JP2001078738A - Antioxidant for food and oil-in-water type emulsion food having excellent oxidation stability - Google Patents
Antioxidant for food and oil-in-water type emulsion food having excellent oxidation stabilityInfo
- Publication number
- JP2001078738A JP2001078738A JP26151299A JP26151299A JP2001078738A JP 2001078738 A JP2001078738 A JP 2001078738A JP 26151299 A JP26151299 A JP 26151299A JP 26151299 A JP26151299 A JP 26151299A JP 2001078738 A JP2001078738 A JP 2001078738A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- food
- water
- leaves
- antioxidant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 235000013305 food Nutrition 0.000 title claims abstract description 70
- 230000003078 antioxidant effect Effects 0.000 title claims abstract description 21
- 239000003963 antioxidant agent Substances 0.000 title claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract description 47
- 230000003647 oxidation Effects 0.000 title abstract description 15
- 238000007254 oxidation reaction Methods 0.000 title abstract description 15
- 239000000839 emulsion Substances 0.000 title abstract description 7
- 239000007764 o/w emulsion Substances 0.000 claims description 39
- 239000006286 aqueous extract Substances 0.000 claims description 17
- 241000196324 Embryophyta Species 0.000 abstract description 31
- 239000000284 extract Substances 0.000 abstract description 31
- 239000000126 substance Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 3
- 230000002411 adverse Effects 0.000 abstract description 2
- 241000219193 Brassicaceae Species 0.000 abstract 2
- 208000019901 Anxiety disease Diseases 0.000 abstract 1
- 230000036506 anxiety Effects 0.000 abstract 1
- 239000002075 main ingredient Substances 0.000 abstract 1
- 239000008346 aqueous phase Substances 0.000 description 15
- 239000003921 oil Substances 0.000 description 15
- 235000019198 oils Nutrition 0.000 description 15
- 230000001590 oxidative effect Effects 0.000 description 14
- 239000012071 phase Substances 0.000 description 14
- 239000002994 raw material Substances 0.000 description 14
- 241000220259 Raphanus Species 0.000 description 12
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 description 12
- 240000007124 Brassica oleracea Species 0.000 description 10
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 10
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 10
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 235000019261 food antioxidant Nutrition 0.000 description 8
- 102000002322 Egg Proteins Human genes 0.000 description 6
- 108010000912 Egg Proteins Proteins 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 235000013345 egg yolk Nutrition 0.000 description 5
- 210000002969 egg yolk Anatomy 0.000 description 5
- 238000004945 emulsification Methods 0.000 description 5
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 4
- 241000256844 Apis mellifera Species 0.000 description 4
- 235000019484 Rapeseed oil Nutrition 0.000 description 4
- 235000010746 mayonnaise Nutrition 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 230000008827 biological function Effects 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 239000008268 mayonnaise Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 235000002639 sodium chloride Nutrition 0.000 description 3
- 239000002344 surface layer Substances 0.000 description 3
- 235000021419 vinegar Nutrition 0.000 description 3
- 239000000052 vinegar Substances 0.000 description 3
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 2
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 2
- 239000008157 edible vegetable oil Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229930014626 natural product Natural products 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- 235000019871 vegetable fat Nutrition 0.000 description 2
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 1
- 241000256837 Apidae Species 0.000 description 1
- AANLCWYVVNBGEE-IDIVVRGQSA-L Disodium inosinate Chemical compound [Na+].[Na+].O[C@@H]1[C@H](O)[C@@H](COP([O-])([O-])=O)O[C@H]1N1C(NC=NC2=O)=C2N=C1 AANLCWYVVNBGEE-IDIVVRGQSA-L 0.000 description 1
- 239000004278 EU approved seasoning Substances 0.000 description 1
- 102000014171 Milk Proteins Human genes 0.000 description 1
- 108010011756 Milk Proteins Proteins 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- 235000019463 artificial additive Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 1
- 235000013890 disodium inosinate Nutrition 0.000 description 1
- 235000014103 egg white Nutrition 0.000 description 1
- 210000000969 egg white Anatomy 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000021239 milk protein Nutrition 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 235000008935 nutritious Nutrition 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000021067 refined food Nutrition 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 229920006298 saran Polymers 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
Landscapes
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Seasonings (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、水中油型エマルジ
ョン食品用などとして好適な食品用抗酸化剤と酸化安定
性に優れた水中油型エマルジョン食品とに関する。The present invention relates to a food antioxidant suitable for use in oil-in-water emulsion foods and the like and an oil-in-water emulsion food having excellent oxidation stability.
【0002】[0002]
【従来の技術】食品中に含まれる油脂は、その期間内に
徐々に酸素を吸収し、それがある段階に達すると急激に
酸化が進む結果、食品の変質をもたらす。2. Description of the Related Art Fats and oils contained in foodstuffs gradually absorb oxygen during the period, and when they reach a certain stage, they rapidly oxidize, resulting in deterioration of the foodstuffs.
【0003】ところで、水相と油相とが水中油型に乳化
されエマルジョン状とされた水中油型エマルジョン食品
の代表的なものとして、マヨネーズやドレッシング類等
がよく知られている。これらは卵黄を用いて乳化され、
美味しく、且つ栄養価の高い食品となっている。油相に
は、大豆油や菜種油等を主体に使用されることが一般的
になっている。[0003] By the way, mayonnaise and dressings are well known as typical examples of oil-in-water emulsion foods in which an aqueous phase and an oil phase are emulsified into an oil-in-water type to form an emulsion. These are emulsified using egg yolk,
It is a delicious and nutritious food. The oil phase generally uses soybean oil, rapeseed oil and the like as a main component.
【0004】ところが卵黄を用いて乳化したこれらマヨ
ネーズやドレッシング類等は、酸化に弱く、長期間酸化
されると変色を生じたり、さらには乳化が破壊され、油
相が分離するなどの欠点があった。However, these mayonnaises and dressings emulsified using egg yolk are susceptible to oxidation, and may suffer from discoloration when oxidized for a long period of time, and furthermore, the emulsification is destroyed and the oil phase is separated. Was.
【0005】酸化を防止するためには、抗酸化作用を有
する化学物質からなる抗酸化剤を添加すればよいが、近
年化学物質の生体機能への悪影響が問題となっており、
消費者は一般的にこのような人工添加物を避ける傾向に
ある。In order to prevent oxidation, an antioxidant consisting of a chemical substance having an antioxidant effect may be added. However, in recent years, the adverse effect of the chemical substance on biological functions has become a problem.
Consumers generally tend to avoid such artificial additives.
【0006】[0006]
【発明が解決しようとする課題】本発明は、上記従来の
問題を解消し、生体への影響が懸念される化学物質を主
成分とせずに食品に優れた酸化安定性を付与することの
できる食品用抗酸化剤を提供することを目的とすると共
に、消費者が敬遠することなく安心して食することがで
き、且つ長期間優れた酸化安定性を持続させることので
きる水中油型エマルジョン食品を提供することを目的と
する。DISCLOSURE OF THE INVENTION The present invention solves the above-mentioned conventional problems and can impart excellent oxidative stability to food without using a chemical substance which is likely to affect the living body as a main component. An oil-in-water emulsion food which is intended to provide an antioxidant for food, and which can be eaten with peace of mind without being shunned by consumers, and which can maintain excellent oxidative stability for a long time. The purpose is to provide.
【0007】[0007]
【課題を解決するための手段】本発明者らは、上記課題
を解決すべく鋭意検討を重ねた結果、驚くべきことに食
用されている十字花科植物の葉の水抽出物が食品用の抗
酸化剤としての作用を有すること、及び、この十字花科
植物の葉の水抽出物を添加して得られる水中油型エマル
ジョン食品が優れた酸化安定性を有することを見出し、
この知見に基いて本発明を完成するに至った。十字花科
植物自体は食用されているが、十字花科植物の葉の水抽
出物が乳化食品用の抗酸化剤としての作用を有すること
は、これまで全く知られていない。Means for Solving the Problems The present inventors have made intensive studies to solve the above-mentioned problems, and as a result, surprisingly, the water extract of leaves of edible cruciferous plants is used for food. Having an action as an antioxidant, and found that the oil-in-water emulsion food obtained by adding the water extract of the leaves of this cruciferous plant has excellent oxidation stability,
The present invention has been completed based on this finding. Although cruciferous plants themselves are edible, it has never been known that an aqueous extract of leaves of cruciferous plants has an action as an antioxidant for emulsified foods.
【0008】すなわち、請求項1に係る本発明は、十字
花科植物の葉の水抽出物からなる食品用抗酸化剤を提供
するものである。請求項2に係る本発明は、十字花科植
物の葉の水抽出物が添加されていることを特徴とする水
中油型エマルジョン食品を提供するものである。[0008] That is, the present invention according to claim 1 provides an antioxidant for food comprising an aqueous extract of leaves of a cruciferous plant. The present invention according to claim 2 provides an oil-in-water emulsion food to which an aqueous extract of leaves of a cruciferous plant is added.
【0009】[0009]
【発明の実施の形態】以下、本発明について、詳細に説
明する。まず、請求項1に係る本発明について説明す
る。請求項1に係る本発明は、十字花科植物の葉の水抽
出物からなる食品用抗酸化剤に関するものである。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail. First, the present invention according to claim 1 will be described. The present invention according to claim 1 relates to a food antioxidant comprising an aqueous extract of leaves of a cruciferous plant.
【0010】本発明でいう十字花科植物とは、十字形に
2枚ずつ対する四弁花を咲かせる植物を指し、アブラ
ナ、ダイコン、キャベツ、ハクサイ、チンゲンサイ、ワ
サビ、カラシ等のいわゆる油菜科植物が該当する。[0010] The term "cruciform plant" as used in the present invention refers to a plant in which four petals of two crosses are bloomed in a cross shape. Applicable.
【0011】請求項1に係る本発明の食品用抗酸化剤
は、このような十字花科植物の葉、つまり十字花科植物
の植物体から茎、根、花を除いた葉の部分の水抽出物か
らなるものであるが、多少、葉以外の茎や根等が混ざっ
ていても差し支えない。請求項1に係る本発明において
は、十字花科植物の葉の水抽出物を用いることが必要で
あって、十字花科以外の植物の葉の水抽出物を使用して
も、目的を達成することはできない。The antioxidant for food according to the present invention according to claim 1 is characterized in that the leaves of such a cruciferous plant, that is, the water of the leaf portion obtained by removing the stems, roots and flowers from the plant of the cruciferous plant. Although it is composed of an extract, stems and roots other than leaves may be mixed to some extent. In the present invention according to claim 1, it is necessary to use an aqueous extract of leaves of a cruciferous plant. I can't.
【0012】十字花科植物の葉の水抽出物は、十字花科
植物の葉重量に対し、約等量の水を添加してよく磨砕
し、次いで遠心分離又はろ過等により繊維分等の不溶物
を除いて得られる。十字花科植物の葉の水抽出物は、そ
のまま食品用抗酸化剤として用いても良いし、或いは濃
縮して食品用抗酸化剤として用いても良い。The water extract of the leaves of the cruciferous plant is thoroughly ground by adding about an equal amount of water to the leaf weight of the cruciferous plant, and then centrifuged or filtered to remove the fiber content. Obtained by removing insolubles. The water extract of the leaves of the cruciferous plant may be used as it is as a food antioxidant, or may be concentrated and used as a food antioxidant.
【0013】請求項1に係る本発明の食品用抗酸化剤
は、上記の如きものであるが、必要に応じて、その機能
を妨げない範囲内で、他の既知の抗酸化成分、例えば天
然抗酸化成分等を配合することもできる。The food antioxidant of the present invention according to claim 1 is as described above, but if necessary, other known antioxidant components, for example, a natural antioxidant, as long as the function is not hindered. An antioxidant component and the like can be added.
【0014】請求項1に係る本発明の食品用抗酸化剤
は、各種食品用、中でも加工食品用、とりわけマヨネー
ズやドレッシング類等の水中油型エマルジョン食品用の
抗酸化剤として有用である。請求項1に係る本発明の食
品用抗酸化剤は、従来の食品用抗酸化剤と同様に、一般
的には食品製造時に添加すれば良いが、食品製造後に用
いることもできる。その添加量は、抽出条件や食品の種
類等によって異なり、一義的に決定することはできない
が、一般的に言うならば、等量の水で抽出した場合、食
品に対して1重量%以上の割合である。1重量%未満で
あると、十分な抗酸化効果が得られない。添加量の上限
は特に制限はないが、50重量%を超えると、抽出物の
味が強くなり、風味上アンバランスを来たす為、好まし
くない。The antioxidant for food of the present invention according to claim 1 is useful as an antioxidant for various foods, especially for processed foods, especially for oil-in-water emulsion foods such as mayonnaise and dressings. The food antioxidant of the present invention according to claim 1 may be generally added at the time of food production, as with the conventional food antioxidant, but may be used after the food is produced. The amount of addition varies depending on the extraction conditions and the type of food, and cannot be unambiguously determined. However, generally speaking, when extracted with an equal amount of water, 1% by weight or more of the food is used. Percentage. If it is less than 1% by weight, a sufficient antioxidant effect cannot be obtained. The upper limit of the amount of addition is not particularly limited, but if it exceeds 50% by weight, the taste of the extract becomes strong and unbalanced in flavor, which is not preferable.
【0015】次に、請求項2に係る本発明について説明
する。請求項2に係る本発明の水中油型エマルジョン食
品は、十字花科植物の葉の水抽出物が添加されているこ
とを特徴とするものであるが、この十字花科植物の葉の
水抽出物については、請求項1に係る本発明の食品用抗
酸化剤に関する説明中に記載した通りである。Next, the present invention according to claim 2 will be described. The oil-in-water emulsion food of the present invention according to claim 2 is characterized in that an aqueous extract of leaves of a cruciferous plant is added, and the aqueous extract of leaves of the cruciferous plant is added. The product is as described in the description of the food antioxidant of the present invention according to claim 1.
【0016】請求項2に係る本発明の水中油型エマルジ
ョン食品とは、水相と油相とが水中油型に乳化され、エ
マルジョン状とされた食品である。請求項2に係る本発
明において、十字花科植物の葉の水抽出物は、水相を構
成する原料(水相原料)の一部として添加される。すな
わち、十字花科植物の葉の水抽出物は、この水相原料と
同様に用いられ、混合、溶解される。前記した如く、水
中油型エマルジョン食品への十字花科植物の葉の水抽出
物の添加量は、抽出条件や食品の種類等によって異な
り、一義的に決定することはできないが、一般的に言う
ならば、等量の水で抽出した場合、該食品に対して1重
量%以上の割合である。1重量%未満であると、十分な
抗酸化効果が得られない。添加量の上限は特に制限はな
いが、50重量%を超えると、抽出物の味が強くなり、
風味上アンバランスを来たす為、好ましくない。The oil-in-water emulsion food of the present invention according to claim 2 is a food in which an aqueous phase and an oil phase are emulsified into an oil-in-water type to form an emulsion. In the present invention according to claim 2, the water extract of the leaves of the cruciferous plant is added as a part of the raw material constituting the aqueous phase (aqueous phase raw material). That is, the water extract of the leaves of the cruciferous plant is used, mixed and dissolved in the same manner as the aqueous phase raw material. As described above, the amount of the water extract of the leaves of the cruciferous plant to be added to the oil-in-water emulsion food varies depending on the extraction conditions and the type of the food, and cannot be uniquely determined. Then, when extracted with an equal amount of water, the ratio is 1% by weight or more based on the food. If it is less than 1% by weight, a sufficient antioxidant effect cannot be obtained. The upper limit of the amount added is not particularly limited, but if it exceeds 50% by weight, the taste of the extract becomes strong,
It is not preferable because of imbalance in flavor.
【0017】請求項2に係る本発明の水中油型エマルジ
ョン食品の水相を構成する原料(水相原料)は、マヨネ
ーズやドレッシング類に使用される原料や配合割合に準
じればよく、特に制限はされない。通常用いられる水相
原料の例としては、水の他、食塩,砂糖,食酢,グルタ
ミン酸ナトリウム,イノシン酸ナトリウム等の調味料、
乳化剤、澱粉、ガム類、香辛料、着香料、着色料等があ
る。乳化剤としては、例えば卵黄、卵白、卵、乳蛋白、
大豆蛋白等が挙げられる。The raw material (water phase raw material) constituting the aqueous phase of the oil-in-water emulsion food of the present invention according to claim 2 may be in accordance with the raw materials used in mayonnaise and dressings and the mixing ratio, and is particularly limited. Is not done. Examples of commonly used aqueous phase raw materials include, in addition to water, seasonings such as salt, sugar, vinegar, sodium glutamate, sodium inosinate, and the like.
There are emulsifiers, starches, gums, spices, flavors, colorings and the like. As emulsifiers, for example, egg yolk, egg white, egg, milk protein,
Soy protein and the like.
【0018】一方、油相を構成する原料(油相原料)と
しては、通常、食品に添加可能な親油性の物質であれば
特に制限はなく、例えば、食用植物油脂や親油性のある
香辛料等が挙げられる。食用植物油脂としては、菜種
油、大豆油、サフラワー油、ヒマワリ油、トウモロコシ
油等が挙げられ、これらを単独で、又は2種以上を混合
して使用することができる。On the other hand, the raw material (oil phase raw material) constituting the oil phase is not particularly limited as long as it is a lipophilic substance that can be added to foods, and examples thereof include edible vegetable oils and fats and lipophilic spices. Is mentioned. Edible vegetable oils and fats include rapeseed oil, soybean oil, safflower oil, sunflower oil, corn oil and the like, and these can be used alone or as a mixture of two or more.
【0019】請求項2に係る本発明の水中油型エマルジ
ョン食品における油相と水相との配合比率は特に制限は
ないが、通常は油相10〜90重量%に対して、水相9
0〜10重量%、好ましくは油相30〜80重量%に対
して、水相70〜20重量%とする。ここで油相の比率
が10重量%未満では、調製された水中油型エマルジョ
ン食品が美味しくなく、一方、油相の比率が90重量%
を超えると、転相し易くなるので、いずれも好ましくな
い。The mixing ratio of the oil phase and the aqueous phase in the oil-in-water emulsion food of the present invention according to claim 2 is not particularly limited.
0 to 10% by weight, preferably 30 to 80% by weight of the oil phase and 70 to 20% by weight of the aqueous phase. Here, when the ratio of the oil phase is less than 10% by weight, the prepared oil-in-water emulsion food is not delicious, while the ratio of the oil phase is 90% by weight.
If more than 3, phase inversion is liable to occur, and both are not preferred.
【0020】請求項2に係る本発明の水中油型エマルジ
ョン食品の製造は、既知の手法によればよく、特に制限
されない。例えば、水以外の水相原料を水等に分散、溶
解し、これに油相原料を加えて一般的な撹拌機、例えば
市販の万能混合撹拌機により予備乳化する。次いで、コ
ロイドミル等の乳化機により仕上げ乳化を行うことによ
って、酸化安定性に優れた水中油型エマルジョン食品を
製造することができる。The production of the oil-in-water emulsion food of the present invention according to claim 2 may be performed by a known method, and is not particularly limited. For example, an aqueous phase material other than water is dispersed and dissolved in water or the like, and the oil phase material is added thereto, and pre-emulsified by a general stirrer, for example, a commercially available universal mixing stirrer. Next, by performing finish emulsification using an emulsifier such as a colloid mill, an oil-in-water emulsion food having excellent oxidation stability can be produced.
【0021】このようにして製造された水中油型エマル
ジョン食品は、十字花科植物の葉の水抽出物が添加され
ていることにより、酸化安定性に優れたものとなってい
る。The oil-in-water emulsion food produced in this way has excellent oxidation stability due to the addition of the water extract of the leaves of the cruciferous plant.
【0022】[0022]
【実施例】次に、本発明を実施例により詳しく説明する
が、本発明の範囲をこれらの実施例に限定するものでな
いことは言うまでもない。EXAMPLES Next, the present invention will be described in more detail with reference to examples, but it goes without saying that the scope of the present invention is not limited to these examples.
【0023】比較例1 第1表に示す組成で水中油型エマルジョン食品を調製し
た。なお、以下の説明において、この比較例1の組成を
「基本配合組成」と称することにする。すなわち、第1
表に示す組成で水相原料である卵黄、食塩、食酢(10
%酸度)及び水を混合溶解して水相原料を調製し、この
水相原料に油相原料として菜種油を加え、ホバルトミキ
サーで予備乳化した。次いで、コロイドミル(クリアラ
ンス:5/10000インチ、回転数:3000rp
m)により仕上げ乳化を行って、水中油型エマルジョン
食品を得た。Comparative Example 1 An oil-in-water emulsion food having the composition shown in Table 1 was prepared. In the following description, the composition of Comparative Example 1 will be referred to as "basic composition". That is, the first
Egg yolk, salt, vinegar (10
% Acidity) and water were mixed and dissolved to prepare an aqueous phase raw material, and rapeseed oil was added to the aqueous phase raw material as an oil phase raw material, followed by preliminary emulsification with a Hobart mixer. Next, a colloid mill (clearance: 5 / 10,000 inches, rotation speed: 3000 rpm)
m) to carry out finish emulsification to obtain an oil-in-water emulsion food.
【0024】得られた水中油型エマルジョン食品につい
て、酸化安定性を評価した。結果を第1表に示す。な
お、酸化安定性の評価は以下のようにして行った。得ら
れた水中油型エマルジョン食品を約200g容のガラス
瓶に約100g充填し、1重のサランラップで口を密封
し、34℃、暗所の条件に保管する。5週間後、水中油
型エマルジョン食品の表層の分離状態により酸化安定性
を次の3段階で評価した。The oxidative stability of the obtained oil-in-water emulsion food was evaluated. The results are shown in Table 1. The oxidation stability was evaluated as follows. About 100 g of the obtained oil-in-water emulsion food is filled in a glass bottle of about 200 g capacity, the mouth is sealed with a single Saran wrap, and stored at 34 ° C. in a dark place. Five weeks later, the oxidative stability was evaluated in the following three stages based on the state of separation of the surface layer of the oil-in-water emulsion food.
【0025】・酸化安定性の評価 安定:油分離していない。 やや安定性:表層に部分的な分離が認められる。 不安定:表層が殆ど分離している。Evaluation of oxidation stability Stable: no oil separation. Slightly stable: partial separation is observed in the surface layer. Unstable: The surface layer is almost separated.
【0026】実施例1 1)ダイコンの葉の水抽出物の調製 ダイコンの葉に等量の水を加え、家庭用のミキサーにて
十分に磨砕した後、磨砕液を10,000rpm、20
分間の条件下で遠心分離を行い、上澄み液よりダイコン
の葉の水抽出物を得た。Example 1 1) Preparation of water extract of radish leaves An equal amount of water was added to radish leaves, and the mixture was sufficiently ground with a household mixer.
The mixture was centrifuged under the conditions of minutes, and an aqueous extract of radish leaves was obtained from the supernatant.
【0027】2)水中油型エマルジョン食品の調製 比較例1において、第1表に示す基本配合組成の水中油
型エマルジョン食品中の水1重量%を、上記1)で得ら
れたダイコンの葉の水抽出物1重量%に置き換えたこと
以外は、比較例1と同様にして、水中油型エマルジョン
食品を調製した。すなわち、水相原料である卵黄、食
塩、食酢(10%酸度)及び水の他に、上記1)で調製
したダイコンの葉の水抽出物を混合溶解して水相を調製
した。この水相に菜種油を加え、ホバルトミキサーで予
備乳化した。次いで、コロイドミル(クリアランス:5
/10000インチ、回転数:3000rpm)により
仕上げ乳化を行って、水中油型エマルジョン食品を得
た。2) Preparation of oil-in-water emulsion food In Comparative Example 1, 1% by weight of water in the oil-in-water emulsion food having the basic composition shown in Table 1 was used for the radish leaves obtained in 1) above. An oil-in-water emulsion food was prepared in the same manner as in Comparative Example 1 except that the water extract was replaced with 1% by weight. That is, an aqueous phase was prepared by mixing and dissolving an aqueous extract of radish leaves prepared in the above 1) in addition to the aqueous phase raw materials egg yolk, salt, vinegar (10% acidity) and water. Rapeseed oil was added to the aqueous phase and pre-emulsified with a Hobart mixer. Next, a colloid mill (clearance: 5
/ 10000 inches, number of revolutions: 3000 rpm) to carry out finish emulsification to obtain an oil-in-water emulsion food.
【0028】得られた水中油型エマルジョン食品につい
て、比較例1と同様にして酸化安定性を評価した。結果
を第1表に示す。The oxidative stability of the obtained oil-in-water emulsion food was evaluated in the same manner as in Comparative Example 1. The results are shown in Table 1.
【0029】実施例2 1)キャベツの葉の水抽出物の調製 実施例1の1)において、ダイコンの葉の代わりに、キ
ャベツの葉を用いたこと以外は実施例1の1)と同様に
して、キャベツの葉の水抽出物を得た。Example 2 1) Preparation of water extract of cabbage leaf In the same manner as 1) of Example 1 except that cabbage leaf was used in place of radish leaf in 1) of Example 1 Thus, an aqueous extract of cabbage leaves was obtained.
【0030】2)水中油型エマルジョン食品の調製 実施例1の2)において、実施例1の1)で得られたダ
イコンの葉の水抽出物1重量%の代わりに、上記1)で
得られたキャベツの葉の水抽出物1重量%を用いたこと
以外は、実施例1の2)と同様にして水中油型エマルジ
ョン食品を調製し、その酸化安定性を評価した。結果を
第1表に示す。2) Preparation of Oil-in-Water Emulsion Food In Example 1-2), 1% by weight of the water extract of radish leaves obtained in Example 1-1) was obtained in the above 1). An oil-in-water emulsion food was prepared in the same manner as in 2) of Example 1 except that 1% by weight of an aqueous extract of cabbage leaves was used, and its oxidative stability was evaluated. The results are shown in Table 1.
【0031】実施例3 実施例2の2)において、キャベツの葉の水抽出物の使
用量を1重量%から5重量%に変えたこと以外は、実施
例2の2)と同様にして水中油型エマルジョン食品を調
製し、その酸化安定性を評価した。結果を第1表に示
す。Example 3 The procedure of Example 2-2) was repeated except that the amount of the water extract of cabbage leaves was changed from 1% by weight to 5% by weight. Oil-type emulsion foods were prepared and their oxidative stability was evaluated. The results are shown in Table 1.
【0032】比較例2 1)ミツバの葉の水抽出物の調製 実施例1の1)において、ダイコンの葉の代わりに、ミ
ツバの葉を用いたこと以外は実施例1の1)と同様にし
て、ミツバの葉の水抽出物を得た。COMPARATIVE EXAMPLE 2 1) Preparation of water extract of honeybee leaf In the same manner as in Example 1-1), except that radish leaves were used instead of radish leaves. Thus, an aqueous extract of honeybee leaves was obtained.
【0033】2)水中油型エマルジョン食品の調製 実施例1の2)において、実施例1の1)で得られたダ
イコンの葉の水抽出物1重量%の代わりに、上記1)で
得られたミツバの葉の水抽出物5重量%を用いたこと以
外は、実施例1の2)と同様にして水中油型エマルジョ
ン食品を調製し、その酸化安定性を評価した。結果を第
1表に示す。2) Preparation of Oil-in-Water Emulsion Food In Example 1-2), 1% by weight of the water extract of radish leaves obtained in Example 1-1) was obtained in the above 1). An oil-in-water emulsion food was prepared in the same manner as in 2) of Example 1 except that 5% by weight of the water extract of the honeybee leaf was used, and its oxidative stability was evaluated. The results are shown in Table 1.
【0034】比較例3 実施例2の2)において、キャベツの葉の水抽出物の使
用量を1重量%から0.5重量%に変えたこと以外は、
実施例2の2)と同様にして水中油型エマルジョン食品
を調製し、その酸化安定性を評価した。結果を第1表に
示す。Comparative Example 3 The procedure of Example 2-2) was repeated except that the amount of the water extract of cabbage leaves was changed from 1% by weight to 0.5% by weight.
An oil-in-water emulsion food was prepared in the same manner as in 2) of Example 2, and the oxidative stability was evaluated. The results are shown in Table 1.
【0035】[0035]
【表1】第1表[原料の組成(重量%)及び酸化安定性
の評価] Table 1 [Evaluation of raw material composition (% by weight) and oxidation stability]
【0036】第1表から、以下のことが分かる。基本配
合組成で作成した比較例1の水中油型エマルジョン食品
は、酸化安定性が低い。これに対し、基本配合組成にお
ける水の一部(1.0重量%)をダイコンの葉の水抽出
物やキャベツの葉の水抽出物に置き換えて調製した実施
例1や実施例2の水中油型エマルジョン食品は、酸化安
定性が高い。このことから、ダイコンの葉の水抽出物や
キャベツの葉の水抽出物を添加することによって、水中
油型エマルジョン食品の酸化安定性が向上することが明
らかである。Table 1 shows the following. The oil-in-water emulsion food of Comparative Example 1 prepared with the basic composition has low oxidation stability. On the other hand, the oil-in-water of Examples 1 and 2 prepared by replacing a part (1.0% by weight) of water in the basic composition with a water extract of radish leaves or a water extract of cabbage leaves. Type emulsion foods have high oxidation stability. From this, it is clear that the oxidative stability of the oil-in-water emulsion food is improved by adding the water extract of radish leaves and the water extract of cabbage leaves.
【0037】また、実施例3のようにキャベツの葉の水
抽出物を5重量%分添加した場合も、水中油型エマルジ
ョン食品の酸化安定性が高いことが明らかである。従っ
て、十字花科植物の葉の水抽出物を添加することによ
り、水中油型エマルジョン食品の酸化安定性が改善され
ることが分かる。これに対して、ミツバの葉の水抽出物
を5重量%分添加して調製した比較例2の水中油型エマ
ルジョン食品は、油分離が見られ、やや不安定と評価さ
れた。ミツバは十字花科植物ではないことから、十字花
科植物以外の植物の葉の水抽出物を添加しても水中油型
エマルジョン食品の酸化安定性は改善されないことが明
らかとなった。さらに、比較例3に示すように、キャベ
ツの葉の水抽出物の添加量が0.5重量%である場合に
は、十分な抗酸化効果が得られないことから、十字花科
植物の葉の水抽出物の添加量が1重量%未満であると、
十分な抗酸化効果が得られないことが分かる。Also, when the water extract of cabbage leaf was added in an amount of 5% by weight as in Example 3, it is clear that the oil-in-water emulsion food has high oxidative stability. Therefore, it is understood that the oxidative stability of the oil-in-water emulsion food is improved by adding the water extract of the leaves of the cruciferous plant. On the other hand, the oil-in-water emulsion food of Comparative Example 2, which was prepared by adding 5% by weight of the water extract of honeybee leaf, showed oil separation and was evaluated as somewhat unstable. Since honeybees are not cruciferous plants, it was revealed that the addition of an aqueous extract of leaves of plants other than cruciferous plants did not improve the oxidative stability of oil-in-water emulsion foods. Further, as shown in Comparative Example 3, when the amount of the water extract of cabbage leaves was 0.5% by weight, a sufficient antioxidant effect was not obtained, and thus the leaves of the cruciferous plants were not obtained. When the amount of the water extract is less than 1% by weight,
It turns out that a sufficient antioxidant effect cannot be obtained.
【0038】[0038]
【発明の効果】請求項1に係る本発明の食品用抗酸化剤
は、天然物であり、食用されている十字花科植物の葉の
水抽出物からなるので、化学物質からなる抗酸化剤のよ
うに消費者が生体機能への影響を懸念することなく、安
心して使用することができる。その上、食品に使用され
ることにより優れた酸化安定性を付与することが可能で
ある。The antioxidant for food according to the present invention according to claim 1 is a natural product, which is composed of an aqueous extract of leaves of edible cruciferous plants, and is therefore composed of a chemical substance. As described above, the consumer can use the apparatus without worrying about the influence on the biological function. In addition, it is possible to impart excellent oxidative stability when used in foods.
【0039】請求項2に係る本発明の水中油型エマルジ
ョン食品は、天然物であり、食用されている十字花科植
物の葉の水抽出物が添加されているので、化学物質から
なる抗酸化剤のように消費者が生体機能への影響を懸念
することなく、安心して食することができる上に、優れ
た酸化安定性を付与するものである。The oil-in-water emulsion food of the present invention according to claim 2 is a natural product, to which an aqueous extract of leaves of edible cruciferous plants is added. Unlike foods, the foods can be eaten with confidence without the consumer having to worry about the effects on biological functions, and also provide excellent oxidation stability.
Claims (2)
品用抗酸化剤。1. An antioxidant for food comprising an aqueous extract of leaves of a cruciferous plant.
ていることを特徴とする水中油型エマルジョン食品。2. An oil-in-water emulsion food to which an aqueous extract of leaves of a cruciferous plant is added.
Priority Applications (1)
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JP26151299A JP2001078738A (en) | 1999-09-16 | 1999-09-16 | Antioxidant for food and oil-in-water type emulsion food having excellent oxidation stability |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26151299A JP2001078738A (en) | 1999-09-16 | 1999-09-16 | Antioxidant for food and oil-in-water type emulsion food having excellent oxidation stability |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2001078738A true JP2001078738A (en) | 2001-03-27 |
Family
ID=17362944
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Application Number | Title | Priority Date | Filing Date |
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JP26151299A Withdrawn JP2001078738A (en) | 1999-09-16 | 1999-09-16 | Antioxidant for food and oil-in-water type emulsion food having excellent oxidation stability |
Country Status (1)
Country | Link |
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JP (1) | JP2001078738A (en) |
-
1999
- 1999-09-16 JP JP26151299A patent/JP2001078738A/en not_active Withdrawn
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