JP2002256283A - Detergent composition - Google Patents

Abstract

(57) [Summary] [Solution] (A) General formula (1) Embedded image [R¹Is C₆~ C_{twenty four}A linear or branched alkyl group or
An alkenyl group; ^TwoAnd R^FourIs C₁~ C₆Archi
Or-(AO)_nH (A: C_Two~ C_FourAn alkylene group of n:
The number of 1 to 6, n A's may be the same or different,
Represents optional), and R^ThreeIs C₁~ C₆An alkyl group, ben
Zyl group or-(A'O)_mH (A ': C_Two~ C_FourAn alkylene group of
m: the number of 1 to 6, m A's may be the same or different
And the sequence is arbitrary), and X^-Represents an anion. ]
An ether type cationic surfactant represented by:
(B) an anionic surfactant, a nonionic surfactant and
Detergent containing at least one selected from amphoteric surfactants
Composition. [Effect] Excellent foam quality during washing, good use for skin and hair
It can provide a feeling of use and a sufficient conditioning effect.
And good stability at low temperatures.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cleaning agent which is excellent in foam quality at the time of washing, can give a good feeling of use and a sufficient conditioning effect to skin and hair, and has good stability at low temperatures. Composition.

[0002]

2. Description of the Related Art A cleaning composition is formulated with a conditioning agent such as a quaternary ammonium salt for the purpose of improving the usability. In particular, quaternary ammonium salts are used in hair cleansing agents for the purpose of improving the smoothness and smoothness of the hair, such as combing and fingering. Specific examples include behenyltrimethylammonium chloride and stearyltrimethylammonium chloride. However, those using quaternary ammonium salts
There is a limitation on the formulation, and there is a problem that foaming quality and stability at low temperatures are reduced when an amount that imparts sufficient smoothness to hair is added.

[0003] On the other hand, quaternary ammonium salts are sometimes added to a cleansing agent other than the hair for the purpose of improving the usability on the skin. Again, in this case,
As described above, there is a problem that the foam quality and stability are reduced.

[0004]

DISCLOSURE OF THE INVENTION The present invention provides a good feeling of use and a sufficient conditioning effect on skin and hair without impairing foam quality and stability at low temperatures while blending a quaternary ammonium salt. It is an object of the present invention to provide a cleaning composition that can be used.

[0005]

Means for Solving the Problems The present inventors have found that the use of a specific ether type cationic surfactant as a quaternary ammonium salt can provide a detergent composition satisfying the above requirements. Was.

That is, the present invention provides the following components (A) and (B) (A)

[0007]

Embedded image

[Wherein, R ¹ represents a linear or branched alkyl group or alkenyl group having 6 to 24 carbon atoms, and R ² and R ⁴ represent an alkyl group having 1 to 6 carbon atoms or-(AO ) _n H (A
Represents an alkylene group having 2 to 4 carbon atoms, n represents a number of 1 to 6, n A's may be the same or different, and the sequence is arbitrary. R ³ represents an alkyl group having 1 to 6 carbon atoms, a benzyl group or — (A′O) _m H (A ′ has 2 to 6 carbon atoms)
4 represents an alkylene group, m represents a number of 1 to 6, m A's may be the same or different, and the sequence is arbitrary. ) And X ^- represents an anion. (B) a detergent composition containing at least one selected from an anionic surfactant, a nonionic surfactant and an amphoteric surfactant; Things.

[0009]

BEST MODE FOR CARRYING OUT THE INVENTION In the general formula (1) representing the ether type cationic surfactant of the component (A), preferred substituents are as follows.

[0010] As R ¹ , the number of carbon atoms is 12 to 22, especially 16 to 18
And a linear alkyl group is preferred.

R ² and R ⁴ are preferably an alkyl group having 1 to 6 carbon atoms and — (CH ₂ CH ₂ O) _n H (n is 1 to 6).
3, particularly preferably 1), more preferably a methyl group and an ethyl group, particularly preferably a methyl group.

R ³ is preferably a methyl group, an ethyl group and a benzyl group, more preferably a methyl group and an ethyl group, particularly preferably a methyl group.

[0013] X ^- is the halide ion include ethyl sulfate ion or the like, in particular a chloride ion.

The ether type cationic surfactant (1) is
For example, it can be produced according to the following reaction formula.

[0015]

Embedded image

Wherein R ¹ , R ² , R ³ and R ⁴ have the same meaning as described above. ]

That is, first, alcohol (2) is reacted with acrylonitrile in the presence of an alkali metal hydroxide to form alkoxypropionitrile (3), and then hydrogenated using a hydrogenation catalyst to obtain alkoxypropylamine. Obtain (4). Then the alkoxypropylamine
(4) is reacted with a tertiary agent (formaldehyde or a combination of alkyl aldehyde having 2 to 6 carbon atoms and hydrogen, or alkylene oxide having 2 to 4 carbon atoms) in the presence of a catalyst to give a tertiary compound. By obtaining an amine (5) and reacting it with a quaternizing agent in a suitable solvent, an ether-type cationic surfactant (1) can be obtained.

(2) → (3) In the reaction of alcohol (2) with acrylonitrile,
The amount of acrylonitrile used is based on alcohol (2)
0.9 to 1.2 equivalents, especially 0.95 to 1.1 equivalents are preferred. Also,
Examples of the alkali metal hydroxide include lithium hydroxide, sodium hydroxide, potassium hydroxide, and the like.The amount of the alkali metal hydroxide used is such that removal of the alkali metal hydroxide is not required after the reaction, and alkoxypropionitrile (3 In terms of purity), at least 0.01 parts by weight based on 100 parts by weight of alcohol (2)
Less than 0.05 part by weight, especially 0.01 to 0.04 part by weight is preferred.

The reaction temperature in this step is 45-70 ° C., especially 50-70 ° C.
~ 65 ° C is preferred. The reaction time is preferably 2 to 5 hours.

(3) → (4) In the hydrogenation reaction of alkoxypropionitrile (3), if the amount of the alkali metal hydroxide used in the preceding step is within the above range, the reaction product is used as it is. Can be. As the hydrogenation catalyst, a cobalt-based catalyst, a nickel-based catalyst, a copper-based catalyst, a noble metal-based catalyst, and the like, preferably
Catalysts based on Ni, Co and / or Ru, more preferably Raney-type catalysts, are used. Further, those in which these metals are supported on a carrier can also be used. The amount of the hydrogenation catalyst to be used is preferably 0.05 to 5 parts by weight, particularly preferably 0.1 to 3 parts by weight, per 100 parts by weight of the alkoxypropionitrile (3).

This step is preferably performed at a hydrogen pressure of 0.3 to 10 MPa. The reaction temperature is preferably from 50 to 250 ° C, particularly preferably from 70 to 180 ° C. The reaction time is preferably about 2 to 15 hours.

In this step, an alkali metal hydroxide may be used, and the amount of the alkali metal hydroxide used is 100% of that of nitrile (3).
0.4 parts by weight or less, especially 0.2 parts by weight or less, based on parts by weight. Further, the reaction may be carried out by adding water, the amount of which is 0.5 to 20 parts by weight per 100 parts by weight of nitrile (3).
Part by weight, especially 3 to 15 parts by weight is preferred. In this case, the alkali metal hydroxide is preferably dissolved in water before use.

Alkoxypropylamine (4) is described in J. Am.
Chem. Soc., 57, 1505 (1945), UK Patent No. 869405, JP-A-48-103505, etc. From the viewpoint of rate, the above method is preferred.

The obtained amine (4) can be used as a raw material in the next step as a reaction product, but is preferably purified by a method such as distillation.

(4) → (5) (Tertiformation Step) When an aldehyde and hydrogen are used as the tertiary agent, the ether tertiary amine (5) is replaced with alkoxypropylamine (4)
Can be produced by a reductive alkylation reaction such as the so-called reductive methylation reaction. Examples of the aldehyde include formaldehyde, acetaldehyde, propanal, butanal, pentanal, hexanal, 2-methylpentanal, and other alkyl aldehydes having a total of 2 to 6 carbon atoms. Of these, formaldehyde and acetaldehyde are preferred. Here, as the formaldehyde, an aqueous solution (such as formalin) or a polymer such as paraformaldehyde can be used. The amount of the aldehyde to be used is 1.0 to 1.0 with respect to one active hydrogen group of the nitrogen of the amine (4).
5 times mol, especially 1.0 to 1.2 times mol is preferable.

As the catalyst, an element selected from Pd, Pt, Rh, Re and Ru, in particular, a metal catalyst containing Pd is preferable.
As the metal catalyst, a powder of the above metal may be used, but it is preferable to use the metal supported on a carrier.
The supported amount of the metal is 0.01 to 20% by weight, particularly 0.1% by weight of the total weight of the catalyst.
1-10% by weight is preferred. As the catalyst, JP-A-64-1675
As described in Patent Document 1, a Raney nickel catalyst adjusted to be acidic with an organic acid can be used, but from the viewpoint of easy separation of the compound (5) from the reaction product, the metal catalyst is used. It is preferred to use. The amount of the metal catalyst varies depending on the kind of the amine (4), the reaction conditions, and the like.
2,000 ppm, especially 5-500 ppm, is preferred.

This reaction is usually carried out in hydrogen gas in the presence of an amine (4).
And supplying the aldehyde to the reaction system charged with the metal catalyst. The hydrogen pressure (gauge pressure) is preferably 0.5 MPa or more, particularly preferably 1 to 10 MPa. Reaction temperature is 60-200
C., especially 110-180.degree. The addition of the aldehyde to the reaction system may be continuous or intermittent, and the addition rate may be adjusted to the reaction rate, but it is preferable to continuously add the aldehyde at a constant rate. This addition time is substantially the reaction time, usually from 1 to 10 hours. After completion of the supply of the aldehyde, aging is preferably performed for 10 to 60 minutes.

When R ² and R ⁴ are — (AO) _n H, an alkylene oxide having 2 to 4 carbon atoms is used as a tertiary agent, and a normal alkylene oxide is added to the amine (4). Tertiary.

Thus, various tertiary amines (5)
Is obtained. The obtained tertiary amine (5) can be used as a raw material in the next step as it is as a reactant, but is preferably purified by a method such as distillation.

(5) → (1) As the quaternizing agent used for quaternizing the tertiary amine (5), for example, alkyl halide having 1 to 6 carbon atoms in the alkyl group, dialkyl sulfate, etc. Is mentioned. After the reaction, the acid salt may be further neutralized with a suitable solvent using hydrogen halide, sulfuric acid, organic acid or the like. Further, a quaternized product can be obtained by adding an alkylene oxide having 2 to 4 carbon atoms to the acid salt of the tertiary amine (5).

The obtained ether type cationic surfactant
(1) can be used as it is as a compounding component of the product of the present invention, but it can also be used after being purified by ordinary purification means. Ether type cationic surfactant (1)
Can be produced by other methods, but is preferably produced by the method described above.

Component (B) is selected from anionic surfactants, nonionic surfactants and amphoteric surfactants.
Examples of the at least one kind of surfactant include the following.

The anionic surfactants are preferably sulfates, sulfonates, carboxylates, phosphates and amino acids, and are, for example, alkyl sulfates. , Polyoxyalkylene alkyl ether sulfate, polyoxyalkylene alkenyl ether sulfate, sulfosuccinate alkyl ester salt, polyoxyalkylene sulfosuccinate alkyl ester salt, polyoxyalkylene alkyl phenyl ether sulfate, alkane sulfonate,
Acyl isethionates, acyl methyl taurates, higher fatty acid salts, polyoxyalkylene alkyl ether acetates, alkyl phosphates, polyoxyalkylene alkyl ether phosphates, acyl glutamates, alanine derivatives, glycine derivatives, arginine derivatives, etc. No.

Of these, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkenyl ether sulfate, alkyl sulfate, acyl isethionate,
Acyl methyl taurate, higher fatty acid salt, polyoxyalkylene alkyl ether acetate, alkyl phosphate,
Polyoxyalkylene alkyl ether phosphate, acylglutamate and alkylalanine derivatives are preferred, and those represented by the general formula (6) or (7) are particularly preferred.

R ⁵ O (CH ₂ CH ₂ O) _p SO ₃ M (6) R ⁶ OSO ₃ M (7)

[Wherein, R ⁵ represents an alkyl group or alkenyl group having 10 to 18 carbon atoms, R ⁶ represents an alkyl group having 10 to 18 carbon atoms, M represents an alkali metal, an alkaline earth metal, ammonium, Represents an alkanolamine or a basic amino acid;
Indicates the number of ]

Examples of the nonionic surfactant include polyoxyalkylene sorbitan fatty acid esters, polyoxyalkylene sorbite fatty acid esters, polyoxyalkylene glycerin fatty acid esters, polyoxyalkylene fatty acid esters, polyoxyalkylene alkyl ethers, Examples include polyoxyalkylene alkyl phenyl ethers, polyoxyalkylene (hardened) castor oils, sucrose fatty acid esters, polyglycerin alkyl ethers, polyglycerin fatty acid esters, fatty acid alkanolamides, alkyl glycosides, and the like. Of these, alkyl glycosides, polyoxyalkylene C ₈ -C ₂₀ fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene hardened castor oil and fatty acid alkanolamides are preferred. Alkyl glycosides include alkyl groups having 8 to 1 carbon atoms.
4, those having a condensation degree of sugar (glucose) of 1 to 2 are preferred. Fatty acid alkanolamides have 8 to 1 carbon atoms
8, particularly those having an acyl group having 10 to 16 carbon atoms are preferable, and any of monoalkanolamide and dialkanolamide may be used, but those having a hydroxyalkyl group having 2 to 3 carbon atoms are preferable. Specific examples of fatty acid alkanolamides include oleic acid diethanolamide,
Palm kernel oil fatty acid diethanolamide, coconut oil fatty acid diethanolamide, lauric acid diethanolamide, polyoxyethylene coconut oil fatty acid monoethanolamide,
Examples include coconut oil fatty acid monoethanolamide, lauric acid monoisopropanolamide, lauric acid monoethanolamide, palm kernel oil fatty acid methylethanolamide, and coconut oil fatty acid methylethanolamide.

Examples of the amphoteric surfactant include a betaine surfactant. Of these, betaine surfactants such as imidazoline betaine, alkyldimethylaminoacetic acid betaine, fatty acid amide propyl betaine, and alkyl hydroxysulfo betaine are more preferable, and alkyl carboxymethyl hydroxyethyl imidazolium betaine, fatty acid amide propyl betaine and alkyl hydroxy sulfo Betaine is particularly preferred. Fatty acid amidopropyl betaine and alkylhydroxysulfobetaine are preferably those having an alkyl group having 8 to 18 carbon atoms, particularly 10 to 16 carbon atoms, particularly lauric amide propyl betaine, palm kernel oil fatty acid amide propyl betaine,
Palm oil fatty acid amidopropyl betaine, lauryl hydroxysulfobetaine and the like are preferred.

The above components in the cleaning composition of the present invention
The content of (A) is preferably from 0.1 to 20% by weight, more preferably from 0.2 to 10% by weight, particularly preferably from 0.5 to 5% by weight, from the viewpoint of improving the conditioning effect, foam quality and stability. Further, the content of the component (B) in the hair cosmetic of the present invention is preferably from 0.1 to 50% by weight, more preferably from 0.5 to 30% by weight, particularly from 5 to 30% by weight, from the viewpoint of improving foaming properties and feeling upon use. 20% by weight is preferred. Further, from the viewpoint of improving the conditioning effect, the foam quality and the stability, the “component (A) / component (B)” (weight ratio) is 1/1 in terms of the use ratio of these components (A) and (B).
~ 1/100, further 1/2-1/80, especially 1/5-1
/ 20 is preferred.

Furthermore, the cleaning composition of the present invention contains
It may contain a cationic surfactant other than (A), and as particularly preferable, described in JP-A-2000-178146, the following general formula (8)

[0041]

Embedded image

[In the formula, among R ⁷ , R ⁸ , R ⁹ and R ¹⁰ ,
At least one is an alkyl group or an alkenyl group which may be substituted with an alkoxy group, an alkenyloxy group, an alkanoylamino group or an alkenoylamino group having a total of 8 to 28 carbon atoms, and the rest is a benzyl group, 5 represents an alkyl group, a hydroxyalkyl group or a polyoxyethylene group having a total added mole number of 10 or less, and Z ⁻ represents a halogen ion or an organic anion. And a quaternary ammonium salt represented by the formula:

Preferred specific examples of the compound (8) include mono-long-chain alkyltrimethylammonium chloride and di-long-chain alkyldimethylammonium chloride.

The cleaning composition of the present invention can contain oils, silicones, cationic polymers, and the like as other conditioning components. Here, the oil agent is usually used in cosmetics, and refers to a solid or liquid oil component that can be dispersed in water and other than silicones.
Hydrocarbons such as petrolatum; higher fatty acid monoesters such as isopropyl palmitate; higher alcohols such as cetyl alcohol; vegetable oils such as camellia oil, macadamia nut oil, mink oil, olive oil, safflower oil, soybean oil, jojoba oil, Animal oils may be mentioned, of which higher alcohols are preferred.

Examples of the silicones include the following. -Dimethylpolysiloxane represented by the following formula:

(CH ₃ ) ₃ Si-[(CH ₃ ) ₂ SiO] _d -Si (CH ₃ ) ₃

[In the formula, d represents a number of 3 to 20,000. ]

Amino-modified silicone: Various amino-modified silicones can be used.
The CTFA dictionary (US, Cosmetic Ingredient Dictionar, US $ 100,000) with the name Amodimethicone
y) Those described in the third edition are preferred. The above amino-modified silicone is preferably used as an aqueous emulsion, and commercially available products include SM8704C (manufactured by Toray Silicone Co., Ltd.) and DC929 (manufactured by Dow Corning).

Other silicones: polyether-modified silicone, methylphenylpolysiloxane, fatty acid-modified silicone, alcohol-modified silicone, alkoxy-modified silicone, epoxy-modified silicone, fluorine-modified silicone, cyclic silicone, alkyl-modified silicone, etc.

Examples of the cationic polymer include a cationized cellulose derivative, a cationic starch, a cationized guar gum derivative, a homopolymer of a diallyl quaternary ammonium salt, a diallyl quaternary ammonium salt / acrylamide copolymer, and a quaternized polyvinyl. Pyrrolidone derivative, polyglycol polyamine condensate, vinyl imidazolinium trichloride / vinyl pyrrolidone copolymer,
Hydroxyethylcellulose / dimethyldiallylammonium chloride copolymer, vinylpyrrolidone / quaternized dimethylaminoethylmethacrylate copolymer, polyvinylpyrrolidone / alkylaminoacrylate copolymer, polyvinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer, vinylpyrrolidone / Methacrylamidopropyl trimethylammonium chloride copolymer, alkyl acrylamide / acrylate /
Alkylaminoalkylacrylamide / polyethylene glycol methacrylate copolymer, adipic acid / dimethylaminohydroxypropylethylenetriamine copolymer (Cartaretin, manufactured by Sandos, USA), JP-A-53-1
Examples include cationic polymers described in JP-A-39734 and JP-A-60-36407, and cationized cellulose derivatives are particularly preferred.

In the cleaning composition of the present invention, in addition to the above components, components used in ordinary cleaning agents, for example, humectants such as propylene glycol, glycerin, diethylene glycol monoethyl ether, sorbitol, panthenol; dyes and pigments Coloring agents such as hydroxyethylcellulose, methylcellulose, polyethylene glycol, ethanol, clay minerals, viscosity adjusting agents such as salts such as sodium chloride; pH adjusting agents such as citric acid and potassium hydroxide; other antidandruff agents, vitamins, In addition to fungicides, anti-inflammatory agents, preservatives, chelating agents, plant extracts, pearling agents, fragrances, pigments, ultraviolet absorbers, antioxidants, etc., ENCYCLOPEDIA OF SHAMPOO INGREDIENTS (MICELLE PRE
SS)] can be appropriately blended.

The cleaning composition of the present invention can be produced according to a conventional method. Also, the dosage form is not particularly limited, and may be a liquid,
It can be in any form such as foam, paste, cream, solid, powder, etc., but is preferably liquid, paste or cream, and particularly preferably liquid. In the case of a liquid state, it is preferable to use water, polyethylene glycol, or the like as a liquid medium,
The amount of water is preferably from 10 to 80% by weight in the whole composition.

The detergent composition of the present invention has an aqueous solution having a pH of 4 to 10, particularly pH 5 when diluted 10 times by weight with water.
8 is preferable, and it may be adjusted by adding an acid or an alkali to the detergent composition.

The cleaning composition of the present invention can be produced according to a conventional method, and can be used as a body cleaning agent such as a hair washing agent, a whole body washing agent, a face wash, a hand washing agent and the like.

[0055]

EXAMPLES Example 1 Hair washing having the composition shown in Table 2 using the ether type cationic surfactants 1 to 4 and other cationic surfactants produced by the method described in this specification shown in Table 1. Agents (Products 1 to 7 of the present invention)
And Comparative products 1 and 2) were produced by a conventional method. The feeling of use and low-temperature stability of these hair cleansing agents were evaluated by the following methods. The numerical values in Table 2 are "% by weight".

[0056]

[Table 1]

<Evaluation method> (Feeling of use) Bundle 20 g (length 20 cm) of hair of a Japanese woman who had been subjected to cold perm in advance, apply 1 g of hair cleansing agent, lather for 30 seconds, rinse, then dry with towel And dried with a dryer. At this time, the foam quality, the feeling during washing, the feeling during drying, and the unity of the hair were evaluated by five expert panelists according to the following criteria.

4: Very good, 3: Good, 2: Neither, 1: Bad

The average score of the evaluations of the five people was determined, and 3.6 or more was evaluated as ◎, 2.6 to 3.4 as ○, 1.6 to 2.4 as Δ, 1.4 or less as ×,
It is shown in Table 2.

(Low-temperature stability) 5 parts of a hair cleanser were placed in a glass bottle with an inner diameter of 3 cm and a height of 7.5 cm with a lid (made of plastic).
After taking 0 g, sealing and leaving still at 0 ° C. for 24 hours, the appearance was evaluated according to the following criteria.

：: Transparent and no change was observed X: Cloudy or precipitate was observed

[0062]

[Table 2]

Example 2 A hair cleansing composition having the following composition was produced. (Wt%) Ether-type cationic surfactant 3 0.5 Sodium polyoxyethylene (3) lauryl ether sulfate 15.0 Diethanolamide laurate 2.0 Cationic polymer (Mercoat 550, manufactured by Calgon) 0.5 Hydroxysulfobetaine 3.5 Denatured alcohol 2.0 Perfume , Methyl paraben suitable amount purified water balance meter 100.0 This hair cleansing agent was excellent in foam quality and feel during washing and after drying.

[0064]

The cleaning composition of the present invention is excellent in foam quality at the time of cleaning, can give a good feeling of use and a sufficient conditioning effect to skin and hair, and has good stability at low temperatures. It is.

 ──────────────────────────────────────────────────の Continuing on the front page (72) Inventor Hiroyuki Masuda 1334 Minato 1334 Minato, Wakayama City, Wakayama Prefecture, Japan Inventor Uichiro Nishimoto 1334 Minato 1 Minato, Wakayama City, Wakayama Prefecture, Kao Research Institute (72) Invention Person Hiroshi Abe Spain 08210 Barcelona Barbera del Valles Pucci Dells Tsudons, 10 F-term in Kao Chemicals Europe (reference) 4C083 AC172 AC442 AC642 AC691 AC692 AC712 AC782 BB04 BB05 BB06 CC38 EE01 EE06 EE07 EE28 4H003 AB05 AD05 AC05 AC05 EB09 ED02 ED28 FA16 FA17 FA21 FA26

Claims (3)

[Claims] (1) The following components (A) and (B) (A) General formula (1) [In the formula, R ¹ represents a linear or branched alkyl group or alkenyl group having 6 to 24 carbon atoms, and R ² and R ⁴ represent an alkyl group having 1 to 6 carbon atoms or-(AO) _n
H (A represents an alkylene group having 2 to 4 carbon atoms, and n represents 1 to
The number 6 is shown, and n A's may be the same or different, and the sequence is arbitrary. ) Indicates, R ³ is an alkyl group having 1 to 6 carbon atoms, a benzyl group or a -
(A'O) _m H (A 'represents an alkylene group having 2 to 4 carbon atoms, m represents a number of 1 to 6, m A's may be the same or different, and the sequence is arbitrary. indicates some), X ^-. represents an anion. (B) a detergent composition containing at least one selected from anionic surfactants, nonionic surfactants and amphoteric surfactants; 2. The cleaning composition according to claim 1, further comprising a cationic surfactant other than the component (A). 3. Component (A) is 0.1 to 20% by weight, component (B) is 0.1% by weight.
-50% by weight, and the weight ratio of (A) / (B) is 1/1 to 1/10
The cleaning composition according to any one of claims 1 to 3, which is 0.