JP2002333642A - Homeotropic alignment liquid-crystalline composition, method for producing homeotropic alignment liquid crystal film and homeotropic alignment liquid crystal film - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a homeotropic alignment liquid-crystalline composition capable of forming a homeotropic alignment liquid crystal film excellent in durability on a substrate without using a homeotropic alignment layer. SOLUTION: The homeotropic alignment liquid-crystalline composition contains a side chain type liquid crystal polymer capable of forming a homeotropic alignment liquid crystal layer on a substrate on which the homeotropic alignment layer is not disposed and a photopolymerizable liquid crystal compound.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a homeotropically aligned liquid crystalline composition and a method for producing a homeotropically aligned liquid crystal film using the homeotropically aligned liquid crystalline composition. The present invention also relates to a homeotropically-aligned liquid crystal film obtained by the production method, and further to an optical film and a liquid crystal display device using the optical film. The homeotropic alignment liquid crystal film can be used alone or in combination with another film as an optical film such as a retardation film, a viewing angle compensation film, an optical compensation film, and an elliptically polarizing film.

[0002]

2. Description of the Related Art Homeotropic alignment of a liquid crystal compound is as follows.
This occurs when the molecular long axis of the liquid crystal phase is on average substantially perpendicular to the substrate forming the thin film (liquid crystal phase). Very few materials undergo spontaneous homeotropic alignment, and therefore vertical alignment agents are generally used to produce such alignment. As a liquid crystal compound that can be homeotropically aligned by a vertical alignment agent,
For example, a nematic liquid crystal compound is known. For an overview on the alignment technique for such liquid crystal compounds, see, for example, Chemical Review 44 (Surface Modification, edited by The Chemical Society of Japan, 156-16).
3).

Various organic or inorganic aligning agents are known as vertical aligning agents capable of homeotropically aligning the liquid crystal compound, but most of the commonly used aligning agents work effectively on a glass substrate. It is designed to be.

[0004] As such conventional organic alignment agents,
For example, lecithin, silane-based surfactant, n-octadecyltriethoxysilane, titanate-based surfactant,
Examples include a pyridinium salt-based polymer surfactant, hexadecyltrimethylammonium halide or a chromium complex. These organic aligning agents are dissolved in a suitable volatile solvent so that the active ingredient is in a very small amount (typically less than 1%) and then, for example, by spin coating or other well-known coating methods. After being applied on the substrate, the volatile solvent is evaporated to form a thin film of an organic alignment agent on the glass substrate. These organic alignment agents are characterized by having a polar end group considered to be attracted to the polar glass surface and a nonpolar long-chain alkyl chain arranged perpendicular to the glass surface. A homeotropic alignment is caused in the liquid crystal compound on such a surface.

[0005] As the inorganic alignment agent, for example,
SiO on the substrate_X Or In_Two O _Three / SnO_Two The vertical
It is known that the film is vapor-deposited at an angle.
Produces a meotropic alignment. Other, alkyl side
Polyimide films with chains can also be used in homeotropic
It is used as a pick alignment film.

However, all of the conventional alignment agents give homeotropic alignment to a liquid crystal compound only on a glass substrate, and are not very suitable for alignment on a substrate made of a polymer substance such as a plastic film or a plastic sheet. It does not work effectively. The surface of the substrate made of a polymeric material is presumed to have poor affinity for the polar end groups of the conventional aligning agents and, therefore, generally exhibits no or only a little homeotropic alignment. It only shows the orientation. Further, heat treatment at a high temperature is necessary for forming the polyimide film having an alkyl side chain, but only a few transparent plastic films can withstand baking of the polyimide alignment film and can be used for optical applications.

[0007]

On the other hand, the present applicant has proposed a monomer unit (a) containing a liquid crystal fragment side chain and a monomer unit (b) containing a non-liquid crystal fragment side chain. It has been found that a liquid crystal polymer can be homeotropically aligned on a substrate without using a vertical alignment film, thereby producing a homeotropically aligned liquid crystal film (Japanese Patent Application No. 2000-370978). However, since these side chain type liquid crystal polymers form a film on a substrate without using a vertical alignment film, the Tg of the liquid crystal film is designed to be low. It is desired that these liquid crystal films have improved durability which can be used for applications such as liquid crystal displays.

The present invention provides a homeotropically oriented liquid crystal composition capable of forming a durable homeotropically oriented liquid crystal film on a substrate without using a vertical alignment film. It is an object of the present invention to provide a method for producing a homeotropically aligned liquid crystal film using a conductive composition, and to provide a homeotropically aligned liquid crystal film obtained by the above production method. It is still another object of the present invention to provide an optical film having a homeotropically-aligned liquid crystal film layer without a vertical alignment film on a substrate, and a liquid crystal display device using the optical film.

[0009]

Means for Solving the Problems The present inventors have conducted intensive studies to solve the above-mentioned problems, and as a result, have found that the above-mentioned objects can be achieved by the following homeotropically aligned liquid crystalline composition, thereby completing the present invention. Reached.

That is, the present invention is characterized in that it comprises a side chain type liquid crystal polymer capable of forming a homeotropic alignment liquid crystal layer on a substrate having no vertical alignment film, and a photopolymerizable liquid crystal compound. A homeotropically aligned liquid crystalline composition.

The photopolymerizable liquid crystal compound contained in the homeotropically aligned liquid crystalline composition of the present invention in addition to the side chain type liquid crystal polymer is converted into a liquid crystal state by heat treatment, for example, by expressing a nematic liquid crystal layer to form a side chain type liquid crystal compound. Homeotropic alignment can be performed together with the liquid crystal polymer, and then the durability of the homeotropically aligned liquid crystal film can be improved by polymerizing or crosslinking the photopolymerizable liquid crystal compound.

In the homeotropically aligned liquid crystalline composition, the side chain type liquid crystal polymer contains a monomer unit (a) containing a liquid crystalline fragment side chain and a monomer unit (b) containing a non-liquid crystalline fragment side chain. It is preferably a side chain type liquid crystal polymer.

The side chain type liquid crystal polymer can realize homeotropic alignment of the liquid crystal polymer without using a vertical alignment film. The side chain type liquid crystal polymer is a monomer unit containing a non-liquid crystal fragment side chain having an alkyl chain or the like in addition to the monomer unit (a) containing a liquid crystal fragment side chain of a normal side chain type liquid crystal polymer. (B), by the action of the monomer unit (b) containing a non-liquid crystalline fragment side chain, the liquid crystal is brought into a liquid crystal state by, for example, heat treatment without using a vertical alignment film, and a nematic liquid crystal phase is developed. It is presumed that the tropic orientation was shown.

Further, the present invention provides a method wherein the above-mentioned homeotropically-aligned liquid crystalline composition is coated on a substrate having no vertical alignment film, and the liquid-crystalline composition is further homeotropically aligned in a liquid crystal state. The present invention relates to a method for producing a homeotropically-aligned liquid crystal film, which comprises irradiating light after fixing while maintaining an aligned state.

After the liquid crystalline composition is homeotropically aligned without using a vertical alignment film, heat is removed to vitrify the liquid crystal composition, and the homeotropically aligned liquid crystal polymer layer is fixed. By polymerizing or crosslinking the hydrophilic liquid crystal compound, a homeotropically aligned liquid crystal film having excellent durability can be obtained.

In the method for producing a homeotropically aligned liquid crystal film, the substrate may be made of various materials such as a polymer substance, a glass substrate, and a metal. Also, polymeric substances are used as plastic sheets or plastic films. The type of substrate used in the production method of the present invention is not limited, and a glass substrate, a polymer substance, and a metal can be used without any particular limitation, and the polymer substance can be used as a plastic sheet or a plastic film.

The present invention also relates to a homeotropically-aligned liquid crystal film obtained by the above production method.

The present invention also provides an optical film comprising a homeotropically-aligned liquid crystal composition provided with a homeotropically-aligned liquid crystal composition layer on which a homeotropically-aligned liquid crystalline composition is homeotropically aligned and fixed on a substrate on which no vertical alignment film is provided. About.

Further, the present invention relates to a liquid crystal display device using the optical film.

[0020]

DESCRIPTION OF THE PREFERRED EMBODIMENTS In the present invention, examples of the liquid crystal polymer capable of forming a homeotropically aligned liquid crystal layer include a monomer unit (a) containing a liquid crystal fragment side chain and a monomer containing a non-liquid crystal fragment side chain. A side chain type liquid crystal polymer containing the unit (b) is used.

The monomer unit (a) has a side chain having nematic liquid crystallinity and has, for example, the general formula (a):

Embedded image (However, R ¹ is a hydrogen atom or a methyl group, a is 1 to
A positive integer of 6, X ¹ represents a —CO ₂ — group or —OCO—
R ² is a cyano group, an alkoxy group having 1 to 6 carbon atoms,
A fluoro group or an alkyl group having 1 to 6 carbon atoms, b and c each represent an integer of 1 or 2; )).

The monomer unit (b) has a linear side chain. For example, the monomer unit (b) has the general formula (b):

Embedded image (However, R ³ is a hydrogen atom or a methyl group, R ⁴ is an alkyl group having 1 to 22 carbon atoms, a fluoroalkyl group having 1 to 22 carbon atoms, or a general formula (c):

Embedded image However, d is a positive integer of 1 to 6, and R ⁵ is 1 to 6 carbon atoms.
Represents an alkyl group. )).

The ratio of the monomer unit (a) to the monomer unit (b) is not particularly limited, and varies depending on the type of the monomer unit. Since the liquid crystal polymer does not show liquid crystal monodomain alignment,
It is preferable that (b) / {(a) 10 (b)} = 0.01 to 0.8 (molar ratio). In particular, it is more preferably 0.1 to 0.5.

The weight average molecular weight of the side chain type liquid crystal polymer is preferably from 2,000 to 100,000. By adjusting the weight average molecular weight in such a range, performance as a liquid crystal polymer is exhibited. If the weight average molecular weight of the side chain type liquid crystal polymer is too small, the film formability of the alignment layer tends to be poor. Therefore, the weight average molecular weight is more preferably at least 25,000. On the other hand, if the weight average molecular weight is too large, the alignment as a liquid crystal tends to be poor, and it is difficult to form a uniform alignment state. Therefore, the weight average molecular weight is more preferably 50,000 or less.

The side chain type liquid crystal polymer can be prepared by copolymerizing an acrylic monomer or a methacrylic monomer corresponding to the monomer units (a) and (b). The monomers corresponding to the monomer units (a) and (b) can be synthesized by a known method. The preparation of the copolymer can be carried out in accordance with a conventional polymerization system of an acrylic monomer such as a radical polymerization system, a cation polymerization system, or an anion polymerization system. When the radical polymerization method is applied, various polymerization initiators can be used, but the decomposition temperature of azobisisobutyronitrile or benzoyl peroxide is not high, and decomposes at an intermediate temperature that is not low. Are preferably used.

The photopolymerizable liquid crystal compound is a liquid crystal compound having at least one unsaturated double bond such as an acryloyl group or a methacryloyl group as a photopolymerizable functional group. Used.
Examples of such a photopolymerizable liquid crystal compound include acrylate and methacrylate serving as the monomer unit (a). As the photopolymerizable liquid crystal compound, a compound having two or more photopolymerizable functional groups is preferable for improving durability. As such a photopolymerizable liquid crystal compound, for example,
Formula 4:

Embedded image (Wherein, R represents a hydrogen atom or a methyl group, and A and D each independently represent a 1,4-phenylene group or a 1,4-
X is each independently -COO.
—, —OCO— or —O—, wherein B is 1,4-phenylene, 1,4-cyclohexylene, 4,4′-
A biphenylene group or a 4,4′-bicyclohexylene group, and g and h each independently represent an integer of 2 to 6. )) And the like.

The ratio of the photopolymerizable liquid crystal compound to the side chain type liquid crystal polymer in the liquid crystalline composition is not particularly limited, and is appropriately determined in consideration of the durability of the obtained homeotropically aligned liquid crystal film. Usually, photopolymerizable liquid crystal compound: side chain type liquid crystal polymer (weight ratio) is preferably about 0.1: 1 to 30: 1, particularly preferably 0.5: 1 to 20: 1.
Further, the ratio is preferably from 1: 1 to 10: 1.

The liquid crystalline composition usually contains a photopolymerization initiator. Various photopolymerization initiators can be used without particular limitation. As the photopolymerization initiator, for example, Irgacure (Ir) manufactured by Ciba Specialty Chemicals, Inc.
gacure) 907, 184, 651, 369
And the like. The amount of the photopolymerization initiator added, in consideration of the type of the photopolymerized liquid crystal compound, the mixing ratio of the liquid crystal composition, and the like,
It is added to an extent that does not disturb the homeotropic alignment of the liquid crystalline composition. Usually, the amount is preferably about 0.5 to 30 parts by weight based on 100 parts by weight of the photopolymerizable liquid crystal compound. Especially 3
~ 15 parts by weight are preferred.

The substrate on which the liquid crystal composition is applied may be any of a glass substrate, a metal foil, a plastic sheet or a plastic film. The thickness of the substrate is usually about 10 to 1000 μm.

The plastic film is not particularly limited as long as it does not change at the temperature at which it is oriented. Examples thereof include polyester polymers such as polyethylene terephthalate and polyethylene naphthalate, diacetyl cellulose, and the like.
Examples of the film include films made of transparent polymers such as cellulose polymers such as triacetyl cellulose, polycarbonate polymers, and acrylic polymers such as polymethyl methacrylate. In addition, polystyrene, styrene-based polymers such as acrylonitrile-styrene copolymer, polyethylene, polypropylene, polyolefin having a cyclic or norbornene structure, olefin-based polymers such as ethylene-propylene copolymer, vinyl chloride-based polymer,
A film made of a transparent polymer such as an amide polymer such as nylon or aromatic polyamide can also be used. Furthermore, imide polymers, sulfone polymers, polyether sulfone polymers, polyether ether ketone polymers, polyphenylene sulfide polymers, vinyl alcohol polymers, vinylidene chloride polymers, vinyl butyral polymers, arylate polymers, polyoxymethylene polymers A film made of a transparent polymer such as a polymer, an epoxy-based polymer, or a blend of the above polymers may also be used. Among these, a plastic film having a high hydrogen bonding property is preferable.

The metal film is, for example, a film formed of aluminum or the like.

As the plastic film, in particular, Zeonor (trade name, manufactured by Nippon Zeon Co., Ltd.), Zeonex (trade name, manufactured by Nippon Zeon Co., Ltd.), Arton (trade name, trade name,
A plastic film made of a polymer substance having a norbornene structure, such as JSR Corporation, has excellent optical characteristics. Since these polymer substances (plastic films) have very small optical anisotropy, the oriented liquid crystal film layer of the liquid crystalline composition formed on the plastic film transfers the oriented liquid crystal film layer to another plastic film. Instead, it can be used as it is as a homeotropic alignment retardation film for an optical film such as for optical compensation of a liquid crystal display.
Further, with respect to the oriented liquid crystal film layer of the liquid crystalline composition formed on a metal film such as a plastic film or aluminum foil having optical anisotropy, after the liquid crystalline composition is formed into an oriented liquid crystal film, a norbornene structure is formed. By transferring directly or through a pressure-sensitive adhesive or adhesive onto a transparent and optically anisotropic small plastic film such as a film or cellulose triacetate having,
It can be used for optical films such as optical compensation films.

The liquid crystal composition is applied to a substrate by a solution coating method using a solution obtained by dissolving the liquid crystal composition in a solvent or a method of melting and applying the liquid crystal composition by melting. Among them, a method of applying a liquid crystal composition solution on a supporting substrate by a solution coating method is preferable.

The solvent used for preparing the solution varies depending on the type of the liquid crystal composition and the substrate and cannot be specified unconditionally. Halogenated hydrocarbons, phenols such as phenol and parachlorophenol, benzene, toluene, xylene,
Aromatic hydrocarbons such as methoxybenzene and 1,2-dimethoxybenzene, and others, acetone, ethyl acetate, te
rt-butyl alcohol, glycerin, ethylene glycol, triethylene glycol, ethylene bricol monomethyl ether, diethylene glycol dimethyl ether, ethyl cellosolve, butyl cellosolve, 2-pyrrolidone, N-methyl-2-pyrrolidone, pyridine, triethylamine, tetrahydrofuran, dimethyl Formamide, dimethylacetamide, dimethylsulfoxide,
Acetonitrile, butyronitrile, carbon disulfide and the like can be used. The concentration of the solution cannot be determined unconditionally because it depends on the solubility of the liquid crystal composition to be used and the thickness of the finally oriented liquid crystal film, but is usually 3 to 50% by weight, preferably 7 to 30% by weight. % Range.

The thickness of the homeotropically-aligned liquid crystal film layer composed of the coated liquid crystalline composition is 1 to 10 μm.
It is preferable to set the degree. In particular, when it is necessary to precisely control the thickness of the homeotropic alignment liquid crystal film, since the thickness is substantially determined at the stage of coating on the substrate,
Special attention must be paid to the control of the concentration of the solution, the thickness of the coating film, and the like.

A method for applying a liquid crystalline composition solution adjusted to a desired concentration using the above-mentioned solvent on a substrate is as follows.
For example, a spin coating method, a bar coating method, or the like can be employed. After coating, the solvent is removed to form a liquid crystal composition layer on the substrate. The conditions for removing the solvent are not particularly limited as long as the solvent can be substantially removed and the liquid crystal composition layer does not flow or even falls off. Usually, the solvent is removed by using drying at room temperature, drying in a drying oven, heating on a hot plate, or the like.

Next, the liquid crystalline composition layer formed on the supporting substrate is brought into a liquid crystal state, and is homeotropically aligned.
For example, heat treatment is performed so that the liquid crystalline composition has a liquid crystal temperature range, and the liquid crystal composition is homeotropically aligned in a liquid crystal state. The heat treatment can be performed by a method similar to the above-described drying method. The heat treatment temperature varies depending on the type of the liquid crystalline composition and the type of the supporting substrate to be used, and cannot be unconditionally determined, but is usually from 60 to 300 ° C., preferably from 70 to 200 ° C.
Perform in the range of ° C. The heat treatment time varies depending on the heat treatment temperature and the type of liquid crystal composition or substrate to be used, and cannot be specified unconditionally. However, it is generally selected in the range of 10 seconds to 2 hours, preferably 20 seconds to 30 minutes. If the time is shorter than 10 seconds, homeotropic alignment may not be sufficiently formed.

After the heat treatment, a cooling operation is performed. As the cooling operation, the homeotropic alignment liquid crystal layer after the heat treatment is
It can be carried out by taking out from the heating atmosphere in the heat treatment operation to room temperature. Also, forced cooling such as air cooling or water cooling may be performed. The alignment of the homeotropic liquid crystal alignment layer of the liquid crystal composition is fixed by cooling the liquid crystal composition to a temperature lower than the glass transition temperature of the liquid crystal polymer.

The homeotropic liquid crystal alignment layer thus fixed is irradiated with light to polymerize or crosslink the photopolymerizable liquid crystal compound, thereby fixing the photopolymerizable liquid crystal compound, thereby improving the durability of the homeotropic liquid crystal compound. A tropically aligned liquid crystal film is obtained. Light irradiation is performed by, for example, ultraviolet irradiation. UV irradiation conditions, to promote the reaction sufficiently,
It is preferable to be in an inert gas atmosphere. Usually about 8
A high-pressure mercury ultraviolet lamp having an illuminance of 0 to 160 mW / cm ² is typically used. Other types of lamps such as metahalide UV lamps and incandescent tubes can also be used. It should be noted that the surface temperature of the liquid h layer at the time of irradiating ultraviolet rays is appropriately adjusted by, for example, a cold mirror, water cooling or other cooling treatment, or increasing the line speed so that the liquid h layer surface temperature falls within the liquid crystal temperature range.

In this way, a thin film of the liquid crystalline composition is formed, and the liquid crystal composition is fixed while maintaining the orientation, whereby a homeotropically aligned liquid crystal film is obtained.
The alignment liquid crystal layer has molecules aligned in the same direction. Therefore, it is well known that the freezing or stabilization of the orientation vector of this oriented liquid crystal layer and the preservation of its anisotropic physical properties are achieved, and such thin films have been confirmed for their optical properties and are used in various applications. Is done. The alignment liquid crystal layer is a thin film having a uniaxial positive birefringence.

The orientation of the homeotropically aligned liquid crystal layer obtained as described above can be quantified by measuring the optical phase difference of the liquid crystal layer at an angle inclined from normal incidence. In the case of homeotropically aligned liquid crystal films, this retardation value is symmetric about normal incidence. There are several methods available for measuring the optical phase difference,
For example, an automatic birefringence measuring device (Oak) and a polarizing microscope (Olympus) can be used. This homeotropic alignment liquid crystal film looks black between the crossed Nicol polarizers.

The homeotropically aligned liquid crystal film thus obtained may be used by peeling it from the substrate, or may be used as it is as an alignment liquid crystal layer formed on the substrate without peeling.

The homeotropically aligned liquid crystal film is used as an optical film. For example, when a homeotropically-aligned liquid crystal film is produced using a uniaxially-aligned retardation film as a base material, a wide-viewing-angle retardation film is obtained. The characteristics, particularly the viewing angle characteristics, can be significantly improved.

[0044]

EXAMPLES One embodiment of the present invention will be described below with reference to examples, but it is needless to say that the present invention is not limited to the examples.

Embodiment 1

Embedded image In the above formula (n = 35 in the formula, the mole% of the monomer unit is shown, and is represented by a block for convenience.
12.5 parts by weight of a side chain type liquid crystal polymer having a weight average molecular weight of 5,000) and a photopolymerizable liquid crystal compound exhibiting a nematic liquid crystal layer (Paliocolor LC2 manufactured by BASF).
42) A solution obtained by dissolving 12.5 parts by weight of a photopolymerization initiator (Irgacure 907, 5% by weight of a photopolymerizable liquid crystal compound, 5% by weight of a photopolymerizable liquid crystal compound) in 75 parts by weight of cyclohexanone was dissolved in a norbornene-based polymer (trade name). A plastic film (20 μm) using ZEONEX, ZEON CORPORATION as a polymer material was applied by spin coating. Then, the liquid crystal layer is heated at 130 ° C. for 1 minute, and then cooled to room temperature at a stretch, whereby the liquid crystal layer is homeotropically aligned and vitrified while maintaining the alignment.
m) was immobilized. Further, a homeotropic alignment liquid crystal film was produced by irradiating the fixed homeotropic alignment liquid crystal layer with ultraviolet rays.

(Homeotropic Alignment) When the sample (homeotropically aligned liquid crystal film with substrate) was observed from a direction perpendicular to the film surface by a polarizing microscope with crossed Nicols, nothing was seen from the front. Was. This confirmed the homeotropic alignment. That is, it was found that no optical phase difference occurred. By tilting this film, light enters obliquely,
Similarly, when observed by crossed Nicols, light transmission was observed. The optical retardation of the film was measured by an automatic birefringence measuring device. 30 when measured from left 30 °
nm.

(Durability test) A sample (homeotropic alignment liquid crystal film with substrate) was placed in a drying oven at 90 ° C.
Heat resistance test for 20 hours, wet heat test for 60 hours at 60 ° C./90% RH, and homeotropic alignment liquid crystal film for 2 hours in a drying oven at 90 ° C. The three kinds of heat adhesion test were performed, and the physical properties before and after introduction were compared. No change was observed in any of the three tests before and after the test.

Example 2 In Example 1, a norbornene-based polymer (trade name: Arton,
A homeotropic alignment liquid crystal film was produced in the same manner as in Example 1 except that JSR (manufactured by JSR Corporation) was used. Also,
The homeotropic orientation of the sample was confirmed in the same manner as in Example 1. Also, no change was observed before and after the tests in any of the three durability tests.

Example 3 A homeotropically-aligned liquid crystal film was produced in the same manner as in Example 1 except that a glass substrate (1 mm) was used instead of the plastic film as the substrate. Further, in the same manner as in Example 1, the homeotropic orientation of the sample was confirmed. Also, no change was observed before and after the tests in any of the three durability tests.

Example 4 In Example 1, the amount of the side-chain type liquid crystal polymer was changed to 2.
5 parts by weight, the amount of the photopolymerizable liquid crystal compound was changed to 22.5 parts by weight, and a homeotropically aligned liquid crystal was prepared in the same manner as in Example 1 except that a glass substrate (1 mm) was used instead of a plastic film as a substrate. A film was prepared.
Further, in the same manner as in Example 1, the homeotropic orientation of the sample was confirmed. Also, no change was observed before and after the tests in any of the three durability tests.

Reference Example 1 Homeotropic alignment was performed in the same manner as in Example 1 except that the photopolymerizable liquid crystal compound and the photopolymerization initiator were not used, and only 25 parts by weight of the side chain type liquid crystal polymer was used. A liquid crystal film was produced. Further, in the same manner as in Example 1, the homeotropic orientation of the sample was confirmed. However, in any of the three types of durability tests, changes such as disorder in orientation were confirmed after the test.

 ──────────────────────────────────────────────────続 き Continued on the front page (72) Hidesaku Nakano 1-1-2 Shimohozumi, Ibaraki-shi, Osaka Nitto Denko Corporation (72) Inventor Takufumi Uejo 1-1-2 Shimohozumi, Ibaraki-shi, Osaka No. Nitto Denko Corporation (72) Inventor Shu Mochizuki 1-2-1, Shimohozumi, Ibaraki-shi, Osaka Nitto Denko Corporation F-term (reference) 2H049 BA04 BA06 BA42 BC02 BC05 BC22 2H088 FA29 GA01 HA01 HA15 JA13 MA07 2H090 JB02 JB03 MA01 4H027 BA01 BA13 BD12 BE01

Claims (7)

[Claims] 1. A homeotropic alignment comprising a side chain type liquid crystal polymer capable of forming a homeotropic alignment liquid crystal layer on a substrate having no vertical alignment film, and a photopolymerizable liquid crystal compound. Liquid crystalline composition. 2. The side chain type liquid crystal polymer is a side chain type liquid crystal polymer containing a monomer unit (a) containing a liquid crystal fragment side chain and a monomer unit (b) containing a non-liquid crystal fragment side chain. The homeotropically aligned liquid crystalline composition according to claim 1, wherein: 3. A homeotropically-aligned liquid crystalline composition according to claim 1 is coated on a substrate on which no vertical alignment film is provided, and the liquid-crystalline composition is further homeotropically aligned in a liquid crystal state. A method for producing a homeotropically-aligned liquid crystal film, comprising fixing the liquid crystal while maintaining its alignment state, and irradiating light. 4. The method according to claim 3, wherein the material of the substrate is a polymer material, glass or metal. 5. A homeotropically-aligned liquid crystal film obtained by the production method according to claim 3. 6. A homeotropically aligned liquid crystal film layer in which the homeotropically aligned liquid crystalline composition according to claim 1 or 2 is homeotropically aligned and fixed on a substrate on which no vertical alignment film is provided. Optical film. 7. A liquid crystal display device to which the optical film according to claim 6 is applied.