[go: up one dir, main page]

JP2002137120A - Surface covered high speed tool steel gear cutting tool having hard covered layer having excellent chip lubrication property - Google Patents

Surface covered high speed tool steel gear cutting tool having hard covered layer having excellent chip lubrication property

Info

Publication number
JP2002137120A
JP2002137120A JP2000332675A JP2000332675A JP2002137120A JP 2002137120 A JP2002137120 A JP 2002137120A JP 2000332675 A JP2000332675 A JP 2000332675A JP 2000332675 A JP2000332675 A JP 2000332675A JP 2002137120 A JP2002137120 A JP 2002137120A
Authority
JP
Japan
Prior art keywords
layer
thin layer
thickness
gear cutting
cutting tool
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000332675A
Other languages
Japanese (ja)
Other versions
JP3543755B2 (en
Inventor
Yasuyuki Yamada
保之 山田
Natsuki Ichinomiya
夏樹 一宮
Koichi Maeda
浩一 前田
Yusuke Tanaka
裕介 田中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MMC Kobelco Tool Co Ltd
Original Assignee
MMC Kobelco Tool Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP2000332675A priority Critical patent/JP3543755B2/en
Application filed by MMC Kobelco Tool Co Ltd filed Critical MMC Kobelco Tool Co Ltd
Priority to KR1020010067364A priority patent/KR100869956B1/en
Priority to EP01125422A priority patent/EP1201776A3/en
Priority to DE60142193T priority patent/DE60142193D1/en
Priority to TW090126973A priority patent/TW554059B/en
Priority to EP06004512A priority patent/EP1683875B1/en
Priority to US09/984,716 priority patent/US6811581B2/en
Publication of JP2002137120A publication Critical patent/JP2002137120A/en
Priority to US10/458,228 priority patent/US7074285B2/en
Application granted granted Critical
Publication of JP3543755B2 publication Critical patent/JP3543755B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a surface covered high speed tool steel gear cutting tool having a hard covered layer having excellent chip lubrication property. SOLUTION: A first thin layer of the surface covered high speed tool steel gear cutting tool which is formed by alternately laminating the first thin layer and a second thin layer having individual average layer thickness of 0.005 to 0.2 μm and has a hard covered layer having average layer thickness of 2 to 15 μm on the whose by physically depositing it on a surface of a high speed tool steel basic body is composed of either or both of a compound nitride of Ti and Al satisfying atomic ratio of X: 0.30 to 0.70 and m: 0.6 to 0.99 and compound carbon-nitride of Ti and Al according to the measurement by an Auger spectral analyzer in a central part in the direction of thickness when expressed by a composition formula: [Ti1-XAlX]N and [Ti1-XAlX]C1-mNm, and the second thin layer is composed of either or both of a compound nitride of Ti, Al, and Ta satisfying atomic ratio of X: 0.30 to 0.70, Y: 0.01 to 0.35, and m: 0.6 to 0.99 and compound carbon-nitride of Ti, Al, and Ta according to the measurement by the Auger spectral analyzer in the central part in the direction of thickness when expressed by a composition formula: [Ti1-(X+Y)AlXTaY]N and [Ti1-(X+Y)AlXTaY]C1-mNm.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】この発明は、硬質被覆層が切
粉に対してすぐれた潤滑性を発揮し、したがって特にき
わめて粘性が高く、かつ切粉が切刃表面に溶着し易い低
合金鋼や軟鋼などの難削材からなる歯車の高速歯切加工
に用いた場合にも、切刃に欠けやチッピング(微小欠
け)などの発生なく、すぐれた切削性能を長期に亘って
発揮する表面被覆高速度工具鋼製歯切工具(以下、被覆
歯切工具という)に関するものである。
BACKGROUND OF THE INVENTION The present invention relates to a low-alloy steel, in which a hard coating layer exhibits excellent lubricating properties against chips, and therefore has a particularly high viscosity and the chips are easily welded to the cutting surface. Even when used for high-speed gear cutting of gears made of difficult-to-cut materials such as mild steel, the surface coating height ensures excellent cutting performance over a long period without chipping or chipping (small chipping) of the cutting edge. The present invention relates to a speed cutting tool made of speed tool steel (hereinafter, referred to as a coated tooth cutting tool).

【0002】[0002]

【従来の技術】従来、一般に、自動車や航空機、さらに
各種駆動装置などの構造部材として各種歯車が用いられ
ており、これら歯車の歯形の歯切加工にホブやピニオン
カッタ、さらにシェービングカッタなどの歯切工具が用
いられている。また、上記の歯切工具として、例えば特
開平7−310173号公報に記載されるように、高速
度工具鋼基体の表面に、組成式:[Ti1-XAlX]Nお
よび同[Ti1-XAlX]C1-mmで表わした場合、厚さ
方向中央部のオージェ分光分析装置による測定で、原子
比で、X:0.30〜0.70、m:0.6〜0.99
を満足するTiとAlの複合窒化物[以下、(Ti,A
l)Nで示す]層およびTiとAlの複合炭窒化物[以
下、(Ti,Al)CNで示す]層のうちのいずれか、
または両方で構成された硬質被覆層を2〜15μmの平
均層厚で物理蒸着してなる被覆歯切工具が広く知られて
いる。
2. Description of the Related Art Conventionally, various gears are generally used as structural members of automobiles, aircrafts, and various types of driving devices. Cutting tools are used. As the above-mentioned gear cutting tool, for example, as described in JP-A-7-310173, a composition formula: [Ti 1-X Al X ] N and [Ti 1 -X Al X ] C 1-m N m , when measured by an Auger spectrometer at the center in the thickness direction, X: 0.30 to 0.70, m: 0.6 to 0.99
Complex nitride of Ti and Al satisfying the following [hereinafter, (Ti, A
l) a layer represented by N] or a composite carbonitride of Ti and Al [hereinafter represented by (Ti, Al) CN] layer;
A coated tooth cutting tool formed by physical vapor deposition of a hard coating layer composed of both with an average layer thickness of 2 to 15 μm is widely known.

【0003】さらに、上記の従来被覆歯切工具が、例え
ば図1に概略説明図で示される物理蒸着装置の1種であ
るアークイオンプレーティング装置を用い、ヒータで装
置内を、例えば雰囲気を20mtorrの真空として、
500℃の温度に加熱した状態で、アノード電極と所定
組成を有するTi−Al合金がセットされたカソード電
極(蒸発源)との間に、例えば電圧:35V、電流:9
0Aの条件でアーク放電を発生させ、同時に装置内に反
応ガスとして窒素ガス、または窒素ガスとメタンガスを
導入し、一方高速度工具鋼からなる基体(以下、単に基
体ともいう)には、例えばー200Vのバイアス電圧を
印加した条件で、前記基体の表面に、上記の硬質被覆層
を物理蒸着することにより製造されることも知られてい
る。
Further, the above-mentioned conventional coated tooth cutting tool uses an arc ion plating apparatus, which is a kind of a physical vapor deposition apparatus schematically shown in FIG. 1, for example, and the inside of the apparatus is heated with a heater, for example, at a pressure of 20 mtorr. As the vacuum of
When heated to a temperature of 500 ° C., for example, a voltage of 35 V and a current of 9 are applied between an anode electrode and a cathode electrode (evaporation source) on which a Ti—Al alloy having a predetermined composition is set.
An arc discharge is generated under the condition of 0 A, and at the same time, a nitrogen gas or a nitrogen gas and a methane gas are introduced into the apparatus as a reaction gas. On the other hand, a base made of high-speed tool steel (hereinafter simply referred to as a base) has, for example,- It is also known that the hard coating layer is manufactured by physical vapor deposition on the surface of the base under a condition that a bias voltage of 200 V is applied.

【0004】[0004]

【発明が解決しようとする課題】近年の歯車加工装置の
FA化はめざましく、一方で歯切加工に対する省力化お
よび省エネ化、さらに低コスト化の要求は強く、これに
伴い、歯切工具には1種類の歯切工具でできるだけ多く
の材種の歯切加工ができる汎用性が求められると共に、
歯切加工も高速化の傾向にあるが、上記の従来被覆歯切
工具においては、これを炭素鋼や鋳鉄などの通常の条件
での歯切加工に用いた場合には問題はないが、これをき
わめて粘性の高い低合金鋼や軟鋼などの歯車の高速歯切
加工に用いた場合には、これら歯車の切粉は、硬質被覆
層を構成する(Ti,Al)N層や(Ti,Al)CN
層に対する親和性が高いために、歯切工具の切刃表面に
溶着し易く、この溶着現象は歯切加工が高速化すればす
るほど顕著に現れるようになり、この溶着現象が原因で
切刃に欠けやチッピングが発生し、この結果比較的短時
間で使用寿命に至るのが現状である。
In recent years, the use of FAs in gear processing devices has been remarkable, but on the other hand, there has been a strong demand for labor saving and energy saving and further cost reduction for gear cutting. A versatility that can cut as many materials as possible with one type of gear cutting tool is required,
Although the speed of gear cutting also tends to increase, there is no problem with the above-mentioned conventional coated gear cutting tool when gear cutting is performed under normal conditions such as carbon steel or cast iron. When is used for high-speed gear cutting of gears such as low-alloy steel and mild steel having extremely high viscosity, the chips of these gears are hardened by the (Ti, Al) N layer or the (Ti, Al) layer constituting the hard coating layer. ) CN
Due to the high affinity for the layer, it is easy to weld to the cutting edge surface of the gear cutting tool, and this welding phenomenon becomes more noticeable as the cutting speed increases, and this welding phenomenon causes the cutting edge At present, chipping and chipping occur, resulting in a relatively short service life.

【0005】[0005]

【課題を解決するための手段】そこで、本発明者等は、
上述のような観点から、特に低合金鋼や軟鋼などの歯車
の高速歯切加工に用いた場合にも、切刃表面に切粉の溶
着し難い被覆歯切工具を開発すべく研究を行った結果、
(a)上記の従来被覆歯切工具の硬質被覆層を構成する
(Ti,Al)N層および(Ti,Al)CN層に、T
iとAlとの合量に占める割合で、かつ厚さ方向中央部
をオージェ分光分析装置で測定して、原子比で、0.0
1〜0.35の割合のTaを固溶含有させると、この結
果のTiとAlとTaの複合窒化物[以下、(Ti,A
l,Ta)Nで示す]層およびTiとAlとTaの複合
炭窒化物[以下、(Ti,Al,Ta)CNで示す]層
で硬質被覆層を構成すると、この硬質被覆層は、Taの
作用で被削材、特に低合金鋼や軟鋼などの粘性の高い難
削材に対する親和性が著しく低くなって、高い切粉潤滑
性をもつようになるため、切粉が切刃に溶着することが
著しく抑制されるようになるが、反面前記(Ti,A
l)N層および(Ti,Al)CN層の具備していたす
ぐれた靭性が損なわれるようになること。
Means for Solving the Problems Accordingly, the present inventors have
In view of the above, research was conducted to develop a coated tooth cutting tool that is less likely to cause cutting powder to adhere to the cutting edge surface, especially when used for high-speed gear cutting of gears such as low alloy steel and mild steel. result,
(A) The (Ti, Al) N layer and the (Ti, Al) CN layer constituting the hard coating layer of the above-mentioned conventional coated tooth cutting tool have T
The ratio of i to Al in the total amount, and the center in the thickness direction was measured with an Auger spectrometer, and the atomic ratio was 0.0
When Ta is contained in a solid solution in a ratio of 1 to 0.35, the resulting composite nitride of Ti, Al, and Ta [hereinafter, (Ti, A
l, Ta) N] layer and a composite carbonitride of Ti, Al, and Ta [hereinafter, referred to as (Ti, Al, Ta) CN] layer, the hard coating layer is made of Ta. Has a markedly low affinity for work materials, especially high-viscosity difficult-to-cut materials such as low-alloy steel and mild steel, and has high chip lubricating properties. Is significantly suppressed, but (Ti, A)
1) The excellent toughness of the N layer and the (Ti, Al) CN layer is impaired.

【0006】(b)一方、上記従来被覆歯切工具の硬質
被覆層の構成層である(Ti,Al)N層および(T
i,Al)CN層と上記(a)の(Ti,Al,Ta)
N層および(Ti,Al,Ta)CN層とを個々の層厚
をきわめて薄くした状態、すなわち0.005〜0.2
μmの平均層厚とした状態で、これら両層を交互積層さ
せて硬質被覆層を構成すると、この硬質被覆層は前記両
層による薄膜化交互積層構造によってそれぞれの層のも
つ問題点、すなわち(Ti,Al)N層および(Ti,
Al)CN層(以下、第1薄層という)のもつ切粉に対
する高い親和性および(Ti,Al,Ta)N層および
(Ti,Al,Ta)CN層(以下、第2薄層という)
のもつ低靭性が相互に消失し合い、前記第1薄層のもつ
すぐれた靭性と前記第2薄層のもつすぐれた切粉潤滑性
を具備するようになることから、この結果の被覆歯切工
具は、これを特に低合金鋼や軟鋼などの粘性の高い難削
材からなる歯車の高速歯切加工に用いても、切刃に欠け
やチッピングの発生がなくなり、長期に亘ってすぐれた
切削性能を発揮するようになること。以上(a)および
(b)に示される研究結果を得たのである。
(B) On the other hand, the (Ti, Al) N layer and (T) which are constituent layers of the hard coating layer of the conventional coated tooth cutting tool described above.
(i, Al) CN layer and (Ti, Al, Ta) of the above (a)
The N layer and the (Ti, Al, Ta) CN layer are in a state where the individual layers are extremely thin, that is, 0.005 to 0.2.
When the hard coating layer is formed by alternately laminating both layers in a state where the average layer thickness is set to μm, the hard coating layer has a problem that each layer has due to the thinned alternate lamination structure of the two layers, namely, ( Ti, Al) N layer and (Ti,
Al) CN layer (hereinafter, referred to as first thin layer) has high affinity for chips, and (Ti, Al, Ta) N layer and (Ti, Al, Ta) CN layer (hereinafter, referred to as second thin layer)
Of the first thin layer and the excellent chip lubrication of the second thin layer, the resulting coated gear cuttings Even if this tool is used for high-speed gear cutting of gears made of highly viscous and difficult-to-cut materials such as low alloy steel and mild steel, the cutting edge will not be chipped or chipped. To be able to demonstrate performance. The research results shown in (a) and (b) above were obtained.

【0007】この発明は、上記の研究結果に基づいてな
されたものであって、高速度工具鋼基体の表面に、2〜
15μmの全体平均層厚で物理蒸着した硬質被覆層が、
個々の平均層厚が0.005〜0.2μmの第1薄層と
第2薄層の交互積層からなり、上記第1薄層を、組成
式:[Ti1-XAlX]Nおよび同[Ti1-XAlX]C1-
mmで表わした場合、厚さ方向中央部のオージェ分光分
析装置による測定で、原子比で、X:0.30〜0.7
0、m:0.6〜0.99を満足する(Ti,Al)N
層および(Ti,Al)CN層のうちのいずれか、また
は両方で構成し、上記第2薄層を、組成式:[Ti
1-(X+Y)AlXTaY]Nおよび同[Ti1-(X+ Y)AlX
Y]C1-mmで表わした場合、厚さ方向中央部のオー
ジェ分光分析装置による測定で、原子比で、X:0.3
0〜0.70、Y:0.01〜0.35、m:0.6〜
0.99を満足する(Ti,Al,Ta)N層および
(Ti,Al,Ta)CN層のうちのいずれか、または
両方で構成してなる、硬質被覆層がすぐれた切粉潤滑性
を有する被覆歯切工具に特徴を有するものである。
[0007] The present invention has been made based on the above-mentioned research results, and has the following effects.
A hard coating layer physically deposited with a total average layer thickness of 15 μm,
Each of the first and second thin layers has an average layer thickness of 0.005 to 0.2 μm and is alternately laminated. The first thin layer is composed of [Ti 1-x Al x ] N and [Ti 1-X Al X ] C 1-
When expressed in m N m, as measured by Auger spectroscopy apparatus in the thickness direction central portion, in terms of atomic ratio, X: .30-.7
0, m: (Ti, Al) N satisfying 0.6 to 0.99
Layer and / or the (Ti, Al) CN layer, and the second thin layer has a composition formula: [Ti
1- (X + Y) Al X Ta Y ] N and [Ti 1- (X + Y) Al X T
a Y ] C 1-m N m , when measured by an Auger spectrometer at the center in the thickness direction, X: 0.3 in atomic ratio
0 to 0.70, Y: 0.01 to 0.35, m: 0.6 to
The hard coating layer composed of one or both of the (Ti, Al, Ta) N layer and the (Ti, Al, Ta) CN layer satisfying 0.99 has excellent chip lubrication. The present invention is characterized in that the coated tooth cutting tool has a feature.

【0008】なお、この発明の被覆歯切工具において、
硬質被覆層の交互積層を構成する第1薄層および第2薄
層の個々の平均層厚をそれぞれ0.005〜0.2μm
としたのは、いずれの薄層においても、その平均層厚が
0.005μm未満になると、それぞれの薄層のもつ特
性、すなわち第1薄層によるすぐれた靭性、第2薄層に
よるすぐれた切粉潤滑性を硬質被覆層に十分満足に具備
せしめることができず、一方その平均層厚がそれぞれ
0.2μmを越えると、それぞれの薄層のもつ問題点、
すなわち第1薄層による切粉溶着性および第2薄層によ
る靭性低下が硬質被覆層に現われるようになるという理
由によるものであり、望ましくは0.007〜0.10
μmとするのがよい。
[0008] In the coated tooth cutting tool of the present invention,
The average thickness of each of the first thin layer and the second thin layer constituting the alternate lamination of the hard coating layers is 0.005 to 0.2 μm, respectively.
The reason is that, when the average thickness of any of the thin layers is less than 0.005 μm, the properties of each thin layer, that is, the excellent toughness by the first thin layer and the excellent cut by the second thin layer. When the hard coating layer cannot be sufficiently satisfactorily provided with the powder lubricity, on the other hand, when the average layer thickness exceeds 0.2 μm, problems with each thin layer,
That is, the reason is that the chip welding property by the first thin layer and the decrease in toughness by the second thin layer appear in the hard coating layer, and preferably 0.007 to 0.10.
It is good to be set to μm.

【0009】また、この発明の被覆歯切工具において、
硬質被覆層の第1薄層を構成する(Ti,Al)N層お
よび(Ti,Al)CN層、並びに同第2薄層を構成す
る(Ti,Al,Ta)N層および(Ti,Al,T
a)CN層におけるAlはTiCNに対して硬さを高
め、もって耐摩耗性を向上させるために固溶するもので
あり、したがって組成式:(Ti1-XAlX)Nおよび同
(Ti1-XAlX)C1-mm、並びに組成式:[Ti
1-(X+Y)AlXTaY]Nおよび同[Ti1-(X+Y)AlX
Y]C1-mmのX値が原子比(以下同じ)で、0.3
未満では所望の耐摩耗性を確保することができず、一方
その値が0.7を越えると、切刃に欠けやチッピングが
発生し易くなると云う理由によりX値を0.3〜0.7
と定めた。望ましくはX値を0.35〜0.65とする
のがよい。
Further, in the coated tooth cutting tool of the present invention,
(Ti, Al) N layer and (Ti, Al) CN layer forming the first thin layer of the hard coating layer, and (Ti, Al, Ta) N layer and (Ti, Al) forming the second thin layer , T
a) Al in the CN layer increases the hardness with respect to TiCN and thus forms a solid solution in order to improve the wear resistance. Therefore, the composition formulas: (Ti 1-x Al x ) N and (Ti 1 -X Al x ) C 1-m N m and the composition formula: [Ti
1- (X + Y) Al X Ta Y ] N and [Ti 1- (X + Y) Al X T
a Y] C 1-m N X values atomic ratio m (hereinafter the same), 0.3
If the value is less than 0.7, the desired wear resistance cannot be ensured. On the other hand, if the value exceeds 0.7, the X value is set to 0.3 to 0.7 for the reason that chipping or chipping is likely to occur in the cutting edge.
It was decided. Desirably, the X value is set to 0.35 to 0.65.

【0010】また、上記の(Ti,Al)CN層および
(Ti,Al,Ta)CN層におけるC成分には、硬さ
を向上させる作用があるので、(Ti,Al)CN層お
よび(Ti,Al,Ta)CN層は上記(Ti,Al)
N層および(Ti,Al,Ta)N層に比してそれぞれ
相対的に高い硬さをもつが、この場合上記の組成式にお
けるC成分の割合が0.01未満、すなわちm値が0.
99を越えると所定の硬さ向上効果が得られず、一方C
成分の割合が0.4を越える、すなわちm値が0.6未
満になると靭性が急激に低下するようになることから、
m値を0.6〜0.99と定めた。望ましくはm値を
0.8〜0.9とするのがよい。
The C component in the (Ti, Al) CN layer and the (Ti, Al, Ta) CN layer has an effect of improving the hardness, so that the (Ti, Al) CN layer and the (Ti, Al) CN layer , Al, Ta) CN layer is the above (Ti, Al)
The N layer and the (Ti, Al, Ta) N layer each have a relatively high hardness, but in this case, the proportion of the C component in the above composition formula is less than 0.01, that is, the m value is 0.
If it exceeds 99, the predetermined hardness improving effect cannot be obtained, while C
When the ratio of the components exceeds 0.4, that is, when the m value is less than 0.6, the toughness rapidly decreases,
The m value was determined to be 0.6 to 0.99. Desirably, the m value is set to 0.8 to 0.9.

【0011】さらに、上記の第2薄層を構成する(T
i,Al,Ta)N層および(Ti,Al,Ta)CN
層は、上記の第1薄層の(Ti,Al)N層および(T
i,Al)CN層に比してTaの作用ですぐれた切粉潤
滑性をもつようになるが、上記の組成式でY値が0.0
1未満ではTaの固溶含有が不充分で所定の切粉潤滑性
向上効果を硬質被覆層に具備せしめることができず、一
方Y値が0.35を越えると、急激に靭性が低下し、こ
の靭性低下は硬質被覆層全体に顕著に現れるようになる
ことから、Y値を0.01〜0.35と定めた。望まし
くはY値を0.07〜0.30とするのがよい。
Further, the above-mentioned second thin layer is formed (T
i, Al, Ta) N layer and (Ti, Al, Ta) CN
The layers are the (Ti, Al) N layer of the first thin layer and the (T
As compared with the (i, Al) CN layer, Ta has an excellent chip lubricating property due to the action of Ta.
When the value is less than 1, the solid solution content of Ta is insufficient, and the predetermined chip lubricating property improving effect cannot be provided to the hard coating layer. On the other hand, when the Y value exceeds 0.35, the toughness rapidly decreases, Since this decrease in toughness appears remarkably in the entire hard coating layer, the Y value is set to 0.01 to 0.35. Desirably, the Y value is set to 0.07 to 0.30.

【0012】また、硬質被覆層の全体平均層厚を2〜1
5μmとしたのは、その層厚が2μmでは所望のすぐれ
た耐摩耗性を確保することができず、一方その層厚が1
5μmを越えると、切刃に欠けやチッピングが発生し易
くなるという理由によるものであり、望ましくは3〜1
0μmとするのがよい。
The hard coating layer has a total average layer thickness of 2 to 1
The reason why the thickness is set to 5 μm is that if the layer thickness is 2 μm, the desired excellent wear resistance cannot be secured, while the layer thickness is 1 μm.
If the thickness exceeds 5 μm, chipping and chipping of the cutting edge are liable to occur.
The thickness is preferably set to 0 μm.

【0013】[0013]

【発明の実施の形態】つぎに、この発明の被覆歯切工具
を実施例により具体的に説明する。高速度工具鋼基体と
して、材質がJIS・SKH55からなり、JIS・B
4354に定める外形:60mm×全長:60mmの寸
法(モジュ―ル:2)をもった歯車用1条ホブと、同じ
く材質がJIS・SKH55で構成され、JIS・B4
356に定める歯数:50,ピッチ円直径:100mm
(モジュ―ル:2)のピニオンカッタを用意し、これら
高速度工具鋼基体を、アセトン中で超音波洗浄し、乾燥
した状態で、それぞれ図1に例示される通常のアークイ
オンプレーティング装置に装入し、一方カソード電極
(蒸発源)として、種々の成分組成をもった第1薄層形
成用Ti−Al合金と第2薄層形成用Ti−Al―Ta
合金のうちから、それぞれ所定の成分組成の合金を所定
の組み合わせで選び出し、これを回転円板上に回転軸を
中心にしてそれぞれが対局した位置に装着し、装置内を
排気して0.5Paの真空に保持しながら、ヒーターで
装置内を500℃に加熱した後、Arガスを装置内に導
入して10PaのAr雰囲気とし、この状態で形成する
層厚に対応して前記回転軸を所定時間経過毎に断続的に
回転し、一方基体には−800vのバイアス電圧を印加
して基体表面をArガスボンバート洗浄し、ついで装置
内に反応ガスとして窒素ガス、または窒素ガスとメタン
ガスを導入して6Paの反応雰囲気とすると共に、前記
基体に印加するバイアス電圧を−200vに下げて、前
記カソード電極(前記回転円板上の片方の合金)とアノー
ド電極との間にアーク放電を発生させ、もって前記基体
の表面に、表1に示される目標組成および目標層厚の第
1薄層と第2薄層とを表2に示される組み合わせで、か
つ同じく表2に示される交互積層数からなる硬質被覆層
を蒸着することにより、本発明被覆歯切工具1〜13を
それぞれ製造した。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, the coated tooth cutting tool of the present invention will be specifically described with reference to examples. As a high-speed tool steel substrate, the material consists of JIS / SKH55, JIS / B
A single hob for gears having the dimensions (module: 2) with the outer shape defined by 4354: 60 mm x total length: 60 mm, and the same material made of JIS / SKH55, JIS / B4
Number of teeth specified in 356: 50, Pitch circle diameter: 100mm
(Module: 2) pinion cutters were prepared, and these high-speed tool steel substrates were ultrasonically cleaned in acetone and dried, and then each of them was applied to a normal arc ion plating apparatus illustrated in FIG. First, a Ti-Al alloy for forming a first thin layer and a Ti-Al-Ta for forming a second thin layer having various component compositions as a cathode electrode (evaporation source).
From among the alloys, an alloy having a predetermined component composition is selected in a predetermined combination, and the selected alloy is mounted on a rotating disk at a position opposite to each other with the rotation axis as a center. While maintaining the vacuum, the inside of the apparatus was heated to 500 ° C. by a heater, and then an Ar gas was introduced into the apparatus to form an Ar atmosphere of 10 Pa. The substrate rotates intermittently with the passage of time, while applying a bias voltage of -800 V to the substrate to clean the substrate surface with Ar gas bombardment. Then, nitrogen gas or nitrogen gas and methane gas are introduced into the apparatus as a reaction gas. 6 Pa and a bias voltage applied to the substrate was lowered to -200 V, and an anode was placed between the cathode electrode (one alloy on the rotating disk) and the anode electrode. And a first thin layer and a second thin layer having the target composition and the target layer thickness shown in Table 1 in the combination shown in Table 2 and also shown in Table 2 on the surface of the substrate. The coated tooth cutting tools 1 to 13 of the present invention were manufactured by depositing hard coating layers having the number of layers alternately laminated.

【0014】また、比較の目的で、同じく上記のアーク
イオンプレーティング装置にて、カソード電極(蒸発
源)として、種々の成分組成をもったTi−Al合金の
うちの所定の1種を装着する以外は同一の条件で、上記
基体の表面に表3に示される通りの目標組成および目標
層厚の(Ti,Al)N層および/または(Ti,A
l)CN層で構成された硬質被覆層を蒸着することによ
り、従来被覆歯切工具1〜12をそれぞれ製造した。
For the purpose of comparison, a predetermined one of Ti-Al alloys having various component compositions is mounted as a cathode electrode (evaporation source) in the above-mentioned arc ion plating apparatus. Except for the (Ti, Al) N layer and / or (Ti, A) having a target composition and a target layer thickness as shown in Table 3,
1) Conventional coated tooth cutting tools 1 to 12 were manufactured by depositing a hard coating layer composed of a CN layer.

【0015】なお、この結果得られた本発明被覆歯切工
具1〜13および従来被覆歯切工具1〜12を構成する
それぞれの硬質被覆層について、これの構成層個々の厚
さ方向中央部の組成をオージェ分光分析装置を用いて測
定し、さらにその層厚を走査型電子顕微鏡を用いて測定
したところ、いずれの場合も目標組成および目標層厚と
実質的に同じ組成および層厚を示した。
The respective hard coating layers constituting the coated tooth cutting tools 1 to 13 of the present invention and the conventional coated tooth cutting tools 1 to 12 obtained as described above are formed at the central portions in the thickness direction of the respective constituent layers. The composition was measured using an Auger spectrometer, and the layer thickness was measured using a scanning electron microscope. In each case, the target composition and the layer thickness were substantially the same as the target composition and the layer thickness. .

【0016】つぎに、上記本発明被覆歯切工具1〜13
および従来被覆歯切工具1〜12のうち、ホブについて
は、 切削速度(回転速度):200m/min(1062r
pm)、 送り:2.0mm/rev、 の高速切削条件で、外径:100mm×長さ:25mm
×歯数:48本の寸法をもち、かつ材質がJIS・SC
r420の低合金鋼からなる歯車の歯切加工を行ない、
またピニオンカッタについては、 ストローク数:750ストローク/min、 円周送り:4mm/ストローク、 半径送り:0.01mm/ストローク、 の高速切削条件で、外径:66mm×長さ:25mm×
歯数:31の寸法をもち、かつ材質がJIS・SCr4
20の低合金鋼からなる歯車の歯切加工を行ない、切刃
の最大逃げ面摩耗が0.02mmに至る(使用寿命)ま
での歯車加工数を測定した。この測定結果をそれぞれ表
2、3に示した。なお、表2、3の歯車加工数の欄の※
印はウエット加工(切削油使用)の結果を示し、無印は
ドライ加工(エアーブロー)の結果を示す。
Next, the above-described coated tooth cutting tools 1 to 13 according to the present invention.
Among the conventional coated gear cutting tools 1 to 12, the cutting speed (rotation speed) of the hob is 200 m / min (1062r).
pm), feed: 2.0 mm / rev, under high-speed cutting conditions, outer diameter: 100 mm x length: 25 mm
× Number of teeth: 48 teeth and material is JIS / SC
gear cutting made of low alloy steel of r420,
Regarding the pinion cutter, the number of strokes: 750 strokes / min, circumferential feed: 4 mm / stroke, radial feed: 0.01 mm / stroke, and outer diameter: 66 mm x length: 25 mm x
Number of teeth: 31 dimensions and the material is JIS / SCr4
Gears made of 20 low alloy steels were subjected to gear cutting, and the number of gears processed until the maximum flank wear of the cutting edge reached 0.02 mm (service life) was measured. The measurement results are shown in Tables 2 and 3, respectively. The number of gears processed in columns 2 and 3
The marks indicate the results of wet processing (using cutting oil), and the non-marks indicate the results of dry processing (air blow).

【0017】[0017]

【表1】 [Table 1]

【0018】[0018]

【表2】 [Table 2]

【0019】[0019]

【表3】 [Table 3]

【0020】[0020]

【発明の効果】表2、3に示される結果から、硬質被覆
層が第1薄層と第2薄層の交互多重積層からなる本発明
被覆歯切工具1〜13は、いずれも低合金鋼の歯切加工
を高い発熱を伴う高速で行っても、前記第2薄層による
切粉潤滑性の著しい向上によって硬質被覆層に対する高
温加熱の切粉の親和性がきわめて低くなり、切粉が前記
硬質被覆層に溶着することがなく、切刃は常にすぐれた
表面潤滑性を維持することから、切刃への切粉溶着が原
因のチッピングが切刃に発生することがなく、すぐれた
耐摩耗性を発揮するのに対して、実質的に硬質被覆層が
前記第1薄層と同じ組成の単一層からなる従来被覆歯切
工具1〜12においては、切粉が硬質被覆層に溶着し易
く、これが原因で硬質被覆層が局部的に剥がし取られる
ことから、切刃にチッピングが発生し、比較的短時間で
使用寿命に至ることが明らかである。上述のように、こ
の発明の被覆歯切工具は、炭素鋼や鋳鉄などの歯車の通
常の条件での歯切加工は勿論のこと、特に粘性が高く、
切粉が切刃表面に溶着し易い低合金鋼や軟鋼などの歯車
の高速歯切加工でも切粉に対してすぐれた表面潤滑性を
発揮し、汎用性のある切削性能を示すものであるから、
歯車加工装置のFA化並びに歯切加工の省力化および省
エネ化、さらに低コスト化に十分満足に対応できるもの
である。
From the results shown in Tables 2 and 3, all of the coated tooth cutting tools 1 to 13 of the present invention, in which the hard coating layer is composed of alternate multiple layers of the first thin layer and the second thin layer, are all low alloy steels. Even when the gear cutting process is performed at high speed with high heat generation, the affinity of the high-temperature heated chips to the hard coating layer becomes extremely low due to the remarkable improvement of the chip lubrication by the second thin layer. Since the cutting edge always maintains excellent surface lubricity without welding to the hard coating layer, chipping due to chip welding to the cutting edge does not occur on the cutting edge and excellent wear resistance On the other hand, in the conventional coated tooth cutting tools 1 to 12 in which the hard coating layer substantially consists of a single layer having the same composition as the first thin layer, chips are easily welded to the hard coating layer. Because of this, the hard coating layer is peeled off locally, Mappings occurs, it is apparent that lead to a relatively short time service life. As described above, the coated gear cutting tool of the present invention is not only gear cutting under normal conditions for gears such as carbon steel or cast iron, but also has a particularly high viscosity,
Even in high-speed gear cutting of gears such as low alloy steel and mild steel in which cutting chips easily adhere to the cutting blade surface, it exhibits excellent surface lubricity against chips and exhibits versatile cutting performance. ,
The present invention can satisfactorily cope with the use of the FA in the gear processing device, the labor saving and the energy saving of the gear cutting, and the cost reduction.

【図面の簡単な説明】[Brief description of the drawings]

【図1】アークイオンプレーティング装置の概略説明図
である。
FIG. 1 is a schematic explanatory view of an arc ion plating apparatus.

フロントページの続き (72)発明者 前田 浩一 兵庫県明石市魚住町金ヶ崎西大池179番地 1 エムエムシーコベルコツ−ル株式会社 内 (72)発明者 田中 裕介 兵庫県明石市魚住町金ヶ崎西大池179番地 1 エムエムシーコベルコツ−ル株式会社 内 Fターム(参考) 3C046 FF02 FF10 FF16 FF19 FF25 4K029 AA02 BA54 BA58 BB02 BC00 BD05 CA04 DB04 DD06 EA01Continuing from the front page (72) Inventor Koichi Maeda 179 Kanegasaki Nishi-Oike, Uozumi-cho, Akashi-shi, Hyogo 1 MMC Kobelco Tool Inc. (72) Inventor Yusuke Tanaka 179, Kanegasaki-Nishi-Oike, Uozumi-cho, Akashi-shi, Hyogo 1 FMC term in MMC Belco Tool Co., Ltd. (reference) 3C046 FF02 FF10 FF16 FF19 FF25 4K029 AA02 BA54 BA58 BB02 BC00 BD05 CA04 DB04 DD06 EA01

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 高速度工具鋼基体の表面に、2〜15μ
mの全体平均層厚で物理蒸着した硬質被覆層が、個々の
平均層厚が0.005〜0.2μmの第1薄層と第2薄
層の交互積層からなり、 上記第1薄層を、組成式:[Ti1-XAlX]Nおよび同
[Ti1-XAlX]C1- mmで表わした場合、厚さ方向中
央部のオージェ分光分析装置による測定で、原子比で、
X:0.30〜0.70、m:0.6〜0.99を満足
するTiとAlの複合窒化物およびTiとAlの複合炭
窒化物のうちのいずれか、または両方で構成し、 上記第2薄層を、組成式:[Ti1-(X+Y)AlXTaY
Nおよび同[Ti1-(X+ Y)AlXTaY]C1-mmで表わ
した場合、厚さ方向中央部のオージェ分光分析装置によ
る測定で、原子比で、X:0.30〜0.70、Y:
0.01〜0.35、m:0.6〜0.99を満足する
TiとAlとTaの複合窒化物およびTiとAlとTa
の複合炭窒化物のうちのいずれか、または両方で構成し
たこと、を特徴とする硬質被覆層がすぐれた切粉潤滑性
を有する表面被覆高速度工具鋼製歯切工具。
1. A high-speed tool steel substrate having a surface of 2 to 15 μm
The hard coating layer physically vapor-deposited with a total average layer thickness of m comprises an alternate lamination of a first thin layer and a second thin layer, each of which has an average layer thickness of 0.005 to 0.2 μm. the composition formula: when represented by [Ti 1-X Al X] N and the [Ti 1-X Al X] C 1- m N m, as measured by Auger spectroscopy apparatus in the thickness direction central portion, the atomic ratio so,
X: 0.30 to 0.70, m: 0.6 to 0.99, which is composed of one or both of a composite nitride of Ti and Al and a composite carbonitride of Ti and Al, The second thin layer is formed by a composition formula: [Ti 1- (X + Y) Al X Ta Y ]
When expressed in N and the [Ti 1- (X + Y) Al X Ta Y] C 1-m N m, as measured by Auger spectroscopy apparatus in the thickness direction central portion, in terms of atomic ratio, X: 0.30 ~ 0.70, Y:
Composite nitride of Ti, Al and Ta and Ti, Al and Ta satisfying 0.01 to 0.35, m: 0.6 to 0.99
A surface-coated high-speed tool steel gear cutting tool having an excellent chip lubrication property, wherein the hard coating layer has excellent chip lubricity, characterized in that the tool is made of any one or both of the following composite carbonitrides.
JP2000332675A 2000-10-31 2000-10-31 Surface coated high-speed tool steel gear cutting tool with excellent chip lubrication property with a hard coating layer Expired - Fee Related JP3543755B2 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
JP2000332675A JP3543755B2 (en) 2000-10-31 2000-10-31 Surface coated high-speed tool steel gear cutting tool with excellent chip lubrication property with a hard coating layer
EP01125422A EP1201776A3 (en) 2000-10-31 2001-10-31 High speed tool steel gear cutting tool and manufacturing method thereof
DE60142193T DE60142193D1 (en) 2000-10-31 2001-10-31 Tool for cutting gears made of high-speed steel
TW090126973A TW554059B (en) 2000-10-31 2001-10-31 High-speed tool steel gear cutting tool and manufacturing method therefor
KR1020010067364A KR100869956B1 (en) 2000-10-31 2001-10-31 High speed tool steel gear cutting tool and manufacturing method therefor
EP06004512A EP1683875B1 (en) 2000-10-31 2001-10-31 High-speed tool steel gear cutting tool
US09/984,716 US6811581B2 (en) 2000-10-31 2001-10-31 High-speed tool steel gear cutting tool and manufacturing method therefor
US10/458,228 US7074285B2 (en) 2000-10-31 2003-06-11 Manufacturing method for high-speed tool steel gear cutting tool

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000332675A JP3543755B2 (en) 2000-10-31 2000-10-31 Surface coated high-speed tool steel gear cutting tool with excellent chip lubrication property with a hard coating layer

Publications (2)

Publication Number Publication Date
JP2002137120A true JP2002137120A (en) 2002-05-14
JP3543755B2 JP3543755B2 (en) 2004-07-21

Family

ID=18808849

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000332675A Expired - Fee Related JP3543755B2 (en) 2000-10-31 2000-10-31 Surface coated high-speed tool steel gear cutting tool with excellent chip lubrication property with a hard coating layer

Country Status (1)

Country Link
JP (1) JP3543755B2 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006224198A (en) * 2005-02-15 2006-08-31 Mitsubishi Materials Corp Cutting tool made of surface coated cemented carbide alloy with hard coating layer displaying excellent abrasion resistance in high speed cutting work of highly reactive work material
JP2006305721A (en) * 2005-04-29 2006-11-09 Ceratizit Austria Gmbh Coated tool
JP2007015071A (en) * 2005-07-08 2007-01-25 Mitsubishi Materials Corp Surface coated high-speed tool steel-made gear cutting tool having hard coating layer exhibiting excellent wear resistance in high-speed gear cutting of high responsive work material
JP2007030131A (en) * 2005-07-29 2007-02-08 Mitsubishi Materials Corp Surface coated cemented carbide gear cutting tool with hard coated layer exhibiting excellent abrasion resistance in high-speed gear cutting processing of high-responsiveness cutting material
JP2010188460A (en) * 2009-02-17 2010-09-02 Sumitomo Electric Ind Ltd Surface coated cutting tool
JP2015533936A (en) * 2012-09-08 2015-11-26 エーリコン・サーフェス・ソリューションズ・アーゲー・トリューバッハ Titanium-aluminum-tantalum-based coatings exhibiting improved thermal stability
WO2019181220A1 (en) * 2018-03-19 2019-09-26 住友電工ハードメタル株式会社 Surface coated cutting tool

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006224198A (en) * 2005-02-15 2006-08-31 Mitsubishi Materials Corp Cutting tool made of surface coated cemented carbide alloy with hard coating layer displaying excellent abrasion resistance in high speed cutting work of highly reactive work material
JP2006305721A (en) * 2005-04-29 2006-11-09 Ceratizit Austria Gmbh Coated tool
JP2007015071A (en) * 2005-07-08 2007-01-25 Mitsubishi Materials Corp Surface coated high-speed tool steel-made gear cutting tool having hard coating layer exhibiting excellent wear resistance in high-speed gear cutting of high responsive work material
JP2007030131A (en) * 2005-07-29 2007-02-08 Mitsubishi Materials Corp Surface coated cemented carbide gear cutting tool with hard coated layer exhibiting excellent abrasion resistance in high-speed gear cutting processing of high-responsiveness cutting material
JP2010188460A (en) * 2009-02-17 2010-09-02 Sumitomo Electric Ind Ltd Surface coated cutting tool
JP2015533936A (en) * 2012-09-08 2015-11-26 エーリコン・サーフェス・ソリューションズ・アーゲー・トリューバッハ Titanium-aluminum-tantalum-based coatings exhibiting improved thermal stability
JP2019143251A (en) * 2012-09-08 2019-08-29 エーリコン・サーフェス・ソリューションズ・アーゲー・プフェフィコン Titanium-aluminum-tantalum-based coated material showing improved heat stability
JP2022003168A (en) * 2012-09-08 2022-01-11 エーリコン・サーフェス・ソリューションズ・アーゲー・プフェフィコン Coating of titanium-aluminum-tantalum base showing improved thermal stability
JP7480098B2 (en) 2012-09-08 2024-05-09 エーリコン・サーフェス・ソリューションズ・アーゲー・プフェフィコン Titanium-aluminum-tantalum based coatings exhibiting improved thermal stability
WO2019181220A1 (en) * 2018-03-19 2019-09-26 住友電工ハードメタル株式会社 Surface coated cutting tool
JPWO2019181220A1 (en) * 2018-03-19 2020-12-17 住友電工ハードメタル株式会社 Surface coating cutting tool
US11534836B2 (en) 2018-03-19 2022-12-27 Sumitomo Electric Hardmetal Corp. Surface-coated cutting tool

Also Published As

Publication number Publication date
JP3543755B2 (en) 2004-07-21

Similar Documents

Publication Publication Date Title
JP4576638B2 (en) Surface coated cutting tool
US7527457B2 (en) Surface-coated cutting tool
JP2000073159A (en) Cutting tool made of surface-coated cemented carbide in which surface coating layer exhibits excellent welding resistance
JP3543755B2 (en) Surface coated high-speed tool steel gear cutting tool with excellent chip lubrication property with a hard coating layer
JP2016185589A (en) Surface-coated cutting tool
JP2019118995A (en) Surface-coated cutting tool
JP2008105107A (en) Surface coated cutting tool with hard coated layer showing excellent wear resistance in high speed cutting
KR101727420B1 (en) Laminated coating film having excellent abrasion resistance
JP7110352B2 (en) Hard film and hard film-coated parts
JP4720987B2 (en) Surface-coated high-speed tool steel gear cutting tool with excellent wear resistance due to high-speed gear cutting of highly reactive work materials
JP5234332B2 (en) A surface-coated cutting tool that exhibits excellent chipping resistance with a hard coating layer in high-speed, high-feed cutting.
JP2009285758A (en) Surface-coated cutting tool with hard coating layer exhibiting superior chipping resistance in high-speed high-feed cutting work
JP2007290090A (en) Surface coated cutting tool having hard coating layer exhibiting excellent chipping resistance in high-speed heavy cutting difficult-to-cut material
JP2012143851A (en) Surface-coated cutting tool
JP2019118997A (en) Surface-coated cutting tool
JP4158191B2 (en) A method of forming a hard coating layer on the surface of a cutting tool that exhibits excellent chipping resistance and wear resistance under high-speed heavy cutting conditions
JP2014087914A (en) Surface-coated cutting tool
JP4716006B2 (en) Surface coated high speed tool steel gear cutting tool with excellent wear resistance with hard coating layer in high speed gear cutting of alloy steel
JP2002331407A (en) Abrasion resistant coating film-covered tool
JP4716095B2 (en) Surface-coated high-speed tool steel gear cutting tool that exhibits excellent chipping resistance due to high-speed gear cutting of alloy steel
JP4706916B2 (en) Surface coated high speed tool steel gear cutting tool with excellent wear resistance with hard coating layer in high speed gear cutting of alloy steel
JP5975343B2 (en) Surface coated cutting tool
JP2014188636A (en) Surface-coated cutting tool
JP2015182160A (en) surface-coated cutting tool
JP2013013979A (en) Surface coated cutting tool

Legal Events

Date Code Title Description
TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20040316

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20040329

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080416

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080416

Year of fee payment: 4

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313111

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080416

Year of fee payment: 4

R360 Written notification for declining of transfer of rights

Free format text: JAPANESE INTERMEDIATE CODE: R360

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080416

Year of fee payment: 4

R360 Written notification for declining of transfer of rights

Free format text: JAPANESE INTERMEDIATE CODE: R360

R371 Transfer withdrawn

Free format text: JAPANESE INTERMEDIATE CODE: R371

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313111

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080416

Year of fee payment: 4

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080416

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090416

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090416

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100416

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100416

Year of fee payment: 6

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100416

Year of fee payment: 6

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110416

Year of fee payment: 7

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120416

Year of fee payment: 8

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120416

Year of fee payment: 8

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130416

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130416

Year of fee payment: 9

LAPS Cancellation because of no payment of annual fees