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JP2003311544A - Electrode wire for wire electric discharge machining - Google Patents

Electrode wire for wire electric discharge machining

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Publication number
JP2003311544A
JP2003311544A JP2002128069A JP2002128069A JP2003311544A JP 2003311544 A JP2003311544 A JP 2003311544A JP 2002128069 A JP2002128069 A JP 2002128069A JP 2002128069 A JP2002128069 A JP 2002128069A JP 2003311544 A JP2003311544 A JP 2003311544A
Authority
JP
Japan
Prior art keywords
wire
electric discharge
discharge machining
electrode wire
electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2002128069A
Other languages
Japanese (ja)
Inventor
Toshiyuki Yamauchi
俊之 山内
Kenichi Kono
研一 河野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP2002128069A priority Critical patent/JP2003311544A/en
Publication of JP2003311544A publication Critical patent/JP2003311544A/en
Pending legal-status Critical Current

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  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
  • Metal Extraction Processes (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide an electric wire designed to suppress the increase in the number of vibrations during electric discharge machining which is an inhibiting factor for stability of electric discharge machining and also designed to eliminate disconnection and improve electric discharge machining performance. <P>SOLUTION: An electrode wire 1 comprises a core material 2 made of a copper line and a plating layer which is formed around the face of the core material 2 and composed of double layers of a lower layer 3 of brass plating and an upper layer 4 of zinc plating. The line diameter d of the electrode wire 1 is 0.02-0.20 mm and tensile strength Ts is (-2500d+3000) to (-2500d+4500) MPa. <P>COPYRIGHT: (C)2004,JPO

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、ワイヤ放電加工の
工具電極として用いる電極線であって、特に精密機器を
構成する部品(以下、被加工品という)の微小・高精度
加工に適した電極線に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an electrode wire used as a tool electrode for wire electric discharge machining, which is particularly suitable for minute and high-precision machining of parts constituting precision equipment (hereinafter referred to as "workpiece"). Regarding the line.

【0002】[0002]

【従来の技術】ワイヤ放電加工は、細いワイヤを電極線
として、加工液(純度の高い水)を放電部位に供給し、
電極線と被加工物(金型やダイス等)に電圧をかけ、電
極線に張力をかけた状態で連続走行させながら、被加工
物と電極線間で加工液中においてパルス状の放電を繰り
返し発生させ、この放電エネルギにより被加工物を加工
するものである。上記放電は、溶融・爆発・飛散・冷却
・スラッジ除去の工程で構成されており、電極線と被加
工物が連続して接近することにより上記の放電加工が繰
り返し実行され、被加工物を所定の形状に加工するもの
である。
2. Description of the Related Art Wire electric discharge machining uses a thin wire as an electrode wire to supply a machining liquid (highly pure water) to an electric discharge site.
Applying a voltage to the electrode wire and the work piece (mold, die, etc.) and continuously running with tension applied to the electrode wire, while repeating pulsed discharge in the working fluid between the work piece and the electrode wire. It is generated and the workpiece is processed by this discharge energy. The electric discharge consists of the steps of melting, explosion, scattering, cooling, and sludge removal.When the electrode wire and the work piece approach each other continuously, the above electric discharge machining is repeatedly executed, and the work piece It is processed into the shape of.

【0003】近年、精密機器はコンパクト化の傾向にあ
り、被加工品の寸法・形状の更なる微小化・精密化の必
要性が高まっている。これに伴って、放電加工精度(表
面粗度及び寸法精度)をより一層向上することが要求さ
れている。
In recent years, precision equipment tends to be compact, and there is an increasing need for further miniaturization and refinement of the size and shape of the work piece. Along with this, it is required to further improve the electric discharge machining accuracy (surface roughness and dimensional accuracy).

【0004】寸法・形状が微小な被加工品を加工するに
は、電極線の線径をできるだけ小さくする必要がある。
また、放電加工精度には、放電加工時の爆発によって発
生する振動が大きく影響するから、電極線には高い張力
をかける必要がある。よって、加工精度の高い微小な被
加工物を放電加工する場合、より細くて高い引張強さを
有する電極線が要求される。
In order to process a work piece having a very small size and shape, it is necessary to make the wire diameter of the electrode wire as small as possible.
Further, since the vibration generated by the explosion during electric discharge machining has a great influence on the accuracy of electric discharge machining, it is necessary to apply a high tension to the electrode wire. Therefore, in the case of electric discharge machining of a minute work piece having a high working accuracy, a thinner electrode wire having a high tensile strength is required.

【0005】従来、微細・精密加工用の電極線として、
タングステンやモリブデン等の重金属線が一般に用いら
れている。これら重金属線は、加工時に付加される張力
に耐え得る引張強さを有している。しかし、材料自体が
高価で、しかも伸線加工が困難で細小化の加工コストが
かかり、また放電加工性能が黄銅線に比較すると劣ると
いう問題があった。
Conventionally, as an electrode wire for fine / precision machining,
Heavy metal wires such as tungsten and molybdenum are generally used. These heavy metal wires have tensile strength capable of withstanding the tension applied during processing. However, there are problems that the material itself is expensive, the wire drawing process is difficult, the processing cost for miniaturization is high, and the electric discharge machining performance is inferior to that of the brass wire.

【0006】そこで、重金属線に代わる電極線として、
芯材を鋼線としたものが各種提案されている(特開20
00−107943号公報、特開2000−19802
7号公報等)。鋼線は、伸線加工硬化によって引張強さ
を上げることができる。
Then, as an electrode wire replacing the heavy metal wire,
Various proposals have been made for a steel wire as the core material (Japanese Patent Application Laid-Open No. 20-1999)
No. 00-107943, Japanese Patent Laid-Open No. 2000-19802.
No. 7, etc.). The tensile strength of steel wire can be increased by wire drawing work hardening.

【0007】上記特開2000−107943号公報記
載の発明は、線径φ0.03〜0.1mmの高炭素のピ
アノ線の表面に順次被覆する銅の厚みの上限と亜鉛の厚
みの範囲を特定することにより、重金属線に代えて使用
可能な高い引張強さを有し、かつ加工速度等の放電加工
性能において同等以上の性能を有する廉価な電極線を提
供しようとしたものである。そして、この公報の段落
[0016]には、引張強さについて、「外径がφ0.
05mmの電極線・・・引張強さは2170N/mm2
であった。」と記載されている。
The invention described in Japanese Patent Laid-Open No. 2000-107943 specifies the upper limit of the thickness of copper and the range of the thickness of zinc that are sequentially coated on the surface of a high carbon piano wire having a wire diameter of 0.03 to 0.1 mm. By doing so, it is intended to provide an inexpensive electrode wire which has a high tensile strength that can be used in place of the heavy metal wire and has a performance equal to or higher than the electric discharge machining performance such as machining speed. And, in paragraph [0016] of this publication, regarding the tensile strength, "the outer diameter is φ0.
05mm electrode wire ・ ・ ・ Tensile strength is 2170N / mm 2
Met. It is described as ".

【0008】また、特開2000−198027号公報
記載の発明は、線径0.03〜0.3mmで、抗張力が
150〜250kgf/mm2である鋼線に、真鍮の被
膜を形成した電極線を前提技術として、真鍮の全体に占
める割合及び銅組成を特定し、かつ鋼線の炭素成分を特
定することにより、加工速度(電導性)及び引張強度を
優れたものにし、芯線の強度が高く外側の真鍮の厚みが
厚い電極線を提供しようとしたものである。そして、こ
の公報の段落[0012]には、「電極線の伸線加工に
よる抗張力は、・・・400〜500kgf/mm2
上限であり、」と記載されている。
The invention described in Japanese Patent Laid-Open No. 2000-198027 discloses an electrode wire in which a brass coating is formed on a steel wire having a wire diameter of 0.03 to 0.3 mm and a tensile strength of 150 to 250 kgf / mm 2. As a prerequisite technology, the processing rate (electrical conductivity) and tensile strength are made excellent by specifying the proportion of copper in the whole brass and the copper composition, and by specifying the carbon component of the steel wire, and the strength of the core wire is high. It is intended to provide an electrode wire having a thick outer brass. In paragraph [0012] of this publication, "the upper limit of the tensile strength of the wire drawing process for the electrode wire is 400 to 500 kgf / mm 2 ," is described.

【0009】[0009]

【発明が解決しようとする課題】しかし、上記公報に記
載されたような、芯材が鋼線で、線径が小さく高い引張
強さを有する電極線を用いて放電加工を行うと、電極線
の振動数が大きくなったり、時に断線することがあっ
た。電極線の振動数増大や断線は、被加工品の寸法精度
及び切断面の表面粗度に悪影響を及ぼす。
However, when electric discharge machining is performed using an electrode wire having a steel wire as a core and having a small wire diameter and high tensile strength as described in the above publication, the electrode wire is There was a case where the frequency of the machine became large and sometimes the wire was broken. The increase in the frequency of the electrode wire and the disconnection adversely affect the dimensional accuracy of the work piece and the surface roughness of the cut surface.

【0010】そこで、本発明者は、放電加工時の振動数
増大原因および断線原因について鋭意研究を行った結
果、放電加工時に付与される張力を考慮して、引張強さ
の領域を最適な範囲に調整すると、振動数を小さく抑制
することができ、かつ靭性の低下に起因する断線を解消
することを知見して、本発明を完成するに至った。
Therefore, as a result of intensive studies on the cause of the increase in the frequency of electric discharge and the cause of wire breakage, the present inventor considers the tension applied during electric discharge machining and determines the range of the tensile strength in the optimum range. The inventors have found that the frequency can be suppressed to a low level by adjusting to, and the disconnection due to the decrease in toughness can be eliminated, and the present invention has been completed.

【0011】よって、本発明は、放電加工安定性の阻害
要因である、放電加工時の振動数の増加を抑制し、かつ
断線を解消し、放電加工性能を向上した電極線を提供す
ることを課題とする。
Therefore, the present invention provides an electrode wire that suppresses an increase in the frequency of electric discharge machining, which is a factor that hinders the stability of electric discharge machining, eliminates disconnection, and improves electric discharge machining performance. It is an issue.

【0012】[0012]

【課題を解決するための手段】本発明のワイヤ放電加工
用ワイヤは、線径が0.02〜0.20mmである鋼線
を芯材とした電極線であり、引張強さTsが次式を満足
し、かつ芯線の表面に真鍮メッキの下層と亜鉛メッキの
上層とからなる二層構造のメッキ層を備えたことを特徴
とする。 [数1] (−2500d+3000)MPa≦Ts≦(−250
0d+4500)MPa Ts:引張強さ(MPa) d :電極線径(m
m)
A wire for electric discharge machining according to the present invention is an electrode wire having a steel wire having a wire diameter of 0.02 to 0.20 mm as a core material, and a tensile strength Ts of the following formula. In addition, the core wire is provided with a plating layer having a two-layer structure consisting of a brass-plated lower layer and a zinc-plated upper layer. [Equation 1] (−2500d + 3000) MPa ≦ Ts ≦ (−250
0d + 4500) MPa Ts: Tensile strength (MPa) d: Electrode wire diameter (m
m)

【0013】本発明の電極線は、芯材が鋼線で、かつ上
記の如く引張強さを特定することで、放電加工安定性の
阻害要因である、放電加工時の振動数の増大および断線
を解消し、放電加工性能を向上することができる。
In the electrode wire of the present invention, the core material is a steel wire, and the tensile strength is specified as described above, so that the increase in the frequency and the disconnection of the frequency during the electric discharge machining, which are the factors that hinder the stability of the electric discharge machining. Can be eliminated, and the electric discharge machining performance can be improved.

【0014】ところで、上記構成において、鋼線の線径
を0.02〜0.20mmとしたのは、0.02mm未
満だと、引張強さが不足し、被加工品の寸法精度および
切断面の表面粗度の向上が得られないからで、0.20
mmを越えると、線径が太すぎて寸法・形状が微小な場
合の精密加工部品を高精度に加工できなくなるからであ
る。より放電加工性能を向上させるためには、鋼線の線
径は、0.02〜0.10がより好ましい範囲である。
By the way, in the above construction, the reason why the wire diameter of the steel wire is 0.02 to 0.20 mm is that if it is less than 0.02 mm, the tensile strength becomes insufficient, and the dimensional accuracy and the cut surface of the workpiece are reduced. 0.20 because the improvement of the surface roughness of
This is because if the diameter exceeds mm, the precision-machined component cannot be processed with high precision when the wire diameter is too large and the size and shape are minute. In order to further improve the electric discharge machining performance, the wire diameter of the steel wire is more preferably 0.02 to 0.10.

【0015】また、引張強さTsを、(−2500d+
3000)〜(−2500d+4500)MPaとした
のは、(−2500d+3000)MPa未満では、引
張強さが不足し、被加工品の寸法精度および切断面の表
面粗度の向上が得られないからで、(−2500d+4
500)MPaを越えると、引張強さが高くなりすぎ、
靭性が低下して放電加工時の断線を誘発するとともに、
振動数が増加して被加工物の表面粗度及び加工精度が低
下するからである。
Further, the tensile strength Ts is (-2500d +
3000) to (-2500d + 4500) MPa is used because, if it is less than (-2500d + 3000) MPa, the tensile strength is insufficient and the dimensional accuracy of the workpiece and the surface roughness of the cut surface cannot be improved. (-2500d + 4
If it exceeds 500) MPa, the tensile strength becomes too high,
The toughness deteriorates and induces wire breakage during electrical discharge machining.
This is because the frequency increases and the surface roughness and processing accuracy of the work piece deteriorate.

【0016】本発明の電極線に使用する鋼線としては、
JIS規格でいう硬鋼線やピアノ線等がある。また、そ
の炭素含有量としては、電極線の引張強さを考慮する
と、0.5重量%以上は必要であるが、伸線加工性から
1.2%までが望ましい。
As the steel wire used for the electrode wire of the present invention,
There are hard steel wires, piano wires, etc., as defined in JIS. Further, considering the tensile strength of the electrode wire, the carbon content needs to be 0.5% by weight or more, but is preferably 1.2% in view of wire drawing workability.

【0017】上記電極線の表面には、真鍮メッキの下層
と亜鉛メッキの上層とからなる二層構造のメッキ層を備
える。真鍮メッキは銅を含有するから電極線の電気伝導
性を向上させ、また亜鉛を含有するのでその上層に設け
る亜鉛メッキ層との親和性に優れ、真鍮メッキと亜鉛め
っきとの固着力を高める。また、亜鉛メッキ層は放電加
工時に発生する熱で亜鉛が昇華し、この昇華による吸熱
で加工部位の温度上昇を抑えることができる。
The surface of the electrode wire is provided with a plating layer having a two-layer structure consisting of a brass-plated lower layer and a zinc-plated upper layer. Since brass plating contains copper, it improves the electric conductivity of the electrode wire, and since it contains zinc, it has excellent affinity with the zinc plating layer provided on top of it, and enhances the bond strength between the brass plating and zinc plating. Further, in the galvanized layer, zinc is sublimated by the heat generated at the time of electric discharge machining, and the heat absorption due to the sublimation can suppress the temperature rise of the processed part.

【0018】[0018]

【発明の実施の形態】図1に示すように、本発明の電極
線1は、炭素含有量0.79〜0.86重量%の硬鋼線
材あるいは0.80〜0.85重量%のピアノ線材を芯
材2とし、芯材2の表面に真鍮メッキの下層3と亜鉛メ
ッキの上層4とからなる二層構造のメッキ層を備えてな
る。そして、この電極線1の線径は、0.02〜0.2
0mmで、引張強さTsは、(−2500d+300
0)〜(−2500d+4500)MPaである。
DESCRIPTION OF THE PREFERRED EMBODIMENTS As shown in FIG. 1, an electrode wire 1 of the present invention is a hard steel wire having a carbon content of 0.79 to 0.86% by weight or a piano wire having a carbon content of 0.80 to 0.85% by weight. The wire is a core material 2, and the surface of the core material 2 is provided with a plating layer having a two-layer structure including a brass-plated lower layer 3 and a zinc-plated upper layer 4. The diameter of the electrode wire 1 is 0.02 to 0.2.
At 0 mm, the tensile strength Ts is (-2500d + 300
0) to (-2500d + 4500) MPa.

【0019】そして、本発明の電極線は、一般的な線径
5.5mmの原線をパテンチング、伸線加工を繰り返し
て所望の線径に仕上げ、この線材に、銅メッキに続いて
亜鉛メッキを施した後、熱拡散処理にて真鍮メッキと
し、この上層に亜鉛メッキを施して得ることができる。
上記製造工程におけるパテンチング、伸線加工で、0.
1〜1.0mm程度の線径に仕上げて、この線材に上記
と同様に真鍮メッキを施した後、伸線加工して所望の線
径に仕上げ、これに亜鉛メッキを施すようにしてもよ
い。真鍮メッキは伸線加工性を向上させるから高速伸線
加工を可能にする。真鍮メッキを施すときの線径は、最
終線径と引張強さから決定される。
In the electrode wire of the present invention, an ordinary wire having a diameter of 5.5 mm is subjected to patenting and drawing to obtain a desired wire diameter, and this wire is plated with copper and then zinc. It can be obtained by applying brass plating after heat treatment, and then zinc plating the upper layer.
With the patenting and wire drawing in the above manufacturing process,
The wire may be finished to a wire diameter of about 1 to 1.0 mm, brass-plated on this wire in the same manner as above, and then drawn to a desired wire diameter, which may be galvanized. . Since brass plating improves wire drawing workability, it enables high speed wire drawing. The wire diameter for brass plating is determined from the final wire diameter and tensile strength.

【0020】最終線径は0.02〜0.20mmで各種
加工物や加工形状に応じて決定される。また、引張強さ
は、原線のC量や最終パテンチング処理を施すときの線
径や温度、あるいは最終伸線工程での減面率等で調整す
ることができる。
The final wire diameter is 0.02 to 0.20 mm and is determined according to various processed products and processed shapes. Further, the tensile strength can be adjusted by the C content of the original wire, the wire diameter and temperature when the final patenting treatment is applied, the area reduction rate in the final wire drawing step, and the like.

【0021】[0021]

【実施例】線径5.5mmの炭素含有量0.82重量%
のピアノ線材をパテンチング、伸線加工を繰り返して、
線径0.1〜1.0mmの中間線材を製造し、この中間
線材に銅・亜鉛メッキを施した後、熱拡散して真鍮メッ
キとし、これを再度伸線加工して各種線径を有する電極
線材を得た。次に、この電極線材に亜鉛メッキを施して
各種線径の電極線を製造した。そして、これら電極線を
用いて、超硬に貫通孔を加工して、その寸法精度及び表
面粗度を比較した。上記銅メッキ、亜鉛メッキは電気メ
ッキで、上記仕上がった電極線の真鍮メッキ層及び亜鉛
メッキ層の厚みは、それぞれ4.5μm、2.5μmと
した。その結果を図2のグラフに示す。
[Example] Carbon content of wire diameter 5.5 mm 0.82% by weight
Repeatedly patenting and wire drawing the piano wire of
After manufacturing an intermediate wire with a wire diameter of 0.1 to 1.0 mm, applying copper / zinc plating to this intermediate wire, heat-spreading it to brass plating, and drawing it again to have various wire diameters. An electrode wire rod was obtained. Next, this electrode wire material was galvanized to manufacture electrode wires of various wire diameters. Then, using these electrode wires, a through hole was processed into a super hard material, and the dimensional accuracy and surface roughness were compared. The copper plating and zinc plating were electroplating, and the thicknesses of the brass plating layer and the zinc plating layer of the finished electrode wire were 4.5 μm and 2.5 μm, respectively. The results are shown in the graph of FIG.

【0022】図中の●は被加工物である超硬の寸法精度
および表面粗度が従来程度あるいはそれ以下のもの、×
は放電加工時に断線が発生したもので、○は全ての点で
問題がなかったものである。図2に示すグラフから、引
張強さが(−2500d+3000)〜(−2500d
+4500)MPaの範囲であれば、断線が発生せず、
被加工物の寸法精度並びに表面粗度が向上することがわ
かる。
In the figure, ● indicates that the dimensional accuracy and surface roughness of the workpiece, which is a carbide, are the same as or lower than conventional ones, ×
Indicates that disconnection occurred during electric discharge machining, and ○ indicates that there were no problems in all points. From the graph shown in FIG. 2, the tensile strength is (-2500d + 3000) to (-2500d).
Within the range of +4500 MPa, no wire breakage occurs,
It can be seen that the dimensional accuracy and surface roughness of the workpiece are improved.

【0023】[0023]

【発明の効果】本発明の電極線は、高い導電性および放
電安定性を有することは勿論のこと、引張強さが高いか
ら、放電加工装置で高い張力を付与することができ、特
に精密機器を構成する部品の微小・高精度加工を可能に
する。また、放電加工時の断線を解消し、しかも電極線
の振動をより小さく抑えることができるから、部品の寸
法精度、および切断面の表面粗度を著しく向上させるこ
とができる。
EFFECT OF THE INVENTION The electrode wire of the present invention has high conductivity and discharge stability, and also has high tensile strength, so that it can be applied with high tension by an electric discharge machine, and particularly precision equipment. It enables minute and high-precision machining of the parts that make up. Further, since the disconnection during the electric discharge machining can be eliminated and the vibration of the electrode wire can be further suppressed, the dimensional accuracy of the component and the surface roughness of the cut surface can be remarkably improved.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の電極線の実施例を示す断面図である。FIG. 1 is a cross-sectional view showing an embodiment of an electrode wire of the present invention.

【図2】各種線径における引張強度とその評価を表すグ
ラフである。
FIG. 2 is a graph showing tensile strength at various wire diameters and evaluation thereof.

【符号の説明】[Explanation of symbols]

1 電極線 2 芯材 3 真鍮メッキ層 4 亜鉛メッキ層 1 electrode wire 2 core material 3 Brass plating layer 4 Galvanized layer

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 線径が0.02〜0.20mmである鋼
線を芯材とした電極線であり、引張強さTsが次式を満
足し、かつ芯線の表面に真鍮メッキの下層と亜鉛メッキ
の上層とからなる二層構造のメッキ層を備えたことを特
徴とするワイヤ放電加工用電極線。 [数1] (−2500d+3000)MPa≦Ts≦(−250
0d+4500)MPa Ts:引張強さ(MPa) d:電極線径(mm)
1. An electrode wire comprising a steel wire having a wire diameter of 0.02 to 0.20 mm as a core material, a tensile strength Ts satisfying the following equation, and a brass-plated lower layer on the surface of the core wire. An electrode wire for wire electric discharge machining, comprising a plating layer having a two-layer structure including an upper layer of zinc plating. [Equation 1] (−2500d + 3000) MPa ≦ Ts ≦ (−250
0d + 4500) MPa Ts: Tensile strength (MPa) d: Electrode wire diameter (mm)
【請求項2】線径が0.02〜0.10mmである請求
項1に記載のワイヤ放電加工用電極線。
2. The electrode wire for wire electric discharge machining according to claim 1, wherein the wire diameter is 0.02 to 0.10 mm.
JP2002128069A 2002-04-30 2002-04-30 Electrode wire for wire electric discharge machining Pending JP2003311544A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2002128069A JP2003311544A (en) 2002-04-30 2002-04-30 Electrode wire for wire electric discharge machining

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2002128069A JP2003311544A (en) 2002-04-30 2002-04-30 Electrode wire for wire electric discharge machining

Publications (1)

Publication Number Publication Date
JP2003311544A true JP2003311544A (en) 2003-11-05

Family

ID=29541941

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2002128069A Pending JP2003311544A (en) 2002-04-30 2002-04-30 Electrode wire for wire electric discharge machining

Country Status (1)

Country Link
JP (1) JP2003311544A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019004392A1 (en) 2017-06-30 2019-01-03 株式会社ブリヂストン Steel cord for rubber component reinforcement and production method therefor
WO2020054673A1 (en) 2018-09-11 2020-03-19 株式会社ブリヂストン Steel cord for reinforcing rubber article
CN111215856A (en) * 2020-02-22 2020-06-02 杭州富阳裕红线材制品设备有限公司 Steel core wire electrode wire plated with copper and then plated with zinc and production process
CN112222552A (en) * 2020-09-07 2021-01-15 宁波康强微电子技术有限公司 Gamma electrode wire and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019004392A1 (en) 2017-06-30 2019-01-03 株式会社ブリヂストン Steel cord for rubber component reinforcement and production method therefor
WO2020054673A1 (en) 2018-09-11 2020-03-19 株式会社ブリヂストン Steel cord for reinforcing rubber article
US11685191B2 (en) 2018-09-11 2023-06-27 Bridgestone Corporation Steel cord for reinforcing rubber article
CN111215856A (en) * 2020-02-22 2020-06-02 杭州富阳裕红线材制品设备有限公司 Steel core wire electrode wire plated with copper and then plated with zinc and production process
CN112222552A (en) * 2020-09-07 2021-01-15 宁波康强微电子技术有限公司 Gamma electrode wire and preparation method thereof
CN112222552B (en) * 2020-09-07 2022-08-26 宁波康强微电子技术有限公司 Gamma electrode wire and preparation method thereof

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