JP2001145872A - Method and apparatus for cleaning polluted ground or waste landfill ground - Google Patents
Method and apparatus for cleaning polluted ground or waste landfill groundInfo
- Publication number
- JP2001145872A JP2001145872A JP33191299A JP33191299A JP2001145872A JP 2001145872 A JP2001145872 A JP 2001145872A JP 33191299 A JP33191299 A JP 33191299A JP 33191299 A JP33191299 A JP 33191299A JP 2001145872 A JP2001145872 A JP 2001145872A
- Authority
- JP
- Japan
- Prior art keywords
- purification
- ground
- injection
- injection well
- waste landfill
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002699 waste material Substances 0.000 title claims abstract description 55
- 238000004140 cleaning Methods 0.000 title claims abstract 7
- 238000000034 method Methods 0.000 title claims description 30
- 238000002347 injection Methods 0.000 claims abstract description 141
- 239000007924 injection Substances 0.000 claims abstract description 141
- 238000000746 purification Methods 0.000 claims description 115
- 230000001737 promoting effect Effects 0.000 claims description 44
- 239000000126 substance Substances 0.000 claims description 34
- 239000007789 gas Substances 0.000 claims description 27
- 244000005700 microbiome Species 0.000 claims description 23
- 239000001301 oxygen Substances 0.000 claims description 19
- 229910052760 oxygen Inorganic materials 0.000 claims description 19
- 239000002689 soil Substances 0.000 claims description 19
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 18
- 239000000356 contaminant Substances 0.000 claims description 17
- 235000015097 nutrients Nutrition 0.000 claims description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 7
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 4
- 230000003213 activating effect Effects 0.000 claims description 3
- 238000007664 blowing Methods 0.000 claims description 2
- 239000013618 particulate matter Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 3
- 239000000243 solution Substances 0.000 abstract 1
- 239000003344 environmental pollutant Substances 0.000 description 10
- 231100000719 pollutant Toxicity 0.000 description 10
- 238000000354 decomposition reaction Methods 0.000 description 8
- 241000894006 Bacteria Species 0.000 description 7
- 238000003915 air pollution Methods 0.000 description 6
- 239000003673 groundwater Substances 0.000 description 6
- 238000003860 storage Methods 0.000 description 5
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 230000000593 degrading effect Effects 0.000 description 3
- 239000002360 explosive Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 101100325793 Arabidopsis thaliana BCA2 gene Proteins 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 230000001546 nitrifying effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 150000004045 organic chlorine compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Processing Of Solid Wastes (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、汚染地盤や廃棄物
埋立地盤(以下、総称して単に「汚染地盤」と記す。)
の浄化方法およびその浄化装置に関し、特に、汚染地盤
や廃棄物埋立地盤に挿入した注入井から超高圧の空気を
短時間の間隔でパルス状にして間欠的に汚染地盤中に吹
き込むようにした汚染地盤や廃棄物埋立地盤の浄化方法
およびその浄化装置に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a contaminated ground or a waste landfill (hereinafter referred to simply as "contaminated ground").
In particular, a method and apparatus for purifying wastewater, in particular, by injecting ultra-high pressure air from an injection well inserted into a contaminated ground or a waste landfill into a pulsed manner at short intervals to intermittently blow the air into the contaminated ground. The present invention relates to a method for purifying a ground or a waste landfill and a purification device therefor.
【0002】[0002]
【従来の技術】汚染物質として有機塩素系化合物および
油分、その他重金属類等様々の物質が挙げられ、更に、
これら汚染物質以外に有機性の分解成分を含めた汚染物
質等で汚染された地盤や廃棄物埋立地盤が大きな問題と
なっている。ここで、本明細書にあっては廃棄物埋立地
盤をも含めて汚染地盤と称するものとする。2. Description of the Related Art Pollutants include various substances such as organochlorine compounds, oils, and other heavy metals.
Grounds and waste landfills contaminated with contaminants including organic decomposition components other than these contaminants have become a major problem. Here, in this specification, the term "contaminated ground" includes the landfill of waste.
【0003】近年では上記汚染物質等の浄化方法および
浄化装置が各種提案されており、特に設備やスペース上
有利になる原位置浄化が多く見受けられる。この原位置
浄化では土着の分解微生物を利用する方法(バイオレメ
ディエーション)があり、この分解微生物の活性化を図
るために空気(酸素)や栄養塩類などの栄養源を地盤中
に注入したり、場合によっては新たに分解微生物を補充
したりすることが提案されている。例えば、特開平10
−216696号公報には汚染土壌に酸素を供給する装
置が開示される。これは汚染土壌下の地下水まで達する
注入井を設け、この注入井から酸素を過分に含む過飽和
水を地下水中に供給して地下水を酸素過飽和状態とし、
この酸素過飽和の地下水から微細気泡を発生させて表層
の汚染土壌に酸素を供給しようとするものである。In recent years, various methods and apparatuses for purifying the above pollutants have been proposed, and in-situ purification, which is particularly advantageous in terms of equipment and space, is often found. In this in situ purification, there is a method (bioremediation) that utilizes indigenous decomposed microorganisms. In order to activate these decomposed microorganisms, nutrients such as air (oxygen) and nutrients are injected into the ground, In some cases, it has been proposed to replenish degrading microorganisms. For example, JP
JP-A-216696 discloses an apparatus for supplying oxygen to contaminated soil. This is to set up an injection well that reaches the groundwater under the contaminated soil, supply supersaturated water containing excess oxygen into the groundwater from this injection well, and make the groundwater oxygen supersaturated,
Micro bubbles are generated from this oxygen supersaturated groundwater to supply oxygen to the contaminated soil on the surface.
【0004】[0004]
【発明が解決しようとする課題】しかしながら、かかる
従来の地下水から汚染土壌に酸素を供給する場合は、土
壌に酸素が自然に浸透することにより土着の分解微生物
が活性化されていくものであるから、著しく長い浄化期
間が必要になり、しかも土壌には割れ目や柔らかい箇所
があって全体に均一ではないので、このような箇所に酸
素が集中して浸透していってしまう結果、土壌全体を均
一に浄化することはできない。However, when oxygen is supplied to contaminated soil from such conventional groundwater, indigenous decomposing microorganisms are activated by the natural infiltration of oxygen into the soil. However, it requires a very long purification period, and the soil has cracks and soft spots, which are not uniform. Can not be purified.
【0005】また、注入井を汚染土壌中に挿入して、酸
素(空気)あるいはその他の分解促進性物質および分解
微生物等の浄化促進成分を土壌中に直接注入することが
考えられている。この場合、該浄化促進成分を水溶液や
ガス状として土壌中に注入することになるが、この場合
にあってもやはり土壌の不均一性により浄化ムラを生ず
る。また、注入に際しては、その注入圧を一定に保って
注入するが、連続的に注入するためその注入圧もさほど
高圧にはすることができず、よって浄化促進成分の到達
距離は短く、これ故、注入井1基当たりの浄化領域を広
く確保することができない。従って、広範な所望領域の
汚染地盤を浄化するためには、注入井の本数を多くしな
ければならず、地盤浄化のコストが高くなってしまうと
いう課題があった。It is also considered that an injection well is inserted into contaminated soil, and oxygen (air) or other decomposing promoting substances and purification promoting components such as decomposing microorganisms are directly injected into the soil. In this case, the purification-promoting component is injected into the soil as an aqueous solution or a gas. However, even in this case, the purification becomes uneven due to the unevenness of the soil. In addition, at the time of injection, the injection pressure is maintained at a constant level. However, since the injection is performed continuously, the injection pressure cannot be made very high. However, it is not possible to secure a wide purification area per injection well. Therefore, in order to purify the contaminated ground in a wide range of desired areas, the number of injection wells must be increased, and there has been a problem that the cost of ground purification is increased.
【0006】本発明はかかる従来の課題に鑑みて成され
たものであり、浄化促進成分をより遠くかつより広範囲
に到達させて汚染地盤の浄化能力を大幅に向上させるこ
とが可能な汚染地盤の浄化方法およびその浄化装置を提
供することを目的とする。[0006] The present invention has been made in view of the above-mentioned conventional problems, and is intended to improve the purification ability of the contaminated ground by allowing the purification-promoting component to reach farther and more widely. It is an object to provide a purification method and a purification device therefor.
【0007】[0007]
【課題を解決するための手段】かかる目的を達成するた
めに本発明の汚染地盤の浄化方法は、汚染地盤や廃棄物
埋立地盤に挿入した注入井に超高圧をもって浄化促進成
分を短時間の間隔でパルス状にして間欠的に供給し、こ
の注入井の噴出口から超高圧の浄化促進成分を該汚染地
盤や廃棄物埋立地盤中に吹き込むことを特徴とする(請
求項1)。According to the present invention, there is provided a method for purifying a contaminated ground, comprising the steps of: And an intermittent supply in the form of a pulse, and an ultrahigh-pressure purification promoting component is blown into the contaminated ground and the waste landfill from the injection port of the injection well (claim 1).
【0008】また、この浄化方法を達成するための浄化
装置は、汚染地盤や廃棄物埋立地盤に挿入される注入井
と、この注入井の上端部に取り付けられて超高圧の圧搾
空気を短時間の間隔でパルス状にして間欠的に該注入井
に供給する高圧間欠注入装置と、該圧搾空気の供給経路
に接続され浄化促進成分を圧搾空気に添加する浄化促進
成分供給設備とを備え、上記注入井の噴出口から圧搾空
気とともに浄化促進成分を汚染地盤や廃棄物埋立地盤中
に吹き込む構成とする(請求項5)。[0008] Further, a purification apparatus for achieving this purification method comprises an injection well inserted into a contaminated ground or a waste landfill, and an ultrahigh-pressure compressed air attached to the upper end of the injection well for a short time. A high-pressure intermittent injection device that supplies pulses to the injection well intermittently at intervals of, and a purification-promoting component supply facility that is connected to the supply path of the compressed air and adds a purification-promoting component to the compressed air, Purification promoting components are blown into the contaminated ground and waste landfill along with compressed air from the injection well outlet.
【0009】この浄化方法およびその浄化装置では、浄
化促進成分が超高圧(例えば2〜10気圧)をもって注
入井に短時間の間隔でパルス状にされて間欠的(例え
ば、1/30〜1/5HZの周期)に供給されるため、該浄化促
進成分は該注入井の噴出口から汚染地盤や廃棄物埋立地
盤中に所定の間欠タイミングをもって超高圧で爆発的に
吹き込まれることになる。このため、注入井から汚染地
盤や廃棄物埋立地盤中に注入される浄化促進成分はより
遠くかつより広い範囲に拡散して到達されることにな
り、汚染地盤や廃棄物埋立地盤中の汚染物質を広範囲に
亘って浄化して、1基当たりの注入井での浄化領域を大
幅に拡大することが可能になる。また、浄化促進成分の
爆発的注入はパルス状にされて間欠的に継続して繰り返
されるため、注入の度に地盤の堆積状況に変化を及ぼし
て浄化促進成分の通り道がランダムになり易く、地盤全
体を可及的にほぼ均一に浄化可能となる。更に、混在す
る汚染物質等に適した浄化促進成分の注入を間欠注入で
実施することにより、注入成分の濃度の管理を容易にし
て無駄が無くなる。In this purification method and its purification apparatus, the purification promoting component is pulsed into the injection well at an extremely high pressure (for example, 2 to 10 atm) at short intervals, and intermittently (for example, 1/30 to 1/1). (5HZ cycle), the purification-promoting component is explosively blown from the injection port of the injection well into the contaminated ground or the waste landfill at an extremely high pressure at a predetermined intermittent timing. As a result, the purification-promoting components injected from the injection well into the contaminated ground or waste landfill will diffuse and reach a farther and wider area, and the contaminants in the contaminated ground or waste landfill will be contaminated. And the purification area per injection well can be greatly expanded. In addition, since the explosive injection of the purification-promoting component is intermittently repeated in the form of a pulse, the path of the purification-promoting component is likely to be random at each injection, and the path of the purification-promoting component is likely to be random. The whole can be purified as uniformly as possible. Further, by intermittently injecting a purification promoting component suitable for mixed contaminants and the like, the concentration of the injected component can be easily controlled and waste can be eliminated.
【0010】更に、上記浄化方法にあって、汚染地盤や
廃棄物埋立地盤に挿入した吸引井から地盤中のガス状物
質を回収し、この回収したガス状物質を浄化処理により
無害化して排出することが望ましい(請求項2)。Further, in the above-mentioned purification method, gaseous substances in the ground are recovered from a suction well inserted into a contaminated ground or a waste landfill, and the recovered gaseous substances are made harmless by a purification treatment and discharged. It is desirable (claim 2).
【0011】また、この浄化方法を達成するための浄化
装置は、汚染地盤や廃棄物埋立地盤に挿入される注入井
と、この注入井の上端部に取り付けられて超高圧の圧搾
空気を短時間の間隔でパルス状にして間欠的に該注入井
に供給する高圧間欠注入装置と、該圧搾空気の供給経路
に接続され浄化促進成分を圧搾空気に添加する浄化促進
成分供給設備と、上記注入井に所定間隔をあけて汚染地
盤や廃棄物埋立地盤に挿入される吸引井と、該吸引井で
回収した地盤中のガス状物質を浄化処理して無害化する
排出ガス浄化設備と、を備えた構成とする(請求項
6)。[0011] Further, a purifying apparatus for achieving this purifying method includes an injection well inserted into a contaminated ground or a waste landfill, and an ultrahigh-pressure compressed air attached to the upper end of the injection well for a short time. A high-pressure intermittent injection device that supplies pulses to the injection well intermittently at intervals of: a purification-promoting-component supply facility that is connected to the compressed-air supply path and adds a purification-promoting component to the compressed air; A suction well inserted at a predetermined interval into a contaminated ground or a waste landfill, and an exhaust gas purification facility for purifying and detoxifying gaseous substances in the ground collected by the suction well. (Claim 6).
【0012】この浄化方法および浄化装置では、注入井
から浄化促進成分を汚染地盤や廃棄物埋立地盤中に注入
する一方で吸収井からガス状物質を吸引するので、浄化
促進成分がより拡散し易くなるとともに、分解ガスや余
剰ガス等の有害なガス状物質が地盤から自然に大気中に
放出される前に、これらを吸引井で捕集して浄化処理し
た後に放出できるため、大気汚染を防止することができ
る。According to the purification method and the purification apparatus, since the purification promoting component is injected from the injection well into the contaminated ground and the waste landfill, while the gaseous substance is sucked from the absorption well, the purification promotion component is more easily diffused. In addition, harmful gaseous substances such as decomposed gas and surplus gas can be released from the ground naturally after being collected and purified by a suction well before being released into the atmosphere, thus preventing air pollution. can do.
【0013】ここで、上記浄化促進成分には、空気や過
酸化水素やオゾン等の酸素含有物質、分解微生物、分解
微生物を活性化する栄養源、などの汚染物質の浄化を促
進する成分を用いることができ、各種汚染物質に即した
浄化を適正に行うことができる(請求項3)。Here, as the above-mentioned purification-promoting component, a component which promotes purification of contaminants such as oxygen-containing substances such as air, hydrogen peroxide and ozone, decomposing microorganisms, and nutrient sources for activating the decomposing microorganisms is used. Thus, purification can be appropriately performed in accordance with various pollutants (claim 3).
【0014】また、浄化装置としては、汚染地盤や廃棄
物埋立地盤に挿入される注入井と、この注入井の上端部
に取り付けられて超高圧の圧搾空気を短時間の間隔でパ
ルス状にして間欠的に該注入井に供給する高圧間欠注入
装置と、該圧搾空気の供給経路に接続され浄化促進成分
を圧搾空気に添加する浄化促進成分供給設備と、地表部
に噴出した地盤中のガス状物質が拡散するのを防止すべ
く該地表部を覆って設けられたシート部材と、該シート
部材と地表部との間に設けられて噴出したガス状物質を
吸引回収する吸引パイプと、該吸引パイプで回収したガ
ス状物質を浄化処理して無害化する排出ガス浄化設備
と、を備えた構成としても良い(請求項7)。[0014] Further, as a purification device, an injection well inserted into a contaminated ground or a waste landfill and an ultrahigh-pressure compressed air attached to the upper end of the injection well are pulsed at short intervals. A high-pressure intermittent injection device that intermittently supplies the injection well, a purification-promoting component supply device that is connected to the compressed-air supply path, and that adds a purification-promoting component to the compressed air; A sheet member provided to cover the ground surface to prevent the substance from diffusing; a suction pipe provided between the sheet member and the ground surface to suction and collect the ejected gaseous substance; An exhaust gas purifying facility for purifying and detoxifying gaseous substances collected by a pipe may be provided (claim 7).
【0015】この、浄化装置では、汚染地盤や廃棄物埋
立地盤の地表部を覆ってシート部材を設けることで、地
盤中から地表部に噴出するガス状物質が大気中に拡散し
てしまうことを防止するとともに、該シート部材と地表
部との間に設けた吸引パイプで地表部に噴出したガス状
物質を吸引回収するので、前記同様に大気汚染を防止し
つつ地盤の浄化が行え、しかも吸引井を地盤中に挿入す
る場合に比して、施工が容易でコストの低減が図れる。[0015] In this purification device, by providing a sheet member covering the surface of the contaminated ground or the landfill of waste, the gaseous substance spouting from the ground to the surface is prevented from diffusing into the atmosphere. In addition to the above, since the gaseous substances ejected to the ground surface are suctioned and collected by the suction pipe provided between the sheet member and the ground surface, the ground can be purified while preventing air pollution as described above. Compared with the case where a well is inserted into the ground, construction is easier and cost can be reduced.
【0016】更にまた、上記浄化方法にあって、上記注
入井の噴出口を汚染地盤や廃棄物埋立地盤中で昇降自在
とし、上記浄化促進成分の注入位置を上下方向に調整す
ることが望ましい(請求項4)。Furthermore, in the above-mentioned purification method, it is desirable that the injection port of the injection well be made movable up and down in a contaminated ground or a waste landfill, and the injection position of the purification promoting component is adjusted vertically. Claim 4).
【0017】また、この浄化方法を達成するための浄化
装置は、上記注入井は、汚染地盤や廃棄物埋立地盤中に
配置される部分の外周を内外方向に連通するガイド管で
囲繞するとともに、該ガイド管内に上記注入井の噴出口
を昇降可能に配置し、該噴出口の上下位置を調整自在に
構成する(請求項8)。Further, in the purification apparatus for achieving this purification method, the injection well surrounds the outer periphery of a portion disposed in the contaminated ground or the waste landfill with a guide pipe communicating inward and outward. The injection port of the injection well is disposed in the guide pipe so as to be able to move up and down, and the vertical position of the injection port is configured to be adjustable.
【0018】この浄化方法および浄化装置では、1つの
注入井で浄化促進成分の注入位置を上下に変化させるこ
とができるため、汚染地盤や廃棄物埋立地盤の汚染領域
の深度が大きい場合にも浄化促進成分を上下方向に均等
に吹き込んで、地盤の浄化を上下方向に均等化すること
ができる。In this purification method and purification device, the injection position of the purification promoting component can be changed up and down in one injection well, so that even when the depth of the contaminated area of the contaminated ground or the waste landfill is large, the purification is performed. The cleansing of the ground can be equalized in the vertical direction by blowing the accelerating component evenly in the vertical direction.
【0019】[0019]
【発明の実施の形態】以下、本発明の実施形態を添付図
面を参照して詳細に説明する。図1は本発明の汚染地盤
の浄化方法の第1実施形態を示し、同図は浄化装置の要
部を概略的に示す断面図である。Embodiments of the present invention will be described below in detail with reference to the accompanying drawings. FIG. 1 shows a first embodiment of a method for purifying contaminated ground according to the present invention, and FIG. 1 is a sectional view schematically showing a main part of a purification apparatus.
【0020】本発明の汚染地盤(廃棄物埋立地盤をも含
むものとする)の浄化方法の基本とするところは、汚染
地盤12に挿入した注入井14に超高圧をもって浄化促
進成分を短時間の間隔でパルス状にして間欠的に供給
し、この注入井14の噴出口14aから超高圧の浄化促
進成分を所定の間欠タイミングをもって該汚染地盤12
中に爆発的に吹き込むことにある。The basis of the method for purifying a contaminated ground (including a waste landfill) according to the present invention is based on the fact that an injection well 14 inserted into a contaminated ground 12 is supplied with an ultrahigh pressure to purify a purification promoting component at short intervals. It is supplied intermittently in the form of a pulse, and an ultra-high pressure purification promoting component is supplied from the injection port 14a of the injection well 14 at a predetermined intermittent timing.
To blow into it explosively.
【0021】即ち、本発明の汚染地盤の浄化方法は図1
に示す浄化装置10をもって達成できる。この浄化装置
10は本発明の浄化方法を達成するための一実施形態を
示し、汚染地盤12に挿入される注入井14と、この注
入井14の上端部に取り付けられて超高圧の圧搾空気を
短時間の間隔でパルス状にして間欠的に該注入井14に
供給する高圧間欠注入装置16と、該圧搾空気の供給経
路18に接続され浄化促進成分を圧搾空気に添加する浄
化促進成分供給設備20とを備えて構成される。That is, the method for purifying contaminated ground of the present invention is shown in FIG.
Can be achieved by the purifying apparatus 10 shown in FIG. This purification apparatus 10 shows one embodiment for achieving the purification method of the present invention, and an injection well 14 inserted into a contaminated ground 12, and an ultrahigh-pressure compressed air attached to the upper end of the injection well 14 A high-pressure intermittent injecting device 16 which supplies pulses to the injection well 14 intermittently at short intervals, and a purification-promoting component supply device connected to the compressed air supply path 18 for adding the purification-promoting component to the compressed air 20.
【0022】上記汚染地盤12は廃棄物埋立処分場の場
合であり、この廃棄物埋立処分場には分解性の有機ゴミ
が埋め立てられており、長期間に亘って分解し、爆発性
ガスや有害ガスおよび悪臭が発せられる。また、分解に
より汚濁物質の多い浸出水も発生することになる。そし
て、該汚染地盤12にはこれに鉛直にボーリングして上
記注入井14が挿入される。該注入井14は所定長さの
パイプで形成され、これの下端部に設けられる噴出口1
4aは汚染地盤12の所定深度に位置するとともに、該
注入井14の上端部は地表に突出した状態にある。The above-mentioned contaminated ground 12 is a case of a waste landfill site, in which decomposable organic trash is buried and decomposed over a long period of time. Gases and odors are emitted. In addition, the decomposition also generates leachate containing a large amount of pollutants. Then, the injection well 14 is inserted into the contaminated ground 12 by boring vertically. The injection well 14 is formed of a pipe of a predetermined length, and a jet port 1 provided at a lower end thereof.
4a is located at a predetermined depth of the contaminated ground 12, and the upper end of the injection well 14 is protruding above the ground.
【0023】上記高圧間欠注入装置16は上記注入井1
4の上端に接続され、該高圧間欠注入装置16にはエア
コンプレッサ22で発生される超高圧(例えば、2〜1
0気圧)の圧搾空気が供給管18aを介して導入され
る。該高圧間欠注入装置16は、図示省略したが圧搾空
気を貯留するタンクと、このタンク内の圧搾空気を間欠
的に排出する間欠バルブとを備え、タンク内の圧力が所
定圧以上になると間欠バルブが瞬時に開弁して高圧空気
を排出するとともに、この排出によってタンク内圧力が
低下されると間欠バルブは瞬時に閉弁される構造となっ
ている。The high-pressure intermittent injection device 16 is connected to the injection well 1
4 and is connected to the high-pressure intermittent injection device 16 with an ultra-high pressure (for example, 2 to 1) generated by the air compressor 22.
(0 atm) of compressed air is introduced via the supply pipe 18a. The high-pressure intermittent injection device 16 includes a tank (not shown) for storing compressed air, and an intermittent valve for intermittently discharging the compressed air in the tank. Are instantaneously opened to discharge high-pressure air, and when the pressure in the tank is reduced by this discharge, the intermittent valve is immediately closed.
【0024】従って、エアコンプレッサ22から圧搾空
気が供給される間は、高圧間欠注入装置16はタンク内
の高圧空気を短時間の間隔でパルス状にして間欠的(例
えば、1/30〜1/5HZの周期)に排出し続け、この圧搾空
気は上記注入井14に供給される。すると、この超高圧
の圧搾空気は注入井14の下端部の噴出口14aから所
定の間欠タイミングをもって瞬間的に汚染地盤12中に
注入される。この注入の際、キャビテーション効果が発
揮されて圧搾空気は爆発的に噴出口14aから吹き出さ
れ、このときの吹き出しエネルギーは著しく大きなもの
となる。Therefore, while the compressed air is supplied from the air compressor 22, the high-pressure intermittent injection device 16 intermittently makes the high-pressure air in the tank pulsed at short intervals (for example, 1/30 to 1/30). The compressed air is supplied to the injection well 14. Then, the ultra-high pressure compressed air is instantaneously injected into the contaminated ground 12 from the jet port 14 a at the lower end of the injection well 14 at a predetermined intermittent timing. At the time of this injection, the cavitation effect is exerted, and the compressed air is explosively blown out from the jet port 14a, and the blowout energy at this time becomes extremely large.
【0025】上記浄化促進成分供給設備20としては、
浄化促進成分を溜める貯蔵タンク24が設けられ、この
貯蔵タンク24は流量調整バルブ26を介して管路24
aで高圧間欠注入装置16の吐出側の供給経路18に連
通される。ここで供給経路18とは、圧搾空気をエアコ
ンプレッサ22から汚染地盤12中に供給する経路であ
り、該エアコンプレッサ22と高圧間欠注入装置16と
を結ぶ上記供給管18a、および該高圧間欠注入装置1
6自体、更に、注入井14を含むものとする。そして、
該流量調整バルブ26を開弁することにより、貯蔵タン
ク24内の浄化促進成分は圧搾空気中に添加され、か
つ、この添加量は該流量調整バルブ26の開度調節によ
り制御される。The purification promoting component supply equipment 20 includes
A storage tank 24 for storing the purification promoting component is provided, and this storage tank 24 is connected to a pipe 24 through a flow control valve 26.
At a, it is connected to the supply path 18 on the discharge side of the high-pressure intermittent injection device 16. Here, the supply path 18 is a path for supplying compressed air from the air compressor 22 into the contaminated ground 12, and the supply pipe 18a connecting the air compressor 22 and the high-pressure intermittent injection device 16, and the high-pressure intermittent injection device. 1
6 itself further includes an injection well 14. And
By opening the flow control valve 26, the purification promoting component in the storage tank 24 is added to the compressed air, and the amount of addition is controlled by adjusting the opening of the flow control valve 26.
【0026】上記貯蔵タンク24に溜められる浄化促進
成分は、空気や過酸化水素(H2O2)やオゾン(O3)
等の酸素含有物質、分解微生物M、この分解微生物Mを
活性化する栄養源、などの汚染物質の浄化を促進する成
分である。汚染物質は特に代表的なものとして有機塩素
系化合物、油、溶剤、揮発性物質、農薬、その他の分解
性の有機性物質、およびシアンなどがある。The purification accelerating components stored in the storage tank 24 include air, hydrogen peroxide (H 2 O 2 ) and ozone (O 3 ).
And other components that promote the purification of contaminants such as oxygen-containing substances such as oxygen-decomposed microorganisms M, nutrients that activate the decomposed microorganisms M, and the like. Pollutants are particularly representative of organochlorines, oils, solvents, volatiles, pesticides, other degradable organics, and cyanide.
【0027】空気はこれに含まれる酸素により好気性微
生物Mの活性化を促進し、H2O2は酸素を発生するとき
の気泡により油汚染土の土粒子より油を剥離する効果が
あり、水と酸素に分解した後は余分な物質が残留せず、
かつ、霧状として容易に注入できる。また、O3は酸化
効率が更に良い。栄養源は、分解微生物Mを増殖するに
適した栄養塩類やこの分解微生物Mを活性化するに適し
た成分が用いられ、例えば、栄養塩類としては、燐,窒
素,カリ,珪素など生物の生命を維持するうえで必要な
主要元素と、マンガンなどの微量元素で炭素、水素、酸
素以外の主に塩類として摂られるものがある。Air promotes the activation of aerobic microorganisms M by oxygen contained therein, and H 2 O 2 has an effect of separating oil from soil particles of oil-contaminated soil by bubbles when generating oxygen, After decomposing into water and oxygen, no extra substances remain,
And it can be easily injected as a mist. O 3 has better oxidation efficiency. As the nutrient source, nutrients suitable for growing the degrading microorganism M and components suitable for activating the degrading microorganism M are used. Examples of the nutrient include phosphorus, nitrogen, potash, silicon, and the like of living organisms. There are some major elements required to maintain the above and trace elements such as manganese which are mainly taken as salts other than carbon, hydrogen and oxygen.
【0028】また、分解微生物MとしてはTCE(トリ
クロロエチレン)を好気分解(酸化)するメタン資化性
菌が知られるが、このメタン資化性菌では栄養源として
メタンが用いられる。また、TCE分解に用いられるそ
の他の分解微生物Mとしては、トルエン資化性菌、フェ
ノール資化性菌、硝化細菌、プロパン酸化細菌、イソプ
ロピレン酸化細菌などが知られ、それぞれに適した栄養
源が用いられる。勿論、TCEに限ることなく汚染地盤
12中のその他の汚染物質に対しては、その汚染物質を
浄化する分解微生物Mに適した栄養源が用いられること
はいうまでもない。As the decomposing microorganism M, a methane-utilizing bacterium that aerobically decomposes (oxidizes) TCE (trichloroethylene) is known. In this methane-utilizing bacterium, methane is used as a nutrient source. Other decomposing microorganisms M used for TCE decomposition include toluene-utilizing bacteria, phenol-utilizing bacteria, nitrifying bacteria, propane-oxidizing bacteria, and isopropylene-oxidizing bacteria. Used. It goes without saying that a nutrient source suitable for the decomposing microorganism M that purifies the contaminant is used for other contaminants in the contaminated ground 12 without being limited to the TCE.
【0029】従って、本実施形態の汚染地盤の浄化方法
では、上記浄化装置10のエアコンプレッサ22を駆動
して圧搾空気を高圧間欠注入装置16に供給することに
より、超高圧の圧搾空気は注入井14の噴出口14aか
ら汚染地盤12中に注入される。このとき、浄化促進成
分供給設備20の流量調整バルブ26を開弁しておくこ
とにより、貯蔵タンク26内の浄化促進成分が上記圧搾
空気とともに汚染地盤12中に注入される。ここで、酸
素を含む圧搾空気は浄化促進成分の1つであり、以下、
該圧搾空気を含めて浄化促進成分として表現する。Therefore, in the method of purifying contaminated ground according to the present embodiment, the compressed air is supplied to the high-pressure intermittent injection device 16 by driving the air compressor 22 of the purification device 10 so that the ultra-high-pressure compressed air is supplied to the injection well. 14 is injected into the contaminated ground 12 from the spout 14a. At this time, by opening the flow control valve 26 of the purification promoting component supply facility 20, the purification promoting component in the storage tank 26 is injected into the contaminated ground 12 together with the compressed air. Here, compressed air containing oxygen is one of the purification promoting components.
Expressed as a purification promoting component including the compressed air.
【0030】そして、汚染地盤12中に注入される浄化
促進成分は、上記高圧間欠注入装置16によって超高圧
をもって短時間の間隔でパルス状にされて所定の間欠タ
イミングで供給されるため、噴出口14aから汚染地盤
12中に爆発的に吹き込まれ、より遠くかつより広範囲
に到達されることになる。また、上記浄化促進成分の爆
発的注入は間欠的に繰り返されるため、注入の度に汚染
地盤12の堆積状況に変化を及ぼして浄化促進成分の通
り道がランダムになり易く、汚染地盤12全体がほぼ均
一に浄化される。更に、上記流量調整バルブ26の開度
調整により浄化促進成分の流量制御が可能となるが、混
在する汚染物質等に適した浄化促進成分の注入を間欠注
入で実施することにより、間欠注入成分の濃度の管理を
容易にして無駄が無くなる。The purification-promoting component injected into the contaminated ground 12 is pulsed at a short interval at an ultra-high pressure by the high-pressure intermittent injection device 16 and supplied at a predetermined intermittent timing. Explosively blown into the contaminated ground 12 from 14a, it will reach farther and more widely. Further, since the explosive injection of the purification promoting component is intermittently repeated, the path of the purification promoting component tends to become random at every injection, which changes the accumulation state of the contaminated ground 12, and the entire contaminated ground 12 is almost completely removed. Purified uniformly. Further, the flow rate of the purification promoting component can be controlled by adjusting the opening degree of the flow control valve 26. However, by performing the injection of the purification promoting component suitable for the mixed pollutants by intermittent injection, the intermittent injection component can be controlled. The concentration can be easily managed and waste can be eliminated.
【0031】このように汚染地盤12に注入された浄化
促進成分はより広範囲に拡散されるため、1基当たりの
注入井14での浄化領域を拡大することができ、一定の
領域の汚染地盤の浄化を行うには浄化装置10全体の注
入井14の本数を減らすことができる。つまり、浄化促
進成分は、空気に含まれる酸素や栄養源により汚染地盤
12中に含まれる分解微生物Mを広範囲で活性化して、
汚染物質の分解を促進する。また、解微生物Mでは浄化
期間が長期化される油や溶剤や揮発性物質が汚染物質の
場合には、それぞれの浄化に適した浄化促進成分を選択
しておくことにより、これら汚染物質を短期間のうちに
適正に浄化できる。更に、土着の分解微生物Mが少ない
場合は、浄化促進成分として補充用の分解微生物Mを含
めることが望ましい。As described above, the purification-promoting component injected into the contaminated ground 12 is diffused over a wider area, so that the purification area per injection well 14 per unit can be expanded, and the contaminated ground in a certain area can be reduced. To perform purification, the number of injection wells 14 in the entire purification apparatus 10 can be reduced. In other words, the purification promoting component activates the decomposing microorganisms M contained in the contaminated ground 12 in a wide range by oxygen and nutrients contained in the air,
Promotes decomposition of pollutants. In addition, in the case of oil, solvent, and volatile substances, the purification period of which is prolonged in the decomposing microorganisms M, when pollutants are used, by selecting a purification promoting component suitable for each purification, these contaminants can be reduced in a short time. It can be properly purified in a while. Furthermore, when the amount of indigenous decomposed microorganisms M is small, it is desirable to include replenished decomposed microorganisms M as a purification promoting component.
【0032】因に、高圧間欠注入装置16を介して浄化
促進成分を汚染地盤12中に注入するにあたって、一定
期間毎に廃棄物埋立処分場の汚染地盤12から発生ガ
ス、埋立物、浸出水をサンプリングして分析し、その浄
化度合いをモニタリングし、その結果が安定化したと判
断された時点で浄化装置10の運転を停止して浄化処理
を完了させる。When the purification promoting component is injected into the contaminated ground 12 through the high-pressure intermittent injection device 16, generated gas, landfills and leachate are discharged from the contaminated ground 12 of the waste landfill site at regular intervals. Sampling and analysis are performed, the degree of purification is monitored, and when it is determined that the result is stabilized, the operation of the purification device 10 is stopped to complete the purification process.
【0033】ところで、本実施形態では汚染地盤12が
廃棄物埋立処分場である場合を開示したが、図2に示す
ように汚染物質が土壌中に拡散してしまっている自然地
盤12aにあっても、上記浄化装置10を用いて同様に
浄化することができる。勿論、この場合は注入井14の
噴出口14aを汚染物質の拡散層Sに位置させてある。
そして、この場合の汚染度合いのモニタリングは、地下
水、発生ガスおよび土壌をサンプリングして分析するこ
とになる。In the present embodiment, the case where the contaminated ground 12 is a waste landfill site is disclosed. However, as shown in FIG. 2, the contaminated ground is located on the natural ground 12a where the contaminants have diffused into the soil. Can be similarly purified using the purification device 10 described above. In this case, of course, the injection port 14a of the injection well 14 is located in the contaminant diffusion layer S.
In this case, monitoring of the degree of pollution involves sampling and analyzing groundwater, generated gas, and soil.
【0034】図3は本発明の第2実施形態を示し、上記
実施形態と同一構成部分に同一符号を付して重複する説
明を省略して述べる。同図は浄化装置の要部を概略的に
示す断面図である。FIG. 3 shows a second embodiment of the present invention, in which the same components as those in the above-described embodiment are denoted by the same reference numerals, and a duplicate description will be omitted. FIG. 3 is a cross-sectional view schematically showing a main part of the purification device.
【0035】この実施形態の汚染地盤の浄化方法では、
汚染地盤12に挿入した吸引井30からガス状物質を回
収し、この回収したガス状物質を浄化処理により無害化
して排出するものである。ガス状物質とは、汚染物質の
浄化により発生する分解ガスや注入井14から供給した
余剰ガス等が挙げられる。In the method of purifying contaminated ground according to this embodiment,
A gaseous substance is collected from the suction well 30 inserted into the contaminated ground 12, and the collected gaseous substance is rendered harmless by a purification treatment and discharged. Examples of the gaseous substance include a decomposition gas generated by purifying a pollutant and an excess gas supplied from the injection well 14.
【0036】即ち、この実施形態の浄化方法を達成する
ための浄化装置10aは、前記実施形態の浄化装置10
に地盤12中のガス状物質を吸引するための吸引井30
を設けて構成される。吸引井30は上記注入井14と同
様にパイプで形成され、1つの注入井14に対して、こ
の注入井14を囲むように所定距離を設けて複数本の吸
引井30が配置される。それぞれの吸引井30の下端部
は汚染地盤12中の汚染物質の拡散層Sに挿入されると
ともに、その下端部には適宜長さに亘ってガス状物質を
吸引するためのスリットや多孔の開口部が形成される。That is, the purifying apparatus 10a for achieving the purifying method of this embodiment is different from the purifying apparatus 10 of the above embodiment.
Suction well 30 for sucking gaseous substances in ground 12
Is provided. The suction well 30 is formed of a pipe in the same manner as the injection well 14, and a plurality of suction wells 30 are arranged at a predetermined distance from one injection well 14 so as to surround the injection well 14. The lower end of each suction well 30 is inserted into the contaminant diffusion layer S in the contaminated ground 12, and the lower end thereof has a slit or a porous opening for sucking gaseous substances over an appropriate length. A part is formed.
【0037】また、吸引井30の地上に突出された上端
部には、気液分離装置32を介してガス吸引用の吸引ポ
ンプ34が接続される。そして、該吸引ポンプ34を稼
働することにより、上記吸引井30の開口部から土壌の
浄化時に発生する分解ガスや、上記注入井14から浄化
促進成分をガス(霧)状にして注入した際の余剰ガス、
および土壌中の水分等が吸引される。このように吸引井
30で吸引された水分混じりのガス状物質は、気液分離
装置32で分離された後にガスのみが該吸引ポンプ34
に吸引される。そして、吸引ポンプ34で吸引されたガ
スは排出ガス浄化装置36に送り込まれ、ここでガスは
浄化処理されて無害化された後に、浄化ガス排気設備3
8から大気中に放出される。A suction pump 34 for gas suction is connected to the upper end of the suction well 30 protruding above the ground via a gas-liquid separator 32. By operating the suction pump 34, the decomposition gas generated at the time of soil purification from the opening of the suction well 30 and the purification promoting component from the injection well 14 in the form of gas (mist) are injected. Surplus gas,
In addition, moisture and the like in the soil are sucked. The gaseous substance mixed with water sucked in the suction well 30 is separated only by the gas-liquid separation device 32 and then only the gas is removed by the suction pump 34.
Is sucked. Then, the gas sucked by the suction pump 34 is sent to the exhaust gas purifying device 36, where the gas is purified and rendered harmless.
8 to the atmosphere.
【0038】従って、この実施形態では注入井14から
浄化促進成分を汚染地盤12中に注入する一方、吸収井
30から吸引するので、この吸引により注入井14から
供給される浄化促進成分がより拡散し易くなる。このた
め、上記注入井14から高圧間欠注入装置16を介して
浄化促進成分が爆発的に吹き込まれることと相俟って、
浄化可能領域を著しく拡大することができる。Accordingly, in this embodiment, while the purification promoting component is injected into the contaminated ground 12 from the injection well 14 and is sucked from the absorption well 30, the purification promoting component supplied from the injection well 14 is further diffused by this suction. Easier to do. For this reason, coupled with the fact that the purification promoting component is explosively blown from the injection well 14 through the high-pressure intermittent injection device 16,
The purifiable area can be significantly expanded.
【0039】また、汚染地盤12中の分解ガスや余剰ガ
スが自然に大気中に放出される前に上記吸引井30で捕
集することができるため、大気汚染を防止することがで
きる。従って、この実施形態では汚染地盤12の浄化・
安定化が短期間のうちに行われるため、特に早期の跡地
利用や環境保全に有益であるとともに、周辺環境に配慮
することができる。勿論、この実施形態にあっても廃棄
物埋立地盤および汚染物質が拡散された自然地盤のいず
れにあっても有効であることはいうまでもない。Further, since the decomposition gas and surplus gas in the contaminated ground 12 can be collected by the suction well 30 before being naturally released into the atmosphere, air pollution can be prevented. Therefore, in this embodiment, purification of the contaminated ground 12
Since the stabilization is performed within a short period of time, it is particularly useful for early use of the site and environmental conservation, and the surrounding environment can be considered. It goes without saying that this embodiment is also effective in any of the waste landfill and the natural ground where the pollutants are diffused.
【0040】図4は本発明の第3実施形態を示し、上記
実施形態と同一構成部分に同一符号を付して重複する説
明を省略して述べる。同図は浄化装置の要部を示す断面
図である。FIG. 4 shows a third embodiment of the present invention, in which the same components as those in the above embodiment are denoted by the same reference numerals, and a duplicate description will be omitted. FIG. 3 is a cross-sectional view showing a main part of the purification device.
【0041】即ち、この実施形態の浄化方法は、注入井
14の噴出口14aを汚染地盤12中で昇降自在とし、
浄化促進成分の注入位置を上下方向に調整するようにし
たもので、上記注入井14は、汚染地盤12中に配置さ
れる部分の外周を内外方向に連通するガイド管40で囲
繞するとともに、該ガイド管40内に上記注入井14の
噴出口14aを昇降可能に配置し、該噴出口14aの上
下位置を調整自在に構成してある。That is, according to the purification method of this embodiment, the injection port 14 a of the injection well 14 can be moved up and down in the contaminated ground 12.
The pouring position of the purification promoting component is adjusted in the vertical direction. The pouring well 14 surrounds the outer periphery of a portion arranged in the contaminated ground 12 with a guide tube 40 communicating inward and outward, The injection port 14a of the injection well 14 is arranged in the guide tube 40 so as to be able to move up and down, and the vertical position of the injection port 14a is adjustable.
【0042】上記ガイド管40の内外方向に連通する構
造としては、該ガイド管40の全長に亘って上下方向に
形成されるスリットを周方向に複数形成して構成され
る。この場合、スリットで分割された管体は適宜位置で
互いに連結される。また、多孔板でガイド管40を形成
することによっても達成される。The structure communicating with the inside and outside of the guide tube 40 is formed by forming a plurality of slits formed in the vertical direction over the entire length of the guide tube 40 in the circumferential direction. In this case, the pipes divided by the slits are connected to each other at appropriate positions. It is also achieved by forming the guide tube 40 with a perforated plate.
【0043】上記注入井14は上記ガイド管40より長
く形成され、噴出口14aがガイド管40の最深部に位
置した状態で、注入井30の上端部が地上に突出される
ようにし、この突出された上端部に高圧間欠注入装置1
6が取り付けられる。そして、注入井14の外周には噴
出口14aの上方に位置してパッカー42が取り付けら
れ、該パッカー42がガイド管40の内周に摺動自在に
密接されることにより、噴出口14aから注入される浄
化促進成分が上方に逃げるのを防止して、集中して汚染
地盤12中に吹き込まれるようになっている。更に望ま
しくは、図示省略したが噴出口14aの下側に注入井1
4と一体となって昇降し、ガイド管40内を摺動自在に
密閉するパッカーを設けることにより、注入される浄化
促進成分の集中度を更に向上することができる。The injection well 14 is formed to be longer than the guide tube 40, and the upper end of the injection well 30 is projected above the ground with the ejection port 14a positioned at the deepest portion of the guide tube 40. High-pressure intermittent injection device 1
6 is attached. A packer 42 is attached to the outer periphery of the injection well 14 above the jet port 14a, and the packer 42 is slidably tightly contacted with the inner circumference of the guide tube 40, so that the injection from the jet port 14a is performed. The purification promotion component is prevented from escaping upward, and is concentrated and blown into the contaminated ground 12. More preferably, although not shown, the injection well 1 is located below the jet port 14a.
By providing a packer that ascends and descends integrally with 4 and slidably seals the inside of the guide tube 40, the concentration of the injected purification promoting component can be further improved.
【0044】従って、この実施形態では注入井14を昇
降することにより噴出口14aを昇降できるため、1つ
の注入井14で浄化促進成分の注入位置を上下変化する
ことができる。このため、汚染地盤12の汚染領域の深
度が大きい場合にも浄化促進成分を上下方向に均等に吹
き込んで、地盤12の浄化を上下方向に均等化すること
ができる。従って、1基の注入井14での浄化領域が更
に拡大されるため、浄化装置10b全体で注入井14の
数を更に削減することができる。また、この実施形態で
は、吸引井30の位置を噴出口14aの位置によって変
化させることが望ましい。Therefore, in this embodiment, the injection port 14a can be moved up and down by moving up and down the injection well 14, so that the injection position of the purification promoting component can be changed up and down in one injection well 14. Therefore, even when the depth of the contaminated area of the contaminated ground 12 is large, the purification promoting component is blown evenly in the vertical direction, so that the purification of the ground 12 can be equalized in the vertical direction. Therefore, since the purification area in one injection well 14 is further expanded, the number of injection wells 14 in the entire purification apparatus 10b can be further reduced. Further, in this embodiment, it is desirable to change the position of the suction well 30 depending on the position of the jet port 14a.
【0045】図5は本発明の第4実施形態を示し、上記
実施形態と同一構成部分に同一符号を付して重複する説
明を省略して述べる。同図は浄化装置の要部を示す断面
図である。図示するように、この第4実施形態では、前
述の実施形態における吸入井30に代えて、汚染地盤1
2上方の地表部に吸引パイプ42を縦横に敷設するとと
もに、当該地表部をシート部材44で覆っており、上記
吸引パイプ42は地表部とシート部材44との間に介在
されている。また上記シート部材44の周縁部44aは
所定幅で地表面下に埋められている。FIG. 5 shows a fourth embodiment of the present invention, in which the same components as those in the above-described embodiment are denoted by the same reference numerals, and a description thereof will be omitted. FIG. 3 is a cross-sectional view showing a main part of the purification device. As shown, in the fourth embodiment, the contaminated ground 1 is replaced with the suction well 30 in the above-described embodiment.
The suction pipe 42 is laid vertically and horizontally on the ground surface portion 2 above, and the ground surface portion is covered with a sheet member 44. The suction pipe 42 is interposed between the ground surface portion and the sheet member 44. Further, the peripheral portion 44a of the sheet member 44 is buried under the ground surface with a predetermined width.
【0046】従って、このような構成でなる当該第4実
施形態の浄化装置では、汚染地盤12の上方の地表部を
覆ってシート部材44を設けることで、地盤12中から
地表部に噴出するガス状物質が大気中に拡散してしまう
ことを防止できるとともに、該シート部材44と地表部
との間に設けた吸引パイプ42で地表部に噴出したガス
状物質を吸引回収するので、前記同様に大気汚染を防止
しつつ地盤12の浄化が行え、しかも前述の実施形態の
ように吸引井を地盤中に挿入する場合に比して、施工が
容易でコストの大幅な低減が図れる。Therefore, in the purification apparatus of the fourth embodiment having the above-described configuration, the sheet member 44 is provided so as to cover the ground surface above the contaminated ground 12, so that the gas ejected from inside the ground 12 to the ground surface is provided. It is possible to prevent the gaseous substance from being diffused into the atmosphere and to collect the gaseous substance ejected to the ground surface by suction with the suction pipe 42 provided between the sheet member 44 and the ground surface. The ground 12 can be purified while preventing air pollution, and the construction is easier and the cost can be significantly reduced as compared with the case where the suction well is inserted into the ground as in the above-described embodiment.
【0047】なお、図5においては図示していないが、
この実施形態にあっても図4の場合と同様に、注入井1
4は汚染地盤12中に配置される部分の外周を内外方向
に連通するガイド管で囲繞するとともに、該ガイド管内
に上記注入井14の噴出口14aを昇降可能に配置し、
該噴出口14aの上下位置を調整自在に構成して、注入
井14の噴出口14aを汚染地盤12中で昇降自在と
し、浄化促進成分の注入位置を上下方向に調整可能に構
成しても良いことはもちろんである。Although not shown in FIG. 5,
In this embodiment, as in the case of FIG.
4 surrounds an outer periphery of a portion arranged in the contaminated ground 12 with a guide pipe communicating inward and outward, and arranges an ejection port 14a of the injection well 14 in the guide pipe so as to be able to move up and down.
The injection port 14a may be configured so that the vertical position of the injection port 14a is adjustable, the injection port 14a of the injection well 14 is vertically movable in the contaminated ground 12, and the injection position of the purification promoting component is adjustable in the vertical direction. Of course.
【0048】[0048]
【発明の効果】以上説明したように本発明の請求項1お
よび請求項5に示す汚染地盤や廃棄物埋立地盤の浄化方
法および浄化装置では、浄化促進成分が注入井の噴出口
から汚染地盤中に短時間の間隔でパルス状にされて所定
の間欠タイミングをもって超高圧で注入されて、爆発的
に吹き込まれるため、浄化促進成分をより遠くかつより
広い範囲に分散して到達させることができる。従って、
1基当たりの注入井の浄化領域を大幅に拡大できること
により、浄化装置全体の注入井の本数を削減して構成を
簡単にできる。また、浄化促進成分の爆発的注入が間欠
的に繰り返されることにより、注入の度に地盤の堆積状
況に変化を及ぼして地盤全体をほぼ均一に浄化すること
ができるとともに、混在する汚染物質等に適した浄化促
進成分の注入を間欠注入で実施することにより、注入成
分の濃度の管理を容易にして無駄が無くなる。As described above, in the method and apparatus for purifying a contaminated ground or a waste landfill according to the first and fifth aspects of the present invention, the purification-promoting component flows from the injection well outlet into the contaminated ground. Since it is pulsed at a short time interval and injected at an extremely high pressure at a predetermined intermittent timing and blown in explosively, the purification-promoting component can be dispersed farther and reach a wider range. Therefore,
Since the purification area of the injection well per unit can be greatly expanded, the number of injection wells in the entire purification apparatus can be reduced and the configuration can be simplified. In addition, the explosive injection of the purification-promoting component is intermittently repeated, which can change the state of soil accumulation every time the injection is performed, thereby making it possible to substantially uniformly clean the entire ground and reduce contaminants that are mixed in. By performing the injection of a suitable purification promoting component by intermittent injection, the concentration of the injected component can be easily controlled and waste can be eliminated.
【0049】また、本発明の請求項2および請求項6に
示す汚染地盤や廃棄物埋立地盤の浄化方法および浄化装
置では、注入井から浄化促進成分を汚染地盤や廃棄物埋
立地盤中に注入しつつ、吸収井から地盤中のガス状物質
を吸引するので、浄化促進成分をより拡散し易くできる
とともに、分解ガスや余剰ガスが地盤から自然に大気中
に放出される前にこれらを吸引井で捕集し、これを浄化
処理した後に放出できるため、大気汚染を防止すること
ができる。Further, in the method and apparatus for purifying a contaminated ground or a waste landfill site according to the second and sixth aspects of the present invention, a purification promoting component is injected from the injection well into the contaminated ground or the waste landfill site. In addition, since the gaseous substances in the ground are sucked from the absorption well, the purification-promoting components can be more easily diffused, and the decomposition gas and surplus gas can be naturally discharged from the ground to the atmosphere by the suction well. Since it can be collected and released after being purified, air pollution can be prevented.
【0050】更に、本発明の請求項3に示す汚染地盤や
廃棄物埋立地盤の浄化方法では、上記浄化促進成分が空
気や過酸化水素やオゾン等の酸素含有物質、分解微生
物、分解微生物を活性化する栄養源、などの汚染物質の
浄化を促進する成分であるため、広い範囲の汚染物質の
種類に対して有効となり、各種汚染物質に即した浄化を
適正に行うことができる。Further, in the method for purifying a contaminated ground or a waste landfill ground according to claim 3 of the present invention, the purification promoting component activates air, oxygen-containing substances such as hydrogen peroxide and ozone, decomposing microorganisms, and decomposing microorganisms. Since it is a component that promotes the purification of contaminants such as nutrient sources that are becoming toxic, it is effective for a wide range of types of contaminants, and it is possible to perform purification appropriately for various contaminants.
【0051】また、本発明の請求項7に示す浄化装置で
は、汚染地盤や廃棄物埋立地盤の地表部を覆ってシート
部材を設けることで、地盤中から地表部に噴出するガス
状物質が大気中に拡散してしまうことを防止するととも
に、該シート部材と地表部との間に設けた吸引パイプで
地表部に噴出したガス状物質を吸引回収するので、前記
同様に大気汚染を防止しつつ地盤の浄化が行え、しかも
吸引井を地盤中に挿入する場合に比して、施工が容易で
コストの低減が図れる。Further, in the purification apparatus according to claim 7 of the present invention, by providing a sheet member covering the surface of the contaminated ground or the landfill of the waste landfill, gaseous substances spouting from the ground to the surface can be reduced to the atmosphere. While preventing gaseous substances ejected to the ground surface by suction with a suction pipe provided between the sheet member and the ground surface while preventing it from diffusing into the inside, it is possible to prevent air pollution as described above. The ground can be purified, and the construction is easier and the cost can be reduced as compared with the case where the suction well is inserted into the ground.
【0052】更にまた、本発明の請求項4および請求項
8に示す汚染地盤や廃棄物埋立地盤の浄化方法および浄
化装置では、1つの注入井で浄化促進成分の注入位置を
上下変化することができるため、汚染地盤や廃棄物埋立
地盤の汚染領域の深度が大きい場合にも浄化促進成分を
上下方向に均等に吹き込んで、地盤の浄化をその深度方
向に均等化することができる。Furthermore, in the method and apparatus for purifying a contaminated ground or a waste landfill ground according to claims 4 and 8 of the present invention, the injection position of the purification promoting component can be changed up and down in one injection well. Therefore, even when the depth of the contaminated area or the contaminated area of the waste landfill is large, the purification promoting component can be evenly blown up and down, and the purification of the ground can be equalized in the depth direction.
【図1】本発明の第1実施形態の要部を概略的に示す断
面図である。FIG. 1 is a sectional view schematically showing a main part of a first embodiment of the present invention.
【図2】本発明の第1実施形態の他の実施形態の要部を
概略的に示す断面図である。FIG. 2 is a sectional view schematically showing a main part of another embodiment of the first embodiment of the present invention.
【図3】本発明の第2実施形態の要部を概略的に示す断
面図である。FIG. 3 is a sectional view schematically showing a main part of a second embodiment of the present invention.
【図4】本発明の第3実施形態の要部を概略的に示す断
面図である。FIG. 4 is a sectional view schematically showing a main part of a third embodiment of the present invention.
【図5】本発明の第4実施形態の要部を概略的に示す断
面図である。FIG. 5 is a sectional view schematically showing a main part of a fourth embodiment of the present invention.
10,10a,10b 浄化装置 12,12a 汚染地盤 14 注入井 14a 噴出口 16 高圧間欠注入装置 18 供給経路 20 浄化促進成分供給設備 30 吸引井 36 排出ガス浄化装置 40 ガイド管 42 吸引パイプ 44 シート部材 10, 10a, 10b Purification device 12, 12a Contaminated ground 14 Injection well 14a Spout port 16 High-pressure intermittent injection device 18 Supply path 20 Purification promoting component supply equipment 30 Suction well 36 Exhaust gas purification device 40 Guide pipe 42 Suction pipe 44 Sheet member
───────────────────────────────────────────────────── フロントページの続き (72)発明者 菊田 勝彦 東京都港区港南2丁目15番2号 株式会社 大林組東京本社内 (72)発明者 坂本 秀一 東京都港区港南2丁目15番2号 株式会社 大林組東京本社内 (72)発明者 石川 洋二 東京都清瀬市下清戸4丁目640番地 株式 会社大林組技術研究所内 (72)発明者 辻 博和 東京都清瀬市下清戸4丁目640番地 株式 会社大林組技術研究所内 (72)発明者 八木 正喜 埼玉県川越市南台1−10−4 株式会社大 林組東京機械工場内 (72)発明者 赤井 亮太 埼玉県川越市南台1−10−4 株式会社大 林組東京機械工場内 Fターム(参考) 4D004 AA41 AC07 CA18 CA34 CA36 CA50 CC02 CC11 CC20 ──────────────────────────────────────────────────続 き Continued on the front page (72) Katsuhiko Kikuta, Inventor 2- 15-2 Konan, Minato-ku, Tokyo Obayashi Gumi Tokyo Head Office (72) Inventor Shuichi Sakamoto 2- 15-2 Konan, Minato-ku, Tokyo Stock Obayashi Corporation Tokyo headquarters (72) Inventor Yoji Ishikawa 4-640 Shimoseito, Kiyose-shi, Tokyo Co., Ltd. Inside Obayashi Corporation Technical Research Institute (72) Inventor Hirokazu Tsuji 4-640 Shimoseito, Kiyose-shi, Tokyo Co., Ltd. (72) Inventor Masayoshi Yagi 1-10-4 Minamidai, Kawagoe-shi, Saitama Prefecture Inside Obayashigumi Tokyo Machinery Factory (72) Inventor Ryota Akai 1-10-4 Minamidai, Kawagoe-shi, Saitama Prefecture Tokyo Machinery Obayashi Corporation F-term in the factory (reference) 4D004 AA41 AC07 CA18 CA34 CA36 CA50 CC02 CC11 CC20
Claims (8)
入井に超高圧をもって浄化促進成分を短時間の間隔でパ
ルス状にして間欠的に供給し、この注入井の噴出口から
超高圧の浄化促進成分を該汚染地盤や廃棄物埋立地盤中
に吹き込むことを特徴とする汚染地盤の浄化方法。1. An ultrahigh-pressure pulse of a purification-promoting component is intermittently supplied at short intervals to an injection well inserted into a contaminated ground or a waste landfill. A method of purifying a contaminated ground, comprising blowing a purification promoting component into the contaminated ground or a waste landfill.
入井に超高圧をもって浄化促進成分を短時間の間隔でパ
ルス状にして間欠的に供給し、この注入井の噴出口から
超高圧の浄化促進成分を該汚染地盤中に吹き込むととも
に、汚染地盤や廃棄物埋立地盤に挿入した吸引井から地
盤中のガス状物質を回収し、この回収したガス状物質を
浄化処理により無害化して排出することを特徴とする汚
染地盤や廃棄物埋立地盤の浄化方法。2. An ultra-high pressure, intermittently supplying a purification-promoting component in a pulsed manner at short intervals to an injection well inserted into a contaminated ground or a landfill for waste disposal. The purification promoting component is blown into the contaminated ground, and gaseous substances in the ground are collected from a suction well inserted into the contaminated ground or the waste landfill, and the collected gaseous substances are rendered harmless by purification treatment and discharged. A method for purifying contaminated ground or waste landfill.
やオゾン等の酸素含有物質、分解微生物、分解微生物を
活性化する栄養源、などの汚染物質の浄化を促進する成
分であることを特徴とする請求項1または2に記載の汚
染地盤や廃棄物埋立地盤の浄化方法。3. The purification-promoting component is a component that promotes the purification of contaminants such as oxygen-containing substances such as air, hydrogen peroxide and ozone, decomposing microorganisms, and nutrient sources for activating decomposing microorganisms. 3. The method for purifying a contaminated ground or a waste landfill site according to claim 1 or 2.
埋立地盤中で昇降自在とし、上記浄化促進成分の注入位
置を上下方向に調整することを特徴とする請求項1また
は2に記載の汚染地や廃棄物埋立地盤盤の浄化方法。4. The injection port of the injection well is capable of moving up and down in a contaminated ground or a waste landfill, and an injection position of the purification promoting component is adjusted in a vertical direction. Of landfills and waste landfills.
注入井と、この注入井の上端部に取り付けられて超高圧
の圧搾空気を短時間の間隔でパルス状にして間欠的に該
注入井に供給する高圧間欠注入装置と、該圧搾空気の供
給経路に接続され浄化促進成分を圧搾空気に添加する浄
化促進成分供給設備とを備え、上記注入井の噴出口から
圧搾空気とともに浄化促進成分を汚染地盤や廃棄物埋立
地盤中に吹き込むことを特徴とする汚染地盤や廃棄物埋
立地盤の浄化装置。5. An injection well inserted into a contaminated ground or a waste landfill, and intermittently intermittently pulsed with ultrahigh-pressure compressed air attached to the upper end of the injection well at short intervals. A high-pressure intermittent injection device for supplying to the well, a purification-promoting component supply device connected to the compressed-air supply path for adding a purification-promoting component to the compressed air, and a purification-promoting component together with the compressed air from the injection port of the injection well. A cleaning device for polluting ground and waste landfill, characterized by injecting air into contaminated ground and waste landfill.
注入井と、この注入井の上端部に取り付けられて超高圧
の圧搾空気を短時間の間隔でパルス状にして間欠的に該
注入井に供給する高圧間欠注入装置と、該圧搾空気の供
給経路に接続され浄化促進成分を圧搾空気に添加する浄
化促進成分供給設備と、上記注入井に所定間隔をあけて
汚染地盤や廃棄物埋立地盤に挿入される吸引井と、該吸
引井で回収した地盤中のガス状物質を浄化処理して無害
化する排出ガス浄化設備と、を備えたことを特徴とする
汚染地盤や廃棄物埋立地盤の浄化装置。6. An injection well inserted into a contaminated ground or a waste landfill, and intermittently intermittently pulsed with ultrahigh-pressure compressed air attached to the upper end of the injection well at short intervals. A high-pressure intermittent injection device for supplying to the well, a purification-promoting-component supply device connected to the compressed-air supply path for adding the purification-promoting component to the compressed air, and a landfill for contaminated soil and waste at a predetermined interval from the injection well. A contaminated ground or waste landfill site, comprising: a suction well inserted into the ground; and an exhaust gas purification facility for purifying and detoxifying gaseous substances in the ground collected by the suction well. Purification equipment.
注入井と、この注入井の上端部に取り付けられて超高圧
の圧搾空気を短時間の間隔でパルス状にして間欠的に該
注入井に供給する高圧間欠注入装置と、該圧搾空気の供
給経路に接続され浄化促進成分を圧搾空気に添加する浄
化促進成分供給設備と、地表部に噴出した地盤中のガス
状物質が拡散するのを防止すべく該地表部を覆って設け
られたシート部材と、 該シート部材と地表部との間に設けられて噴出したガス
状物質を吸引回収する吸引パイプと、 該吸引パイプで回収したガス状物質を浄化処理して無害
化する排出ガス浄化設備と、を備えたことを特徴とする
汚染地盤や廃棄物埋立地盤の浄化装置。7. An injection well inserted into a contaminated ground or a waste landfill, and intermittently intermittently pulsed with ultra-high pressure compressed air attached to the upper end of the injection well at short intervals. A high-pressure intermittent injection device for supplying to the well, a purification-promoting component supply device connected to the compressed-air supply path for adding the purification-promoting component to the compressed air, A sheet member provided so as to cover the ground surface portion in order to prevent the occurrence of a gaseous substance; a suction pipe provided between the sheet member and the ground surface portion for sucking and collecting gaseous substances ejected; and a gas collected by the suction pipe. A purification device for contaminated ground and waste landfill, comprising: an exhaust gas purification facility for purifying and detoxifying particulate matter.
盤中に配置される部分の外周を内外方向に連通するガイ
ド管で囲繞するとともに、該ガイド管内に上記注入井の
噴出口を昇降可能に配置し、該噴出口の上下位置を調整
自在としたことを特徴とする請求項5〜7のいずれかに
記載の汚染地盤や廃棄物埋立地盤の浄化装置。8. The injection well surrounds a periphery of a portion disposed in a contaminated ground or a waste landfill with a guide pipe communicating inward and outward, and moves up and down an ejection port of the injection well in the guide pipe. The apparatus for purifying a contaminated soil or a waste landfill according to any one of claims 5 to 7, wherein the apparatus is arranged so as to be capable of adjusting the vertical position of the spout.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP33191299A JP3711819B2 (en) | 1999-11-22 | 1999-11-22 | Method and device for purifying contaminated ground and waste landfill |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP33191299A JP3711819B2 (en) | 1999-11-22 | 1999-11-22 | Method and device for purifying contaminated ground and waste landfill |
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JP2001145872A true JP2001145872A (en) | 2001-05-29 |
JP3711819B2 JP3711819B2 (en) | 2005-11-02 |
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JP33191299A Expired - Fee Related JP3711819B2 (en) | 1999-11-22 | 1999-11-22 | Method and device for purifying contaminated ground and waste landfill |
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JP2002254062A (en) * | 2001-02-28 | 2002-09-10 | Shimizu Corp | In situ restoration method and restoration equipment for organic contaminated soil |
WO2003031087A3 (en) * | 2001-10-08 | 2003-09-25 | Bay Zoltan Foundation For Appl | Method for land improvement and microorganisms therefor |
JP2006061793A (en) * | 2004-08-25 | 2006-03-09 | Taisei Corp | Waste final disposal site |
JP2006198566A (en) * | 2005-01-24 | 2006-08-03 | Shimane Pref Gov | High pressure air supply device for promoting aerobic fermentation and fermentation method |
JP2010115604A (en) * | 2008-11-13 | 2010-05-27 | Ohbayashi Corp | Cleaning method of contaminated ground, and cleaning apparatus of contaminated ground |
JP2019103987A (en) * | 2017-12-14 | 2019-06-27 | 日鉄エンジニアリング株式会社 | Soil cleaning method |
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KR101018082B1 (en) | 2008-03-31 | 2011-03-02 | 디. 플레바니 코넬 | Method and device for improving the efficiency of underground contaminated soil and groundwater pollution using compression crushing and multi-component liquid or solid media |
KR101065269B1 (en) | 2010-11-01 | 2011-09-19 | 디. 플레바니 코넬 | Method and apparatus using pneumatic fracturing and multicomponent injection of a liquid or dry media for the treatment non-naturally occurring subsurface soil and groundwater contamination |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002254062A (en) * | 2001-02-28 | 2002-09-10 | Shimizu Corp | In situ restoration method and restoration equipment for organic contaminated soil |
WO2003031087A3 (en) * | 2001-10-08 | 2003-09-25 | Bay Zoltan Foundation For Appl | Method for land improvement and microorganisms therefor |
JP2006061793A (en) * | 2004-08-25 | 2006-03-09 | Taisei Corp | Waste final disposal site |
JP2006198566A (en) * | 2005-01-24 | 2006-08-03 | Shimane Pref Gov | High pressure air supply device for promoting aerobic fermentation and fermentation method |
JP2010115604A (en) * | 2008-11-13 | 2010-05-27 | Ohbayashi Corp | Cleaning method of contaminated ground, and cleaning apparatus of contaminated ground |
JP2019103987A (en) * | 2017-12-14 | 2019-06-27 | 日鉄エンジニアリング株式会社 | Soil cleaning method |
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