JP2001200255A - Production method for water-soluble inorganic noncombustible liquid - Google Patents
Production method for water-soluble inorganic noncombustible liquidInfo
- Publication number
- JP2001200255A JP2001200255A JP2000045053A JP2000045053A JP2001200255A JP 2001200255 A JP2001200255 A JP 2001200255A JP 2000045053 A JP2000045053 A JP 2000045053A JP 2000045053 A JP2000045053 A JP 2000045053A JP 2001200255 A JP2001200255 A JP 2001200255A
- Authority
- JP
- Japan
- Prior art keywords
- building materials
- liquid
- fire
- water
- noncombustible
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 239000000126 substance Substances 0.000 claims abstract 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 claims 1
- 229910021538 borax Inorganic materials 0.000 claims 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims 1
- 239000004327 boric acid Substances 0.000 claims 1
- 239000004328 sodium tetraborate Substances 0.000 claims 1
- 235000010339 sodium tetraborate Nutrition 0.000 claims 1
- 239000008234 soft water Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 22
- 239000004566 building material Substances 0.000 abstract description 16
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003063 flame retardant Substances 0.000 abstract description 3
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 abstract description 2
- 238000005192 partition Methods 0.000 abstract description 2
- 230000009970 fire resistant effect Effects 0.000 abstract 2
- 239000004952 Polyamide Substances 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 238000004078 waterproofing Methods 0.000 abstract 1
- 239000000123 paper Substances 0.000 description 10
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000010902 straw Substances 0.000 description 2
- 239000002341 toxic gas Substances 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- IDCBOTIENDVCBQ-UHFFFAOYSA-N TEPP Chemical compound CCOP(=O)(OCC)OP(=O)(OCC)OCC IDCBOTIENDVCBQ-UHFFFAOYSA-N 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Fireproofing Substances (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】テトロン、ナイロン等の無害性樹
脂を耐熱性にする他、主に建材を無機不燃液で500℃
〜800℃でも延焼しない無害性素材に適応させる。[Industrial application] In addition to making harmless resins such as tetron and nylon heat resistant, building materials are mainly made of inorganic nonflammable liquid at 500 ° C.
Suitable for harmless materials that do not spread even at ~ 800 ° C.
【0002】[0002]
【従来の技術及びその問題点】従来から使用されている
建材の大半は難燃性の壁紙等はあるが床材である畳、カ
ーペット、障子紙、襖紙、間仕切り板等の大半は延焼す
るものが使用されている。また難燃性の壁紙は塩ビを使
用したものが多く火災の際、有害な塩素ガスを発生させ
煙を吸って死亡する事例は多い。2. Description of the Related Art Most of conventional building materials have flame-retardant wallpaper, but most of the floor materials such as tatami mats, carpets, shoji paper, fusuma paper, partition boards, etc. are spread. Things are used. In addition, many flame-retardant wallpapers use PVC, and in the event of a fire, harmful chlorine gas is generated and smoke is killed in many cases.
【0003】[0003]
【発明が解決しようとしている課題】火災の大半は床面
から発火し、壁面が延焼し天井面に燃え広がる例が多
い。特に畳、障子紙、襖紙等は瞬時に燃え広がらせ、火
力を増加させる素材である。本発明は、これらの素材を
不燃性液を含浸乾燥させ500℃(ライターの火)〜8
00℃でも局部的な炭化はするが延焼しない上、有害性
のガス等は一切発生しない建材にする事にある。Most of the fires are ignited from the floor, and the wall spreads and burns to the ceiling in many cases. In particular, tatami, shoji paper, fusuma paper, and the like are materials that instantly burn and increase the heat. According to the present invention, these materials are impregnated with a nonflammable liquid and dried to a temperature of 500 ° C. (lighter fire) to 8 ° C.
Even at 00 ° C., it is possible to provide a building material that is locally carbonized but does not spread fire and that does not generate any harmful gas.
【0004】[0004]
【課題を解決しようとする手段】床面で燃焼する建材の
主たる素材は畳、カーペット等である。この種の建材は
畳の場合藺草がタバコの火等で藁床に延焼するため藺
草、カーペットは本発明の請求項のA不燃液(無害性)
を含浸させ乾燥すると500℃〜600℃の不燃材とな
り藺草の表面にタバコの火を置き燃えつくしても表面藺
草の半分が炭化し裏面迄は炭化もなく藁床迄炭化する事
はない。カーペットも同様の効果をもたらす。The main building materials that burn on the floor are tatami mats, carpets and the like. In the case of tatami mats, this type of building material burns on a straw bed due to cigarette fire or the like.
When impregnated and dried, it becomes a non-combustible material at 500 to 600 ° C. Even if a cigarette is put on the surface of the rush and burns, half of the surface rush will carbonize and the back will not carbonize and will not carbonize to the straw bed. Carpets have a similar effect.
【0005】次に壁材であるカーテン、並び壁紙である
が、カーテン等は洗濯するためA不燃液を含浸乾燥後更
に防水加工が必要となる。更に壁紙においては従来の表
面素材の塩ビ使用でなく、織布又は不織布並び不織紙を
A不燃液並びB不燃液を適度に配合した不燃液を含浸乾
燥させ表面不燃材を作る。裏面紙はA不燃液を含浸乾燥
させて不燃材を作る、表面不燃材と裏面不燃材との間に
不燃接着剤として、珪酸ナトリウム70%〜90%、カ
オリン1.5%〜5.0%、酸化鉄0.5%〜3.0
%、シリコーン1.5%〜3.0%の重量比で配合混合
した不燃接着材で表裏面を一体化した無機不燃壁紙は8
00℃でも延焼しない上、有毒ガス等一切発生しない不
燃壁材並び不燃天井壁材になる。[0005] Next, curtains and wall paper, which are wall materials, need to be further waterproofed after being impregnated and dried with a noncombustible liquid A for washing in order to be washed. Furthermore, in the case of wallpaper, instead of using PVC as a conventional surface material, a woven or nonwoven fabric and a nonwoven paper are impregnated and dried with a nonflammable liquid containing a nonflammable liquid A and a nonflammable liquid B appropriately. The back paper is impregnated with the noncombustible liquid A to make a noncombustible material. As a noncombustible adhesive between the front noncombustible material and the back noncombustible material, sodium silicate 70% to 90%, kaolin 1.5% to 5.0% , Iron oxide 0.5% to 3.0
%, Silicone is 1.5% to 3.0% by weight and a non-combustible adhesive is used.
It becomes a non-combustible wall material and a non-combustible ceiling wall material that does not spread even at 00 ° C. and does not generate any toxic gas.
【0006】天井材の不燃天井壁材は前述の無機不燃壁
を使用し天井板として20倍に発泡した細粒パーライト
を主原材とし、珪酸ナトリウム、シリコーンオイル、補
強繊維を混合し、プレス成型したパーライト繊維板を張
り付ける事で800℃以上の耐火天井材をもたらす。[0006] The non-combustible ceiling wall material is made of the above-mentioned inorganic non-combustible wall, and the main raw material is a fine pearlite foamed 20 times as a ceiling plate, mixed with sodium silicate, silicone oil and reinforcing fibers, and press-molded. A fireproof ceiling material of 800 ° C. or higher can be obtained by attaching a perlite fiberboard.
【0007】[0007]
【 作用 】本発明の不燃液は床面から側壁並び天井材
迄無機質で無害性な建材で構成されており600℃〜8
00℃で炭化はするが延焼しない上有毒ガス等一切発生
しない建材であるため、従来の建材よりはるかに耐火建
築の家として適応するものである。次に本発明の不燃液
の配合比率(重量比)の炭化率(炭化長さ)を表1によ
って示す。 試験方法 (A)試験品 1.障子紙(試料1〜試料4) 2.壁紙 和紙+不燃接着剤+障子紙(試料5〜試料
6) (B)燃焼方法 巾2cm長さ15cmに切断し下
図の様にライターの火(460℃)5分発火させる。The nonflammable liquid of the present invention is composed of inorganic and harmless building materials from the floor surface to the side walls and ceiling materials.
Since it is a building material that carbonizes at 00 ° C but does not spread and does not generate any toxic gas, it is much more suitable for a house with a fireproof construction than conventional building materials. Next, Table 1 shows the carbonization ratio (carbonization length) of the compounding ratio (weight ratio) of the nonflammable liquid of the present invention. Test method (A) Test product 1. Shoji paper (Sample 1 to Sample 4) Wallpaper Japanese paper + non-combustible adhesive + shoji paper (sample 5 to sample 6) (B) Burning method Cut to 2 cm wide and 15 cm long and ignite for 5 minutes on a lighter fire (460 ° C) as shown below.
【0008】[0008]
【表1】 [Table 1]
Claims (1)
水とし、温水重量比55%〜85%に無機化学薬品とし
てスルファミン酸アンモニウム10%〜35%、ほう酸
1.0%〜3.0%、ほう砂1.0%〜3.0%、水性
シリコーン0.5%〜3.0%、等の化学薬品を混合し
てなるA不燃液にカオリン0.5%〜1.0%、酸化鉄
0.5%〜2.0%等の化学薬品をA不燃液に混入して
なるB不燃液を綿、紙、樹脂、乾燥草、木、等に種類別
にA,B液を各品毎に適応し組合せ含浸乾燥させて不燃
性をもたらす水溶性無機不燃液の製造法。1. The alkaline soft water is hot water at 80 ° C. to 100 ° C., and the weight ratio of hot water is 55% to 85%, ammonium sulfamate 10% to 35%, boric acid 1.0% to 3.0% as inorganic chemicals, Kaolin 0.5% to 1.0%, iron oxide in non-flammable liquid A made by mixing chemicals such as borax 1.0% to 3.0%, aqueous silicone 0.5% to 3.0%, etc. A non-combustible liquid obtained by mixing a chemical such as 0.5% to 2.0% into the non-combustible liquid is used. A method for producing a water-soluble inorganic nonflammable liquid that is adapted and combined and impregnated and dried to provide nonflammability.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000045053A JP2001200255A (en) | 2000-01-19 | 2000-01-19 | Production method for water-soluble inorganic noncombustible liquid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000045053A JP2001200255A (en) | 2000-01-19 | 2000-01-19 | Production method for water-soluble inorganic noncombustible liquid |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2001200255A true JP2001200255A (en) | 2001-07-24 |
Family
ID=18567713
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2000045053A Pending JP2001200255A (en) | 2000-01-19 | 2000-01-19 | Production method for water-soluble inorganic noncombustible liquid |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2001200255A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003041925A1 (en) * | 2001-11-16 | 2003-05-22 | Asano Mokuzai Industry Co., Ltd | Method of manufacturing noncombustible wood |
-
2000
- 2000-01-19 JP JP2000045053A patent/JP2001200255A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003041925A1 (en) * | 2001-11-16 | 2003-05-22 | Asano Mokuzai Industry Co., Ltd | Method of manufacturing noncombustible wood |
US7178263B2 (en) | 2001-11-16 | 2007-02-20 | Asano Mokuzai Industry Co., Ltd. | Method of manufacturing incombustible wood |
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