentation method; and Broto, 1984, Eur. J. Med. Ch
em. -Chim. Theor. Vol. 19, page 71
It       [0327]Detergency builder   It is effective as a hard surface detergent and reduces film formation and streaking to a decisive level.
Detergent builders may also be included in the cleaning ingredients. Preferred detergent builders
Includes citric acid and tartaric acid, which were previously described as part of the disclosure of polycarboxylic acids.
It is a carboxylic acid. Tartaric acid improves cleanability, and detergent builders use hard surfaces.
Minimize the filming / streaking problems that normally occur when added to detergents.
Can be stopped.       [0328]   Detergent builders are present at levels that provide detergent formation and are adjusted to the acidic pH described above.
The non-aligned part is usually about 0.01% by mass to about 0.3% by mass of the cleaning component.
%, More preferably from about 0.005% to about 0.2%, most preferably
It is present at a level of about 0.05% by weight to about 0.1% by weight.       [0329]Buffer   The cleaning components of this article may include various other ingredients known for detergent compositions.
Additional ingredients may also be included. Preferably, they have unacceptable film formation
/ Not used at levels that cause streaking. The buffer is heavy in this application.
It is an essential ingredient of an additional ingredient. This is mainly due to the low levels of active substances used
Exists as a result of being. The ideal buffer system is streaking / membrane
Maintains pH over the desired narrow range while not inducing growth. Background of the invention
The preferred buffer is highly volatile and has good cleaning properties during use.
Can be provided. As such it is a corresponding buffer with low volatility.
They are advantageous in that they can be used at a much higher level.
Such buffers tend to have low molecular weight, ie less than about 150 g / mol.
In general, it tends to contain hydroxyl groups not exceeding 1. Examples of preferred buffers
, Ammonia, methanolamine, ethanolamine, 2-amino-2-methyl
-1-propanol, 2-dimethylamino-2-methyl-1-propanol, vinegar
Examples thereof include acids and glycolic acids. Of these, the most preferable are ammonia and 2
-Dimethylamino-2-methyl-1-propanol and acetic acid. Place to use
If such a buffering agent is present at about 0.005% to about 0.5%,
For higher compounds, higher levels are even more preferred.       [0330]   Non-volatile buffers can also be used in the present invention. Such a buffer is
Generally lower than preferred level due to increased tendency to burning / film formation
Must be used at the level. Examples of such buffers include sodium carbonate, charcoal
Potassium acid and potassium bicarbonate, 1,3-bis (aminomethyl) cyclohexane
, Sodium citrate, citric acid, maleic acid, tartaric acid, etc.
Not limited to. Maleic acid is buffered because of its tendency to not induce surface damage.
Is particularly preferable. As it provides antimicrobial benefits as a registered EPA active,
Citric acid is also desirable. In addition, cleaning components containing hydrophilic polymers are
When the product is used for daily shower cleaning, acidity is
To provide good wetting and a long-lasting "sheeting" effect
Have been found. When used, the non-volatile buffer is about 0.001% of the composition.
% To about 0.05% by weight.       [0331]   Non-limiting examples of other additional ingredients are: they are detrimental to film formation / streaking
Enzymes such as protease; toluene sulfonate
Like thorium, sodium cumene sulfonate and potassium xylene sulfonate
Hydrotrope; about 0.01% to about 0.5%, preferably about 0.01% to about 0.
． Thickeners other than hydrophilic polymers at a level of 1%; and aesthetics like colorants
It is an ingredient to enhance.       [0332]Antiseptic and antibacterial agent   Articles for which preservatives can be used and are intended for domestic use, especially high levels of water
May be required in a number of beneficial ingredients in articles containing. Examples of preservatives
, Angus chemical (Northbrook, Illinois, USA,
Hexenodine, bronopol sold by Thunder Road 211)
Is mentioned. Other preservatives include Kathon, 2-((hydroxymethyl) (
Mino) ethanol, propylene glycol, hydroxymethylaminoacetic acid Natri
Um, formaldehyde and glutaraldehyde, dichloro-s-triazine
Trione, trichloro-s-triazinetrione, and dioctyldimethylan
Monium chloride, didecyldimethylammonium chloride, C₁₂, C₁₄And C ₁₆ The quaternary ammonium salt containing dimethyl benzyl is mentioned. Preferred antiseptic
Agents include Avicia Chemicals (1989, Delaware,
1,2-Benzisothiazolin-3-one sold by Wilmington)
And polyhexamethylene biguanide and Aldrich-Sigma
ma) (1001 West Saint Paul Avenue, Milwaukee, WI 53233 Wis
1001 West Saint Paul Avenue, Milwaukee, Consin
), Chlorhexidine diacetate, Arc Chemicals (Ar
ch Chemicals) (06856 Merritt Seven, Norwalk, CT)
Examples include sodium pyrithione sold at address 01 PO Box 5204).
Be done. When used, preservatives are preferred at concentrations of about 0.0001% to about 0.01%.
Exist. These same preservatives will provide antimicrobial control at the surface.
However, higher levels, typically about 0.005% to about 0.1%, are possible.
Needs to be used on a bell. There are other antibacterial agents including quaternary ammonium salts
Can be done at higher levels, ie levels above about 0.05%
, Not preferable in the background of the present invention. Such compounds are preferred polymers
Interfering points are often found. In particular, quaternary ammonium surfactants
Tend to hydrophobically modify hard surfaces. Therefore, a sufficient concentration of quaternary ammonium
It has been found that the preferred polymer is not effective in the composition containing the aluminum surfactant.
ing. Zwitterionic surfactants containing lauryl betaine and cocoamido betaine
Similar results have been found with agents. If present, cationic or amphoteric
The level of ionic surfactant is less than about 0.1%, preferably about 0.05%.
Should be lower. Further, such as orthobenzyl-para-chlorophenol
Very hydrophobic antibacterial / bactericidal agents are avoided. If present, such material is approximately 0.0
It should be kept at a level below 5%.       [0333]Additional ingredients suitable for inclusion in the articles of the present invention Additional layers   In a particular embodiment, the articles of the present invention can be separated from laminated webs by those skilled in the art and
It may include one or more additional layers that will be recognized as identifiable. Such additional
The additional layers may help the effectiveness of the article by complementing the materiality of the article. Pa
-In the context of personal care, additional layers should be cleaned and / or tone
Suitable for enhancing the soft feel of the surface of the article that contacts the area to be trimmed
. Suitable additional layers are layers of the materials discussed above as suitable layers for the laminated web.
Also includes things.       [0334]   Nonwovens are a preferred additional layer for the present invention. Useful in the present invention,
Suitable nonwovens made of synthetic material are also available from a wide variety of commercial sources. product
Non-limiting examples of suitable materials useful herein for the layers of the layered web include about 50% laser.
Material containing perforated water and 50% polyester
It has a basis weight of about 61 grams per meter (gsm), and Veratech
.HEF40-047; MAHEF140-10 available from Inc. Walpole)
2 (contains about 50% rayon and 50% polyester, and has a hole wound with water
The material has a basis weight of about 67 gsm and is sold by Veratech Co., Ltd.)
Novonet (registered trademark) 149-616, (about 100% polypro
A heat-bonded grid pattern material containing pyrene, having a basis weight of about 60 gsm,
(Sold by Veratech, Inc.); Novonet (registered trademark) 149-8
01, (containing about 69% rayon, about 25% polypropylene, and about 6% cotton,
A heat-bonded grid pattern material with a basis weight of about 90 gsm,
From Novonet (registered trademark) 149-191, (about 69%
Rayon, about 25% polypropylene, and about 6% cotton, heat bonded grid pattern
This material has a basis weight of about 120 gsm and is sold by Veratech Co., Ltd.
HEF Nubtex (registered trademark) 149-801, (about 100
% Material that contains% polyester and has a hole that is tapped and wound with water.
It has the basis weight of and is sold by Veratech, Inc. above;
) ® 951V, containing about 75% rayon, about 25% acrylic fiber
, A dry, perforated material, having a basis weight of about 51 gsm, Chicopee,
New Brunswick, N.J.); Keyback® 1368,
(Contains about 75% rayon and about 25% polyester.
It has a basis weight of gsm and is available from Chicope above);
ce) (registered trademark) 1236, (hole containing about 100% rayon and wound with water
A material with a basis weight of about 48 to about 138 gsm, obtained from Chicopee above.
DURALACE® 5904, (contains about 100% polyester)
It has a hole material wound with water and has a basis weight of about 48 to about 138 gsm,
Available from Chicopee above); Chicopee® 5763
, (With carded and water perforated material (8x6 holes per inch, 3x per centimeter)
2 holes), 70% rayon and 30% polyester, and optionally up to 5% by weight
Latex binder (based on acrylate or EVA), from about 60 to
Has a basis weight of about 90 gsm and is available from Chicope); Chicope®
9900 series (eg Chicope 9931-62gsm, 50/50 laser
Yeon / Polyester, Chicope 9950-50Gsm, 50/50 Rayo
(Polyester) (50% rayon / 50% made from carded and rolled up material)
From 0% rayon / 100% polyester or 100% rayon
Yon / 0% polyester fiber composition, about 36 gsm to about 84 g
has a basis weight of sm and is available from Chicope); Sontara 8868
, (50% cellulose and about 50% polyester made of water wrapped material
It has a basis weight of about 72 gsm and is available from DuPont Chemicals).
You can Preferred nonwoven substrate materials are from about 24 gsm to about 96 gsm, more preferably
Preferably about 36 gsm to about 84 gsm, and most preferably about 42 gsm to about 78.
It has a basis weight of gsm.       [0335]   Additional layers are described in European patent application EP 7025 published March 27, 1996.
50A1 may include a polymeric reticulated sponge, such as
Are all incorporated herein by reference. Such polymer mesh sponge
Is nylon or an addition polymer of olefin monomer and polycarboxylic acid
Extruded, tubular mesh made from strong and flexible polymers such as Liamide
Includes multiple layers of processed mesh.       [0336]   The additional layer also contains a formed film and composite material, i.e. a number of materials.
Molded films can also be included. Preferably, such a molded film has a skin
Including plastics that tend to be soft. Suitable soft plastic molding
Examples of the film include polyolefin such as low density polyethylene (LDPE).
However, the present invention is not limited to these. Additional layers include molded plastic film
In such cases, the layer is perforated such that the layer is liquid permeable, eg
It is preferable to have large holes or fine holes. In one embodiment, the layers are
, Including a film made of plastic with only minute holes. Another
In an embodiment, the additional layer is a plastic with both fine and large pores.
Including molded film. In such an embodiment, the layer has such fine pores.
Having a cloth-like feel, cleansed and / or treated
Adapted to contact the area to be treated. Preferably such an embodiment
In, the surface deformation of the fine holes faces the opposite of the surface deformation of the large holes in the additional layer.
It In such cases, the three-dimensional thickness formed from the surface deformation causes
The pores of the mold maximize the wetness and foaming of the entire article, and surface deformation during use of the article
It is thought that a bubbly whirlpool-like object is created by constant compression and decompression.       [0337]   In any case, the additional layers, including the molded film, are preferably less
About 100 holes / cm², More preferably at least 500 holes / cm²,
Even more preferably at least about 1000 holes / cm², And most preferably
At least about 1500 holes / cm²The base material has holes. Further preferred of the present invention
The preferred embodiment is about 5 cm³/ Cm²/ Sec to about 70 cm³/ Cm²/ Second, more preferably
Is about 10 cm³/ Cm²/ Sec to about 50 cm³/ Cm²/ Sec and most preferably about 15
cm³/ Cm²/ Sec to about 40 cm³/ Cm²Includes a non-woven layer having a water flow rate of 1 / sec
To do.       [0338]   Suitable molded films useful in the nonwoven layers of the present invention and composites containing molded films.
Each of the composite materials is incorporated by reference in its entirety in US Pat.
No. 4,342,314 (issued August 3, 1982, Radel et al.), General
Co-pending application Ser. No. 08 / 326,571 and PC assigned to
T Application No. US95 / 07435 filed on June 12, 1995, and 199
(Published January 11, 2006), and US Pat. No. 4,629,643 (198).
Issued on December 16, 2006, and disclosed by Curro et al.
, But is not limited to this. Moreover, the nonwoven layer comprises at least one molded film and
And at least one non-woven fabric, wherein the layers are formed in a vacuum
It may be a composite material. A suitable molded film composite material has a basis weight of 30 g.
Combining sm-carded and fluffed polypropylene non-woven fabric with molded film
Examples of the vacuum laminated composite molding film material formed by
Not limited to.       [0339]   Another preferred material suitable for the additional layer is cotton wadding. Preferably heel
The stuffing contains synthetic materials. As used herein, "synthetic" refers to this
These materials are mainly obtained from various artificial materials or natural materials that have been further modified.
Means that. Suitable synthetic materials include acetate fiber, acrylic fiber, cellulose
Ester fiber, acrylic fiber, polyamide fiber, polyester fiber, poly
Olefin fiber, polyvinyl alcohol fiber, rayon fiber, polyethylene foam
Polymers, polyurethane foams and combinations thereof, but not limited to
Not determined. Preferred synthetic materials, especially fibers such as nylon fiber, rayon fiber, poly fiber
Selected from the group consisting of olefin fibers, polyester fibers and combinations thereof
can do. Preferred polyolefin fibers are polyethylene and polypropylene.
Len, polybutylene, polypentene, and combinations and copolymers thereof
A fiber selected from the group consisting of: A more preferred polyolefin fiber is
Made from polyethylene, polypropylene, and combinations and copolymers of these.
Fiber selected from the group consisting of: A preferred polyester fiber is polyethylene
Lephthalate, polybutylene terephthalate, polycyclohexylene dimethylene
Selected from the group consisting of terephthalates, and combinations and copolymers thereof
Is a fiber that is made. A more preferable polyester fiber is polyethylene terephthalate.
, Polybutylene terephthalate, and combinations and copolymers thereof
A fiber selected from the group consisting of: The most preferred synthetic fiber is polyethylene
Contain solid staple polyester fiber containing terephthalate homopolymer
I'm out. Included among suitable synthetic materials are solid single components (ie, chemically uniform).
Quality fiber, multi-constituent (ie two fibers each)
Fibers made from the above materials, multi-component (ie more than two types)
A synthetic) fiber made by twisting different filaments above into a thick fiber, and
There is a combination of these. Preferred fibers are bicomponent fibers, multicons
It is a tutuent fiber and a combination thereof. Bicomponent like this
The filaments may have a core-sheath arrangement or a side-by-side arrangement. In either case
However, the wadding is a combination of fibers containing the materials listed above or itself
It may include any of the fibers including the listed materials.       [0340]   The core-sheath fibers preferably have a core of at least about 1 more than the sheath material.
0 ° C higher T_gPolyesters, polyolefins, and combinations thereof
Including a material selected from the group consisting of: On the contrary, the bicomponent fiber sheet
The T is preferably at least about 10 ° C. below the core material._gHaving polio
T at least about 10 ° C lower than the refining and core materials_gPolyester with
Includes materials selected from the group consisting of polyolefins and combinations thereof
. Whether in a side-by-side arrangement, a core-sheath arrangement or a solid single component arrangement,
Woven fibers, especially bicomponent-type fibers, are spiral or spiral or pleated.
The attached arrangement can be shown.       [0341]Cleansing, conditioning, makeup, polishing of surfaces requiring such treatment / Cleaning and how to clean   The present invention cleans skin or hair with the personal care articles of the present invention.
And how to condition. The present invention further comprises a cosmetic agent
It relates to a method of delivery to the skin and / or hair. The present invention also requires such treatment.
For domestic use such as polishing / cleaning or cleaning hard surfaces.
Each such method is: a) optionally, a substantially dry, disposable of the present invention.
A step of wetting the article with water and b) removing the wet article with a wiping or rubbing motion.
Contacting the surface in need of treatment.       [0342]   【Example】   The following examples further describe and explain embodiments within the scope of the present invention. Less than
In the Examples, all ingredients are listed at activity levels. These examples are merely illustrative.
It is shown for purposes only and the invention may be made without departing from the spirit and scope of the invention.
Many modifications are possible and do not limit the invention. The components are identified by their chemical name, CTFA name.       [0343] I. Cleansing ingredientsExample 1   Representative cleansing ingredients for articles of the present invention are prepared by the following method.   Shave 53.0 grams of bar soap containing the following ingredients. :   [Table 2]       [0344]   Grated glycerol (99.7%) 37.0 gms, water 9.5 gms
, And 0.5 gms of fragrance. 200 ° with continuous stirring of the mixture
Heat to F. Cool and mill the mixture in a standard 3-roll mill into a suitable sealed container.
Store cleansing ingredients.       [0345]Example 2   Representative cleansing ingredients for articles of the present invention are prepared by the following method.   Shave 40.0 grams of bar soap containing the following ingredients:   [Table 3]       [0346]   Grated glycerol (99.7% by mass) 45.0 gms, water 4.5 g
ms, and 0.5 gms of fragrance. While continuously stirring the mixture, 20
Heat to 0 ° F. Cool and mill the mixture in a standard 3-roll mill to a suitable seal volume.
Store cleansing ingredients in a container.       [0347]Example 3   A representative powdered cleansing component of the article of the present invention is prepared by the following method.
.   Shave 40.0 grams of bar soap containing the following ingredients:   [Table 4]   Store the soap flake in a suitable sealed container.       [0348]Example 4   A representative powdered cleansing component of the article of the present invention is prepared by the following method.
.   Shave 40.0 grams of bar soap containing the following ingredients:   [Table 5]       [0349]   The soap flake is mixed with sodium bicarbonate in a weight ratio of 90:10. Standard
Grind the mixture twice in a quasi 3-roll mill. A suitable sealed container for collecting flakes
Store in.       [0350]Example 5   Representative cleansing ingredients for articles of the present invention are prepared by the following method. Example
2 cleansing ingredients with 0.1% protea based on the weight of the soap bar
Mix with enzyme. Then, the resulting mixture, relative to the mass of cleansing ingredients
Mixed with 2% dry hydrocolloid sodium carboxymethylcellulose
,Smash. Store the enzyme-containing cleansing ingredients in a suitable sealed container.       [0351]Example 6   A representative liquid cleansing ingredient is prepared containing the following ingredients.   [Table 6]       [0352] Example 7   Representative cleansing ingredients for articles of the present invention are prepared by the following method. 3/4
Soap shavings of Example 2 with 3 cups of isopropyl alcohol (99%) in a cup
Heat the soap until the soap dissolves. Once the soap has dissolved add the rest of the alcohol
. Add 10 ounces of sugar dissolved in as little water as possible. 8 oz glyce
Mix about 4 tsp of dye with phosphorus. Add glycerin (99.7%). Stirring
To do. The concentration changes from a thin liquid to a rope-like ribbon falling from the stirring tool,
Continue heating until an aliquot of material drops onto a cold surface until it solidifies. Suitable content
Pour the mixture into a container and harden. The advantage of the mixture is that it can be remelted when heated.
In addition, it allows for easy processing to prepare the article.       [0353]Example 8   An exemplary non-lacrimatory liquid cleansing component is prepared that includes the following components.   [Table 7]   The distinguishing feature of this composition is that it is non-irritating to the skin and eyes.       [0354] Example 9   A typical liquid cleansing ingredient is prepared including the following ingredients.   [Table 8]   The mixture is mild to use on sensitive skin.       [0355] Example 10   Prepare a typical liquid cleansing ingredient by mixing the following ingredients
.   [Table 9]       [0356] Example 11   A representative cleansing ingredient is prepared by mixing the following ingredients.   [Table 10]       [0357] Example 12   A representative cleansing ingredient is prepared that includes the following ingredients.   [Table 11]       [0358]   Heat the mixture to 50 degrees Celsius, the mixture loses 38% of its original mass, paste
Stir continuously until it has a similar concentration. The paste advantageously has a base layer
It is easily processed and requires no further drying.       [0359] Example 13   A representative cleansing ingredient is prepared that includes the following ingredients.   [Table 12]   Ethylene vinyl in SEFA cottonate by high speed shear mixing at 90 degrees Celsius
Melt the acetate polymer. Add surfactant powder and citric acid and mix
It Microbeads of silicone polymer are added, mixed, cooled and fixed. set
The product is remeltable and easily impregnated into the substrate layer and coated onto it.       [0360] Example 14   A representative cleansing ingredient is prepared containing the following ingredients.   [Table 13]   Melt alcohol ethoxylate. Mix the carboxylate until homogeneous.
To meet. The mixture is then cooled and solidified until ready for use. Composition remelts
It is possible and easily impregnated into the fabric and coated on top.       [0361] Example 15   A representative cleansing ingredient is prepared that includes the following ingredients.   [Table 14]   The mixture is heated to 70 ° C. and continuously stirred until it becomes paste-like. Cool down
Solidify until ready for use.       [0362] Example 16   A representative cleansing ingredient is prepared that includes the following ingredients.   [Table 15]   The ingredients are heated together with gentle stirring until homogeneous.       [0363] Example 17   A representative cleansing ingredient is prepared that includes the following ingredients.   [Table 16]   Add the ingredients slowly at 60 ° C in the following order until each is dissolved in water.
Ru: TEA, lauryl phosphate, glucose amide. Cool to 45 ° C and stir
Below, add sultaine, polyquaternium-39 and sulfate. Fragrance, preservative
And cool to room temperature.       [0364] Example 18   A representative cleansing ingredient is prepared by mixing the following ingredients.   [Table 17]       [0365] Example 19   A representative cleansing ingredient is prepared by mixing the following ingredients.   [Table 18]       [0366] Example 20   Prepare a typical antimicrobial cleansing ingredient by mixing the following ingredients
.   [Table 19]       [0367]Example 21   Prepare a typical antimicrobial cleansing ingredient by mixing the following ingredients
.   [Table 20]       [0368] II. Conditioning ingredients Examples 22-26   Prepare a typical skin conditioning ingredient by mixing the following ingredients
To do.   [Table 21]       [0369] Examples 27-31   Prepare a typical skin conditioning ingredient by mixing the following ingredients
To do.   [Table 22]       [0370] Example 32   Prepare a typical skin conditioning ingredient by mixing the following ingredients
To do.   [Table 23]       [0371] Examples 33-35   Prepare a typical skin conditioning ingredient by mixing the following ingredients
To do.   [Table 24]       [0372]Examples 36-40   Representative conditioning components for articles of the invention are prepared by the following method.   [Table 25]       [0373] Treatment for all emulsions:   Heat the hydrophobic phase to 70 ° C and add active hydrophobic skincare ingredients to homogenize.
Stir until dry. Pre-mix hydrophilic phase ingredients with active hydrophilic skin care ingredients
And gently heat if necessary to dissolve or disperse them. Gradually these
To the hydrophobic phase and continue stirring. Homogenize (high shear mixer; ultrasonic
Homogenizer; or Microfluidics Corp.
High pressure homogenizer such as Microfluidizer). straight
It is then applied to the surface of the substrate and rapidly cooled below room temperature in ice or ice water. Chemistry
Store in a controlled environment in the presence of nitrogen if necessary for physical stability.       [0374]Examples 41-45   The following ingredients were used, as described in Examples 30-40, in a representative condition.
Prepare the conditioning component.   [Table 26]       [0375]Examples 46-50   The following components were used, as described in Examples 36-40, to prepare representative conditions.
Prepare the conditioning component.   [Table 27]       [0376]Example 47 :   Glycerin incorporated into microparticles is then mixed with the melted lipid phase and stored
Cooled or applied to the substrate.       [0377] Examples 51-56   The following components were used, as described in Examples 36-40, to prepare representative conditions.
Prepare the conditioning component.   [Table 28] Examples 57-59   Representative conditioning components for articles of the invention are prepared by the following method.   [Table 29]       [0378]   All ingredients are stirred together until a microemulsion is formed. Its solubility para
The skin care ingredients are added first to the phase where the meter most closely matches. Add wax
In the case of wax, it is slowly heated to just the melting point of the wax and diffused by stirring to diffuse it into the base material.
Or cool to room temperature and store.       [0379]Examples 60-62   Representative conditioning components for articles of the invention are prepared by the following method.   [Table 30]       [0380]   First add the skin care ingredients to the phase whose solubility parameters most closely match
. The ingredients are then stirred together until a microemulsion is formed. Of base material
Coat the surface.       [0380]Examples 63-68   Representative conditioning components for articles of the invention are prepared by the following method.   [Table 31]       [0382]   While heating to 65 ° C, use a low-speed impeller mixer to mix the surfactant and the aliphatic alcohol.
Mix. While mixing, remove heat source and cool to 65 ° C. Positive ion system
Add limmer and stir until homogeneous. While stirring, add the remaining ingredients of Part A
Add gradually. Homogenize and disperse SEFA as an emulsion. About 6.5
Titrate with concentrated sulfuric acid until the pH is reached. Spread the composition of Part A onto the tray and essentially
A suitable oven (vacuum or convection) at a temperature not exceeding 65 ° C until the water runs out
A dry mixture is prepared by drying in. Dried part A to part B
Mix with the polymer gelling agent from (1) and heat to dissolve or disperse. The composition obtained
Is mixed with a physical gelling agent. It is heated to melt and the gelling agent is dissolved in the composition.
It is applied to the surface of the substrate or cooled to room temperature and stored.       [0383]Examples 69-74   Representative of Articles of the Invention Using the Following Components as Described in Examples 63-68
A general conditioning ingredient is prepared.   [Table 32]       [0384] Examples 75-78   A representative skin conditioning ingredient is prepared containing the following ingredients.   [Table 33]       [0385]   Melt lipid components, add water (if applicable) and humectant, add surfactant
Continue heating and stir until homogeneous. Cool to room temperature and use skin care
Add a substance and a depositing agent. Adjust the pH to about 7.0 with sulfuric acid. Spray on base material
-Roll, wrap, dip or otherwise apply and allow to dry (including water) before packaging.
If you have).       [0386]Examples 79-82   A representative skin conditioning ingredient is prepared that includes the following ingredients.   [Table 34]       [0387]Examples 83-86   A representative skin conditioning ingredient is prepared that includes the following ingredients.   [Table 35]       [0388]Examples 87-88   A representative skin conditioning ingredient is prepared that includes the following ingredients.   [Table 36]       [0389]Example 89   Mixing the following ingredients makes it especially suitable for use by babies, infants and children.
Prepare suitable representative skin conditioning ingredients.   [Table 37]       [0390] III. Cleaning ingredientsExamples 90-91   Use as a daily shower detergent by combining the following ingredients
A representative cleaning ingredient suitable for is prepared.   [Table 38]       [0391]Examples 92-105   A typical floor cleaning ingredient is prepared by mixing the following ingredients.   [Table 39]       [0390]Note: All formulations in Examples 92-105 were Dow Corning at 0.015%. Gu's AF suds suppressor, containing a balance of perfume and deionized water at 0.04%. composition : Purchase all commercially available raw materials. The PVNO used in the above examples is Ray
Made of Reilly Industry with a molecular weight of about 20,000 g / mol
It The surfactant is Plantaren 2 commercially available from Henkel.
000, cosmetic grade, C_8-16Alkyl polyglucoside, Henkel's plastic
Ntalene 1200 is a commercial cosmetic grade C_{10 ~ 16}Alkyl polyglucoside
It Akzo AG-6210 is a commercially available_8-12Alkyl polyglucoside
And Neodol C11EO5 has an average chain length of about 11 carbon atoms.
Commercially available non-ionic containing alkyl groups and on average about 5 ethoxy groups per molecule
It is a system alkyl ethoxylate. The solvent used is Sigma-Aldrich
Propylene glycol propyl ether.       [0393]Examples 106-111   Prepare typical antibacterial hard surface cleaning ingredients by mixing the following ingredients:
To make.   [Table 40]       [0394]Examples 112-115   Prepare typical antibacterial hard surface cleaning ingredients by mixing the following ingredients:
To make.   [Table 41]       [0395]Examples AE   A cleaning ingredient suitable for cleaning and refreshing fabric through a storage bag
To prepare. The following ingredients are mixed.   [Table 42]       [0396]   In addition, the preferred cleaning ingredients for use in the dryer are:   [Table 43]       [0397]   In addition, the preferred cleaning ingredients for use in the dryer are:   [Table 44]       [0398] IV. Cosmetic ingredientsExample 116   A cosmetic ingredient suitable to provide protection against UV irradiation to the skin is prepared.   [Table 45]       [0399] V. Laminated web   The following examples are shown in Table 1 as an exemplary laminated web suitable for the article of the present invention.
You The choice of outer and inner layers and combinations is practically limitless, so the implementation shown
The examples are meant to illustrate the possible construction of laminated webs,
It is not meant to be limited to any particular material or structure.       [0400]   Various combinations of materials are shown in Table 1. Layer from outer layer of laminated web to next layer
They are numbered in order of structural proximity. Therefore, layer 1 is always the outer layer,
The last numbered layer is also the outer layer.       [0401]   Is Clopay Molded Film Cropay from Cincinnati, Ohio?
I got it from The "molded film" has its origins in one of the web's
Capillary network structure that extends from one side and ends by forming holes in the other side
It means a macroscopically stretched three-dimensional plastic web including a continuous structure.
Such a forming film is generally described in commonly assigned U.S. Pat. No. 4,342,314 (1
Published August 3, 982, Radel et al.).       [0402]   Elastomer molding film is available from Tredegar (Tr
edegar) Obtained from Film Products. Such films are generally
Filed on Mar. 14, 1997 in the name of the assigned Curro et al.
U.S. patent copending application Ser. No. 08 /
816,106, an improvement on the aforementioned Radel et al. Web disclosed in US Pat.
Claw No. 106 is a known elastomeric material, generally according to Radel et al., Supra.
Resilient polymer, which may be manufactured from or laminated from polymeric materials
-The website is disclosed. This kind of laminate is less elastic with elastomeric materials
Can be prepared by co-extrusion of the membrane layer, not the waist belt
It may be used on the part and along the body of absorbent clothing such as the folding of pants.
Yes.       [0403]   The open cell foamable material of the high internal phase emulsion is described in the above-mentioned US Pat. No. 5,260.
, 345 and US Pat. No. 5,268,224.
It   BBA and Corovin / BBA non-woven fabrics are available from Kucoa, South Carolina.
Obtained from BBA, Leanville.   BOUNTY® Paper Towels, Cincinnah, Ohio
Obtained from Procter & Gamble Company of Tee.       [0404]   For the materials listed below, the basis weight is given in grams per square meter (gsm).
You Low density polyethylene is indicated by "LDPE"; polypropylene is "PP"
, And polyethylene is indicated by “PE”. Spunbond is indicated by "SB".       [0405]   [Table 46]       [0406] V. Article of the present inventionExample 125   Skin Conditioning Ingredient Any One of Examples 22-26 and Examples
A typical skin cleansing and conditioner utilizing 124 laminated webs.
To prepare the article.       [0407]   Both parts of the base web are added in such a proportion that the components per finished web equal 1.25 g.
Skin conditioning from hot containers by pumping on surface through slot dies
Slot the components and use a cooling fan to cool the components quickly on the outer surface of the article.
Cross it. For individual articles with rounded corners of about 120 mm x 160 mm rectangle,
Disconnect the web.       [0408]Example 126   Representative skin cleansing products and skin conditioning products by the following methods
Manufacture goods.   Continue through the coating tip in a single line along the center of the web.
The cleansing ingredients of Example 11 were added to the product of Example 117 by successive extrusion.
Apply to one side of a layered web. Percentage to get 0.5 grams per finished article
Extrude the cleansing ingredients. 20mm away from cleansing ingredients, cleanse
The skin conditioner of Example 23 in two stripes 30 mm wide on both sides of the ring component.
Slot coating with the conditioning component. Skin conditioning per finished product
Slot component on one side of the laminated web at a rate such that the loading component equals 1.25 g.
Apply the skin conditioning ingredients in a hot container with a pump via a.
The web is traversed by a cooling fan for rapid cooling on the exterior surface of the article. Horny
The web is cut into individual articles that are rounded to a rectangle of approximately 140 mm x 105 mm.       [0409]Example 127   A representative cleansing article is prepared by the following method.   The laminated web of Example 121 is cut into 200 mm x 200 mm pieces. 0.
Cleanse ingredients of Example 19 until 25 g of cleansing ingredients have been applied.
Apply to the web with Rashi. Articles are dried and stored until needed for use. Goods
Is two-sided with one soft surface and another polishing surface for deep cleaning
Is.       [0410]Examples 128-132   Using the skin conditioning ingredients of Examples 36-40, a representative skin tone
Prepare ranging and conditioning articles.   Continue through the coating tip in a single line along the center of the web.
The cleansing ingredients of Example 11 were added to the product of Example 119 by successive extrusion.
Apply to one side of a layered web. Percentage to get 0.5 grams per finished article
Is an air-laid, bulky, low-density wadding that extrudes cleansing ingredients with
The second base material web is contacted with a layer containing a cleansing component onto the first base material.
To send continuously. Bottling is 10% 15 denier PET fiber, 50% 3 denier
Of 40% bicomponent fiber with PET core and PE sheath
Of 10 denier bicomponent fibers of identical core-sheath composition
And having a basis weight of about 50 grams per square meter (gsm). Across the web
Cut and sift with a dot pattern that includes a grid of 4 mm diameter seal points that are evenly spaced.
The web is continuously fed to the ultrasonic sealing machine. Per finished web
Substrate web at a rate where the components are equal to 0.25 g (approx. 13 gsm add-on)
Pump the skin condition from the hot container through the slot die on both sides of the
Slots the conditioning component to allow the conditioning component to cool quickly on the exterior surface of the article.
Cross the cooling fan to dismiss. Continuously mix slot coating containers
Maintains emulsion stability. A rectangle with rounded corners of about 120 mm x 160 mm
Cut the web into individual articles that will become       [0411]Examples 132-136   Representative examples using the skin conditioning ingredients of Examples 27-31 respectively
A simple skin cleansing and conditioning article is prepared.   Continue through the coating tip in a single line along the center of the web.
The cleansing ingredients of Example 11 were added to the product of Example 120 by successive extrusion.
Apply to one side of a layered web. Percentage to get 0.5 grams per finished article
Extrude the cleansing ingredients. The first to place and place it in contact with the surfactant-containing layer
A second substrate web is continuously fed over the substrate. The second substrate is from DuPont
50:50 hydroentangled rayon and polyester 50:50 mix available
It is a thing. A grid of 4 mm diameter seal points, evenly spaced across the web
Continuously feed the web into an ultrasonic sealing machine, which seals with a dot pattern containing.
Ingredients per finished web equal to 0.25g (approx. 13gsm add-on)
Pumped through both sides of the substrate web through slot dies at a rate
Slot-coating with skin conditioning ingredients that allow the ingredients to quickly
Cross the cooling fan to cool. Continuously mix slot coating containers
Maintain the stability of the emulsion. Rectangular shape with rounded corners of about 200 mm x 130 mm
The web is cut into individual articles to be shaped.Example 137       [0412]   Using the liquid cleansing ingredient of Example 8, a representative skin cleanser was prepared by the following method.
Prepare a ging article.   Bath the composition of 150 mm x 115 mm substrate until the mass increases by about 8 grams.
The liquid cleansing component is applied to the first substrate by dipping in liquid. The base material is
, Is a cotton wadding containing polyester fibers bound through the air, per square meter
It has a basis weight of about 100 grams (gsm). Dry the substrate. Product of Example 119
A second substrate, which is a layer web, is placed on top of the first substrate. The laminated web of Example 119.
A second piece of the material under the first substrate. Evenly spaced across the web
An ultrasonic sealing machine that seals with a point pattern including a grid of sealing points with a diameter of 4 mm
Are used to seal the substrates together. With a rectangle with rounded corners of about 140 mm x 105 mm
Cut the web into individual articles.       [0413]Examples 138-141   Using the laminated webs of Examples 117, 118, 119, and 123, respectively,
A representative cleansing article is prepared by the following method.   Continuously through the tip of the coating into 4 lines separated by 20 mm
By extruding, the cleansing component of Example 11 was applied to one side of the first substrate.
To use. Clean at a rate of 4.4 grams of cleansing ingredients per finished article.
Extrude the ranging ingredients. Base material is 30% 15 denier PET fiber, 35%
3 denier PET core and PE sheath bicomponent fiber, and 35% 10 denier
Air-laid, bulky, low-density containing bicomponent fibers of the same core-sheath composition
Degree cot and has a basis weight of about 85 grams per square meter (gsm).
The second substrate, which is the laminated web, is placed in contact with the layer containing the surfactant.
Continuously feed onto the substrate. 4m evenly spaced across the web
The ultrasonic sealing machine continuously seals in a point pattern including a grid of m sealing points.
Send in the web. Individual objects with a rounded corner and a rectangle of about 120 mm x 160 mm
Cut the web into pieces.       [0414]Examples 142-146   Using the skin conditioning ingredients of Examples 22-26,
Prepare a cleansing and conditioning article.   Insert the coating tip into four linear lines that are separated by 20 mm across each side.
And continuously extruding the cleansing ingredients of Example 11 from the first substrate.
Apply to one side. 4.4 grams of cleansing ingredient was obtained per finished article
The cleansing ingredients are extruded in a ratio such that The base material is 30% 15 denier
PET fiber, bicomponent fiber of 35% 3 denier PET core and PE sheath, and
Air-laid containing 35% 10 denier bicomponent fibers of the same core-sheath composition
It is a high-density, bulky, low-density cotton wadding that weighs approximately 85 grams per square meter (gsm).
). On top of the first substrate that contacts and places the surfactant-containing layer
The second base material is continuously sent out. This second substrate is the same as the first. Example 1
A third backing web, which is a laminated web of nineteen, into a second backing so that it contacts the second backing.
Is continuously fed onto the base material web. Evenly spaced across the web
Ultrasonic sealing machine that seals with a point pattern including a grid of sealing points with a diameter of 4 mm
Feed the web continuously. 2g skin conditioning per finished article
Pump from hot vessel through extruded jet tip, in proportion to component
Dot coat skin conditioning components on both sides of the web. About 0 each
． It contains 1 g of conditioning ingredients, has a diameter of about 4 mm,
The components are distributed in the dots located in a part. Cools quickly on the outside of the item
And pass the article across the cooling fan. With rounded corners of about 140 mm x 105 mm
Cut the web into individual articles that will be rectangular.       [0415]Examples 147-151   Using the skin conditioning ingredients of Examples 41-45,
Prepare a cleansing and conditioning article.   Continuously through the tip of the coating into 4 lines separated by 20 mm
By extruding, the cleansing component of Example 11 was applied to one side of the first substrate.
To use. Ratio such that 4.0 grams of cleansing ingredient per finished article is obtained.
Extrude the cleansing ingredients at a rate. The base material is 30% 15 denier PET fiber,
35% 3 denier PET core and PE sheath bicomponent fiber, and 35% 10
Airlaid, bulky containing bicomponent fibers of the same core-sheath composition of denier
It is a low density cotton pad and has a basis weight of about 85 grams per square meter (gsm).
To do. The second substrate is placed on top of the first substrate that contacts and places the surfactant-containing layer.
Continue to send. This second substrate is the same as the first. Laminated wafer of Example 117
The third substrate web, which is a tub, so that it contacts the second substrate.
Continuously feed up. A 4 mm diameter sheet that is evenly spaced across the web.
Web in an ultrasonic sealing machine that seals with a dot pattern that includes a grid of grid points.
Send in. Equal to 2g of skin conditioning ingredient per finished article
The hot water from the hot container to the laminated web through the tip of the extrusion jet.
Dot coat skin conditioning ingredients. About 0.1g of each
Containing a positioning component, has a diameter of about 4 mm and is located at a part of the sealing point
The components are distributed in the dots. Cool the ingredients so that they cool quickly on the exterior surface of the article.
Pass the item across the fan. With a rectangle with rounded corners of about 140 mm x 105 mm
Cut the web into individual articles.       [0416]Examples 152-154   Using the skin conditioning ingredients of Examples 57-59, as follows:
A representative skin cleansing and conditioning article is prepared.   Continuously through the tip of the coating into 4 lines separated by 20 mm
By extruding, the cleansing component of Example 12 was applied to one side of the first substrate.
To use. Ratio such that 4.0 grams of cleansing ingredient per finished article is obtained.
Extrude the cleansing ingredients at a rate. The base material is 30% 15 denier PET fiber,
35% 3 denier PET core and PE sheath bicomponent fiber, and 35% 10
Airlaid, bulky containing bicomponent fibers of the same core-sheath composition in denier
It is a low density cotton pad and has a basis weight of about 85 grams per square meter (gsm).
To do. A second on top of a first substrate that contacts and lays the cleansing ingredient-containing web
The base material of is sent out continuously. This second substrate is the same as the first. Example 117
A third substrate web that is a laminated web of the second substrate so as to contact the second substrate.
Continuously feed on the material web. Uniformly spaced diameters across the web
Continuous with ultrasonic sealing machine, which seals with a point pattern including a grid of 4mm sealing points
To send the web. Ingredients per finished web are 2g (approx.
ON) at a rate equal to (on) through the slot die on both sides of the substrate web.
Slot coat the skin conditioning ingredients from a hot container,
Cross the cooling fan for rapid cooling outside the product. Ingredients on the exterior of the article
Thread the article by a cooling fan for quick cooling. Approximately 140 mm with rounded corners
Cut the web into individual articles that will be rectangular X 105 mm.       [0417]Examples 155-156   Representative cleansing with skin conditioning ingredients of Examples 29-30
Prepare a conditioning and conditioning article.   At a distance of 20 mm, 40 mm, and 20 mm, respectively, across the width of the web
The ends of the coating to form four pairs of parallel lines on each side of the web.
The cleansing ingredients of Example 12 were first extruded by continuously extruding through the ends.
Apply to one side of the substrate. 4.4 grams of cleansing ingredients per finished article
The cleansing ingredients are extruded in a ratio such that The base material is 10d polyester
Air-laid, bulky, low-density cottage containing tellur fiber, square meters
It has a basis weight of about 100 grams per. Put it in contact with the surfactant-containing layer
The second base material is continuously fed onto the first base material. This second base material is used in Example 1
18 laminated webs. 4 mm diameter, evenly spaced across the web
The ultrasonic sealing machine continuously seals with a dot pattern including a grid of sealing points.
Send in a bu. Cut the web into a rectangle with approximately 120mm x 160mm with rounded corners
. 2 g of skin conditioning component is applied to the article on the laminated web. Coe
Hot liquid with a pipette so that the tings are in the form of dots with a diameter of about 4 mm.
Apply the ingredients to the article as (60-70 ° C). Each dot is about 0.1g composition
, Such dots are located at a portion of the seal point.       [0418]Examples 157-159   Representative skin creams with the cleansing ingredients of Examples 1, 2 and 5 were prepared in the following manner.
Prepare a conditioning and skin conditioning article.   Space between the edges and quadrants to seal the layer in the absence of surfactant
The low temperature is kept in the four divisions that form the rectangle of about 10 inches x 12 inches.
A permeable, fusible web containing heat-sealable fibers of melting, and 8 grams of crease
Apply the component. Transparent webs are commonly supplied by sewing tool distributors.
Handable, fibrous, low density polyethylene (LDPE or LLDPE) material
is there. 4 oz / square yard polyester wadding cut to the same size as the web
Layers of fusible material on the fusible web. Polyester stuffing is 4 oz / yd²The basis weight of
And composed of polyester fibers having an average diameter of about 30 microns, adhesively bonded,
For example, Stearns Textil in Cincinnati, Ohio.
es) Mountain Mist Extra Heavy Batting # 205 (Mo
Untain Mist Extra Heavy Batting). Example 12
3 layers of laminated web can be fused with carded non-woven fabric that makes up the outer surface of the article
Put it under the web. Sencorp, Hyannis, Massachusetts
Platen, such as the Sentinel 808 heat seal machine available from
By using the sealing device of the
Flow into and thus form a proper seal, typically about 300 ° F and 30 ps
a mechanical pressure seal of 6-10 seconds at i is sufficient, with sufficient temperature and pressure,
The layers are sealed together in a rectangular windowpane mold. The seal is continuous around the rim
, With window-like cross members in the X- and Y-directions, each reaching a width of about 2 mm.
To do. After cooling, 3 g of the skin conditioning ingredient of Example 22 was completed.
Apply to one side of the product. So that the coating has a dot shape with a diameter of about 7 mm,
Conditioned as hot liquid (70-80 ° C) through the tip of the extrusion jet.
Apply the training component. Each dot contains about 0.3g of conditioning ingredients
To do. Finish, round corners and store until ready for use.       [0419]Examples 160-163   Hot melt cleansing set of Examples 7, 13, 14 and 15 by the following method
Representative skin cleansing products and skin conditioning products
Prepare.   Coating the components with slots uniformly across the web at a rate of about 80 gsm
The hot melt cleansing ingredients are continuously added to the web by. The web is
40% 15 denier polyester fiber, 30% 3 denier PET core
PE sheath bicomponent fiber and 30% 10 denier same core-sheath composition
Is a bulky, air-laid cottage containing two component fibers of
It has a basis weight of 85 grams (gsm). Put it in contact with the surfactant-containing layer
The second base material is continuously fed onto the first base material. This second base material is used in Example 1
21 laminated web. 4 mm diameter, evenly spaced across the web
The ultrasonic sealing machine continuously seals with a dot pattern including a grid of sealing points.
Send in a bu. Condense across both sides of the product at a rate of about 3g per finished product
The skin condition of Example 26 was obtained by coating the yonning component with dots.
Add the ingredients to the web. Each dot contains about 0.1g of ingredients,
With a diameter of 5 mm, the conditioning component dots are
Located together in a patch so that it is in the center. Rounded corners about 120mmX160m
The substrate is cut into individual articles that are rectangular in m.       [0420]Example 164   A representative cleansing article is prepared by the following method.   Across the web, four lines of coating separated by 20 mm were used.
The cleansing ingredient of Example 11 was first extruded by continuously extruding through the tip.
Applied to one side of the substrate. 4.0g cleansing composition per finished article
The cleansing ingredients are extruded in proportions such that minutes are obtained. The base material is 15% of 30%.
PET fiber of Neil, bicomponent fiber of 35% 3 denier PET core and PE sheath
Fiber and 35% 10 denier bicomponent fiber of the same core-sheath composition
Arrayed, bulky, low density cotton wadding, approximately 85 grams per square meter
It has a basis weight of (gsm). First substrate in contact with and placing a surfactant-containing layer
The second base material is continuously sent onto the above. This second substrate is per square meter
A mixture of polyester and pulp fibers having a basis weight (gsm) of about 120 grams.
It The third substrate is delivered over the second. This third substrate is the laminate of Example 119.
It's the web. Of 4 mm diameter seal points, evenly spaced across the web
Continuously feed the web to an ultrasonic sealing machine that seals the dot pattern including the grid
Recommit. Cut the web into a rectangle with rounded corners, approximately 140 mm x 105 mm.       [0421]Example 165   Representative skin cleansing products and skin conditioning products by the following methods
Manufacture goods.   Across the web, four lines of coating separated by 20 mm were used.
The cleansing ingredient of Example 11 was first extruded by continuously extruding through the tip.
Applied to one side of the substrate. 4.0g cleansing composition per finished article
The cleansing ingredients are extruded in proportions such that minutes are obtained. The base material is 15% of 30%.
PET fiber of Neil, bicomponent fiber of 35% 3 denier PET core and PE sheath
Fiber and 35% 10 denier bicomponent fiber of the same core-sheath composition
Arrayed, bulky, low density cotton wadding, approximately 85 grams per square meter
It has a basis weight of (gsm). First place the cleansing ingredient-containing layer in contact with it
The second base material is continuously fed onto the base material. This second substrate is a square meter
Mixing polyester and pulp fibers with a basis weight (gsm) of about 120 grams per
It is a thing. The third base material is delivered onto the second base material. The third base material is 30% of 1
5 denier PET fiber, 35% 3 denier PET core and PE sheath
Fiber and 35% 10 denier bicomponent fiber of the same core-sheath composition.
Air-laid, bulky, low-density wadding, approximately 85 g / m2
It has a basis weight of ram (gsm). The fourth substrate web was the laminated web of Example 117.
Is sent onto the third web which is Straight, evenly spaced across the web
Ultrasonic sealing machine that seals a dot pattern including a grid of sealing points with a diameter of 4 mm
Continuously feed the web to.       [0422]Examples 166-170   Representative skin cleansing products and skin conditioning products by the following methods
Manufacture goods.   Across the web, four lines of coating separated by 20 mm were used.
The cleansing ingredient of Example 11 was first extruded by continuously extruding through the tip.
Applied to one side of the substrate. 4.0g cleansing composition per finished article
The cleansing ingredients are extruded in proportions such that minutes are obtained. The base material is 15% of 30%.
PET fiber of Neil, bicomponent fiber of 35% 3 denier PET core and PE sheath
Fiber and 35% 10 denier bicomponent fiber of the same core-sheath composition.
Arrayed, bulky, low density cotton wadding, approximately 85 grams per square meter
It has a basis weight of (gsm). First place the cleansing ingredient-containing layer in contact with it
The second base material is continuously fed onto the base material. This second substrate is a square meter
Mixing polyester and pulp fibers with a basis weight (gsm) of about 120 grams per
It is a thing. The third substrate is delivered over the second. The third substrate is 30% 15 denier
PET fiber, 35% 3 denier PET core and PE sheath bicomponent fiber
And 35% 10 denier bicomponent fibers of the same core-sheath composition
A laid, bulky, low-density wadding, approximately 85 grams per square meter (
gsm). The fourth substrate web is the laminated web of Example 117.
Send to the top of the third web. Rewind the web. Cut a length of web
The cut and includes a grid of 4 mm diameter seal points that are evenly spaced across the article.
Seal the pattern together using an ultrasonic sealing machine. About 70
Tip of multipipette with heated container, pump, on / off valve maintained at ℃
Includes a motorized XY coordinate control system for edges and coating tips,
Both sides using an XY table, which is a gram-controlled controlled metering system
2 g of the conditioning composition of any of Examples 22-26 onto the article.
Cover. Dot contains about 0.1g of conditioning system,
It has a diameter of 4 mm. The components cool rapidly on the surface of the article. Until just before use
To package.       [0423]Examples 171-172   With the surfactant powder (cleansing ingredient) of Examples 3 and 4 by the following method
Representative skin cleansing and skin conditioning articles are prepared.
4 grams of dried surfactant powder was made up of heat-sealable fibers with a low melting point.
Applied to one side of a permeable, fusible web formed. Transparent
Eb is manufactured by Peron and manufactured by H. H. of Chicago, Illinois. Levinson (H.
 Wonder Under available from Levinson & Co.)
. Disperse the powder evenly over an oval area of about 17 cm x 19 cm. Same as web
A fusible web with a layer of 2 ounces / square yard of polyester wadding cut into pieces
Put on. Polyester wadding has a basis weight of 2 ounces per square yard and an average diameter of approximately
It is composed of a mixture of 23 micron fibers and 40 micron fibers, at least
Is partly crimped. The batting thickness is about 0.23 inches, measured at 5 gsi
Is. About 1270 cfm / ft²Air permeability and critical pressure of about 2.7c
mH₂It has O bubble permeability. It is thought that the padding is heat-bonded without using an adhesive.
To be The second substrate layer, which is the laminated web of Example 118, was used as the fusible web.
Cut into one size. The second layer is placed under the fusible web, Massachusetts
808 heat sealed available from Sencorp, Hyannis, USA
Machine using pressure platen heat sealer to seal the layers together using point glue
Also, the circumference of 2 mm width is sealed with a heat-sealing die. Each point adhesive has a diameter of about 3 mm
, There are about 51 independent sealing points that are evenly spaced. Finish the article
Skin conditioning composition according to any one of Examples 32, 33, 34, or 35
Apply 2.5 grams of min to one side of the finished article. Each coating is about 0.1g
Use a pipette to draw hot liquid (about 50
C.) as the composition is applied to the surface of the article, such dots forming part of the seal point.
To position. The components cool quickly on the surface of the article and are sealed with a metal foil that is sealed until ready for use.
Store in the rum packaging.       [0424]Example 173   A representative cleansing article is prepared by the following method.   4 grams of the cleansing ingredient of Example 11 was added to a low melting point, heat sealable polyurea.
Apply to one side of a permeable, fusible web containing mid fibers. Transparent
Eb is manufactured by Peron and manufactured by H. H. of Chicago, Illinois. Levinson (H.
 Wonder Under available from Levinson & Co.)
. The cleansing component is applied to an elliptical area of about 13 cm x 18 cm. Cleansing
Air dry the ingredients. 2 oz / sq yard poker cut to the same size as the web
A layer of reester wadding is placed on the fusible web. Polyester stuffing is 2 basis weight
The average diameter is about 23 microns and the fiber is 40 microns.
It is composed of a mixture of fibers, at least part of which is crimped. Stuffed cotton is an adhesive
It is considered that they are bonded by heat without using. Fusing the layers of the laminated web of Example 123
Put on opposite side of sex web. The shape of the article is an egg shape of about 122 mm x 160 mm
Is. Available from Sencorp, Hyannis, Massachusetts
Sealing device for pressure platen such as Sentinel 808 heat sealing machine
The layers together using spot bonding in a grid pattern by a heat sealing mold
Seal it. The spot adhesion reached about 4 mm in diameter and about 51 evenly spaced.
There are individual seal points. The article is finished and the article is ready for use.       [0425]Examples 174-194   Utilizing the skin conditioning compositions of Examples 36-56 in the following manner.
To prepare typical skin cleansing and skin conditioning articles
It   At a distance of 20 mm, 40 mm, and 20 mm, respectively, across the width of the web
Through the tip of the coating into four lines that form a pair of parallel lines on each side of the web.
And continuously extruding the cleansing ingredients of Example 11 from the first substrate.
Apply to one side. 4.0 grams of cleansing ingredients were obtained per finished article
The cleansing ingredients are extruded in a ratio such that The base material includes polyester fibers
Air-laid, bulky, low-density wadding, about 100 per square meter
It has a basis weight of grams. Clean the laminated web of Example 120, which is the second substrate.
Dispense onto a first substrate that is placed in contact with the ing ingredient. Uniform across the web
Seal with a point pattern that includes a grid of seal points with a diameter of 4 mm spaced at
Continuously feed the web into the sonic sealing machine. 3g of ingredients per finished web
On both sides of the substrate web at a rate equal to (about 140 gsm add-on per side)
The skin conditioner is pumped from the hot container through the extruded jet tip.
The yonning ingredient is covered with beads, but each dot is about 0.2g of conditioner.
And is localized at the seal point. So that the ingredients cool rapidly on the exterior surface of the article,
Thread it across the cooling fan. Emulsion by continuously mixing coating containers
Maintain stability. Each of them becomes a rectangle with rounded corners of about 120 mm x 160 mm.
Cut the web into articles.       [0426]Examples 195-197   Representative skin cleansing with liquid cleansing ingredients of Examples 6, 9 and 10.
Prepare the article.   2 grams of cleansing ingredients in the shape of the window glass avoiding the edges and sealing areas
Liquid cleansing by solidifying and coating with a brush until applied
The ingredients are applied to one side of the first substrate. Base material is 30% 15 denier PET fiber
Wei, 35% 3 denier bicomponent with PET core and PE sheath
Bicomponent with the same core-sheath composition of 10% denier and 35%
Contains a mixture of ent fiber and has a basis weight of about 100 grams per square meter
(Gsm) air laid, bulky, low density cot. Cleansing success
Air dry the minutes. A second substrate, the laminated web of Example 120, is placed on the first substrate.
Send to. Entered from Sencorp, Hyannis, Massachusetts
A pressure platen sheet, such as the hand-held Sentinel 808 heat seal machine
The heat-sealing mold is sufficient to form a suitable seal using
Together with temperature and pressure, the layers are sealed together in a rectangular glazing mold. Seal is edge
Are continuous around the window and reach a width of about 2 mm.
It has a cross-shaped member. Finish the article to a size of 200mm x 180mm       [0427]Examples 198-200   Representative skin cleanse with skin conditioning ingredients of Examples 60-62
Prepare a ging article.   2 grams of cleansing ingredients in the shape of the window glass avoiding the edges and sealing areas
The liquid clay of Example 10 was solidified and coated with a brush until applied.
The ranging component is applied to one side of the first substrate. The first substrate is 30% of 15
Denier PET fiber, 35% 3 denier, with PET core and PE sheath
Bicomponent fiber and 35% 10 denier bicomponent with identical core-sheath composition
Contains a mixture of fibers and has a basis weight of about 100 grams per square meter (gsm
) Airlaid, bulky, low density cotton wadding. Air dry cleansing ingredients
It A second substrate, the laminated web of Example 120, is delivered over the first substrate.
Sen available from Sencorp, Hyannis, Massachusetts
Utilize a pressure platen sealing device such as the Sentinel 808 heat sealing machine
And the heat seal mold provides sufficient temperature and pressure to form a suitable seal.
Together, the layers are sealed together in a rectangular windowpane mold. The seal is continuous around the edge
And a window glass-like cross in the X- and Y-directions, each reaching a width of approximately 2 mm.
Have members. Articles are cut and aligned and 1.5 grams of skin conditioner
Mechanically equipped with a feeding container kept with a gap of 1.5 mm and about 60 ° C.
Bulky packing of articles by sending ingredients through slotted rolling devices
Apply to the cotton side. The ingredients cool quickly on the surface of the article and are sealed until just before use.
Store in metal film packaging.       [0428]Example 201   The cleansing ingredients of Example 11 and the laminated webs of Examples 123 and 121 were
Is used to prepare a representative skin cleansing article in the following manner.   4 linear coating tips 20 mm apart across the web
The cleansing component of Example 11 was continuously extruded through the first group
Apply to one side of the material. 4.0 grams of cleansing ingredient per finished article
The cleansing ingredients are extruded in the ratio as obtained. Base material is 30% 15 denier
PET fiber, 35% 3 denier PET core and PE sheath bicomponent fiber,
And 35% 10 denier bicomponent fibers of the same core-sheath composition
It is a bulky, low-density cotton stuffed with about 85 grams (g
sm). The second substrate, which is the laminated web of Example 121, was interfacial activated.
It is continuously fed onto a first substrate which is placed in contact with the layer containing the sexualizing agent. Further research
The laminated web is positioned so that the molded film side to be abraded forms the surface of the article. Fruit
The third base material web, which is the laminated web of Example 123, was not carded on the outer surface of the article.
It is fed under the first substrate together with the woven cloth. Evenly spaced across the web
Ultrasonic sealing machine that seals with a point pattern including a grid of sealing points with a diameter of 4 mm
Feed the web continuously. The product is a 120 mm x 160 mm service with rounded corners.
It is cut into pieces individually and has a different feel on the two surfaces.       [0429]Example 202   Representative skin cleansing products and skin conditioning products by the following methods
Manufacture goods.   4 grams of the skin conditioning ingredient of Example 57 is applied to the finish of Example 173.
Apply half on each side of the item. 5mm wide and 2cm from each side of the article
Composition using an extruded jet tip to create two stripes 100 mm long
It is applied as a hot liquid (60-70 ° C).       [0430]Example 203   Representative skin cleansing products and skin conditioning products by the following methods
Manufacture goods.   3 grams of the skin conditioning ingredient of any one of Examples 69-72
Apply half on each side of the finished article of Example 173. Half of the ingredients on each side of the article
The ingredients are slot coated into the product as a uniformly hot liquid (60-70 ° C).
Apply by applying.Example 204 [0431] A representative cleansing article is prepared by the following method.       [0432]   Transversely across, with the tip of the coating in 4 lines spaced 20 mm apart.
And continuously extruding the cleansing ingredients of Example 11 from the first substrate.
Apply to one side. 4.4 grams of cleansing ingredient was obtained per finished article
The cleansing ingredients are extruded in a ratio such that The first substrate is 30% 15 denier
PET fiber, 35% 3 denier, with PET core and PE sheath
Component fiber and 35% 10 denier bicomponent fiber with identical core-sheath composition
Air having a basis weight of about 85 grams per square meter (gsm) containing a mixture of
It is a laid, bulky, low density cotton wadding. Contact the cleansing ingredient-containing layer
The second substrate is continuously fed over the first substrate on which it is placed. This second base material
Is the same as the first. The laminated web of Example 119, which is a third substrate web, is
The second substrate is contacted and continuously fed onto the second substrate web. Cross the web
And seal with a point pattern that includes a grid of 4 mm diameter seal points that are evenly spaced
The web is continuously fed into the ultrasonic sealing machine. Approximately 140 mm x 1 with rounded corners
The web is cut into individual articles that result in a 05 mm rectangle.       [0433]Example 205   Representative skin cleansing articles and skin conditioning
Manufacture   A representative cleansing article of Example 204 is prepared.   Separated by 20mm, 40mm, and 20mm from the width of the web,
, 4 mm wide, each forming a pair of parallel lines on each side of the web.
Of any of Examples 22-89 by continuously extruding through the tip of the coating.
By applying one or more conditioning components to one side of the first substrate.
Thus, a skin conditioning article is prepared. 3 grams per finished article
The cleansing ingredients are extruded in proportions to obtain minutes. The base material is 70% rayon
Spunlace blend of 30% PET fiber, styrene-butadiene adhesive
Approximately 70g
It has a basic mass of sm. A second, air-laid, bulky, low-density cot
Contacting the web with a first substrate on a surface that does not contain skin conditioning components
Then, it is continuously fed onto the first base material. Bottling is 30% 15 denier PE
Bicomponent with T-fiber, 35% 3 denier, with PET core and PE sheath
Bicon of dent fiber and 35% 10 denier with the same core-sheath composition
Containing a mixture of component fibers, basis weight of about 100 grams per square meter
With (gsm). A 4 mm diameter sheet that is evenly spaced across the web.
The web continuously on an ultrasonic sealing machine that seals with a dot pattern that includes a grid of
Send in. About 120mm x 160m with a total of about 51 sealing points per article
Cut the web into m rectangular, rounded individual articles.   Skin cleansing and skin conditioning products together in a single package
Be packaged.       [0434]Example 206   Representative skin cleansing using the cleansing ingredients of Example 11 by the following method
To prepare the article.   2g of cleansing ingredients in a 5cm x 8cm rough elliptical first substrate
Spread on top. The substrate is available from General Foam,
Polyether foam having a thickness of 320 mils. The laminated web of Example 117
A small piece of the second substrate is placed on top of the first substrate. Of the laminated web of Example 117
A second piece is placed under the first substrate. Straight, evenly spaced across the web
Use an ultrasonic sealing machine that seals with a point pattern including a grid of sealing points with a diameter of 4 mm
Seal the substrates together. It is a rectangle with rounded corners of about 140 mm x 105 mm.
Cut the web into individual articles according to       [0435]Example 207   A representative cleansing article is prepared by the following method.   Across the web, four lines of coating separated by 20 mm were used.
The cleansing ingredient of Example 11 was first extruded by continuously extruding through the tip.
Applied to one side of the substrate. 4.0g cleansing composition per finished article
The cleansing ingredients are extruded in proportions such that minutes are obtained. The first substrate is a polystar
-(Polystar) AB1 from Libeltex NV (Belgium)
Airlaid, bulky, low density, resin containing available polyester fibers
It is a stuffed cotton that is combined with. Base material is about 80 grams per square meter (gsm)
Have quantity. A first substrate is placed over the first substrate that contacts and places the cleansing ingredient-containing layer.
2 base materials are continuously sent out. This second substrate is the laminated web of Example 120.
is there. A third substrate is continuously underneath the first substrate web. This third base also
, The laminated web of Example 120. Straight, evenly spaced across the web
Connect to an ultrasonic sealing machine that seals with a point pattern that includes a grid of sealing points with a diameter of 4 mm.
Send web continuously. A piece with a rounded corner and a rectangle of about 140 mm x 105 mm
Cut the web into individual articles.       [0436]Example 208   A 300 mm x 400 mm laminated web piece of Example 118 or Example 122;
Wrapping the article of Example 142 to provide pediatric skin cleansing and
Prepare a drying kit.       [0437]Example 209   The laminated web of any one of Examples 117-124 was used in Examples 106-115.
A typical antibacterial hard surface cleaner is saturated by the indicated cleaning ingredients.
A wet article, for example, a moist wipe article having antimicrobial properties is prepared. Preferably
Webs at about 3.2 mounting elements to form a pre-moistened wipe.
Put the ingredients on top. The resulting wiped article is then wrapped individually or in multiple wraps.
You may wear it.       [0438]Example 210   Examples 117-12 with any of the antimicrobial cleaning ingredients of Examples 21 and 22
By saturating any one of the four laminated webs, a typical antibacterial hard surface
Prepare a moist wipe for aging. Then, the obtained wiping article
It may be packaged individually or in multiple packages.       [0439]Example 211   A representative conditioning article is made by the following method.   Form dots, each containing about 0.05 g of component and a diameter of about 3 mm
As described in Examples 22-89 by extruding through the tip of an extrusion jet.
Of any of the conditioning components of Examples 117-124
Apply in a lag. Extrude ingredients at a rate of 1.1 grams of ingredient per finished article
You A second web of air-laid, bulky, low-density cotton is applied to the skin
Contacting the first base material on the surface not containing the conditioning component and on the first base material
Send in continuously. Bottling is 10% 15 denier PET fiber, 50% 3 denier
Neel polyethylene terephthalate (PET) core and polyethylene (PE) sheet
Of the same core-sheath composition of 40% 10 denier
Contains a mixture of fiber densities and has a basis weight of about 80 grams per square meter (gsm)
To do. Includes a grid of 4 mm diameter seal points evenly spaced across the web
The web is continuously fed to an ultrasonic sealing machine that seals in a dot pattern. Per item
Reaching a rectangle of about 120 mm x 90 mm with a total of about 51 sealing points,
Cut the web into individual articles with rounded corners. The article is a small area of skin, for example,
It is convenient to apply to the face, elbows, neck and / or feet.       [0440]Example 212   A typical floor cleaning article is manufactured in the following manner.   A laminated web of any one of Examples 117-124 was applied to a 100 x 130 mm pad.
Cut into a pad. A poly-barrier provided by Clopay on the back of the sheet
Install on the side. 2x25mm wide mounting stripes along the length of the pad
And attach the pad to the tool. Swiffer (Swiffer) for dry cleaning
100 x 130 mm tip of mop (including rotary head that causes wiping action)
Cut to the size of. Glue a male Velcro piece to the tip of this mop
A drug stop provides a means for attaching the pad. Examples 92-105
Soak one of the cleaning ingredients into the tip of the mop. Used by consumers
Wrap the tip of the mop so that the ingredients do not leak before using.       [0441]Example 213   A typical floor polish / cleaning article is manufactured in the following manner.   A laminated web of any one of Examples 117-124 was applied to a 100 x 130 mm pad.
Cut into a pad. A poly-barrier provided by Clopay on the back of the sheet
Install on the side. 2x25mm wide mounting stripes along the length of the pad
And attach the pad to the tool. Swiffer (registered trademark
) The tip of the mop for dry cleaning is 100X130mm (rotating
(Including the pad). At the tip of this mop, a male Velcro (Velc
ro) glue the pieces together and provide a means for attaching the pads. Pad
Before attaching to the tip of the mop, include a 1: 1 mass ratio mixture of mineral and wax.
The polishing cleaning component which it has is attached to a pad. Once you put the ingredients on the pad,
The product obtained is packaged until just before use.       [0442]Example 214   A typical polishing / cleaning article is manufactured in the following manner.   A laminated web of any one of Examples 117-124 was applied to a 100 x 130 mm pad.
Cut into a pad. Polish cleaning containing a 1: 1 weight ratio mixture of minerals and wax
Put the ingredients on the pad. Once you put the ingredients on the pad, get it until just before use
The packaged goods.       [0443]Example 215   A representative fabric cleaning / refresh article is made in the following manner.   A laminated web of any one of Examples 117-124 was applied to a 100 x 130 mm pad.
Cut into a pad. A sheet is loaded with any one of the cleaning components of Examples AE.
To wear. Once the components are attached to the sheet, the product obtained is packaged until just before use
To do. [Brief description of drawings]     FIG. 1 is a perspective view of one embodiment of the laminated web of the present invention.     2 is a cross-sectional view of a portion of the laminated web shown in FIG.     FIG. 3 is an enlarged detail view of one of the bonding sites of the laminated web of the present invention.     FIG. 4 is a top plan view of another embodiment of the laminated web of the present invention.     5 is a cross-sectional view of a portion of the laminated web shown in FIG.     FIG. 6 is a top plan view of another embodiment of the laminated web of the present invention.     7 is a cross-sectional view of a portion of the laminated web shown in FIG.     FIG. 8 is a photomicrograph of one embodiment of the laminated web of the present invention.     FIG. 9 is a schematic diagram of a method for producing a laminated web of the present invention.     FIG. 10 is a perspective view of a fusion bonded calender method device.     FIG. 11 is a schematic diagram of a pattern related to a protruding portion of a roll of a calendar method.
is there.     FIG. 12 shows a device for stretching a laminate of the invention and forming holes therein.
It is a perspective view.     13 is a cross-sectional view of the mating portion of the device shown in FIG.     FIG. 14 illustrates the invention in a direction transverse to the machine to form holes therein.
FIG. 6 is a perspective view of another device for stretching a stack.     FIG. 15: Stretch the laminate of the invention in the machine direction to form holes therein.
FIG. 6 is a perspective view of another alternative device for tensioning.     FIG. 16: Direction and machine direction intersecting the machine to form holes therein
FIG. 6 is a perspective view of an apparatus for stretching a laminate of the present invention in both directions.     FIG. 17: Use with components that can be made from the laminated web stock of the present invention.
FIG. 3 is a perspective view of a discarded absorbent article.

─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. ⁷ Identification code FI theme code (reference) A61K 7/00 A61K 7/42 7/50 A41B 13/02 E 7/32 S 7/42 B 7/50 (31) Priority claim number 09 / 584,676 (32) Priority date May 31, 2000 (May 31, 2000) (33) Priority claiming country United States (US) (81) Designated country EP (AT , BE, CH, CY, DE, DK, ES, FI, FR, GB, GR, IE, IT, LU, MC, NL, PT, SE, TR), OA (BF, BJ, CF, CG, CI) , CM, GA, GN, GW, ML, MR, NE, SN, TD, TG), AP (GH, GM, KE, LS, MW, MZ, SD, SL, SZ, TZ, UG, ZW), EA (AM, AZ, BY, KG, K , MD, RU, TJ, TM), AE, AG, AL, AM, AT, AU, AZ, BA, BB, BG, BR, BY, BZ, CA, CH, CN, CR, CU, CZ, DE. , DK, DM, DZ, EE, ES, FI, GB, GD, GE, GH, GM, HR, HU, ID, IL, IN, IS, JP, KE, KG, KP, KR, KZ, LC, LK, LR, LS, LT, LU, LV, MA, MD, MG, MK, MN, MW, MX, MZ, NO, NZ, PL, PT, RO, RU, SD, SE, SG, SI, SK , SL, TJ, TM, TR, TT, TZ, UA, UG, UZ, VN, YU, ZA, ZW (72) Inventor Die, Deborah Loose England, Middlesex, Tida Abur 18, 4 Arex, Staines , Lark, Avenue 37 (72) Inventor Carlo , John Joseph United States of America Ohio, Cincinnati, Stable Watch, Court 11604 (72) Inventor Benson, Douglas Helin United States Indiana, West, Harrison, Jamison, Road 206 (72) Inventor Struv, John Bryan Hamilton, United States of America Ohio , Jennifer, Drive 4208 F-term (reference) 3B029 BA05 BA18 BB03 BB06 BF03 BF04 4C083 AA082 AA122 AB032 AB172 AB242 AB332 AB372 AB412 AC012 AC122 AC152 AC172 AC242 AC302 AC312 AC342 AC742 AC472 AC04 AC01 AC342 AC642 AC352 AC372 AC402 AC422 AC432 AC04 AC01 AC342 AC642 AC652 AC372 AC402 AC422 AC432 AC442 AC01 AC472 AC642 AC042 AD162 AD172 AD212 AD252 AD261 AD412 AD432 AD492 AD532 AD572 AD642 AD662 CC02 CC11 CC17 CC19 CC24 DD12 EE14 EE17 EE18 4C098 AA09 DD05 DD10 DD13 DD25 DD26 DD28

Claims (10)

[Claims] 1. A disposable article, the article comprising: a) a laminated web having a plurality of holes, 1) a first extensible web having a first elongation to break; 2). A second extensible web that is connected to the first extensible web at a plurality of bonding sites, the second extensible web having an elongation to a second break; and 3) the first And a third web material disposed between the second web and
A third web material having a third elongation to break less than the first or second elongation to break; a laminated web comprising: b) disposed adjacent to the laminated web. An article, comprising: a beneficial ingredient; 2. The article of claim 1, wherein the article is selected from the group consisting of personal care articles, household care articles, automotive maintenance articles, and pet care articles. 3. Article according to any one of the preceding claims, wherein the laminated webs are connected by a bond in the absence of an adhesive. 4. An article according to any one of the preceding claims, wherein the bonding sites are selected from the group consisting of discontinuous thermal bonding and discontinuous ultrasonic bonding. 5. The article of any one of the preceding claims, wherein the first and / or second extensible web comprises a material selected from the group consisting of nonwovens, polymeric films, and combinations thereof. 6. An article according to any one of the preceding claims wherein the first and second extensible webs are the same. 7. The article of any one of the preceding claims, wherein the third web comprises a material selected from the group consisting of cellulosic tissue paper, metal foil, polymer film, foam, and combinations thereof. . 8. An article according to any one of the preceding claims, wherein the beneficial ingredient is selected from the group consisting of cleansing ingredients, conditioning ingredients, cosmetic ingredients, cleaning ingredients, polish / cleaning ingredients, and combinations thereof. 9. The beneficial component is a vitamin compound, a skin treatment agent, an anti-acne agent, an anti-wrinkle agent, an anti-skin atrophy agent, an anti-inflammatory agent, a local anesthetic, an artificial tanning agent, and an accelerator,
A cosmetic ingredient comprising an active substance selected from the group consisting of antibacterial agents, antifungal agents, sunscreen agents, antioxidants, skin exfoliants, deodorants / antiperspirants, and combinations thereof. Item 1. 10. A disposable article, the article comprising: a) a laminated web having a plurality of holes, 1) first and second stretches connected at a plurality of discontinuous bond sites. A laminated web comprising: a) a web; 2) a third material disposed between the first and second nonwoven webs; and b) a beneficial ingredient disposed adjacent to the laminated web. Wherein the first and second extensible webs are in fluid communication through the pores and at least one selected from the group consisting of basis weight, fiber orientation, thickness, and density. An article having an identifiable area that is distinguished by one characteristic.