JP2003119110A - Makeup cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a makeup cosmetic compounded with a non-aqueous polymer dispersion, good at touch feeling in use. SOLUTION: This makeup cosmetic comprises a non-aqueous polymer dispersion with a polymer dispersed in a volatile silicone and an aqueous polymer emulsion.

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to makeup cosmetics. More specifically, the present invention relates to a makeup cosmetic containing a non-aqueous polymer dispersion in which the feel during application is further improved.

[0002]

2. Description of the Related Art Conventionally, makeup cosmetics have been classified according to their compositional classification into emulsion type, film type, oil type,
Oily film type and non-aqueous polymer dispersion type are known.

Although many improvements have been made in terms of usability, these makeup cosmetics have sufficient odor during application, gloss after application, water resistance, oil resistance, adhesion, and makeup lasting. The satisfactory ones have not been developed so far and have had some drawbacks.

Among these drawbacks, many improvements have been made, especially to improve makeup lasting. For example, in JP-A-5-178722, an oily solid cosmetic (oil-based makeup cosmetic, lipstick, foundation, eye, etc.) containing one or more polyoxyalkylene-modified organopolysiloxanes and excellent in makeup lasting is provided. shadow),
Japanese Unexamined Patent Publication No. 6-199630 discloses an anti-deterioration cosmetic composition containing a volatile solvent, a silicone resin, a wax, a powder, and an oil component (makeup cosmetic composition applied to the lips and skin), Japanese Unexamined Patent Publication No. 6-298623. JP-A-7-17831 discloses a lip care cosmetic composition containing a specific alkylmethylpolysiloxane and having excellent durability and abrasion resistance.
In JP-A No. 2003-242242, a nonionic surfactant obtained by addition polymerization of ethylene oxide, a liquid oil agent containing a perfluoroalkyl group, a liquid oil, a semisolid fat or solid fat, and an oily cosmetic excellent in makeup lasting containing a pigment (lipstick ), JP-A-7-336
JP-A No. 22-52 discloses a polyoxyalkylene-modified silicone, a liquid oil agent containing a perfluoroalkyl group, a liquid oil, a semisolid fat or solid fat, and an oily cosmetic excellent in makeup lasting (lipstick) containing a pigment. ing. Further, Japanese Patent Application Laid-Open No. 61-161211 discloses a makeup cosmetic composition containing an organic silicone resin and having excellent cosmetic durability, and Japanese Patent Application Laid-Open No. 9-124430 discloses a high molecular weight organic silicone resin and a volatile substance. Disclosed is a makeup cosmetic composition containing oil and having excellent makeup retention.

Further, Japanese Patent Publication No. 61-12884 discloses a cosmetic makeup containing a non-aqueous polymer dispersion prepared by dispersing a dispersion polymer in an organic medium in which the dispersion polymer is not dissolved, as a film-forming component. An excellent makeup cosmetic (eyeliner, mascara, eyebrow, nail enamel) is disclosed in JP-A-10-874.
JP-A No. 35-35 discloses a makeup cosmetic having a long-lasting makeup, in which a non-aqueous polymer dispersion in which a polymer is dispersed in volatile silicone is blended.

[0006]

However, these make-up cosmetics have makeup retention, water resistance, oil resistance,
Although it has a certain level of function, for example, especially in the case of a foundation, the feeling such as freshness at the time of application could not be sufficiently exhibited. In addition, it was not possible to exert a sufficient effect on the distortion of the foundation, floating, and runoff caused by sweat, sebum, or oil of other cosmetics.

The inventors of the present invention have conducted extensive studies in view of the above circumstances, and as a result, in a cosmetic containing a makeup, a foundation containing a non-aqueous polymer dispersion in which a polymer is dispersed in a volatile silicone, an aqueous polymer emulsion. It has been found that the addition of the compound (1) makes it possible to impart a favorable feeling of use that is not only fresh during application, but also has the effects of excellent makeup retention, water resistance, and oil resistance, and has completed the present invention.

On the other hand, makeup cosmetics include foundation, eyeliner, mascara, etc., but there are emulsion type and oil type in composition classification.
Among them, the emulsion type can be classified into an oil-in-water type cosmetic (hereinafter referred to as an O / W type cosmetic) and a water-in-oil type cosmetic (hereinafter referred to as a W / O type cosmetic). Since these emulsified cosmetics contain water in their components as compared with oily cosmetics, they give a refreshing feel when applied to the skin and further suppress the oily feel. In addition, many of them are liquid or cream-like in shape, and their performances are such that they spread well on the skin and it is easy to obtain a uniform finish without unevenness. In particular, W / O type cosmetics, compared to O / W emulsion cosmetics,
Since the oil phase is a continuous phase, it is highly resistant to microorganisms, leaving an oil film with low moisture permeability on the skin surface even during use, protecting the skin from dryness for a long time, and by water bath or water work, sweating etc. Re-emulsification does not occur even when contacted with water, and it has excellent properties such as less likely to cause makeup discoloration such as color unevenness and twisting. In addition, the oil-based type has a property that makeup is less likely to be damaged by an aqueous component such as sweat, but has poor sebum resistance, and has a greasy or sticky feeling as a feeling of use. However, it had a drawback that it became thick even when finished.

However, these makeup cosmetics do not have sufficient cosmetic durability even under hot and humid conditions in summer.
Therefore, conventionally, in order to obtain a makeup cosmetic having good water resistance and oil resistance, a technique of blending silicone oil, fluorine oil, cellulose resin, highly oil-absorbing powder, or using an organic silicone resin as a film forming agent has been proposed. Known,
Still, the effect of preventing makeup deterioration and rubbing resistance (secondary adhesion)
Was not always satisfactory in terms of. In addition, if the effect of preventing makeup deterioration is enhanced, there is a drawback that a film feeling on the skin is remarkably produced as a feeling of use.

The present inventors have conducted intensive studies in view of the above problems, and as a result, in a makeup cosmetic containing a non-aqueous polymer dispersion in which a polymer is dispersed in a volatile silicone, an inorganic powder is added, It has been found that the above-mentioned problems can be solved by incorporating a polyether-modified silicone, and the present invention has been completed.

[0011]

The present invention is as follows.

The invention according to claim 1 comprises a non-aqueous polymer dispersion in which a polymer is dispersed in a volatile silicone, and an aqueous polymer emulsion, wherein the non-aqueous polymer dispersion is 1 to 20% of the total amount.
(Mass percentage), wherein the water-based polymer emulsion is 1 to 20% (mass percentage) based on the total amount, which is an emulsified makeup cosmetic.

According to a second aspect of the present invention, a non-aqueous polymer dispersion in which a polymer is dispersed in a volatile silicone, and a general formula (1), (2), (3), (4), (5) or One or more polyether-modified silicones represented by (6) and an inorganic powder are contained, the non-aqueous polymer dispersion is 1 to 40% (mass percentage), and the polyether-modified silicone is 0.5. ~ 20
% (Mass percentage), and the inorganic powder is 3 to 60% (mass percentage), which is a makeup cosmetic.

[Chemical 9] (1) (In the formula, a is 2 to 50, b is 0 to 50, and m is 10 to 60.
0 and n show the integer of 1-100, and R shows an alkyl group or a hydrogen atom. R is preferably a methyl group. )

[Chemical 10] (2) (In the formula, a is 2 to 80, b is 0 to 100, and m is 10 to 3.
00, n is 1 to 150, o is an integer of 1 to 50, and R
Represents an alkyl group having 6 to 26 carbon atoms, and R ′ represents an alkyl group or a hydrogen atom. R'is preferably a methyl group. )

[Chemical 11] (3) R = - (CH 2) 3 -O- (C 2 H 4 O) a (C 3 H 6 O) b H ( wherein, a is 1 to 40, b is 0 to 50, m is 1 ~ 30
0, n are 1 to 300, o is an integer of 1 to 300, and R
Represents an alkyl group having 6 to 26 carbon atoms. )

[Chemical 12] (4) R = - (CH 2) 3 -O- (C 2 H 4 O) a (C 3 H 6 O) b H ( wherein, a is 1 to 40, b is 0 to 50, m is 1 ~ 300
Indicates an integer. )

[Chemical 13] (5) (In the formula, a is 2 to 80, b is 0 to 100, and m is 1 to 30.
0 and n show the integer of 1-150, and R has 1-10 carbon atoms.
Represents an alkyl group or a hydrogen atom. R'is carbon number 1 to
10 alkylene groups are shown. Both R and R'have 4 carbon atoms
Alkyl groups and alkylene groups of are preferred. )

[Chemical 14] (6) R = - (CH 2) 3 -O- (C 2 H 4 O) a (C 3 H 6 O) b H ( wherein, a is 1 to 40, b is 1 to 40, m is 1 ~ 80,
n is an integer of 1 to 50 and o is an integer of 1 to 80. )

The invention according to claim 3 further has a particle size of 1
The emulsified makeup cosmetic composition according to claim 2, characterized in that the emulsified makeup cosmetic composition contains a spherical powder having a particle size of ˜50 μm.
0% (mass percentage), the spherical powder is 1 to the total amount
It is 20% (mass percentage), and the said inorganic powder is 3-60% (mass percentage) with respect to the total amount, It is a makeup cosmetics characterized by the above-mentioned.

The invention according to claim 4 is characterized in that the polymer is a polymer of acrylic acid ester or methacrylic acid ester, or a copolymer of acrylic acid ester and methacrylic acid ester. It is the makeup cosmetic described in 2 or 3.

The invention according to claim 5 is characterized in that the volatile silicone is one or more volatile silicones represented by the following general formula (1) or (2). It is the makeup cosmetic of 2, 3, or 4.

[Chemical 15] (7) (In the formula, n represents an integer of 3 to 7.)

[Chemical 16] (8) (In the formula, m represents an integer of 0 to 5.)

The invention according to claim 6 is characterized in that the total content of the non-aqueous polymer dispersion and the aqueous polymer emulsion is 5 to 35% (mass percentage). Cosmetics.

[0018]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below.

[Invention of Claim 1] The non-aqueous polymer dispersion referred to in the present invention means a resin liquid in which a volatile silicone is used as a medium and a polymer is dispersed therein. Usually, it can be produced by polymerizing a polymerizable monomer in a volatile silicone solvent. Although any polymerizable monomer can be used here, a radical polymerizable monomer is particularly preferable, and it can be produced by radical polymerization using a radical initiator in a volatile silicone solvent. it can. It is also possible to stably disperse a polymer polymerized by any method such as anionic polymerization, cationic polymerization, and radical polymerization in a volatile silicone, but the one prepared by the above-mentioned polymerization method has dispersion stability It is preferable from the aspect.
The composition ratio of the polymer and the volatile silicone in the non-aqueous polymer dispersion is arbitrary, but preferably,
(Polymer): (volatile silicone) = 1: 25 to 6: 1
And more preferably in the range of 1: 7 to 2: 1.

The polymer contained in the non-aqueous polymer dispersion contained in the makeup cosmetic composition of the present invention may be of any kind, for example, an ester of acrylic acid or methacrylic acid and an alcohol having 1 to 10 carbon atoms. Polymers having as a monomer, acrylic acid or methacrylic acid silicone ester polymers, polymers such as styrene, α-methylstyrene, vinyl acetate, vinyl propionate, etc. can be used, and they can be homopolymers or copolymers. Although it is good, it is preferably a polymer of acrylic acid ester or methacrylic acid ester, or a copolymer of acrylic acid ester and methacrylic acid ester.

The non-aqueous polymer dispersion is preferably prepared by dispersing sucrose benzoate together with the above polymer in volatile silicone.

The non-aqueous polymer dispersion contained in the makeup cosmetic of the present invention uses a volatile silicone having excellent odor and skin safety properties as a medium in which the polymer is dispersed. The medium is not particularly limited as long as it is a volatile silicone, but the volatile silicones represented by the above general formulas (7) and (8) are preferable. More preferred is a polysiloxane represented by the general formula (7). Examples of these readily available polysiloxanes include SH manufactured by Toray Silicone Co.
244, SH344, SH245, DC345, Shin-Etsu Chemical Co., Ltd. KF994, KF995, KF996, KF
9956, TSF404, TSF4 manufactured by Toshiba Silicone Co., Ltd.
05, TSF406 and the like.

The content of the non-aqueous polymer dispersion is preferably in the range of 1 to 20% (mass percentage), and preferably 5 to 15 mass% with respect to the total amount of the makeup cosmetic.
Is. If the blending amount is 1% or less, water resistance, oil resistance, and makeup last will be poor. Further, if the blending amount is 20% or more, the freshness is poor only at the time of application, which is not preferable.

The aqueous polymer emulsion used in the present invention is a known raw material for cosmetics, and the polymer emulsion obtained by the emulsion polymerization method can be used as it is.

The polymer contained in the aqueous polymer dispersion may be of any kind, for example, a polymer having an ester of acrylic acid or methacrylic acid and an alcohol having 1 to 10 carbon atoms as a monomer, acrylic acid or methacrylic acid. Acid silicone ester polymer, styrene,
Polymers such as α-methylstyrene, vinyl acetate and vinyl propionate can be used, and may be homopolymers or copolymers, but are preferably polymers of acrylic acid ester or methacrylic acid ester, or acrylic acid. It is a copolymer of ester and methacrylic acid ester.

The content of the water-based polymer emulsion is preferably in the range of 1 to 20% (mass percentage), and preferably 5 to 15 mass% with respect to the total amount of the makeup cosmetic. If the blending amount is 1% or less, water resistance, oil resistance, and makeup last will be poor. Moreover, this compounding quantity is 20
% Is not preferable because the freshness is poor only at the time of application.

In the present invention, the total content of the non-aqueous polymer dispersion and the aqueous polymer emulsion is preferably 5 to 35% (mass percentage).

The makeup cosmetic of the present invention can be produced by a conventional method by adding other components in addition to the above-mentioned essential components depending on the intended makeup cosmetic. For example, powder component, liquid oil, solid oil, wax,
Hydrocarbons, higher fatty acids, higher alcohols, ester oils,
Silicone oil, anionic surfactant, cationic surfactant, amphoteric surfactant, nonionic surfactant, moisturizer, water-soluble polymer, thickener, film agent, ultraviolet absorber, sequestering agent, lower alcohol , Polyhydric alcohol, sugar, amino acid, organic amine, polymer emulsion, pH adjusting agent, skin nutrient, vitamin, antioxidant, antioxidant auxiliary, fragrance, water, etc., if necessary, appropriately mixed, The emulsified composition can be produced by the method. Specific ingredients that can be blended are listed below, but the desired emulsified makeup cosmetic can be produced by a conventional method by blending the above-mentioned essential ingredients and any one or more of the following ingredients.

The powder component is, for example, an inorganic powder (eg, talc, kaolin, mica, sericite),
Muscovite, phlogopite, synthetic mica, phlogopite, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, tungstate metal salt, magnesium, Silica, zeolite, barium sulfate, calcined calcium sulfate (calculated gypsum), calcium phosphate, fluoroapatite, hydroxyapatite, ceramic powder, metal soap (eg, zinc myristate, calcium palmitate, aluminum stearate), boron nitride, etc .; organic Powder (for example, polyamide resin powder (nylon powder), polyethylene powder, polymethylmethacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, benzoguanamine resin powder, polytetrafluoroethylene powder) Powder, cellulose powder, etc .; inorganic white pigment (eg titanium dioxide, zinc oxide etc.); inorganic red pigment (eg iron oxide (red iron oxide), iron titanate etc.); inorganic brown pigment (eg γ-oxidation) Inorganic yellow pigments (eg yellow iron oxide, ocher etc.); Inorganic black pigments (eg black iron oxide, low order titanium oxide etc.); Inorganic purple pigments (eg manganese violet, cobalt violet etc.) ); Inorganic green pigments (eg, chromium oxide, chromium hydroxide, cobalt titanate, etc.); Inorganic blue pigments (eg, ultramarine blue, navy blue, etc.); Pearl pigments (eg,
Titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil); metal powder pigments (for example, aluminum powder, copper powder, etc.); zirconium, barium or Organic pigments such as aluminum lake (for example, red 20
No. 1, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 228, Red No. 405
No. 203, Orange No. 203, Orange No. 204, Yellow No. 205, Yellow No. 401, Blue No. 404, and other organic pigments, Red 3
Red No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange No. 205
No., Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203
No. 3, Green No. 3, Blue No. 1, etc.); natural pigments (eg, chlorophyll, β-carotene, etc.) and the like.

Examples of liquid oils and fats include avocado oil,
Camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, southern oil, castor oil, linseed oil, safflower oil, cottonseed oil, eno oil, Soybean oil, peanut oil, teaseed oil, kaya oil, rice bran oil, cinnamon oil, Japanese tung oil, jojoba oil, germ oil, triglycerin and the like can be mentioned.

Examples of the solid oils and fats include cocoa butter, coconut oil, hydrogenated coconut oil, palm oil, palm kernel oil, sorghum kernel oil, hydrogenated oil, sorghum, and hydrogenated castor oil.

Examples of the wax include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax,
Ibotaro, whale wax, montan wax, nukarou, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, P
OE Lanolin alcohol acetate, POE cholesterol ether, Lanolin fatty acid polyethylene glycol, PO
E Hydrogenated lanolin alcohol ether and the like can be mentioned.

Examples of the hydrocarbon oil include liquid paraffin, ozokerite, squalane, pristane, paraffin, ceresin, squalene, petrolatum and microcrystalline wax.

Examples of the higher fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, tall oil fatty acid, isostearic acid, linoleic acid, linoleic acid, eicosapentaenoic acid (EPA). , Docosahexaenoic acid (DHA) and the like.

Examples of higher alcohols include straight chain alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol, etc.); branched chain alcohols (eg, monostearyl glycerin ether). (Batyl alcohol), 2-
Decyltetradecinol, lanolin alcohol, cholesterol, phytosterols, hexyldecanol,
(Isostearyl alcohol, octyldodecanol, etc.)
Etc.

Examples of ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyldecyl dimethyloctanoate, lactic acid. Cetyl, myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate,
Cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, diisostearyl malate, di-2-heptylundecanoic acid Glycerin, trimethylolpropane tri-2-ethylhexanoate, trimethylolpropane triisostearate, pentaerythritol tetra-2-ethylhexanoate, glyceryl tri-2-ethylhexanoate, glyceryl trioctanoate, glyceryl triisopalmitate, tri Trimethylolpropane isostearate, cetyl 2-
Ethyl hexanoate, 2-ethylhexyl palmitate, glycerin trimyristate, tri-2-heptylundecanoic acid glyceride, castor oil fatty acid methyl ester, oleyl oleate, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L-glutamic acid-2-octyldodecyl ester, di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyldecyl adipate, diisopropyl sebacate, 2-ethylhexyl succinate, triethyl citrate and the like can be mentioned.

Examples of the silicone oil include linear polysiloxanes (eg, dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.); cyclic polysiloxanes (eg, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, etc.) Dodecamethylcyclohexasiloxane, etc.) Silicone resin forming a three-dimensional network structure, silicone rubber, various modified polysiloxanes (amino modified polysiloxane, polyether modified polysiloxane, alkyl modified polysiloxane, fluorine modified polysiloxane, etc.) Etc.

Examples of the anionic surfactant include fatty acid soap (eg, sodium laurate, sodium palmitate, etc.); higher alkyl sulfate ester salt (eg, sodium lauryl sulfate, potassium lauryl sulfate); alkyl ether sulfate ester salt. (For example,
POE-triethanolamine lauryl sulfate, POE-sodium lauryl sulfate, etc.); N-acyl sarcosinic acid (eg,
Lauroyl sarcosine sodium, etc .; Higher fatty acid amide sulfonate (eg, N-myristoyl-N-methyl taurine sodium, coconut oil fatty acid methyl taurine sodium, lauryl methyl taurine sodium, etc.); Phosphate ester salt (POE-oleyl ether phosphate) sodium,
POE-stearyl ether phosphoric acid, etc.); sulfosuccinate (eg, sodium di-2-ethylhexyl sulfosuccinate, monolauroyl monoethanolamide sodium polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate, etc.); alkylbenzene sulfonate ( For example, sodium linear dodecylbenzene sulfonate, triethanolamine linear dodecylbenzene sulfonate, linear dodecyl benzene sulfonic acid, etc .; higher fatty acid ester sulfate ester salt (for example, hydrogenated coconut oil fatty acid glycerin sodium sulfate, etc.); N-acyl glutamate (For example, monosodium N-lauroylglutamate, disodium N-stearoylglutamate, N-myristoyl-L-monosodium glutamate, etc.); Sulfuric acid Oil (eg, funnel oil); POE-alkyl ether carboxylic acid; POE-alkyl allyl ether carboxylate; α-olefin sulfonate; higher fatty acid ester sulfonate; secondary alcohol sulfate ester salt; higher fatty acid alkylol Examples thereof include amide sulfate ester salts; sodium lauroyl monoethanolamide succinate; ditriethanolamine N-palmitoyl aspartate; sodium caseinate and the like.

Examples of the cationic surfactant include alkyl trimethyl ammonium salts (eg stearyl trimethyl ammonium chloride, lauryl trimethyl ammonium chloride, etc.); alkyl pyridinium salts (eg,
Cetylpyridinium chloride, etc.); Distearyldimethylammonium dialkyldimethylammonium chloride; Poly (N, N'-dimethyl-3,5-methylenepiperidinium) chloride;
Alkyl quaternary ammonium salts; Alkyl dimethyl benzyl ammonium salts; Alkyl isoquinolinium salts; Dialkyl morphonium salts; POE-alkyl amines; Alkyl amine salts; Polyamine fatty acid derivatives; Amyl alcohol fatty acid derivatives; Benzalkonium chloride; Benzethonium chloride Etc.

As the amphoteric surfactant, for example, an imidazoline-based amphoteric surfactant (eg, 2-undecyl-N, N, N) is used.
-(Hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt, etc .; betaine surfactant (eg, 2-heptadecyl-N- Carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkyl betaine, amidobetaine, sulfobetaine, etc.) and the like.

Examples of lipophilic nonionic surfactants include sorbitan fatty acid esters (eg, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquis). Oleate, sorbitan trioleate, penta-2-ethylhexyl diglycerol sorbitan, tetra-2-ethylhexyl diglycerol sorbitan, etc.); glycerin polyglycerin fatty acids (eg monocotton oil fatty acid glycerin, monoerucic acid glycerin, sesquioleate glycerin) , Glyceryl monostearate, α, α '
-Glycerin oleate pyroglutamate, glyceryl monostearate malic acid, etc.); propylene glycol fatty acid esters (eg, propylene glycol monostearate etc.); hydrogenated castor oil derivative; glycerin alkyl ether and the like.

Examples of hydrophilic nonionic surfactants include POE-sorbitan fatty acid esters (eg, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan tetraoleate). Etc.); POE sorbit fatty acid esters (eg, POE-sorbit monolaurate, POE-sorbit monooleate, POE-sorbit pentaoleate, POE-sorbit monostearate, etc.); POE-glycerin fatty acid esters (eg, POE-glycerin monostearate, POE-glycerin monoisostearate, PO
E-glycerin triisostearate and other POE-monooleates, etc .; POE-fatty acid esters (eg, POE-distearate, POE-monodioleate, ethylene glycol distearate, etc.); POE-alkyl ethers (eg, POE-lauryl ether) , POE-oleyl ether, PO
E-stearyl ether, POE-behenyl ether, POE-2-
Octyldodecyl ether, POE-cholestanol ether, etc.); Pluronic types (eg, Pluronics); POE / POP-alkyl ethers (eg, POE / PO)
P-cetyl ether, POE ・ POP-2-decyl tetradecyl ether, POE ・ POP-monobutyl ether, POE ・ POP-hydrogenated lanolin, POE ・ POP-glycerin ether, etc.); Tetra P
OE / tetra-POP-ethylenediamine condensates (eg, Tetronic); POE-castor oil hydrogenated castor oil derivatives (eg, POE-castor oil, POE-hardened castor oil, POE-hardened castor oil monoisostearate, POE -Cured castor oil triisostearate, POE-cured castor oil monopyroglutamic acid monoisostearate diester, POE-cured castor oil maleic acid, etc .; POE-beeswax lanolin derivative (for example, POE-sorbit beeswax, etc.); alkanolamide (For example, coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE-propylene glycol fatty acid ester; PO
Examples include E-alkylamines; POE-fatty acid amides; sucrose fatty acid esters; alkylethoxydimethylamine oxides; trioleylphosphoric acid.

Examples of moisturizers include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12-. Examples thereof include hydroxystearate, sodium lactate, bile salts, dl-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO) PO adducts, Izayoba rose extract, Achillea millefolium extract and Merrilot extract.

Examples of natural water-soluble polymers include plant-based polymers (eg, gum arabic, tragacanth, galactan, guar gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (quince), algecoloid (cassou extract). ), Starch (rice, corn, potato, wheat), glycyrrhizic acid); microbial macromolecules (for example, xanthan gum, dextran, succinoglucan, bullan, etc.); animal macromolecules (for example, collagen, casein,
Albumin, gelatin, etc.) and the like.

As the semi-synthetic water-soluble polymer, for example,
Starch-based polymers (for example, carboxymethyl starch, methyl hydroxypropyl starch, etc.); Cellulose-based polymers (methyl cellulose, ethyl cellulose, methyl hydroxypropyl cellulose, hydroxyethyl cellulose, sodium cellulose sulfate, hydroxypropyl cellulose, carboxymethyl cellulose, carboxymethyl cellulose sodium, Crystalline cellulose,
Cellulose powder, etc.); alginic acid-based polymers (eg, sodium alginate, propylene glycol alginate, etc.) and the like.

As the synthetic water-soluble polymer, for example, vinyl-based polymer (eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinylpyrrolidone, carboxyvinyl polymer, etc.); polyoxyethylene-based polymer (eg, polyethylene glycol 20,000, 40,000, 6
Examples include polyoxyethylene-polyoxypropylene copolymers of 0,000); acrylic polymers (eg, sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.); polyethyleneimine; cationic polymers and the like.

Examples of the thickener include gum arabic,
Carrageenan, karaya gum, tragacanth gum, carob gum, quince seed (quince), casein, dextrin, gelatin, sodium pectate, sodium alginate, methyl cellulose, ethyl cellulose,
CMC, hydroxyethyl cellulose, hydroxypropyl cellulose, PVA, PVM, PVP, sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarind gum, dialkyldimethylammonium sulfate cellulose, xanthan gum, magnesium aluminum silicate, bentonite,
Hectorite, silicic acid A1Mg (veegum), laponite, silicic acid anhydride and the like can be mentioned.

Examples of the ultraviolet absorber include the following compounds. Benzoic acid-based UV absorbers, for example, para-aminobenzoic acid (hereinafter abbreviated as PABA), PABA
Monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester, N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N-dimethyl PABA ethyl ester and the like. Anthranilic acid type ultraviolet absorber, for example, homomenthyl-N-acetylanthranilate. Salicylic acid-based ultraviolet absorber, for example, amyl salicylate, menthyl salicylate,
Homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate, etc. Cinnamic acid-based UV absorbers, for example, octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate , Propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, octyl-
p-methoxycinnamate (2-ethylhexyl-p-methoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate, cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2- Ethylhexyl-α-cyano-β-phenylcinnamate, glyceryl mono-2-ethylhexanoyl-diparamethoxycinnamate, etc. Triazine-based UV absorber, for example, bisresorcinyltriazine. More specifically, bis {[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} -6- (4-methoxyphenyl)
1,3,5-triazine, 2,4,6-tris {4-
(2-Ethylhexyloxycarbonyl) anilino} 1,
3,5-triazine and the like. Other UV absorbers, for example, 3- (4'-methylbenzylidene) -d, l-camphor,
3-benzylidene-d, l-camphor, 2-phenyl-5-methylbenzoxazole, 2,2'-hydroxy-5-methylphenylbenzotriazole, 2- (2'-hydroxy-5'-t-octylphenyl ) Benzotriazole, 2- (2'-hydroxy-5'-
Methylphenylbenzotriazole, dibenzalazine,
Dianisoylmethane, 4-methoxy-4'-t-butyldibenzoylmethane, 5- (3,3-dimethyl-2-norbornylidene) -3-
Such as pentan-2-one. Pyridazine derivatives such as dimorpholinopyridazinone.

Examples of the sequestering agent include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, edetate disodium, edetate trisodium, and edet. Tetrasodium acid, sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid,
Examples thereof include ascorbic acid, succinic acid, edetic acid, trisodium ethylenediamine hydroxyethyl triacetate and the like.

Examples of the lower alcohol include ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.

Examples of the polyhydric alcohol include dihydric alcohols (eg, ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3-). Butylene glycol, pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol, octylene glycol, etc.); trivalent alcohol (eg, glycerin, trimethylolpropane, etc.);
Tetrahydric alcohol (eg, pentaerythritol such as 1,2,6-hexanetriol); pentahydric alcohol (eg, xylitol); hexahydric alcohol (eg, sorbitol, mannitol); polyhydric alcohol polymer (eg, , Diethylene glycol, dipropylene glycol, triethylene glycol, polypropylene glycol, tetraethylene glycol, diglycerin, polyethylene glycol, triglycerin, tetraglycerin, polyglycerin, etc.); divalent alcohol alkyl ethers (for example, ethylene glycol monomethyl ether, Ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, ethylene glycol monohexyl ether, ethylene glycol Cole mono 2-methylhexyl ether, ethylene glycol isoamyl ether, ethylene glycol benzyl ether, ethylene glycol isopropyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, etc .; Dihydric alcohol alkyl ethers (for example, diethylene glycol monomethyl) Ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol butyl ether, diethylene glycol methyl ethyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, pro Pyrene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol isopropyl ether,
Dipropylene glycol methyl ether, dipropylene glycol ethyl ether, dipropylene glycol butyl ether, etc.); dihydric alcohol ether ester (eg, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl) Ether acetate, ethylene glycol diabate, ethylene glycol disuccinate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate , Propylene glycol monophenyl ether acetate); glycerol monoalkyl ethers (e.g., chimyl alcohol, selachyl alcohol, batyl alcohol); sugar alcohols (e.g.,
Sorbitol, maltitol, maltotriose, mannitol, sucrose, erythritol, glucose, fructose, starch-decomposing sugar, maltose, xylitose, starch-decomposing sugar reducing alcohol, etc.); Glysolid; Tetrahydrofurfuryl alcohol; POE-Tetrahydrofur Furyl alcohol; POP-butyl ether;
POP / POE-butyl ether; tripolyoxypropylene glycerin ether; POP-glycerin ether; POP-glycerin ether phosphoric acid; POP / POE-pentane erythritol ether, polyglycerin and the like.

As the monosaccharide, for example, tricarbose (for example,
D-glyceryl aldehyde, dihydroxyacetone, etc.);
Four-carbon sugar (for example, D-erythrose, D-erythrulose,
D-threose, erythritol, etc.); pentoses (eg,
L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc .; hexose (eg, D-glucose, D-talose, D- Bucose, D-galactose, D-fructose, L-galactose, L-mannose, D-tagatose and the like); heptacarbon sugar (for example, aldoheptose, heprose and the like); octose sugar (for example, octulose and the like); deoxy sugar (for example, , 2-deoxy-D-ribose, 6-deoxy-L-
Galactose, 6-deoxy-L-mannose, etc.); Amino sugar (eg, D-glucosamine, D-galactosamine, sialic acid, aminouronic acid, muramic acid, etc.); Uronic acid (eg, D-glucuronic acid, D-mannuronic acid) , L-guluronic acid, D-galacturonic acid, L-iduronic acid, etc.) and the like.

Examples of the oligosaccharides include sucrose, umbelliferose, lactose, planteose, isoliknoses, α, α-trehalose, raffinose, licinoses, umbilicin, stachyose verbascose and the like.

Examples of polysaccharides include cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, hyaluronic acid, tragacanth gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guar gum and dextran. , Keratosulfate, locust bingham, succinoglucan, caronic acid and the like.

Examples of amino acids include neutral amino acids (eg, threonine, cysteine, etc.); basic amino acids (eg, hydroxylysine, etc.) and the like. Examples of the amino acid derivative include sodium acyl sarcosine (sodium lauroyl sarcosine), acyl glutamate, sodium β-alanine acyl, glutathione, and pyrrolidone carboxylic acid.

Examples of the organic amine include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-methyl-1. -Propanol and the like can be mentioned.

As the polymer emulsion, for example, acrylic resin emulsion, polyethyl acrylate emulsion, acrylic resin liquid, polyacrylic alkyl ester emulsion, polyvinyl acetate resin emulsion,
Examples thereof include natural rubber latex.

Examples of the pH adjusting agent include lactic acid-sodium lactate, citric acid-sodium citrate, succinic acid-
Examples include buffering agents such as sodium succinate.

Examples of vitamins include vitamin A,
Examples include B1, B2, B6, C, E and derivatives thereof, pantothenic acid and derivatives thereof, biotin and the like.

Examples of the antioxidant include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, gallic acid esters and the like.

As the antioxidant aid, for example, phosphoric acid,
Examples thereof include citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid and ethylenediaminetetraacetic acid.

Other components that can be mixed are, for example,
Preservatives (methylparaben, ethylparaben, butylparaben, phenoxyethanol etc.); anti-inflammatory agents (eg glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin etc.); whitening agents (eg Yukinoshita extract, arbutin). Etc.); various extracts (for example, psyllium, citrus, cypress, peony, assembly, birch, sage, loquat,
Carrots, aloe, mallow, iris, grapes, yellow quinine, loofah, lily, saffron, senkyu, ginger, Hypericum perforatum, Ononis, garlic, capsicum, chimp, touki, seaweed, etc., activator (for example, royal jelly, photosensitizer, cholesterol) Derivatives and the like); blood circulation promoting agents (eg, nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, zingerone, cantharisin tincture, ictamol, tannic acid, α-borneol, nicotinic acid tocopherol, inositol hexanicotinate, siku Randerate, cinnarizine, trazoline, acetylcholine, verapamil, cepharanthin, γ-oryzanol, etc.); antiseborrheic agents (eg, sulfur, thiantol, etc.); anti-inflammatory agents (eg, tranexamic acid, thiazine). Taurine, hypotaurine, etc.)
Etc.

The make-up cosmetic composition of the present invention has an emulsion composition and can be either an O / W emulsion system or a W / O emulsion system.

In the case of a foundation, the makeup cosmetic composition of the present invention is preferable because the freshness is particularly exhibited only upon application. Even in the case of eyeliner, mascara, eyebrow, foundation, and eye shadow, it exerts an extremely excellent effect of preventing makeup from being damaged by sweat, tears, swimming, sebum, etc.

[Invention of Claim 2] The non-aqueous polymer dispersion in which a polymer is dispersed in volatile silicone, which is the main part of the constitution of the present invention, is the same as that used in the invention of Claim 1. is there. The compounding amount is 1 to 40% (mass percentage) based on the total amount, preferably 5 to 20
% (Mass percentage).

The above general formulas (1), (2), (3),
The polyether-modified silicone represented by (4), (5), or (6) acts as an emulsifier to form an emulsion composition. Examples of easily available commercially available polyether-modified silicones include SH3771M, SH3772M, SH manufactured by Toray Dow Corning Silicone Co., Ltd.
3773M, SH3775M, SH3746M, SH3
748, SH3749, DC5200; Nippon Unicar Co., Ltd. SILWET series; GOLDSCHMI
Examples include ABIL EM 90 and ABIL EM 97 manufactured by DT. 0.5-20% of the total amount
(Mass percentage), preferably 1 to 7% (mass percentage)
Is.

Examples of the inorganic powder include talc,
Extender pigments such as sericite, mica, kaolin, silica;
Colorants such as titanium oxide, iron oxide, zinc oxide, ultramarine blue, dark blue, and chromium oxide; and composite pigments such as titanium mica and iron oxide coated mica. For inorganic powder, PM
MA resin powder, nylon powder, polyethylene powder, silk powder, cellulose powder, organic tar dye, lake, etc. may coexist. Further, these powders may be surface-repellent treated. Examples of the surface water repellent treatment agent include silicone, higher fatty acid, higher alcohol, fatty acid ester, metal soap, amino acid, alkylphosphoether, fluorine compound and the like. Preferable ones are powders which have been subjected to water repellent treatment using higher fatty acid, dextrin fatty acid ester, fluorine compound, silicone and the like. The powder thus obtained has the strongest water repellency, and even when it is actually applied to an emulsion, it is strong against water and sweat, and the makeup is most unlikely to be damaged. In addition, the emulsified particles are dense and have the longest stability. Even when using untreated powder that is not water repellent,
A relatively stable emulsion can be obtained, but the hydrophilicity of the powder surface makes it very easy to cause makeup damage due to water or sweat.

The content of the inorganic powder is 3.0 to 60.0% (mass percentage), preferably 7.0 to 30.0% (mass percentage), based on the total amount of the makeup cosmetic composition. 3.0
If it is less than%, the color development is poor and it may be unsuitable as a makeup cosmetic. When it is more than 60.0%, the powderyness becomes remarkable, and the feeling of use during application and the durability of makeup after application, which are the effects of the composition of the present invention, are deteriorated.

The components that can be blended with the above essential components are the same as the various components listed in the invention of claim 1, and the emulsified makeup cosmetic composition of the present invention can be produced by a conventional method.

The makeup cosmetic of the present invention is an emulsion type,
It is possible to provide any of the oily type bases which are excellent in the feel at the time of application and the durability of the makeup after application and are also excellent in stability over time. In particular, there are many types of cosmetics that are excellent in makeup lasting, and various coating agents are mixed, which is contrary to the goodness of makeup lasting and causes a feeling of thickness and filminess on the feeling of use. There were many things that were difficult to remove during cleaning. The non-aqueous polymer dispersion used in the present invention not only excels in makeup lasting, but also has a very flexible film forming ability, so that it does not cause a thick feeling or a film feeling on the feel of use, and is washed. It is a solution to the conventional problems that it is easy to remove even at times, and it is particularly preferable to apply it to summer makeup cosmetics in which makeup breakage easily occurs.

[Invention of Claim 3] The invention of Claim 3 further comprises spherical powder having a particle diameter of 1 to 50 μm in addition to the invention of Claim 2 to give a beautiful matt feeling to makeup cosmetics. It has been demonstrated. Particle size is 1 μm
If it is less than 50 μm, the feeling of use is not spread well and a squeaky feeling is produced. Examples of the spherical powder include, but are not limited to, silica, PMMA, silicone elastomer, silicone resin, composite of silicone elastomer and resin, nylon, urethane, polyethylene, silk, cellulose and other materials. . The spherical powder is blended separately from the above inorganic powder, and is 1 to 40.0% (mass percentage), preferably 2.0, with respect to the total amount of the makeup cosmetic.
20.0% (mass percentage). When it is blended in an amount of more than 40.0%, a beautiful matte finish is not exerted as its effect, but the spread of the feel is worsened, and when it is less than 1.0%, the effect is weak.

[0072]

EXAMPLES The present invention will be described in more detail with reference to Examples and Comparative Examples. The invention is not limited to the examples described below. Unless otherwise specified, the unit of the blended amount is% (mass percentage).

The non-aqueous polymer dispersions used in all Examples and Comparative Examples were manufactured by the following method. As the other components, those commercially available as raw materials for cosmetics were used.

Production of "Non-Aqueous Polymer Dispersion A" Methyl methacrylate monomer 15%, ethyl acrylate monomer 25%, polymerization initiator 0.1%, dispersion stabilizer dimethylpolysiloxane graft polymer (molecular weight about 1
50,000) 5% was added to 54.9% of the dispersion medium decamethylcyclopentasiloxane (n = 5 in the general formula (4)).
Polymerization was carried out by stirring at 120 ° C. for 10 hours. Then, after demonomerization is performed under reduced pressure, the mixture is cooled to 25 ° C. and the appearance is milky white and the average particle diameter of the dispersion polymer particles is 1 μm.
A non-aqueous polymer dispersion containing m of volatile silicone as a dispersion medium was obtained.

The evaluation of all Examples and Comparative Examples was carried out by the following method. The foundation of each Example and Comparative Example was applied to the left and right sides of the face on a panel dedicated to "freshness during application" (20 persons), and the freshness was evaluated according to the following criteria. <Evaluation Criteria> A: 16 to 20 persons were judged to be good. Good: 11 to 15 persons were judged to be good. Δ: 6 to 10 persons were judged to be good. X: 0 to 5 persons were judged to be good. The foundation of each Example and Comparative Example was applied to the "makeup mochi" specialized panel (20 persons) on the right and left sides of the face, and the state after 4 hours was evaluated according to the following criteria. <Evaluation Criteria> A: 16 to 20 persons were judged to be good. Good: 11 to 15 persons were judged to be good. Δ: 6 to 10 persons were judged to be good. X: 0 to 5 persons were judged to be good. The foundations of each Example and Comparative Example were applied to the "non-filmy" specialty panel (20 persons) on the right and left sides of the face, and the state after 4 hours was evaluated according to the following criteria. <Evaluation Criteria> A: 16 to 20 persons were judged to be good. Good: 11 to 15 persons were judged to be good. Δ: 6 to 10 persons were judged to be good. X: 0 to 5 persons were judged to be good. "Water resistance" A nylon plate having a length of 5 cm, a width of 1 cm and a thickness of 1 mm was uniformly coated with the foundations of the examples and comparative examples to prepare samples. After this sample was dried, it was set in a 20 ml glass sample tube containing 10 ml of ion-exchanged water, shaken for 10 minutes with a shaker, and the state of remaining coating film was evaluated according to the following criteria. A: Very good. ◯: Good. Δ: Bad X: Extremely defective. "Oil resistance" A nylon plate having a length of 5 cm, a width of 1 cm and a thickness of 1 mm was uniformly coated with the foundations of the examples and comparative examples to prepare samples. After drying this sample, it was set in a 20 ml glass sample tube containing 10 ml of oil (triglyceride) and shaken for 10 minutes on a shaker,
The remaining state of the coating film was evaluated according to the following criteria. A: Very good. ◯: Good. Δ: Bad X: Extremely defective.

"Examples of the Invention of Claim 1"<Examples 1-1 to 1-6, Comparative Examples 1-1 to 1-8> O / W emulsified foundation was prepared according to the formulation shown in "Table 1". And W / O emulsion foundations were manufactured and evaluated.

(Production method) 1,3-butylene glycol in which bentonite, which is an O / W type emulsion foundation water-based thickener, was dispersed, was added to purified water and treated with a homomixer at 70 ° C., and the remaining aqueous phase components were removed. Add and stir well. To this, the powder portion that has been thoroughly mixed and pulverized is added with stirring, and subjected to homomixer treatment at 70 ° C. Next, 70
Gradually add the oil phase heated and dissolved at ~ 80 ° C to 70 ° C.
At a homomixer. A preservative and a fragrance are cold-added to this while stirring, and cooled to room temperature. Finally, degas and fill the container.

(Manufacturing Method) The W / O type emulsion foundation aqueous phase was heated and stirred at 70 ° C., and then the powder portion thoroughly mixed and pulverized was added with stirring to disperse bentonite which is a system thickener 1. Add 3-butylene glycol to purified water,
Perform homomixer treatment at 70 ° C. Next, the oil phase heated and stirred and mixed at 70 ° C. is gradually added and treated at 70 ° C. with a homomixer. A preservative and a fragrance are cold-added to this while stirring, and cooled to room temperature. Finally, degas and fill the container.

[0079]

[Table 1] * 1: Aqueous acrylic polymer emulsion obtained by a usual emulsion polymerization method. The polymer is a terpolymer of methyl methacrylate / butyl acrylate / 2 ethylhexyl acrylate, and its composition is methyl methacrylate: butyl acrylate: 2 ethylhexyl acrylate = 3: 4: 3. Polymer concentration is 50%
(Mass percentage), average particle diameter 0.2 μm.

As is clear from Table 1, the foundation of the present invention has a good feeling in use and long-lasting makeup as compared with the comparative example.

[Examples of the Invention According to Claim 2] <Examples 2-1 to 2-9, Comparative Examples 2-1 to 2-12> Various foundations having a blending composition shown in Table 2 were produced and applied. The freshness, makeup retention, water resistance, oil resistance, and lack of film feeling were evaluated. The results are shown in Table 2. The manufacturing method is as follows. (Production method) The W / O type emulsion foundation powder and the oil phase were mixed, and the powder was uniformly dispersed by a homomixer. The aqueous phase was added to the mixture while stirring to emulsify the mixture, followed by homomixer treatment. Then, it is deaerated and filled in a container. (Production method) 1,3-butylene glycol in which O / W emulsified foundation bentonite is dispersed is added to purified water and subjected to a homomixer treatment at 70 ° C, and then the remaining water phase components are added and sufficiently stirred. To this, the powder portion that has been thoroughly mixed and pulverized is added with stirring, and subjected to homomixer treatment at 70 ° C. Next, the oil phase heated and dissolved at 70 to 80 ° C is gradually added and treated at 70 ° C with a homomixer. This is cooled with stirring, the fragrance is added at 45 ° C., and it is cooled to room temperature. Finally, degas and fill the container. (Production method) Oily foundation Oily component and solid wax are melted at 85 ° C., and the powder part which is sufficiently mixed and pulverized is added thereto with stirring,
Perform homomixer treatment at 85 ° C. Next, add spices,
After degassing, pour into a container at 70 ° C. and cool. * 1): In the general formula (1), a is 10, b is 0, m is 60, n is an integer of 3, and R is methyl.

[0082]

[Table 2] As is clear from Table 2, the foundation of the present invention has a good feeling in use and long-lasting makeup as compared with the comparative example. Other examples of the present invention will be described below.

Example 2-10 Eyeliner (1) Silicone-treated black iron oxide 20.0% (2) Dimethylpolysiloxane 5.0 (3) Decamethylcyclopentasiloxane 17.0 (4) Vitamin E acetate 0.1. 2 (5) Jojoba oil 2.0 (6) Fragrance 0.1 (7) Bentonite 3.0 (8) Non-aqueous polymer dispersion 5.0 (9) Polyether-modified silicone 3.0 (General formula (2) A = 55, b = 70, m = 100, n = 50, o = 10, R = C16 alkyl group, R '= hydrogen atom) (10) Purified water residual amount (11) 1 , 3-Butylene glycol 10.0 (Production method) (1) to (9) were heated and stirred, then (9) and (10) were added and emulsified to obtain an eyeliner. This eyeliner is 40
It was stable at ℃, 25 ℃, and 0 ℃ for 1 month or more, respectively, and had a refreshing feeling of use, and both water resistance and sweat resistance were ⊚, which was excellent in makeup retention.

Example 2-11 Mascara (1) Isopar E 10.0% (2) Vinyl acetate emulsion 8.0 (3) Polyether-modified silicone 2.5 (in the general formula (3), a = 10, b = 8, m = 40, n = 60, o = 40) (4) Decamethylcyclopentapolysiloxane 30.0 (5) Paraben 0.1 (6) Perfume 0.1 (7) Clay mineral 3. 0 (8) Palmitic acid treated iron oxide black 3.1 (9) Non-aqueous polymer dispersion 10.0 (10) Propylene glycol 3.0 (11) Purified water Residual amount (production method) (1) to (9) (10), (11) is heated to 60 ℃, (1) ~
(10) and (11) were added to (9) with stirring to emulsify and then cooled to obtain a mascara. This mascara is 40 ℃, 25 ℃, 0
Each of them was stable at 1 ° C or more for 1 month or more, had a refreshing feeling of use, and had water resistance and sweat resistance of ⊚, which was excellent in makeup retention.

Example 2-12 Pre-Making (1) Liquid Paraffin 10.0% (2) Polyether-modified Silicone 2.5 (in the general formula (4), a = 10, b = 10, m = 60 (3) Non-aqueous polymer dispersion 7.0 (4) Decamethylcyclopentapolysiloxane 26.0 (5) Octyl methoxycinnamate 1.5 (6) Perfume 0.1 (7) Paraben 0.1 ( 8) Fluorine-treated talc 3.0 (9) Spherical nylon powder 1.0 (10) 10% by weight ethyl alcohol aqueous solution Remaining amount (11) Polyethylene glycol 1.4 (12) Propylene glycol 8.0 (production method) (1) -(9) and (10)-(12) are separately heated and stirred at 70 ° C, (10)-(12) are added to (1)-(9) with stirring to emulsify, and then cooled. Premade lotions were manufactured. This lotion was stable at 37 ° C., 25 ° C., and 0 ° C. for 1 month or more, respectively. In addition, the water resistance and sweat resistance were both ◎, which was excellent in makeup lasting, while having a refreshing feeling of use. When the powdery foundation was applied repeatedly, the makeup lasting property was improved as compared with the case of applying without the lotion.

Example 2-13 Foundation (1) Decamethylpentacyclosiloxane 20.0% (2) Nonaqueous Polymer Dispersion 8.0 (3) Vitamin E Acetate 0.1 (4) Polyether Modified Silicone 3. 5 (in the general formula (5), a = 10, b = 5, m = 100, R = C ₄ H ₉ , R ′ = C ₄ H ₈ ) (5) Bentonite 0.6 (6) Fluorine treatment Titanium dioxide 5.8 (7) Fluorine treated talc 4.2 (8) Fluorine treated iron oxide 2.1 (9) 15 wt% ethyl alcohol aqueous solution Residual amount (10) Propylene glycol 8.0 (11) Paraben 0.1 (Production method) (1) to (8) are stirred, (9) to (11) are heated and stirred at 70 ° C., and (9) to (11) are added to (1) to (8) with stirring. After emulsifying, a foundation was obtained. This foundation was stable at 37 ° C., 25 ° C. and 0 ° C. for 1 month or more, respectively. In addition, it had a refreshing feeling of use, and both water resistance and sweat resistance were ⊚, which was excellent in makeup retention.

Example 2-14 Cream Foundation (1) Decamethylpentacyclosiloxane 15.0% (2) Dimethylpolysiloxane 3.0 (3) Nonaqueous Polymer Dispersion 10.0 (4) Polyether Modified Silicone 3 0.0 (in the general formula (1), a = 25, b = 25, m = 500, n = 10, R = hydrogen atom) (5) Octyl methoxycinnamate 2.0 (6) Silicone treated titanium dioxide 8.0 (7) Silicone treated sericite 5.0 (8) Silicone treated iron oxide 2.0 (9) Butylene glycol 5.0 (10) 30 wt% ethyl alcohol aqueous solution Residual amount (11) Paraben 0.1 ( (Production method) (1) to (8) are stirred, (9) to (11) are heated and stirred at 70 ° C, and (9) to (11) are added to (1) to (8) with stirring to emulsify. After the foundation Obtained. This foundation was stable at 37 ° C., 25 ° C. and 0 ° C. for 1 month or more, respectively. In addition, it had a refreshing feeling of use, and both water resistance and sweat resistance were ⊚, which was excellent in makeup retention.

Example 2-15 Foundation (1) Dimethylpolysiloxane 20.0% (2) Non-aqueous polymer dispersion 12.0 (3) Squalane 5.0 (4) Behenyl alcohol 1.0 (5) Perfume 0.1. 1 (6) Paraben 0.1 (7) Octyl methoxycinnamate 2.5 (8) Polyether modified silicone 4.0 (in the general formula (6), a = 20, b = 20, m = 15, n = 2, o = 15) (9) Silicone treated titanium dioxide 5.8 (10) Silicone treated sericite 4.2 (11) Silicone treated iron oxide 2.1 (12) Butylene glycol 5.0 (13) Purification Water balance (production method) (1) to (11) and (12) to (13) are heated and stirred separately to make them uniform, while stirring (1) to (11) to (12) to (13). After additionally emulsifying, it was cooled to produce a foundation.
This foundation is stable at 40 ° C., 25 ° C. and 0 ° C. for 1 month or more, and has a refreshing feeling on use, water resistance and sweat resistance are both ⊚, and is excellent in makeup retention. It was

[Examples of the Invention According to Claim 3] <Examples 3-1 to 3-2, Comparative Examples 3-1 to 3-5> Various foundations having a blending composition shown in Table 3 were produced to give a matt finish. Finish,
The freeness, the durability of makeup, and the lack of film feeling were evaluated. The results are shown in Table 3. The manufacturing method is as follows.

The "matte finish" and "spreadiness" were evaluated by the following methods. The foundation of each Example and Comparative Example was applied to a specialized panel (20 persons) on the right and left sides of the face and evaluated according to the following criteria. <Evaluation Criteria> A: 16 to 20 persons were judged to be good. Good: 11 to 15 persons were judged to be good. Δ: 6 to 10 persons were judged to be good. X: 0 to 5 persons were judged to be good.

(Production Method) W / O type emulsion foundation powder was mixed with an oil phase, and the powder was uniformly dispersed with a homomixer. The aqueous phase was added to the mixture while stirring to emulsify, and the mixture was treated with a homomixer. did. Then, it is deaerated and filled in a container.

[Table 3] * 1) In the general formula (3), a = 10, b = 0, m =
An integer of 60 and n = 3 is shown, and one having R = H is used.

As is clear from Table 3, the foundation of the present invention shows a good matte finish, a good feeling in use and a long lasting makeup, as compared with those of the comparative example. Other examples of the present invention will be described below.

Example 3-3 O / W Emulsion Foundation (1) Pigment Grade Titanium Oxide (Particle Diameter 0.2 to 0.5 μm) 10.0% (2) Ultrafine Titanium Oxide 2.0 (3) Talc 2.0 (4) Sericite 1.0 (5) Red iron oxide 0.5 (6) Yellow iron oxide 1.4 (7) Black iron oxide 0.1 (8) Spherical silica 8.0 (9) Purified water balance (10 ) 1,3-Butylene glycol 5.0 (11) Glycerin 3.0 (12) Bentonite 0.5 (13) Polyoxyethylenesorbitan monostearate 0.9 (14) Triethanolamine 1.0 (15) Non Water-based polymer dispersion 5.0 (16) Squalane 2.0 (17) Decamethylpentacyclosiloxane 2.0 (18) Stearic acid 2.0 (19) Glycerin monostearate 2.0 (20) Isohexadecyl alcohol 5.0 (Process) Add 1,3-butylene glycol with bentonite dispersed to purified water After homomixer treatment with 70 ° C., then add the remaining water phase ingredients, thoroughly stirred. To this, add the powder portion that has been thoroughly mixed and pulverized while stirring,
Perform homomixer treatment at 70 ° C. Next, 70-80 ℃
The oil phase heated and dissolved in is gradually added and treated with a homomixer at 70 ° C. Cool this while stirring, 45
Add perfume at ℃ and cool to room temperature. Finally, degas and fill the container.

Example 3-4 Oily Foundation (1) Pigment Grade Titanium Oxide (Particle Diameter 0.2 to 0.5 μm) 15.0% (2) Ultrafine Titanium Oxide 5.0 (3) Talc 8.0 (4) Sericite 5.0 (5) Red iron oxide 1.0 (6) Yellow iron oxide 2.8 (7) Black iron oxide 0.2 (8) Spherical silicone resin powder 7.0 (9) Polyether-modified silicone * 2) 2.0 (10) Non-aqueous polymer dispersion 5.0 (11) Squalane 10.0 (12) Decamethylpentacyclosiloxane Residual amount (13) Dimethylpolysiloxane 4.5 (14) Solid paraffin 2.0 (15 ) Microcrystalline wax 7.0 * 2) In the general formula (3), a = 20, b = 20, m
= 300, n = 10, and R = H. (Manufacturing method) The oily component and the solid wax are dissolved at 85 ° C., and the powder portion which has been sufficiently mixed and pulverized is added thereto with stirring, and a homomixer treatment is performed at 85 ° C. Next, after adding a fragrance | flavor and deaerating, it pours in a container at 70 degreeC, and cools it.

Example 3-5 Eyeliner (1) Silicone-treated black iron oxide 15.0% (2) Dimethylpolysiloxane 5.0 (3) Nylon 5.0 (4) Decamethylcyclopentasiloxane 17.0 ( 5) Vitamin E acetate 0.2 (6) Jojoba oil 2.0 (7) Fragrance 0.1 (8) Bentonite 3.0 (9) Non-aqueous polymer dispersion 5.0 (10) Polyether-modified silicone * 3 ) 3.0 (11) Purified water Residual amount (12) 1,3-butylene glycol 10.0 * 3) In the general formula (3), a = 10, b = 10, m
= 60, n = 3, and R = H. (Production method) After heating and stirring (1) to (10), (11) and (12) were added and emulsified to obtain an eyeliner. This eyeliner is 40
It was stable at ℃, 25 ℃, and 0 ℃ for 1 month or more, spreads well, was excellent in feeling of use, and was excellent in durability.

Example 3-6 Mascara (1) Isopar E 10.0% (2) Vinyl acetate emulsion 8.0 (3) Polyether-modified silicone * 4) 2.5 (4) Decamethylcyclopentapolysiloxane 25 .0 (5) Paraben 0.1 (6) Perfume 0.1 (7) Clay mineral 3.0 (8) Palmitic acid treated iron oxide black 3.1 (9) PMMA powder 5.0 (10) Non-aqueous polymer Dispersion 10.0 (11) Propylene glycol 3.0 (12) Purified water Residual amount * 4) In the general formula (3), a = 3, b = 0, m = 3
An integer of 0 and n = 5 was shown, and one with R = H was used. (Production method) (1) ~ (10) and (11), (12) is heated to 60 ℃, (1)
To (10), (11) and (12) were added with stirring to emulsify and then cooled to obtain a mascara. This mascara is 40 ℃, 25
The composition was stable at 0 ° C and 0 ° C for 1 month or longer, spreads well, has an excellent feeling in use, and has a long-lasting makeup.

Example 3-7 Pre-mechration (1) Liquid paraffin 8.0% (2) Polyether-modified silicone * 5) 2.5 (3) Non-aqueous polymer dispersion 7.0 (4) Decamethylcyclo Pentapolysiloxane 25.0 (5) Octyl methoxycinnamate 1.5 (6) Perfume 0.1 (7) Paraben 0.1 (8) Fluorine treated talc 2.0 (9) Spherical nylon powder 7.0 (10 ) 10 wt% ethyl alcohol aqueous solution Remaining amount (11) Polyethylene glycol 1.4 (12) Propylene glycol 8.0 * 5) In the general formula (3), a = 20, b = 24, m
= 300, n = 6, and R = H. (Production method) (1) to (9) and (10) to (12) are separately heated and stirred at 70 ° C, and (10) to (12) are added to (1) to (9) with stirring to emulsify. After that, it was cooled to produce a pre-make lotion. This lotion was stable at 37 ° C., 25 ° C., and 0 ° C. for 1 month or more, respectively. In addition, it had a good feeling of spread and was excellent in holding makeup. When the powdery foundation was applied repeatedly, the makeup lasting property was improved as compared with the case of applying without the lotion.

Example 3-8 Foundation (1) Decamethylpentacyclosiloxane 20.0% (2) Nonaqueous Polymer Dispersion 8.0 (3) Vitamin E Acetate 0.1 (4) Polyether Modified Silicone * 6 ) 3.5 (5) Bentonite 0.6 (6) Fluorine treated titanium dioxide 5.8 (7) Fluorine treated talc 4.2 (8) Fluorine treated iron oxide 2.1 (9) 15% by weight ethyl alcohol aqueous solution residue Amount (10) Propylene glycol 8.0 (11) Paraben 0.1 * 6) In the general formula (3), a = 10, b = 10, m
= 40, n = 10, and R = H. (Production method) (1) to (8) are stirred, (9) to (11) are heated and stirred at 70 ° C., and (9) to (11) are added to (1) to (8) with stirring. After emulsifying, a foundation was obtained. This foundation was stable at 37 ° C., 25 ° C. and 0 ° C. for 1 month or more, respectively. In addition, it had a good feeling of spread and excellent durability for makeup.

Example 3-9 Cream foundation (1) Decamethylpentacyclosiloxane 15.0% (2) Dimethylpolysiloxane 3.0 (3) Non-aqueous polymer dispersion 10.0 (4) Polyether-modified silicone * 7) 3.0 (5) Octyl methoxycinnamate 2.0 (6) Silicone treated titanium dioxide 8.0 (7) Silicone treated sericite 5.0 (8) Silicone treated iron oxide 2.0 (9) Silicone resin Spherical powder 6.0 (10) Butylene glycol 5.0 (11) 30 wt% ethyl alcohol aqueous solution Residual amount (12) Paraben 0.1 * 7) In the general formula (3), a = 5, b = 0, m = 2
An integer of 0 and n = 3 was shown, and one with R = H was used. (Production method) (1) to (9) are stirred, (10) to (12) are heated and stirred at 70 ° C., and (10) to (12) are added to (1) to (9) with stirring. After emulsifying, a foundation was obtained. This foundation was stable at 37 ° C., 25 ° C. and 0 ° C. for 1 month or more, respectively. Moreover, it spreads well and was excellent in holding makeup.

Example 3-10 Foundation (1) Dimethylpolysiloxane 20.0% (2) Non-aqueous polymer dispersion 12.0 (3) Squalane 5.0 (4) Behenyl alcohol 1.0 (5) Perfume 0.1. 1 (6) Paraben 0.1 (7) Octyl methoxycinnamate 2.5 (8) Polyether modified silicone * 8) 4.0 (9) Silicone treated titanium dioxide 5.8 (10) Silicone treated sericite 2. 2 (11) Silicone treated iron oxide 2.1 (12) Spherical silica 7.0 (13) Butylene glycol 5.0 (14) Purified water residual amount * 8) In the general formula (3), a = 8, b = 0, m = 5
An integer of 0 and n = 5 was shown, and one with R = H was used. (Production method) (1) to (12) and (13) to (14) are heated and stirred separately to homogenize, and (1) to (12) are added to (13) to (14) with stirring to emulsify. Then, it cooled and manufactured the foundation.
This foundation was stable at 40 ° C., 25 ° C., and 0 ° C. for 1 month or longer, spreads well, was excellent in the feeling of use, and was excellent in holding the makeup.

[0101]

EFFECTS OF THE INVENTION According to the present invention, it is possible to provide a makeup cosmetic which is excellent in both the feeling to use and the durability of makeup. In particular, it is possible to provide an excellent foundation which is excellent in freshness upon application and has no film feeling due to the non-aqueous polymer dispersion. Further, it is possible to provide a foundation having a good matte finish.

   ─────────────────────────────────────────────────── ─── Continued front page    (72) Inventor Yusuke Miura             2-2-1 Hayabuchi, Tsuzuki Ward, Yokohama City, Kanagawa Prefecture             Shiseido Research Center (Shin-Yokohama)             Within (72) Inventor Noto Ogura             2-2-1 Hayabuchi, Tsuzuki Ward, Yokohama City, Kanagawa Prefecture             Shiseido Research Center (Shin-Yokohama)             Within (72) Inventor Daisuke Aso             2-2-1 Hayabuchi, Tsuzuki Ward, Yokohama City, Kanagawa Prefecture             Shiseido Research Center (Shin-Yokohama)             Within (72) Inventor Sadaki Takada             2-2-1 Hayabuchi, Tsuzuki Ward, Yokohama City, Kanagawa Prefecture             Shiseido Research Center (Shin-Yokohama)             Within (72) Inventor Fumitaka Sato             2-2-1 Hayabuchi, Tsuzuki Ward, Yokohama City, Kanagawa Prefecture             Shiseido Research Center (Shin-Yokohama)             Within F-term (reference) 4C083 AB232 AB242 AB432 AB442                       AC012 AC022 AC072 AC122                       AC262 AC342 AC392 AC442                       AC482 AC542 AD072 AD091                       AD092 AD151 AD152 AD161                       AD162 AD171 AD172 AD662                       BB23 BB26 CC03 CC05 CC12                       CC14 DD31 EE01 EE06

Claims (6)

[Claims] 1. A non-aqueous polymer dispersion in which a polymer is dispersed in a volatile silicone, and an aqueous polymer emulsion, wherein the non-aqueous polymer dispersion is 1 to 20% (mass percentage) based on the total amount. The water-based polymer emulsion is 1 to the total amount.
20% (mass percentage), an emulsified makeup cosmetic. 2. A non-aqueous polymer dispersion in which a polymer is dispersed in volatile silicone, and a general formula (1),
(2), (3), (4), (5) or (6) containing one or more polyether-modified silicone represented by, and an inorganic powder, the non-aqueous polymer dispersion 1 ~ 40% (mass percentage), said polyether modified silicone is 0.5 to 20% (mass percentage), and inorganic powder is 3 to 60% (mass percentage), The makeup cosmetics characterized by the above-mentioned. [Chemical 1] (1) (In the formula, a is 2 to 50, b is 0 to 50, and m is 10 to 60.
0 and n show the integer of 1-100, and R shows an alkyl group or a hydrogen atom. ) [Chemical 2] (2) (In the formula, a is 2 to 80, b is 0 to 100, and m is 10 to 3.
00, n is 1 to 150, o is an integer of 1 to 50, and R
Represents an alkyl group having 6 to 26 carbon atoms, and R ′ represents an alkyl group or a hydrogen atom. ) [Chemical 3] (3) R = - (CH 2) 3 -O- (C 2 H 4 O) a (C 3 H 6 O) b H ( wherein, a is 1 to 40, b is 0 to 50, m is 1 ~ 30
0, n are 1 to 300, o is an integer of 1 to 300, and R
Represents an alkyl group having 6 to 26 carbon atoms. ) [Chemical 4] (4) R = - (CH 2) 3 -O- (C 2 H 4 O) a (C 3 H 6 O) b H ( wherein, a is 1 to 40, b is 0 to 50, m is 1 ~ 300
Indicates an integer. ) [Chemical 5] (5) (In the formula, a is 2 to 80, b is 0 to 100, and m is 1 to 30.
0 and n show the integer of 1-150, and R has 1-10 carbon atoms.
Represents an alkyl group or a hydrogen atom. R'is carbon number 1 to
10 alkylene groups are shown. ) [Chemical 6] (6) R = - (CH 2) 3 -O- (C 2 H 4 O) a (C 3 H 6 O) b H ( wherein, a is 1 to 40, b is 1 to 40, m is 1 ~ 80,
n is an integer of 1 to 50 and o is an integer of 1 to 80. ) 3. The emulsified makeup cosmetic composition according to claim 2, further comprising a spherical powder having a particle size of 1 to 50 μm, wherein the non-aqueous polymer dispersion is 1 to the total amount. 40% (mass percentage),
1 to 20% (mass percentage) of the spherical powder with respect to the total amount
And the said inorganic powder is 3-60% (mass percentage) with respect to the total amount, The makeup cosmetics characterized by the above-mentioned. 4. The makeup according to claim 1, 2 or 3, wherein the polymer is a polymer of acrylic acid ester or methacrylic acid ester or a copolymer of acrylic acid ester and methacrylic acid ester. Cosmetics. 5. The volatile silicone is one or more volatile silicones represented by the following general formula (1) or (2), wherein:
The makeup cosmetic according to 3 or 4. [Chemical 7] (7) (In the formula, n represents an integer of 3 to 7.) (8) (In the formula, m represents an integer of 0 to 5.) 6. The total content of the non-aqueous polymer dispersion and the aqueous polymer emulsion is 5 to 35.
% (Mass percentage) is the emulsified makeup cosmetic composition according to claim 1.