JP2001516701A - Hair care composition comprising an optical brightener and a hair conditioning agent - Google Patents

Abstract

  (57) [Summary] (A) an effective amount of an optical brightener and (b) a hair conditioning agent selected from the group consisting of silicone compounds, cationic compounds, high melting point compounds, fragrance compounds, water-insoluble high molecular weight oily compounds and mixtures thereof. A hair care composition is disclosed.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD OF THE INVENTION

The present invention relates to a hair care composition comprising an optical brightener that changes the color of the hair while increasing the gloss of the hair and without further damaging the hair. More particularly, the present invention relates to a hair care composition comprising an optical brightener and a hair conditioning agent.

[0002] The desire to regain the natural color and luster of damaged hair and the desire to change it to a more attractive hair color are all held. Consumers will notice damaged hair as a poor looking hair and a more unmanageable condition. These poor appearances include alteration and fading of the original color, poorer shine and less gloss.

[0003] A common way to alleviate the bad appearance of damaged hair and achieve an attractive hair color is to dye the hair to the desired color. Hair dyeing provides consumers with a stable hair color over a relatively long period of time. However, dyeing hair is generally time-consuming, cumbersome and cumbersome. Dyes can be chemically harmful to hair, scalp and skin. Hair can be further damaged by dyeing. Therefore, hair dye products are not suitable for everyday use. In addition, the hair looks less shiny, as dyeing can cause the hair to have a dull appearance.

[0004]

[Problems to be solved by the invention]

Based on the foregoing, there is a need for a hair composition that can be used on a daily basis while also increasing the gloss of the hair and without further damaging the hair, and that can also change the color of the hair.

[0005]

[Prior art]

The use of optical brighteners, ie, compounds otherwise referred to by names such as fluorescent whitening agents, fluorescent brighteners or fluorescent dyes in the field of hair care, is disclosed in US Pat. No. 3,658,985 and US Pat. No. 4,312. No. 855, Canadian Patent No. 1,255,603, U.S. Pat. No. 3,577,528, British Patent Specification No. 1
No. 328,108, South African Application No. 676,049, European Patent No. 87,0.
No. 60 and British Patent Specification No. 2,307,639 and the like.

However, when the optical brightener is used alone, good combing, smoothness,
It may not provide sufficient conditioning benefits such as reduced static. Accordingly, there is also a need for a hair care composition that comprises an optical brightener and that provides good conditioning benefits.

[0007] None of the existing technologies can provide all the advantages and benefits of the present invention.

[0008]

Means for Solving the Invention

The present invention relates to (a) an effective amount of an optical brightener and (b) a hair conditioning agent selected from the group consisting of a silicone compound, a cationic compound, a high melting point compound, a fragrance compound, a water-insoluble high molecular weight oily compound and a mixture thereof. A hair care composition comprising:

[0009] These and other features, aspects and advantages of the present invention will become apparent to those skilled in the art from a knowledge of the present disclosure.

While the specification concludes with claims particularly pointing out and distinctly claiming the invention, it is believed that the present invention will be better understood from the following description.

[0011] All percentages are by weight of the total composition unless otherwise indicated. All ratios are by weight unless otherwise indicated. All percentages, ratios, and levels of the components described herein are based on the actual component amounts, unless otherwise indicated, and are based on solvents, fillers, or other components with which the components can be mixed together as a commercial product. Does not contain materials.

As used herein, “comprising” means that other steps and other ingredients which do not affect the end result can be added. The terms "consisting of" and "consisting primarily of
ssentially of).

All references are incorporated herein by reference in their entirety. Citation of any reference is not an admission regarding any determination as to its utility as prior art to the claimed invention.

Optical Brighteners Optical brighteners are compounds that absorb ultraviolet light and re-emit energy in the form of visible light. Specifically, optical brighteners useful herein are about 1n
absorbance at a wavelength between m and about 420 nm, preferably the main absorption peak, and about 360
It emits at a wavelength between nm and about 830 nm, preferably having a main emission peak having a longer wavelength than the main absorption peak. More preferably, the optical brighteners useful herein have a main absorption peak at a wavelength between about 200 nm and about 420 nm,
It has a main emission peak at a wavelength between about 400 nm and about 780 nm. Optical brighteners may or may not have a small absorption peak in the visible range of wavelength between about 360 nm and about 830 nm. Optical brighteners are sometimes referred to in the art and other industries by other names, such as fluorescent whitening agents, fluorescent brighteners, and fluorescent dyes.

When applied to hair via a suitable medium, the optical brighteners herein benefit hair in three areas. First, the optical brightener herein is:
The hair color is changed by the radiation in the visible region. Second, the optical brighteners herein enhance the gloss of hair by radiation in the visible region. Third, the optical brightener herein protects hair from ultraviolet radiation by absorbing it.

Optical brighteners are generally based on aromatic and heteroaromatic structures that provide these unique characteristics. Optical brighteners useful in the present invention can be classified according to their basic structure, as described below. Preferred optical brighteners herein include polystyrylstilbene, triazinestilbene, hydroxycoumarin, aminocoumarin, triazole, pyrazoline, oxazole, pyrene, porphyrin and imidazole, more preferably polystyrylstilbene and triazinestilbene. No.

The optical brightener herein is preferably from about 0.001% to about 20%
, More preferably from about 0.01% to about 10% by weight level in the hair care compositions of the present invention.

Polystyrylstilbene Polystyrylstilbene is a class of compounds having two or more of the following basic structures.

[0019]

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The polystyryl stilbenes useful in the present invention are of the formula (1) wherein R ¹⁰¹ is H, OH, SO ₃ M, COOM, OSO ₃ M, OPO (OH) OM, where M is H, Na, K, Ca, Mg, ammonium, mono-, - di -, tri - or tetra -C ₁ -C ₃₀ alkylammonium, mono-, - di - or tri -C ₁ -C ₃₀ - hydroxyalkyl ammonium or, Ammonium which is di- or tri-substituted by a mixed group of a C ₁ -C ₃₀ alkyl group and a C ₁ -C ₃₀ -hydroxyalkyl group), SO ₂ N (C ₁ -C ₃₀ alkyl) ₂ , O - (C ₁ ~C ₃₀ alkyl), CN, Cl, COO ( C 1 ~C 30 alkyl), CON (C ₁ ~C ₃₀ alkyl) ₂ or ^{_{O (CH 2) 3 N +}} (CH 3) 2 X - (wherein X ^- is chloride Bromide, iodide, formate, acetate, propionate, glycolate, lactate, acrylate, methanephosphonate, phosphite anion, dimethyl or diethyl phosphite anion), CN or Alkyl having 1 to 30 carbons, R ¹⁰² and R ¹⁰³ are independently H, SO ₃ M (where M is as defined above), and x is 0 or 1 (In this case, the compound has a trans or co-planar orientation.) Preferably, x is 1, R ¹⁰¹ is SO ₃ Na, and R ¹⁰² and R ¹⁰³ are H, wherein , The compound has a trans-coplanar orientation), (2) wherein R ¹⁰⁴ and R ¹⁰⁵ are independently CN, COO (C ₁ -C ₃₀ alkyl), CONHC ₁ -C ₄ alkyl, or CON (C _{1 ~C 4} alkyl) ₂ Some (in this case, the compound has a trans coplanar orientation or cis flush Oriented). Preferably, R ¹⁰⁴ and R ¹⁰⁵ is 2-cyano, in this case,
The compound has a trans coplanar orientation) and (3) (wherein each R ¹⁰⁶ is independently H or alkyl having 1 to 30 carbons), wherein the compound is trans coplanar or cis identical. Having a planar orientation, and preferably having a trans-coplanar orientation).

[0021]

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[0022]

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[0023]

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Suitable polystyryl stilbenes include Ciba Specialty Chemicals (Cib)
a Disodium-1,4'-bis (2-sulfostyryl) bisphenyl of Tinopal CBS-X (Color Index Fluorescent Brightener 351) available from Specialty Chemicals, available from BASF (BASF) Product name Ultraphor RN
1,4-bis (2-cyanostyryl) benzene (Color Index Fluorescent Brightener 199).

Triazine stilbene Triazine stilbene is a class of compounds having both a triazine structure and a stilbene structure in the same molecule.

[0026] Useful triazine stilbenes in the present invention, in the following formula (4) (wherein, R ^{10 7} and R ¹⁰⁸ are independently phenylamino, mono - or disulfonated phenylamino, morpholino, N (CH ₂ CH ₂ OH) ₂ , N (CH ₃ ) (CH ₂ CH ₂ OH),
NH ₂ , N (C ₁ -C ₄ alkyl) ₂ , OCH ₃ , Cl, NH— (CH ₂ ) _1-4 SO ₃ H or NH— (CH ₂ ) _1-4 OH, and An ⁻ is carboxy Is an anion of a rate, sulfate, sulfonate or phosphate, wherein M is as previously defined (in this case, the compound has a trans or cis coplanar orientation). Preferably, R ¹⁰⁷ is 2,5-disulfophenylamino and each R ¹⁰⁸ is morpholino. Alternatively, each R ¹⁰⁷ is 2,5-disulfophenylamino and each R ¹⁰⁸ is N (C ₂ H ₅ ) ₂ . Alternatively, each R ¹⁰⁷ is 3-sulfophenyl, and each R ¹⁰⁸ is NH (CH ₂ CH ₂ OH) or N (CH ₂ CH ₂ OH) ₂ . Alternatively, each R ¹⁰⁷ is a 4-sulfophenyl, each R ¹⁰⁸ is _{N (C H 2 CH 2 OH} ) 2, in each case, the sulfo group is SO ₃ M (in which M is sodium ), In which case the compounds have trans-coplanar orientation).

[0027]

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Suitable triazine stilbenes include Tinopearl (trade name) available from Ciba Specialty Chemicals.
(Tinopal) 4,4'-bis-[(4-anilino-6-bis (2-hydroxyethyl) amino-1,3,5-triazin-2-yl) amino] stilbene-2,2 of UNPA-GX '-Disulfonic acid, 4,4'-bis-[(4-anilino-6-morpholine-1,3,5) under the trade name Tinopal AMS-GX, available from Ciba Specialty Chemicals. -Triazin-2-yl) amino] stilbene-2,2'-disodium sulfonate, 4,4'-bis- [Tinopal 5BM-GX trade name available from Ciba Specialty Chemicals] (4-anilino-6- (2-hydroxyethyl) methylami -1,3,5-triazin-2-yl) amino] stilbene-2,2'-disodium sulfonate, 4 ', 4-bis - [(4
, 6-Dianilino-1,3,5-triazin-2-yl) amino] stilbene-2,2'-disodium sulfonate, 4,4'-bis-[(4-anilino-6methylamino-1,3 , 5-Triazin-2-yl) amino] stilbene-2,2'-disodium sulfonate, 4,4'-bis-[(4-anilino-6-ethylamino-1,3,5-triazine-2- Yl) amino] stilbene-2,2 ′ disodium sulfonate and 4,4′-bis (4-phenyl-1,2,3
-Triazol-2-yl) stilbene-2,2 'disodium sulfonate.

Hydroxycoumarin Hydroxycoumarin is a compound having the following basic coumarin structure and having at least one hydroxy moiety.

[0030]

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The hydroxycoumarone useful in the present invention is represented by the following formula (5), wherein R ²⁰¹ is H, OH, Cl, CH ₃ , CH ₂ COOH, CH ₂ SO ₃ H, CH ₂ OSO a ₃ H or _{CH 2 OPO (OH) OH,} R 202 is, H, phenyl, a group of the COO-C ₁ ~C _{3 0} alkyl, glucose, or the following formula (6), R ²⁰³ is, OH or a O-C ₁ ~C ₃₀ alkyl, R ²⁰⁴ is, OH, a group of the O-C ₁ ~C ₃₀ alkyl, glycoside, or the following formula (7), R ²⁰⁵ and R ^206, which independently phenyl amino, mono - or disulfonated phenylamino, _{morpholino, N (CH 2 C H 2} OH) 2, N (CH 3) (CH 2 CH 2 OH), NH 2, N (C 1 ~C 30 alkyl) _{2, OCH 3, Cl, NH- (CH} 2) 1~4 SO 3 H or NH- ( Including those of CH ₂₎ a _{1 to 4} OH).

[0032]

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[0033]

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[0034]

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Suitable hydroxycoumarins include 6,7-dihydroxycoumarin available from Wako Chemicals, 4-methyl-7-hydroxycoumarin available from Wako Chemicals, Wako Pure Chemicals (Wako Chemicals).
4-methyl-6,7-dihydroxycoumarin available from Wako Chemicals, esculin available from Wako Chemicals, and umbelliferone (4-hydroxycoumarin) available from Wako Chemicals. Can be

Aminocoumarins Aminocoumarins are compounds having a basic coumarin structure and having at least one amino group moiety.

The aminocoumarins useful in the present invention are of the formula (8) wherein R ²⁰⁷ is H, Cl, CH ₃ , CH ₂ COOH, CH ₂ SO ₃ H, CH ₂ OSO ₃ H or CH ₂ OPO (OH) OH; R ²⁰⁸ is H, phenyl or COOC ₁ -C ₃₀ alkyl; R ²⁰⁹ and R ²¹⁰ are independently H, NH ₂ , N (C ₁ -C ₃₀ alkyl) ₂ , including those of N HC ₁ -C ₃₀ alkyl or NHCOC ₁ ~C ₃₀ alkyl).

[0038]

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Suitable aminocoumarins include 4-methyl-7,7′-diethylaminocoumarin, trade name Calcofluor-RWP, available from BASF, Calcofluor-L, trade name available from BASF.
4-methyl-7,7'-dimethylaminocoumarin of D;

Triazoles Triazoles are compounds having the following basic structure.

[0041]

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The triazoles useful in the present invention are represented by formulas (9) to (12) and (15)
To (20).

[0043]

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Wherein R ³⁰¹ and R ³⁰² are independently H, C ₁ -C ₃₀ alkyl, phenyl or monosulfonated phenyl, and An ⁻ and M are as previously defined (wherein If the compound has a trans-coplanar or cis-coplanar orientation)
. Preferably, R ³⁰¹ is phenyl, R ³⁰² is H, and M is sodium, wherein the compound has a trans-coplanar orientation.

[0045]

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Wherein R ³⁰³ is H or Cl, R ³⁰⁴ is SO ₃ M, SO ₂ N (C ₁ -C ₃₀ alkyl) ₂ , SO ₂ O-phenyl or CN, and R ³⁰⁵ is , H, SO ₃ M, C
OOM, OSO ₃ M, or OPO (OH) OM, where M is as previously defined (where the compound has a trans or cis coplanar orientation). Preferably, R ³⁰³ and R ³⁰⁵ are H and R ³⁰⁴ is SO ₃ M (
Where M is Na), where the compound has a trans-coplanar orientation)

[0047]

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(Wherein each R³⁰⁶And R³¹²Is independently H, a sulfonic acid group or a salt thereof,
Or amide, carboxylic acid group or its salt, ester or amide, cyano group
A halogen atom, an unsubstituted or substituted alkylsulfonyl, an arylsulfonyl,
Alkyl, alkoxy, aralkyl, aryl, aryloxy, aralkoxy
Or a cycloalkyl group, two or three nitrogen atoms or one oxygen atom and one or
Represents an unsubstituted or substituted 5-membered heterocyclic ring containing two nitrogen atoms. Alternatively, R ³⁰⁷ And R³¹³Methylenedioxy, ethylenedioxy, methylenedioxy
Xymethyleneoxy, trimethylene, tetramethylene, propenylene, butenile
Or a butadienylene group. Each R³⁰⁷And R³¹³Is independently H, sulfone
Acid group or its salt, ester or amide, carboxylic acid group or its salt, ester
Or amide, cyano group, halogen atom, unsubstituted or substituted alkyl or
It represents a lucoxy group. Alternatively, R³⁰⁶And R³¹²Along with methylenedioxy
, Ethylenedioxy, methyleneoxymethyleneoxy, trimethylene, tetrame
Represents a tylene, propenylene, butenylene or butadienylene group. Each R³⁰⁸And R³¹⁴Represents independently H, a halogen atom or an unsubstituted or substituted alkyl group. Each R³⁰⁹And R³¹¹Is independently H, a halogen atom, a cyano group, a sulfonic acid
Groups or salts thereof, esters or amides, or carboxylic acid groups or salts thereof,
Indicates an ester or amide. R³¹⁰Independently represents H, a halogen atom, a cyano group, a sulfonic acid group or a salt thereof. Here, the alkyl group is preferably hydroxy
, Alkoxy having 1 to 30 carbon atoms, cyano, halogen, carboxy, sulfone
Carboxalkoxy having 1 to 30 carbon atoms in the acid group and the alkoxy moiety
), Phenyl or phenoxy. The alkoxy group is
Roxy, alkoxy having 1 to 30 carbon atoms, cyano, halogen, carboxy, a
Carbalkoxy, phenyl or phenyl having 1 to 30 carbon atoms in the alkoxy group portion.
Can be replaced by enoxy. Phenyl, phenylalkyl or phenoxy
The group has a halogen, cyano, carboxy or alkoxy group moiety having 1 to 1 carbon atom.
30 carbalkoxy, sulfo, or alkyl each having 1 to 30 carbon atoms
(Where the compound is trans-coplanar)
Orientation or cis-coplanar orientation). Possible cycloalkyl groups are preferably
Is cyclohexyl and cycloalkyl which can be substituted by alkyl having 1 to 30 carbon atoms.
It is a clopentyl group. Possible 5-membered heterocyclic rings have from 1 to 1 carbon atoms as substituents.
4 carbon atoms of alkyl group, halogen, phenyl, carboxy, alkoxy moiety
Carboalkoxy, cyano, benzyl having 1 to 30 carbon atoms,
V-triazole, ox, which can include lucoxy, phenoxy or sulfo
Sazol or 1,3,4-oxadiazole group. Here, triazole
And the two adjacent substituents of the oxazole group together are a substituted or unsubstituted fused base.
It is possible to form benzene nuclei where the compound is trans-coplanar
With direction)

[0049]

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Wherein Q ¹ represents ^one of the ring systems (13) or (14)

[0051]

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[0052]

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(Wherein, R ³¹⁷ is H, an alkyl group having 1 to 30 carbon atoms, cyclohexyl, phenylalkyl having an alkyl moiety of C _{1 to} C ₃₀ carbon atoms, phenyl, alkoxy having 1 to 30 carbon atoms) Or Cl, or together with R ³¹⁸ , alkylene having 3 to 30 carbon atoms, R ³¹⁸ represents H or alkyl having 1 to 30 carbon atoms, or R ³¹⁷ . Represents alkylene having 3 to 30 carbon atoms, R ³¹⁹ represents H or methyl, R ³²⁰ represents H, alkyl having 1 to 30 carbon atoms, phenyl, alkoxy having 1 to 30 carbon atoms, or Represents Cl or a condensed benzene ring together with R ^321. R ³²¹ represents H or Cl or a condensed benzene ring together with R ^320. R ³¹⁵ is H and has 1 carbon atom
-30 alkyl, C1-C30 alkoxy or Cl. R ³¹⁶ represents H or Cl; Q ² represents H, Cl, alkyl having 1 to 30 carbon atoms, or phenyl; Q ³ represents H or Cl; With coplanar or cis coplanar orientation, preferably trans coplanar orientation)

[0054]

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[0055]

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Wherein R ³²² represents H, Cl, methyl, phenyl, benzyl, cyclohexyl or methoxy; R ³²³ represents H or methyl; Z represents O or S; The compound has a trans coplanar orientation or a cis coplanar orientation, preferably a trans coplanar orientation)

[0057]

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[0058]

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[0059]

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[0060]

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(Wherein, R ³²⁴ represents H, Cl, alkyl having 1 to 30 carbon atoms, phenylalkyl having 1 to 30 carbon atoms, phenyl or alkoxy having 1 to 30 carbon atoms, or R ³²⁴ represents a condensed benzene group together with R ^325. R ³²⁵ represents H or methyl, or R ³²⁵ represents a condensed benzene group together with R ³²⁴ .
R ³²⁶ represents H, alkyl having 1 to 30 carbon atoms, alkoxy having 1 to 30 carbon atoms, Cl, carboalkoxy having 1 to 30 carbon atoms or alkylsulfonyl having 1 to 30 carbon atoms, and R ³²⁷ represents H, Cl, methyl or methoxy, in which formula the compound has a trans or cis coplanar orientation, preferably a trans coplanar orientation)

Suitable triazoles include 2- (4-styryl-3-sulfophenyl) -2H-naphtho, available from Ciba Specialty chemicals under the trade name Tinopal RBS.
[1,2-d] triazole (color index fluorescent brightener 46).

Pyrazolines Pyrazolins are compounds having the following basic structure.

[0064]

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The pyrazolines useful in the present invention are represented by the following formula (21), wherein R ⁴⁰¹ is H 2, Cl or N (C ₁ -C ₃₀ alkyl) ₂ , and R ⁴⁰² is H, Cl, SO ₃ M (
Where M is as defined _{previously), SO 2 NH 2, SO} 2 NH- (C 1 ~C 30 alkyl), COO-C _{1 ~C 30} alkyl, SO ₂ -C ₁ ~C ₃₀ alkyl , SO ₂ N
^{_{H (CH 2) 1~4 N +}} (CH 3) 3 or _{SO 2 (CH 2) 1~4 N} + H (C 1 ~C 30 alkyl) ₂ An ^- (wherein An ^- is defined in the previous R ⁴⁰³ and R ⁴⁰⁴ are the same or different and are each H, C ₁ -C ₃₀ alkyl or phenyl, and R ⁴⁰⁵ is H or Cl. Preferably, R ⁴⁰¹ is Cl, R ⁴⁰² is SO ₂ CH ₂ CH ₂ N ⁺ H (C ₁ -C ₄ alkyl) ₂ An ⁻ where An ⁻ is a phosphite, R ⁴⁰³ , R ⁴⁰⁴ and R ⁴⁰⁵ is each H), and those of formulas (22) and (23).

[0066]

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[0067]

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[0068]

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Suitable pyrazolines include 1- (4-amidosulfonylphenyl) -3- (4-chlorophenyl) -2-pyrazoline (Blankophor DCB trade name available from Bayer) (color index fluorescent brightener 121), 1- [4- (2-sulfoethylsulfonyl) phenyl]-
3- (4-chlorophenyl) -2-pyrazolin, 1- [4- (2-sulfoethylsulfonyl) phenyl] -3- (3,4-dichloro-6-methylphenyl) -2
-Pyrazolin, 1- <4- {N- [3- (N, N, N-trimethylammonio)
Propyl] -amidosulfonyl} phenyl> -3- (4-chlorophenyl) -2
Pyrazoline methyl sulfate, and 1- <4- {2- [1-methyl-2-
(N, N-dimethylamino) ethoxy] ethylsulfonyl {phenyl> -3- (
4-chlorophenyl) -2-pyrazoline methyl sulfate.

Oxazole Oxazole is a compound having the following basic structure.

[0071]

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The oxazoles useful in the present invention are represented by the following formula (24):⁵⁰¹And R⁵⁰²Is independently H, Cl, C₁~ C₃₀Alkyl or SO_Two-C₁~ C₃₀Archi
(In this case, the compound has a trans or cis coplanar orientation.
Have). Preferably, R⁵⁰¹Is 4-CH_ThreeAnd R⁵⁰²Is 2-CH_ThreeAnd this
Wherein the compound has a trans-coplanar orientation), formula (25), wherein R⁵⁰³ Is independently H, C (CH_Three)_Three, C (CH_Three)_Two-Phenyl, C₁~ C₃₀Alkyl or COO-C₁~ C₃₀Alkyl, preferably H, Q_FourIs -CH = CH-
Alternatively, the following equation (25-1), equation (25-2), equation (25-3) or equation (2)
5-4), preferably formula (25-4) or one of the rings
Two R⁵⁰³The group is 2-methyl and the other R⁵⁰³The group is H and Q^FourIs -CH = CH-, or one R in each ring⁵⁰³The group is 2-C (CH_Three)_ThreeAnd the other R⁵⁰³The group is H, in which the compound has a trans-coplanar or cis-coplanar orientation, and preferably has a trans-coplanar orientation),
Formula (26) (wherein, R⁵⁰⁴Is CN, Cl, COO-C₁~ C₃₀Alkyl or
Enyl and R⁵⁰⁵And R⁵⁰⁶Is an atom required to form a fused benzene ring
Or R⁵⁰⁶And R⁵⁰⁸Is independently H or C₁~ C₃₀Alkyl and R⁵⁰⁷Is H, C₁~ C₃₀Alkyl or phenyl (in this case the compound
Objects have a trans-coplanar or cis-coplanar orientation). Preferably, R ⁵⁰⁴ Is a 4-phenyl group, and each R⁵⁰⁵-R⁵⁰⁸Is H, in which case the compound has a trans-coplanar orientation), and formula (27), wherein R⁵⁰⁹Is H, C1, alkyl having 1 to 30 carbon atoms, cyclohexyl, carbon atom in the alkyl moiety
Phenylalkyl having 1 to 3 carbon atoms, phenyl or alkoxy having 1 to 30 carbon atoms
And R⁵¹⁰Represents H or alkyl having 1 to 30 carbon atoms;_FiveIs
(Formula 27-1) or (Formula 27-2) (wherein R⁵¹¹Is H, alkyl having 1 to 30 carbon atoms, alkoxy having 1 to 30 carbon atoms, Cl, 1 to 30 carbon atoms.
Carboalkoxy, unsubstituted sulfamoyl, or alkyl having 1 to 30 carbon atoms
Sulfamoi mono- or disubstituted by kill or hydroxyalkyl
Or alkylsulfonyl having 1 to 30 carbon atoms)
In this formula, the compound is trans coplanar or cis coplanar.
And preferably has a trans-coplanar orientation).

[0073]

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[0074]

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[0075]

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[0076]

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[0077]

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[0078]

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Suitable oxazoles include 4,4′-bis (5-methylbenzoxazole-
2-yl) stilbene and 2- (4-methoxycarbonylstyryl) benzoxazole.

Pyrenes The pyrenes useful in the present invention include compounds of the following formula (28), wherein each R ⁶⁰¹ is independently C ₁ -C ₃₀ alkoxy, preferably ethoxy: Wherein each R ⁶⁰² is independently H, OH, SO ₃ M, where M is as defined above, or sulfonated phenylamino, ie, sulfonated anilino. Include.

[0081]

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[0082]

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Suitable pyrenes include Fluorite XMF 2,4
-Dimethoxy-6- (1'-pyrenyl) -1,3,5-triazine (color index fluorescent brightener 179), pyrene 8-hydroxy-1,3,6-trisulfonate (D & C Green (D & C Green) ) No. 8), and pyrene 3-hydroxy-5,8,10-trisulfanilate.

Porphyrins Porphyrins useful in the present invention are represented by the following formulas (30), (31), wherein R ⁷⁰¹ is CH ₃ or CHO, and R ⁷⁰² is H or COOC ₁ -C ₃₀ alkyl. , R ⁷⁰³ is H or an alkyl group having 1 to 30 carbon atoms) and formula (32), wherein each R ⁷⁰⁴ is independently H, SO ₃ M, COOM, OSO ₃ M, OPO (OH) OM (where M is as defined above), halide or alkyl having 1 to 30 carbon atoms, and Q ⁶ is Cu, Mg, Fe, Cr, Co having a cationic charge or a mixture thereof. Which is a group).

[0085]

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[0086]

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[0087]

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Suitable porphyrins include porphyrins available from Wako Chemicals, and copper II phthalocyanines available from Wako Chemicals.

Imidazoles Imidazoles are compounds having the following basic structure.

[0090]

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[0091] Imidazoles useful in the present invention include those having the following formula (33), wherein X is as defined above.

[0092]

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Suitable imidazoles include the trade name Color Index Fluorescent Brightener 352
, A Uvtex A (Uvtex A) available from Ciba Specialty Chemical.
T).

Compositions Hair care compositions of the present invention can comprise materials that characterize the form of the product. Product forms useful herein include, but are not limited to, shampoos, conditioners, treatments, mousses, sprays, lotions, gels and cream products. All of them can be designed for "rinse-off" or "leave-on" convenience. Product features useful in the present invention include, but are not limited to, cleansing and conditioning products. Materials and their levels are selected by those skilled in the art depending on the required properties of the product.

Hair Care Conditioning Agent The composition of the present invention comprises a hair conditioning agent selected from the group consisting of silicone compounds, cationic compounds, water-insoluble high melting point compounds, fragrance compounds, high molecular weight oily compounds and mixtures thereof. . The hair conditioning compositions herein provide good conditioning benefits such as good combing, smoothness, and reduced static. Preferably, the hair conditioning agent is included in the composition at a level from about 0.01% to about 20% by weight.

Silicone Compounds Silicone compounds are useful hair conditioning agents herein and are preferably included at a level of about 0.01% to about 15%. Silicone compounds useful herein include volatile soluble or insoluble, nonvolatile soluble or insoluble silicone conditioning agents. Soluble means that the silicone compound mixes with the carrier of the composition to form part of the same phase. Insoluble is
It means that the silicone forms a discrete phase separate from the carrier, such as in the form of an emulsion or suspension of silicone drops. The silicone compounds herein can be prepared by any suitable method known in the art, including emulsion polymerization. The silicone compound can be further incorporated into the composition in the form of an emulsion. Here, the emulsion is mechanically, with or without the aid of a surfactant selected from the group consisting of anionic surfactants, nonionic surfactants, cationic surfactants and mixtures thereof. It is produced by mixing or at the stage of synthesis via emulsion polymerization.

[0097] In one embodiment, the silicone compounds useful herein are high molecular weight silicone compounds. High molecular weight silicone compounds useful herein include from about 1,000 to about 2,000,000 centistokes at 25 ° C.
More preferably, it has a viscosity of from about 10,000 to about 1,800,000, even more preferably from about 100,000 to about 1,500,000. Viscosity, 1970 7
It can be measured by a glass capillary viscometer as specified in Dow Corning's in-house test method CTM 004 on March 20. High molecular weight silicone compounds can be prepared by emulsion polymerization. Suitable silicone fluids include polyalkylsiloxanes , Polyaryl siloxanes, polyalkylaryl siloxanes, polyether siloxane copolymers, and mixtures thereof Other non-volatile silicone compounds having hair conditioning properties can also be used.

[0098] The silicone compound herein is preferably used at a level of about 0.1% to about 60%, more preferably about 0.1 to about 40% by weight of the composition.

The silicone compounds herein include polyalkylsiloxanes of the following structure (I) wherein R ⁹³ is alkyl or aryl and x is an integer from about 7 to about 8,000: Also included are polyarylsiloxanes. “Z ⁸ ” represents a group that closes both ends of the silicone chain. The alkyl or aryl group (R ⁹³ ) substituted on the siloxane chain or the alkyl or aryl group (Z ⁸ ) substituted at both ends of the siloxane is such that the resulting silicone remains fluid at room temperature, Is non-irritating, toxic or harmful when applied to hair, is compatible with other materials of the composition, is chemically stable under normal use and storage conditions, and can adhere to hair Yes, as long as the hair is conditioned. Suitable Z ⁸ groups include hydroxy, methyl, methoxy, ethoxy, propoxy and aryloxy. The two R ⁹³ groups on a silicon atom can represent the same or different groups. Preferably, the two R ⁹³ groups represent the same group. Suitable ^R93 groups include methyl, ethyl, propyl, phenyl, methylphenyl and phenylmethyl. Preferred silicone compounds are polydimethylsiloxane, polydiethylsiloxane and polymethylphenylsiloxane. Polydimethylsiloxane, also known as dimethicone, is particularly preferred. Polyalkylsiloxanes that can be used include, for example, polydimethylsiloxane. These silicone compounds are available, for example, from the General Electric Company in the Viscasil® and SF96 series, and from Dow Corning in the Dow Corning.
ning) 2000 series.

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[0101] Polyalkylaryl siloxane fluids can also be used, and include, for example, polymethylphenyl siloxane. These siloxanes
For example, General Electric Comp (General Electric Comp)
any.) as SF-1075 methylphenyl fluid or from Dow Corning as 556 Cosmetic Grade Fluid.

Highly arylated silicone compounds, such as highly phenylated polyethyl silicones, having a refractive index of about 1.46 or more, especially about 1.52 or more, are particularly preferred for enhancing gloss properties. When using these high refractive index silicone compounds, they should be mixed with a spreading agent, such as a surfactant or a silicone resin, as described below, to reduce the surface tension of the material and increase film forming capabilities. It is.

Examples of the silicone compound that can be used include polypropylene oxide-modified polydimethylsiloxane. However, ethylene oxide or a mixture of ethylene oxide and propylene oxide can also be used. The levels of ethylene oxide and propylene oxide need to be low enough to not interfere with the dispersibility of the silicone. These materials are also known as dimethicone copolyols.

Other silicone compounds include amino-substituted materials. Suitable alkylamino-substituted silicone compounds have the following structure (II), wherein R ⁹⁴ is
H, CH ₃ or OH, where p ¹ , p ² , q ¹ and q ² are integers depending on the molecular weight whose average molecular weight is between about 5,000 and 10,000) Things. This polymer is also known as "Amodimethicone".

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Suitable amino-substituted silicone fluids are of formula (III) wherein G is selected from the group consisting of hydrogen, phenyl, OH, C ₁ -C ₈ alkyl, preferably methyl, and a is 0 Or represents an integer of 1 to 3, preferably equal to 0. b represents 0 or 1, and preferably equal to 1. The sum of p ³ + p ⁴ is a number of 1 to 2,000, preferably 50 to 150. and a, p ³ is 0～1,999 preferably may represent a number of forty-nine to one hundred and forty-nine, p ⁴ is 1 to 2,000, preferably can represent integer from 1 to 10 there .R ⁹⁷ is wherein _{C q3} H 2q3 L (wherein, q ³ is an integer of 2 to 8, L _{^{is, -N (R 96) CH 2}} -CH 2 -N (R 96) 2, - N ( ^R96 ) ₂ , -N
(R ⁹⁶ ) ₃ X ′, —N (R ⁹⁶ ) CH ₂ —CH ₂ —NR ⁹⁶ H ₂ X ′ (where R ⁹⁶ is selected from the group consisting of hydrogen, phenyl, benzyl, and a saturated hydrocarbon group; Preferably, it is an alkyl group having 1 to 20 carbon atoms, and X ′ is a monovalent group selected from the group consisting of:

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A particularly preferred amino-substituted silicone corresponding to formula (II) is the polymer of the above formula, wherein R ⁹⁴ is CH ₃ , also known as “trimethylsilyl amodimethicone”.

Other amino-substituted silicone polymers that can be used are of the following formula (V
) (Where R⁹⁸Is a monovalent hydrocarbon group having 1 to 18 carbon atoms, preferably methyl
Represents an alkyl or alkenyl group. R⁹⁹Is a hydrocarbon group, preferably C ₁ ~ C₁₈Alkylene group or C₁~ C₁₈Alkyleneoxy group, more preferably C₁ ~ C₈Q represents an alkyleneoxy group;^-Is a halide ion, preferably chloride
Thing, p^FiveRepresents the average statistic of 2-20, preferably 2-8, p⁶Is 2
0 to 200, preferably representing an average statistic of 20 to 50). This
A preferred polymer of the type is available from Union Carbide under the trade name "UCAR SILICONE ALE56".

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References disclosing suitable non-volatile dispersing silicone compounds include US Pat. No. 2,826,551 to Green, and US Pat. No. 3,964,500; U.S. Pat. No. 4,364,837 to Pader;
, and British Patent No. 849,433. "Silicon Compounds," distributed by Petrarch Systems (Inc.) in 1984, provides an extensive, but not exclusive, listing of suitable silicone compounds.

Another particularly useful non-volatile dispersed silicone is silicone rubber. As used herein, the term "silicone rubber" refers to
A polyorganosiloxane material having a viscosity of 2,000 centistokes or more. It is also recognized that the silicone rubbers described herein may have some overlap with the silicone compounds disclosed above. This overlap is not to be considered a limitation on any of these materials. Silicone rubber is available from Petralk
Arch), and U.S. Patent No. 4,152,416 issued May 1, 1979 to Spitzer et al., and "Noll Walter, Chemistry and Technology of Silicones,
New York, Academic Press 1968 "and others. General Electric Silicon
Ne Rubber Product Data Sheets SE30, SE33, SE54 and SE76 also describe silicone rubber. "Silicone rubber" typically has a mass molecular weight of greater than about 200,000, generally between about 200,000 and about 1,000,000. Specific examples include polydimethylsiloxane, poly (dimethylsiloxane-methylvinylsiloxane) copolymer,
Poly (dimethylsiloxane-diphenylsiloxane-methylvinylsiloxane)
And copolymers and mixtures thereof.

[0113] Silicone resins that are highly cross-linked polymeric siloxanes are also useful. Crosslinking is introduced through the incorporation of trifunctional and tetrafunctional silanes into monofunctional or difunctional silanes or both during the production of the silicone resin. As is well understood in the art, the degree of crosslinking required to form a silicone resin depends on the particular silane units incorporated into the silicone resin.
In general, silicone materials having a sufficient level of tri- and tetra-functional siloxane monomer units to dry to a hard or high contrast film, and thus a sufficient level of cross-linking, are considered silicone resins. The ratio of oxygen atoms to silicon atoms is indicative of the level of crosslinking in a particular silicone material. A silicone material of at least about 1: 1 oxygen atoms to silicon atoms is generally a silicone resin herein. Preferably, the ratio of oxygen atoms to silicon atoms is at least about 1.2: 1.0. Silanes used in the production of silicone resins include:
Mention is made of monomethyl-, dimethyl-, trimethyl-, monophenyl-, diphenyl-, methylphenyl-, monovinyl-, and methylvinyl-chlorosilane and tetrachlorosilane, with methyl-substituted silanes being the most commonly used.
Preferred resins are sold by General Electric as GE SS4230 and SS4267. Commercially available silicone resins are generally supplied in dissolved form in low viscosity volatile or non-volatile silicone fluids. The silicone resins used herein should be supplied and formulated into the composition in such a dissolved form, as will be readily apparent to those skilled in the art. Without being bound by theory, it is believed that the silicone resin can enhance the adhesion of other silicone compounds to the hair, and can enhance the gloss of the hair by the high refractive index portions.

[0114] Other useful silicone resins are silicone resin powders, such as materials given the CTFA designation polymethylsilsequioxane, from Toshiba Silicone to Tospearl (TM). ).

The method for producing these silicone compounds is described in “Encyclopedia of Polymer Science and Engineering, Vol.
Ume15, Second Edition, pp204-308, John
Wiley & Sons, Inc. , 1989 ".

[0116] Silicone materials and silicone resins can be conveniently identified, inter alia, by an abbreviated terminology well known to those skilled in the art as the "MDTQ" term. In this system, the silicone is described by the presence of the various siloxane monomer units that make up the silicone. Briefly, the symbol M represents a monofunctional unit (CH ₃ ) ₃ SiO _0.5 , D represents a bifunctional unit (CH ₃ ) ₂ SiO, T represents a trifunctional unit (CH ₃ ) SiO _1.5 , Q Represents a 4- or tetra-functional unit SiO ₂ . The initials of unit symbols, for example, M ', D'T' and Q 'represent substituents other than methyl and must be clearly defined at each occurrence. Typical alternative substituents include groups such as vinyl, phenyl, amino, hydroxy, and the like. Either the molar ratio of the various units with respect to the subscript to the symbol indicating the total number or average of each type of units in the silicone, or the molar ratio of the various units as a ratio explicitly indicated in combination with the molecular weight is Complete the description of silicone materials in MTDQ systems. A higher relative molar amount of T, Q, T 'and / or Q' to D, D'M and / or M 'in the silicone resin is indicative of a higher level of crosslinking. However, as mentioned above, the overall level of crosslinking can also be dictated by the oxygen to silicone ratio.

Preferred silicone resins used herein are MQ, MT, MTQ
, MQ and MDTQ resins. Thus, the preferred silicone substituent is methyl. MQ resins having an M: Q ratio of about 0.5: 1.0 to about 1.5: 1.0 and an average molecular weight of the resin of about 1,000 to about 10,000 are particularly preferred.

Particularly suitable silicone compounds herein are non-volatile silicone oils having a molecular weight of about 200,000 to about 600,000, such as dimethicone and dimethiconol. These silicone compounds can be incorporated into the present compositions as solutions of volatile or non-volatile silicone oils.

Commercially available silicone compounds useful herein include Dow Corning (
DC3, available from Dow Corning Corporation
45 dimethicone, a solution of dimethicone rubber under the trade names SE30, SE33, SE54 and SE76 available from General Electric, Dow Corning Corpora
trade names DCQ2-1403 and DCQ2-1401
And the emulsion polymerized dimethiconol available from Toshiba Silicone as described in GB Application No. 2,303,857.

Cationic Compounds Cationic compounds useful herein include cationic polymers and cationic surfactants. Preferably, the cationic compound has no fluorescent properties, and
. Present at levels from 01% to about 10%.

Cationic Polymer As used herein, the term “polymer” is intended to include a material (ie, a copolymer) made by the polymerization of one monomer or made by more than one monomer. And

[0122] Preferably, the cationic polymer is a water-soluble cationic polymer. “Water-soluble cationic polymer” is a polymer that is sufficiently soluble in water (distilled water or equivalent water) at 25 ° C. to form a substantially clear solution to the naked eye at a concentration of 0.1%. Means Preferred polymers are sufficiently soluble to form a substantially clear solution at a concentration of 0.5%, more preferably at a concentration of 1.0%.

The cationic polymers herein generally have a weight average molecular weight of at least about 5,000, typically at least about 10,000, and less than about 10,000,000. Preferably, the molecular weight is between about 100,000 and about 2,000.
, 000. Cationic polymers generally have a cationic nitrogen-containing moiety, such as a quaternary ammonium or cationic amino moiety and mixtures thereof.

The cationic charge density is preferably at least about 0.1 meq / gram, more preferably at least about 1.5 meq / gram, even more preferably at least about 1.1 meq / gram, and even more preferably at least 1.2meq /
Gram. The cationic charge density of the cationic polymer can be measured by the Kjeldahl method. One skilled in the art will recognize that the charge density of the amino-containing polymer will vary depending on the pH and isoelectric point of the amino groups. The charge density should be within the above mentioned limits at the pH of the intended application.

[0125] Any anion counterion can be utilized for the cationic polymer, as long as it meets the criteria for water solubility. Suitable counterions include halides (eg, Cl, Br, I or F, preferably Cl, Br or I), sulfate and methyl sulfate. The ones listed here are not exclusive and other ones can be used.

The cationic nitrogen-containing moiety is generally present as a substituent on a portion of the total monomer units of the cationic hair conditioning polymer. Thus, the cationic polymer can comprise copolymers, terpolymers, and the like of quaternary ammonium units or cationic amine-substituted monomer units, referred to herein as spacer monomer units, and other non-cationic units. Such polymers are known in the art and include the CTFA Cosmetic Ingredient Dictionary, 3rd edition, edited by Estr.
in, Crosley, and Haynes (The Cosmetic, To
iletry, and Fragrance Association, Inc.
, Washington, D.C. C. , 1982).

Suitable cationic polymers include, for example, vinyl monomers having a cationic amine or quaternary ammonium functionality, and acrylamide, methacrylamide, alkyl and dialkylacrylamide, alkyl and dialkylmethacrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone and Copolymers with water-soluble spacer monomers such as vinylpyrrolidone. The alkyl and dialkyl substituted monomers preferably have C ₁ -C ₇ alkyl groups, more preferably C ₁ -C ₃ alkyl groups. Other suitable spacer monomers include vinyl esters, vinyl alcohol (made by hydrolysis of polyvinyl acetate), maleic anhydride, propylene glycol and ethylene glycol.

The cationic amine can be a primary, secondary or tertiary amine, depending on the particular species and pH of the composition. Generally, secondary and tertiary amines, especially tertiary amines, are preferred.

The amine-substituted vinyl monomer can be polymerized in the form of an amine, and then optionally quaternized
It can be converted to ammonium by reaction. Amine is in the form of a polymer
It can also be quaternized after formation. For example, a tertiary amine functional group has the formula R'X
Wherein R 'is a short chain alkyl, preferably C₁~ C₇Alkyl, more preferably C ₁ ~ C_ThreeX is an anion which forms a water-soluble salt with quaternary ammonium
) Can be quaternized by reacting with a salt of

[0130] Suitable cationic amino and quaternary ammonium monomers include, for example, dial
Killaminoalkyl acrylate, dialkylaminoalkyl methacrylate,
Monoalkylaminoalkyl acrylate, monoalkylaminoalkyl methacrylate
Relate, trialkyl methacryloxyalkyl ammonium salt, trialkyl
Acryloxyalkyl ammonium salt, substituted with diallyl quaternary ammonium salt
Vinyl compounds and cyclic cation nitrogen such as pyridinium and imidazolium
Vinyl quaternary ammonium monomers having a ring containing, and quaternary pyrrolidone, examples
For example, alkyl vinyl imidazolium, alkyl vinyl pyridinium, alkyl
And vinylpyrrolidone salts. The alkyl portion of these monomers is preferred
H, C₁~ C_ThreeAlkyl, more preferably C₁And C_TwoLower alkyl such as alkyl
Kill. Suitable amine-substituted vinyl monomers for use herein are
Is dialkylaminoalkyl acrylate, dialkylaminoalkyl methacrylate
Relate, dialkylaminoalkylacrylamide and dialkylaminoamine
And alkyl methacrylamide. In this case, the alkyl group is preferably C ₁ ~ C₇Hydrocarbyl, more preferably C₁~ C_ThreeAlkyl.

The cationic polymers herein are amine- and / or quaternary ammonium-
It can comprise a mixture of monomer units derived from substituted monomers and / or compatible spacer monomers.

Suitable cationic hair conditioning polymers are commercially available, for example, from BASF Wyandotte Corp. (Parsipani, NJ, USA) under the trade name LUVIQUAT (eg, LUVIQUAT FC370). Copolymers of 1-vinyl-2-pyrrolidone and 1-vinyl-3-methylimidazolium salts (e.g., chloride salts), such as those manufactured by the Polyquaternium-16 Co., Ltd. GAF (GAF Corporation) (Wayne, NJ, USA).
Copolymers of 1-vinyl-2-pyrrolidone and dimethylaminoethyl methacrylate, such as those commercially available under the trade name QUAT (GAFQUAT 755N), which is referred to in the industry as polyquaternium-11 by the CTFA. Cationic diallyl quaternary ammonium, referred to in the industry (CRFA) as polyquaternium-6 and polyquaternium-7, respectively, including, for example, dimethyldiallylammonium chloride homopolymer and copolymers of acrylamide and dimethyldiallylammonium chloride Containing polymer, U.S. Pat.
Mineral acid salts of aminoalkyl esters of homo- and copolymers of unsaturated carboxylic acids having 3 to 5 carbon atoms, such as those described in WO 09/256.
This patent is hereby incorporated by reference.

Other cationic polymers that can be used include polysaccharide polymers such as cationic cellulose derivatives and cationic starch derivatives.

Cationic polysaccharide polymer materials suitable for use herein have the following formula (A is an anhydrous glucose residue, such as a starch or cellulose anhydrous glucose residue, and R is an alkyleneoxyalkylene, R ¹ , R ² and R ³ are independently up to about 18 carbon atoms and the total number of carbon atoms per cation moiety (ie, R ¹ , R ² and total) is Ru preferably der about 20 or less alkyl carbon atoms in R ^3, aryl, alkylaryl, arylalkyl, alkoxyalkyl, or alkoxyaryl groups,, X is an anion counterion as described above ).

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Cationic cellulose is a salt of hydroxyethylcellulose reacted with polyquaternium-10 and a trimethylammonium-substituted epoxide, referred to in the industry (CTFA) as Amerchol Corp. (Edison, NJ, USA). Available in Polymer JR® and LR® polymer series. Another type of cationic cellulose includes the polymeric quaternary ammonium salt of hydroxyethyl cellulose reacted with polyquaternium-24 and a lauryl dimethyl ammonium substituted epoxide, referred to in the industry (CTFA). These materials are available from Amerchol Corp. (Edison, NJ, USA) under the trade name Polymer LM-200®.

Other cationic polymers that may be used include cationic guar rubber derivatives such as garhydroxypropyltrimonium chloride (commercially available from Celanese Corp. in the Jaguar R series). . Other materials include quaternary nitrogen-containing cellulose ethers (eg, those described in US Pat. No. 3,962,418, which is incorporated herein by reference) and copolymers of etherified cellulose and starch (eg, No. 3,958,581, incorporated herein by reference).

Cationic Surfactants The cationic surfactants useful herein are any known to those of skill in the art.

The cationic surfactants useful herein include the following Formula (I) wherein R ¹ , R^Two, R^ThreeAnd R^FourAt least one is an aliphatic group having 8 to 30 carbon atoms, or
Or an aromatic, alkoxy, polyoxyalkylene, a
From rukylamido, hydroxyalkyl, aryl, or alkylaryl groups
Selected, R¹, R^Two, R^ThreeAnd R^FourAre independently from 1 to about 22 carbon atoms.
Aliphatic groups, or aromatic, alkoxy, polyoxyalkyl groups having up to about 22 carbon atoms
Kylene, alkylamide, hydroxyalkyl, aryl, or alkylant
Is selected from the group consisting of Wherein X is a halogen (eg, chloride, bromide),
Acetate, citrate, lactate, glycolate, phosphate, nitrate
, Sulfonate, sulfate, alkyl sulfate, and alkyl sulfo
Which are salt-forming anions, such as those selected from nate groups)
No. Aliphatic groups have, in addition to carbon and hydrogen atoms, an ether linkage, and
Other groups such as amino groups can be included. Longer chain aliphatic groups, for example
For example, those having about 12 or more carbon atoms can be saturated or unsaturated.
R¹, R^Two, R^ThreeAnd R^FourIs independently C₁~ About C_{twenty two}Preferably, it is selected from alkyl. Non-limiting examples of useful cationic surfactants include the CTFA designation, Quate
Lunium (quaternium-8), Quaternium-24, Quaternium
Quaternium-27, quaternium-30, quaternium-3
3, Quaternium-43, Quaternium-52, Quaternium-53, Quarternium-53
Athenium-56, Quaternium-60, Quaternium-62, Quatel
Nium-70, Quaternium-72, Quaternium-75, Quaternium
-77, Quaternium-78, Quaternium-80, Quaternium-81
, Quaternium-82, Quaternium-83, Quaternium-84
And mixtures thereof.

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In the above formula, R¹And R^TwoAt least one of the groups is alkoxy (preferably C₁ ~ C_ThreeAlkoxy), polyoxyalkylene (preferably C₁~ C_ThreePolyoxyalkylene), alkylamides, hydroxyalkyl, alkyl esters, and
And at least one hydrophilic moiety selected from the group consisting of
One or more than one aromatic, ether present as a substituent or bond in the chain of the group.
Hydrophilically substituted cations containing a ter, ester, amide, or amino moiety
Surfactants are also preferred. Preferably, a hydrophilically substituted cationic condition
The surfactant has between 2 and about 10 nonionic hydrophilic moieties located within the range described above.
Including minutes. Preferred hydrophilically substituted cationic surfactants have the formula (II)
Wherein n is from 8 to about 28, x + y is from 2 to about 40, and Z¹Is a short-chain alkyl, preferably C₁~ C_ThreeAlkyl, more preferably methyl, or-(CH _Two CH_TwoO)_zH, wherein x + y + z is less than or equal to 60 and X is a salt-forming anion as defined above; formula (III), wherein m is 1-5;
R^Five, R⁶And R⁷Is independently C₁~ C₃₀Alkyl and the remainder is -C
H_TwoCH_TwoOH and R⁸, R⁹And R^TenOne or two are independently C₁~ C_{Three 0} Alkyl and the remainder is -CH_TwoCH_TwoOH, X is a salt-forming anion as described above), formula (IV), wherein Z^TwoIs an alkyl, preferably C₁~ C _Three Alkyl, more preferably methyl, Z^ThreeIs a short-chain hydroxyalkyl,
Preferably, it is hydroxymethyl or hydroxyethyl, and p and q are independently
2 to 4, preferably an integer of 2 to 3, more preferably 2;¹¹and
R¹²Are independently substituted or unsubstituted hydrocarbyls, preferably C₁₂~ C₂₀Archi
Or X is a salt-forming anion as defined above
), Formula (V) (where R¹³Is a hydrocarbyl, preferably C₁~ C_ThreeAlkyl,
More preferably methyl, Z^FourAnd Z^FiveAre independently short-chain hydrocarbyls
Preferably C_Two~ C_FourAlkyl or alkenyl, more preferably ethyl, a
Is from about 2 to about 40, preferably from about 7 to about 30, and X is a salt as defined above
Is a forming anion), formula (VI) (wherein R¹⁴And R^FifteenIs independently C₁~ C_ThreeAlkyl, preferably methyl, Z⁶Is C₁₂~ C_{twenty two}Hydrocarbyl, al
A is a protein, preferably a collagen,
Keratin, milk protein, silk, soy protein, wheat protein or their hydrolysis
X is a salt-forming anion as defined above), and
And formula (VII) (where b is 2 or 3;¹⁶And R¹⁷Is independently C₁ ~ C_ThreeHydrocarbyl, preferably methyl, and X is a salt-forming anion as defined above). Useful hydrophilically substituted cations
Non-limiting examples of surfactants include the CTFA designation, quaternium (quaternium).
nium) -16, quaternium-61, quaternium-71, quaterni
Um-79 hydrolyzed collagen, quaternium-79 hydrolyzed keratin, qua
Ternium-79 hydrolyzed milk protein, Quaternium-79 hydrolyzed silk, Quate
Lunium-79 hydrolyzed soy protein, Quaternium-79 hydrolyzed wheat protein
Materials. Highly preferred compounds include Witco Chemical (Witc)
o Chemical name VARIQUAT K1215 and 638; McIntyre trade name MacPro
(MACKPRO) KLP, Mac Pro (MACKPRO) WLW, Mac Pro
(MACKPRO) MLP, Mac Pro (MACKPRO) NSP, Mac Pro
(MACKPRO) NLW, Mac Pro (MACKPRO) WWP, Mac Pro
(MACKPRO) NLP, MACPRO (MACKPRO) SLP, Akzo (A
kzo), trade name ETHOQUAD 18/25, etoqua
(ETHOQUAD) O / 12PG, ETHOQUAD (ETHOQUAD) C
/ 25, ETHOQUAD S / 25 and ETDUQUAD
(ETHODUOQUAD), trade name from Henkel
Commercially available materials under the trade name ATLAS G265 from DEHYQUAT SP and ICI America.

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[0143]

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[0144]

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[0145]

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[0146]

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[0147]

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Salts of primary, secondary and tertiary aliphatic amines are also suitable cationic surfactants.
The alkyl group of such amines preferably has about 12 to about 22 carbon atoms and can be substituted or unsubstituted. Amide substituted tertiary aliphatic amines are particularly useful. Such amines useful herein include stearamidopropyldimethylamine, stearamidopropyldiethylamine, stearamidoethyldiethylamine, stearamidoethyldimethylamine, palmitoamidopropyldimethylamine, palmitoamidopropyldiethylamine, Palmitoamidoethyldiethylamine, palmitoamidoethyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldiethylamine, behenamidoethyldiethylamine, behenamidoethyldimethylamine, arachidoamidopropyldimethylamine, arachidoamidopropyldiethylamine, arachidoamidoethyldiethylamine , Arachidamidoethyldimethylamine, diethylaminoethylstearamide It is. Also useful are dimethylstearamine, dimethylsoiamine, soiamine, myristylamine, tridecylamine, ethylstearylamine, N-tallowpropanediamine, ethoxylated (with 5 moles of ethylene oxide) stearamine, dihydroxyethylstearamine and arachidylbehenylamine It is. These amines are L-glutamic acid, lactic acid,
It can be used in combination with acids such as hydrochloric acid, maleic acid, succinic acid, acetic acid, fumaric acid, tartaric acid, citric acid, L-glutamic acid hydrochloride and mixtures thereof, more preferably L-glutamic acid, lactic acid and citric acid. Among the useful ones are the cationic amine surfactants, published on June 23, 1981, by Nachtgal (Nacht).
igal) in U.S. Patent No. 4,275,055, which is incorporated herein by reference.

As used herein, a cationic surfactant may also include a plurality of ammonium quaternary or amino moieties or a mixture thereof.

High Melting Point Compounds Useful hair care conditioning agents have a melting point of at least about 25 ° C. selected from the group consisting of fatty alcohols, fatty acids, fatty alcohol derivatives, fatty acid derivatives, hydrocarbons, steroids and mixtures thereof. Includes high melting point compounds. Without being bound by theory, it is believed that these high melting compounds wrap the hair surface and reduce friction, thus giving the hair a smooth feel and making it easier to comb. It will be appreciated by those skilled in the art that the compounds disclosed in this section of the specification may optionally fall into more than one class. For example, some aliphatic alcohol derivatives can be classified as fatty acid derivatives. However, a given classification is not intended to be specific to a particular compound, but rather for classification and systematic purposes. Moreover, it will be apparent to those skilled in the art that, depending on the number and position of double bonds, the length and position of the branches, certain compounds having certain requisite carbon atoms may have melting points below about 25 ° C. Such low melting point compounds are not intended to be included in this section. Non-limiting examples of high melting point compounds are described in International Cosmetic Ingredient Dictionary, Fifth Edition, 1993, and CTF A Cosmetic Ingredient Handbook, Second.
Edition, 1992, both of which are incorporated herein by reference.

The aliphatic alcohols useful herein are those having about 14 to about 30, preferably about 16 to about 22, carbon atoms. These fatty alcohols
It can be a straight or branched chain alcohol and can be saturated or unsaturated. Non-limiting examples of aliphatic alcohols include cetyl alcohol,
Stearyl alcohol, behenyl alcohol and mixtures thereof.

The fatty acids useful herein are those having about 10 to about 30, preferably about 12 to about 22, and more preferably about 16 to about 22 carbon atoms. These fatty acids can be straight or branched chain acids and can be saturated or unsaturated. A diacid that satisfies the requirements herein,
Also included are triacids and other polyacids. In the present specification, salts of these fatty acids are also included. Non-limiting examples of fatty acids include lauric, palmitic, stearic, behenic, sebacic acids and mixtures thereof.

The aliphatic alcohol derivatives and fatty acid derivatives useful herein include alkyl ethers of fatty alcohols, alkoxylated fatty alcohols, alkyl ethers of alkoxylated fatty alcohols, esters of fatty alcohols, esterifiable esters. Fatty acid esters of compounds having a suitable hydroxy group, hydroxy-substituted fatty acids, and mixtures thereof. Non-limiting examples of aliphatic alcohol and fatty acid derivatives include materials such as methyl stearyl ether, ceteth-1 to ceteth-4, which are ethylene glycol ethers of cetyl alcohol.
5 (the number designation indicates the number of ethylene glycol moieties present), and steareth-series compounds such as steareth-1 to steareth-10, which are ethylene glycol ethers of steareth alcohol (number designations are:
Ceteareth-1 to ceteareth-10, which are the ethylene glycol ethers of ceteareth alcohol, ie, a mixture of aliphatic alcohols containing mainly cetyl alcohol and stearyl alcohol (numerical designation is , Representing the number of ethylene glycol moieties present), C ₁ -C ₃₀ alkyl ethers of the ceteth compounds, steareth compounds and ceteareth compounds, polyoxyethylene ether of behenyl alcohol, ethyl stearate, cetyl stearate just described. , Cetyl palmitate, stearyl stearate, myristyl myristate, polyoxyethylene cetyl ether stearate, polyoxyethylene stearyl ether stearate, polyoxyethylene la Uryl ether stearate, ethylene glycol monostearate, polyoxyethylene monostearate, polyoxyethylene distearate, propylene glycol monostearate, propylene glycol distearate, trimethylolpropane distearate, sorbitan stearate,
Examples include polyglyceryl stearate, glyceryl monostearate, glyceryl distearate, glyceryl tristearate, and mixtures thereof.

[0154] Hydrocarbons useful herein include compounds having at least about 20 carbons.

[0155] Steroids useful herein include compounds such as cholesterol.

High-boiling, single-compound, high-boiling compounds are preferred. Highly preferred are single compounds of pure aliphatic alcohols selected from the group of pure cetyl alcohol, stearyl alcohol and behenyl alcohol. As used herein, "pure" means that the compound has a purity of at least about 90%, preferably at least about 95%. These single compounds of high purity provide good rinseability from the hair when the consumer rinses the composition.

Commercially available high boiling compounds useful herein include Shin Nippon Chemical (Ne)
cetyl alcohol, stearyl alcohol and behenyl alcohol, and Wako Pure Chemicals (WAKO) of the Konol (KONOL) series available from w Japan Chemical (Osaka, Japan) and the NAA series available from NOF (NOF) (Tokyo, Japan). Product name 1 available from Osaka, Japan
-Pure behenyl alcohol of docosanol (1-DOCOSANOL), Akzo (
Akzo) (Chicago, Illinois, USA).
O-FAT), Hysterene and Baby (Vev), available from Witco Corp. (Dublin, Ohio, USA).
y) Various fatty acids under the trade name DERMA available from (Genoa, Italy) and cholesterol under the trade name Nikkol AGUASOME LA available from Nikko. Preferably, the high melting point compound is present in the hair care compositions herein at a level from about 0.01 to about 20%.

Fragrance Compounds Fragrances are desirable components of hair care compositions because they can eliminate unwanted odors of other components of the hair care composition and provide a pleasant sensory aroma. The perfume compounds herein can further provide conditioning benefits.

A variety of perfumes are known to those skilled in the art and are commercially available. The particular fragrance used is often a matter of choice. However, perfume should be used at a level effective to impart a perceivable scent to the composition or to counteract the undesirable scent of the composition.

In general, the compositions will comprise from about 0.01% to about 10%, preferably about 0.0%, of a perfume compound containing a carbonyl, ether or hydroxy functionality or a mixture thereof.
From 5% to about 7%, more preferably from about 0.05% to about 3%. As used herein, "perfume compound" refers to a fragrance active ingredient, while "perfume" or "perfume material" includes the total perfume compound and any accompanying perfume solution.

[0161] Fragrances are manufactured by those skilled in the art with a variety of aromas and intensities. Typical fragrances are
"Arcstander, Perfume and Flavor Chemicals (Aroma Chemicals), Vols. I and II (1996)" and "Arctander, Perfume and Flavour Materials 19 (Natural).

[0162] The carbonyl-containing perfume compound contains a functional group selected from the group consisting of aldehydes, ketones, esters, carboxyls, and mixtures thereof. These materials are
It can be aliphatic (saturated or unsaturated), aromatic, heterocyclic or cycloaliphatic. Generally, they will have from about 6 to about 18 carbon atoms.

[0163] Non-limiting examples of aliphatic aldehyde fragrance compounds herein include hexylaldehyde, heptylaldehyde, octylaldehyde, decylaldehyde, undecylaldehyde, undecylinic, lauric aldehyde, methylmonyl. Examples include acetaldehyde, myristic aldehyde and nonyl aldehyde. Aromatic aldehydes include cinnamaldehyde, such as amyl cinnamaldehyde and hexyl cinnamaldehyde, anisaldehyde, helitropin, benzaldehyde and vanillin. Heterocyclic aldehydes include piperonal and furan.

[0164] Non-limiting examples of aliphatic ketone flavor compounds herein include hexanone,
Heptanone, octane, inone, undecalactone, nonalactone (go
mma) -nonyllactone), camphor, alpha-methylionone, (sesame-undecyllactone) sesame-methylinone and beta-methylnaphthyl ketone. The alicyclic ketone includes, for example, amylcyclohexanone. Aromatic ketones include beta-naphthyl methyl ketone, para-hydroxyphenol butanone, laevo carvone and musk ketone. Heterocyclic ketones include tuzeon, cedrenone and exaltolide.

Non-limiting examples of the aliphatic ester perfume compounds herein include: ethyl butyrate, ethyl formate, butyl acetate, isopropyl butyrate, ethyl formate, cis-3-hexyl acetate, ethyl acetoacetate Acetate, butyrate and formate, and phenylethylphenylacetate, such as methyloctyne carbonate, and phthalate, such as diethylphthalate. Heterocyclic esters include seryl formate and sedolyl acetate. Benzyl acetate, aromatic esters
Benzyl salicylate, cis-3-hexyl acetate, cis-3-hexyl salicylate and methyl anthranilate. Other esters include cycloaliphatic esters such as 4-t-butylcyclohexyl acetate and aliphatic / cycloaliphatic esters. Ester flavors include materials derived from flower materials and fruits and animal odors (natural isolates of civet, beaver and musk)
And materials derived from.

Non-limiting examples of ether perfume compounds herein include Ambrox (
ambrox), galaxolide and rose oxide.

Non-limiting examples of hydroxy fragrance compounds herein include 1-decanol, 1-nonanol, 1-octen-3-ol, 1-terpineol (beta)
, 1-undecanol, 2,4-decadien-1-ol, 2,4-octadien-1-ol, 2,6-dimethyl-6-hepten-1-ol, 2-hexen-1-ol, 2-octene -1-ol, 3,7,9-trimethyl-1,6-
Decadien-3-ol, 3,7-dimethyl-7-methoxyoctane-2-ol, 3,7-dimethyloctane-1-ol, 3-methyloctane-3-ol, 3-octanol, 9-decene-1 -Ol, α-terpineol, benzyl alcohol, (+)-cedrol, cinnamon alcohol, cis-3-hexene-1
-Ol, citronellol, dihydrolinalool, dihydromyrcenol, dihydroterpineol, dimethylbenzylcarbinol, dimethol, ethyl linalool, eugenol, farnesol, gamma-terpineol, geraniol,
Iso-phytol, isopropylcyclohexanol, l-methanol, lavandulol, linalool, methylphenylcarbinol, nerol, p-tolylethyl alcohol, patchouli alcohol, phenylethyl alcohol, phenylhexyl alcohol, roselea, terpineol (Α-form, β-form and γ-form), sendren (send
olen), tetrahydrogeraniol, tetrahydrolinalool, tetrahydromyrcenol, vanillin, ethyl-2-phenoxy-ethanol, 3-methyloctane-3-ol, ethyl linalool (3,7-dimethyl-1,6-nonadiene-3- Oars).

[0168] Non-limiting examples of ether with hydroxy perfume compounds herein include 2-phenoxyethanol, carbitol (diethylene glycol monoethyl ether), dipropylene glycol and triethyl citrate.

Non-limiting examples of ether carbonyl perfume compounds herein include 2-phenoxyethyl-iso-butyrate, allylcyclohexanepropionate, allylphenoxyacetate, benzylacetate, benzylbutyrate , Benzyl cinnamate, benzyl salicylate, cinnamyl cinnamate, cis-3-hexenyl acetate, cis-3-hexenyl butyrate, cis-3-hexenyl salicylate, citronellol acetate, citronellyl formate, citro Neryl propionate, dimethylbenzylcarbinyl-
Iso-butyrate, ethyl acetate, ethyl butyrate, ethyl caprylate, ethyl decylate, ethyl-2-methyl butyrate, ethylene brush rate,
Exatolide, flor acetate, γ-decalactone, γ-dodecalactone, γ-nonalactone, γ-undecalactone, geranyl acetate, geranyl formate, herional, heliotropin, hexyl acetate, hexyl salicylate, iso-amyl Acetate, iso-amyl salicylate, isopropyl myristate, linalyl acetate, menthyl acetate, methyl anthranilate, methyl benzoate, methyl phenyl carbyl acetate, neryl acetate, phenyl ethyl acetate, phenyl acetate and trichloromethyl phenyl carbyl acetate No.

In addition, some perfume compounds may fall into one or more of the categories described herein. As the skilled artisan will appreciate, the designation given to a particular compound does not affect its suitability for use herein.

Perfume solvents are well known in the art, and conventional ones such as dipropylene glycol, diethylene glycol, C ₁ -C ₆ alcohols and the like can be used herein.

The hydrophobicity of a perfume raw material, referred to herein as RPM, can be characterized by its octanol / water partition coefficient, P. Octanol in organic compounds /
The water partition coefficient is the ratio of its equilibrium concentrations in octane and water. Since the partition coefficient of an organic compound is typically very large, its partition coefficient is
It is more conveniently given in logarithmic form.

The log P of many compounds has been reported. For example, Daylight Chemical Information Systems
nation Systems, Inc. The Pomona 92 database, available from (Daylight CIS), contains many, along with citations in the original literature.

However, logP values are most conveniently calculated by the “CLOGP” program, also available from Daylight CIS. The program also lists experimental logP values when available in the Pomona 92 database. "Computed logP" (ClogP) is based on the Hansch and Leo fragment approach (A. Leo, Comprehen).
five Medical Chemistry, Vol. 4; Hansch
, P. G. FIG. Sammens, J .; B. Taylor and C.I. A. Ramde
n, Eds. p. 295, Pergamon Press, 1990). The fragment approach is based on the chemical structure of the compound and takes into account the number and type of atoms, the connectivity of the atoms and the chemical bonds. The ClogP value, the most reliable and widely used estimate for this physicochemical property, is:
It can be used instead of the experimental logP value in selecting the perfume compound. The perfume compound of the present composition preferably has a ClogP value between -1.0 and 8.0.

Without being bound by theory, it is believed that the addition of perfume compounds to the compositions of the present invention can affect the stability of the composition, including viscosity and phase separation, and the conditioning properties of the composition.

In the case of a shampoo composition, an increase in the viscosity of the composition can be observed by adding RPM. The increase in viscosity is due to the increase in R to the barrier layer between the hydrocarbon core and the micelle surface.
It is thought that it is caused by solubilization of PM. These molecules enlarge the area between the surfactant molecules in the micelle, increasing the size of the micelle. Larger micelles increase micelle-to-micellar interactions, such as entanglement of cylindrical micelles, as a result of the increasing volume fraction of micelles.

Water-Insoluble High-Molecular-Weight Oil Compound The water-insoluble high-molecular-weight oil compound of the present invention provides excellent conditioning advantages such as smoothness to hair and ease of combing. Without being bound by theory, it is contemplated that the water-insoluble high molecular weight oleaginous compounds of the present invention can adhere to and condition hair. It is also conceivable that the water-insoluble high molecular weight oleaginous compound covers the surface of the hair and consequently reduces the friction of the hair and gives the hair smoothness. Water-insoluble high molecular weight oleaginous compounds are chemically stable under normal use and storage conditions.

The term “water-insoluble oily compound” as used herein means that the compound is not sufficiently soluble in water at room temperature. When the compound is mixed with water at a concentration higher than 1.0%, more preferably higher than 0.5%, the compound will temporarily disperse to form an unstable colloid in water, and then Quickly separates from water into two phases.

Water-insoluble high molecular weight oleaginous compounds useful in the present invention are those having a specific gravity of at least about 0.9 at 25 ° C. and at least about 800, as long as they are liquid.
Preferably it has a molecular weight of at least about 1000, more preferably at least about 1200.

The water-insoluble high molecular weight oleaginous compounds useful herein are represented by the following formula (I), wherein A ¹ , A ² , A ³ and A ⁴ are independently C ₁ to about C ₃₀ alkyl. , alkenyl, aryl, alkylaryl, hydroxyalkyl, alkoxyl, alkoxyalkyl, acyl, acyl and alkyl acyl oxyl group, or a group of the _{formula, - (CH 2) n -O} -OCR ( wherein R is, C ₁ ~ about C ₃₀ Or n is an integer from 1 to about 30, preferably 1.)
Includes

[0181]

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Preferably, the water-insoluble high molecular weight oleaginous compounds of the present invention are all A¹, A^Two, A ^Three And A^FourIs an ester group, or A¹, A^Two, A^ThreeAnd A^FourThree of d
The ester is a stele group, and the rest are alkyl groups. More preferred
Is that the water-insoluble high molecular weight oleaginous compound of the present invention₁₂ ~ About C_{twenty two}Esters of fatty acids, about C with trimethylolalkane₁₂~ About C_{twenty two}Fat
Esters of fatty acids and mixtures thereof.

Preferred water-insoluble high molecular weight oily compounds are those having the same substituent that is an ester group for A ¹ , A ² , A ³ and A ⁴ .

Preferred water-insoluble high molecular weight oleaginous compounds of the present invention are pentaerythritol tetraisostearate, trimethylpropane triisostearate, pentaerythritol tetraoleate, trimethylolpropane trioleate and mixtures thereof.

Suitable ester compounds include, for example, pentaerythritol tetraisostearate and trimethylolpropane triisostearate, available from Kokuu Alcohol under the trade names KAKPTI and KAKTI. Pentaerythritol tetraoleate and trimethylolpropane trioleate, available under the trade names PTO and ENUJERUB U from Shinnihon Rika, respectively.

The water-insoluble high molecular weight oleaginous compound is present in an amount from about 0.1 to about 20.0% by weight of the composition.
%, Preferably about 0.1% 10.0%, more preferably about 0.2% to about 5.0%
Used at the level.

Detergent Surfactants The compositions herein can include a detersive surfactant. The detersive surfactant herein is one that is suitable for cleaning hair. Detergent surfactants useful herein include anionic, amphoteric, zwitterionic and nonionic surfactants.

[0188] When a detersive surfactant is present, it is preferably included at a level of about 0.01% to about 75% by weight of the composition. Two or more surfactants can be used.

Anionic Surfactants Useful anionic surfactants herein include alkyl and alkyl ether sulfates. These materials have the formulas ROSO ₃ M and RO (C ₂ H ₄ O) _x SO ₃ M, respectively, where R is alkyl or alkenyl having from about 8 to about 30 carbon atoms and x is from 1 to About 10 and M is hydrogen or ammonium, alkanol ammonium (eg, triethanol ammonium)
, Such as monovalent metal cations (eg, sodium and potassium) or polyvalent metal cations (eg, magnesium and calcium). Preferably, M should be selected such that the anionic surfactant material is water-soluble. The anionic surfactant or surfactants should be selected so that the Kraft temperature is less than or equal to about 15 ° C, preferably less than or equal to about 10 ° C, and more preferably less than or equal to about 0 ° C. It is also preferred that the anionic surfactant be soluble in the compositions herein.

The Kraft temperature is a temperature corresponding to a temperature at which the solubility of an ionic surfactant is measured by the crystal lattice energy and the heat of hydration, and the solubility rapidly and discontinuously increases as the temperature increases. Means Each type of surfactant has its own unique Kraft temperature. Kraft temperatures for ionic surfactants are generally well known and understood in the art. For example, "Myers, Drew, Surfactant Science and
d Technology, pp. 82-85, VCH Publishers
, Inc. (New York, New York, USA), 1988 (I
SBN 0-89573-399-0) ". The entirety of this document is incorporated herein by reference.

In the above-mentioned alkyl and alkyl ether sulfates, preferably,
R has about 8 to about 18 carbon atoms in both the alkyl and alkyl ether sulfates. Alkyl ether sulfates are typically prepared as a condensation product of ethylene oxide and a monohydric alcohol having from about 8 to about 24 carbon atoms. It is possible to derive alcohol from fats and oils such as coconut oil, palm oil, tallow, etc., ie to synthesize alcohol. Lauryl alcohol and straight chain alcohols derived from coconut oil and palm oil are preferred herein. These alcohols have a molar ratio of 1 to about 10, especially about 3
The resulting mixture of molecular species having, for example, an average of 3 moles of ethylene oxide per mole of alcohol is sulfated and neutralized.

Specific examples of alkyl ether sulfates that can be used are the sodium and ammonium salts of coconut alkyl triethylene glycol ether sulfate, tallow alkyl triethylene glycol ether sulfate and tallow alkyl hexaoxyethylene sulfate. Highly preferred alkyl ether sulfates are those comprising a mixture of the individual compounds having an average alkyl chain length of about 8 to about 16 carbon atoms and an average degree of ethoxylation of 1 to about 4 moles of ethylene oxide. . Such mixtures may also contain, C _{12 to 13} compounds from 0% to about 20 wt%, C _14～15～16 compound of about 60% to about 100% by weight, 0% to
About 20% by weight of a _C17-18-19 compound, about 3% to about 30% by weight of a compound having a degree of ethoxylation of 0 to about 45% by weight to about 90% by weight of a ethoxylation degree of 1 to about 4; From about 10% to about 25% by weight of a compound having a degree of ethoxylation of about 4 to about 8 and from about 0.1% to about 15% by weight of a compound having a degree of ethoxylation greater than about 8. Comprising.

Other suitable anionic surfactants have the general formula [R¹-SO_Three-M] (where R ¹ Is selected from the group consisting of straight or branched chain saturated aliphatic hydrocarbon groups having about 8 to about 24, preferably about 8 to about 18 carbon atoms, and M is as previously described in this section.
Is a water-soluble salt of the organic sulfuric acid reaction product of Examples of such surfactants are
It contains iso-, neo- and n-paraffins and has about 8 to about 24 carbon atoms, preferably
Or from about 8 to about 24 carbon atoms, including bleaching and hydrolysis.
Sulfonating agents, such as SO_Three, H_TwoSO_FourIt is a salt of an organic sulfuric acid reaction product of a methane series hydrocarbon having the formula: Alkali metals and ammo
Nium sulfonated C_8-18n-Paraffin is preferred.

Still other suitable anionic surfactants include, for example, the reaction product of a fatty acid wherein the fatty acid is esterified with isethionic acid derived from coconut oil or palm oil and neutralized with sodium hydroxide, or For example, the sodium or potassium salt of a fatty acid amide of methyl tauride derived from coconut oil. Other similar anionic surfactants are described in U.S. Patent Nos. 2,486,921, 2,486,922 and 2,396,278, which are incorporated herein in their entirety. Are included for reference.

Another anionic surfactant suitable for use in the shampoo composition is a β-alkyloxyalkane sulfonate. These compounds have the following formula: wherein R ₁ is a linear alkyl group having about 6 to about 20 carbon atoms, and R ₂ is a lower alkyl group having about 1 to preferably 3 carbon atoms. , M are as described above)
Having. Many other anionic surfactants suitable for use in shampoo compositions are described in "McCutcheon's Emulsifiers a," published by MC Publishing Co.
nd Detergents, 1989 Annual "and U.S. Patent No. 3,929,678, which are incorporated herein by reference in their entirety. Preferred anionic surfactants for use in the shampoo composition include ammonium lauryl sulfate, ammonium laureth sulfate, triethylamine lauryl sulfate, triethylamine laureth sulfate, triethanolamine lauryl sulfate, triethanolamine laureth sulfate, monoethanolamine lauryl sulfate, laureth sulfate Monoethanolamine, dientanolamine lauryl sulfate, dientanolamine laureth sulfate, sodium lauryl monoglyceride sulfate, sodium lauryl sulfate, sodium laureth sulfate, potassium lauryl sulfate, potassium laureth sulfate, ammonium cocoyl sulfate, ammonium lauroyl sulfate, sodium cocoyl sulfate, sodium lauroyl sulfate , Potassium cocoyl sulfate, potassium lauryl sulfate, lauryl Triethanolamine, cocoyl sulfate, monoethanolamine lauryl sulfate, monoethanolamine, sodium tridecyl benzene sulfonate, sodium dodecyl benzene sulfonate and mixtures thereof.

[0196]

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[0197] Other anionic surfactants used herein include polyhydrophilic anionic surfactants. As used herein, "polyhydrophilic" means a surfactant having at least two hydrophilic groups that provide hydrophilicity. Polyhydrophilic surfactants useful herein are only those having at least two hydrophilic groups in the molecule and are not intended to include those having only one hydrophilic group. One molecule of the polyhydrophilic anionic surfactant herein can comprise the same or different hydrophilic groups. Specifically, the polyhydrophilic anionic surfactant comprises at least one group selected from the group consisting of carboxy, hydroxy, sulfate, sulfonate, and phosphate. Suitable polyhydrophilic anionic surfactants are those comprising at least one carboxy, sulfate or sulfonate group, more preferably those comprising at least one carboxy group.

Non-limiting examples of polyhydrophilic anionic surfactants include N-acyl-L-glutamate, such as N-cocoyl-L-glutamate, N-lauroyl-L-glutamate, laurinominodipropionate, N-acyl-L-aspartate, di-
(N-lauroyl-N-methyltaurate), polyoxyethylene lauryl sulfosuccinate, disodium N-octadecyl sulfonate, disodium lauryl sulfosuccinate, diammonium lauryl sulfosuccinate, tetrasodium N- ( 1,2-dicarboxyethyl) -N-octadecylsulfosuccinate, diamyl ester of sodium sulfosuccinate, dihexyl ester of sodium sulfosuccinate, dioctyl ester of sodium sulfosuccinate and 2-cocoalkyl-N-carboxyethyl-N -Carboxyethoxyethyl imidazolinium betaine, lauroamphoteric hydroxypropylsulfonate, cocoglyceryl ether salt, cocoglyceride sulfate, lauroylisethionate, lauroamphoterium acetate (Wherein, R is alkyl of 8-18 carbon atoms) over bets, and the following formulas include those of. Other polyhydrophilic anionic surfactants include olefin sulfonates having about 10 to about 24 carbon atoms. The term "olefin sulfonate" refers to the sulfonation of alpha-olefins using uncomplexed sulfur trioxide, after which any sulfone formed in the reaction is hydrolyzed to produce the corresponding hydroxy-alkane sulfonate It is used herein to mean a compound that can be prepared by neutralizing an acidic reaction mixture under such conditions. Sulfur trioxide can be liquid or gaseous and is usually an inert diluent, for example when used in liquid form, liquid SO ₂ , chlorinated hydrocarbons, etc., or when used in gaseous form. , Air, nitrogen, gaseous SO _2, etc., but need not necessarily be diluted. The α-olefin from which the olefin sulfonate is derived is a mono-olefin having about 8 to about 24 carbon atoms, preferably about 10 to about 16 carbon atoms, and is preferably a straight-chain olefin. In addition to the true alkene sulfonate and some of the hydroxy-alkane sulfonates, olefin sulfonates can be used depending on the reaction conditions, the proportions of the reactants, the nature of the impurities in the starting olefin and olefin stock, and side reactions during the sulfonation process. , It is possible to contain small amounts of other materials such as alkene disulfonates. Certain α-olefin sulfonate mixtures of the type described above are disclosed in Pfluomer and Kessl, issued July 25, 1967.
er) is more fully described in U.S. Patent No. 3,332,880, which is incorporated herein by reference in its entirety.

[0199]

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Another class of polyhydrophilic anionic surfactants are amino acid surfactants, which have the basic chemical structure of an amino acid compound, ie, contain one component of a natural amino acid It is. It goes without saying to those skilled in the art that some surfactants can be considered both polyhydrophilic anionic surfactants and amino acid surfactants. These surfactants are suitable anionic surfactants.

Non-limiting examples of amino acid surfactants include N-cocoylalaninate, N-acyl-N-methyl-β-alanate, N-acyl sarcosinate, N-alkylaminopropionate and N-acylaminopropionate. -Alkyl iminodipropionates,
Particular examples thereof include N-lauryl-β-aminopropionic acid or a salt thereof,
N-lauryl-β-iminodipropionate, N-acyl-DL-alaninate, sodium lauryl sarcosinate, sodium lauroyl sarcosinate,
Lauryl sarcosine, cocoyl sarcosine, N-acyl-N-methyl taurate, lauroyl taurate and lauroyl lactylate.

Suitable commercially available anionic surfactants include N-acyl-L-glutamate under the trade name AMISOFT CT-12S, and N under the trade name AMILITE GCK-12 supplied by Ajinomoto. -Acyl potassium glycine, Lauroyl glutamate under the trade name AMISOFT LS-11 and N-acyl-DL-alaninate under the trade name AMILITE ACT-12, trade name supplied by Mitsubishi Chemical (Mitsubishi Chemical) It is an acyl aspartate of ASPARACK and AAS, and an acyl derivative of trade name ED3A supplied by Hampshire Chemical Corp.

[0203] Optionally, the counter ion of the anionic surfactant may be a polyvalent cation. These anionic surfactants, in addition to the cation conditioning agent, and the polyvalent metal cations described below have been found to form coacervates in the composition. A cationic conditioning agent may be included in the composition to provide a single product shampoo that achieves both hair washing and conditioning.

The formation of coacervates depends on a variety of criteria, such as molecular weight, material concentration, ionic strength ratio of interacting ionic materials, charge densities of cationic and anionic materials, pH and temperature. Coacervate systems and the effect of these parameters are known in the art.

It is believed that it is particularly advantageous for anionic surfactants and polyvalent metal cations at certain levels to be present with the cation conditioning agent in the coacervate phase. It is believed that the coacervate formed in the composition will readily adhere to the hair when the coacervate is diluted with sufficient water, ie, with a shampoo rinse.

Without being bound by theory, it is believed that coacervate has two main effects on the shampoo composition. First, the critical micelle concentration of the composition (
(Hereinafter referred to as "CMC"). A decrease in CMC is associated with a decrease in surface tension, thus improving foam performance. Second, the presence of an anionic surfactant in addition to the polyvalent metal cation enlarges the coacervate region in the composition. As the cationic conditioning agents in the composition migrate primarily to the hair via these coacervates, the expansion of the coacervate area will allow more cationic conditioning agents to migrate to the hair. Thus, a composition that provides both cleaning and conditioning from a single product, improves overall conditioning benefits, and provides improved foaming is provided.

Assay techniques for the formation of complex coacervates are known in the art. For example, microscopic analysis of the shampoo composition at any selected dilution step can be utilized to determine whether a coacervate phase has formed. Such a coacervate phase can be identified as an additional emulsified phase in the composition. The use of a dye can help distinguish the core sorbate phase from other insoluble phases dispersed in the shampoo composition.

Amphoteric and Zwitterionic Surfactants As used herein, amphoteric surfactants are those in which the aliphatic group is straight or branched and one of the aliphatic substituents is from about 8 to about Derivatives of aliphatic secondary and tertiary amines containing 18 carbon atoms and including anionic water solubilizing groups such as carboxy, sulfonate, sulfate, phosphate or phosphonate.

The amphoteric surfactants used herein include those in which the aliphatic group is straight or branched, one of the aliphatic substituents contains about 8 to about 18 carbon atoms, and Derivatives of aliphatic quaternary ammonium, phosphonium and sulfonium compounds, including groups such as carboxy, sulfonate, sulfate, phosphate or phosphonate.

The general formula for these compounds is the following: wherein R ² is an alkyl, alkenyl or hydroxyalkyl group having from about 8 to about 18 carbon atoms, an ethylene oxide moiety having from 0 to about 10 and 0 to about One glyceryl moiety, Y is selected from the group consisting of nitrogen, phosphorus and sulfur atoms, R ³ is an alkyl or monohydroxyalkyl group having 1 to about 3 carbon atoms, and X is 1, Y when the atom is 2 when a nitrogen or phosphorus atom, R ⁴ is also alkylene carbon atoms from 1 to about 4 hydroxy alkylene, Z is carboxylate, sulfonate, sulfate, phosphonate and phosphate A group selected from the group consisting of groups).

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Examples of amphoteric and zwitterionic surfactants also include sultain and amide sultaine. Sultaines, including amidosultaine, include, for example, cocodimethylpropylsultaine, stearyldimethylpropylsultein and lauryl-bis- (2-hydroxyethyl) pyrsultein and the like, and cocoamidodimethylpropylsultein, stearylamidodimethylpropyl And amide sultaines such as sultaine and laurylamido-bis- (2-hydroxyethyl) propylsultaine. C ₈ -C ₁₈ amido hydroxysultaine lutein such hydrocarbyl amidopropyl hydroxysultaine lutein, particularly C ₈ -C ₁₄ hydrocarbyl amidopropyl hydroxysultaine lutein, for example, lauric Lil amidopropyl hydroxysultaine lutein and cocoamidopropyl hydroxysultaine lutein preferred. Other sultaines are disclosed in US Pat. No. 3,950,417.
And this patent is hereby incorporated by reference.

Other suitable amphoteric surfactants are aminoalkanoates of the formula RNH (CH ₂ ) _n COOM, of the formula RN [(CH ₂ ) _m COOM] ₂ , wherein n and m are a number from 1 to about 4 and a, R is C ₈ -C ₂₂ alkyl or alkenyl, M is hydrogen, alkali metal, alkaline earth metal, iminodialkanoates and mixtures thereof and is) ammonium or alkanolammonium and the like.

Other suitable amphoteric surfactants are of the formula:¹Is C₈~ C_{twenty two}Archi
Or alkenyl, preferably C₈~ C₁₆And R^TwoAnd R^ThreeIs independently hydrogen, -CH_TwoCO_TwoM, -CH_TwoCH_TwoOH, -CH_TwoCH_TwoOCH_TwoCH_TwoCOOM,
Or-(CH_TwoCH_TwoO)_mH wherein m is an integer from 1 to about 25;^FourIs hydrogen, -CH_TwoCH_TwoOH or CH_TwoCH_TwoOCH_TwoCH _Two COOM, and Z is CO_TwoM or CH_TwoCO_TwoM and n is 2 or 3,
M is preferably hydrogen or an alkyl metal (eg, lithium,
Sodium and potassium, alkaline earth metals (beryllium, magnesium, cal
Cations such as (sium, strontium, barium) or ammonium
)). This type of surfactant is imidazoline
It is sometimes classified as a type of amphoteric surfactant. However, this surfactant
Direct or indirect induction through imidazoline intermediates is not required
That should be appreciated. Suitable materials of this type are available under the trade name Milanor (
MIRANOL), and is believed to comprise a complex mixture of species.
Understood, and R^TwoBe present in a protonated or non-protonated species, depending on the pH for the species capable of having hydrogen at
Is possible. Include all such variations and species by the above formula.
Trying to do it.

[0215]

Embedded image

Examples of surfactants of the above formula are monocarboxylates and dicarboxylates. Examples of these materials include coco amphoteric carboxypropionate, coco amphoteric carboxypropionic acid, coco amphoteric carboxyglycinate (also called coco amphoteric diacetate) and coco amphoteric acetate.

Commercially available amphoteric surfactants include MIRANOL C
2M CONC. N. P. , MIRANOL C2M CONC. O
. P. MIRANOL C2M SF, MIRANOL CM SSPECIAL (Milanol Inc.), ALKATERIC 2CIB (Alkaline Chemicals (Alka)
ril Chemicals), AMPHOTERGE W-2 (Lonza, Inc.), MONATERIC
CDX-38, Monateric CSH-32 (Mona
na Industries), REWOTERIC AM-2C (Rewo Chemical Group), and SHERCOTERIC MS-2 (Shark Chemicals).
Scher Chemicals)).

A betaine surfactant, or zwitterionic surfactant, suitable for use in the conditioning composition is selected from the group consisting of the following formula (R ¹ is COOM and CH (OH) CH ₂ SO ₃ M: R ² is lower alkyl or hydroxyalkyl; R ³ is lower alkyl or hydroxyalkyl; and R ⁴ is a member selected from the group consisting of hydrogen and lower alkyl. R ⁵ is higher alkyl or alkenyl, Y is lower alkyl, preferably methyl, m is an integer of 2-7, preferably 2-3, and n is 1 or 0 And M is hydrogen or a cation as described above, such as an alkali metal, alkaline earth metal or ammonium. is there. The term "lower alkyl" or "lower hydroxyalkyl" refers to straight or branched, saturated aliphatic carbon atoms having 1 to about 3 carbon atoms, such as, for example, methyl, ethyl, propyl, isopropyl, hydroxypropyl, and hydroxyethyl. It means a hydrogen group and a substituted hydrocarbon group. The term "higher alkyl or alkenyl" refers to straight or branched chain saturated or unsaturated (i.e., "higher alkyl") having about 8 to about 20 carbon atoms, such as, for example, lauryl, cetyl, stearyl and oleyl. A "higher alkenyl" aliphatic hydrocarbon group, wherein the term "higher alkyl or alkenyl" refers to one or more intermediate such as an ether or polyether bond, or a non-functional substituent such as a hydroxy or halogen group. It is to be understood that it encompasses a mixture of groups that retains hydrophobic properties that may include bonds.

[0219]

Embedded image

Examples of surfactant betaines of the above formula (where n is 0) useful herein are cocodimethylcarboxymethylbetaine, lauryldimethylcarboxymethylbetaine, lauryldimethyl-α-carboxy. Ethyl betaine, cetyl dimethyl carboxymethyl betaine, lauryl-bis- (2-hydroxyethyl) -carboxymethyl betaine, stearyl-bis- (2-hydroxypropyl) carboxymethyl betaine, oleyldimethyl-γ-carboxypropyl betaine, lauryl-bis And alkyl betaines such as-(2-hydroxypropyl) -α-carboxyethyl betaine. Representative of the sulfobetaines are cocodimethylsulfopropylbetaine, stearyldimethylsulfopropylbetaine and lauryl-bis- (2-hydroxyethyl) -sulfopropylbetaine.

Particular examples of amidobetaines and amidosulfobetaines useful in the conditioning compositions include cocoamidodimethylcarboxymethylbetaine, laurylamidodimethylcarboxymethylbetaine, cetylamidodimethylcarboxymethylbetaine, laurylamido-bis- ( Amidocarboxybetaines such as 2-hydroxyethyl) carboxymethylbetaine and cocoamide-bis- (2-hydroxyethyl) -carboxymethylbetaine. Representative of the amidosulfobetaines are cocoamidodimethylsulfopropylbetaine, stearylamidodimethylsulfopropylbetaine and laurylamide-bis- (2-hydroxyethyl) -sulfopropylbetaine.

Nonionic Surfactants The compositions of the present invention can comprise a nonionic surfactant. Nonionic surfactants include compounds made by condensation of a substantially hydrophilic group of alkylene oxides with an organic hydrophobic compound, which may be aliphatic or alkylaromatic in nature.

Preferred non-limiting examples of non-ionic surfactants for shampoo compositions include the following.

(1) A polyethylene oxide condensate of an alkyl phenol, for example, an alkyl phenol having an alkyl group having about 6 to about 20 carbon atoms in either a linear or branched chain, and about 10 to about 60 per mole of the alkyl phenol Condensation products with ethylene oxide present in the amount of moles of ethylene oxide.

(2) Products derived from the condensation of ethylene oxide with the product resulting from the reaction of a propylene oxide product with an ethylene diamine product.

(3) Condensates of ethylene oxide with aliphatic alcohols of about 8 to about 18 carbon atoms, either linear or branched, for example, about 10 to about 30 moles per mole of coconut alcohol A coconut alcohol ethylene oxide condensate having ethylene oxide, wherein the coconut alcohol fraction has about 8 to about 14 carbon atoms.

(4) Formula [R ¹ R ² R ³ N → O] (wherein, R ¹ is an alkyl, alkenyl or monohydroxyalkyl group having about 8 to about 18 carbon atoms, 0 to about 10 carbon atoms) include ethylene oxide moieties and from 0 to about 1 glyceryl moiety, R ² and R ³ is from about 1 to about 3
Long-chain tertiary amine oxides containing from 0 to about 1 hydroxy group, for example a methyl, ethyl, propyl, hydroxyethyl or hydroxypropyl group.

(5) Formula [RR′R ″ P → O] (where R is an alkyl, alkenyl or monohydroxyalkyl group having a chain length of about 8 to about 18 carbon atoms, 0 to about 10 R ′ and R ′, comprising at least one ethylene oxide moiety and 0 to about 1 glyceryl moiety.
Is an alkyl or monohydroxyalkyl group, each having from about 1 to about 3 carbon atoms).

(6) One short-chain alkyl or hydroxyalkyl group having 1 to about 3 carbon atoms (
(Usually methyl), one hydrophobic long chain containing an alkyl, alkenyl, hydroxyalkyl or ketoalkyl group having about 8 to about 20 carbon atoms, 0 to about 10 ethylene oxide moieties and 0 to 1 glyceryl moieties. Long chain dialkyl sulfoxides containing.

(7) Alkyl polysaccharide (APS) surfactant (eg, alkyl polyglucoside). Examples are described in U.S. Pat. No. 4,565,647, which describes polysaccharides as hydrophobic and hydrophilic groups having 6 to about 30 carbon atoms.
(E.g., polyglycosides) are disclosed, which patent is hereby incorporated by reference. Optionally, there can be a polyalkylene oxide group attaching the hydrophobic group and the hydrophilic moiety. Also, the alkyl group (ie, the hydrophobic moiety) can be saturated or unsaturated, branched or unbranched, unsubstituted or substituted (eg, by a hydroxy or cyclic ring). Preferred materials are Henkel, ICI
(America) and Seppic.

(8) Polyethylene alkyl ethers such as those of the formula RO (CH ₂ CH ₂ ) _n H and of the formula R (O) OCH ₂ CH (OH) CH ₂ (OCH ₂ CH ₂ ) _n OH n is from 1 to about 200, preferably from about 20 to about 100, and R is alkyl having about 8 to about 22 carbon atoms) such as polyethylene glycol (PEG) glyceryl aliphatic esters.

Carrier The hair care compositions of the present invention comprise a carrier. The level and species of the carrier are selected according to the compatibility with other materials and the properties required for the product. For example, high percentages of low boiling volatile solvents and / or propellants are suitably used in the case of product forms intended to remain on the hair. On the other hand, aqueous solutions of volatile and non-volatile solvents
Appropriately used when the product is intended to be rinsed after washing or treating hair with the product.

[0233] Carriers useful in the present invention include volatile solvents, non-volatile solvents, propellants and mixtures thereof.

Volatile solvents useful herein include water, lower alkyl alcohols having 1 to 3 carbons, and hydrocarbons having about 5 to about 8 carbons. Preferred volatile solvents are water, ethanol, isopropanol, pentane, hexane and heptane. Water useful herein includes deionized water and water from natural sources containing mineral cations. Deionized water is preferred.

[0235] Non-volatile solvents useful herein include alkyl alcohols having more than 3 carbons and polyhydric alcohols. Polyhydric alcohols useful herein include 1,2-propanediol, i.e., propylene glycol, 1,
3-propanediol, hexylene glycol, glycerin, diethylene glycol, dipropylene glycol, 1,2-butylene glycol and 1,4-butylene glycol.

Propellants may be used in the form of mousse and hair spray products. When a propellant is used in the present invention, it is selected depending on variables such as whether the remaining materials, packaging, and product are designed to be used upright or upside down.

Useful propellants herein include difluoroethane 152a (Dupont (
Supplied by DuPont), dimethyl ether,
And hydrocarbons such as propane, isobutane, n-butane, mixtures of hydrocarbons such as LPG (liquefied petroleum gas), carbon dioxide, nitric oxide, nitrogen and compressed air.

Additional Conditioning Agents Additional conditioning agents useful herein include oleaginous compounds and non-ionic polymers.

Oily Compounds Compounds useful herein have a melting point below about 25 ° C. and are selected from the group consisting of first oily compounds, second oily compounds and mixtures thereof. The oily compounds useful herein may be volatile or non-volatile. Without being bound by theory, it is believed that the oily compound penetrates the hair and modifies the hydroxy bonds in the hair, thus imparting softness and suppleness to the hair. The oleaginous compound can comprise any of the first or second oleaginous compounds described herein. Preferably, a mixture of the first oily compound and the second oily compound is used. The oily compounds in this section should be distinguished from the high melting point compounds described above. Non-limiting examples of oleaginous compounds include International Cosmetic Ingredient Dictionary, Fifth Edition, 1993, and CTFA Cosmetic Ingredient.
Handbook, Second Edition, 1992,
Both of these are incorporated herein by reference.

First Oily Compounds Aliphatic alcohols useful herein include those having about 10 to about 30 carbon atoms.
Preferably from about 12 to about 22 carbon atoms, more preferably from about 16 to about 2 carbon atoms.
2 are mentioned. These aliphatic alcohols can be straight or branched chain alcohols, can be saturated or unsaturated, and are preferably unsaturated alcohols. Non-limiting examples of these compounds include oleyl alcohol, palmitolein alcohol, isostearyl alcohol, isocetyl alcohol, undecanol, octyl dodecanol, octyl decanol,
Octyl alcohol, caprylic alcohol, decyl alcohol and lauryl alcohol are included.

[0241] Fatty acids useful herein include those having about 10 to about 30, preferably about 12 to about 22, and more preferably about 16 to about 22 carbon atoms. These fatty acids can be straight or branched chain acids,
It can be saturated or unsaturated. Suitable fatty acids include, for example, oleic, linoleic, isostearic, linolenic, ethyllinolenic, arachidonic and ricinoleic acids.

The fatty acid derivatives and fatty alcohol derivatives include, for example, esters of fatty alcohols, alkoxylated fatty alcohols, alkyl ethers of fatty alcohols, alkyl ethers of alkoxylated fatty alcohols, and mixtures thereof. As defined herein. Non-limiting examples of fatty acid derivatives and fatty alcohol derivatives include, for example, methyl linoleate, ethyl linoleate, isopropyl linoleate, isodecyl oleate, isopropyl oleate,
Ethyl oleate, octyl dodecyl oleate, oleyl oleate, decyl oleate, butyl oleate, methyl oleate, octyl dodecyl stearate, octyl dodecyl isostearate, octyl dodecyl isopalmitate, octyl isoperagonate, octyl perella Gonate, hexyl isostearate, isopropyl isostearate, isodecyl isononanoate, Oleth
-2, pentaerythritol tetraoleate, pentaerythritol tetraisostearate, trimethylolpropane trioleate and trimethylolpropane triisostearate.

[0243] Commercially available first oily compounds useful herein include Shin Nippon Chemical (N
ew Japan Chemical (U.J. Chemical)
NJECOL) 90BHR oleyl alcohol, cocu alcohol (Ko)
available from Kyu Alcohol (Chiba, Japan), pentaerythritol tetraisostearate and trimethylolpropane triisostearate of Kakputi (KA KPTI) and Kakuchi (KAKTI), available from New Japan Chemical. Pentaerythritol tetraoleate having the same trade name as the compound name, New Japan Chemical (New Japan)
Chemical Name: ENUJERUBU
Trimethylolpropane trioleate of the series, various liquid esters of the SCHRCEMOL series available from Scher, and hexyl isostearate of the HIS brand available from Kokiu Alcohol. And product name Zips (Z
(PIS) isopropyl isostearate.

Second Oily Compounds Second oily compounds useful herein include linear, cyclic and cyclic, which can be either saturated or unsaturated as long as they have a melting point of about 25 ° C. or less. And branched chain hydrocarbons. These hydrocarbons have from about 12 to about 40 carbon atoms,
Preferably it has from about 12 to about 30, preferably from about 12 to about 22, carbon atoms. Polymeric hydrocarbons alkenyl monomers, such as polymers of C ₂ ~ ₆ alkenyl monomers are encompassed herein. These polymers can be linear or branched polymers. Linear polymers are typically relatively short-chain and have a total number of carbon atoms as described above. A branched polymer can have a substantially longer chain length. The number average molecular weight of such materials can vary widely, but is typically less than about 500, preferably from about 200 to about 400.
, More preferably from about 300 to about 350. Various grades of mineral oil are also useful herein. Mineral oil is a liquid mixture of hydrocarbons obtained from petroleum.
Particular examples of suitable hydrocarbon materials include paraffin oil, mineral oil, dodecane, isododecane, hexadecane, isohexadecane, eicosene, isoeicosene, tridecane, tetradecane, polybutene, polyisobutene and mixtures thereof. Hydrocarbons selected from the group consisting of mineral oil, isododecane, isohexadecane, polybutene, polyisobutene and mixtures thereof are preferred for use herein.

Commercially available second oleaginous compounds useful herein include Presperse (
Presperse (South Plainfield, NJ, USA) under the trade name PERMETHYL 99A, Permethyl (P
ERMETHYL) 101A and Permethyl (PERMETHYL) 1082
Isododecane, isohexadecane and isoeicosene, amoko chemicals (
A copolymer of isobutene and normal butene of INDOPOL H-100 available from Amoco Chemicals (Chicago, Illinois, USA), a product of Benol (BEN) available from Witco
OL) mineral oil, Isoparaffin under the trade name ISOPAR from Exxon Chemical Co. (Houston, Texas, USA), α- under the trade name PURESYN6 from Mobil Chemical Co. Olefin oligomers, and trimethylolpropane tricaprylate / tricaplate under the trade name MOBIL ESTER P43 from Mobil Chemical Co.

Nonionic Polymers Nonionic polymers useful herein include cellulose derivatives, hydrophobically modified cellulose derivatives, ethylene oxide polymers, and ethylene oxide / propylene oxide based polymers. Suitable nonionic polymers are all supplied by Herculus under the trade name Venecel (B
ENCEL), cellulose derivatives including hydroxyethyl cellulose under the trade name NATROSOL, hydroxypropyl cellulose under the trade name KLUCEL, and cetyl hydroxyethyl cellulose under the trade name POLYSURF67. Other suitable non-ionic polymers are CARBOWAX PEG, POLYOX W, all trade names supplied by Amerchol.
It is an ethylene oxide and / or propylene oxide based polymer of ASR and UCON FLUIDS.

Polyalkylene Glycols These polyalkylene glycol compounds are particularly useful for compositions designed to impart a soft, moisturizing effect to hair. The polyalkylene glycol, when present, is typically from about 0.025 to about 1.5%, preferably from about 0.05% to about 1%, more preferably from about 0.1 to about 0.1% of the composition. Used at the 5% level.

The polyalkylene glycol is characterized by the following formula: wherein R is selected from the group consisting of H, methyl and mixtures thereof. When R is H, these materials are polymers of ethylene oxide, also known as polyethylene oxide, polyoxyethylene and polyethylene glycol. R
When is methyl, these materials are polymers of propylene oxide, also known as polypropylene oxide, polyoxypropylene and polypropylene glycol. When R is methyl, it goes without saying that various isomers may exist depending on the position of the resulting polymer.

[0249]

Embedded image

In the above structure, n is about 1500 to about 25,000, preferably about 250
It has an average value of from about 0 to about 20,000, more preferably from about 3500 to about 15,000.

[0251] Polyethylene glycol polymers useful herein are those wherein R is H;
PEG-2M where n has an average value of about 2,000 (PEG-2M is also known as Polyox WSR® N-10, which is a PEG from Union Carbide). -2,000), wherein R is H and n has an average value of about 5,000
-5M (PEG-5M is a Polyox WSR® N)
-35 and Polyox WSR® N-80, both available as PEG-5,000 and polyethylene glycol 300,000 from Union Carbide), R Is H and n is an average of about 7,000 PEG-7M
(PEG-7M is also known as Polyox WSR® N-750, available from Union Carbide), where R is H and n is about 9,000. PEG-9 with average value
M (PEG-9M is also known as Polyox WSR® N-3333, available from Union Carbide), where R is H and n is about 14,000. PE with average value
G-14M (PEG-14M is a Polyox WSR® N-3 available from Union Carbide).
000).

Other useful polymers include polypropylene glycol and mixed polyethylene / polypropylene glycol.

Additional Materials The compositions of the present invention can include a variety of additional materials that can be selected by one skilled in the art depending on the required properties of the final product. Additional materials include, for example, polyvalent metal cations, suspending agents, and other additional materials.

Polyvalent Metal Cations Suitable polyvalent metal cations include divalent and trivalent metals, with divalent metals being preferred. Examples of metal cations include alkaline earth metals such as magnesium, calcium, zinc and copper and trivalent metals such as aluminum and iron. Calcium and magnesium are preferred.

The polyvalent metal cation can be added as an inorganic salt, an organic salt or a hydroxide. The polyvalent metal cation can also be added as a salt with an anionic surfactant, including a primary anionic surfactant as described above or a detersive surfactant as described below.

Preferably, the polyvalent metal cation is introduced as an inorganic or organic salt. Examples of the inorganic salt include chloride, bromide, iodide, nitrate and sulfate, and more preferably chloride or sulfate. Organic salts include L-glutamate,
Malate, succinate, acetate, fumarate, L-glutamate and tartrate.

When a polyvalent salt of an anionic surfactant is used as a method for introducing a polyvalent metal cation into the composition of the present specification, it is possible that only a part of the anionic surfactant is in a polyvalent form, It will be apparent to those skilled in the art that the rest of the anionic surfactant is necessarily added in monovalent form.

The hardness of the conditioning shampoo composition can be measured by using ethylenediaminetetraacetic acid (E
It can be measured by standard methods in the art, such as DTA) titration. If the composition contains a dye or other colorant that interferes with the ability of the EDTA titration to produce a perceptible color change, hardness should be measured on the composition without any interfering dyes or colorants. It is.

Suspensions Preferred additional materials are, in particular, suspensions for compositions comprising silicone compounds of high viscosity and / or large particle size. Suspensions, when present, are in a dispersed form in the composition. Suspensions generally comprise from about 0.1% to about 10%, more typically from about 0.3% to about 5.0%, by weight of the composition.

Preferred suspending agents include acyl derivatives such as ethylene glycol monostearate and ethylene glycol distearate, long chain amine oxides such as alkyl (C ₁₆ -C ₂₂ ) dimethylamine oxide, for example, stearyl dimethylamine oxide And mixtures thereof. When used in shampoo compositions, these preferred suspending agents are present in the composition in crystalline form. These suspending agents are described in U.S. Pat. No. 4,741,855.

Other suitable suspending agents include alkanolamides of fatty acids, preferably having about 16 to about 22 carbon atoms, more preferably about 16 to 18 carbon atoms, and preferred examples thereof include stearin Acid monoethanolamide, coco monoethanolamide, stearic acid diethanolamide, stearic acid monoisopropanolamide and stearic acid monoethanolamide stearate.

Other suitable suspending agents include N, N-dihydrocarbylamidobenzoic acid and its soluble salts (eg, Na and K salts), especially the N, N-di (hydrogenated) C _{16 of} this family. , _C18 and tallowamide benzoic acid species, which are commercially available from Stepan Company (Northfield, Ill., USA).

Other suitable suspending agents include xanthan gum. The use of xanthan gum as a suspending agent in silicone-containing shampoo compositions is described, for example, in US Pat. No. 4,788,006, which is incorporated herein by reference in its entirety. is there. Mixtures of long chain acyl derivatives and xanthan gum can also be used as suspending agents in shampoo compositions. Such mixtures are described in U.S. Pat. No. 4,704,272, which is incorporated by reference herein in its entirety.

Other suitable suspending agents include carboxyvinyl polymers. Among these polymers, copolymers of acrylic acid crosslinked with polyallyl saccharose, as described in U.S. Pat. No. 2,798,053, are preferred. The entirety of this patent is hereby incorporated by reference. Examples of these polymers include carbomer, a homopolymer of acrylic acid cross-linked with allyl ether of pentaerythritol, allyl ether of saccharose, or allyl ether of propylene. Neutralizing agents, such as aminomethylpropanol, triethanolamine or sodium hydroxide may be required.

Cellulose ethers such as hydroxyethyl cellulose, hydroxymethyl cellulose, hydroxypropyl cellulose, guar gum, polyvinyl alcohol,
Other suitable suspending agents, including those that can impart gel-like viscosity to the composition, such as water-soluble polymers or colloidal water-soluble polymers, such as materials such as polyvinylpyrrolidone, hydroxypropyl guar gum, starch and starch derivatives. It can be used in compositions.

Other Additional Ingredients A variety of other additional ingredients can be incorporated into the composition. These include
Peptein (trade name) available from Hormel
Other conditioning agents such as 2000 hydrolyzed collagen, Eisai (E
vitamin E under the trade name Emix-d available from isai), panthenol available from Roche, panthenyl ethyl ether available from Roche, hydrolyzed keratin, protein, plant extracts, nutrients, Hair fixing polymers such as amphoteric fixing polymers, cationic fixing polymers, anionic fixing polymers, nonionic fixing polymers and silicone graft copolymers, preservatives such as benzyl alcohol, methyl paraben, propyl paraben and imidazolidinyl urea, citric acid, PH adjusters such as sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate,
Salts such as potassium acetate and sodium chloride, colorants such as either FD & C or D & C dyes, hair oxidizing (bleaching) agents such as hydrogen peroxide, perborate and persulfate salts, hair reduction such as thioglycolate Agents, fragrances, suspending agents such as disodium ethylenediaminetetraacetate, ultraviolet and infrared shielding and absorbing agents such as octyl salicylate, and antidandruff agents such as zinc pyridinethione. Such optional ingredients individually comprise generally from about 0.01% to about 10.0% by weight of the composition;
Preferably, it is used at a level of about 0.01% to about 5.0%.

[0267]

【Example】

The following examples further describe and demonstrate embodiments within the scope of the present invention. These examples are provided for illustrative purposes only, and many modifications may be made without departing from the spirit and scope of the present invention and should not be considered as limiting of the invention. The various components are identified by chemical name or CTFA name, or defined separately below.

Methods of Manufacturing Hairsprays, mousses, lotions and conditioners are suitably manufactured as follows. If a polymeric material is included in the formulation, it is dispersed in water at room temperature. If desired, polymeric materials such as carbomer and acrylate / steareth-20 methacrylate copolymer may be neutralized after dispersion. Mix 6 then
Heat above 0 ° C. and add the fatty alcohol and emulsifier, if included, to the formulation. After cooling below 50 ° C., add the remaining ingredients with stirring and then cool to about 30 ° C. If ethanol is included in the formulation, it is added here. If necessary, the material can be dispersed using a triblender and mill. Optionally, the mixture thus obtained can be filled into a propellant-containing aerosol can.

Shampoos are suitably manufactured by any conventional method well known in the art. A suitable method is as follows. The polymer and surfactant are dispersed in water to form a homogeneous mixture. The silicone emulsion (if present), flavors and other ingredients except for the salts are added to the mixture and the resulting mixture is stirred. If a silicone emulsion is present, prepare it with dimethicone or dimethiconol, a small amount of detersive surfactant and a portion of the water. Thereafter, the resulting mixture is cooled through a heat exchanger, and the silicone emulsion, flavor and salt are added. The resulting composition is poured into a bottle to produce a hair shampoo composition.

Alternatively, the surfactant and water and any other solids that need to be melted can be mixed together at an elevated temperature, eg, above about 70 ° C., to facilitate mixing into the shampoo. . Additional ingredients can be added to the hot premix or after the premix has cooled. The various components are thoroughly mixed at elevated temperature, then pumped through a high shear mill and then through a heat exchanger to cool them to room temperature. If silicone is present in the composition, add the silicone emulsified at room temperature in concentrated surfactant to the cooled mixture.

[0271]

[Table 1]

[0272]

[Table 2]

[0273]

[Table 3]

[0274]

[Table 4]

[0275]

[Table 5]

[0276]

[Table 6]

[0277]

[Table 7]

[0278]

[Table 8]

[0279]

[Table 9]

[0280]

[Table 10]

[0281]

[Table 11]

[0282]

[Table 12]

[0283]

[Table 13]

[0284]

[Table 14]

[0285]

[Table 15]

[0286]

[Table 16]

[0287]

[Table 17]

[0288]

[Table 18]

[0289]

[Table 19]

[0290]

[Table 20]

[0291]

[Table 21]

[0292]

[Table 22]

Definitions ^* 1 Disodium-1,4-bis (2-sulfostyryl) biphenyl: TINOPAL CBX purchased from Ciba Geigy ^* 2 4,4'-bis [(4-anilino -6-bis (2-hydroxyethyl)
-Amino-1,3,5-triazin-2-yl) amino] stilbene-2,2'-disulfonic acid: TINOPAL UNPA-GX ^* 34-methyl- purchased from Ciba Geigy 6,7-dihydroxycoumarin: available from Wako Pure Chemical Industries (Wako). ^* 4 4-Methyl-7,7'-dimethylaminocoumarin: available from Wako Pure Chemical Industries (Wako). ^* 5 1- (4-Amidosulfonylphenyl) -3- (4-chlorophenyl) -2-pyrazolin: Blancophor (purchased from Bayer)
BLANKOPHOR) DCB ^* 6 2,4-Dimethoxy-6- (1'pyrenyl) -1,3,5-triazine: available from Ciba Geigy. ^* 7 Glycerin: Glycerin USP purchased from Nihon Yuushi ^* 8 Propylene glycol: Lexol (LEXOL) PG-865 ^* 9 purchased from Inolex ^* 9 N-acyl-L-glutamate tri Ethanolamine: CT12S ^* 10 sodium lauroyl sarcosinate purchased from Ajinomoto: Soypon (SOY) purchased from Kawaken Fine Chemical.
PON) ^* 11 Cocoamidopropyl betaine: TEGOBETAIN purchased from Th. Gold schmidt AG. ^* 12 Laureth-20: BL-20 ^* 13 alkyl polyglucoside purchased from Nikko. PLANTACARE 2000 UP ^* 14 Ethylene glycol distearate: purchased from Henkel: EGDS ^* 15 purchased from Gold Schmidt (Th. Goldschmidt AG.) Silicone emulsion: Tosyl / GE (Tosil / GE) X65-4829 ^* 16 polyoxyethylene glycol purchased from Amercol) WSR N-10 ^* 17 hydroxyethyl cellulose purchased from Amerchol Source: Available from Aqualon. ^* 18 Polyquaternium-10: UCARE POLYMER LR400 purchased from Amerchol ^* 19 Cetyl alcohol: KONOL SERIES ^* purchased from Shinnihon Rika ^* 20 Stearyl alcohol: Conol series purchased from Shinihon Rika ^* 21 Behenyl alcohol: 1-Docosanol (97%) purchased from Wako Pure Chemicals (Wako) ^* 22 pentaerythritol tetraisostearate: Kokyu alcohol Kakupuchi purchased from (Kokyu alcohol) (KAK PTI) * 23 trimethylolpropane triisostearate Over door: Kokyu alcohol Kakutsuchi purchased from (Kokyu alcohol) (KAK TTI) * 24 trimethylol propane trioleate: New Japan Chemical Enujerubu purchased from (Shinih on Rika) (ENUJERUBU) TP3S O * 25 4,4 ' -Bis (5-methylbenzoxazol-2-yl) stilbene: available from TCI ^* 26 Polysorbate 60: TWEEN 60 ^* 27 purchased from ICI Laurylmethyl gluses-10 hydroxypropyldimonium chloride : Gluquat purchased from Amerchol (GLUQUA)
T) 125 ^* 28 dihydrogenated tallowamidoethylhydroxyethylmonium methosulfate: VARISOFT 11 purchased from Wako Pure Chemical Industries (Wako)
0 ^* 29 citric acid: Anhydrous Citric Acid purchased from Haarman & Reimer
CID) ^* 30 Hydroxypropylcellulose: METLOSE, purchased from Shinetsu ^* 31 Aminomethylpropanol: AMP-regular, purchased from Angus ^* 32 Acrylate / Steares-20 methacrylate Copolymer: ACULYN purchased from Rohm & Haas
) ^* 33 Cetyl hydroxyethylcellulose: POLYSURF 67 ^* 34 purchased from Aqualon Polyquaternium-7: MERQUAT S ^* 35 15/85 silicone formulation purchased from calgon : Available from Shinetsu. ^* 36 Stealamidopropyldimethylamine: Amidoamine MPS purchased from Nikko ^* 37 L-Glutamic acid: L-glutamic acid (L-GLUTAMIC ACID) (cosmetic grade) purchased from Ajinomoto ^* 38 Carbomer: CARBOPOL 980 ^* 39, purchased from BF Goodrich, available from Toho (TOHO). ^* 40 Hydrolyzed collagen: PEPTEIN 2000, purchased from Hormel ^* 41 Vitamin E: Emix-d, purchased from Eisai ^* 42 Pantenol: Roche (Roche). ^* 43 Panthenyl ethyl ether: available from Roche.

[0294]

【The invention's effect】

The embodiments disclosed and illustrated by the above-described examples have many advantages. For example, they can provide the benefits associated with optical brighteners (eg, gloss, UV protection, color change) while providing desirable conditioning benefits.

The examples and embodiments described herein are for illustrative purposes only, and various modifications and alterations in light of those will be suggested to those skilled in the art without departing from the spirit and scope of the invention. Needless to say.

──────────────────────────────────────────────────続 き Continued on front page (31) Priority claim number US9716618 (32) Priority date September 17, 1997 (September 17, 1997) (33) Priority claim country United States (US) (31) Priority Claim number US9716619 (32) Priority date September 17, 1997 (September 17, 1997) (33) Priority claiming country United States (US) (31) Priority claim number US9716615 (32) Priority date September 1997 (17 Sep 1997) (33) Priority country United States (US) (81) Designated country EP (AT, BE, CH, CY, DE, DK, ES, FI, FR, GB, GR, IE, IT, LU, MC, NL, PT, SE), OA (BF, BJ, CF, CG, CI, CM, GA, GN, GW, ML, MR, NE, SN, TD, TG), AP (GH, GM, K , LS, MW, SD, SZ, UG, ZW), EA (AM, AZ, BY, KG, KZ, MD, RU, TJ, TM), AL, AM, AT, AU, AZ, BA, BB, BG , BR, BY, CA, CH, CN, CU, CZ, DE, DK, EE, ES, FI, GB, GE, GH, GM, HR, HU, ID, IL, IS, JP, KE, KG, KP, KR, KZ, LC, LK, LR, LS, LT, LU, LV, MD, MG, MK, MN, MW, MX, NO, NZ, PL, PT, RO, RU, SD, SE, SG , SI, SK, SL, TJ, TM, TR, TT, UA, UG, US, UZ, VN, YU, ZW. 72 ) Inventor Hirotaka Uchiyama 5-8-17-3B, Nishiokamoto, Higashi-Nada-ku, Kobe, Japan Term (Reference) 4C083 AB282 AB342 AC071 AC072 AC102 AC122 AC212 AC302 AC392 AC542 AC582 AC642 AC662 AC692 AC712 AC782 AC792 AC841 AC842 AC851 AC852 AD042 AD092 AD131 AD151 AD152 AD212 AD282 AD432 AD532 AD662 BB01 BB36 BB53 CC31 CC33 EE07 BB08

Claims (49)

[Claims] 1. A hair conditioning selected from the group consisting of (a) an effective amount of an optical brightener and (b) a silicone compound, a cationic compound, a high melting point compound, a fragrance compound, a water-insoluble high molecular weight oily compound and mixtures thereof. A hair care composition comprising: 2. An effective amount of an optical brightener selected from the group consisting of (a) polystyrylstilbene, hydroxycoumarin, triazole, pyrazoline, oxazole, pyrene, porphyrin, imidazole and mixtures thereof, and (b)
A) hair care composition comprising a silicone compound. 3. The hair care composition according to claim 2, further comprising a carrier suitable for applying to hair. 4. The hair care composition according to claim 2, wherein said optical brightener is polystyrylstilbene. 5. The hair care composition according to claim 2, wherein the optical brightener is hydroxycoumarin. 6. A hair care composition comprising (a) an effective amount of an optical brightener and (b) a silicone compound selected from the group consisting of high molecular weight dimethicones. 7. The hair care composition according to claim 6, further comprising a carrier suitable for applying to hair. 8. The hair care composition according to claim 7, wherein said optical brightener is polystyrylstilbene. 9. The hair care composition according to claim 7, wherein the optical brightener is hydroxycoumarin. 10. The hair care composition according to claim 7, wherein the optical brightener is a triazine stilbene. 11. The hair care composition according to claim 2 or 6, comprising about 0.001% to about 20% by weight of the optical brightener. 12. The hair care composition according to claim 11, comprising from about 0.01% to about 15% by weight of the silicone compound. 13. A hair care composition according to any one of claims 2 to 12, further comprising another conditioning agent. 14. A shampoo composition comprising (a) an effective amount of an optical brightener, (b) a cleaning surfactant suitable for cleaning hair, and (c) a silicone compound. 15. The composition of claim 14, further comprising a carrier suitable for applying to hair.
A shampoo composition according to claim 1. 16. The optical brightener of claim 15, wherein the optical brightener is selected from the group consisting of polystyrylstilbene, triazinestilbene, hydroxycoumarin, aminocoumarin, triazole, pyrazoline, oxazole, pyrene, porphyrin, imidazole and mixtures thereof. A shampoo composition according to claim 1. 17. The shampoo composition according to claim 16, comprising from about 0.001% to about 20% by weight of the optical brightener. 18. The shampoo composition according to claim 17, comprising from about 0.01% to about 15% by weight of the silicone compound. 19. A shampoo composition according to any one of claims 2 to 18, further comprising another conditioning agent. 20. A hair care composition comprising (a) an effective amount of an optical brightener, (b) a cationic compound, and (c) a carrier suitable for applying to hair. 21. The composition according to claim 20, further comprising a cleaning surfactant suitable for cleaning hair. 22. The composition of claim 21, further comprising another conditioning agent. 23. The composition of claim 20, further comprising another conditioning agent. 24. The optical brightener of claim 20, wherein the optical brightener is selected from the group consisting of polystyrylstilbene, triazinestilbene, hydroxycoumarin, aminocoumarin, triazole, pyrazoline, oxazole, pyrene, porphyrin, imidazole and mixtures thereof. 24. The composition according to any one of claims 1 to 23. 25. The composition of claim 24, comprising from about 0.001% to about 20% by weight of said optical brightener. 26. The composition of claim 25, comprising from about 0.01% to about 10% by weight of said silicone compound. 27. A hair care composition comprising (a) an effective amount of an optical brightener, (b) a high melting point compound, and (c) a carrier suitable for applying to hair. 28. The hair care composition according to claim 27, further comprising a cleaning surfactant suitable for cleaning hair. 29. The composition according to claim 28, further comprising another conditioning agent. 30. The composition of claim 27, further comprising another conditioning agent. 31. The optical brightener is selected from the group consisting of polystyrylstilbene, triazinestilbene, hydroxycoumarin, aminocoumarin, triazole, pyrazoline, oxazole, pyrene, porphyrin, imidazole and mixtures thereof. 31. The hair care composition according to any one of claims to 30. 32. The composition of claim 31, comprising about 0.001% to about 20% by weight of said optical brightener. 33. The composition of claim 32, comprising from about 0.01% to about 20% by weight of said high melting point compound. 34. The composition according to claim 33, wherein said high melting point compound is selected from the group consisting of cetyl alcohol, stearyl alcohol, behenyl alcohol, oleyl alcohol and mixtures thereof. 35. A composition comprising: (a) an effective amount of an optical brightener; (b) a fragrance compound having a CLogP between about -1.0 to about 8.0; and (c) a carrier suitable for applying to hair. A hair care composition comprising: 36. The composition of claim 35, further comprising a cleaning surfactant suitable for cleaning hair. 37. The composition according to claim 36, further comprising another conditioning agent. 38. The composition of claim 35, further comprising another conditioning agent. 39. The optical brightener is selected from the group consisting of polystyrylstilbene, triazinestilbene, hydroxycoumarin, aminocoumarin, triazole, pyrazoline, oxazole, pyrene, porphyrin, imidazole and mixtures thereof. 39. The composition according to any one of the preceding claims. 40. The composition of claim 39, comprising from about 0.001% to about 20% by weight of said optical brightener. 41. A composition comprising at least about 0.05 weight percent of the perfume compound.
41. The composition of claim 40. 42. The composition of claim 41, wherein said perfume compound is selected from the group consisting of carbonyl-containing perfume compounds, ether-containing perfume compounds, hydroxy-containing perfume compounds, and mixtures thereof. 43. A hair care composition comprising (a) an effective amount of an optical brightener and (b) a water-insoluble high molecular weight oily compound. 44. The composition of claim 43, further comprising a carrier suitable for applying to hair.
3. The hair care composition according to item 1. 45. The composition according to claim 44, further comprising a cleaning surfactant suitable for cleaning hair. 46. The composition according to claim 45, further comprising another conditioning agent. 47. The optical brightener of claim 43, wherein the optical brightener is selected from the group consisting of polystyrylstilbene, triazinestilbene, hydroxycoumarin, aminocoumarin, triazole, pyrazoline, oxazole, pyrene, porphyrin, imidazole, and mixtures thereof. 47. The composition according to any one of claims 46. 48. The composition of claim 43, comprising from about 0.001% to about 20% by weight of said optical brightener. 49. The composition of claim 48, comprising from about 0.1% to about 10% by weight of said water-insoluble high molecular weight oleaginous compound.