JP2001139991A - Washing soap - Google Patents
Washing soapInfo
- Publication number
- JP2001139991A JP2001139991A JP32869499A JP32869499A JP2001139991A JP 2001139991 A JP2001139991 A JP 2001139991A JP 32869499 A JP32869499 A JP 32869499A JP 32869499 A JP32869499 A JP 32869499A JP 2001139991 A JP2001139991 A JP 2001139991A
- Authority
- JP
- Japan
- Prior art keywords
- calcium carbonate
- shell
- powder
- shells
- calcite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Detergent Compositions (AREA)
Abstract
(57)【要約】
【課題】食品素材の表面などに付着した化学物質を取り
除く用途や殺菌を行なう用途に使用できる洗浄剤をホタ
テの貝殻から得るようにし、健康障害や病気を生じさせ
ないとともに、不用物の有効利用を図る。
【解決手段】洗浄剤を、炭酸カルシウムの方解石型構造
による結晶構造体を備えた貝殻を粉砕した粉末からなる
炭酸カルシウム粉末と該炭酸カルシウム粉末を焼成して
なる酸化カルシウム粉末とを混合して得る。(57) [Abstract] [Problem] To obtain a cleaning agent from a scallop shell that can be used for removing chemical substances attached to the surface of a food material or for sterilizing, so as not to cause health disorders and diseases, Effective use of waste. A detergent is obtained by mixing a calcium carbonate powder made of a powder obtained by pulverizing a shell having a crystal structure with a calcite-type structure of calcium carbonate and a calcium oxide powder obtained by firing the calcium carbonate powder. .
Description
【0001】[0001]
【発明の属する技術分野】本発明は洗浄剤に関するもの
である。TECHNICAL FIELD The present invention relates to a cleaning agent.
【0002】[0002]
【発明が解決しようとする課題】現在、小中学校の給食
における食品素材は卸売市場などから未加工の状態で一
括的に納入する形態を採ることが多い。そして、納入さ
れた野菜などの農産物では農薬が表面に付着して残って
いるため、また、各種の細菌を殺菌するために次亜鉛酸
ナトリウムが食品素材の洗浄に用いられている。一方、
一般家庭においては合成洗剤が食品素材や食器などの洗
浄に用いられている。このように農産物などの食品素材
の表面に残る農薬や細菌を取り除くために次亜鉛酸ナト
リウムを使用したり、一般家庭で合成洗剤を使用してい
るが、これらは化学製品であって人体内への取り込みが
懸念されるため、使用後には食品素材を十分に水洗いす
る必要がある。よって、先の次亜鉛酸ナトリウムや合成
洗剤に代えて人体に対して有害とはならないものにより
農薬の取り除きや殺菌が行なえるようにしたいとの要望
もなされている。また、上記食品素材以外においても一
般家庭では手洗いや掃除に際して合成洗剤が多く利用さ
れているが、この合成洗剤は石油を原料とする化学物質
から形成されているものが多くあり、石油資源の枯渇を
早める点が問題視されるようになってきた。At present, in many cases, food materials used for lunch at elementary and junior high schools are collectively delivered unprocessed from wholesale markets and the like. In agricultural products such as delivered vegetables, pesticides are adhered and remain on the surface, and sodium hypochlorite is used for cleaning food materials in order to sterilize various bacteria. on the other hand,
In general households, synthetic detergents are used for cleaning food materials and tableware. In this way, sodium hypochlorite is used to remove pesticides and bacteria remaining on the surface of food materials such as agricultural products, and synthetic detergents are used in ordinary households. It is necessary to thoroughly wash the food material after use since there is a concern that the food may be taken up. Therefore, there has been a demand for removing pesticides and disinfecting with pesticides that are not harmful to the human body in place of sodium hypochlorite and synthetic detergents. In addition to the above-mentioned food materials, general households often use synthetic detergents for hand washing and cleaning, but many of these synthetic detergents are formed from petroleum-based chemical substances, which deplete petroleum resources. Hastened to be a problem.
【0003】上述した問題に対して本発明者は、不用物
として処分されてきたホタテの貝殻を粉砕し、その粉体
が、他の貝の貝殻よりなる粉体に比べて、化学物質を吸
着する効果と細菌に対してその繁殖を抑える効果が極め
て高いことに着目したものである。そこで、本発明は上
記事情に鑑みて、農薬などの化学物質を取り除き殺菌を
行なう洗浄剤をホタテの貝殻から得るようにすることを
課題とし、不用物の有効利用を図ることを目的とする。[0003] In response to the above-mentioned problems, the present inventors crushed scallop shells that have been disposed of as waste, and the powder adsorbs chemical substances as compared with powder made of shells of other shells. And the effect of inhibiting the growth of bacteria is extremely high. In view of the above circumstances, an object of the present invention is to obtain a cleaning agent for removing and sterilizing chemical substances such as pesticides from scallop shells, and an object of the present invention is to effectively use waste materials.
【0004】[0004]
【課題を解決するための手段】本発明は上記課題を考慮
してなされたもので、炭酸カルシウムの方解石型構造に
よる結晶構造体を備えた貝殻を粉砕した粉末からなる炭
酸カルシウム粉末と、該炭酸カルシウム粉末を焼成して
なる酸化カルシウム粉末とが混合されていることを特徴
とする洗浄剤を提供して、上記課題を解消するものであ
る。SUMMARY OF THE INVENTION The present invention has been made in view of the above problems, and has a calcium carbonate powder comprising a powder obtained by pulverizing a shell having a crystal structure having a calcite-type structure of calcium carbonate; An object of the present invention is to provide a detergent characterized by being mixed with a calcium oxide powder obtained by calcining a calcium powder, and to solve the above problem.
【0005】[0005]
【発明の実施の形態】つぎに本発明を発明の実施の形態
に基づいて詳細に説明する。洗浄剤を得るに当たって
は、まず、少なくとも貝殻主要部分が炭酸カルシウムの
方解石型構造による結晶構造体としている貝殻を用いる
もので、この貝殻はホタテの貝殻であり、貝殻の大部分
をこの結晶構造体としている点でホタテの貝殻は他の貝
殻と異なる。即ち、ホタテはその生態において、貝殻を
開閉して海水を勢いよく外部に放出することで「海中を
泳ぐ」と表現されるように機敏に移動を行い、捕捉者
(ヒトデなど)から逃げる動作が特長的であり、この動
作が行なえるように大きな貝柱を有するとともに、貝殻
自体が、比較的薄く軽量で、かつ、強度を有するという
条件を兼ね備えており、その貝殻では、炭酸カルシウム
の方解石型構造の結晶構造体が葉状構造を呈して貝内面
側が形成され、貝内層(貝殻厚さ方向での芯となる層)
では、炭酸カルシウムの方解石型構造の結晶構造体が板
状構造を呈していて、この貝内面側と貝内層との構造が
貝殻の主要部(表層部や蝶番部を除いた部分)を形作っ
ているため、薄く軽量でありながら強度のあるものとな
っている。Next, the present invention will be described in detail based on embodiments of the present invention. In order to obtain the cleaning agent, first, at least the main part of the shell is a shell made of a crystal structure of a calcite-type structure of calcium carbonate, this shell is a scallop shell, and most of the shell is made of this crystal structure Scallop shells differ from other shells in that In other words, in its ecology, scallops open and close their shells and release seawater vigorously to the outside, so they move quickly as described as "swimming in the sea" and escape from trappers (starfish etc.). In addition to having a large scallop so that this operation can be performed, the shell itself has conditions that it is relatively thin and lightweight and has strength, and the shell has a calcite-type structure of calcium carbonate. The inner shell side of the shell is formed by the foliate structure of the crystal structure of the shell, and the inner layer of the shell (the core layer in the shell thickness direction)
In the above, the calcite-type crystal structure of calcium carbonate has a plate-like structure, and the structure between the inner surface of the shell and the inner layer of the shell forms the main part of the shell (excluding the surface layer and hinges). Therefore, it is thin and lightweight, yet strong.
【0006】そして、前述したようホタテの貝殻の主要
部において、内面側は、炭酸カルシウムの方解石型構造
の結晶構造体が葉状構造となる(針状結晶が剣山状に密
に詰まって敷き並べられている状態)とともに、貝内層
は、炭酸カルシウムの方解石型構造の結晶構造体が板状
構造としている(ベニヤ板のように、針状結晶が同一方
向に並んだ層が幾重にも重なり、針状結晶の向きが層ご
とに異なっている状態)としているため、後述するよう
にこのホタテの貝殻から得られた粒体は方解石型構造が
残って多孔質性を備えたものとなる。これに比べて他の
貝殻では、炭酸カルシウムの結晶が面状に広がって重な
った構造となっており、これによりパール状光沢を呈す
るものとなっているが、粒体とした場合にはほとんど多
孔質性を呈しないものとなっている。As described above, in the main part of the shell of the scallop, the calcite-type crystal structure of calcium carbonate has a leaf-like structure on the inner surface side (needle-shaped crystals are densely packed in a sword-like shape and laid. In addition, the shell inner layer has a plate-like structure of a calcite-type crystal structure of calcium carbonate (layers of needle-like crystals arranged in the same direction, such as plywood, overlap each other to form a needle-like structure). (The direction of the crystal is different for each layer.) As described later, the particles obtained from the shell of the scallop have a calcite-type structure and are porous. In contrast, other shells have a structure in which calcium carbonate crystals are spread in a plane and overlapped, giving a pearly luster. It does not exhibit quality.
【0007】上述したように洗浄剤を得るに当たってホ
タテの貝殻を原材料としているが、ホタテの貝柱を取り
除いた後において不用物として処理されてきたものを利
用でき、廃棄物の有用な利用が行なえる。まず、集めら
れた貝殻を天日乾燥を行なって乾かし硬化させる。つぎ
に天日乾燥によって硬化した貝殻を粒径約200μmと
なるまでに粉砕する。粉砕方法自体は特に限定するもの
ではなく、既存の粉砕装置を用いればよい。このように
して炭酸カルシウム粉末が得られるものものであり、粒
体は多孔性粒体となっている。つぎに上述の多孔質性粒
体からなる炭酸カルシウム粉末の一部分を用いてこれを
セラミックの壺に入れて約1000℃の温度で数十分か
ら数時間程度の時間で加熱して酸化カルシウム粉末を得
るようにする。そして、このようにして得られた酸化カ
ルシウム粉末と上記炭酸カルシウム粉末とを混合するこ
とで洗浄剤が得られる。As described above, scallop shells are used as a raw material for obtaining a detergent, but those that have been treated as waste after removing the scallop can be used, and useful waste can be used. . First, the collected shells are dried in the sun and dried and hardened. Next, the shells hardened by sun drying are crushed to a particle size of about 200 μm. The crushing method itself is not particularly limited, and an existing crushing device may be used. Thus, calcium carbonate powder is obtained, and the granules are porous granules. Next, a part of the calcium carbonate powder composed of the above-mentioned porous granules is used, put into a ceramic jar, and heated at a temperature of about 1000 ° C. for several tens minutes to several hours to obtain a calcium oxide powder. To get. Then, a detergent is obtained by mixing the calcium oxide powder thus obtained and the calcium carbonate powder.
【0008】上記洗浄剤中、炭酸カルシウム粉末分は上
述したようにホタテの貝殻粉末の独特な多孔質粒体から
なるもので、吸着効果が大である。また、酸化カルシウ
ム粉末分はアルカリ性であり、殺菌性を示すものであ
る。よって、この洗浄剤は、農薬などの化学物質を吸着
する効果があり、この洗浄剤と水とを混合してなる洗浄
液に食品素材を浸したり、その洗浄液を流水状態にして
その流水を食品素材に当てて洗うようにすることで、付
着している農薬などの化学物質を取り去ることができ、
アルカリ性の作用により細菌やカビなどを死滅させるよ
うになる。食品素材の洗浄ばかりでなく、手洗いや汚れ
た物品の洗浄においても手や前記物品の表面に付いてい
た化学物質や微細な汚染物質を多孔質粒体が吸着し、ア
ルカリ性の作用にて細菌などを死滅させる。なお、前記
洗浄液による洗浄を終えた後には水洗いすればよく、仮
に、酸化カルシウム粉末分が残留したとしても炭酸カル
シウムに変化し人体に無毒であり、カルシウムイオンの
人体への取り込みにも寄与できる。なお、洗浄剤におい
て上記炭酸カルシウム粉末分と上記酸化カルシウム粉末
分との割合は適宜に変更できるものであり、割合を変え
ることで脱臭吸着の効能の方を高くしたり殺菌性の効能
の方を高くすることでき、用途に応じてその割合を変え
ることが可能である。[0008] In the above-mentioned detergent, the calcium carbonate powder is composed of unique porous particles of scallop shell powder as described above, and has a large adsorption effect. The calcium oxide powder is alkaline and shows bactericidal properties. Therefore, this cleaning agent has the effect of adsorbing chemicals such as pesticides, soaking the food material in a cleaning solution that is a mixture of this cleaning agent and water, or making the cleaning solution in a running water state and using the running water as a food material. By washing it against, it is possible to remove attached chemicals such as pesticides,
Alkaline action kills bacteria and mold. In addition to cleaning food materials, porous particles adsorb chemicals and fine contaminants attached to hands and the surface of the articles in hand washing and cleaning of dirty articles, and bacteria and the like are removed by alkaline action. To kill. After the washing with the washing liquid, washing with water is sufficient, and even if calcium oxide powder remains, it changes into calcium carbonate and is nontoxic to the human body, and can also contribute to the incorporation of calcium ions into the human body. The ratio of the calcium carbonate powder component and the calcium oxide powder component in the detergent can be appropriately changed, and by changing the ratio, the effect of deodorizing adsorption is improved or the effect of sterilization is improved. It can be higher and its proportion can be changed depending on the application.
【0009】[0009]
【発明の効果】以上説明した本発明により、この洗浄剤
を、野菜などの食品素材の洗浄や一般の汚れた物品の洗
浄に用いれば、表面に付着していた化学物質や微細な汚
染物質を取り除くようになるとともに、殺菌が行なえる
ようになる。そして、洗浄後に残留したとしても人体に
無害なものに変化するという利点がある。さらに、貝殻
を原材料としているため、今迄多く不用物として処分さ
れてきた貝殻を有効に利用でき、ゴミの削減化に大きく
寄与できる。そして、製造方法は煩雑な工程を経るもの
ではなく、上述した有用な洗浄剤を低コストにて提供で
きるなど、実用性に優れた効果を奏するものである。According to the present invention described above, if this detergent is used for cleaning food materials such as vegetables and for cleaning general soiled articles, chemical substances and fine contaminants adhering to the surface can be eliminated. It can be removed and sterilized. And, even if it remains after washing, there is an advantage that it changes to something harmless to the human body. In addition, since shells are used as a raw material, shells that have been disposed of as waste can be effectively used, which can greatly contribute to reduction of garbage. And the manufacturing method does not go through complicated steps, and has an effect excellent in practicality, such as providing the above-mentioned useful cleaning agent at low cost.
Claims (1)
構造体を備えた貝殻を粉砕した粉末からなる炭酸カルシ
ウム粉末と該炭酸カルシウム粉末を焼成してなる酸化カ
ルシウム粉末とが混合されていることを特徴とする洗浄
剤。The present invention is characterized in that a calcium carbonate powder obtained by crushing a shell having a crystal structure having a calcite-type structure of calcium carbonate and a calcium oxide powder obtained by firing the calcium carbonate powder are mixed. And cleaning agent.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP32869499A JP4366672B2 (en) | 1999-11-18 | 1999-11-18 | Washing soap |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP32869499A JP4366672B2 (en) | 1999-11-18 | 1999-11-18 | Washing soap |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2001139991A true JP2001139991A (en) | 2001-05-22 |
JP4366672B2 JP4366672B2 (en) | 2009-11-18 |
Family
ID=18213136
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP32869499A Expired - Fee Related JP4366672B2 (en) | 1999-11-18 | 1999-11-18 | Washing soap |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP4366672B2 (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004180991A (en) * | 2002-12-04 | 2004-07-02 | Takenet:Kk | Washing tank cleaner |
JP2007302840A (en) * | 2006-05-15 | 2007-11-22 | Takenet:Kk | Detergent composition for laundry |
CN104073377A (en) * | 2014-06-12 | 2014-10-01 | 浙江海洋学院 | Method for preparing pure natural fruit and vegetable cleaning agent |
CN105419985A (en) * | 2015-12-30 | 2016-03-23 | 上海力来生物科技有限公司 | Cleaning agent and preparing method thereof |
CN107012032A (en) * | 2017-05-28 | 2017-08-04 | 重庆晋豪美耐皿制品有限公司 | A kind of gourd, fruit and vegetable efficient cleaner and preparation method thereof |
JP2018070673A (en) * | 2016-10-25 | 2018-05-10 | フィーネ株式会社 | Powdery detergent and liquid detergent |
JP2020055719A (en) * | 2018-10-03 | 2020-04-09 | 株式会社プラスラボ | Calcined product containing calcium oxide |
KR102583387B1 (en) * | 2023-05-18 | 2023-09-26 | 김진호 | Method for the Cleaning of the Wet Scrubber Filling Using Eco-Friendly Material |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102025114B1 (en) * | 2017-11-07 | 2019-09-25 | (주)에스케이생활건강 | Manufacuring method of detergent with ionized calcium and detergent with ionized calcium using the same |
-
1999
- 1999-11-18 JP JP32869499A patent/JP4366672B2/en not_active Expired - Fee Related
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004180991A (en) * | 2002-12-04 | 2004-07-02 | Takenet:Kk | Washing tank cleaner |
JP2007302840A (en) * | 2006-05-15 | 2007-11-22 | Takenet:Kk | Detergent composition for laundry |
CN104073377A (en) * | 2014-06-12 | 2014-10-01 | 浙江海洋学院 | Method for preparing pure natural fruit and vegetable cleaning agent |
CN105419985A (en) * | 2015-12-30 | 2016-03-23 | 上海力来生物科技有限公司 | Cleaning agent and preparing method thereof |
JP2018070673A (en) * | 2016-10-25 | 2018-05-10 | フィーネ株式会社 | Powdery detergent and liquid detergent |
CN107012032A (en) * | 2017-05-28 | 2017-08-04 | 重庆晋豪美耐皿制品有限公司 | A kind of gourd, fruit and vegetable efficient cleaner and preparation method thereof |
JP2020055719A (en) * | 2018-10-03 | 2020-04-09 | 株式会社プラスラボ | Calcined product containing calcium oxide |
JP7215670B2 (en) | 2018-10-03 | 2023-01-31 | 株式会社プラスラボ | Firing products containing calcium oxide |
KR102583387B1 (en) * | 2023-05-18 | 2023-09-26 | 김진호 | Method for the Cleaning of the Wet Scrubber Filling Using Eco-Friendly Material |
Also Published As
Publication number | Publication date |
---|---|
JP4366672B2 (en) | 2009-11-18 |
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